CN103183499A - Mud brick fired by environment-friendly comprehensive utilization of wastes and preparation method thereof - Google Patents
Mud brick fired by environment-friendly comprehensive utilization of wastes and preparation method thereof Download PDFInfo
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Abstract
The invention belongs to the field of waste resource environment-friendly utilization, and particularly relates to a mud brick fired by environment-friendly comprehensive utilization of wastes and a preparation method thereof. The mud brick comprises the following components by weight percent: 35-65 percent of dredging silt, 5-15 percent of sludge, 15-25 percent of domestic waste incineration slag, 10-25 percent of fly ash and 1-5 percent of quicklime, wherein the dredging silt is in large rivers, lakes, rivers or sea and has the water content of less than or equal to 80 percent and the clay component content of more than or equal to 30 percent; the sludge is generated after water treatment in a sewage treatment plant and has the clay component content of more than or equal to 30 percent; the domestic waste incineration slag and the fly ash are active wastes generated by incineration of domestic wastes; and quicklime is common quicklime II. The invention has the advantages that various wastes are comprehensively utilized in an environment-friendly manner and changed into valuables to avoid secondary pollution, and the social and economic benefits are remarkable. The mud brick can be extensively used in municipal engineering and construction engineering, protects the environment and saves resources.
Description
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Technical field
The invention belongs to the waste resource environmental protection and utilize field, particularly relate to brick made of mud and method thereof that a kind of Environmental-protection comprehensive utilizes waste to fire.
Background technology
Produce a large amount of dredging silts in Jiang,Hu,He, extra large desilting process, the dredging silt regeneration needs processed, and processed is very difficult, and mud disposal options majority is to adopt stockyard to stack now, takies a large amount of farmlands contaminate environment.Produce the end slag of 22% left and right and the flying dust of 3-5% after burning city domestic garbage, wherein end slag can be processed into to gather materials and carry out the engineering application, flying dust is because being processed containing more heavy metal regeneration, at present, majority state adopts melting and solidification, cement solidification or chemical stabilization to the heavy metal in incineration of refuse flyash.Sewage plant sludge contains heavy metal because of it, and developed country has not been allowed for farm crop fertilizer, needs to process, and reduces the impact on environment.Environmental-protection comprehensive utilization to the waste resources such as slag, flying dust, mud at the bottom of dredging silt, consumer waste incineration has become difficult point and the focus that current castoff regenerative utilizes.
Chinese patent 02137159.8 discloses " a kind of brick made of mud " manufacture method, although the method has been utilized mud preferably, also has the following disadvantages, and the one, the method is added the solidifying agent of 15-35%, needs to consume other a large amount of resources, uneconomical; The 2nd, the toxicity leaching problem of heavy metal in sludge fails to solve; The 3rd, the mud water content is not clear and definite, directly affects the curing effect of goods.
Chinese patent 200380110486.4 discloses " being manufactured the method for goods by flying dust ", although the method can be removed the heavy metal in flying dust by sintering, also have the following disadvantages, the one, described method need be blended together flying dust and water, add water in flying dust, consumed water resources; The 2nd, easily produce flying dust in water ash mixing process and raise outward, contaminate environment; The 3rd, extrudate density is larger, and as Constracture unit, from great, structural load is heavy.
Chinese patent 200410014679.6 discloses " utilizing mud to manufacture the method for clay brick ", although raw material has been found in the production that the method is clay brick, but also have the following disadvantages, the one, add 10-20% dry powder and 5-10% powder ash in mud, the toxicity that can not solve heavy metal in sludge leaches problem; The 2nd, technique is numerous and diverse, needs machinery more, needs power more, and manufacturing cost is high; The 3rd, the clay brick folding strength deficiency of extrusion molding, be restricted range of application.
Chinese patent 200610040094.0 discloses " utilizing the method for pure sludge brickmaking ", although the method has been utilized the mud in Jiang,He,Hu, sea, the effect of reserved resource is arranged, but also have the following disadvantages, the one, the toxicity that the method can not solve heavy metal in sludge leaches problem; The 2nd, by sludge dewatering, water ratio reaches below 30% and is difficult to realize, operability is not strong.
Chinese patent 201010287142 discloses " utilizing domestic sludge, river and lake mud to fire the method for self-heat conserving energy-saving brick ", although the method has utilized municipal sludge and lake silt to make finished bricks, but also have the following disadvantages, the one, by mud, naturally stack to water ratio 50-60% stand-by, need take a large amount of places, the current silt stockyard of China has been a difficult problem, and uneconomical; The 2nd, because winter temperature is low, summer rainy water again, naturally reduce water ratio outdoor infeasible; The 3rd, to add the pore-forming material of fluxing of 3-8% in the brickmaking process, increased operation, and DeGrain, because mud itself can produce micropore through roast; The 4th, cast waste sand material source deficiency, and inevitably contain metallic particles and iron rust composition in cast waste sand, increased the deadweight of brick; The 5th, domestic sludge and riverway sludge have essence different, and the amount of sludge in Jiang,He,Hu, sea is much larger than the amount of domestic sludge, and the method lacks exploitativeness because failing the open measure that should take.
In sum, the subject matter that prior art exists has: the one, and sludge dewatering method operability is not strong; The 2nd, heavy metal during extruding brickmaking in mud is effectively solved, and the 3rd, riverway sludge and domestic sludge to be obscured, the intrinsic characteristics of mud and mud itself are underutilized.
How to overcome the deficiencies in the prior art, fully utilize multiple waste, become current waste resource environmental protection and utilized one of field crucial difficult problem urgently to be resolved hurrily.
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Summary of the invention
The brick made of mud and the method thereof that the object of the invention is to overcome the deficiencies in the prior art and provide a kind of Environmental-protection comprehensive to utilize waste to fire, brick made of mud of the present invention can digest slag and flying dust at the bottom of a large amount of dredging silts, mud, consumer waste incineration, have advantages of that Environmental-protection comprehensive utilizes multiple waste to turn waste into wealth and non-secondary pollution produces, economic results in society are remarkable; Brick made of mud method for cooking provided by the invention is easy to implement, practicality is reliable.
The brick made of mud that a kind of Environmental-protection comprehensive proposed according to the present invention utilizes waste to fire, is characterized in that component by weight ratio is: slag 15-25%, flying dust 10-25% and unslaked lime 1-5% at the bottom of dredging silt 35-65%, mud 5-15%, consumer waste incineration; Wherein: the Jiang,Hu,He that dredging silt is water ratio≤80%, clay component content >=30% or marine dredging silt, the mud produced after sewage work's water treatment that mud is clay component content >=30%, at the bottom of consumer waste incineration, slag, flying dust are the activated waste of tool produced after consumer waste incineration, and unslaked lime is common II level unslaked lime.The further preferred version of the present invention is: described brick made of mud, component by weight ratio is: slag 20%, flying dust 17.5% and unslaked lime 2.5% at the bottom of dredging silt 50%, mud 10%, consumer waste incineration.
A kind of Environmental-protection comprehensive proposed according to the present invention utilizes waste to fire the method for brick made of mud, it is characterized in that by starting raw material through select materials → batch mixing → ageing → base → drying → roasting, and makes the brick made of mud finished product, and concrete steps are as follows:
Step 1, select materials: choose water ratio through preliminary hydro-extraction≤80%, the Jiang,Hu,He of clay component content >=30% or marine dredging silt, choose the mud produced after sewage work's water treatment of clay component content >=30%, choose slag at the bottom of the consumer waste incineration that meets " life garbage incinerator slag aggregate " (GB/T 25032-2010) standard, choose the flying dust with active waste produced after consumer waste incineration, choose common II level unslaked lime, the weight proportion of selected parent material meets component claimed in claim 1;
Step 2, batch mixing: at first measure selecting materials after weighing step 1 proportioning, then adopt Manual material feeding or machine automatization material-uploading style, put into concrete mixer and be uniformly mixed 3-5 minute, make various mixing of materials even;
Step 3, ageing: the material that step 2 is mixed is placed 24-48 hour at normal temperatures naturally;
Step 4, base: the specification needed according to difference, the mixture that the step 3 ageing is completed is made adobe;
Step 5, drying: the adobe that step 4 is made is dry 24-48 hour under 20-25 ℃ of condition;
Step 6, roasting: the dry brick that step 5 is made is put into the incinerating kiln that temperature is 1050 ℃-1200 ℃ and is fired 15-30 minute, makes the brick made of mud finished product.
Environmental-protection comprehensive of the present invention utilizes the principle of waste to be: the present invention is directed to that the dredging silt water ratio is high, the difficult problem of dewatering, by slag and flying dust at the bottom of the waste incineration that adds proportional quantity of the present invention, after physics water suction and chemical reaction, can reduce the mud water ratio; Clay content in dredging silt is higher simultaneously, and clay particle has stronger adsorption to the heavy metal in end slag and flying dust, in sintering process, further solidifies, and has avoided the toxicity of heavy metal in the brick made of mud finished product to leach; End slag can play skeleton function through sintering in the brick made of mud finished product, adds the composition of mud medium sand, has guaranteed the intensity of brick; The clay of dredging silt and mud in proportioning of the present invention, can produce micropore and expansion through roast, increased the heat-insulating property during brick made of mud is used in the time of the deadweight that alleviates the brick made of mud finished product; Heavy metal has fluxing action in the roast process, and after roast, the Leaching of Heavy Metals problem has obtained further solution.
The present invention compared with prior art its remarkable advantage is: the one, and in the present invention, the relative merits of various wastes all become favourable condition and are fully used, have advantages of that Environmental-protection comprehensive utilizes multiple waste, the problems such as toxicity leaching of heavy metal in sludge have particularly been solved, danger wastes has been become to renewable resource, save a large amount of landfills soil, realized thus the purpose turned waste into wealth; The 2nd, the cost of brick made of mud of the present invention is low, compares with patent 200410014679.6 and reduces more than 30%, and economic results in society are remarkable; The 3rd, the quality of brick made of mud of the present invention reaches GB5101-2003 fired common brick technological standard, and grade of compressive strength surpasses MU10.The present invention can be widely used in public works and construction work, and protection of the environment economizes on resources.
The accompanying drawing explanation
Fig. 1 is a kind of process flow sheet that utilizes waste to fire the brick made of mud method that the present invention proposes
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Embodiment
Below in conjunction with drawings and Examples, the present invention is described in further detail.
A kind of brick made of mud that utilizes waste to fire proposed according to the present invention, component by weight ratio is: slag 15-25%, flying dust 10-25% and unslaked lime 1-5% at the bottom of dredging silt 35-65%, mud 5-15%, consumer waste incineration; Wherein: the Jiang,Hu,He that dredging silt is water ratio≤80%, clay component content >=30% or marine dredging silt, the mud produced after sewage work's water treatment that mud is clay component content >=30%, at the bottom of consumer waste incineration, slag, flying dust are the activated waste of tool produced after consumer waste incineration, and unslaked lime is common II level unslaked lime.In conjunction with Fig. 1, of the present invention specifically to fire step as follows:
Step 1, select materials: choose water ratio through preliminary hydro-extraction≤80%, the Jiang,Hu,He of clay component content >=30% or marine dredging silt, choose the mud produced after sewage work's water treatment of clay component content >=30%, choose slag at the bottom of the consumer waste incineration that meets " life garbage incinerator slag aggregate " (GB/T 25032-2010) standard, choose the flying dust with active waste produced after consumer waste incineration, choose common II level unslaked lime, all component weight proportions according to the invention of selecting materials;
Step 2, batch mixing: at first measure selecting materials after weighing step 1 proportioning, then adopt Manual material feeding or machine automatization material-uploading style, put into concrete mixer and be uniformly mixed 3-5 minute, make various mixing of materials even;
Step 3, ageing: the material that step 2 is mixed is placed 24-48 hour at normal temperatures naturally;
Step 4, base: the specification needed according to difference, the mixture that the step 3 ageing is completed is made adobe;
Step 5, drying: the adobe that step 4 is made is dry 24-48 hour under 20-25 ℃ of condition;
Step 6, roasting: the dry brick that step 5 is made is put into the incinerating kiln that temperature is 1050 ℃-1200 ℃ and is fired 15-30 minute, makes the brick made of mud finished product.
embodiment 1
Step 1, select materials: choose water ratio through preliminary hydro-extraction≤80%, the dredging silt in the dredging silt stockyard, lake, Baima of clay component content >=30%, choose the mud produced after the south of the River, Changshu water utilities sewage work water treatment of clay component content >=30%, choose the flying dust with active waste produced from after slag and consumer waste incineration at the bottom of the consumer waste incineration that meets " life garbage incinerator slag aggregate " (GB/T 25032-2010) standard of Pudong Development Bank, Changshu burning power plant, choose common II level unslaked lime, all component weight proportions according to the invention of selecting materials,
Step 2, batch mixing: be that slag 20% at the bottom of dredging silt 50%, mud 10%, consumer waste incineration, flying dust 17.5% and unslaked lime 2.5% weight proportion weigh 12.2 ㎏ that select materials according to the component of selecting materials, the JZC500 drum mixer that adopts Zhengzhou innovation building machinery Manufacturing Co., Ltd to produce, adopt the machine automatization material-uploading style, to put into this stirrer and be uniformly mixed 4 minutes, and make various mixing of materials even;
Step 3, ageing: the material that step 2 is mixed is placed 36 hours at normal temperatures naturally, carries out ageing;
Step 4, base: the mixture that the step 3 ageing is completed is made 240mm * 115mm * 53mm adobe, and quantity is 6;
Step 5, drying: the adobe that step 4 is made under 22 ℃ of conditions dry 36 hours;
Step 6, roasting: the dry brick that step 5 is made is put into the incinerating kiln that temperature is 1100 ℃ and is fired 22 minutes, makes the brick made of mud finished product.
embodiment 2
Step 1, select materials: Ningbo City's three rivers road mud of choosing water ratio through preliminary hydro-extraction≤80%, clay component content >=30%, choose the sludge of sewage treatment plant of clay component content >=30%, choose the flying dust with active waste produced from after slag and consumer waste incineration at the bottom of the consumer waste incineration that meets " life garbage incinerator slag aggregate " (GB/T 25032-2010) standard of wide Suzhou garbage incinerating power plant, choose common II level unslaked lime, all component weight proportions according to the invention of selecting materials;
Step 2, batch mixing: be that slag 25% at the bottom of dredging silt 35%, mud 15%, consumer waste incineration, flying dust 20% and unslaked lime 5% weight proportion weigh 16.2 ㎏ that select materials according to the component of selecting materials, the JZC500 drum mixer that adopts Zhengzhou innovation building machinery Manufacturing Co., Ltd to produce, adopt the machine automatization material-uploading style, to put into this stirrer and be uniformly mixed 5 minutes, and make various mixing of materials even;
Step 3, ageing: the material that step 2 is mixed is placed 48 hours at normal temperatures naturally, carries out ageing;
Step 4, base: the mixture that the step 3 ageing is completed is made 240mm * 115mm * 53mm adobe, and quantity is 8;
Step 5, drying: the adobe that step 4 is made under 25 ℃ of conditions dry 24 hours;
Step 6, roasting: the dry brick that step 5 is made is put into the incinerating kiln that temperature is 1200 ℃ and is fired 15 minutes, makes the brick made of mud finished product.
embodiment 3
Step 1, select materials: the Qiantang River dredging silt of choosing water ratio through preliminary hydro-extraction≤80%, clay component content >=30%, choose the sludge of sewage treatment plant of clay component content >=30%, choose the flying dust with active waste produced from after slag and consumer waste incineration at the bottom of the consumer waste incineration that meets " life garbage incinerator slag aggregate " (GB/T 25032-2010) standard of the imperial bridge burning power plant in Pudong Development Bank, Shanghai, choose common II level unslaked lime, all component weight proportions according to the invention of selecting materials;
Step 2, batch mixing: be that slag 20% at the bottom of dredging silt 65%, mud 5%, consumer waste incineration, flying dust 7.5% and unslaked lime 2.5% weight proportion weigh 12.2 ㎏ that select materials according to the component of selecting materials, the JZC500 drum mixer that adopts Zhengzhou innovation building machinery Manufacturing Co., Ltd to produce, adopt the machine automatization material-uploading style, to put into this stirrer and be uniformly mixed 4 minutes, and make various mixing of materials even;
Step 3, ageing: the material that step 2 is mixed is placed 24 hours at normal temperatures naturally, carries out ageing;
Step 4, base: the mixture that the step 3 ageing is completed is made 240mm * 115mm * 53mm adobe, and quantity is 6;
Step 5, drying: the adobe that step 4 is made under 20 ℃ of conditions dry 48 hours;
Step 6, roasting: the dry brick that step 5 is made is put into the incinerating kiln that temperature is 1050 ℃ and is fired 30 minutes, makes the brick made of mud finished product.
embodiment 4
Step 1, select materials: the coastal mudflat sludge of Quanzhou Region of choosing water ratio through preliminary hydro-extraction≤80%, clay component content >=30%, choose the sludge of sewage treatment plant of clay component content >=30%, choose the flying dust with active waste produced from after slag and consumer waste incineration at the bottom of the consumer waste incineration that meets " life garbage incinerator slag aggregate " (GB/T 25032-2010) standard of Shenzhen Yantian burning power plant, choose common II level unslaked lime, all component weight proportions according to the invention of selecting materials;
Step 2, batch mixing: be that slag 15% at the bottom of dredging silt 60%, mud 10%, consumer waste incineration, flying dust 14% and unslaked lime 1% weight proportion weigh 16.2 ㎏ that select materials according to the component of selecting materials, the JZC500 drum mixer that adopts Zhengzhou innovation building machinery Manufacturing Co., Ltd to produce, adopt the machine automatization material-uploading style, to put into this stirrer and be uniformly mixed 3 minutes, and make various mixing of materials even;
Step 3, ageing: the material that step 2 is mixed is placed 40 hours at normal temperatures naturally, carries out ageing;
Step 4, base: the mixture that the step 3 ageing is completed is made 240mm * 115mm * 53mm adobe, and quantity is 8;
Step 5, drying: the adobe that step 4 is made under 25 ℃ of conditions dry 30 hours;
Step 6, roasting: the dry brick that step 5 is made is put into the incinerating kiln that temperature is 1100 ℃ and is fired 20 minutes, makes the brick made of mud finished product.
The present invention, through validation trial, has obtained and has been satisfied with effect.
Claims (3)
1. the brick made of mud that Environmental-protection comprehensive utilizes waste to fire, is characterized in that component by weight ratio is: slag 15-25%, flying dust 10-25% and unslaked lime 1-5% at the bottom of dredging silt 35-65%, mud 5-15%, consumer waste incineration; Wherein: the Jiang,Hu,He that dredging silt is water ratio≤80%, clay component content >=30% or marine dredging silt, the mud produced after sewage work's water treatment that mud is clay component content >=30%, at the bottom of consumer waste incineration, slag, flying dust are the activated waste of tool produced after consumer waste incineration, and unslaked lime is common II level unslaked lime.
2. brick made of mud according to claim 1, is characterized in that component by weight ratio is: slag 20%, flying dust 17.5% and unslaked lime 2.5% at the bottom of dredging silt 50%, mud 10%, consumer waste incineration.
3. an Environmental-protection comprehensive utilizes waste to fire the method for brick made of mud, it is characterized in that starting raw material is through select materials → batch mixing → ageing → base → drying → roasting, and makes the brick made of mud finished product, and concrete steps are as follows:
Step 1, select materials: choose water ratio through preliminary hydro-extraction≤80%, the Jiang,Hu,He of clay component content >=30% or marine dredging silt, choose the mud produced after sewage work's water treatment of clay component content >=30%, choose slag at the bottom of the consumer waste incineration that meets " life garbage incinerator slag aggregate " (GB/T 25032-2010) standard, choose the flying dust with active waste produced after consumer waste incineration, choose common II level unslaked lime, the weight proportion of selected parent material meets component claimed in claim 1;
Step 2, batch mixing: at first measure selecting materials after weighing step 1 proportioning, then adopt Manual material feeding or machine automatization material-uploading style, put into concrete mixer and be uniformly mixed 3-5 minute, make various mixing of materials even;
Step 3, ageing: the material that step 2 is mixed is placed 24-48 hour at normal temperatures naturally;
Step 4, base: the specification needed according to difference, the mixture that the step 3 ageing is completed is made adobe;
Step 5, drying: the adobe that step 4 is made is dry 24-48 hour under 20-25 ℃ of condition;
Step 6, roasting: the dry brick that step 5 is made is put into the incinerating kiln that temperature is 1050 ℃-1200 ℃ and is fired 15-30 minute, makes the brick made of mud finished product.
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Cited By (12)
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CN103496031A (en) * | 2013-10-08 | 2014-01-08 | 谢鸣燕 | Plate making system and method by utilizing sludge |
CN103496950A (en) * | 2013-10-16 | 2014-01-08 | 青岛磊鑫混凝土有限公司 | Ceramsite for concrete and preparation method of ceramsite |
CN104909816A (en) * | 2015-06-09 | 2015-09-16 | 古耀坤 | Sintering swelled ultra-lightweight ceramsite produced by using silt and manufacturing method thereof |
CN106187092A (en) * | 2016-09-08 | 2016-12-07 | 河海大学 | A kind of method utilizing mud and mud to fire sponge brick |
CN106938914A (en) * | 2017-03-17 | 2017-07-11 | 江苏中宜生态土研究院有限公司 | A kind of sludge and silt sintering brick preparation method |
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CN111792910A (en) * | 2020-06-24 | 2020-10-20 | 上海应用技术大学 | Baked brick prepared from household garbage incineration fly ash and sludge and preparation method thereof |
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CN103496031A (en) * | 2013-10-08 | 2014-01-08 | 谢鸣燕 | Plate making system and method by utilizing sludge |
CN103496950A (en) * | 2013-10-16 | 2014-01-08 | 青岛磊鑫混凝土有限公司 | Ceramsite for concrete and preparation method of ceramsite |
CN103496950B (en) * | 2013-10-16 | 2014-12-24 | 青岛磊鑫混凝土有限公司 | Ceramsite for concrete and preparation method of ceramsite |
CN104909816A (en) * | 2015-06-09 | 2015-09-16 | 古耀坤 | Sintering swelled ultra-lightweight ceramsite produced by using silt and manufacturing method thereof |
CN106187092B (en) * | 2016-09-08 | 2019-03-01 | 河海大学 | A method of sponge brick is fired using sludge and mud |
CN106187092A (en) * | 2016-09-08 | 2016-12-07 | 河海大学 | A kind of method utilizing mud and mud to fire sponge brick |
CN106938914A (en) * | 2017-03-17 | 2017-07-11 | 江苏中宜生态土研究院有限公司 | A kind of sludge and silt sintering brick preparation method |
CN107082649A (en) * | 2017-04-06 | 2017-08-22 | 合肥欧克斯新型建材有限公司 | A kind of waste incineration slag regeneration honeycomb energy-saving brick and preparation method thereof |
CN107324772A (en) * | 2017-06-14 | 2017-11-07 | 湖北楚荆新型建材有限公司 | A kind of fly ash baked brick and its preparation technology |
CN111792910A (en) * | 2020-06-24 | 2020-10-20 | 上海应用技术大学 | Baked brick prepared from household garbage incineration fly ash and sludge and preparation method thereof |
CN114057436A (en) * | 2020-08-07 | 2022-02-18 | 台北科技大学 | Multifunctional inorganic polymer soil brick |
CN112979275A (en) * | 2021-02-05 | 2021-06-18 | 中冶成都勘察研究总院有限公司 | Method for preparing adsorption type perforated brick from sludge with high organic matter content |
CN114538844A (en) * | 2022-01-28 | 2022-05-27 | 戴建远 | Low-carbon concrete and preparation method and application thereof |
CN114524660A (en) * | 2022-02-22 | 2022-05-24 | 中国科学院武汉岩土力学研究所 | Low-carbon solidification method for high-liquid limit sludge engineering muck |
CN114524660B (en) * | 2022-02-22 | 2022-11-01 | 中国科学院武汉岩土力学研究所 | Low-carbon solidification method for high-liquid limit sludge engineering muck |
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