CN108218356A - A kind of preparation method of solid waste compound water seepage material - Google Patents
A kind of preparation method of solid waste compound water seepage material Download PDFInfo
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- CN108218356A CN108218356A CN201711443050.7A CN201711443050A CN108218356A CN 108218356 A CN108218356 A CN 108218356A CN 201711443050 A CN201711443050 A CN 201711443050A CN 108218356 A CN108218356 A CN 108218356A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
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- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
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- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
- C04B2111/00284—Materials permeable to liquids
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00612—Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
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- C08L2205/00—Polymer mixtures characterised by other features
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Ceramic Engineering (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
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- Road Paving Structures (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
A kind of preparation method of solid waste compound water seepage material, the seepage material are divided into base material and are cast in the surface material on the base material surface, and preparation method includes the following steps：In parts by weight, take 45 ~ 55 parts of cement, 120 ~ 180 parts of solid waste coarse aggregate, 100 ~ 120 parts of solid waste fine aggregate, 10 ~ 20 parts of additive, 15 ~ 25 parts of water, water and additive are added in cement, stir 1 ~ 2min, it is put into solid waste coarse aggregate and continues 1 ~ 2min of stirring, solid waste fine aggregate is added, after-pouring is stirred evenly and the base material that thickness is 2 ~ 3cm is made, it is spare；In parts by weight, take 80 ~ 100 parts of thermoplastics, 5 ~ 10 parts of water-absorbing resins and 30 ~ 35 parts of reinforcing fibers, thermoplastic is put into injection molding machine and is heated to 75 ~ 110 DEG C, water-absorbing resin and reinforcing fiber are added in several times, and the surface material that thickness is 0.5 ~ 1cm is formed in the base material surface injection of preparation after stirring evenly；Seepage material prepared by the present invention can take into account water penetration and crushing resistance.
Description
Technical field
The present invention relates to seepage material field, specifically a kind of preparation side of solid waste compound water seepage material
Method.
Background technology
City dweller occupies residence mainly by waterproof with granite, marble, glazed tile, cement and pitch etc. at present
Material be laid with city square, commercial street, pavement, community activity, the ground in parking lot etc. surround, hardened ground pair
The harm of urban environment is very big, and when raining, hardened ground prevents rainwater and directly infiltrates through ground, and completely ponding makes one
Trip become very inconvenient；And when not raining, hardened ground is again extremely dry, easily accumulates dust, dust is caused to fly everywhere
The situation raised, ground and air carry out heat, moisture exchanges relatively difficult, adjust urban surface temperature, the ability of humidity
And then it being lower, the radiant heat of the sun can also largely be reflected, retain and be discharged in ground, substantially increase the tropical island effect in city,
Greatly reduce The Surroundings in Cities comfort level.
The dank material of some water-permeable bricks of building materials field, porous pavement etc. mainly uses bulky grain bone currently on the market
Frame and cement composition are formed using artificial treatment sand and high polymer binder, the problem is that cement water-permeable brick permeability rate
Not high or compression strength is insufficient, this two aspects performance difficulty is taken into account, while the exploitation of raw material causes the destruction to environment；According to system
The discharge capacity of the solid waste such as meter, slag, ferrochrome slag, gangue is very big, and about 180Kg can all be discharged by often producing 1 ton of crude steel
Slag, the discharge capacity of ferrochrome slag is being increased every year with the speed more than 400,000 tons, if not comprehensively utilized, these solid wastes
Object will deposit river, filling water channel, appropriation of land, polluted source and air, cause environmental hazard；In view of these solid waste
Inside is porous structure, but has certain intensity, therefore can be used for solid waste to manufacture seepy material, can both be reduced
The discharge of solid waste, and resource can be utilized, achieve the purpose that two-win.
Invention content
The purpose of the present invention is to solve the deficiency of above-mentioned technical problem, the present invention proposes that a kind of solid waste is compound
The preparation method of seepage material, the seepage material of preparation are included by cement, solid waste coarse aggregate, solid waste fine aggregate
The base material of composition and the surface material formed by thermoplastic, water-absorbing resin, reinforcing fiber can take into account water penetration and resist
Pressure property.
Present invention deficiency to solve above-mentioned technical problem and the technical solution adopted is that：A kind of solid waste composite cementation
The preparation method of water material, the seepage material are divided into base material and are cast in the face layer material on the base material surface
Material, preparation method include the following steps：
（1）In parts by weight, 45 ~ 55 parts of cement, 120 ~ 180 parts of solid waste coarse aggregate, solid waste fine aggregate 100 are taken
~ 120 parts, 10 ~ 20 parts of additive, 15 ~ 25 parts of water, water and additive are added in cement, 1 ~ 2min is stirred, is put into solid waste
Object coarse aggregate continues 1 ~ 2min of stirring, adds solid waste fine aggregate, and it is 2 ~ 3cm's to stir evenly after-pouring and thickness is made
Base material, it is spare；
（2）In parts by weight, 80 ~ 100 parts of thermoplastics, 5 ~ 10 parts of water-absorbing resins and 30 ~ 35 parts of reinforcing fibers are taken, by thermoplastic
Property plastics be put into injection molding machine and be heated to 75 ~ 110 DEG C, water-absorbing resin and reinforcing fiber are added in several times, in step after stirring evenly
Suddenly（1）The base material surface injection of preparation forms the surface material that thickness is 0.5 ~ 1cm.
Further, the preparation method of the solid waste coarse aggregate includes the following steps：
（1）The slag, ferrochrome slag, gangue that are come out from high temperature are first passed through water quenching and form the coarse inflated slag in internal aperture；
（2）One or more of inflated slag of slag, ferrochrome slag, gangue is taken, is put into crusher and is crushed to 5 ~ 10mm's
Particle；
（3）Take in parts by weight again 5~10 parts of silicone oil, 20~30 parts of polyacrylate emulsions, 0.5~1 part of surfactant, 5~
10 parts of organic solvents and 89 ~ 100 parts of water are deployed into modification liquid, and broken particle is put into progress surface hydrophobicity in modification liquid changes
Property processing, dried after being disposed and can be prepared by solid waste coarse aggregate.
Further, the preparation method of the solid waste fine aggregate includes the following steps：
（1）The slag come out from high temperature, ferrochrome slag, gangue are first passed through into natural cooling and form tiny closely knit in internal aperture
Slag；
（2）Take one or more of closely knit slag of slag, ferrochrome slag, gangue, be put into after crushing in ball mill grinding into
Fine powder adds the kaolin of fine powder total weight 10 ~ 15% and the water of fine powder total weight 3 ~ 5%, is granulated and controls after mixing
Grain size is 0.1 ~ 6mm, and the furnace cooling after 1300 ~ 1350 DEG C of 1 ~ 2h of sintering is put into high temperature furnace after dry, and obtained grain size is
The particle of 0.08 ~ 0.5mm, it is spare；
（3）Take in parts by weight again 5~10 parts of silicone oil, 20~30 parts of polyacrylate emulsions, 0.5~1 part of surfactant, 5~
10 parts of organic solvents and 89 ~ 100 parts of water are deployed into modification liquid, and particle after cooling is put into progress surface hydrophobicity in modification liquid changes
Property processing, dried after being disposed and can be prepared by solid waste fine aggregate.
Further, the cement is aluminate cement, and the additive is antifreezing agent.
Further, the thermoplastic for polyethylene, polypropylene, polyvinyl chloride, makrolon, polyvinyl alcohol,
Any one of polyacrylic acid, Maranyl.
Further, the reinforcing fiber is degreasing cotton fiber, degreasing flaxen fiber, bamboo fibre, polyethylene fibre, poly- third
Any one of alkene fiber, polyvinyl chloride fibre, styroflex, Fypro, polyester fiber or arbitrary several group
It closes.
The beneficial effects of the invention are as follows：
The present invention is to provide a kind of solid waste compound water seepage materials, are divided into base material and are cast in base material surface
Surface material, base material include following components：Cement, solid waste coarse aggregate, solid waste fine aggregate, additive
And water, solid waste coarse aggregate include being crushed to grain size by the mixture of one or more of slag, ferrochrome slag, gangue
For the particle of 5 ~ 10mm, solid waste fine aggregate includes the mixture by one or more of slag, ferrochrome slag, gangue
The grain size that fine powder obtained is fired into is the particle of 0.08 ~ 5mm, is then placed in progress surface hydrophobicity modification in modification liquid,
One layer of dense film is formed in aggregate surface and pore surface, interfacial transition zone can be optimized, is blocked and outside moisture and ion
Interchange channel avoids aggregate water absorbing properties from being lower, while hydrophobic treatment can flow through the moisture of aggregate and aggregate internal void
It is not absorbed by aggregate, permeates down；Surface material is using thermoplastic as matrix, using water-absorbing resin and reinforcing fiber as enhancing
Made from body is dispersed in the thermoplastic matrix, water-absorbing resin can be by the moisture absorption on surface, the water not absorbed
Divide and permeated toward base material, the intensity of material can be improved by increasing reinforcing fiber；Utilize the solids such as slag, ferrochrome slag, gangue
Waste makes seepage material, turns waste into wealth, cheap compared with resin type seepy material, water penetration is good, can answer extensively
For the pervious bed on the road surfaces such as pavement, park and residential quarters, conducive to ground water circulation.
Specific embodiment
With reference to specific embodiment, the present invention is further elaborated.
Its specific embodiment is：
A kind of preparation method of solid waste compound water seepage material, the seepage material are divided into base material and are cast in institute
The surface material on base material surface is stated, preparation method includes the following steps：
（1）In parts by weight, 45 ~ 55 parts of cement, 120 ~ 180 parts of solid waste coarse aggregate, solid waste fine aggregate 100 are taken
~ 120 parts, 10 ~ 20 parts of additive, 15 ~ 25 parts of water, water and additive are added in cement, 1 ~ 2min is stirred, is put into solid waste
Object coarse aggregate continues 1 ~ 2min of stirring, adds solid waste fine aggregate, and it is 2 ~ 3cm's to stir evenly after-pouring and thickness is made
Base material, it is spare；
（2）In parts by weight, 80 ~ 100 parts of thermoplastics, 5 ~ 10 parts of water-absorbing resins and 30 ~ 35 parts of reinforcing fibers are taken, by thermoplastic
Property plastics be put into injection molding machine and be heated to 75 ~ 110 DEG C, water-absorbing resin and reinforcing fiber are added in several times, in step after stirring evenly
Suddenly（1）The base material surface injection of preparation forms the surface material that thickness is 0.5 ~ 1cm.
Further, the preparation method of the solid waste coarse aggregate includes the following steps：
（1）The slag, ferrochrome slag, gangue that are come out from high temperature are first passed through water quenching and form the coarse inflated slag in internal aperture；
（2）One or more of inflated slag of slag, ferrochrome slag, gangue is taken, is put into crusher and is crushed to 5 ~ 10mm's
Particle；
（3）Take in parts by weight again 5~10 parts of silicone oil, 20~30 parts of polyacrylate emulsions, 0.5~1 part of surfactant, 5~
10 parts of organic solvents and 89 ~ 100 parts of water are deployed into modification liquid, and broken particle is put into progress surface hydrophobicity in modification liquid changes
Property processing, dried after being disposed and can be prepared by solid waste coarse aggregate.
Further, the preparation method of the solid waste fine aggregate includes the following steps：
（1）The slag come out from high temperature, ferrochrome slag, gangue are first passed through into natural cooling and form tiny closely knit in internal aperture
Slag；
（2）Take one or more of closely knit slag of slag, ferrochrome slag, gangue, be put into after crushing in ball mill grinding into
Fine powder adds the kaolin of fine powder total weight 10 ~ 15% and the water of fine powder total weight 3 ~ 5%, is granulated and controls after mixing
Grain size is 0.1 ~ 6mm, and the furnace cooling after 1300 ~ 1350 DEG C of 1 ~ 2h of sintering is put into high temperature furnace after dry, and obtained grain size is
The particle of 0.08 ~ 0.5mm, it is spare；
（3）Take in parts by weight again 5~10 parts of silicone oil, 20~30 parts of polyacrylate emulsions, 0.5~1 part of surfactant, 5~
10 parts of organic solvents and 89 ~ 100 parts of water are deployed into modification liquid, and particle after cooling is put into progress surface hydrophobicity in modification liquid changes
Property processing, dried after being disposed and can be prepared by solid waste fine aggregate.
Further, the cement is aluminate cement, and the additive is antifreezing agent.
Further, the thermoplastic for polyethylene, polypropylene, polyvinyl chloride, makrolon, polyvinyl alcohol,
Any one of polyacrylic acid, Maranyl.
Further, the reinforcing fiber is degreasing cotton fiber, degreasing flaxen fiber, bamboo fibre, polyethylene fibre, poly- third
Any one of alkene fiber, polyvinyl chloride fibre, styroflex, Fypro, polyester fiber or arbitrary several group
It closes.
Embodiment 1
A kind of preparation method of solid waste compound water seepage material, the seepage material are divided into base material and are cast in institute
The surface material on base material surface is stated, preparation method includes the following steps：
（1）In parts by weight, 45 parts of cement, 120 parts of solid waste coarse aggregate, 100 parts of solid waste fine aggregate, additional is taken
10 parts of agent, 15 parts of water add in water and additive in cement, stir 1 ~ 2min, are put into solid waste coarse aggregate and continue stirring 1
~ 2min adds solid waste fine aggregate, stirs evenly after-pouring and the base material that thickness is 2cm is made, spare；
（2）In parts by weight, 80 parts of thermoplastics, 5 parts of water-absorbing resins and 30 parts of reinforcing fibers are taken, thermoplastic is put into
75 DEG C are heated in injection molding machine, water-absorbing resin and reinforcing fiber are added in several times, in step after stirring evenly（1）The base of preparation
Material surface injects the surface material to form that thickness is 0.5cm.
Further, the preparation method of the solid waste coarse aggregate includes the following steps：
（1）The slag, ferrochrome slag, gangue that are come out from high temperature are first passed through water quenching and form the coarse inflated slag in internal aperture；
（2）One or more of inflated slag of slag, ferrochrome slag, gangue is taken, is put into crusher and is crushed to 5 ~ 10mm's
Particle；
（3）Take 5 parts of silicone oil, 20 parts of polyacrylate emulsions, 0.5 part of surfactant, 5 parts of organic solvents and 89 in parts by weight again
Part water is deployed into modification liquid, and broken particle is put into progress surface hydrophobicity modification in modification liquid, is dried in the air after being disposed
It is dry to can be prepared by solid waste coarse aggregate.
Further, the preparation method of the solid waste fine aggregate includes the following steps：
（1）The slag come out from high temperature, ferrochrome slag, gangue are first passed through into natural cooling and form tiny closely knit in internal aperture
Slag；
（2）Take one or more of closely knit slag of slag, ferrochrome slag, gangue, be put into after crushing in ball mill grinding into
Fine powder adds the kaolin of fine powder total weight 10% and the water of fine powder total weight 3%, is granulated after mixing and controls the grain size to be
0.1 ~ 6mm is put into high temperature furnace the furnace cooling after 1300 DEG C of 1 ~ 2h of sintering after dry, that grain size is 0.08 ~ 0.5mm is made
Grain, it is spare；
（3）Take 5 parts of silicone oil, 20 parts of polyacrylate emulsions, 0.5 part of surfactant, 5 parts of organic solvents and 89 in parts by weight again
Part water is deployed into modification liquid, and particle after cooling is put into progress surface hydrophobicity modification in modification liquid, is dried in the air after being disposed
It is dry to can be prepared by solid waste fine aggregate.
Further, the cement is aluminate cement, and the additive is antifreezing agent.
Further, the thermoplastic for polyethylene, polypropylene, polyvinyl chloride, makrolon, polyvinyl alcohol,
Any one of polyacrylic acid, Maranyl.
Further, the reinforcing fiber is degreasing cotton fiber, degreasing flaxen fiber, bamboo fibre, polyethylene fibre, poly- third
Any one of alkene fiber, polyvinyl chloride fibre, styroflex, Fypro, polyester fiber or arbitrary several group
It closes.
Embodiment 2
A kind of preparation method of solid waste compound water seepage material, the seepage material are divided into base material and are cast in institute
The surface material on base material surface is stated, preparation method includes the following steps：
（1）In parts by weight, 50 parts of cement, 150 parts of solid waste coarse aggregate, 110 parts of solid waste fine aggregate, additional is taken
15 parts of agent, 20 parts of water add in water and additive in cement, stir 1 ~ 2min, are put into solid waste coarse aggregate and continue stirring 1
~ 2min adds solid waste fine aggregate, stirs evenly after-pouring and the base material that thickness is 2.5cm is made, spare；
（2）In parts by weight, 90 parts of thermoplastics, 8 parts of water-absorbing resins and 32 parts of reinforcing fibers are taken, thermoplastic is put into
85 DEG C are heated in injection molding machine, water-absorbing resin and reinforcing fiber are added in several times, in step after stirring evenly（1）The base of preparation
Material surface injects the surface material to form that thickness is 0.8cm.
Further, the preparation method of the solid waste coarse aggregate includes the following steps：
（1）The slag, ferrochrome slag, gangue that are come out from high temperature are first passed through water quenching and form the coarse inflated slag in internal aperture；
（2）One or more of inflated slag of slag, ferrochrome slag, gangue is taken, is put into crusher and is crushed to 5 ~ 10mm's
Particle；
（3）Take 8 parts of silicone oil, 25 parts of polyacrylate emulsions, 0.8 part of surfactant, 8 parts of organic solvents and 95 in parts by weight again
Part water is deployed into modification liquid, and broken particle is put into progress surface hydrophobicity modification in modification liquid, is dried in the air after being disposed
It is dry to can be prepared by solid waste coarse aggregate.
Further, the preparation method of the solid waste fine aggregate includes the following steps：
（1）The slag come out from high temperature, ferrochrome slag, gangue are first passed through into natural cooling and form tiny closely knit in internal aperture
Slag；
（2）Take one or more of closely knit slag of slag, ferrochrome slag, gangue, be put into after crushing in ball mill grinding into
Fine powder adds the kaolin of fine powder total weight 12% and the water of fine powder total weight 4%, is granulated after mixing and controls the grain size to be
0.1 ~ 6mm is put into high temperature furnace the furnace cooling after 1320 DEG C of 1 ~ 2h of sintering after dry, that grain size is 0.08 ~ 0.5mm is made
Grain, it is spare；
（3）Take 8 parts of silicone oil, 25 parts of polyacrylate emulsions, 0.8 part of surfactant, 8 parts of organic solvents and 95 in parts by weight again
Part water is deployed into modification liquid, and particle after cooling is put into progress surface hydrophobicity modification in modification liquid, is dried in the air after being disposed
It is dry to can be prepared by solid waste fine aggregate.
Further, the cement is aluminate cement, and the additive is antifreezing agent.
Further, the thermoplastic for polyethylene, polypropylene, polyvinyl chloride, makrolon, polyvinyl alcohol,
Any one of polyacrylic acid, Maranyl.
Further, the reinforcing fiber is degreasing cotton fiber, degreasing flaxen fiber, bamboo fibre, polyethylene fibre, poly- third
Any one of alkene fiber, polyvinyl chloride fibre, styroflex, Fypro, polyester fiber or arbitrary several group
It closes.
Embodiment 3
A kind of preparation method of solid waste compound water seepage material, the seepage material are divided into base material and are cast in institute
The surface material on base material surface is stated, preparation method includes the following steps：
（1）In parts by weight, 55 parts of cement, 180 parts of solid waste coarse aggregate, 120 parts of solid waste fine aggregate, additional is taken
20 parts of agent, 25 parts of water add in water and additive in cement, stir 1 ~ 2min, are put into solid waste coarse aggregate and continue stirring 1
~ 2min adds solid waste fine aggregate, stirs evenly after-pouring and the base material that thickness is 3cm is made, spare；
（2）In parts by weight, 100 parts of thermoplastics, 10 parts of water-absorbing resins and 35 parts of reinforcing fibers are taken, thermoplastic is put
Enter and 110 DEG C are heated in injection molding machine, water-absorbing resin and reinforcing fiber are added in several times, in step after stirring evenly（1）It prepares
Base material surface injection forms the surface material that thickness is 1cm.
Further, the preparation method of the solid waste coarse aggregate includes the following steps：
（1）The slag, ferrochrome slag, gangue that are come out from high temperature are first passed through water quenching and form the coarse inflated slag in internal aperture；
（2）One or more of inflated slag of slag, ferrochrome slag, gangue is taken, is put into crusher and is crushed to 5 ~ 10mm's
Particle；
（3）Take in parts by weight again 10 parts of silicone oil, 30 parts of polyacrylate emulsions, 1 part of surfactant, 10 parts of organic solvents and
100 parts of water are deployed into modification liquid, broken particle are put into progress surface hydrophobicity modification in modification liquid, after being disposed
It dries and can be prepared by solid waste coarse aggregate.
Further, the preparation method of the solid waste fine aggregate includes the following steps：
（1）The slag come out from high temperature, ferrochrome slag, gangue are first passed through into natural cooling and form tiny closely knit in internal aperture
Slag；
（2）Take one or more of closely knit slag of slag, ferrochrome slag, gangue, be put into after crushing in ball mill grinding into
Fine powder adds the kaolin of fine powder total weight 15% and the water of fine powder total weight 5%, is granulated after mixing and controls the grain size to be
0.1 ~ 6mm is put into high temperature furnace the furnace cooling after 1350 DEG C of 1 ~ 2h of sintering after dry, that grain size is 0.08 ~ 0.5mm is made
Grain, it is spare；
（3）Take in parts by weight again 10 parts of silicone oil, 30 parts of polyacrylate emulsions, 1 part of surfactant, 10 parts of organic solvents and
100 parts of water are deployed into modification liquid, particle after cooling are put into progress surface hydrophobicity modification in modification liquid, after being disposed
It dries and can be prepared by solid waste fine aggregate.
Further, the cement is aluminate cement, and the additive is antifreezing agent.
Further, the thermoplastic for polyethylene, polypropylene, polyvinyl chloride, makrolon, polyvinyl alcohol,
Any one of polyacrylic acid, Maranyl.
Further, the reinforcing fiber is degreasing cotton fiber, degreasing flaxen fiber, bamboo fibre, polyethylene fibre, poly- third
Any one of alkene fiber, polyvinyl chloride fibre, styroflex, Fypro, polyester fiber or arbitrary several group
It closes.
The existing water-permeable brick sample 1 prepared by general aggregate, the water-permeable brick sample prepared by sand are bought on the market
2, it is compared with the embodiment of the present invention 1, it is as a result as follows：
From the foregoing, it will be observed that solid waste compound water seepage material made from the method for the present invention, since solid waste is thick in base
The presence of aggregate and solid waste fine aggregate, and coarse aggregate and fine aggregate are also put into modification liquid and carry out at surface hydrophobicity modification
Reason forms one layer of dense film in aggregate surface and pore surface, can optimize interfacial transition zone, block with outside moisture and from
Sub- interchange channel avoids aggregate water absorbing properties from being lower, while hydrophobic treatment can flow through the water of aggregate and aggregate internal void
Divide and do not absorbed by aggregate, permeated down, therefore not only make base layer that there is certain intensity, while also there is centainly permeable
Property；Compared with the water-permeable brick sample 1 prepared by general aggregate, the water-permeable brick sample 2 prepared by sand, have higher intensity and
Preferable water penetration, and the present invention makes seepage material using solid waste such as slag, ferrochrome slag, gangues, turns waste into wealth,
Cheap, water penetration is good, the pervious bed on the road surfaces such as pavement, park and residential quarters is can be widely applied to, conducive to underground
Water recycles.
The foregoing description of the disclosed embodiments, only for professional and technical personnel in the field is enable to realize or use this
Invention.A variety of modifications of these embodiments will be apparent for those skilled in the art, institute herein
The General Principle of definition can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore,
The present invention is not intended to be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty
The consistent most wide range of point.
Claims (6)
1. a kind of preparation method of solid waste compound water seepage material, which is characterized in that the seepage material is divided into base
Material and the surface material for being cast in the base material surface, preparation method include the following steps：
（1）In parts by weight, 45 ~ 55 parts of cement, 120 ~ 180 parts of solid waste coarse aggregate, solid waste fine aggregate 100 are taken
~ 120 parts, 10 ~ 20 parts of additive, 15 ~ 25 parts of water, water and additive are added in cement, 1 ~ 2min is stirred, is put into solid waste
Object coarse aggregate continues 1 ~ 2min of stirring, adds solid waste fine aggregate, and it is 2 ~ 3cm's to stir evenly after-pouring and thickness is made
Base material, it is spare；
（2）In parts by weight, 80 ~ 100 parts of thermoplastics, 5 ~ 10 parts of water-absorbing resins and 30 ~ 35 parts of reinforcing fibers are taken, by thermoplastic
Property plastics be put into injection molding machine and be heated to 75 ~ 110 DEG C, water-absorbing resin and reinforcing fiber are added in several times, in step after stirring evenly
Suddenly（1）The base material surface injection of preparation forms the surface material that thickness is 0.5 ~ 1cm.
2. a kind of preparation method of solid waste compound water seepage material as described in claim 1, which is characterized in that described
The preparation method of solid waste coarse aggregate includes the following steps：
（1）The slag, ferrochrome slag, gangue that are come out from high temperature are first passed through water quenching and form the coarse inflated slag in internal aperture；
（2）One or more of inflated slag of slag, ferrochrome slag, gangue is taken, is put into crusher and is crushed to 5 ~ 10mm's
Particle；
（3）Take in parts by weight again 5~10 parts of silicone oil, 20~30 parts of polyacrylate emulsions, 0.5~1 part of surfactant, 5~
10 parts of organic solvents and 89 ~ 100 parts of water are deployed into modification liquid, and broken particle is put into progress surface hydrophobicity in modification liquid changes
Property processing, dried after being disposed and can be prepared by solid waste coarse aggregate.
3. a kind of preparation method of solid waste compound water seepage material as described in claim 1, which is characterized in that described
The preparation method of solid waste fine aggregate includes the following steps：
（1）The slag come out from high temperature, ferrochrome slag, gangue are first passed through into natural cooling and form tiny closely knit in internal aperture
Slag；
（2）Take one or more of closely knit slag of slag, ferrochrome slag, gangue, be put into after crushing in ball mill grinding into
Fine powder adds the kaolin of fine powder total weight 10 ~ 15% and the water of fine powder total weight 3 ~ 5%, is granulated and controls after mixing
Grain size is 0.1 ~ 6mm, and the furnace cooling after 1300 ~ 1350 DEG C of 1 ~ 2h of sintering is put into high temperature furnace after dry, and obtained grain size is
The particle of 0.08 ~ 0.5mm, it is spare；
（3）Take in parts by weight again 5~10 parts of silicone oil, 20~30 parts of polyacrylate emulsions, 0.5~1 part of surfactant, 5~
10 parts of organic solvents and 89 ~ 100 parts of water are deployed into modification liquid, and particle after cooling is put into progress surface hydrophobicity in modification liquid changes
Property processing, dried after being disposed and can be prepared by solid waste fine aggregate.
A kind of 4. preparation method of solid waste compound water seepage material as described in claim 1, which is characterized in that the water
Mud is aluminate cement, and the additive is antifreezing agent.
5. a kind of preparation method of solid waste compound water seepage material as described in claim 1, which is characterized in that described
Thermoplastic is polyethylene, in polypropylene, polyvinyl chloride, makrolon, polyvinyl alcohol, polyacrylic acid, Maranyl
It is any.
6. a kind of preparation method of solid waste compound water seepage material as described in claim 1, which is characterized in that described
Reinforcing fiber is degreasing cotton fiber, degreasing flaxen fiber, bamboo fibre, polyethylene fibre, polypropylene fibre, polyvinyl chloride fibre, is gathered
Any one of styrene fiber, Fypro, polyester fiber or arbitrary several combination.
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| CN113105191A (en) * | 2021-04-28 | 2021-07-13 | 绍兴职业技术学院 | Preparation method for producing assembled environment-friendly energy-saving insulation board based on urban solid waste garbage |
| CN114956682A (en) * | 2022-05-11 | 2022-08-30 | 广西军泰建材有限公司 | Concrete produced by utilizing industrial solid wastes and preparation method thereof |
| CN115849838A (en) * | 2022-10-25 | 2023-03-28 | 广州理工学院 | Low-alkali concrete and preparation method thereof |
| CN116425504A (en) * | 2023-06-13 | 2023-07-14 | 北京慕湖外加剂有限公司 | Light-transmitting concrete, preparation method and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113105191A (en) * | 2021-04-28 | 2021-07-13 | 绍兴职业技术学院 | Preparation method for producing assembled environment-friendly energy-saving insulation board based on urban solid waste garbage |
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| CN116425504B (en) * | 2023-06-13 | 2023-09-01 | 北京慕湖外加剂有限公司 | Light-transmitting concrete, preparation method and application thereof |
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| CN108218356B (en) | 2020-09-22 |
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