CN107904966A - 一种耐磨混纺面料的制备方法 - Google Patents

一种耐磨混纺面料的制备方法 Download PDF

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CN107904966A
CN107904966A CN201711367317.9A CN201711367317A CN107904966A CN 107904966 A CN107904966 A CN 107904966A CN 201711367317 A CN201711367317 A CN 201711367317A CN 107904966 A CN107904966 A CN 107904966A
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苏文珊
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Dalian Little Loli Clothing Co Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0036—Polyester fibres
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    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/06—Polyurethanes from polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0038—Polyolefin fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/142—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer
    • D06N3/143—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer with polyurethanes and other polycondensation or polyaddition products, e.g. aminoplast
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/147—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes characterised by the isocyanates used
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1685—Wear resistance

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Abstract

本发明涉及一种耐磨混纺面料的制备方法，属于服装面料领域。所述制备方法包括耐磨涂层液制备步骤；所述耐磨涂层液制备步骤为：按重量份，取20‑50份聚酯树脂、10‑30份二苯基甲烷二异氰酸酯、5‑20份聚酰胺多胺环氧氯丙烷、1‑10份引发剂、1‑10份促进剂；将聚酯树脂、二苯基甲烷二异氰酸酯、聚酰胺多胺环氧氯丙烷、引发剂与促进剂加热至溶解，得到耐磨涂层液。本发明改进了现有耐磨涂层的配方，使其制备的耐磨混纺面料的耐磨性优于现有同类产品。

Description

一种耐磨混纺面料的制备方法
技术领域
本发明涉及一种耐磨混纺面料的制备方法，属于服装面料领域。
背景技术
斜纹布分为粗斜纹和细斜纹两种。粗斜纹布用32号以上(18英支以下)棉纱作经、纬纱；细斜纹布用18号以下(32英支以上)棉纱作经、纬纱。斜纹布有本白、漂白和杂色等种类，常用作制服、运动服、运动鞋的夹里、金刚砂布底布和衬垫料。宽幅漂白斜纹布可作被单，经印花加工后也可作床单。元色和杂色细斜纹布经电光或轧光整理后布面光亮，可作伞面和服装夹里。
尼龙可以混纺或纯纺成各种医疗及针织品。锦纶长丝多用于针织及丝绸工业，如织单丝袜、弹力丝袜等各种耐磨的锦纶袜、锦纶纱巾、蚊帐、锦纶花边、弹力锦纶外衣、各种锦纶绸或交织的丝绸品。锦纶短纤维大都用来与羊毛或其它化学纤维的毛型产品混纺，制成各种耐磨经穿的衣料。
棉涤指的是棉和涤纶纤维混纺的织物，是以棉为主要成份，涤棉混纺物是以棉为主要成份，采用65-67％棉和33-35％的棉混纺织成的纺织品，棉涤布俗称棉涤，与涤棉相反。其优点为：涤纶纤维是合成纤维中最主要的品种，学名为“聚酯纤维”。织物坚牢弹性好，是所有纤维中抗皱最好的，耐热耐光，并有较好的一次定型性能；其缺点为：对油污的亲和力比较强，容易吸附油污，而且穿着过程中易产生静电而吸附灰尘，难以洗涤，而且不能用高温熨烫和沸水浸泡，吸湿透气性能差，吸湿率为0.4％，易聚静电，吸灰法，需在高压下染色。
棉麻布是棉布含麻的成分，又称为棉麻交织布料。棉麻布呢有苎麻棉和亚麻棉等等。黄麻布粗狂、手感硬、毛羽多，不适合服装用料。采用织物后整理的手段，研发成功的棉和黄麻交织的布料。棉麻布经各种颜色的染色加工，具有丰富色彩。由于织物比较厚实，且黄麻纤维独特的高吸放湿特性，该织物特别适合劳动防护服装用料，可替代牛仔布，但价格比牛仔布低廉得多。
发明内容
本发明通过调整耐磨涂层的配方，使本发明制备的耐磨混纺面料耐磨强度优于现有的耐磨面料。
本发明提供了一种耐磨混纺面料的制备方法，所述制备方法包括耐磨涂层液制备步骤；
所述耐磨涂层液制备步骤为：
按重量份，取20-50份聚酯树脂、10-30份二苯基甲烷二异氰酸酯、5-20份聚酰胺多胺环氧氯丙烷、1-10份引发剂、1-10份促进剂；
将聚酯树脂、二苯基甲烷二异氰酸酯、聚酰胺多胺环氧氯丙烷、引发剂与促进剂加热至溶解，得到耐磨涂层液。
本发明所述耐磨涂层液制备步骤优选为：
按重量份，取25-45份聚酯树脂、12-25份二苯基甲烷二异氰酸酯、8-15份聚酰胺多胺环氧氯丙烷、1.5-8份引发剂、2-8份促进剂；
将聚酯树脂、二苯基甲烷二异氰酸酯、聚酰胺多胺环氧氯丙烷、引发剂与促进剂加热至溶解，得到耐磨涂层液。
本发明所述制备方法优选为包括基布层制备步骤；
所述基布层制备步骤为：
按重量份，取7-10份聚酯纤维、1-5份聚丙烯纤维；
将聚酯纤维与聚丙烯纤维混纺得到基布层。
本发明所述基布层制备步骤优选为：
按重量份，取8-10份聚酯纤维、1-3份聚丙烯纤维；
将聚酯纤维与聚丙烯纤维混纺得到基布层。
本发明所述制备方法优选为包括如下步骤：
将聚酯纤维与聚丙烯纤维混纺得到基布层；
将聚酯树脂、二苯基甲烷二异氰酸酯、聚酰胺多胺环氧氯丙烷、过氧化苯甲酰与N,N-二甲基苯胺加热至溶解，得到耐磨涂层液；
将耐磨涂层液均匀涂在基布层的外表面上，干燥，得到耐磨混纺面料。
本发明所述耐磨涂层的厚度优选为0.1-0.5mm。
本发明所述干燥的方法优选为：15-20℃冷风吹干。
本发明所述制备方法包括耐磨涂层液制备步骤；所述耐磨涂层液制备步骤为：按重量份，取20-50份聚酯树脂、10-30份二苯基甲烷二异氰酸酯、5-20份聚酰胺多胺环氧氯丙烷、1-10份引发剂、1-10份促进剂；将聚酯树脂、二苯基甲烷二异氰酸酯、聚酰胺多胺环氧氯丙烷、引发剂与促进剂加热至溶解，得到耐磨涂层液。本发明改进了现有耐磨涂层的配方，使其制备的耐磨混纺面料的耐磨性优于现有同类产品，解决了现有面料耐磨性差的问题。
具体实施方式
下述非限制性实施例可以使本领域的普通技术人员更全面地理解本发明，但不以任何方式限制本发明。
实施例1
一种耐磨混纺面料的制备方法，所述制备方法包括如下步骤：
按重量份，取7份聚酯纤维、5份聚丙烯纤维；
将聚酯纤维与聚丙烯纤维混纺得到基布层；
按重量份，取50份聚酯树脂、10份二苯基甲烷二异氰酸酯、6份聚酰胺多胺环氧氯丙烷、2份过氧化苯甲酰、1份N,N-二甲基苯胺；
将聚酯树脂、二苯基甲烷二异氰酸酯、聚酰胺多胺环氧氯丙烷、过氧化苯甲酰与N,N-二甲基苯胺加热至溶解，得到耐磨涂层液；
将耐磨涂层液均匀涂在基布层的外表面上，耐磨涂层的厚度为0.2mm，15℃冷风吹干，得到耐磨混纺面料。
实施例2
一种耐磨混纺面料的制备方法，所述制备方法包括如下步骤：
按重量份，取8份聚酯纤维、3份聚丙烯纤维；
将聚酯纤维与聚丙烯纤维混纺得到基布层；
按重量份，取40份聚酯树脂、20份二苯基甲烷二异氰酸酯、12份聚酰胺多胺环氧氯丙烷、2.5份过氧化苯甲酰、2份N,N-二甲基苯胺；
将聚酯树脂、二苯基甲烷二异氰酸酯、聚酰胺多胺环氧氯丙烷、过氧化苯甲酰与N,N-二甲基苯胺加热至溶解，得到耐磨涂层液；
将耐磨涂层液均匀涂在基布层的外表面上，耐磨涂层的厚度为0.15mm，15℃冷风吹干，得到耐磨混纺面料。
实施例3
一种耐磨混纺面料的制备方法，所述制备方法包括如下步骤：
按重量份，取10份聚酯纤维、2份聚丙烯纤维；
将聚酯纤维与聚丙烯纤维混纺得到基布层；
按重量份，取30份聚酯树脂、25份二苯基甲烷二异氰酸酯、15份聚酰胺多胺环氧氯丙烷、1.5份过氧化苯甲酰、2.5份N,N-二甲基苯胺；
将聚酯树脂、二苯基甲烷二异氰酸酯、聚酰胺多胺环氧氯丙烷、过氧化苯甲酰与N,N-二甲基苯胺加热至溶解，得到耐磨涂层液；
将耐磨涂层液均匀涂在基布层的外表面上，耐磨涂层的厚度为0.25mm，15℃冷风吹干，得到耐磨混纺面料。
测试例1
分别将实施例1-3制备的耐磨混纺面料采用织物平磨仪测试其耐磨损性能，重锤质量为395g，夹持器与磨台相对运动速度为50r/min，10min后测耐磨混纺面料的质量损失率，其结果见表1。
表1 实施例1-3制备的耐磨混纺面料质量损失率的测试结果

Claims (7)

1.一种耐磨混纺面料的制备方法，其特征在于：所述制备方法包括耐磨涂层液制备步骤；
所述耐磨涂层液制备步骤为：
按重量份，取20-50份聚酯树脂、10-30份二苯基甲烷二异氰酸酯、5-20份聚酰胺多胺环氧氯丙烷、1-10份引发剂、1-10份促进剂；
将聚酯树脂、二苯基甲烷二异氰酸酯、聚酰胺多胺环氧氯丙烷、引发剂与促进剂加热至溶解，得到耐磨涂层液。
2.根据权利要求1所述的制备方法，其特征在于：所述耐磨涂层液制备步骤为：
按重量份，取25-45份聚酯树脂、12-25份二苯基甲烷二异氰酸酯、8-15份聚酰胺多胺环氧氯丙烷、1.5-8份引发剂、2-8份促进剂；
将聚酯树脂、二苯基甲烷二异氰酸酯、聚酰胺多胺环氧氯丙烷、引发剂与促进剂加热至溶解，得到耐磨涂层液。
3.根据权利要求2所述的制备方法，其特征在于：所述制备方法包括基布层制备步骤；
所述基布层制备步骤为：
按重量份，取7-10份聚酯纤维、1-5份聚丙烯纤维；
将聚酯纤维与聚丙烯纤维混纺得到基布层。
4.根据权利要求3所述的制备方法，其特征在于：所述基布层制备步骤为：
按重量份，取8-10份聚酯纤维、1-3份聚丙烯纤维；
将聚酯纤维与聚丙烯纤维混纺得到基布层。
5.根据权利要求4所述的制备方法，其特征在于：所述制备方法包括如下步骤：
将聚酯纤维与聚丙烯纤维混纺得到基布层；
将聚酯树脂、二苯基甲烷二异氰酸酯、聚酰胺多胺环氧氯丙烷、过氧化苯甲酰与N,N-二甲基苯胺加热至溶解，得到耐磨涂层液；
将耐磨涂层液均匀涂在基布层的外表面上，干燥，得到耐磨混纺面料。
6.根据权利要求5所述的制备方法，其特征在于：所述耐磨涂层的厚度为0.1-0.5mm。
7.根据权利要求6所述的制备方法，其特征在于：所述干燥的方法为：15-20℃冷风吹干。
CN201711367317.9A 2017-12-18 2017-12-18 一种耐磨混纺面料的制备方法 Pending CN107904966A (zh)

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