CN108085830A - 一种高强阻燃防静电面料 - Google Patents

一种高强阻燃防静电面料 Download PDF

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CN108085830A
CN108085830A CN201711199156.7A CN201711199156A CN108085830A CN 108085830 A CN108085830 A CN 108085830A CN 201711199156 A CN201711199156 A CN 201711199156A CN 108085830 A CN108085830 A CN 108085830A
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fire
retardant
cotton
dyeing
fiber
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靳云平
金辉
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Xinxiang Patron Saint Special Fabric Co Ltd
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    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/533—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/44—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing nitrogen and phosphorus
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D06M2101/36—Aromatic polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D10B2201/02—Cotton
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明涉及一种高强阻燃防静电面料，它的制备方法包括以下步骤：（1）纱线成分配比：（2）纺纱：各成分混配均匀一致，棉纤维采用长绒棉，纺纱方式采用赛络纺工艺，采用导电纤维与其它纤维掺混到一起以确保每一根纱上都含有导电纤维，采用合股线，加中度捻；（3）织布：采用喷气织机或箭杆织机；（4）染色：采用棉布长车轧染工艺；接着依次按照如下流程进行：翻布缝头→烧毛→退浆、煮练、漂白→丝光→染色→阻燃→氨熏→氧化→水洗→烘干→焙烘→预缩→检验包装。该工艺制作的面料手感柔软，富有透气性、良好的防静电性能、阻燃性和可生物降解性等特点。

Description

一种高强阻燃防静电面料
技术领域
本发明属于阻燃面料的制备工艺技术领域，具体涉及一种高强阻燃防静电面料。
背景技术
中国专利CN1732295A中公开了一种皮芯结构的双组分纤维的阻燃织物，采用具有阻燃性能的聚合物作为皮部分，热塑性聚合物作为芯成分，但由于该织物的手感较硬，热稳定性差，因而限制在很多方面的应用。
中国专利CN1331767A中公开了一种含纤维素纺织材料的生产方法，由于在该专利中需要用到大量的交联剂，交联剂的虽然能使纤维有着良好的力学强度，但交联剂对环境的污染性和环境稳定性较差，不能使材料保持持久的力学性能。
随着人们安全意识的不断提高，对织物的阻燃性能也有了相应要求，特别是织物对于预防、延缓或者终止火灾的作用。由于一般 的阻燃剂多为卤系和磷系，大部分都具有较大的毒性，而且在制备过程中需要用到甲醛或甲苯，使得有机物残留，对人体健康产生一定危险，同时，经处理后的织物手感硬、强力损伤大，穿着舒适度低，严重影响阻燃织物的品质和使用效果。
发明内容
本发明针对现有技术中存在的不足之处，提供一种高强阻燃防弹性面料，该面料手感柔软，富有弹性，颜色可以按照客户要求定做，穿着舒服，性价比较高，即适用于工装又可用于时装。
本发明的目的是以下述方式实现的：
本发明提供了一种高强阻燃防静电面料，它的制备方法包括以下步骤：
（1）纱线成分配比：20~59wt%芳纶1313、40~80wt%棉纤维和1~2wt%导电纤维；（2）纺纱：各成分混配均匀一致，棉纤维采用长绒棉，纺纱方式采用赛络纺工艺，采用导电纤维与其它纤维掺混到一起以确保每一根纱上都含有导电纤维，采用合股线，加中度捻；（3）织布：采用喷气织机或箭杆织机；（4）染色：采用棉布长车轧染工艺；（5）接着依次按照如下流程进行：翻布缝头→烧毛→退浆、煮练、漂白→丝光→染色→阻燃→氨熏→氧化→水洗→烘干→焙烘→预缩→检验包装。
根据上述的高强阻燃防静电面料，步骤（1）中纱线成分配比：38wt%芳纶1313 、60wt%棉纤维和2wt%导电纤维。
根据上述的高强阻燃防弹性面料，步骤（5）中阻燃过程中用的阻燃剂由如下成分制成：四羟甲基氯化磷尿素缩合物 300～400g/l、渗透剂JFC 1～3g/l、柔软剂 10～20g/l、抗油拒水剂40g～80g/l。
根据上述的高强阻燃防静电面料，步骤（5）中阻燃过程中用的阻燃剂由如下成分制成：四羟甲基氯化磷尿素缩合物 350g/l、渗透剂JFC 2g/l、柔软剂 15g/l、抗油拒水剂50g/l。
与现有技术相比，本发明的有益效果：
本发明提供的一种高强阻燃防静电面料，该工艺充分利用了几种高性能纤维的特点，实现了优势互补，成功开发出来一种高强、阻燃、防静电面料。该工艺制作的面料手感柔软，富有透气性、良好的防静电性能、阻燃性和可生物降解性等特点，但强力差不耐磨，不可单独用于工作服。
具体实施方式
实施例1：
本发明提供了一种高强阻燃防静电面料，它的制备方法包括以下步骤：
（1）纱线成分配比：20wt%芳纶1313 、79wt%棉纤维和1wt%导电纤维；（2）纺纱：各成分混配均匀一致，棉纤维采用长绒棉，纺纱方式采用赛络纺工艺，采用导电纤维与其它纤维掺混到一起以确保每一根纱上都含有导电纤维，采用合股线，加中度捻；（3）织布：采用喷气织机或箭杆织机；（4）染色：采用高温高压液流工艺；（5）接着依次按照如下流程进行：翻布缝头→烧毛→退浆、煮练、漂白→丝光→染色→阻燃→氨熏→氧化→水洗→烘干→焙烘→预缩→检验包装。
步骤（5）中阻燃过程中用的阻燃剂由如下成分制成：四羟甲基氯化磷尿素缩合物300～400g/l、渗透剂JFC 1～3g/l、柔软剂 10～20g/l、抗油拒水剂40g～80g/l。
实施例2：
与实施例1相同部分不再重述，不同之处在于：步骤（1）中纱线成分配比：38wt%芳纶1313 、60wt%棉纤维和2wt%导电纤维。
实施例3：
与实施例1相同部分不再重述，不同之处在于：步骤（5）中阻燃过程中用的阻燃剂由如下成分制成：四羟甲基氯化磷尿素缩合物 350g/l、渗透剂JFC 2g/l、柔软剂 15g/l、抗油拒水剂 50g/l。
以上所述的仅是本发明的优选实施方式，应当指出，对于本领域的技术人员来说，在不脱离本发明整体构思前提下，还可以作出若干改变和改进，这些也应该视为本发明的保护范围。

Claims (4)

1.一种高强阻燃防静电面料，其特征在于它的制备方法包括以下步骤：
（1）纱线成分配比：20~59wt%芳纶1313 、40~80wt%棉纤维和1~2wt%导电纤维；
（2）纺纱：各成分混配均匀一致，棉纤维采用长绒棉，纺纱方式采用赛络纺工艺，采用导电纤维与其它纤维掺混到一起以确保每一根纱上都含有导电纤维，采用合股线，加中度捻；（3）织布：采用喷气织机或箭杆织机；
（4）染色：采用高温高压液流工艺；
（5）接着依次按照如下流程进行：翻布缝头→烧毛→退浆、煮练、漂白→丝光→染色→阻燃→氨熏→氧化→水洗→烘干→焙烘→预缩→检验包装。
2.根据权利要求1所述的高强阻燃防静电面料，其特征在于：步骤（1）中纱线成分配比：38wt%芳纶1414 、60wt%棉纤维和2wt%导电纤维。
3.根据权利要求1所述的高强阻燃防静电面料，其特征在于：步骤（5）中阻燃过程中用的阻燃剂由如下成分制成：四羟甲基氯化磷尿素缩合物 300～400g/l、渗透剂JFC 1～3g/l、柔软剂 10～20g/l、抗油拒水剂40g～80g/l。
4.根据权利要求3所述的高强阻燃防静电面料，其特征在于：步骤（5）中阻燃过程中用的阻燃剂由如下成分制成：四羟甲基氯化磷尿素缩合物 350g/l、渗透剂JFC 2g/l、柔软剂15g/l、抗油拒水剂 50g/l。
CN201711199156.7A 2017-11-26 2017-11-26 一种高强阻燃防静电面料 Pending CN108085830A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112281468A (zh) * 2019-07-22 2021-01-29 新乡市护神特种织物有限公司 一种防静电阻燃针织物及其制造方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101627158A (zh) * 2007-05-11 2010-01-13 亨茨曼纺织货品（德国）有限责任公司 纤维材料的阻燃整理
CN103541079A (zh) * 2013-10-06 2014-01-29 太原理工大学 一种高强、阻燃、抗静电混纺纱线及其生产方法
CN104611806A (zh) * 2015-02-13 2015-05-13 上海特安纶纤维有限公司 包含含砜基的芳香族聚合物纤维的阻燃纱线和由其制得的织物及制备方法
CN104630958A (zh) * 2015-02-13 2015-05-20 上海特安纶纤维有限公司 包含芳香族聚酰胺和聚芳砜的共混聚合物纤维的阻燃纱线制得的织物和及制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101627158A (zh) * 2007-05-11 2010-01-13 亨茨曼纺织货品（德国）有限责任公司 纤维材料的阻燃整理
CN103541079A (zh) * 2013-10-06 2014-01-29 太原理工大学 一种高强、阻燃、抗静电混纺纱线及其生产方法
CN104611806A (zh) * 2015-02-13 2015-05-13 上海特安纶纤维有限公司 包含含砜基的芳香族聚合物纤维的阻燃纱线和由其制得的织物及制备方法
CN104630958A (zh) * 2015-02-13 2015-05-20 上海特安纶纤维有限公司 包含芳香族聚酰胺和聚芳砜的共混聚合物纤维的阻燃纱线制得的织物和及制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112281468A (zh) * 2019-07-22 2021-01-29 新乡市护神特种织物有限公司 一种防静电阻燃针织物及其制造方法

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