CN108017154A - A kind of preparation and its application of the compounded mix biological floating bed applied to combined type triple effect - Google Patents
A kind of preparation and its application of the compounded mix biological floating bed applied to combined type triple effect Download PDFInfo
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- CN108017154A CN108017154A CN201711140463.8A CN201711140463A CN108017154A CN 108017154 A CN108017154 A CN 108017154A CN 201711140463 A CN201711140463 A CN 201711140463A CN 108017154 A CN108017154 A CN 108017154A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/32—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/105—Phosphorus compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/308—Dyes; Colorants; Fluorescent agents
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Abstract
The invention discloses a kind of preparation method and applications of the filler biological floating bed applied to combined type triple effect, to improve the purification of water quality ability of existing biological floating bed matrix and nutrient supply performance.The filler is combined by hard solid filler A and polyurethane sponge soft-filler B.Preparation process includes dispensing, mixing granulation, drying, curing, cooling, composite foamed.Raw materials used cheap, production method is simple, and the filler of gained has the advantages that specific surface area is big, porosity is high, microorganism colonization performance is good, denitrogenation dephosphorizing ability is strong.By applying filler in combined type triple effect is biological floating bed, removal ability of the ecological floating bed device to Water phosphorus nutrition element can be drastically increased, and filler has nitrogen phosphorus sustained release performance, the nutrient supply environment of stabilization can be provided for plant growth, it is highly suitable for the purified in situ processing of eutrophication water, the especially purification of agricultural non -point pollution water body.
Description
Technical field
The invention belongs to water treatment field, and in particular to a kind of compounded mix biological floating bed applied to combined type triple effect
Preparation method and applications.
Background technology
Biological floating bed is a kind of water body in-situ recovery technique risen in recent years.At present, the technology is in lake eutrophication water
It is widely used in the purification of body and fishery cultivating waste water.The technology has without taking up an area, cheap, easy for installation, reparation
The characteristics of effect is good, operational management is simple.
By years of researches and practice, researcher has found traditional following deficiency of biological floating bed presence：(1) root system of plant
It is suspended in water body and is easily swallowed by herbivorous animal；(2) biomembrane of floating bed plant root system apposition growth is limited；(3) floating bed pair
Plant root fixed effect is bad, and plant easily floats, so as to cause floating bed clean-up effect not good enough.In recent years, researchers send out again
Now artificial swamp is combined with biological floating bed technology, biological floating bed middle using with bio-carrier and matrix suction-operated
Bifunctional material, can the more powerful wetland type of constructing function it is combined biological floating bed.Since this novel ecological floating bed is integrated with
Plant absorption, filtrate absorption and bio-film colonization triple function are in one, therefore also known as combined type triple effect is biological floating bed.It is Chinese special
Profit 2012101630837 discloses a kind of complex ecological floating bed for providing habitat and uses at least one of zeolite and biological ceramic particle
As filler matrix, Chinese patent 2014106492847 discloses a kind of combined biological floating bed equipped with floating ball, its filling base
Matter is mixed by magnesium slag ceramic filtration ball, bentonite clay particle and zeolite and formed.Combined biological floating bed filling substrate is mainly at present
Used after one-component filler, or a variety of single filler simple physical mixing as mixed fillers.
In recent years, chemical fertilizer is excessively used in planting industry production process, causes to have accumulated a large amount of nitrogen P elements in soil.
Under the driving of rainfall and irrigation, these phosphorus and nitrogens enter water by agricultural surface runoff, agricultural drain and underground percolation
Body, causes body eutrophication.The loss of farmland nitrogen phosphorus be cause China's water environment degradation and lake eutrophication it is important because
Element.It is biological floating bed as a kind of cost is low, water body purification technology in situ of easy care have in Control of Agricultural Non-point Source Pollution it is wide
Wealthy application prospect.But due to being influenced be subject to factors such as rainfall intensity, dose, fertilization time, fertilizer types, farmland face source
The pollution amount of having the characteristics that is big, concentration is low, fluctuation of concentration is big, and existing biological floating bed technology is difficult to ensure that purification of water quality is imitated at the same time
Fruit and water plant normal growth.
The content of the invention
It is above-mentioned in order to solve the problems, such as, it is an object of the invention to overcome the defects of conventional biological floating bed, propose one
The preparation method of kind multiple elements design filler and its application process in purifying the water body by planting industry pollution of area source and handling.This hair
Bright filler production method step is simple, material is easy to get, and the filler being prepared into can effectively improve biological floating bed purification of water quality energy
Power, and ensure the good growth of biological floating bed crop.
It is an object of the invention to provide a kind of compounded mix biological floating bed applied to combined type triple effect.
Another object of the present invention is to provide a kind of method for preparing above-mentioned compounded mix.
It is still another object of the present invention to provide above-mentioned compounded mix application.
The technical solution used in the present invention is：
A kind of compounded mix biological floating bed applied to combined type triple effect, the compounded mix is by hard solid filler A and gathers
Urethane sponge soft-filler B is 1.5~10 in mass ratio：1 is made；
The component of the hard solid filler A and the percentage by weight of each component are respectively：Charcoal 30~45%, zeolite
20~40%, iron oxide 10~20%, bentonite 10~25%, the sum of binding agent 4~10%, the percentage of above material are
100%；
The component of the polyurethane sponge soft-filler B and the percentage by weight of each component are respectively：Polyether polyol 50
~80%, isocyanates 16~40%, foaming agent 2.5~10%, silicone oil 0.5~1.3%, tin catalyst 0.1~0.4%, amine
The sum of catalyst 0.04~0.3%, the percentage of above material is 100%.
Further, the binding agent is selected from starch, lignin, polyvinyl alcohol, phenolic resin, polyethylene glycol oxide, carboxylic first
At least one of base cellulose and its derivates.
Further, the polyether polyol is selected from polyether polyol 330, polyether polyol DEP-330N, polyether polyols
Alcohol DEP-505S, polyether polyol POP36/28, poly- tetrahydrochysene are barked at least one of ether glycol of muttering.
Further, the isocyanates is selected from toluene di-isocyanate(TDI), methyl diphenylene diisocyanate (MDI), 4,
In 4 '-dicyclohexyl methyl hydride diisocyanate, isophorone diisocyanate, 1,6- hexa-methylene diamino-methyl formates extremely
Few one kind.
Further, the foaming agent is selected from least one of water, dichloromethane solution.
The preparation method of any of the above-described compounded mix, comprises the following steps：
1) dispensing：The charcoal for being crushed to suitable size, zeolite, iron oxide, bentonite are configured as described.
Binding agent is fully dissolved with suitable quantity of water, is configured to the binder solution of 3~7wt.%；
2) mixing granulation：Charcoal, zeolite, iron oxide, bentonite stir evenly, and mix while to spray into binding agent molten
Liquid, is made water content up to 40~65%, particle diameter is the spheric granules of 1.0~5.0mm；
3) it is dry：Spheric granules is put into baking oven in 45~80 DEG C of dry 3~8h；
4) cure：Dry bead is put into 110~180 DEG C of high temperature oven progress hot settings, hardening time for 0.5~
3h；
5) cool down：By the spherical hard solid filler A cooled to room temperatures obtained by step 4)；
6) it is composite foamed：By in the spherical hard solid filler A obtained by step 5), polyether polyol, foaming agent, silicon are added
Oil meter face activating agent, tin catalyst and amine catalyst, after stirring evenly, add isocyanates, continue 0.1~1.0min of stirring,
Then stand foaming is molded；
The dosage of above-mentioned all raw materials is as described in any of the above-described.
Application of the compounded mix described in any of the above-described in planting aquatic plants.
Application of the compounded mix described in any of the above-described in water body in planting plants.
Further, the plant is water plant.
A kind of method of the planting plants in water body, the compounded mix weighed described in any of the above-described is positioned over biological floating bed
Plant in basket, by plant cultivating in the compounded mix.
The beneficial effects of the invention are as follows：
(1) the biological floating bed multiple elements design filler material of combined type triple effect that is applied to of the invention is easy to get, preparation method letter
It is single, it is low without high-temperature firing, production cost.The filler being prepared is environment friendly and pollution-free, stable in physicochemical property.
(2) compounded mix organic matter of the present invention, nitrogen, phosphorus absorption property are strong, effectively suppress the growth of Measures of Algae in Water Body.At the same time
The matrix also has nitrogen phosphorus slow-release capability, and when can not meet plant growth when nitrogen phosphorus is low when pollutant load, it can delay
The nutriment such as On The Drug Release nitrogen and phosphorus, to meet the growth demand of plant.
(3) hole of compounded mix of the present invention enriches, and bioaffinity is good, can be effectively increased microorganism colonization amount and improve
Biofilm efficiency.The powerful adsorption capacity of compounded mix provides good nutrient environment for the microorganism adhered to thereon, promotes micro- life
Thing is grown, and further improves biological floating bed purification of water quality ability.
(4) preparation process of the present invention can realize that the spherical uniform original positions of hard solid filler A are doped in that urethane sponge is soft to fill out
In the skeleton structure for expecting B, you can solution exclusive use urethane sponge soft-filler B density is low, the problem of easily bubbling through the water column, and can
Avoid Ball-type packing A in current mutually collision and caused by abrasion.
(5) initial stage of plant growth, filler of the present invention can protect the newborn micro- root system of plant well, improve surviving for plant
Rate.Vegetation period is not easy to lodge.
Embodiment
The operation principle of the present invention
Compounded mix of the present invention has selective absorption and the performance slowly desorbed to Organic substance in water, ammonia nitrogen and phosphorus, can
The organic carbon source and nitrogen phosphorus nutrient supply environment of stabilization are provided for the plant of the biological floating bed middle cultivation of combined type triple effect, avoids farmland
Discharge influence of the variation water quality of water to floating bed plant normal growth；Compounded mix of the present invention has good caking property and plastic
Property, improves the compression strength of particle.Compounded mix of the present invention has three-dimensional network loose structure and surface hydrophilicity, suitable micro- life
Thing is inhabited, multiplied, and can be shortened microbial film and be formed the time, is conducive to improve microorganism sewage water treatment effeciency.Polyurethane sea at the same time
The skeleton structure of soft filler B can realize that spherical hard solid filler A's is dispersed, and can avoid Ball-type packing in current
In mutually collide and cause to wear.Cultivation matrix using adsorption stuffing as aquatic crops, is absorbed using aquatic crops root system and cut
The nutrient in adsorbing base filler is stayed, and the service life of adsorption stuffing can be extended.
A kind of compounded mix biological floating bed applied to combined type triple effect, the compounded mix is by hard solid filler A and gathers
Urethane sponge soft-filler B is 1.5~10 in mass ratio：1 is made；
The component of the hard solid filler A and the percentage by weight of each component are respectively：Charcoal 30~45%, zeolite
20~40%, iron oxide 10~20%, bentonite 10~25%, the sum of binding agent 4~10%, the percentage of above material are
100%；
The component of the polyurethane sponge soft-filler B and the percentage by weight of each component are respectively：Polyether polyol 50
~80%, isocyanates 16~40%, foaming agent 2.5~10%, silicone oil 0.5~1.3%, tin catalyst 0.1~0.4%, amine
The sum of catalyst 0.04~0.3%, the percentage of above material is 100%.
Preferably, the charcoal in the hard solid filler A preparing raw materials, zeolite, iron oxide, the grain of bentonite powder
Footpath is less than 60 mesh.
Preferably, the binding agent is selected from starch, lignin, polyvinyl alcohol, phenolic resin, polyethylene glycol oxide, carboxymethyl
At least one of cellulose and its derivates.
Preferably, the polyether polyol is selected from polyether polyol 330, polyether polyol DEP-330N, polyether polyol
DEP-505S, polyether polyol POP36/28, poly- tetrahydrochysene are barked at least one of ether glycol of muttering.
Preferably, the isocyanates be selected from toluene di-isocyanate(TDI) (TDI), methyl diphenylene diisocyanate (MDI),
4, in 4 '-dicyclohexyl methyl hydride diisocyanate, isophorone diisocyanate, 1,6- hexa-methylene diamino-methyl formates
It is at least one.
Preferably, the foaming agent is selected from least one of water, dichloromethane solution.
Preferably, the tin catalyst is at least one of stannous octoate, dibutyl tin laurate.
Preferably, the amine catalyst is triethylene diamine (A33), triethanolamine, triethylamine, dimethyl cyclohexyl amine, three
At least one of ethylene diamine, N, N- dimethyl cyclohexyl amines.
The preparation method of any of the above-described compounded mix, comprises the following steps：
1) dispensing：The charcoal for being crushed to suitable size, zeolite, iron oxide, bentonite are configured as described.
Binding agent is fully dissolved with suitable quantity of water, is configured to the binder solution of 3~7wt.%；
2) mixing granulation：Charcoal, zeolite, iron oxide, bentonite stir evenly, and mix while to spray into binding agent molten
Liquid, is made water content up to 40~65%, particle diameter is the spheric granules of 1.0~5.0mm；
3) it is dry：Spheric granules is put into baking oven in 45~80 DEG C of dry 3~8h；
4) cure：Dry bead is put into 110~180 DEG C of high temperature oven progress hot settings, hardening time for 0.5~
3h；
5) cool down：By the spherical hard solid filler A cooled to room temperatures obtained by step 4)；
6) it is composite foamed：By in the spherical hard solid filler A obtained by step 5), polyether polyol, foaming agent, silicon are added
Oil meter face activating agent, tin catalyst and amine catalyst, after stirring evenly, add isocyanates, continue 0.1~1.0min of stirring,
Then stand foaming is molded；
The dosage of above-mentioned all raw materials is as described in any of the above-described.
Preferably, in step 5), the rotating speed of the stirring is 800~2000rpm.
Application of the compounded mix described in any of the above-described in planting aquatic plants.
Application of the compounded mix described in any of the above-described in water body in planting plants.
Preferably, the plant is water plant.
A kind of method of the planting plants in water body, biological floating bed kind is positioned over by the compounded mix described in any of the above-described
Plant in basket, by plant cultivating in the compounded mix.
With reference to specific embodiment, the present invention is further illustrated.
A kind of preparation method of the biological floating bed filler of combined type triple effect of embodiment 1.
(1) 2.0kg charcoals, 1.5kg zeolites, 1.0kg iron oxide, 0.5kg bentonites are weighed respectively, are crushed and are crossed 60 mesh
Sieve, it is then that 4 kinds of material physical mixeds are uniform；
(2) 0.25kg sodium carboxymethylcelluloses 50 DEG C of water of 5.0L are dissolved, is configured to binder solution；
(3) step (1) resulting material is put into granulating disc, while rotating, while spraying into step (2) prepares gained
Binder solution, obtains the Ball-type packing that diameter is about 1.0~2.0mm；
(4) Ball-type packing obtained by step (3) is put into baking oven at 60 DEG C and dries 6.0h.
(5) filler after drying is put into 140 DEG C of high temperature oven processing 2.0h, afterwards cooled to room temperature.
(6) prepared by step (5) the spherical hard solid filler A of gained to be put into agitator tank, then adds 1.28kg polyethers
Polyalcohol 330, foaming agent (including 55g water and 60g dichloromethane), 15g silicone oil, 3.3g stannous octoates, 1.5g A33.Above-mentioned thing
After expecting that high-speed stirred is uniform under 1000 revs/min of speed, 330g toluene di-isocyanate(TDI)s (TDI) are added, continue high-speed stirring
Mix 10s.Then stand foaming is molded, and cuts into the filling block of 2.0 × 2.0 × 2.0cm or so.
The biological floating bed filler of combined type triple effect prepared below to embodiment 1 makees further effect detection：Prepare gained
The bulk density of spherical hard solid filler A is 1217kg/m3, compression strength 4.87MPa, wear rate 0.08%, compares table
Area is 366m2/g.Staticadsorption experiment shows, the filler to water Methylene Blue, ammonium nitrogen, dihydrogen phosphate adsorbance
Respectively 67.9mg/g, 1.57mg/g, 0.054mg/g, respectively wait quality commodities haydite 162 times, 368 times and 9.5 times.
Filler is respectively 41% and 34% to the resolution factor of ammonia nitrogen and phosphorus in deionized water.Hard solid filler A and polyurethane sponge are soft
After property filler B is compound, the bulk density of compounded mix is 964kg/m3.It is heavy using sewage treatment plants aerobic section sewage and two
Pond returned sludge carries out biofilm experiment to compounded mix, and during by 2d, bacterial plaque occurs in filler surface, and extension is basically completed when running 9d
Film.Biofilm Colonization amount about 82.6mg/g on final every gram of compounded mix, is the final biofilm amount of spherical hard solid filler A
9.6 again.Embodiment 1, which prepares gained filler, has preferable organic matter, nitrogen, phosphorus absorption property, and nitrogen, phosphorus nutrient desorption performance,
There is preferable biomembrane adhesion property at the same time.
A kind of application of the biological floating bed filler of combined type triple effect of embodiment 2.
By embodiment 1 prepare gained compounded mix is fitted into biological floating bed filler frame, in filler cuttage enter highly about
15cm, has a water spinach plant of 2~4 branches, 5 plants of water spinaches of cuttage in each floating bed filler basket.By biological floating bed placement
Discharged in farmland water in irrigation canals and ditches, and make the biological floating bed coverage rate in processing section up to 30%.Experiment last 30 days, on-test and
At the end of microbial biomass in water quality, water spinach biomass, filler is detected.Testing result shows：Use embodiment 1
Prepare gained compounded mix and plant the biological floating bed processing of water spinach, the ammonia nitrogen concentration of water body is down to from 61.2mg/L
10.5mg/L, purifying rate is up to 82.8%；TN concentration is reduced to 35.8mg/L from 125.7mg/L, and purifying rate is up to 71.5%；TP is dense
Degree drops to 0.02mg/L from 1.05mg/L, and purifying rate is up to 98.1%；Water spinach biomass averagely increases in each floating bed unit
103g.Experiment there is provided space management and uses ceramics filling and the equally biological floating bed processing of plantation water spinach at the same time.With reference to
The situation of change of water body TN, TP, calculate and understand, compared with ordinary ceramsite is biological floating bed, make before and after being tested in blank control processing
With present example 1 prepare gained filler the biological floating bed detergent power to ammonia nitrogen, TN and TP can be respectively increased 12.8%,
9.4% and 19.7%, water spinach biomass improves 9.1% in each floating bed unit.Example 1 prepares gained filler after the test
Upper microorganism wt is 12.6 times of general goods haydite.Therefore, removal effect of the filler of the present invention to Water phosphorus
And the performance of aquatic plants growth is promoted to be superior to general goods haydite.
A kind of preparation method of the biological floating bed filler of combined type triple effect of embodiment 3.
(1) 3.5kg charcoals, 3.5kg zeolites, 1.5kg iron oxide, 1.5kg bentonites are weighed respectively, are crushed and are crossed 60 mesh
Sieve, it is then that 4 kinds of material physical mixeds are uniform；
(2) 0.75kg polyvinyl alcohol is configured to binder solution with after 90 DEG C of water dissolvings of 11.0L；
(3) step (1) resulting material is put into granulating disc, while rotating, while spraying into step (2) prepares gained
Binder solution, obtains the Ball-type packing that diameter is about 1.0~2.0mm
(4) Ball-type packing obtained by step (3) is put into baking oven at 70 DEG C and dries 5.0h.
(5) filler after drying is put into 170 DEG C of high temperature oven processing 1.0h, afterwards cooled to room temperature.
(6) prepared by step (5) the spherical hard solid filler A of gained to be put into agitator tank, then adds 1.48kg polyethers
Polyalcohol 330, foaming agent (including 70g water and 135g dichloromethane), 19.2g silicone oil, 4.4g stannous octoates, 1.8g triethylenes two
Amine (A33).Above-mentioned material adds 435g toluene di-isocyanate(TDI)s after high-speed stirred is uniform under 1000 revs/min of speed
(TDI), high-speed stirred 15s is continued.Then stand foaming is molded, and cuts into the filling block of 2.5 × 2.5 × 2.5cm or so.
The biological floating bed filler of combined type triple effect prepared below to embodiment 1 makees further effect detection：Prepare gained
The bulk density of spherical hard solid filler A is 1105kg/m3, compression strength 5.14MPa, wear rate 0.07%, compares table
Area is 297m2/g.Staticadsorption experiment shows, the filler to water Methylene Blue, ammonium nitrogen, dihydrogen phosphate adsorbance
Respectively 55.7mg/g, 1.86mg/g, 0.048mg/g, respectively wait quality commodities haydite 133 times, 436 times and 8.4 times.
Filler is respectively 45% and 28% to the resolution factor of ammonia nitrogen and phosphorus in deionized water.Hard solid filler A and polyurethane sponge are soft
After property filler B is compound, the bulk density of compounded mix is 989kg/m3.It is heavy using sewage treatment plants aerobic section sewage and two
Pond returned sludge carries out biofilm experiment to compounded mix, and during by 2d, bacterial plaque occurs in filler surface, is basically completed when running 10d
Biofilm.Biofilm Colonization amount about 76.1mg/g on final every gram of compounded mix, is the final biofilm amount of spherical hard solid filler A
8.8 times.Embodiment 3, which prepares gained compounded mix, has preferable organic matter, nitrogen, phosphorus absorption property, and nitrogen, phosphorus nutrient desorption
Performance, while there is preferable biomembrane adhesion property.
A kind of application of the biological floating bed filler of combined type triple effect of embodiment 4.
By embodiment 3 prepare gained compounded mix is fitted into it is biological floating bed in filler frame, in filler cuttage enter highly about
10cm, has a Chinese celery seedling of 2~3 branches, 6 plants of Chinese celeries of cuttage in each floating bed filler basket.Farmland is positioned over by biological floating bed
In water discharge irrigation canals and ditches, and make the biological floating bed coverage rate in processing section up to 35%.Experiment lasts 30 days, and on-test is with the end of
Microbial biomass in water quality, Chinese celery biomass, filler is detected.Testing result shows：Gained is prepared using embodiment 3
Compounded mix and the biological floating bed processing for planting Chinese celery, the ammonia nitrogen concentration of water body are down to 8.7mg/L from 49.8mg/L, and purifying rate reaches
82.5%, TN concentration are reduced to 27.3mg/L from 100.5mg/L, and purifying rate is up to 72.8%；TP concentration is dropped to from 1.05mg/L
0.08mg/L, purifying rate is up to 92.3%；Chinese celery biomass averagely increases 127.4g in each floating bed unit.Experiment is provided with the same time
Space management and use ceramics filling and the biological floating bed processing for equally planting Chinese celery.Before and after being tested in being handled with reference to blank control
The situation of change of water body TN, TP, calculate and understand, compared with ordinary ceramsite is biological floating bed, prepares gained using present example 3 and fill out
The biological floating bed detergent power to ammonia nitrogen, TN and TP of material can be respectively increased 11.5%, 8.7% and 16.2%, each floating bed list
Chinese celery biomass improves 10.2% in member.
A kind of preparation method of the biological floating bed filler of combined type triple effect of embodiment 5.
(1) 3.5kg charcoals, 3.5kg zeolites, 1.5kg iron oxide, 1.5kg bentonites are weighed respectively, are crushed and are crossed 60 mesh
Sieve, it is then that 4 kinds of material physical mixeds are uniform；
(2) 0.75kg phenolic resin is configured to binder solution with after 90 DEG C of water dissolvings of 11.0L；
(3) step (1) resulting material is put into granulating disc, while rotating, while spraying into step (2) prepares gained
Binder solution, obtains the Ball-type packing that diameter is about 1.0~2.0mm
(4) Ball-type packing obtained by step (3) is put into baking oven at 70 DEG C and dries 5.0h.
(5) filler after drying is put into 170 DEG C of high temperature oven processing 1.0h, afterwards cooled to room temperature.
(6) prepared by step (5) the spherical hard solid filler A of gained to be put into agitator tank, then adds 1.48kg poly- four
Hydrogen is barked ether glycol of muttering, foaming agent (including 70g water and 135g dichloromethane), 19.2g silicone oil, 4.4g stannous octoates, tri- second of 1.8g
Hydramine.Above-mentioned material adds 435g methyl diphenylene diisocyanates after high-speed stirred is uniform under 1000 revs/min of speed
(MDI), high-speed stirred 15s is continued.Then stand foaming is molded, and cuts into the filling block of 2.5 × 2.5 × 2.5cm or so.
A kind of preparation method of the biological floating bed filler of combined type triple effect of embodiment 6.
(1) 3.5kg charcoals, 3.5kg zeolites, 1.5kg iron oxide, 1.5kg bentonites are weighed respectively, are crushed and are crossed 60 mesh
Sieve, it is then that 4 kinds of material physical mixeds are uniform；
(2) 0.75kg polyethylene glycol oxides are configured to binder solution with after 90 DEG C of water dissolvings of 11.0L；
(3) step (1) resulting material is put into granulating disc, while rotating, while spraying into step (2) prepares gained
Binder solution, obtains the Ball-type packing that diameter is about 1.0~2.0mm
(4) Ball-type packing obtained by step (3) is put into baking oven at 70 DEG C and dries 5.0h.
(5) filler after drying is put into 170 DEG C of high temperature oven processing 1.0h, afterwards cooled to room temperature.
(6) prepared by step (5) the spherical hard solid filler A of gained to be put into agitator tank, then adds 1.48kg polyethers
Polyalcohol POP36/28, foaming agent (200g water), 19.2g silicone oil, 4.4g stannous octoates, 1.8g triethylenediamines.Above-mentioned thing
After expecting that high-speed stirred is uniform under 1000 revs/min of speed, addition 435g 4,4 '-dicyclohexyl methyl hydride diisocyanate, after
Continuous high-speed stirred 15s.Then stand foaming is molded, and cuts into the filling block of 2.5 × 2.5 × 2.5cm or so.
A kind of preparation method of the biological floating bed filler of combined type triple effect of embodiment 7.
(1) 3.5kg charcoals, 3.5kg zeolites, 1.5kg iron oxide, 1.5kg bentonites are weighed respectively, are crushed and are crossed 60 mesh
Sieve, it is then that 4 kinds of material physical mixeds are uniform；
(2) 0.75kg lignin is configured to binder solution with after 90 DEG C of water dissolvings of 11.0L；
(3) step (1) resulting material is put into granulating disc, while rotating, while spraying into step (2) prepares gained
Binder solution, obtains the Ball-type packing that diameter is about 1.0~2.0mm
(4) Ball-type packing obtained by step (3) is put into baking oven at 70 DEG C and dries 5.0h.
(5) filler after drying is put into 170 DEG C of high temperature oven processing 1.0h, afterwards cooled to room temperature.
(6) prepared by step (5) the spherical hard solid filler A of gained to be put into agitator tank, then adds 1.48kg polyethers
Polyalcohol DEP-505S, foaming agent (including 70g water and 135g dichloromethane), 19.2g silicone oil, 4.4g di lauric dibutyls
Tin, 1.8g N, N- dimethyl cyclohexyl amines.Above-mentioned material adds 435g after high-speed stirred is uniform under 1000 revs/min of speed
1,6- hexa-methylene diamino-methyl formate, continues high-speed stirred 15s.Then stand foaming is molded, and cuts into 2.5 × 2.5
The filling block of × 2.5cm or so.
Above-described embodiment is the preferable embodiment of the present invention, but embodiments of the present invention and from above-described embodiment
Limitation, other any Spirit Essences without departing from the present invention with made under principle change, modification, replacement, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (10)
1. a kind of compounded mix biological floating bed applied to combined type triple effect, it is characterised in that the compounded mix is by hard solid
Filler A and polyurethane sponge soft-filler B is 1.5~10 in mass ratio：1 is made；
The component of the hard solid filler A and the percentage by weight of each component are respectively：Charcoal 30~45%, zeolite 20~
40%th, iron oxide 10~20%, bentonite 10~25%, the sum of binding agent 4~10%, the percentage of above material are 100%；
The component of the polyurethane sponge soft-filler B and the percentage by weight of each component are respectively：Polyether polyol 50~
80%, isocyanates 16~40%, foaming agent 2.5~10%, silicone oil 0.5~1.3%, tin catalyst 0.1~0.4%, amine is urged
The sum of agent 0.04~0.3%, the percentage of above material is 100%.
2. compounded mix according to claim 1, it is characterised in that the binding agent is selected from starch, lignin, polyethylene
At least one of alcohol, phenolic resin, polyethylene glycol oxide, carboxymethyl cellulose and its derivative.
3. compounded mix according to claim 1, it is characterised in that the polyether polyol be selected from polyether polyol 330,
Polyether polyol DEP-330N, polyether polyol DEP-505S, polyether polyol POP36/28, poly- tetrahydrochysene, which are barked, mutters in ether glycol
It is at least one.
4. compounded mix according to claim 1, it is characterised in that the isocyanates be selected from toluene di-isocyanate(TDI),
Methyl diphenylene diisocyanate (MDI), 4,4 '-dicyclohexyl methyl hydride diisocyanate, isophorone diisocyanate, 1,6-
At least one of hexa-methylene diamino-methyl formate.
5. compounded mix according to claim 1, it is characterised in that the foaming agent is in water, dichloromethane solution
At least one.
6. the preparation method of any compounded mix of Claims 1 to 5, it is characterised in that comprise the following steps：
1) dispensing：The charcoal for being crushed to suitable size, zeolite, iron oxide, bentonite are configured as described.Will be viscous
Knot agent is fully dissolved with suitable quantity of water, is configured to the binder solution of 3~7wt.%；
2) mixing granulation：Charcoal, zeolite, iron oxide, bentonite stir evenly, and mix while spray into binder solution,
Water content is made up to 40~65%, particle diameter is the spheric granules of 1.0~5.0mm；
3) it is dry：Spheric granules is put into baking oven in 45~80 DEG C of dry 3~8h；
4) cure：Dry bead is put into 110~180 DEG C of progress hot settings of high temperature oven, and hardening time is 0.5~3h；
5) cool down：By the spherical hard solid filler A cooled to room temperatures obtained by step 4)；
6) it is composite foamed：By in the spherical hard solid filler A obtained by step 5), polyether polyol, foaming agent, silicone oil table are added
Face activating agent, tin catalyst and amine catalyst, after stirring evenly, add isocyanates, continue 0.1~1.0min of stirring, then
Stand foaming is molded；
The dosage of above-mentioned all raw materials is as described in any one of Claims 1 to 5.
7. application of any one of Claims 1 to 5 compounded mix in planting aquatic plants.
8. application of any one of Claims 1 to 5 compounded mix in water body in planting plants.
9. application according to claim 8, it is characterised in that the plant is water plant.
A kind of 10. method of the planting plants in water body, it is characterised in that fill out Claims 1 to 5 any one of them is compound
Material is positioned in biological floating bed plantation basket, by plant cultivating in the compounded mix.
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| CN108821443A (en) * | 2018-07-13 | 2018-11-16 | 北京师范大学 | For controlling the biological floating bed and its constructing technology of water body in lake blue algae growth |
| CN109095614A (en) * | 2018-06-28 | 2018-12-28 | 浙江大学 | The biological floating bed and its matrix and preparation method prepared by biomass carbon source |
| CN109250683A (en) * | 2018-09-30 | 2019-01-22 | 武汉市能智达科技有限公司 | It is a kind of using magnesium hydride as the hydrogen production process of hydrogen storage material and device |
| CN112390368A (en) * | 2020-10-09 | 2021-02-23 | 淮阴工学院 | Novel bentonite composite active carbon ecological floating bed filler and preparation method thereof |
| CN113185001A (en) * | 2021-06-03 | 2021-07-30 | 吉林省林业科学研究院 | Agricultural microbial filter bed |
| CN115057645A (en) * | 2022-06-09 | 2022-09-16 | 苏州中晟环境修复有限公司 | Production process and device of composite ecological filler |
| CN117550740A (en) * | 2023-11-17 | 2024-02-13 | 湖南易净环保科技有限公司 | Sewage treatment system and method suitable for treating village sewage |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109250683A (en) * | 2018-09-30 | 2019-01-22 | 武汉市能智达科技有限公司 | It is a kind of using magnesium hydride as the hydrogen production process of hydrogen storage material and device |
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| CN113185001A (en) * | 2021-06-03 | 2021-07-30 | 吉林省林业科学研究院 | Agricultural microbial filter bed |
| CN115057645A (en) * | 2022-06-09 | 2022-09-16 | 苏州中晟环境修复有限公司 | Production process and device of composite ecological filler |
| CN117550740A (en) * | 2023-11-17 | 2024-02-13 | 湖南易净环保科技有限公司 | Sewage treatment system and method suitable for treating village sewage |
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