CN108085162A - 绿色环保洗涤剂 - Google Patents

绿色环保洗涤剂 Download PDF

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CN108085162A
CN108085162A CN201711270417.XA CN201711270417A CN108085162A CN 108085162 A CN108085162 A CN 108085162A CN 201711270417 A CN201711270417 A CN 201711270417A CN 108085162 A CN108085162 A CN 108085162A
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徐云丽
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Hangzhou New Picture Biotechnology Co ltd
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Abstract

本发明公开了一种绿色环保洗涤剂，包括以下重量份组份：水40‑60份；柠檬酸钠0.2‑0.8份；茶皂素1‑3份；2,5‑二甲基苯并恶唑0.2‑0.8份；1,2‑丙二醇1‑5份；三乙醇胺1‑3份；α‑十六烷基‑ω‑羟基‑聚(氧乙烯)4‑8份；月桂醇聚醚硫酸酯钠3‑7份；N,N‑二(2‑羟乙基)十二烷基酰胺0.5‑1.5份；十二烷基葡萄糖苷3‑7份；二甲苯磺酸钠1‑3份。本发明的绿色环保洗涤剂，绿色环保，并且具有优异的去污功能，无皮肤刺激，并且能够有效去除果蔬上残留的农药。

Description

绿色环保洗涤剂
技术领域
本发明涉及一种洗涤剂，尤其涉及一种绿色环保洗涤剂。
背景技术
洗涤剂又叫洗调剂，其主要成分是表面活性剂，表面活性剂是分子结构中含有亲水基和亲油基两部分的有机化合物。一般是根据表面活性剂在水溶液中能否分解为离子，又将其分为离子型表面活性剂和非离子型表面活性剂的两大类。离子型表面活性剂又可分为阳离子表面活性剂、阴离子表面活性剂和两性离子表面活性剂三种。
洗涤剂按照外观形态分：粉体洗涤剂、液体洗涤剂、固体洗涤剂；洗涤剂按照使用范畴分：民用洗涤剂、工业洗涤剂。
随着我国新型工业化进程的加快，清洗已经成为工业生产中的一个必不可少的重要环节，工业清洁用品的市场需求将会保持持续高位增长，同时这样对清洗技术进步提出了新的、更高的要求。中国现有约4000家清洗用品制造商、分销商和代理商，工业和商业用途用清洁用品的最终用户就达到500万家。工业清洁洗涤剂行业的产值约为200亿元。
现有技术中，洗涤剂去污功能并不理想。
发明内容
针对现有技术中存在的不足，本发明所要解决的技术问题是提供一种绿色环保洗涤剂。
本发明是采用如下技术方案实现的：
一种绿色环保洗涤剂，包括以下重量份组份：
水40-60份；
柠檬酸钠(CAS号：6132-04-3)0.2-0.8份；
茶皂素(CAS号：8047-15-2)1-3份；
2,5-二甲基苯并恶唑(CAS号：5676-58-4)0.2-0.8份；
1,2-丙二醇1-5份；
三乙醇胺1-3份；
α-十六烷基-ω-羟基-聚(氧乙烯)(CAS号：9004-95-9)4-8份；
月桂醇聚醚硫酸酯钠(CAS号：9004-82-4)3-7份；
N,N-二(2-羟乙基)十二烷基酰胺(CAS号：120-40-1)0.5-1.5份；
十二烷基葡萄糖苷(CAS号：110615-47-9)3-7份；
二甲苯磺酸钠(CAS号：1300-72-7)1-3份。
优选的，一种绿色环保洗涤剂，包括以下重量份组份：
水40-60份；
柠檬酸钠0.2-0.8份；
茶皂素1-3份；
2,5-二甲基苯并恶唑0.2-0.8份；
1,2-丙二醇1-5份；
三乙醇胺1-3份；
α-十六烷基-ω-羟基-聚(氧乙烯)4-8份；
月桂醇聚醚硫酸酯钠3-7份；
N,N-二(2-羟乙基)十二烷基酰胺0.5-1.5份；
十二烷基葡萄糖苷3-7份；
二甲苯磺酸钠1-3份；
酶0.05-0.15份。
优选的，所述酶为脂肪酶、淀粉葡糖苷酶、纤维素酶、脱氧核糖核酸酶、漆酶、木质素酶、超氧歧化酶、辅酶A、无花果蛋白酶、过氧化氢酶、柚苷酶、橙皮苷酶、菠萝蛋白酶、淀粉酶、葡糖氧化酶、胃蛋白酶中的至少一种。
最优的，所述酶为无花果蛋白酶、柚苷酶和橙皮苷酶按质量比为8：(1-3)：(1-3)混合而成。
常用本领域通用方法即可制得本发明的绿色环保洗涤剂，例如将水加热至40℃，再将其他原料加入，搅拌混合均匀，冷却至室温即可。
本发明的绿色环保洗涤剂，绿色环保，并且具有良好的去污功能，无皮肤刺激，并且能够有效去除果蔬上残留的农药。
具体实施方式
实施例中部分原料的参数如下：
柚苷酶：酶活力5万U/g。
橙皮苷酶：酶活力10万U/g。
无花果蛋白酶：酶活力10万U/g。
实施例1
一种绿色环保洗涤剂，包括以下重量份组份：
水50份；
柠檬酸钠0.5份；
茶皂素2份；
2,5-二甲基苯并恶唑0.5份；
1,2-丙二醇3份；
三乙醇胺2份；
α-十六烷基-ω-羟基-聚(氧乙烯)6份；
月桂醇聚醚硫酸酯钠5份；
N,N-二(2-羟乙基)十二烷基酰胺1份；
十二烷基葡萄糖苷5份；
二甲苯磺酸钠2份。
实施例2
一种绿色环保洗涤剂，包括以下重量份组份：
水50份；
柠檬酸钠0.5份；
茶皂素2份；
2,5-二甲基苯并恶唑0.5份；
1,2-丙二醇3份；
三乙醇胺2份；
α-十六烷基-ω-羟基-聚(氧乙烯)6份；
月桂醇聚醚硫酸酯钠5份；
N,N-二(2-羟乙基)十二烷基酰胺1份；
十二烷基葡萄糖苷5份；
二甲苯磺酸钠2份；
酶0.1份。
所述酶为柚苷酶和橙皮苷酶按质量比为1:1混合而成。
实施例3
一种绿色环保洗涤剂，包括以下重量份组份：
水50份；
柠檬酸钠0.5份；
茶皂素2份；
2,5-二甲基苯并恶唑0.5份；
1,2-丙二醇3份；
三乙醇胺2份；
α-十六烷基-ω-羟基-聚(氧乙烯)6份；
月桂醇聚醚硫酸酯钠5份；
N,N-二(2-羟乙基)十二烷基酰胺1份；
十二烷基葡萄糖苷5份；
二甲苯磺酸钠2份；
酶0.1份。
所述酶为无花果蛋白酶和柚苷酶按质量比为2:1混合而成。
实施例4
一种绿色环保洗涤剂，包括以下重量份组份：
水50份；
柠檬酸钠0.5份；
茶皂素2份；
2,5-二甲基苯并恶唑0.5份；
1,2-丙二醇3份；
三乙醇胺2份；
α-十六烷基-ω-羟基-聚(氧乙烯)6份；
月桂醇聚醚硫酸酯钠5份；
N,N-二(2-羟乙基)十二烷基酰胺1份；
十二烷基葡萄糖苷5份；
二甲苯磺酸钠2份；
酶0.1份。
所述酶为无花果蛋白酶和橙皮苷酶按质量比为2:1混合而成。
实施例5
一种绿色环保洗涤剂，包括以下重量份组份：
水50份；
柠檬酸钠0.5份；
茶皂素2份；
2,5-二甲基苯并恶唑0.5份；
1,2-丙二醇3份；
三乙醇胺2份；
α-十六烷基-ω-羟基-聚(氧乙烯)6份；
月桂醇聚醚硫酸酯钠5份；
N,N-二(2-羟乙基)十二烷基酰胺1份；
十二烷基葡萄糖苷5份；
二甲苯磺酸钠2份；
酶0.1份。
所述酶为无花果蛋白酶、柚苷酶和橙皮苷酶按质量比为4:1:1混合而成。
将水加热至40℃，再将其他原料加入，搅拌混合均匀，冷却至室温即可制得各实施例的绿色环保洗涤剂。
测试例1
对实施例进行去除农药残留性能测试。
分别将实施例1-5绿色环保洗涤剂与去离子水按质量比为1:2000混合均匀，得到绿色环保洗涤剂的稀释液；将同一蔬菜地采摘的韭菜随机分组，每组500g，分别浸泡在2000g温度为25℃的绿色环保洗涤剂的稀释液中，最后一组浸泡在2000g温度为25℃的去离子水中作为对照组，浸泡时间为15分钟，取出用4000g清水漂洗15分钟，晾干，测试清洗后韭菜中的农药残留量。农药残留测试方法参照国标GB/T20769-2008进行。具体测试结果见表1。
表1：韭菜农药残留量测试结果表
多菌灵，mg/kg
实施例1 0.086
实施例2 0.051
实施例3 0.038
实施例4 0.037
实施例5 0.027
对照组 0.256
测试例2
对实施例进行去污力性能测试。采用CN103205323B测试例1的方法进行测试，具体结果见表2。
表2：去污力性能测试表
去污力ω，％
实施例1 40.2
实施例2 42.5
实施例3 43.3
实施例4 43.2
实施例5 45.7
本发明的绿色环保洗涤剂，绿色环保，并且具有优异的去污功能，无皮肤刺激，并且能够有效去除果蔬上残留的农药。

Claims (3)

1.一种绿色环保洗涤剂，包括以下重量份组份：
水40-60份；
柠檬酸钠0.2-0.8份；
茶皂素1-3份；
2,5-二甲基苯并恶唑0.2-0.8份；
1,2-丙二醇1-5份；
三乙醇胺1-3份；
α-十六烷基-ω-羟基-聚(氧乙烯)4-8份；
月桂醇聚醚硫酸酯钠3-7份；
N,N-二(2-羟乙基)十二烷基酰胺0.5-1.5份；
十二烷基葡萄糖苷3-7份；
二甲苯磺酸钠1-3份。
2.如权利要求1所述的绿色环保洗涤剂，包括以下重量份组份：
水40-60份；
柠檬酸钠0.2-0.8份；
茶皂素1-3份；
2,5-二甲基苯并恶唑0.2-0.8份；
1,2-丙二醇1-5份；
三乙醇胺1-3份；
α-十六烷基-ω-羟基-聚(氧乙烯)4-8份；
月桂醇聚醚硫酸酯钠3-7份；
N,N-二(2-羟乙基)十二烷基酰胺0.5-1.5份；
十二烷基葡萄糖苷3-7份；
二甲苯磺酸钠1-3份；
酶0.05-0.15份。
3.如权利要求1和2所述的绿色环保洗涤剂，其特征在于：所述酶为脂肪酶、淀粉葡糖苷酶、纤维素酶、脱氧核糖核酸酶、漆酶、木质素酶、超氧歧化酶、辅酶A、无花果蛋白酶、过氧化氢酶、柚苷酶、橙皮苷酶、菠萝蛋白酶、淀粉酶、葡糖氧化酶、胃蛋白酶中的至少一种。
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CN103937621A (zh) * 2014-04-10 2014-07-23 沈阳化工大学 含茶皂素除农药洗涤剂及其制备方法
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* Cited by examiner, † Cited by third party
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