CN108109922A - A kind of method for reducing metal-oxide-semiconductor stress effect - Google Patents

A kind of method for reducing metal-oxide-semiconductor stress effect Download PDF

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Publication number
CN108109922A
CN108109922A CN201711378886.3A CN201711378886A CN108109922A CN 108109922 A CN108109922 A CN 108109922A CN 201711378886 A CN201711378886 A CN 201711378886A CN 108109922 A CN108109922 A CN 108109922A
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oxide
stress effect
particle
source
reducing metal
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CN108109922B (en
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王鹏鹏
李春杰
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Wuhan Xinxin Integrated Circuit Co ltd
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Wuhan Xinxin Semiconductor Manufacturing Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/26Bombardment with radiation
    • H01L21/263Bombardment with radiation with high-energy radiation
    • H01L21/265Bombardment with radiation with high-energy radiation producing ion implantation
    • H01L21/26506Bombardment with radiation with high-energy radiation producing ion implantation in group IV semiconductors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/26Bombardment with radiation
    • H01L21/263Bombardment with radiation with high-energy radiation
    • H01L21/265Bombardment with radiation with high-energy radiation producing ion implantation
    • H01L21/26586Bombardment with radiation with high-energy radiation producing ion implantation characterised by the angle between the ion beam and the crystal planes or the main crystal surface
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/06Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
    • H01L29/08Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions with semiconductor regions connected to an electrode carrying current to be rectified, amplified or switched and such electrode being part of a semiconductor device which comprises three or more electrodes
    • H01L29/0843Source or drain regions of field-effect devices
    • H01L29/0847Source or drain regions of field-effect devices of field-effect transistors with insulated gate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/7842Field effect transistors with field effect produced by an insulated gate means for exerting mechanical stress on the crystal lattice of the channel region, e.g. using a flexible substrate
    • H01L29/7848Field effect transistors with field effect produced by an insulated gate means for exerting mechanical stress on the crystal lattice of the channel region, e.g. using a flexible substrate the means being located in the source/drain region, e.g. SiGe source and drain

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  • Engineering & Computer Science (AREA)
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  • Microelectronics & Electronic Packaging (AREA)
  • Computer Hardware Design (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • High Energy & Nuclear Physics (AREA)
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  • Crystallography & Structural Chemistry (AREA)
  • Insulated Gate Type Field-Effect Transistor (AREA)

Abstract

The invention discloses a kind of methods for reducing metal-oxide-semiconductor stress effect, belong to the technology of field of semiconductor processing, including:Step S1 prepares area to the source-drain electrode with one first particle and carries out one first injection technology;Step S2 prepares area to the source-drain electrode with one second particle and carries out one second injection technology;Step S3 prepares area to the source-drain electrode with one the 3rd particle and carries out one the 3rd injection technology;Step S4 prepares area to the source-drain electrode and carries out heat treatment process.The advantageous effect of the technical solution is:Invention increases the ion concentrations in the source region or drain region formed after ion implanting, reduce the stress effect in metal-oxide-semiconductor.

Description

A kind of method for reducing metal-oxide-semiconductor stress effect
Technical field
The present invention relates to a kind of technologies of field of semiconductor processing, are specifically a kind of reduction metal-oxide-semiconductor stress effect Method.
Background technology
The generation early start of shallow grooved-isolation technique (Shallow Trench Isolation, STI) was in 80 years last century Generation, but initially there are with high costs, and the problem of being still not perfect and just start quilt until last century Mo in terms of technology It accepts extensively and quotes.Shallow grooved-isolation technique be different from before technology, it is completely flat a kind of new Isolation technology, and shallow trench isolation technology avoid completely before processing technology used in high temperature technological problems;And It can guarantee effective area of the device in active area;It is put down in addition, the surface of silicon substrate and spacer medium is all completely disposed in one On face;In addition shallow-trench isolation technology also improves the problem of junction capacity is with minimum isolating partition, and more important point is low temperature Technique also potentially improves board yield, reduces the cost of production, and the above advantage is but also STI isolation technologies become The essential isolation technology in Deep submicron devi8 field at present.
Shallow-trench isolation technology is that a kind of technique of the isolated area between transistor active area is made in wafer substrate, can be had Effect ensures that N-type and P-doped zone can thoroughly be separated.Shallow trench isolation technology is in N-type and P-doped zone first by mask definition Silicon area etch away, be allowed to form a shallow trench, then insert the material of insulation into groove again, presently act as this The mainly silica of packing material, so as to have the function that insulation.Compared to traditional native oxide isolation technology, shallow trench every Can be than the breakdown voltage of native oxide isolation technology bigger from technology, and interelectrode leakage current can be reduced.
STI technique is widely used in current metal-oxide-semiconductor because of the advantages that its isolation performance is excellent, and leakage current is small and prepares In technique.But using STI technique after, stress effect can be generated.Stress effect (i.e. LOD effects) refers to that STI isolation generates not Sizing or uneven twin shaft compression, it is uneven so as to cause the stress distribution of active area, influence the expansion of active area intermediate ion It dissipates, and then harmful effect can be generated to every electric property of device.
Improve the common method of LOD effects at present as change wires design, but this method can reduce the integrated level of metal-oxide-semiconductor.
The content of the invention
The present invention proposes a kind of method for reducing metal-oxide-semiconductor stress effect for deficiencies of the prior art.This hair The bright ion concentration added in the source region formed after ion implanting or drain region, reduces the stress effect in metal-oxide-semiconductor.
The present invention is achieved by the following technical solutions:
The present invention relates to a kind of methods for the stress effect for reducing metal-oxide-semiconductor, provide a substrate, shallow in being formed on the substrate Groove isolation construction, the fleet plough groove isolation structure separate the substrate to form at least one active area, described have in each Source region forms gate patterns and prepares area to separate the active area and form source-drain electrode;
It is further comprising the steps of:
Step S1 prepares area to the source-drain electrode with one first particle and carries out one first injection technology;
Step S2 prepares area to the source-drain electrode with one second particle and carries out one second injection technology;
Step S3 prepares area to the source-drain electrode with one the 3rd particle and carries out one the 3rd injection technology;
Step S4 prepares area to the source-drain electrode and carries out heat treatment process.
Preferably, the method for the stress effect of the reduction metal-oxide-semiconductor, wherein, in the step S1, the first injection work The particle injection direction of skill has a predetermined angle with the substrate.
Preferably, the method for the stress effect of the reduction metal-oxide-semiconductor, wherein, the predetermined angle is 90 degree.
Preferably, the method for the stress effect of the reduction metal-oxide-semiconductor, wherein, in the step S1, first particle is Carbon atom.
Preferably, the method for the stress effect of the reduction metal-oxide-semiconductor, wherein, the Implantation Energy scope of the carbon atom is 10 ~50keV.
Preferably, the method for the stress effect of the reduction metal-oxide-semiconductor, wherein, the implantation dosage of the carbon atom is 1013/cm2 ~1015/cm2
Preferably, the method for the stress effect of the reduction metal-oxide-semiconductor, wherein, second particle is arsenic ion;And/or
3rd particle is phosphonium ion.
Preferably, the method for the stress effect of the reduction metal-oxide-semiconductor, wherein, second particle has one first dosage, institute The 3rd particle is stated with one second dosage, the ratio of first dosage and second dosage is 20~50.
Preferably, the method for the stress effect of the reduction metal-oxide-semiconductor, wherein, first dosage and second dosage Ratio is 35.
Preferably, the method for the stress effect of the reduction metal-oxide-semiconductor, wherein, in the step S4, the heat treatment process With a preset temperature, the preset temperature is 1020 degrees Celsius;And/or
The heat treatment process continues a preset time, and the preset time is 16 seconds.
The advantageous effect of above-mentioned technical proposal is:
Invention increases the ion concentrations in the source region or drain region formed after ion implanting, reduce answering in metal-oxide-semiconductor Stress effect.
Description of the drawings
Fig. 1 is a kind of method flow schematic diagram for reducing metal-oxide-semiconductor stress effect in the preferred embodiment of the present invention;
Fig. 2 is a kind of method carbon atom injection process for reducing metal-oxide-semiconductor stress effect in the preferred embodiment of the present invention Schematic diagram;
In the preferred embodiment of Fig. 3 present invention, a kind of method arsenic ion injection process for reducing metal-oxide-semiconductor stress effect is shown It is intended to;
In the preferred embodiment of Fig. 4 present invention, a kind of method phosphonium ion injection process for reducing metal-oxide-semiconductor stress effect is shown It is intended to;
In the preferred embodiment of Fig. 5 present invention, the ion solubility that the source-drain electrode after heat treatment prepares the section in area is bent Line comparison diagram;
In the preferred embodiment of Fig. 6 present invention, the source-drain electrode after heat treatment prepares the arsenic ion and phosphorus of the section in area The solubility curve comparison diagram of ion;
In figure:1 gate patterns, 2 fleet plough groove isolation structures, 3 substrates.
Specific embodiment
Below in conjunction with the attached drawing in the embodiment of the present invention, the technical solution in the embodiment of the present invention is carried out clear, complete Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art obtained on the premise of creative work is not made it is all its His embodiment, belongs to the scope of protection of the invention.
It should be noted that in the case where there is no conflict, the feature in embodiment and embodiment in the present invention can phase Mutually combination.
The invention will be further described in the following with reference to the drawings and specific embodiments, but not as limiting to the invention.
As shown in Figure 1, the present embodiment is related to a kind of method for the stress effect for reducing metal-oxide-semiconductor,
A substrate 3 is provided, in forming fleet plough groove isolation structure 2 on substrate 3, the fleet plough groove isolation structure 2 separates substrate 3 To form at least one active area, gate patterns 1 are formed in each active area to separate active area and form source-drain electrode and prepare area.
Specifically include following steps:
Step S1, as shown in Fig. 2, preparing area to source-drain electrode with one first particle carries out one first injection technology.
In first injection technology, the first particle is carbon atom, i.e., it is former to carry out carbon in the upper surface that source-drain electrode is prepared in area Son injection.
First injection technology particle injection direction has a predetermined angle with substrate 3, and carbon atom injects source with predetermined angle Drain electrode is prepared in area.
The predetermined angle of the injection of carbon atom is 90 degree.
The Implantation Energy scope of carbon atom is 10~50keV.
The implantation dosage of carbon atom is 1013/cm2~1015/cm2
Step S2, as shown in figure 3, preparing area to source-drain electrode with one second particle carries out one second injection technology.
In second injection technology, the second particle is arsenic ion, that is, carries out arsenic ion injection.Arsenic ion is injected into complete The source-drain electrode injected into carbon atom prepares the surface in area.
For the dosage of arsenic ion injection for the first dosage, i.e. arsenic ion in the second injection technology is injected into source with the first dosage Drain electrode prepares area.
Step S3, as shown in figure 4, preparing area to source-drain electrode with one the 3rd particle carries out one the 3rd injection technology.
In 3rd injection technology, the 3rd particle is phosphonium ion, that is, carries out phosphonium ion injection.Phosphonium ion is injected into complete The source-drain electrode injected into arsenic ion is prepared in area.
The implantation dosage of phosphonium ion is the second dosage, i.e., carries out the 3rd injection technology with the second dosage.
The ratio of first dosage and the second dosage is 20~50.
In the present embodiment, the ratio of the first dosage and the second dosage is 35.
Step S4 prepares area to source-drain electrode and carries out heat treatment process.
Heat treatment process has a preset temperature, and preset temperature is 1020 degrees Celsius.
Optionally, heat treatment process continues a preset time, and preset time is 16 seconds.After Overheating Treatment, source-drain electrode system Further it is processed into source electrode or the drain electrode of metal-oxide-semiconductor in preparation area.Preset temperature and preset time can meet simultaneously.
As shown in figure 5, showing that source-drain electrode prepares the ion concentration of the longitudinal cross-section in area, a curve is without carbon atom Injection, another is to be injected by carbon atom, and the ion concentration distribution after carbon atom injects is substantially better than without carbon atom The ion concentration distribution of injection.After the first injection technology carbon atom injection technology, source-drain electrode prepares the doping that area is formed The scope bigger of profile.
As shown in fig. 6, in a source-drain electrode prepares area's longitudinal profile, after carbon atom injection technology, prepared by source-drain electrode Arsenic ion concentration and phosphate ion concentration in area increase.
The power of the stress effect in metal-oxide-semiconductor is indicated with the absolute value of Δ, wherein:
VtSaminThreshold voltage when width S a for source-drain electrode preparation area is minimum value;
VtSa=10Threshold voltage when width S a for source-drain electrode preparation area is 10um.
Δ is -0.326 when being injected without carbon atom, and Δ is -0.262 after carbon atom injects, i.e., by carbon atom The absolute value of Δ reduces 6.4% after injection.
The method of the reduction metal-oxide-semiconductor stress effect of the present invention, compared with prior art:After ion implanting Ion concentration in the source region of formation or drain region reduces the stress effect in metal-oxide-semiconductor.
The foregoing is merely preferred embodiments of the present invention, not thereby limit embodiments of the present invention and protection model It encloses, to those skilled in the art, should can appreciate that all with made by description of the invention and diagramatic content Equivalent substitution and obviously change obtained scheme, should all include within the scope of the present invention.

Claims (10)

  1. A kind of 1. method for reducing metal-oxide-semiconductor stress effect, which is characterized in that
    A substrate is provided, in forming fleet plough groove isolation structure on the substrate, the fleet plough groove isolation structure separates the substrate To form at least one active area, gate patterns are formed in each active area to separate the active area and form source-drain electrode Prepare area;
    It is further comprising the steps of:
    Step S1 prepares area to the source-drain electrode with one first particle and carries out one first injection technology;
    Step S2 prepares area to the source-drain electrode with one second particle and carries out one second injection technology;
    Step S3 prepares area to the source-drain electrode with one the 3rd particle and carries out one the 3rd injection technology;
    Step S4 prepares area to the source-drain electrode and carries out heat treatment process.
  2. 2. the method according to claim 1 for reducing metal-oxide-semiconductor stress effect, which is characterized in that
    In the step S1, the particle injection direction of first injection technology has a predetermined angle with the substrate.
  3. 3. the method according to claim 2 for reducing metal-oxide-semiconductor stress effect, which is characterized in that
    The predetermined angle is 90 degree.
  4. 4. the method according to claim 1 for reducing metal-oxide-semiconductor stress effect, which is characterized in that
    In the step S1, first particle is carbon atom.
  5. 5. the method according to claim 4 for reducing metal-oxide-semiconductor stress effect, which is characterized in that
    The Implantation Energy scope of the carbon atom is 10~50keV.
  6. 6. the method according to claim 4 for reducing metal-oxide-semiconductor stress effect, which is characterized in that
    The implantation dosage of the carbon atom is 1013/cm2~1015/cm2
  7. 7. the method according to claim 1 for reducing metal-oxide-semiconductor stress effect, which is characterized in that
    Second particle is arsenic ion;And/or
    3rd particle is phosphonium ion.
  8. 8. the method according to claim 1 for reducing metal-oxide-semiconductor stress effect, which is characterized in that
    Second particle have one first dosage, the 3rd particle have one second dosage, first dosage with it is described The ratio of second dosage is 20~50.
  9. 9. the method according to claim 8 for reducing metal-oxide-semiconductor stress effect, which is characterized in that
    The ratio of first dosage and second dosage is 35.
  10. 10. the method according to claim 1 for reducing metal-oxide-semiconductor stress effect, which is characterized in that
    In the step S4, the heat treatment process has a preset temperature, and the preset temperature is 1020 degrees Celsius;With/ Or
    The heat treatment process continues a preset time, and the preset time is 16 seconds.
CN201711378886.3A 2017-12-19 2017-12-19 A method of reducing metal-oxide-semiconductor stress effect Active CN108109922B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109659236A (en) * 2018-12-17 2019-04-19 吉林华微电子股份有限公司 Reduce the process and its VDMOS semiconductor devices of VDMOS recovery time

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0499037A (en) * 1990-08-06 1992-03-31 Fujitsu Ltd Manufacture of semiconductor device
JPH07226509A (en) * 1994-02-14 1995-08-22 Sanyo Electric Co Ltd Semiconductor integrated circuit and manufacture thereof
JPH10303418A (en) * 1997-04-30 1998-11-13 Fujitsu Ltd Manufacture of semiconductor device
US20030030077A1 (en) * 2001-08-07 2003-02-13 Jung Woo-Chan Semiconductor device and method for manufacturing the same
CN101752253A (en) * 2008-12-08 2010-06-23 中芯国际集成电路制造(上海)有限公司 Manufacture method of metal oxide semiconductor (MOS) transistor
CN101834137A (en) * 2009-03-12 2010-09-15 中芯国际集成电路制造(上海)有限公司 Ion implantation method for source/drain electrodes

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0499037A (en) * 1990-08-06 1992-03-31 Fujitsu Ltd Manufacture of semiconductor device
JPH07226509A (en) * 1994-02-14 1995-08-22 Sanyo Electric Co Ltd Semiconductor integrated circuit and manufacture thereof
JPH10303418A (en) * 1997-04-30 1998-11-13 Fujitsu Ltd Manufacture of semiconductor device
US20030030077A1 (en) * 2001-08-07 2003-02-13 Jung Woo-Chan Semiconductor device and method for manufacturing the same
CN101752253A (en) * 2008-12-08 2010-06-23 中芯国际集成电路制造(上海)有限公司 Manufacture method of metal oxide semiconductor (MOS) transistor
CN101834137A (en) * 2009-03-12 2010-09-15 中芯国际集成电路制造(上海)有限公司 Ion implantation method for source/drain electrodes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109659236A (en) * 2018-12-17 2019-04-19 吉林华微电子股份有限公司 Reduce the process and its VDMOS semiconductor devices of VDMOS recovery time
CN109659236B (en) * 2018-12-17 2022-08-09 吉林华微电子股份有限公司 Process method for reducing VDMOS recovery time and VDMOS semiconductor device thereof

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Address after: 430205 No.18, Gaoxin 4th Road, Donghu Development Zone, Wuhan City, Hubei Province

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Address before: 430205 No.18, Gaoxin 4th Road, Donghu Development Zone, Wuhan City, Hubei Province

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