CN106187092A - A kind of method utilizing mud and mud to fire sponge brick - Google Patents

A kind of method utilizing mud and mud to fire sponge brick Download PDF

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Publication number
CN106187092A
CN106187092A CN201610810982.XA CN201610810982A CN106187092A CN 106187092 A CN106187092 A CN 106187092A CN 201610810982 A CN201610810982 A CN 201610810982A CN 106187092 A CN106187092 A CN 106187092A
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Prior art keywords
mud
sponge brick
method utilizing
cement
brick
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CN106187092B (en
Inventor
朱伟
范惜辉
苏瑛
林乃喜
王辰宇
黄俊杰
吴思麟
徐浩青
王升位
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Hohai University HHU
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Hohai University HHU
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/063Preparing or treating the raw materials individually or as batches
    • C04B38/0635Compounding ingredients
    • C04B38/0645Burnable, meltable, sublimable materials
    • C04B38/0665Waste material; Refuse other than vegetable refuse
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1321Waste slurries, e.g. harbour sludge, industrial muds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Abstract

The present invention discloses a kind of method utilizing mud and mud to fire sponge brick, comprises the steps: S1, dewatered sludge, mud, cement, waterglass is stirred;S2, the compound feeding brickmaking machine that will stir, be pressed into adobe;S3, by green compact at room temperature maintenance and be dried;S4, dried green compact are put into kiln and are sintered, and prepare sponge brick.Wherein in terms of mass fraction, dewatered sludge accounts for 30~70%, mud 10~50%, cement 3~10%, waterglass 1~5%.The inventive method with dewatered sludge of urban sewage plant and dredging silt as primary raw material, burn out a kind of good water permeability, meet as Route for pedestrians rheobase requirement, and there is the sponge brick of water conservation, reduction of heat effect.

Description

A kind of method utilizing mud and mud to fire sponge brick
Technical field
The invention belongs to construction timber technical field, be specifically related to a kind of side utilizing mud and mud to fire sponge brick Method.
Background technology
The development in city, wetland, the minimizing in greenery patches so that city occurs in that problems.Rainstorm weather, limited row Water measure makes urban parts location waterlogging occur, has had a strong impact on the safety of resident, has carried various to the development in city Uncertain factor.Waterproof pavement has blocked and has oozed under rainwater, causes rainwater can only be arranged by special sump, storm sewer Put.This drainage system the drainage works under being unsatisfactory for extra torrential rain.
Armored concrete building, cement pavement etc., the tropical island effect for city has material impact.City underlying surface, Such as concrete road, asphalt road etc., specific heat is little, and heat absorption is fast, and under identical solar radiation, temperature quickly raises;And it is such Hyposmosis road surface, has intercepted the evaporation of the following steam in road surface, and heat is difficult to dissipate, and exacerbates tropical island effect.
Existing baking bricks in technique, using clay (including gangue, shale powder) is primary raw material, in " limit viscous prohibit real " Under policy conditions, the use of clay material is very restricted.Existing frequently-used high osmosis water-permeable brick, mainly uses pottery Or coarse granule cement material makes, cost cost is big.And mud in city, mud yield are the biggest.Dredging silt solid phase mainly by Clay mineral forms, generally Organic substance, calcination in the case of roasting in mud, and forms pore channel, advantageously forms sea Continuous brick.
Summary of the invention
For above-mentioned deficiency of the prior art, the invention provides one and become silted up with dewatered sludge of urban sewage plant and dredging Mud is primary raw material, burns out a kind of good water permeability, meets as Route for pedestrians rheobase requirement, and has water conservation, reduction of heat work The method of sponge brick.
For achieving the above object, present invention employs techniques below scheme:
A kind of method utilizing mud and mud to fire sponge brick, comprises the steps:
S1, dewatered sludge, mud, cement, waterglass are stirred;
S2, the compound feeding brickmaking machine that will stir, be pressed into adobe;
S3, by green compact at room temperature maintenance and be dried;
S4, dried green compact are put into kiln and are sintered, and prepare sponge brick.
Preferably, in step S1, in terms of mass fraction, dewatered sludge account for 35~70%, mud 10~50%, cement 3~ 10%, waterglass 1~5%.
Further, the wet basis moisture content of described dewatered sludge is 60~85%;The moisture content of described mud be 45~ 65%, cosmid (particle diameter is less than 5 μm) content is more than 30%, at stirring front row except bulky grain foreign material in mud.
Further, described cement is Portland cement, is numbered OPC32.5;Or employing quick hardening sulphoaluminate Cement.
Preferably, using twice paddling process in step S1, mud, mud, cement three kinds mix the mixing speed of material and are 300~500r/min, mixing time is 5~10min;Add the mixing speed after waterglass constant, mixing time be 10~ 15min。
Preferably, in step S3, green compact curing time at room temperature is 3 days, and baking temperature is 90~105 DEG C, when being dried Between be 8~12h.
Preferably, in step S4, sintering temperature is 1050 DEG C, and sintering time is 6~9h.
Preferably, the described sponge brick porosity that step S4 prepares is 40~60%, and infiltration coefficient is 1.2 × 10-2~6.2 ×10-2cm/s。
The beneficial effects of the present invention is:
1), this method uses mud and mud at high temperature to ensure that the cement of intensity, waterglass conduct by adding Cementing material, is fired into the novel floor tile being applicable to sea urban construction, i.e. sponge brick;Ensure that sponge brick had both had the biggest Porosity ensures again the highest intensity.Containing substantial amounts of organic matter in mud, in roasting process, organic calcination, generate certainly Right concrete dynamic modulus passage, the beneficially formation of sponge brick pore channel;The sponge brick infiltration coefficient prepared is 10-2Cm/s quantity Level, reaches as water-permeable brick GB/T25993-2010 " permeable pavement brick and porous pavement plate " the permeable class requirement of B level.
2), general mud, mud brickmaking in prior art, must mummification or reduce moisture content, Yi Mian largely Sintering procedure occurs volume contraction or be full of cracks;And utilize cement and waterglass as hardened material in the present invention, it is not necessary to right Mud or mud carry out early stage drying and other treatment, and (the wet basis moisture content of dewatered sludge is 60~85%, is general urban life dirty Moisture content scope after waterworks sludge process;The moisture content of river and lake silt is 45~65%, for general dredging silt go out aqueous Rate) scope can be obviously improved intensity and the hardness of sponge brick, fragment of brick surfacing, no significant defect.
3), the present invention utilize sewage plant sludge and mud as firing the main material of sponge brick, belong to twice laid, Can not only economize on resources, can partly solve place to go and the process of river and lake dredging mud of domestic sewage factory mud simultaneously.
4) in sum, the sponge brick that the present invention is fired, hole is big, good water permeability, beneficially rainfall water drainage, increase air Heat exchange with ground;The raw material of this sponge brick, it is not necessary to pre-treatment, process is simple;Cement, the secondary of waterglass is used to mix Enter stirring technique, the intensity of sponge brick can be significantly improved, meet the strength demand as footpath brick;This sponge brick is adopted Main material mud, the big garbage that need to process of the mud amount of belonging to, thus the present invention to be that offal treatment provides new Approach, and reduce brick making cost.
Detailed description of the invention
Below in conjunction with the embodiment of the present invention, the technical scheme in the present invention is clearly and completely described.Following reality Execute example and be only used for clearly illustrating technical scheme, and can not limit the scope of the invention with this.
If no special instructions, all per distribution ratio content in the present invention, all in terms of mass fraction.
Embodiment 1
A kind of method utilizing mud and mud to fire sponge brick, step is as follows:
S1, mud, mud, cement are stirred 5min with the speed of 300r/min;Waterglass is added in mixture, continue With identical speed stirring 10min;
S2, the compound feeding brickmaking machine that will stir, be pressed into adobe;
S3, by the green compact at room temperature maintenance that obtains 3 days, green compact put into hothouse 12 hours, and hothouse temperature is 100 ℃;
S4, dried green compact are in roasting process, and temperature is set to 1050 DEG C, sinter 6h, organic complete in mud Clean burn loses;Prepare sponge brick.
Wherein, the mass fraction of each dispensing (weight in wet base) is:
Municipal sludge moisture content is 81%, and mud moisture content is 65%.
Portland cement is numbered OPC32.5.
According to specification " permeable pavement brick and porous pavement plate " (GB/T25993-2010), the sponge brick that the present embodiment obtains Physical mechanics property as shown in table 1:
The physico-mechanical properties of table 1 sponge brick
Character Result
Rupture strength 3.2MPa
Linear failing load 220N/mm
Tensile splitting strength 3.5MPa
Coefficient of permeability 6.2×10-2cm/s
Porosity 58%
By table 1, the sponge brick good water permeability that the present embodiment prepares, meet as Route for pedestrians rheobase requirement, Have that porosity is big, intensity is high, porous, permeable, water suction, the characteristic of water conservation.
Embodiment 2
A kind of method utilizing mud and mud to fire sponge brick, step is as follows:
S1, mud, mud, cement are stirred 6min with the speed of 350r/min;Waterglass is added in mixture, continue With identical speed stirring 12min;
S2, the compound feeding brickmaking machine that will stir, be pressed into adobe;
S3, by the green compact at room temperature maintenance that obtains 3 days, green compact put into hothouse 12 hours, and hothouse temperature is 100 ℃;
S4, dried green compact are in roasting process, and temperature is set to 1050 DEG C, sinter 6h, organic complete in mud Clean burn loses;Prepare sponge brick.
Wherein, the mass fraction of each dispensing (weight in wet base) is:
Municipal sludge moisture content is 72%, and mud moisture content is 62%.
Portland cement is numbered OPC32.5.
According to specification " permeable pavement brick and porous pavement plate " (GB/T25993-2010), the sponge brick that the present embodiment obtains Physical mechanics property as shown in table 2:
The physico-mechanical properties of table 2 sponge brick
Character Result
Rupture strength 3.4MPa
Linear failing load 250N/mm
Tensile splitting strength 3.6MPa
Coefficient of permeability 2.9×10-2cm/s
Porosity 42%
By table 2, the sponge brick good water permeability that the present embodiment prepares, meet as Route for pedestrians rheobase requirement, Reach water conservation, reduction of heat effect simultaneously.
Embodiment 3
A kind of method utilizing mud and mud to fire sponge brick, step is as follows:
S1, mud, mud, cement are stirred 8min with the speed of 350r/min;Waterglass is added in mixture, continue With identical speed stirring 15min;
S2, the compound feeding brickmaking machine that will stir, be pressed into adobe;
S3, by the green compact at room temperature maintenance that obtains 3 days, green compact put into hothouse 12 hours, and hothouse temperature is 98 DEG C;
S4, dried green compact are in roasting process, and temperature is set to 1050 DEG C, sinter 8h, organic complete in mud Clean burn loses;Prepare sponge brick.
Wherein, the mass fraction of each dispensing (weight in wet base) is:
Municipal sludge moisture content is 81%, and mud moisture content is 65%.
Portland cement is numbered OPC32.5.
According to specification " permeable pavement brick and porous pavement plate " (GB/T25993-2010), the sponge brick that the present embodiment obtains Physical mechanics property as shown in table 3:
The physico-mechanical properties of table 3 sponge brick
Character Result
Rupture strength 3.4MPa
Linear failing load 250N/mm
Tensile splitting strength 3.6MPa
Coefficient of permeability 4.9×10-2cm/s
Porosity 53%
By table 3, the sponge brick good water permeability that the present embodiment prepares, meet as Route for pedestrians rheobase requirement, Have that porosity is big, intensity is high, porous, permeable, water suction, the characteristic of water conservation.
Embodiment 4
A kind of method utilizing mud and mud to fire sponge brick, step is as follows:
S1, mud, mud, cement are stirred 5min with the speed of 500r/min;Waterglass is added in mixture, continue With identical speed stirring 10min;
S2, the compound feeding brickmaking machine that will stir, be pressed into adobe;
S3, by the green compact at room temperature maintenance that obtains 3 days, green compact put into hothouse 12 hours, and hothouse temperature is 90 DEG C;
S4, dried green compact are in roasting process, and temperature is set to 1050 DEG C, sinter 9h, organic complete in mud Clean burn loses;Prepare sponge brick.
Wherein, the mass fraction of each dispensing (weight in wet base) is:
Municipal sludge moisture content is 85%, and mud moisture content is 65%.
Portland cement is numbered OPC32.5.
According to specification " permeable pavement brick and porous pavement plate " (GB/T25993-2010), the sponge brick that the present embodiment obtains Physical mechanics property as shown in table 4:
The physico-mechanical properties of table 4 sponge brick
Character Result
Rupture strength 3.3MPa
Linear failing load 230N/mm
Tensile splitting strength 3.6MPa
Coefficient of permeability 4.2×10-2cm/s
Porosity 43%
By table 4, the sponge brick good water permeability that the present embodiment prepares, meet as Route for pedestrians rheobase requirement, Have that porosity is big, intensity is high, porous, permeable, water suction, the characteristic of water conservation.
Embodiment 5
A kind of method utilizing mud and mud to fire sponge brick, step is as follows:
S1, mud, mud, cement are stirred 10min with the speed of 300r/min;Waterglass is added in mixture, continue Continuous with identical speed stirring 15min;
S2, the compound feeding brickmaking machine that will stir, be pressed into adobe;
S3, by the green compact at room temperature maintenance that obtains 3 days, green compact put into hothouse 12 hours, and hothouse temperature is 105 ℃;
S4, dried green compact are in roasting process, and temperature is set to 1050 DEG C, sinter 6h, organic complete in mud Clean burn loses;Prepare sponge brick.
Wherein, the mass fraction of each dispensing (weight in wet base) is:
Municipal sludge moisture content is 60%, and mud moisture content is 45%.
Portland cement is numbered OPC32.5.
According to specification " permeable pavement brick and porous pavement plate " (GB/T25993-2010), the sponge brick that the present embodiment obtains Physical mechanics property as shown in table 5:
The physico-mechanical properties of table 5 sponge brick
Character Result
Rupture strength 3.4MPa
Linear failing load 240N/mm
Tensile splitting strength 3.6MPa
Coefficient of permeability 5.2×10-2cm/s
Porosity 52%
By table 5, the sponge brick good water permeability that the present embodiment prepares, meet as Route for pedestrians rheobase requirement, Reach water conservation, reduction of heat effect simultaneously.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For Yuan, on the premise of without departing from the technology of the present invention principle, it is also possible to make some improvement and deformation, these improve and deformation Also should be regarded as protection scope of the present invention.

Claims (8)

1. one kind utilizes the method that mud and mud fire sponge brick, it is characterised in that comprise the steps:
S1, dewatered sludge, mud, cement, waterglass are stirred;
S2, the compound feeding brickmaking machine that will stir, be pressed into adobe;
S3, by green compact at room temperature maintenance and be dried;
S4, dried green compact are put into kiln and are sintered, and prepare sponge brick.
A kind of method utilizing mud and mud to fire sponge brick the most according to claim 1, it is characterised in that: step S1 In, in terms of mass fraction, dewatered sludge accounts for 35~70%, mud 10~50%, cement 3~10%, waterglass 1~5%.
A kind of method utilizing mud and mud to fire sponge brick the most according to claim 2, it is characterised in that: described de- The wet basis moisture content of sewage sludge is 60~85%;The moisture content of described mud is 45~65%.
A kind of method utilizing mud and mud to fire sponge brick the most according to claim 2, it is characterised in that: described water Mud is Portland cement, is numbered OPC32.5;Or employing quick hardening sulphoaluminate cement.
A kind of method utilizing mud and mud to fire sponge brick the most according to claim 1, it is characterised in that: step S1 Twice paddling process of middle employing, mud, mud, cement three kinds mixing material mixing speed be 300~500r/min, during stirring Between be 5~10min;Adding the mixing speed after waterglass constant, mixing time is 10~15min.
A kind of method utilizing mud and mud to fire sponge brick the most according to claim 1, it is characterised in that: step S3 Middle green compact curing time at room temperature is 3 days, and baking temperature is 90~105 DEG C, and drying time is 8~12h.
A kind of method utilizing mud and mud to fire sponge brick the most according to claim 1, it is characterised in that: step S4 Middle sintering temperature is 1050 DEG C, and sintering time is 6~9h.
A kind of method utilizing mud and mud to fire sponge brick the most according to claim 1, it is characterised in that: step S4 The described sponge brick porosity prepared is 40~60%, and infiltration coefficient is 1.2 × 10-2~6.2 × 10-2cm/s。
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106800363A (en) * 2017-03-10 2017-06-06 中国科学院武汉岩土力学研究所 A kind of mud/sludge stockyard in-situ solidifying device
CN108863400A (en) * 2018-06-21 2018-11-23 湖南双晟科技信息咨询有限公司 A method of water-permeable brick is prepared using municipal sludge
CN110078531A (en) * 2019-05-22 2019-08-02 济南市坤鹏技术开发中心 A kind of environmental-friendly construction material can be used for building sponge city
CN110092642A (en) * 2019-05-22 2019-08-06 济南市坤鹏技术开发中心 A kind of environmentally friendly recoverying and utilizing method of municipal sludge mud
CN111499404A (en) * 2020-04-26 2020-08-07 中国科学院城市环境研究所 Method and system for preparing perforated bricks by adopting raw sludge
CN113816724A (en) * 2021-10-19 2021-12-21 山西富鸿科技开发有限公司 Coal gangue sandstone sponge brick and preparation method thereof
CN114105612A (en) * 2021-12-20 2022-03-01 淄博天之润生态科技有限公司 Sponge brick produced from aluminum ash and preparation process thereof
CN115432995A (en) * 2022-06-28 2022-12-06 广州市北二环交通科技有限公司 Perforated brick prepared by utilizing engineering waste slurry

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106800363A (en) * 2017-03-10 2017-06-06 中国科学院武汉岩土力学研究所 A kind of mud/sludge stockyard in-situ solidifying device
CN108863400A (en) * 2018-06-21 2018-11-23 湖南双晟科技信息咨询有限公司 A method of water-permeable brick is prepared using municipal sludge
CN110078531A (en) * 2019-05-22 2019-08-02 济南市坤鹏技术开发中心 A kind of environmental-friendly construction material can be used for building sponge city
CN110092642A (en) * 2019-05-22 2019-08-06 济南市坤鹏技术开发中心 A kind of environmentally friendly recoverying and utilizing method of municipal sludge mud
CN111499404A (en) * 2020-04-26 2020-08-07 中国科学院城市环境研究所 Method and system for preparing perforated bricks by adopting raw sludge
CN113816724A (en) * 2021-10-19 2021-12-21 山西富鸿科技开发有限公司 Coal gangue sandstone sponge brick and preparation method thereof
CN114105612A (en) * 2021-12-20 2022-03-01 淄博天之润生态科技有限公司 Sponge brick produced from aluminum ash and preparation process thereof
CN115432995A (en) * 2022-06-28 2022-12-06 广州市北二环交通科技有限公司 Perforated brick prepared by utilizing engineering waste slurry
CN115432995B (en) * 2022-06-28 2023-09-12 广州市北二环交通科技有限公司 Porous brick prepared from engineering waste slurry

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