CN108083773A - 一种连续无机纤维增强陶瓷的制备方法 - Google Patents
一种连续无机纤维增强陶瓷的制备方法 Download PDFInfo
- Publication number
- CN108083773A CN108083773A CN201810074600.0A CN201810074600A CN108083773A CN 108083773 A CN108083773 A CN 108083773A CN 201810074600 A CN201810074600 A CN 201810074600A CN 108083773 A CN108083773 A CN 108083773A
- Authority
- CN
- China
- Prior art keywords
- printing
- inorganic fiber
- ceramic
- printer
- continuous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 57
- 239000012784 inorganic fiber Substances 0.000 title claims abstract description 37
- 230000002708 enhancing effect Effects 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 5
- 238000010146 3D printing Methods 0.000 claims abstract description 55
- 239000000463 material Substances 0.000 claims abstract description 46
- 239000004927 clay Substances 0.000 claims abstract description 41
- 239000000835 fiber Substances 0.000 claims abstract description 25
- 238000005245 sintering Methods 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 14
- 239000002994 raw material Substances 0.000 claims description 11
- 239000004014 plasticizer Substances 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- 239000002689 soil Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 24
- 229910010293 ceramic material Inorganic materials 0.000 abstract description 14
- 238000007493 shaping process Methods 0.000 abstract description 7
- 238000007639 printing Methods 0.000 abstract description 4
- 150000001875 compounds Chemical class 0.000 abstract description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 30
- 235000019441 ethanol Nutrition 0.000 description 12
- 239000000843 powder Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 6
- 229910052901 montmorillonite Inorganic materials 0.000 description 6
- 239000005995 Aluminium silicate Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920002748 Basalt fiber Polymers 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000010433 feldspar Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- -1 and of low cost Substances 0.000 description 1
- 229940036811 bone meal Drugs 0.000 description 1
- 239000002374 bone meal Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000012681 fiber drawing Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 235000021552 granulated sugar Nutrition 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/36—Reinforced clay-wares
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5216—Inorganic
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5216—Inorganic
- C04B2235/524—Non-oxidic, e.g. borides, carbides, silicides or nitrides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5216—Inorganic
- C04B2235/524—Non-oxidic, e.g. borides, carbides, silicides or nitrides
- C04B2235/5244—Silicon carbide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5216—Inorganic
- C04B2235/524—Non-oxidic, e.g. borides, carbides, silicides or nitrides
- C04B2235/5248—Carbon, e.g. graphite
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
本发明公开了一种连续无机纤维增强陶瓷的制备方法。通过本发明所公开的方法,利用3D打印机的打印头由内外重叠双头复合的优势,膏状粘土材料和纤维同时出料,粘土材料将纤维包覆然后挤出,打印成型得到了一种具有高强度和高韧性的陶瓷材料。本发明既扩展了陶瓷材料的应用范围,也促进了3D打印技术在陶瓷材料成型中的应用。
Description
本申请是申请号为2015109814334,申请日为2015年12月24日,发明创造名称为“一种连续无机纤维增强陶瓷及其3D打印成型方法”的专利的分案申请。
技术领域
本发明涉及一种陶瓷材料的3D打印成型方法,具体涉及一种连续无机纤维增强陶瓷及其3D打印成型方法。
背景技术
3D打印技术又称增材制造技术,是快速成型领域的一种新兴技术,它是一种以数字模型文件为基础,运用粉末状金属或塑料等可粘合材料,通过逐层打印的方式来构造物体的技术。随着3D打印技术的发展和应用,材料成为限制3D打印技术未来走向的关键因素之一,在某种程度上,材料的发展决定着3D打印能否有更广泛的应用。目前,3D打印材料主要包括工程塑料、光敏树脂、橡胶类材料、金属材料和陶瓷材料等,除此之外,彩色石膏材料、人造骨粉、细胞生物原料、木质材料以及砂糖等食品材料也在3D打印领域得到了应用。
利用3D打印技术来成型制备陶瓷产品具有成型速度快,性能好,精度高,能成型复杂结构产品的优点,被人们所接受并在各个领域得到应用,但陶瓷本身的易脆性并没有得到改善和提高,在粘土中加入长纤维等材料后采用传统的成型方法进行成型,会严重影响其塑性,导致无法成型或成型困难,而常用的3D打印陶瓷材料为经过烧结处理的陶瓷微粒,不再适合加入增韧材料对陶瓷进行增强增韧,也不适合3D打印技术对陶瓷材料的成型工艺,因而,陶瓷材料的易脆性一直未得到很好的解决办法,也严重制约了陶瓷产品在生活中的应用范围。
发明内容
本发明针对目前陶瓷材料易脆的缺点提出了一种连续无机纤维增强陶瓷及其3D打印成型方法,利用3D打印粘土材料与连续纤维的复合,制备得到一种具有高强度和高韧性的陶瓷材料,扩展了陶瓷材料的应用范围,也促进了3D打印技术在陶瓷材料成型中的应用。
本发明一种连续无机纤维增强陶瓷,其特征在于是一种含有连续无机纤维材料的陶瓷材料,其原材料包括80-90份的3D打印粘土材料和5-15份的连续无机纤维。
上述一种连续无机纤维增强陶瓷,其中所述的3D打印粘土材料由50-65份的粘土,30-45份的润湿剂,0-30份的骨料和5-10份的增塑剂通过混合得到;所述的无机连续纤维为玄武岩纤维、玻璃纤维、碳纤维、碳化硅纤维、氮化硅纤维、氮化硼纤维中的一种或多种。
上述一种连续无机纤维增强陶瓷,其中所述的粘土为经过高温煅烧去除了有机质的细度为800-2000目的高岭土、蒙脱土中的一种或两种;所述的骨料为细度为500-2000目的水白云母粉末、蒙脱石粉末、石英粉末和长石粉末中的一种或多种;所述的润湿剂为水与乙醇按1∶1混溶的乙醇溶液;所述的增塑剂为甘油、植物油中的一种或两种。
上述一种连续无机纤维增强陶瓷,是通过以下3D打印成型方法制备得到的,具体步骤如下:
1、提供3D打印的原料,包括80-90份的3D打印粘土材料和5-15份的连续无机纤维;
2、提供一台连续长纤维粘土3D打印机,将步骤1的3D打印粘土材料放置于3D打印机料槽内,将连续无机纤维放置在料盘上;
3、使用计算机辅助设计软件绘制陶瓷产品的三维立体结构模型;
4、启动3D打印机,将所述陶瓷产品的三维立体结构模型文件导入到步骤2中的3D打印机中,并使3D打印机开始打印,得到陶瓷胚体;
5、设置烧结曲线,将步骤4得到的陶瓷胚体在600-800℃的温度下预烧结16-20h,在1200-1500℃的温度下烧结3-4h,然后进行冷却,制得连续无机纤维增强陶瓷产品。
上述一种连续无机纤维增强陶瓷的3D打印成型方法,其中所述的连续长纤维粘土3D打印机其特点在于其打印头由内外重叠双头复合而成,内为纤维牵引头,外为粘土喷头;打印时,膏状粘土材料和纤维同时出料,粘土材料将纤维包覆然后挤出,进行打印成型。
本发明利用了3D打印粘土材料高塑性的特点,在成3D打印成型过程中添加连续无机纤维材料对陶瓷材料进行增强改性,最后经过烧结得到具有高强度和高韧性的陶瓷材料,解决了陶瓷制品易碎的缺陷,扩大了陶瓷产品的应用范围,该成型方法工艺简单,易于工业化生产,促进了3D打印成型技术在生活中的推广应用,具有广阔的市场前景。
本发明突出的特点和有益效果在于:
1、本发明解决了陶瓷制品易碎的缺陷,制备得到了具有高强度和高韧性的陶瓷材料产品。
2、本发明直接用粘土材料和连续无机纤维材料作为原料,成本低廉,原料易得。
3、本发明成型方法工艺简单,易于工业化生产。
具体实施方式
以下通过具体实施方式对本发明作进一步的详细说明,但不应将此理解为本发明的范围仅限于以下的实例。在不脱离本发明上述方法思想的情况下,根据本领域普通技术知识和惯用手段做出的各种替换或变更,均应包含在本发明的范围内。
实施例1
1、提供3D打印的原料,包括80份的3D打印粘土材料和15份的连续无机纤维;
2、提供一台连续长纤维粘土3D打印机,将步骤1的3D打印粘土材料放置于3D打印机料槽内,将连续无机纤维放置在料盘上;
3、使用计算机辅助设计软件绘制陶瓷产品的三维立体结构模型;
4、启动3D打印机,将所述陶瓷产品的三维立体结构模型文件导入到步骤2中的3D打印机中,并使3D打印机开始打印,得到陶瓷胚体;
5、设置烧结曲线,将步骤4得到的陶瓷胚体在600℃的温度下预烧结16h,在1200℃的温度下烧结3h,然后进行冷却,制得连续无机纤维增强陶瓷产品。
其中步骤1中的3D打印粘土材料由50重量的高岭土、10重量份的水白云母粉末加、30重量份的水与乙醇按1∶1混溶的乙醇溶液、5重量份的甘油混合而成;所述的无机连续纤维为玄武岩纤维。
实施例2
1、提供3D打印的原料,包括90份的3D打印粘土材料和5份的连续无机纤维;
2、提供一台连续长纤维粘土3D打印机,将步骤1的3D打印粘土材料放置于3D打印机料槽内,将连续无机纤维放置在料盘上;
3、使用计算机辅助设计软件绘制陶瓷产品的三维立体结构模型;
4、启动3D打印机,将所述陶瓷产品的三维立体结构模型文件导入到步骤2中的3D打印机中,并使3D打印机开始打印,得到陶瓷胚体;
5、设置烧结曲线,将步骤4得到的陶瓷胚体在800℃的温度下预烧结20h,在1500℃的温度下烧结4h,然后进行冷却,制得连续无机纤维增强陶瓷产品。
其中步骤1中的3D打印粘土材料由65重量的高岭土、20重量份的蒙脱石粉末、45重量份的水与乙醇按1∶1混溶的乙醇溶液、10重量份的菜籽油混合而成;所述的无机连续纤维为玻璃纤维。
实施例3
1、提供3D打印的原料,包括85份的3D打印粘土材料和15份的连续无机纤维;
2、提供一台连续长纤维粘土3D打印机,将步骤1的3D打印粘土材料放置于3D打印机料槽内,将连续无机纤维放置在料盘上;
3、使用计算机辅助设计软件绘制陶瓷产品的三维立体结构模型;
4、启动3D打印机,将所述陶瓷产品的三维立体结构模型文件导入到步骤2中的3D打印机中,并使3D打印机开始打印,得到陶瓷胚体;
5、设置烧结曲线,将步骤4得到的陶瓷胚体在700℃的温度下预烧结18h,在1300℃的温度下烧结4h,然后进行冷却,制得连续无机纤维增强陶瓷产品。
其中步骤1中的3D打印粘土材料由55重量的蒙脱土、10重量份的石英粉末、30重量份的水与乙醇按1∶1混溶的乙醇溶液、8重量份的棉籽油混合而成;所述的无机连续纤维为碳化硅纤维。
实施例4
1、提供3D打印的原料,包括85份的3D打印粘土材料和5份的连续无机纤维;
2、提供一台连续长纤维粘土3D打印机,将步骤1的3D打印粘土材料放置于3D打印机料槽内,将连续无机纤维放置在料盘上;
3、使用计算机辅助设计软件绘制陶瓷产品的三维立体结构模型;
4、启动3D打印机,将所述陶瓷产品的三维立体结构模型文件导入到步骤2中的3D打印机中,并使3D打印机开始打印,得到陶瓷胚体;
5、设置烧结曲线,将步骤4得到的陶瓷胚体在600-800℃的温度下预烧结20h,在1400℃的温度下烧结3.5h,然后进行冷却,制得连续无机纤维增强陶瓷产品。
其中步骤1中的3D打印粘土材料由60重量的蒙脱土、15重量份的长石粉末、35重量份的水与乙醇按1∶1混溶的乙醇溶液、7重量份的蓖麻油混合而成;所述的无机连续纤维为氮化硅纤维。
实施例5
1、提供3D打印的原料,包括80份的3D打印粘土材料和10份的连续无机纤维;
2、提供一台连续长纤维粘土3D打印机,将步骤1的3D打印粘土材料放置于3D打印机料槽内,将连续无机纤维放置在料盘上;
3、使用计算机辅助设计软件绘制陶瓷产品的三维立体结构模型;
4、启动3D打印机,将所述陶瓷产品的三维立体结构模型文件导入到步骤2中的3D打印机中,并使3D打印机开始打印,得到陶瓷胚体;
5、设置烧结曲线,将步骤4得到的陶瓷胚体在800℃的温度下预烧结19h,在1350℃的温度下烧结4h,然后进行冷却,制得连续无机纤维增强陶瓷产品。
其中步骤1中的3D打印粘土材料由50重量的高岭土、30重量份的水蒙脱石粉末、30重量份的水与乙醇按1∶1混溶的乙醇溶液、10重量份的花生油混合而成;所述的无机连续氮化硼纤维。
Claims (2)
1.一种连续无机纤维增强陶瓷的制备方法,其特征在于,包括以下步骤,(1)提供3D打印的原料,包括80-90份的3D打印粘土材料和5-15份的连续无机纤维;
(2)提供一台连续长纤维粘土3D打印机,将步骤(1)的3D打印粘土材料放置于3D打印机料槽内,将连续无机纤维放置在料盘上;
(3)使用计算机辅助设计软件绘制陶瓷产品的三维立体结构模型;
(4)启动3D打印机,将所述陶瓷产品的三维立体结构模型文件导入到步骤(2)中的3D打印机中,并使3D打印机开始打印,得到陶瓷胚体;
(5)设置烧结曲线,将步骤(4)得到的陶瓷胚体在600-800℃的温度下预烧结16-20h,在1200-1500℃的温度下烧结3-4h,然后进行冷却,制得连续无机纤维增强陶瓷产品。
2.如权利要求1所述的连续无机纤维增强陶瓷的制备方法,其特征在于,所述3D打印粘土材料由50-65份的粘土,30-45份的润湿剂,0-30份的骨料和5-10份的增塑剂通过混合得到。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810074600.0A CN108083773B (zh) | 2015-12-24 | 2015-12-24 | 一种连续无机纤维增强陶瓷的制备方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810074600.0A CN108083773B (zh) | 2015-12-24 | 2015-12-24 | 一种连续无机纤维增强陶瓷的制备方法 |
CN201510981433.4A CN105541298B (zh) | 2015-12-24 | 2015-12-24 | 一种连续无机纤维增强陶瓷及其3d打印成型方法 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510981433.4A Division CN105541298B (zh) | 2015-12-24 | 2015-12-24 | 一种连续无机纤维增强陶瓷及其3d打印成型方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN108083773A true CN108083773A (zh) | 2018-05-29 |
CN108083773B CN108083773B (zh) | 2021-06-25 |
Family
ID=55820924
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510981433.4A Active CN105541298B (zh) | 2015-12-24 | 2015-12-24 | 一种连续无机纤维增强陶瓷及其3d打印成型方法 |
CN201810074600.0A Active CN108083773B (zh) | 2015-12-24 | 2015-12-24 | 一种连续无机纤维增强陶瓷的制备方法 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510981433.4A Active CN105541298B (zh) | 2015-12-24 | 2015-12-24 | 一种连续无机纤维增强陶瓷及其3d打印成型方法 |
Country Status (1)
Country | Link |
---|---|
CN (2) | CN105541298B (zh) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106242507B (zh) * | 2016-08-27 | 2022-05-17 | 景德镇陶瓷大学 | 一种直接成型3d陶瓷打印用粘土泥料及其制备方法和应用 |
CN106631081A (zh) * | 2016-11-28 | 2017-05-10 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | 3d打印氮化镁陶瓷材料及其制备方法 |
CN106630960A (zh) * | 2016-11-28 | 2017-05-10 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | 3d打印氮化钽陶瓷材料及其制备方法 |
CN106699110A (zh) * | 2016-11-28 | 2017-05-24 | 安徽省春谷3D打印智能装备产业技术研究院有限公司 | 3d打印氮化硼陶瓷材料及其制备方法 |
CN106747333A (zh) * | 2016-12-21 | 2017-05-31 | 周易 | 一种高韧性陶瓷材料及其制备方法 |
CN107056246A (zh) * | 2016-12-21 | 2017-08-18 | 周易 | 一种耐高温陶瓷材料及其制备方法 |
CN106866164B (zh) * | 2017-02-27 | 2020-03-17 | 西安交通大学 | 一种基于纤维增强陶瓷先驱体3d打印技术的陶瓷复合材料成形方法 |
CN106966693A (zh) * | 2017-03-16 | 2017-07-21 | 张丹丹 | 一种用于生产超薄低脆性管件的3d打印材料 |
CN108069706A (zh) * | 2017-12-15 | 2018-05-25 | 天津大学 | 一种基于3d打印技术的纤维增强陶瓷薄壁件的成型方法 |
CN108115810B (zh) * | 2017-12-30 | 2019-08-02 | 许昌学院 | 一种陶瓷玻璃复合结构3d打印成形装置及方法 |
CN109293382A (zh) * | 2018-09-18 | 2019-02-01 | 西安交通大学 | 一种基于3d打印技术的核壳结构陶瓷复合材料成形方法 |
CN109482886B (zh) * | 2019-01-07 | 2021-02-26 | 吉林大学 | 一种3d打印陶瓷与纤维复合增强铝基材料的制备方法 |
CN112174575A (zh) * | 2020-09-27 | 2021-01-05 | 嘉兴饶稷科技有限公司 | 一种光固化黏土打印材料及其制备方法 |
CN112759314B (zh) * | 2021-04-07 | 2021-06-25 | 西南交通大学 | 一种玄武岩纤维复合筋混凝土智能3d打印装置 |
CN114163250A (zh) * | 2021-11-26 | 2022-03-11 | 南京航空航天大学 | 3d打印连续碳纤维增韧碳化硅陶瓷制备方法及装置 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103817767A (zh) * | 2014-03-14 | 2014-05-28 | 邓湘凌 | 应用3d打印技术的陶瓷产品制作方法 |
US20140339745A1 (en) * | 2013-05-17 | 2014-11-20 | Stuart URAM | Molds for ceramic casting |
CN104193345A (zh) * | 2014-08-20 | 2014-12-10 | 中南大学 | 基于3d打印技术制备吸波陶瓷部件的方法 |
CN105174907A (zh) * | 2015-06-30 | 2015-12-23 | 成都新柯力化工科技有限公司 | 一种3d打印用粘土材料及其制备方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2504164A4 (en) * | 2009-11-23 | 2013-07-17 | Applied Nanostructured Sols | CERAMIC COMPOSITE MATERIALS CONTAINING FIBER MATERIALS IMPREGNATED WITH CARBON NANOTUBES AND METHODS OF MAKING SAME |
CN103992088B (zh) * | 2014-05-23 | 2015-11-18 | 广东轻工职业技术学院 | 一种用于三维打印的快速成型粉末材料及其制备方法与应用 |
CN104446392A (zh) * | 2014-12-01 | 2015-03-25 | 青岛麦特瑞欧新材料技术有限公司 | 一种用于3d打印的掺钙无机纳米复合材料及其制备方法 |
CN104385606B (zh) * | 2014-12-14 | 2018-03-09 | 机械科学研究总院先进制造技术研究中心 | 一种复合材料零部件3d打印成形方法 |
-
2015
- 2015-12-24 CN CN201510981433.4A patent/CN105541298B/zh active Active
- 2015-12-24 CN CN201810074600.0A patent/CN108083773B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20140339745A1 (en) * | 2013-05-17 | 2014-11-20 | Stuart URAM | Molds for ceramic casting |
CN103817767A (zh) * | 2014-03-14 | 2014-05-28 | 邓湘凌 | 应用3d打印技术的陶瓷产品制作方法 |
CN104193345A (zh) * | 2014-08-20 | 2014-12-10 | 中南大学 | 基于3d打印技术制备吸波陶瓷部件的方法 |
CN105174907A (zh) * | 2015-06-30 | 2015-12-23 | 成都新柯力化工科技有限公司 | 一种3d打印用粘土材料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN105541298A (zh) | 2016-05-04 |
CN105541298B (zh) | 2018-06-19 |
CN108083773B (zh) | 2021-06-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105541298B (zh) | 一种连续无机纤维增强陶瓷及其3d打印成型方法 | |
CN105563610B (zh) | 一种用3d打印技术制备金属陶瓷的方法 | |
CN105503147B (zh) | 一种用于3d打印的粘土材料及其制备方法 | |
CN105619572B (zh) | 一种陶瓷材料的3d打印成型方法 | |
CN108083777A (zh) | 一种光固化3d打印用铝基陶瓷料浆及陶瓷型芯的制备方法 | |
CN106621846A (zh) | 一种中空平板全陶瓷过滤膜元件及其制备工艺方法 | |
CN105645923B (zh) | 一种用于3d打印的丝状粘土材料及其制备方法 | |
CN102976721A (zh) | 一种低温烧成的陶瓷釉面砖及其制备方法 | |
WO2006017676A3 (en) | Method for fabricating ceramic articles and ceramic articles produced thereby | |
CN111233443A (zh) | 一种高固相含量3d打印陶瓷型芯浆料及制备方法 | |
CN103232719B (zh) | 一种烟花筒体材料及其制备方法 | |
CN102515812A (zh) | 碳碳化硅坩埚及其制作工艺 | |
CN110216930A (zh) | 一种高强度可陶瓷化树脂复合材料及其制备方法 | |
CN107698270A (zh) | 原位合成非晶态SiOC纳米线增强陶瓷型芯的方法 | |
CN106945149A (zh) | 一种陶瓷坯体3d打印工艺 | |
CN106587780A (zh) | 用于3d打印的铝硅酸盐聚合物复合材料的制备及打印方法 | |
CN107721435B (zh) | 用废旧陶瓷料制作的陶瓷制品及其制作方法 | |
CN1093072A (zh) | 刚玉陶瓷材料及其制法和用途 | |
CN110216926A (zh) | 一种可陶瓷化硅基树脂复合材料及其制备方法 | |
CN113548882B (zh) | 一种堇青石陶瓷器件及其制备方法与应用 | |
CN107500779A (zh) | 一种多孔硅基结构陶瓷及其制备方法 | |
CN101844906B (zh) | 一种利用煅烧提高活性制备淤积泥沙成高强度建筑材料的方法 | |
CN101560074B (zh) | 利用锆硅渣生产的减水剂及其生产方法 | |
CN106581938A (zh) | 一种室外太空漫步机 | |
CN202529995U (zh) | 一种具有镀金属花纹釉面陶瓷制品及其模具 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20211209 Address after: 437000 Ceramic Industrial Park, Tongcheng Economic Development Zone, Xianning City, Hubei Province Patentee after: HUBEI ASIA CERAMICS CO.,LTD. Patentee after: Asia Building Materials Co., Ltd Address before: 362400 Cross Town Village, Chengxiang Town, Anxi, Quanzhou, Fujian Patentee before: TIANJIN FUNAYUANCHUANG TECHNOLOGY CO.,LTD. |
|
TR01 | Transfer of patent right |