CN106116479A - A kind of method utilizing mud and building castoff sintering self-insulating brick - Google Patents

A kind of method utilizing mud and building castoff sintering self-insulating brick Download PDF

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Publication number
CN106116479A
CN106116479A CN201610439185.5A CN201610439185A CN106116479A CN 106116479 A CN106116479 A CN 106116479A CN 201610439185 A CN201610439185 A CN 201610439185A CN 106116479 A CN106116479 A CN 106116479A
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CN
China
Prior art keywords
mud
building castoff
self
insulating brick
sintering
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610439185.5A
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Chinese (zh)
Inventor
刘心中
翁仁贵
彭蕾
倪柳芳
靳贵晓
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Fujian University of Technology
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Fujian University of Technology
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Priority to CN201610439185.5A priority Critical patent/CN106116479A/en
Publication of CN106116479A publication Critical patent/CN106116479A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1321Waste slurries, e.g. harbour sludge, industrial muds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1324Recycled material, e.g. tile dust, stone waste, spent refractory material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/24Manufacture of porcelain or white ware
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The invention provides a kind of method utilizing mud and building castoff sintering self-insulating brick, including: mud is dehydrated through pressure filter, reaches 40% 70% to moisture content;Building castoff accounts for more than 50% through the fine powder being crushed to particle diameter 60 70 mesh, and remaining particle diameter is at below 2.5mm;By mud and the building castoff mix and blend of 60 70 weight portions of 30 40 weight portions, pre-homogenizing 6 12h, it is aged 12 24h;The sulfate slag pore creating material mixing of 0.2 0.5 weight portions is added, it is thus achieved that blank toward raw material;Blank is carried out hydraulic pressure compressing, obtain adobe;Adobe drying to moisture content is 5% 8%, is then fed into tunnel cave roasting, and sintering temperature is 950 DEG C 1050 DEG C, and sintering time is 5h 8h, obtains self-insulating brick.The present invention turns waste into wealth, reduces environmental pollution, and technique is simple, low cost, and intensity is high, and the heat transfer coefficient of self-insulating brick is good, and outward appearance is good.

Description

A kind of method utilizing mud and building castoff sintering self-insulating brick
Technical field
Present invention relates particularly to a kind of method utilizing mud and building castoff sintering self-insulating brick.
Background technology
At present, building trade is flourish, huge to the demand of fired brick, and country has forbidden clay solid brick Use and produce, using solid waste brickmaking to become the trend substituting clay-brickmaking.Along with China's urban wastewater treatment firm Building, the generation amount of its mud also sharply increases.Mud is organic by Organic substance, inorganic particle, colloid, heavy metal and persistency Thing and microorganism etc. form, can be to environment if not being acted upon utilization.Building industry is produced as the mainstay of the national economy One of industry, China has been achieved for the development advanced by leaps and bounds.Over the nearlyest 30 years, along with the high speed development of Chinese Urbanization, city City updates rapidly, and construction scale constantly expands, and generation and the discharge of building castoff also grow at top speed.Low developed area and city Overwhelming majority rubbish is unprocessed, directly transports countryside or rural area soot air storage or landfill to, takies a large amount of soil, make again Become serious environmental pollution.Differ again on building castoff (brick and tile, concrete) and tradition clay brick raw material composition , there is the difficulty of technology for fired brick in sample.How to deal carefully with mud and subway is cut the earth, it is achieved its recycling, and not Pollute environment, be our urgent need to solve the problem.
Summary of the invention
The technical problem to be solved in the present invention, is that providing a kind of utilizes mud and building castoff sintering self-insulating brick Method.
The present invention is achieved in that a kind of method utilizing mud and building castoff sintering self-insulating brick, including with Lower step:
(1) sewage adds flocculation aid in settlement treatment process, and the mud precipitated is dehydrated through pressure filter, until mud Moisture content reach 40%-70%, standby;Described sewage is the sewage handled by municipal sewage plant;
(2) building castoff accounts for more than 50% through the fine powder being crushed to particle diameter 60-70 mesh, remaining particle diameter 2.5mm with Under, standby;
(3) by the building castoff mixing machinery stirring of the mud of 30-40 weight portion and 60-70 weight portion, the most pre-all Change 6-12h, then be aged 12-24h;Use the operation of pre-homogenizing, make raw material mix homogeneously;
(4) the sulfate slag pore creating material mixing of 0.2-0.5 weight portion is added toward the raw material after ageing, it is thus achieved that blank;Sulfate slag The interpolation of pore creating material makes green brick forming easy, and is provided that calorific value when burning, can form again microcellular structure, make sintering go out Product can be incubated.
(5) blank is carried out under pressure 35-50MPa hydraulic pressure compressing, obtain adobe;Hyperpressure is compressing to be made The self-insulating brick intensity prepared is high;
(6) adobe is sent into hothouse and is dried to moisture content is 5%-8%, is then fed into tunnel cave roasting, and sintering temperature is 950 DEG C-1050 DEG C, sintering time is 5h-8h, obtains self-insulating brick.
Further, described flocculation aid is blast furnace ash or flyash;The flocculation aid such as blast furnace ash or flyash is utilized to realize dirt The efficient low-consume dehydration of mud.
Further, described self-insulating brick is solid brick, porous brick or hollow brick.
It is an advantage of the current invention that: utilize mud and building castoff fired brick, it is not necessary to burning coal powder in adding, it is achieved become useless For precious, minimizing environmental pollution;Technique is simple, low cost, and intensity is high, and the heat transfer coefficient 0.3-1.35W/ (m of self-insulating brick2· K), outward appearance is good.
Detailed description of the invention
Embodiment 1
A kind of method utilizing mud and building castoff sintering self-insulating brick, comprises the following steps:
(1) sewage adds flocculation aid in settlement treatment process, and the mud precipitated is dehydrated through pressure filter, until mud Moisture content reach 40%, standby;
(2) building castoff accounts for more than 50% through the fine powder being crushed to particle diameter 60 mesh, remaining particle diameter at below 2.5mm, Standby;
(3) by mud and the building castoff mixing machinery stirring of 70 weight portions of 30 weight portions, the most pre-homogenizing 6h, then Ageing 12h;
(4) the sulfate slag pore creating material mixing of 0.2 weight portion is added toward the raw material after ageing, it is thus achieved that blank;
(5) blank is carried out under pressure 35MPa hydraulic pressure compressing, obtain adobe;
(6) adobe is sent into hothouse and is dried to moisture content is 5%, is then fed into tunnel cave roasting, and sintering temperature is 950 DEG C, sintering time is 5h, obtains solid brick.
Embodiment 2
This part is with embodiment difference:
(1) moisture content of mud reaches 70%;
The fine powder of (2) 70 mesh accounts for more than 60%, and remaining particle diameter is at below 1.5mm;
(3) by mud and the building castoff mixing machinery stirring of 60 weight portions of 40 weight portions, the most pre-homogenizing 12h, It is aged 24h again;
(4) the sulfate slag pore creating material mixing of 0.5 weight portion is added toward the raw material after ageing;
(5) blank is carried out under pressure 50MPa hydraulic pressure compressing;
(6) adobe is sent into hothouse and is dried to moisture content is 8%, and sintering temperature is 1050 DEG C, and sintering time is 8h, to obtain final product Porous brick.
Embodiment 3
This part is with embodiment difference:
(1) moisture content of mud reaches 56%;
The fine powder of (2) 70 mesh accounts for more than 70%, and remaining particle diameter is at below 2.3mm;
(3) by mud and the building castoff mixing machinery stirring of 62 weight portions of 38 weight portions, the most pre-homogenizing 12h, It is aged 24h again;
(4) the sulfate slag pore creating material mixing of 0.5 weight portion is added toward the raw material after ageing;
(5) blank is carried out under pressure 44MPa hydraulic pressure compressing;
(6) adobe is sent into hothouse and is dried to moisture content is 7%, and sintering temperature is 1000 DEG C, and sintering time is 7h, to obtain final product Hollow brick.
The present invention utilizes mud and building castoff fired brick, it is not necessary to burning coal powder in adding, and mud is provided that when burning A large amount of calorific values, can form microcellular structure simultaneously, and the brick enabling sintering to go out is incubated.Realization is turned waste into wealth, is reduced environmental pollution.Work Skill is simple, low cost, and intensity is high, and the intensity of solid brick reaches 20-25MPa, and the intensity of porous brick reaches 15-20MPa, hollow brick Intensity reach 10-15MPa, and the heat transfer coefficient 0.3-1.35W/ (m of the self-insulating brick of the present invention2K), outward appearance is good.
Although the foregoing describing the detailed description of the invention of the present invention, but those familiar with the art should managing Solving, our described specific embodiment is merely exemplary rather than for the restriction to the scope of the present invention, is familiar with this The technical staff in field, in the equivalent modification made according to the spirit of the present invention and change, should be contained the present invention's In scope of the claimed protection.

Claims (3)

1. the method utilizing mud and building castoff sintering self-insulating brick, it is characterised in that: comprise the following steps:
(1) sewage adds flocculation aid in settlement treatment process, and the mud precipitated is dehydrated through pressure filter, until the containing of mud Water rate reaches 40%-70%, standby;
(2) building castoff accounts for more than 50% through the fine powder being crushed to particle diameter 60-70 mesh, and remaining particle diameter is at below 2.5mm, standby With;
(3) by mud and the building castoff mixing machinery stirring of 60-70 weight portion, the most pre-homogenizing 6-of 30-40 weight portion 12h, then it is aged 12-24h;
(4) the sulfate slag pore creating material mixing of 0.2-0.5 weight portion is added toward the raw material after ageing, it is thus achieved that blank;
(5) blank is carried out under pressure 35-50MPa hydraulic pressure compressing, obtain adobe;
(6) adobe is sent into hothouse and is dried to moisture content is 5%-8%, is then fed into tunnel cave roasting, and sintering temperature is 950 DEG C-1050 DEG C, sintering time is 5h-8h, obtains self-insulating brick.
A kind of method utilizing mud and building castoff sintering self-insulating brick, it is characterised in that: Described flocculation aid is blast furnace ash or flyash.
A kind of method utilizing mud and building castoff sintering self-insulating brick, it is characterised in that: Described self-insulating brick is solid brick, porous brick or hollow brick.
CN201610439185.5A 2016-06-17 2016-06-17 A kind of method utilizing mud and building castoff sintering self-insulating brick Pending CN106116479A (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106673612A (en) * 2016-12-19 2017-05-17 苏州唐氏机械制造有限公司 Brick making method for sludge of sewage treatment plant
CN106747593A (en) * 2016-11-21 2017-05-31 福建工程学院 A kind of method that utilization sludge prepares haydite with building castoff
CN106747596A (en) * 2016-11-21 2017-05-31 福建工程学院 A kind of method that utilization mineralized waste, sludge and building castoff prepare haydite
CN107216124A (en) * 2017-06-15 2017-09-29 福建工程学院 One kind utilizes sewage sludge sintering heat insulation building block and its method
CN107244890A (en) * 2017-06-15 2017-10-13 福建闽盛新型建材有限公司 A kind of method of utilization sludge and coal gangue sintering self-insulating brick
CN107500730A (en) * 2017-09-21 2017-12-22 四川省三台县合强建材有限公司 A kind of environment-friendly type hollow brick and preparation method thereof
CN108249893A (en) * 2018-01-23 2018-07-06 合肥峰腾节能科技有限公司 It is a kind of to utilize useless brick and the insulating brick of pond sludge production
CN109279870A (en) * 2018-09-28 2019-01-29 温州雨泽建材加工厂 A kind of brick and preparation method of building castoff preparation
CN110757624A (en) * 2019-09-29 2020-02-07 中原环资科技有限公司 Process for producing hollow building block
CN110803879A (en) * 2019-09-28 2020-02-18 中原环资科技有限公司 Inorganic waste synergistic comprehensive recycling process method
CN113979724A (en) * 2021-10-28 2022-01-28 青岛农业大学 Sintered brick and preparation method and application thereof
CN114477956A (en) * 2022-03-02 2022-05-13 深圳市坤鹏环保建筑废料处理有限公司 Light construction waste regeneration brick and preparation method thereof

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CN101565264A (en) * 2009-06-05 2009-10-28 福建工程学院 Method for treating sludge and method for recycling sludge building material and producing into fertilizer

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106747593A (en) * 2016-11-21 2017-05-31 福建工程学院 A kind of method that utilization sludge prepares haydite with building castoff
CN106747596A (en) * 2016-11-21 2017-05-31 福建工程学院 A kind of method that utilization mineralized waste, sludge and building castoff prepare haydite
CN106673612A (en) * 2016-12-19 2017-05-17 苏州唐氏机械制造有限公司 Brick making method for sludge of sewage treatment plant
CN107216124A (en) * 2017-06-15 2017-09-29 福建工程学院 One kind utilizes sewage sludge sintering heat insulation building block and its method
CN107244890A (en) * 2017-06-15 2017-10-13 福建闽盛新型建材有限公司 A kind of method of utilization sludge and coal gangue sintering self-insulating brick
CN107500730A (en) * 2017-09-21 2017-12-22 四川省三台县合强建材有限公司 A kind of environment-friendly type hollow brick and preparation method thereof
CN108249893A (en) * 2018-01-23 2018-07-06 合肥峰腾节能科技有限公司 It is a kind of to utilize useless brick and the insulating brick of pond sludge production
CN109279870A (en) * 2018-09-28 2019-01-29 温州雨泽建材加工厂 A kind of brick and preparation method of building castoff preparation
CN110803879A (en) * 2019-09-28 2020-02-18 中原环资科技有限公司 Inorganic waste synergistic comprehensive recycling process method
CN110757624A (en) * 2019-09-29 2020-02-07 中原环资科技有限公司 Process for producing hollow building block
CN113979724A (en) * 2021-10-28 2022-01-28 青岛农业大学 Sintered brick and preparation method and application thereof
CN114477956A (en) * 2022-03-02 2022-05-13 深圳市坤鹏环保建筑废料处理有限公司 Light construction waste regeneration brick and preparation method thereof
CN114477956B (en) * 2022-03-02 2022-12-16 深圳市坤鹏环保建筑废料处理有限公司 Light construction waste regeneration brick and preparation method thereof

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