CN107836452A - A kind of Herbicidal combinations of humulone of sulphur containing triazole and its application - Google Patents

A kind of Herbicidal combinations of humulone of sulphur containing triazole and its application Download PDF

Info

Publication number
CN107836452A
CN107836452A CN201711095793.XA CN201711095793A CN107836452A CN 107836452 A CN107836452 A CN 107836452A CN 201711095793 A CN201711095793 A CN 201711095793A CN 107836452 A CN107836452 A CN 107836452A
Authority
CN
China
Prior art keywords
humulone
sulphur humulone
triazole
triazole sulphur
grass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201711095793.XA
Other languages
Chinese (zh)
Other versions
CN107836452B (en
Inventor
彭学岗
赵德
张景远
刘娜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Qing Yuan Compound Co Ltd
Qingdao Kingagroot Chemical Compound Co Ltd
Original Assignee
Qingdao Qing Yuan Compound Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Qing Yuan Compound Co Ltd filed Critical Qingdao Qing Yuan Compound Co Ltd
Priority to CN202110266478.9A priority Critical patent/CN112998022B/en
Priority to CN201711095793.XA priority patent/CN107836452B/en
Priority to PCT/CN2017/112016 priority patent/WO2019090814A1/en
Publication of CN107836452A publication Critical patent/CN107836452A/en
Application granted granted Critical
Publication of CN107836452B publication Critical patent/CN107836452B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04—Aryloxy-acetic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A01N41/06—Sulfonic acid amides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof

Abstract

The invention belongs to pesticide field, and in particular to a kind of Herbicidal combinations of humulone of sulphur containing triazole and its application.It is triazole sulphur humulone that the composition, which includes the active components A of herbicidally effective amount and B, A, and B may be selected from the one or more of following compound：VLCFA, PPO, PSII, ALS, microtubules, HPPD, PDS, lipid synthesis, EPSPS, GS, PSI, DHP inhibitor class and synthetic hormone class etc..Said composition can effectively prevent and kill off the weed problems such as barnyard grass in the crop fields, moleplant seed, Descurainia sophia, ox chickweed, Monochoria vaginalis, difformed galingale herb, have the characteristics that to expand herbicide controlling spectrum, reduce amount of application, to crop safety, synergistic effect can be produced and solve resistant weed.

Description

A kind of Herbicidal combinations of humulone of sulphur containing triazole and its application
Technical field
The invention belongs to pesticide field, and in particular to a kind of Herbicidal combinations of humulone of sulphur containing triazole and its application.
Background technology
Chemical weed control is means the most economical and effective during farmland weed is prevented and kill off, but uses list for a long time continuous high dose The chemical herbicide of one kind or the single mode of action, the problems such as easily causing weeds resistance and resistance evolution.
Triazole sulphur humulone chemical structural formula isBelong to HPPD enzyme inhibitor class compounds, Belong to inner-adsorption conduction-type herbicide, can be absorbed by the number of ways such as the blade and root of weeds, stem, be not easy recurrence of turning green.Should The mechanism of action of class compound is the activity that photosynthesis key pigment enzyme is controlled by suppressing plant, is converted into its substrate Alcapton process is obstructed, and so as to cause tocopherol and plastoquinone not to synthesize normally, influences carotenogenesis in target body, Cause yellow leaf, turn white, influence photosynthesis in plant and be normally carried out, it is final thoroughly dead.
The reasonable compounding or mixture of herbicidal compounds, which have, to be expanded weeds spectrum, improves preventive effect, delays weeds resistance Property and it is drug-fast generation with development the advantages that, be one of maximally efficient method to solve the above problems.Therefore in production urgently Safe, broad weed-killing spectrum need to be developed, synergistic effect can be produced and solves the problems, such as the Herbicidal combinations kind of resistant weed.
The content of the invention
To solve the above-mentioned problems in the prior art, the present invention provides a kind of Herbicidal combinations of the humulone of sulphur containing triazole And its application.Said composition can effectively prevent and kill off barnyard grass in the crop fields, moleplant seed, Descurainia sophia, ox chickweed, Monochoria vaginalis, special-shaped Sha The weed problems such as grass, have expand herbicide controlling spectrum, reduce amount of application, to crop safety, synergistic effect can be produced and solve resistance The features such as weeds.
A kind of Herbicidal combinations of the humulone of sulphur containing triazole, including the active components A of herbicidally effective amount and active component B, its In, active components A is triazole sulphur humulone, and active component B may be selected from the one or more of following compound:
(1) VLCFA inhibitor:S-metolachlor (CAS accession number:178961-20-1), (CAS is logged in flufenacet Number:142459-58-3), napropamide (CAS accession number:15299-99-7), sulfone pyrrole grass azoles (CAS accession number:447399-55-5)、 Xylenol grass amine (CAS accession number:87674-68-8), cafenstrole (CAS accession number:125306-83-4), (CAS is stepped on propisochlor Record number:86763-47-5), metazachlor (CAS accession number:67129-08-2), propachlor (CAS accession number:1918-16-7)、 Pethoxamid (CAS accession number:106700-29-2)；
(2) PPO inhibitor:Fomesafen (CAS accession number:72178-02-0), flumioxazin (CAS accession number: 103361-09-7), tiafenacil (CAS accession number:1220411-29-9), benzene flumetsulam (CAS accession number:372137- 35-4), pyraflufen-ethyl (CAS accession number:129630-19-9)；
(3) PSII inhibitor:Atrazine (CAS accession number:102029-43-6), terbutryn (CAS accession number:886-50- 0), ametryn (CAS accession number:834-12-8), dipropetryn (CAS accession number:4147-51-7), net (the CAS accession number of evil grass: 845-52-3), desmetryn (CAS accession number:1014-69-3), Simanex (CAS accession number:122-34-9), (CAS is stepped on metribuzin Record number:21087-64-9), ethiozin (CAS accession number:64529-56-2), metamitron (CAS accession number:41394-05- 2), cyanazine (CAS accession number:21725-46-2), chlortoluron (CAS accession number:15545-48-9), (CAS is logged in diuron Number:330-54-1), fluometuron (CAS accession number:2164-17-2), linuron (CAS accession number:330-55-2), tebuthiuron (CAS accession number:34014-18-1), afesin (CAS accession number:1746-81-2), metobromuron (CAS accession number:3060-89- 7), neburea (CAS accession number:555-37-3), alcohol pyridazines (CAS accession number:40020-01-7), hexazinone (CAS accession number: 51235-04-2), dimethametryn (CAS accession number:22936-75-0), trietazine (CAS accession number:1912-26-1), lenacil (CAS accession number:2164-08-1), terbacil (CAS accession number:5902-51-2), methabenzthiazuron (CAS accession number:18691- 97-9), Tupersan (CAS accession number:1982-49-6) grand (the CAS accession number of, Yi Evil:55861-78-4), (CAS is logged in metoxuron Number:19937-59-8), chloroxifenidium (CAS accession number:1982-47-4), trifluoro grass piperazine (CAS accession number:1258836-72-4)、 Desmedipham (CAS accession number:13684-56-5), phenmedipham (CAS accession number:13684-63-4)；
(4) ALS inhibitor:Tribenuron-methyl (CAS accession number:101200-48-0), thifensulfuronmethyl (CAS accession number:79277- 27-3), grand (the CAS accession number of thiophene ketone sulphur:317815-83-1), rimsulfuron (CAS accession number:122931-48-0), fluorine azoles sulphur Grand (CAS accession number:181274-17-9), mesosulfuron (CAS accession number:208465-21-8), (CAS is logged in nicosulfuron Number:111991-09-4), foramsulfuron (CAS accession number:173159-57-4), Flumetsulam (CAS accession number:98967- 40-9), fluorine ketone sulphur grass amine (CAS accession number:96525-23-4), cloransulammethyl (CAS accession number:147150-35-4), pyridine sulphur Careless amine (CAS accession number:422556-08-9), imazamox (CAS accession number:114311-32-9), AC 263222 (CAS Accession number:104098-48-8), imazethapyr (CAS accession number:81385-77-5), Arsenal (CAS accession number:81334- 34-1)；
(5) microtubules inhibitor:Trefanocide (CAS accession number:1582-09-8), Amex820 (CAS accession number:33629- 47-9), ethalfluralin (CAS accession number:55283-68-6), oryzalin (CAS accession number:19044-88-3), benfluralin (CAS accession number:1861-40-1), thiazopyr (CAS accession number:117718-60-2), pronamide (CAS accession number:23950- 58-5), chlorthal (CAS accession number:1861-32-1), butamifos (CAS accession number:36335-67-8)；
(6) HPPD inhibitor:Sulphur humulone (CAS accession number:99105-77-8), lancotrione (CAS accession number: 1486617-21-3), benzene azoles fluorine humulone (CAS accession number:1992017-55-6), sulphonyl grass pyrazoles (CAS accession number:365400- 11-9), tolpyralate (CAS accession number:1101132-67-5), fenquinotrione (CAS accession number:1342891- 70-6), isoxaflutoles (CAS accession number:141112-29-0)；
(7) PDS inhibitor:Fluorochloridone (CAS accession number:61213-25-0), flurtamone (CAS accession number:96525- 23-4), diflufenican (CAS accession number:83164-33-4), fluorine pyrrole acyl grass amine (CAS accession number:137641-05-5), fluorine fourth Acyl grass amine (CAS accession number:113614-08-7), norflurazon (CAS accession number:27314-13-2), (CAS is logged in fluridone Number:59756-60-4)；
(8) lipid synthesis (non-acetyl-CoA carboxylase) inhibitor:Prosulfocarb (CAS accession number:52888-80-9), furan Straw colour (CAS accession number:68505-69-1), ethofumesate (CAS accession number:26225-79-6), tri-allate (CAS accession number: 2303-17-5), benthiocarb (CAS accession number:28249-77-6), herbicide enemy (CAS accession number:1929-77-7), Ding Caote (CAS accession number:2008-41-5), cycloate (CAS accession number:1134-23-2), dimepiperate (CAS accession number:61432-55- 1), esprocarb (CAS accession number:85785-20-2)；
(9) synthetic hormone class:Fluroxypyr different monooctyl ester (CAS accession number:81406-37-3), trichlopyr (CAS accession number:55335-06-3), clopyralid (CAS accession number:1702-17-6), picloram (CAS accession number: 1918-02-1), Mediben (CAS accession number:1918-00-9), 2-methyl-4-chlorophenoxyacetic acid (CAS accession number:94-74- 6), chloro- phenol second thioesters (the CAS accession number of 2- methyl -4-:25319-90-8), MCPB (CAS accession number:94-81-5), 2- first Base -4- chlorine phenoxy propionic acid (CAS accession number:93-65-2), 2-methyl-4-chlorophenoxyacetic acid sodium (CAS accession number:3653-48- 3), the different monooctyl ester of 2-methyl-4-chlorophenoxyacetic acid (CAS accession number:29450-45-1), 2,4 dichloro benzene ethoxyacetic acid butyl ester (CAS Accession number:94-80-4), the different monooctyl ester of 2,4 dichlorophenoxyacetic acid (CAS accession number:25168-26-7), 2,4 dichlorophenoxyacetic acid (CAS accession number:94-75-7), 4- (2,4 dichloro benzene epoxide) propionic acid (CAS accession number:120-36-5), quinmerac (CAS Accession number:90717-03-6), Thistrol (CAS accession number:94-81-5), 2,4- Embutoxs (CAS accession number:94-82- 6)；
(10) EPSPS inhibitor:Sulphosate (CAS accession number:81591-81-3)；
(11) GS inhibitor:Bialaphos (CAS accession number:35597-43-4), smart glufosinate-ammonium (CAS accession number:35597- 44-5)；
(12) PSI inhibitor:Paraquat (CAS accession number:1910-42-5), diquat dibromide (CAS accession number:6385-62- 2)；
(13) DHP inhibitor:Clever (the CAS accession number of sulphur grass:3337-71-1)；
(14) other:Cinmethylin (CAS accession number:87818-31-3).
Wherein, A and B weight ratio is 1:200-200:1, preferably 1:150-150:1, more preferably 1:120-120:1；Enter one Step ground, A and B weight ratio are 1:100-100:1, preferably 1:80-80:1, more preferably 1:50-50:1；Further, A and B Weight ratio be 1:30-30:1, preferably 1:10-10:1, more preferably 1:5-5:1.
A, B weight/mass percentage composition account for the 1-95% of total amount, preferably 10-80% in the Herbicidal combinations.
Conven-tional adjuvants are also included in the Herbicidal combinations, the conven-tional adjuvants include carrier, surfactant.
Term " carrier " herein represents a kind of organic or inorganic, natural or synthetic material.They contribute to activity The administration of composition, the carrier are usually inert and must be agriculturally acceptable, and particularly processed plant is received. Carrier can be solid, such as clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer；Or liquid Body, such as water, alcohols, ketone, petroleum distillate, aromatic hydrocarbons or wax hydrocarbon, chlorohydrocarbon, liquefied gas.
Surfactant may include emulsifying agent, dispersant or wetting agent, and it can be ionic or nonionic.It can carry And example be the salt of polyacrylic acid, lignosulfonates, phenolsulfonic acid or naphthalene sulfonic acids salt, oxirane and aliphatic alcohol or Polymer, sulfosuccinic acid with aliphatic acid or with aliphatic amine and fortified phenol (particularly alkylphenol or aryl phenol) Phosphate, the alkyl of salt, taurine derivatives (particularly taurine alkane fat) and the phenol of alcohol phosphate or multi-hydroxy ethyl Sulfonate, alkylaryl sulfonates, alkyl sulfate, lauryl ether sulfate, aliphatic alcohol sulfate, and sulphation 16-, 17-and octadecanol and sulphated fatty alcohol glycol ether, in addition with the condensation of naphthalene or naphthalene sulfonic acids and phenol and formaldehyde Thing, NONIN HS 240, ethoxylated isooctyl-phenol, octyl phenol or nonyl phenol, alkyl phenyl polyglycol ether, three fourths Base phenyl polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol, alcohol and fatty alcohol/ethylene oxide contracting Compound, ethoxylated castor oil, polyoxyethylene alkyl ether, ethoxylation polyoxypropylene, laruyl alcohol polyglycol ether acetal, sorb Alcohol ester, lignin sulfite waste liquor, and protein, albuminate, polysaccharide (such as methylcellulose), Hydrophobic Modified Starch, Polyvinyl alcohol, polycarboxylate, poly-alkoxyl compound, polyvinylamine, polyvinylpyrrolidone and its copolymer.At least need one kind Surfactant is present, to be advantageous to scattered in water of active component and be advantageous to enable them to correctly be applied to plant.
Above-mentioned composition also contains various other components, such as protecting colloid, adhesive, thickener, thixotropic agent, infiltration Agent, stabilizer, chelating agent, dyestuff, colouring agent and polymer.
The composition of the present invention can be used by user before use through dilution or directly.It, which is prepared, to be added by common Work method prepare, i.e., after active material is mixed with liquid flux or solid carrier, add surfactant such as dispersant, surely Determine the one or more in agent, wetting agent, adhesive, defoamer etc..
The specific preparation of the Herbicidal combinations be dispersible oil-suspending agent, aqueous suspension agent, suspension emulsion, wettable powder, Missible oil, water dispersible granules (dry suspending agent), aqueous emulsion, microemulsion.
In brief, composition of the invention can be with conventional use of solid and liquid addition in the formula of prior art Agent mixes.
In addition, compound A and B composition can mix with following active material, such as《World pesticide new varieties technology It is complete works of》, Scientia Agricultura Sinica technology publishing house, 2010.9 and document incorporated herein in known substance.It is such as mentioned below Herbicidal activity material, (remarks:The title of compound, or be the common name according to International Organization for standardization (ISO), Or be chemical name, have code name when appropriate):Acetochlor, butachlor, alachlor, propisochlor, isopropyl methoxalamine, essence The left-handed naphthalene propionyl grass amine of isopropyl methoxalamine, pretilachlor, propachlor, kecaoan, naphthalene propionyl grass amine, R-, propanil, mefenacet, Diphenamide, diflufenican, N-alpha-chloroacetyl-N-isopropyl-o ethylaniline, beflubutamid, bromobutide, dimethenamid, dimethenamidP, Ethobenzanid, flufenacet, thenylchlor, metazachlor, isoxaben, flampropMmethyl, flampropMisopropyl, Allidochlor, pethoxamid, chloranocryl, ring pretilachlor, mefluidide, monalide, delachlor, prynachlor, spy Butachlor, xylachlor, dimethachlor, amine of taking to the greenwood, front three ring grass amine, clomeprop, propyzamide, valeryl benzene grass Amine, the careless amine of card, suffer, three rings match careless amine, butenachlor, tebutam, benzyl grass amine, quinone duckweed amine, dichlofluanid, naproanilide, second Acyl alachlor, quinclorac, fenacet, pyrrole cyanogen grass amine, more grams of benzene grass are dead, chlorothiamid, chlorine phthalimide, fourth amidine amine, fluorine metazachlor, green bristlegrass Go Tianjin, Simanex, prometryn, cyanatryn, symetryne, ametryn, propazine, dipropetryn, SSH-108, terbutryn, Garagard, three Piperazine benfluralin, cyprazine, proglinazine, trietazine, prometon, Gesadrual, nitrine are net, desmetryn, dimethametryn, third blue or green Tianjin of ring, Green bristlegrass of going out Tianjin, another Ding Jin, Zhong Dingtong, Te Dingtong, methoxy third are net, cyanatryn, ipazine, chlorazine, atraton, weed eradication are logical, radix glycyrrhizae Tianjin, cyanuric acid, Indaziflam, green sulphur are grand, metsulfuron-methyl, bensulfuron-methyl, chlorimuron, tribenuron-methyl, thifensulfuron methyl, the phonetic Huang of pyrrole Grand, mesosulfuron, iodosulfuron-methyl-sodium, formamido group Sulfometuron Methyl, cinosulfuron, triasulfuron, sulfometuronmethyl, the phonetic sulphur of cigarette Grand, ethametsulfuron, amidosulfuron, ethoxysulfuron, AC322140, rimsulfuron, azimsulfuron, pyridine ethyl methyl, list are phonetic Sulphur is grand, single phonetic sulphur ester, flucarbazone, flupyrsulfuron-methyl-sodium, fluorine pyrazosulfuron, oxasulfuron, imazosulfuron, primisulfuronmethyl, Procarbazone, prosulfuron, Sulfosulfuron, trifloxysulfuron, triflusulfuronmethyl, tritosulfuron, metsulfuron-methyl sodium salt, fluorine pyrrole sulphur Grand, Sulfonylurea, orthosulfamuron, Propyrisulfuron (promazine Sulfometuron Methyl), piperazine pyrazosulfuron, acifluorfen, fluorine Sulfanilamide (SN) grass ether, lactofen, fluoroglycofen-ethyl, Oxyfluorfen, Mo 9 granular, aclonifen, ethoxyfen-ethyl, first carboxylic weeding Ether, fluoroform grass ether, chlomethoxyfen, fluorodifen, fluorination nitrofen, fluorine furan grass ether, nitrofen, first grass ether, diformazan grass Ether, fluorine lactazone grass ether, AKH7088 ester, Halosafen, chlortoluron, isoproturon, linuron, diuron, Sha flutter grand, fluometuron, benzene Thiophene is grand, methabenzthiazuron, cumyluron, ethidimuron, isouron, terbufos benzthiazuron, buturon, bromax, methyldymron, acyl grass Grand, methoxy daimuron, metobromuron, metoxuron, afesin, telvar, Tupersan, fenuron, fluorine sulphur are grand, neburea, chloroxifenidium, It is herban, isonoruron, Alipur-O, thiazfluron, tebuthiuron, difenoxuron, different to fluon, methylamine methabenz thiazuron, Long Caote, front three Urea, dimefuron, Monisouron, Anisuron, Methiuron, Chloreturon, four fluon, phenmedipham, phenmedipham-second The careless spirit of ester, desmedipham, sulphur, terbucarb, oatax, Chem hoe, chlorpropham, benzyl dichloride grass ester, swep, chlorbufam, Carboxazole, Chlorprocarb, Fenasulam, BCPC, CPPC, Carbasulam, Ding Caote, benthiocarb, vernolate, The careless spy of molinate, tri-allate, dimepiperate, esprocarb, pyributicarb, cycloate, Avadex, bactericide, second sulphur, orbencarb, gram grass Suddenly, prosulfocarb, tiocarbazil, sulfuric acid, dimexan, Isopolinate, Methiobencarb, 2,4- d butyl ester, the chlorine of 2 first 4 Sodium, the different monooctyl ester of 2,4- drops, the different monooctyl ester of the chlorine of 2 first 4,2,4- drops sodium salt, 2,4- drops dimethylamine salt, the chloroethene thioesters of 2 first 4, the chlorine of 2 first 4,2, 4- drops propionic acid, high 2,4- drops propionate, 2,4- Embutoxs, Vi par, Vi par salt, Thistrol, 2,4,5- Tears, 2,4,5- tears propionic acid, 2,4,5- tears butyric acid, the chloramines salt of 2 first 4, Mediben, erbon, Fenac, match pine, trichlorobenzoic acid, ammonia Dichloro benzoic acid, methoxy trichlorobenzoic acid, diclofop-methyl, fluazifop, efficient fluazifop, haloxyfop-P-methyl, efficient pyrrole fluorine chlorine standing grain Spirit, quizalofop-ethyl, Quizalotop-ethyl, fenoxaprop-P, fenoxapropPethyl, propaquizafop, cyhalofop-butyl, metamifop, clodinafop-propargyl, Diclofop-methyl thiazole, chloroazifoppropynyl, the spirit of the standing grain of hydroxyl penta, trifluoro dogstail oxime, isoxapyrifop, paraquat, diquat dibromide, oryzalin, second butylene fluorine Spirit, isopropalin, nitralin, profluralin, prodiamine, benfluralin, fluchloraline, the spirit of amino second fluorine, dipropalin, Chloroethene dipropalin, Methalpropalin, the third nitre phenol, glyphosate, Sha barnyard grass phosphine, glufosinate-ammonium, amiprophos-methyl, sulphosate, piperazine grass Phosphine, bialaphos, bensulide, butamifos, creeping weed phosphorus, cut down ridge phosphorus, double first amiprophos, dow crabgrass killer, imazapyr, imidazoles second cigarette Acid, imazaquin, imazamox, imazamox ammonium salt, AC 263222, miaow grass ester, fluroxypyr, chlorine fluorine pyrrole The different monooctyl ester of fluoroacetic acid, clopyralid, picloram, trichlopyr, dithiopyr, halogen grass are fixed, phenolate trichloropyridine, thiophene Careless pyridine, fluridone, chlorine Fampridine acid, diflufenzopyr, triclopyr butoxyethyl ester, Cliodinate, sethoxydim, alkene Humulone, cycloxydim, alloxydimsodium, clefoxidim, butroxydim, tralkoxydim, tepraloxydim, Buthidazole, metribuzin, ring piperazine Ketone, metamitron, ethiozin, Ametridione, Amibuzin, Brominal, bromoxynil octanoate, ioxynil octanoate, iodobenzene Nitrile, dichlobenil, diphenatril, pyraclonil, chloroxynil, Iodobonil, Flumetsulam, florasulam, penoxsulam Amine, metosulam, cloransulammethyl, diclosulam, pyroxsulam, fluorine straw colour, bispyribac-sodium, pyribenzoxim, pyriftalid, KIH 6127, pyrithiobacsodium, benzobicylon, mesotrione, sulphur humulone, Tembotrione, Tefuryltrione, It is Bicyclopyrone, Ketodpiradox, isoxaflutole, isoxachlorotole, Fenoxasulfone, Methiozolin, different Third pyrrole grass ester, pyraflufen-ethyl, pyrazolate, difenzoquat, pyrazoxyfen, benzofenap, pyrrole chlorine grass amine, Pyrasulfotole, topramezone, Pyroxasulfone, cafenstrole, flupoxam, Amrol, amicarbazone, azafenidin, profluazone, sulfentrazone, Bencarbazone, benzfendizone, butafenacil, bromacil, isoprocil, lenacil, terbacil, Flupropacil, Yin Diindyl ketone grass ester, Flumiclorac pentyl, flumioxazin, alkynes grass amine, phthalein benzyl oxide, Flumezin, pentachlorophenol (sodium), dinoseb, dinoterb, Dinoterb acetate, dinosam, Chemox PE, chlorine nitre phenol, medinoterb acetate, Di Lete, oxadiargyl, oxadiazon, pentoxazone, fluorine azoles grass Amine, fluthiacet, fentrazamide, flufenpyrethyl, pyrazon, brompyrazon, diformazan reach careless volt, Kusakira, careless pyridazone, grass Rattle away pine, norflurazon, Pyridafol, dichloro quinolinic acid, quinmerac, Bentazon, pyridate, oxaziclomefone, benazolin, different Oxadiazon, cinmethylin, iso-propyl-ester nitrofen, propyl-ester nitorfen, indanofan, sodium chlorate, Dalapon, trichloroacetic acid, monochloroacetic acid, six Chlroacetone, tetrafluoro propionic acid, herbage are fast, bromofenoxim, triazole sulphur, kill azoles, flurtamone, benfuresate, ethofumesate, phonetic careless amine, chlorine Phthalandione, fluorochloridone, barnyard grass, methacrylaldehyde, bentranil, tridiphane, Bidisin, thiadiazoles grass amine, phenisopham, hydroxyl humulone, first Oxybenzone, benzene flumetsulam, chlorine acyl grass phosphine, chloropon, Alorac, Diethamquat, Etnipromid, Iprymidam, Ipfencarbazone、Thiencarbazone-methyl、Pyrimisulfan、Chlorflurazole、 Tripropindan, Sulglycapin, first sulphur nitralin, Cambendichlor, the pyrimidine acid of ring third, rodethanii, benoxacor, Fenclorim, flurazole, fenchlorazole, the careless quinoline of solution, oxabetrinil, MG191, cyometrinil, DKA_24, mefenpyrdiethyl, furans solution grass Azoles, fluxofenim, isoxadifen, allyl dichloride amine, fluorine chloropyridine ester, DOW chlorine fluorine pyridine ester, UBH-509, D489, LS 82- 556、KPP-300、NC-324、NC-330、KH-218、DPX-N8189、SC-0744、DOWCO535、DK-8910、V-53482、 PP-600, MBH-001, KIH-9201, ET-751, KIH-6127 and KIH-2023.
The Herbicidal combinations further comprise safener, and it is selected from isoxadifen (CAS accession number:163520-33- 0), cyprosulfamide (CAS accession number:221667-31-8), mefenpyrdiethyl (CAS accession number:135590-91-9), solve Malicious quinoline (CAS accession number:99607-70-2), gibberellic acid (CAS accession number:77-06-5), furilazole (CAS accession number: 121776-33-8), metcamifen (CAS accession number:One or more in 129531-12-0).
The composition of the present invention can be applied on pending plant leaf blade by the method for spraying, that is, is applied to weeds, On the surface that the weed infestation or easy invasion being particularly harmful on plant growth influence.
When applying the Herbicidal combinations of the present invention, unexpected synergistic effect is obtained, and activity of weeding ratio makes It is individually active more notable with the expected summation of the activity of single herbicide, and single herbicide.Synergistic effect shows as applying Measure reduction, broader weeds distribution spectrum, herbicide effect faster, it is more longlasting, these characteristics are needed for Weeds distribution practice process Want.For described characteristic, these new compositions are significantly superior to existing herbicide.
The Herbicidal combinations of the present invention, which also have, to be had the advantage that:
(1) composition of the invention is environmentally friendly to be easy to degrade in the environment, suitable for various crop field.
(2) Herbicidal combinations cost of the invention is low, easy to use, and its popularization and application has huge economic benefit and society Benefit.
Embodiment
The following example not limits the present invention, and is used only to how the explanation present invention realizes.For some miscellaneous Grass, these embodiments show especially significant validity.It is exemplified below:
A) embodiment
1st, 46% triazole sulphur humulone S-metolachlor suspension emulsion (6+40)
The phenethyl phenol polyethenoxy ether sulphur of+40% S-metolachlor+5%150# solvent naphthas of 6% triazole sulphur humulone+3% The xanthans of+2.5% castor oil polyoxyethylene ether of acid esters triethanolamine+1% phenethyl phenol polyethenoxy ether of dipersant+0.06% + 5% glycerine+water is supplied.
2nd, 22% triazole sulphur humulone flufenacet suspending agent (12+10)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 12%+10% flufenacet of triazole sulphur humulone+3% disperses The aluminium-magnesium silicate+5% of+0.18% xanthans of the propylene glycol block polyether of agent+2%+1% AEO of dispersant+1.8% Glycerine+water is supplied.
3rd, 28% triazole sulphur humulone napropamide suspending agent (3+25)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+25% napropamide of triazole sulphur humulone+5%+ + 5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of 2% AEO+1.6%+water is supplied.
4th, 55% triazole sulphur humulone sulphur grass Lingshui Spring dispersible granule (2.25+52.75)
The clever pull open powder+1% of+8% polycarboxylic acid salt's dispersant+6% of the sulphur of 2.25% triazole sulphur humulone+52.75% grass is disintegrated + 5% precipitated silica of agent polyvinyl alcohol+filler diatomite is supplied.
5th, 32% triazole sulphur humulone sulfone pyrrole grass azole suspending agent (12+20)
The AEO of+20%+5% polycarboxylate salt dispersant of sulfone pyrrole grass azoles of 12% triazole sulphur humulone+2%+ + 5% glycerine of aluminium-magnesium silicate of 0.16% xanthans+1.6%+water is supplied.
6th, the 18% triazole sulphur humulone dispersible oil-suspending agent of xylenol grass amine (3+15)
The NPE of+15%+5% calcium dodecyl benzene sulfonate of xylenol grass amine of 3% triazole sulphur humulone+6%+ Fumed silica+10%150# the solvent naphthas of+1.6% organobentonite of 4% castor oil polyoxyethylene ether+1.5%+oleic acid first Ester is supplied.
7th, 27% triazole sulphur humulone cafenstrole suspending agent (12+15)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 12%+15% cafenstrole of triazole sulphur humulone+4% + 5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of+1.5% AEO+1.6%+water is supplied.
8th, 28% triazole sulphur humulone propisochlor suspension emulsion (3+25)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 3%+25% propisochlor of triazole sulphur humulone+3% disperses + 5% glycerine of xanthans of+2% castor oil polyoxyethylene ether of the phenethyl phenol polyethenoxy ether of agent+2%+0.14%+water is supplied.
9th, 31% triazole sulphur humulone metazachlor suspension emulsion (6+25)
The phenethyl phenol polyethenoxy ether phosphate of+25% metazachlor+10%150# solvent naphthas of 6% triazole sulphur humulone+3% The xanthans+5% third of+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of triethanolamine dipersant+0.14% Triol+water is supplied.
10th, 41% triazole sulphur humulone propachlor suspension emulsion (3+38)
The phenethyl phenol polyethenoxy ether phosphate three of+38% propachlor+5%150# solvent naphthas of 3% triazole sulphur humulone+3% The xanthans+5% of+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of ethanolamine salt dispersant+0.12% the third three Alcohol+water is supplied.
11st, 43% triazole sulphur humulone pethoxamid suspension emulsion (3+40)
The phenethyl phenol polyethenoxy ether phosphate three of+40% pethoxamid+5%150# solvent naphthas of 3% triazole sulphur humulone+3% The xanthans+5% of+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of ethanolamine salt dispersant+0.13% the third three Alcohol+water is supplied.
12nd, 9% triazole sulphur humulone fomesafen suspending agent (3+6)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 3%+6% fomesafen of triazole sulphur humulone+4% disperses + 5% glycerine of aluminium-magnesium silicate of+0.22% xanthans of the AEO of agent+1.5%+2.0%+water is supplied.
13rd, 18% triazole sulphur humulone flumioxazin suspending agent (12+6)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+6% flumioxazin of triazole sulphur humulone+4% + 5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of the AEO of powder+1.5%+1.5%+water is supplied.
14th, 28% triazole sulphur humulone tiafenacil suspending agents (24+4)
24% triazole sulphur humulone+4%tiafenacil+4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinities + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the AEO of powder+1.5%+1.5%+water is supplied.
15th, the 12% triazole sulphur dispersible oil-suspending agent of humulone benzene flumetsulam (9+3)
The NPE of 9%+5% calcium dodecyl benzene sulfonate of triazole sulphur+3% benzene flumetsulam of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+3.0% organobentonite of 4% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
16th, the 10% triazole dispersible oil-suspending agent of sulphur humulone pyraflufen-ethyl (9+1)
The castor of 9%+6% NPE of triazole sulphur humulone+5% calcium dodecyl benzene sulfonate of+1% pyraflufen-ethyl+4% Fumed silica+10%150# the solvent naphthas of+2.6% organobentonite of sesame oil APEO+2.5%+methyl oleate is mended Foot.
17th, 50% triazole sulphur humulone atrazine suspending agent (12+38)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 12%+38% atrazine of triazole sulphur humulone+4% + 5% glycerine of xanthans of+1.5% AEO+0.08%+water is supplied.
18th, 33% triazole sulphur humulone terbutryn suspending agent (3+30)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+30% terbutryn of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of 1.5% AEO+1.4%+water is supplied.
19th, 43% triazole sulphur humulone ametryn suspending agent (3+40)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+40% ametryn of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.1% xanthans of 1.5% AEO+1.0%+water is supplied.
20th, 53% triazole sulphur humulone dipropetryn suspending agent (3+50)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+50% dipropetryn of triazole sulphur humulone+4%+ + 5% glycerine of xanthans of 1.5% AEO+0.06%+water is supplied.
21st, 53% triazole sulphur humulone does harm to careless net suspension agent (3+50)
Net+4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3% triazole sulphur humulone+50% evil grass+ + 5% glycerine of xanthans of 1.5% AEO+0.06%+water is supplied.
22nd, 44% triazole sulphur humulone desmetryn suspending agent (6+38)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+38% desmetryn of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.1% xanthans of 1.5% AEO+0.5%+water is supplied.
23rd, 33% triazole sulphur humulone Simanex suspending agent (3+30)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+30% Simanex of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of 1.5% AEO+1.5%+water is supplied.
24th, 19% triazole sulphur humulone metribuzin suspending agent (4+15)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 4%+15% metribuzin of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of 1.5% AEO+2.0%+water is supplied.
25th, 30% triazole sulphur humulone ethiozin suspending agent (6+24)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 6%+24% ethiozin of triazole sulphur humulone+4% disperses + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the AEO of agent+1.5%+1.5%+water is supplied.
26th, 67% triazole sulphur humulone metamitron water dispersible granules (2+65)
The disintegrant of 2%+6% pull open powder of triazole sulphur humulone+8% polycarboxylic acid salt's dispersant of+65% metamitron+1% gathers The precipitated silica of vinyl alcohol+5%+filler diatomite is supplied.
27th, 28% triazole sulphur humulone cyanazine suspending agent (3+25)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+25% cyanazine of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of 1.5% AEO+1.8%+water is supplied.
28th, 53% triazole sulphur humulone chlortoluron suspending agent (3+50)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+50% chlortoluron of triazole sulphur humulone+4%+ + 5% glycerine of xanthans of 1.5% AEO+0.06%+water is supplied.
29th, 36% triazole sulphur humulone diuron suspending agent (6+30)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+30% diuron of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of 1.5% AEO+1.5%+water is supplied.
30th, 46% triazole sulphur humulone fluometuron suspending agent (6+40)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+40% fluometuron of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.1% xanthans of 1.5% AEO+1.0%+water is supplied.
31st, 28% triazole sulphur humulone linuron suspending agent (3+25)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+25% linuron of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of 1.5% AEO+1.5%+water is supplied.
32nd, 33% triazole sulphur humulone tebuthiuron suspending agent (3+30)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+30% tebuthiuron of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of 1.5% AEO+1.6%+water is supplied.
33rd, 53% triazole sulphur humulone afesin suspending agent (3+50)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+50% afesin of triazole sulphur humulone+4%+ + 5% glycerine of xanthans of 1.5% AEO+0.06%+water is supplied.
34th, 39% triazole sulphur humulone metobromuron suspending agent (6+33)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+33% metobromuron of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.1% xanthans of 1.5% AEO+1.0%+water is supplied.
35th, 67% triazole sulphur humulone neburea water dispersible granules (3+64)
The poly- second of disintegrant of 3%+6% pull open powder of triazole sulphur humulone+8% polycarboxylic acid salt's dispersant of+64% neburea+1% The precipitated silica of enol+5%+filler diatomite is supplied.
36th, 39% triazole sulphur humulone alcohol pyridazines suspending agent (6+33)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+33% alcohol pyridazines of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.1% xanthans of 1.5% AEO+1.0%+water is supplied.
37th, 41% triazole sulphur humulone hexazinone suspending agent (3+38)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+38% hexazinone of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.1% xanthans of 1.5% AEO+1.0%+water is supplied.
38th, 45% triazole sulphur humulone dimethametryn suspending agent (3+42)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 3%+42% dimethametryn of triazole sulphur humulone+4% disperses + 5% glycerine of aluminium-magnesium silicate of+0.08% xanthans of the AEO of agent+1.5%+0.8%+water is supplied.
39th, 43% triazole sulphur humulone trietazine suspending agent (3+40)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+40% trietazine of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.1% xanthans of 1.5% AEO+1.0%+water is supplied.
40th, 46% triazole sulphur humulone lenacil suspending agent (6+40)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+40% lenacil of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.08% xanthans of 1.5% AEO+0.5%+water is supplied.
41st, 63% triazole sulphur humulone terbacil water dispersible granules (3+60)
The poly- second of disintegrant of 3%+6% pull open powder of triazole sulphur humulone+8% polycarboxylic acid salt's dispersant of+60% terbacil+1% The precipitated silica of enol+5%+filler diatomite is supplied.
42nd, 26% triazole sulphur humulone methabenzthiazuron suspending agent (12+14)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+14% methabenzthiazuron of triazole sulphur humulone+4% + 5% glycerine of aluminium-magnesium silicate of+0.13% xanthans of the AEO of powder+1.5%+1.5%+water is supplied.
43rd, 63% triazole sulphur humulone Tupersan water dispersible granules (3+60)
The lauryl sodium sulfate+1% of 3%+6% polycarboxylic acid salt's dispersant of triazole sulphur+60% Tupersan of humulone+4% collapses + 5% precipitated silica of solution agent polyvinyl alcohol+filler diatomite is supplied.
44th, the 36% triazole sulphur grand suspending agents of humulone Yi Evil (3+33)
+ 33% different grand+4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersants of Evil of 3% triazole sulphur humulone+ + 5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of 1.5% AEO+1.5%+water is supplied.
45th, 70% triazole sulphur humulone metoxuron water dispersible granules (3+67)
The poly- second of disintegrant of 3%+5% pull open powder of triazole sulphur humulone+5% polycarboxylic acid salt's dispersant of+67% metoxuron+1% The precipitated silica of enol+5%+filler diatomite is supplied.
46th, 70% triazole sulphur humulone chloroxifenidium water dispersible granules (3+67)
The poly- second of disintegrant of 3%+6% pull open powder of triazole sulphur humulone+6% polycarboxylic acid salt's dispersant of+67% chloroxifenidium+1% The precipitated silica of enol+5%+filler diatomite is supplied.
47th, 32% triazole sulphur humulone trifluoro grass piperazine suspending agent (12+20)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of+20% trifluoro grass piperazine of 12% triazole sulphur humulone+4% disperses + 5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of the AEO of agent+1.5%+1.5%+water is supplied.
48th, 36% triazole sulphur humulone desmedipham suspending agent (4.5+31.5)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 4.5%+31.5% desmedipham of triazole sulphur humulone+4% + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the AEO of powder+1.5%+1.5%+water is supplied.
49th, 36% triazole sulphur humulone phenmedipham suspending agent (4.5+31.5)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 4.5%+31.5% phenmedipham of triazole sulphur humulone+4% + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the AEO of powder+1.5%+1.5%+water is supplied.
50th, the 14% triazole dispersible oil-suspending agent of sulphur humulone tribenuron-methyl (12+2)
The NPE+4% of 12%+5% calcium dodecyl benzene sulfonate of triazole sulphur+2% tribenuron-methyl of humulone+6% Fumed silica+10%150# the solvent naphthas of the organobentonite of castor oil polyoxyethylene ether+2.6%+2.5%+methyl oleate Supply.
51st, the 14% triazole dispersible oil-suspending agent of sulphur humulone thifensulfuronmethyl (12+2)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of triazole sulphur+2% thifensulfuronmethyl of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+2.6% organobentonite of 4% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
52nd, the 15% grand dispersible oil-suspending agent (12+3) of triazole sulphur humulone thiophene ketone sulphur
The grand NPE of+5% calcium dodecyl benzene sulfonate+6% of thiophene ketone sulphur of 12% triazole sulphur humulone+3%+ Fumed silica+10%150# the solvent naphthas of+2.6% organobentonite of 4% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
53rd, the 27% triazole dispersible oil-suspending agent of sulphur humulone rimsulfuron (24+3)
The NPE of 24%+5% calcium dodecyl benzene sulfonate of triazole sulphur+3% rimsulfuron of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+1.4% organobentonite of 4% castor oil polyoxyethylene ether+1.5%+oleic acid first Ester is supplied.
54th, the 15% triazole dispersible oil-suspending agent of sulphur humulone flucarbazone (12+3)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of triazole sulphur+3% flucarbazone of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+2.6% organobentonite of 4% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
55th, the 26% triazole dispersible oil-suspending agent of sulphur humulone mesosulfuron (24+2)
The NPE of 24%+5% calcium dodecyl benzene sulfonate of triazole sulphur+2% mesosulfuron of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+2.6% organobentonite of 4% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
56th, the 16% triazole dispersible oil-suspending agent of sulphur humulone nicosulfuron (12+4)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of triazole sulphur+4% nicosulfuron of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+2.6% organobentonite of 4% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
57th, the 15% triazole dispersible oil-suspending agent of sulphur humulone foramsulfuron (12+3)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of triazole sulphur+3% foramsulfuron of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+2.6% organobentonite of 4% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
58th, the 15% triazole dispersible oil-suspending agent of sulphur humulone Flumetsulam (12+3)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of triazole sulphur+3% Flumetsulam of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+2.6% organobentonite of 4% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
59th, the 29% triazole sulphur humulone fluorine ketone dispersible oil-suspending agent of sulphur grass amine (24+5)
The NPE of+5%+5% calcium dodecyl benzene sulfonate of fluorine ketone sulphur grass amine of 24% triazole sulphur humulone+6%+ Fumed silica+10%150# the solvent naphthas of+1.0% organobentonite of 4% castor oil polyoxyethylene ether+0.5%+oleic acid first Ester is supplied.
60th, the 14% triazole dispersible oil-suspending agent of sulphur humulone cloransulammethyl (12+2)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of triazole sulphur+2% cloransulammethyl of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+2.6% organobentonite of 4% castor oil polyoxyethylene ether+2.0%+oleic acid first Ester is supplied.
61st, the 26% triazole dispersible oil-suspending agent of sulphur humulone pyroxsulam (24+2)
The NPE of 24%+5% calcium dodecyl benzene sulfonate of triazole sulphur+2% pyroxsulam of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+1.0% organobentonite of 4% castor oil polyoxyethylene ether+1.0%+oleic acid first Ester is supplied.
62nd, the 15% triazole dispersible oil-suspending agent of sulphur humulone imazamox (12+3)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of triazole sulphur+3% imazamox of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+2.2% organobentonite of 4% castor oil polyoxyethylene ether+1.5%+oleic acid first Ester is supplied.
63rd, the 22% triazole dispersible oil-suspending agent of sulphur humulone AC 263222 (12+10)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of triazole sulphur+10% AC 263222 of humulone+6% Fumed silica+10%150# the solvent naphthas of+1.5% organobentonite of+4% castor oil polyoxyethylene ether+1.5%+oleic acid Methyl esters is supplied.
64th, the 19% triazole dispersible oil-suspending agent of sulphur humulone imazethapyr (12+7)
The NPE of 12%+5% calcium dodecyl benzene sulfonate of triazole sulphur+7% imazethapyr of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+1.4% organobentonite of 4% castor oil polyoxyethylene ether+1.5%+oleic acid first Ester is supplied.
65th, the 28% triazole dispersible oil-suspending agent of sulphur humulone Arsenal (3+25)
The NPE+4% of 3%+5% calcium dodecyl benzene sulfonate of triazole sulphur+25% Arsenal of humulone+6% Fumed silica+10%150# the solvent naphthas of the organobentonite of castor oil polyoxyethylene ether+1.0%+1.0%+methyl oleate Supply.
66th, 42% triazole sulphur humulone trefanocide suspending agent (6+36)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+36% trefanocide of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.08% xanthans of 1.5% AEO+1.0%+water is supplied.
67th, 39% triazole sulphur humulone Amex820 suspending agent (3+36)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+36% Amex820 of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.1% xanthans of 1.5% AEO+0.8%+water is supplied.
68th, 38% triazole sulphur humulone ethalfluralin suspending agent (3+35)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 3%+35% ethalfluralin of triazole sulphur humulone+4% + 5% glycerine of aluminium-magnesium silicate of+0.1% xanthans of the AEO of powder+1.5%+1.0%+water is supplied.
69th, 28% triazole sulphur humulone oryzalin suspending agent (3+25)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 3%+25% oryzalin of triazole sulphur humulone+4% disperses + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the AEO of agent+1.5%+1.5%+water is supplied.
70th, 35% triazole sulphur humulone benfluralin suspending agent (6+29)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+29% benfluralin of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of 1.5% AEO+1.5%+water is supplied.
71st, 39% triazole sulphur humulone thiazopyr suspending agent (6+33)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+33% thiazopyr of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of 1.5% AEO+1.0%+water is supplied.
72nd, 39% triazole sulphur humulone pronamide suspending agent (6+33)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+33% pronamide of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.1% xanthans of 1.5% AEO+1.0%+water is supplied.
73rd, 53% triazole sulphur humulone Chlorthal suspension agent (3+50)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+50% chlorthal of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.06% xanthans of 1.5% AEO+0.5%+water is supplied.
74th, 58% triazole sulphur humulone butamifos suspending agent (3+55)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+55% butamifos of triazole sulphur humulone+4%+ + 5% glycerine of xanthans of 1.5% AEO+0.05%+water is supplied.
75th, 36% triazole sulphur humulone sulphur humulone suspending agent (6+30)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+30% sulphur humulone of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of 1.5% AEO+1.2%+water is supplied.
76th, 32% triazole sulphur humulone lancotrione suspending agents (24+8)
24% triazole sulphur humulone+8%lancotrione+4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinities + 5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of the AEO of powder+1.5%+1.2%+water is supplied.
77th, 24% triazole sulphur humulone benzene azoles fluorine humulone suspending agent (12+12)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of+12% benzene azoles fluorine humulone of 12% triazole sulphur humulone+4% + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the AEO of powder+1.5%+1.5%+water is supplied.
78th, the 11% triazole sulphur humulone dispersible oil-suspending agent of sulphonyl grass pyrazoles (9+2)
The NPE of+2%+5% calcium dodecyl benzene sulfonate of sulphonyl grass pyrazoles of 9% triazole sulphur humulone+6%+ Fumed silica+10%150# the solvent naphthas of+2.8% organobentonite of 4% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
79th, 32% triazole sulphur humulone tolpyralate suspending agents (12+20)
12% triazole sulphur humulone+20%tolpyralate+4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salts + 5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of the AEO of dispersant+1.5%+1.5%+water is supplied.
80th, 32% triazole sulphur humulone fenquinotrione suspending agents (12+20)
12% triazole sulphur humulone+20%fenquinotrione+4% phenethyl phenol polyethenoxy ether phosphate triethanolamines + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the AEO of dipersant+1.5%+1.5%+water is supplied.
81st, 18% triazole sulphur humulone isoxaflutole suspending agent (12+6)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+6% isoxaflutole of triazole sulphur humulone+4% + 5% glycerine of aluminium-magnesium silicate of+0.17% xanthans of the AEO of powder+1.5%+1.5%+water is supplied.
82nd, 31% triazole sulphur humulone fluorochloridone suspending agent (6+25)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 6%+25% fluorochloridone of triazole sulphur humulone+4% disperses + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the AEO of agent+1.5%+1.5%+water is supplied.
83rd, 22% triazole sulphur humulone flurtamone suspending agent (12+10)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 12%+10% flurtamone of triazole sulphur humulone+4% + 5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of+1.5% AEO+1.6%+water is supplied.
84th, 30% triazole sulphur humulone diflufenican suspending agent (12+18)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+18% diflufenican of triazole sulphur humulone+4% + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the AEO of powder+1.5%+1.5%+water is supplied.
85th, 29% triazole sulphur humulone fluorine pyrrole acyl grass amine suspending agent (12+17)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of+17% fluorine pyrrole acyl grass amine of 12% triazole sulphur humulone+4% + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the AEO of powder+1.5%+1.5%+water is supplied.
86th, 29% triazole sulphur humulone beflubutamid suspending agent (12+17)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+17% beflubutamid of triazole sulphur humulone+4% + 5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the AEO of powder+1.5%+1.5%+water is supplied.
87th, 40% triazole sulphur humulone norflurazon suspending agent (3+37)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+37% norflurazon of triazole sulphur humulone+4%+ + 5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of 1.5% AEO+1.2%+water is supplied.
88th, 52% triazole sulphur humulone fluridone water dispersible granules (2+50)
The disintegrant of 2%+6% pull open powder of triazole sulphur humulone+8% polycarboxylic acid salt's dispersant of+50% fluridone+1% gathers The precipitated silica of vinyl alcohol+5%+filler diatomite is supplied.
89th, 46% triazole sulphur humulone prosulfocarb suspension emulsion (2+44)
The phenethyl phenol polyethenoxy ether phosphate three of+44% prosulfocarb+5%150# solvent naphthas of 2% triazole sulphur humulone+3% The xanthans+5% of+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of ethanolamine salt dispersant+0.12% the third three Alcohol+water is supplied.
90th, 50% triazole sulphur humulone benfuresate suspension emulsion (3+47)
The phenethyl phenol polyethenoxy ether phosphate three of+47% benfuresate+5%150# solvent naphthas of 3% triazole sulphur humulone+3% The xanthans+5% of+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of ethanolamine salt dispersant+0.08% the third three Alcohol+water is supplied.
91st, 29% triazole sulphur humulone ethofumesate suspension emulsion (2.25+26.75)
The phenethyl phenol polyoxyethylene of+26.75% ethofumesate+10%150# solvent naphthas of 2.25% triazole sulphur humulone+3% The xanthan of+3% castor oil polyoxyethylene ether of ether phosphate triethanolamine+2% phenethyl phenol polyethenoxy ether of dipersant+0.12% The glycerine of glue+5%+water is supplied.
92nd, 28% triazole sulphur humulone tri-allate suspension emulsion (3+25)
The phenethyl phenol polyethenoxy ether phosphate three of+25% tri-allate+10%150# solvent naphthas of 3% triazole sulphur humulone+3% The xanthans+5% of+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of ethanolamine salt dispersant+0.15% the third three Alcohol+water is supplied.
93rd, 35% triazole sulphur humulone benthiocarb suspension emulsion (3+32)
The phenethyl phenol polyethenoxy ether phosphate three of+32% benthiocarb+5%150# solvent naphthas of 3% triazole sulphur humulone+3% The xanthans+5% of+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of ethanolamine salt dispersant+0.15% the third three Alcohol+water is supplied.
94th, 61% triazole sulphur humulone herbicide enemy's water dispersible granules (3+58)
The herbicide of 3% triazole sulphur humulone+58% opposes the poly- second of disintegrant of+6% pull open powder of+8% polycarboxylic acid salt's dispersant+1% The precipitated silica of enol+5%+filler diatomite is supplied.
95th, the special suspension emulsion (12+20) of 32% triazole sulphur humulone fourth grass
The phenethyl phenol polyethenoxy ether phosphate three of+20% fourth grass spy+5%150# solvent naphthas of 12% triazole sulphur humulone+3% The xanthans+5% of+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of ethanolamine salt dispersant+0.16% the third three Alcohol+water is supplied.
96th, 32% triazole sulphur humulone cycloate suspension emulsion (12+20)
The phenethyl phenol polyethenoxy ether phosphate three of+20% cycloate+5%150# solvent naphthas of 12% triazole sulphur humulone+3% The xanthans+5% of+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of ethanolamine salt dispersant+0.16% the third three Alcohol+water is supplied.
97th, 36% triazole sulphur humulone dimepiperate suspension emulsion (3+33)
The phenethyl phenol polyethenoxy ether phosphate three of+33% dimepiperate+10%150# solvent naphthas of 3% triazole sulphur humulone+3% The xanthans+5% of+3% castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of ethanolamine salt dispersant+0.15% the third three Alcohol+water is supplied.
98th, 70% triazole sulphur humulone esprocarb water dispersible granules (3+67)
The poly- second of disintegrant of 3%+6% pull open powder of triazole sulphur humulone+8% polycarboxylic acid salt's dispersant of+67% esprocarb+1% The precipitated silica of enol+5%+filler diatomite is supplied.
99th, the 28% different monooctyl ester suspension emulsion (9+19) of triazole sulphur humulone fluroxypyr
The different phenethyl phenol polyoxy second of monooctyl ester+20%150# solvent naphthas+3% of the fluroxypyr of 9% triazole sulphur humulone+19% + 2%+3% castor oil polyoxyethylene ether of phenethyl phenol polyethenoxy ether of alkene ether phosphate triethanolamine dipersant+0.12% is yellow The glycerine of virgin rubber+5%+water is supplied.
100th, 54% triazole sulphur humulone trichlopyr water dispersible granules (2.25+51.75)
The pull open powder of 2.25%+8% polycarboxylic acid salt's dispersant of triazole sulphur+51.75% trichlopyr of humulone+6%+ 1%+5% precipitated silica of disintegrant polyvinyl alcohol+filler diatomite is supplied.
101st, the 21% triazole dispersible oil-suspending agent of sulphur humulone clopyralid (9+12)
The NPE of 9%+5% calcium dodecyl benzene sulfonate of triazole sulphur+12% clopyralid of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+1.8% organobentonite of 4% castor oil polyoxyethylene ether+1.6%+oleic acid first Ester is supplied.
102nd, 43% triazole sulphur humulone picloram water dispersible granules (3+40)
The disintegrant of 3%+6% pull open powder of triazole sulphur humulone+8% polycarboxylic acid salt's dispersant of+40% picloram+1% The precipitated silica of polyvinyl alcohol+5%+filler diatomite is supplied.
103rd, the 23% triazole dispersible oil-suspending agent of sulphur humulone Mediben (9+14)
The NPE+4% of 9%+5% calcium dodecyl benzene sulfonate of triazole sulphur+14% Mediben of humulone+6% Fumed silica+10%150# the solvent naphthas of the organobentonite of castor oil polyoxyethylene ether+2.0%+2.5%+methyl oleate Supply.
104th, 28% triazole sulphur humulone 2-methyl-4-chlorophenoxyacetic acid water dispersible granules (9+19)
The 9% triazole sulphur humulone+19%2- methyl-pull open powder of the polycarboxylic acid salt of 4-chlorophenoxyacetic acid+8% dispersant+6%+ 1%+5% precipitated silica of disintegrant polyvinyl alcohol+filler diatomite is supplied.
105th, the 28% chloro- phenol second thioesters water dispersible granules (3+25) of triazole sulphur humulone 2- methyl -4-
The 3% chloro- polycarboxylic acid salt's dispersants+6% of phenol second thioesters+8% of triazole sulphur humulone+25%2- methyl -4- pull open + 5% precipitated silica of the disintegrant polyvinyl alcohol of powder+1%+filler diatomite is supplied.
106th, 26% triazole sulphur humulone MCPB water dispersible granules (3+23)
The disintegrant polyethylene of 3%+6% pull open powder of triazole sulphur humulone+23%MCPB+8% polycarboxylic acid salts dispersant+1% The precipitated silica of alcohol+5%+filler diatomite is supplied.
107th, 25% triazole sulphur humulone 2- methyl -4- chlorine phenoxy propionic acid water dispersible granules (3+22)
The pull open powder of 3%+8% polycarboxylic acid salt's dispersant of triazole sulphur humulone+22%2- methyl -4- chlorine phenoxy propionic acids+6%+ 1%+5% precipitated silica of disintegrant polyvinyl alcohol+filler diatomite is supplied.
108th, 25% triazole sulphur humulone 2-methyl-4-chlorophenoxyacetic acid sodium water dispersible granules (3+22)
The 3% triazole sulphur humulone+22%2- methyl-pull open powder of+8% polycarboxylic acid salt's dispersant of 4-chlorophenoxyacetic acid sodium+6% + 1%+5% precipitated silica of disintegrant polyvinyl alcohol+filler diatomite is supplied.
109th, the 35% different monooctyl ester suspension emulsion (3+32) of triazole sulphur humulone 2-methyl-4-chlorophenoxyacetic acid
The 3% triazole sulphur humulone+32%2- methyl-different phenethyl phenol of monooctyl ester+5%150# solvent naphthas+3% of 4-chlorophenoxyacetic acid The castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of polyoxyethylene ether phosphate triethanolamine dipersant+3%+ 0.12%+5% glycerine of xanthans+water is supplied.
110th, 15% triazole sulphur humulone 2,4 dichloro benzene ethoxyacetic acid butyl ester suspension emulsion (3+12)
The phenethyl phenol of 3% triazole sulphur humulone+12%2,4- dichlorophenoxyacetic acid butyl ester+10%150# solvent naphthas+3% is gathered The castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of oxygen ethene ether phosphate triethanolamine salt dispersant+3%+ 0.18%+5% glycerine of xanthans+water is supplied.
111st, 17% triazole sulphur humulone 2, the different monooctyl ester suspension emulsion (3+14) of 4- dichlorphenoxyacetic acids
3% triazole sulphur humulone+14%2, the different phenethyl phenol of monooctyl ester+10%150# solvent naphthas+3% of 4- dichlorphenoxyacetic acids are gathered The castor oil polyoxyethylene ether of+2% phenethyl phenol polyethenoxy ether of oxygen ethene ether phosphate triethanolamine salt dispersant+3%+ 0.22%+5% glycerine of xanthans+water is supplied.
112nd, 12% triazole sulphur humulone 2, the dispersible oil-suspending agent of 4- dichlorphenoxyacetic acids (3+9)
3% triazole sulphur humulone+9%2, the polyoxyethylene nonyl phenyl second of+5% calcium dodecyl benzene sulfonate of 4- dichlorphenoxyacetic acids+6% Fumed silica+10%150# the solvent naphthas of+3.0% organobentonite of+4% castor oil polyoxyethylene ether of alkene ether+2.5%+ Methyl oleate is supplied.
113rd, the 12% triazole sulphur humulone 4- dispersible oil-suspending agents of (2,4 dichloro benzene epoxide) propionic acid (3+9)
The nonyl phenol of 3% triazole sulphur humulone+9%4- (2,4 dichloro benzene epoxide) calcium dodecyl benzene sulfonate of propionic acid+5%+6% Fumed silica+the 10%150# of+3.0% organobentonite of the castor oil polyoxyethylene ether of APEO+4%+2.5% is molten Agent oil+methyl oleate is supplied.
114th, 27% triazole sulphur humulone quinmerac suspending agent (9+18)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 9%+18% quinmerac of triazole sulphur humulone+4% + 5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of the AEO of powder+1.5%+1.5%+water is supplied.
115th, 28% triazole sulphur humulone cinmethylin suspending agent (24+4)
The phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 24%+4% cinmethylin of triazole sulphur humulone+4% disperses + 5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of the AEO of agent+1.5%+1.5%+water is supplied.
116th, 38% triazole sulphur humulone sulphosate water dispersible granules (1.5+36.5)
The disintegrant of 1.5%+6% pull open powder of triazole sulphur humulone+8% polycarboxylic acid salt's dispersant of+36.5% sulphosate+1% The precipitated silica of polyvinyl alcohol+5%+filler diatomite is supplied.
117th, 30% triazole sulphur humulone bialaphos water dispersible granules (2.25+27.75)
The pull open powder+1% of 2.25%+8% polycarboxylic acid salt's dispersant of triazole sulphur+27.75% bialaphos of humulone+6% collapses + 5% precipitated silica of solution agent polyvinyl alcohol+filler diatomite is supplied.
118th, 35% triazole sulphur humulone essence glufosinate-ammonium water dispersible granules (4.5+30.5)
+ 30.5% smart pull open powder+1% of the polycarboxylic acid salt of glufosinate-ammonium+8% dispersant+6% disintegration of 4.5% triazole sulphur humulone + 5% precipitated silica of agent polyvinyl alcohol+filler diatomite is supplied.
119th, 45% triazole sulphur humulone paraquat water dispersible granules (4.5+40.5)
The disintegrant of 4.5%+6% pull open powder of triazole sulphur humulone+8% polycarboxylic acid salt's dispersant of+40.5% paraquat+1% The precipitated silica of polyvinyl alcohol+5%+filler diatomite is supplied.
120th, 40% triazole sulphur humulone diquat dibromide water dispersible granules (4.5+35.5)
The disintegrant of 4.5%+6% pull open powder of triazole sulphur humulone+8% polycarboxylic acid salt's dispersant of+35.5% diquat dibromide+1% The precipitated silica of polyvinyl alcohol+5%+filler diatomite is supplied.
121st, the 26% triazole dispersible oil-suspending agent of sulphur humulone Thistrol (3+23)
The NPE of 3%+5% calcium dodecyl benzene sulfonate of triazole sulphur+23%2 mcpb 2 of humulone+6%+ Fumed silica+10%150# the solvent naphthas of+2.8% organobentonite of 4% castor oil polyoxyethylene ether+2.5%+oleic acid first Ester is supplied.
122nd, 20% triazole sulphur humulone 2, the dispersible oil-suspending agent of 4- Embutoxs (4.5+15.5)
4.5% triazole sulphur humulone+15.5%2, the polyoxyethylene nonyl phenyl second of+5% calcium dodecyl benzene sulfonate of 4- Embutoxs+6% Fumed silica+10%150# the solvent naphthas of+2.8% organobentonite of+4% castor oil polyoxyethylene ether of alkene ether+2.5%+ Methyl oleate is supplied.
Above-mentioned aqueous suspension agent process equipment:Mixing kettle, colloid mill, sand mill, cutter etc..
Above-mentioned aqueous suspension agent process:By all materials put into mixing kettle in, after being stirred cross colloid mill, it is laggard Enter sand mill three-level sanding, finally sheared in cutter uniformly, after chemical examination is qualified, it is filling to be transferred to storage tank.
Above-mentioned dispersible oil-suspending agent process equipment:Mixing kettle, colloid mill, sand mill, cutter etc..
Above-mentioned dispersible oil-suspending agent process:All materials are put into mixing kettle, colloid mill is crossed after being stirred, Enter sand mill three-level sanding afterwards, finally sheared in cutter uniformly, after chemical examination is qualified, it is filling to be transferred to storage tank.
Above-mentioned water dispersible granules process equipment:Airslide disintegrating mill, coulter type mixer, basket comminutor, drying box, screening Machine etc..
Above-mentioned water dispersible granules process:Above-mentioned material was well mixed air-flow crushing, adds water to enter to mediate granulation, it After dry, final sizing obtains finished product.
Above-mentioned suspension emulsion process equipment:Mixing kettle, colloid mill, sand mill, cutter etc..
Above-mentioned suspension emulsion process:Aqueous phase material is put into mixing kettle, colloid mill is crossed after being stirred, is entered afterwards Sand mill three-level sanding, finally sheared in cutter uniformly, it is standby to chemically examine qualified rear transfer；Oil phase material is put into mixing kettle In, add solvent naphtha and emulsifying agent, stirring and dissolving are uniform；Aqueous phase material is added in cutting kettle afterwards, and under shearing condition, Oil phase material is slowly pumped into cutting kettle, sheared in Chou Liao, continues shearing uniformly, after chemical examination is qualified, is transferred to storage tank filling Dress.B) the test of pesticide effectiveness
After seedling cauline leaf spraying treatment:
1) experimental condition
1.1), for trying target
Descurainia sophia picks up from Taian Shandong, and barnyard grass picks up from Lujiang, Anhui, and ox chickweed picks up from Jiangsu Xinghua, and above-mentioned weeds use basin Hydroponics culture, with 180 х 140mm plastic nutrition bowls, it is placed in enamel tray, it is built-in that the top layer for backing through and air-drying sieving is adopted from farmland Soil (at 4/5), soil moisture control 20%, select the homogeneous weed seed of full seed, soaked with 25 DEG C of warm water initial stages Bubble 6 hours, the vernalization in 28 DEG C of biochemical cultivation cases (dark), soil surface is uniformly placed in by the weed seed just to have showed money or valuables one carries unintentionally, According to seed particle size size and then earthing 0.5-1cm.
1.2), condition of culture
Carried out in controllable heliogreenhouse, 20~30 DEG C of temperature, natural lighting, relative humidity 57%~72%.
Soil types is loam, the content of organic matter 1.63%, pH=7.1, alkali-hydrolyzable nitrogen 84.3mg/kg, rapid available phosphorus 38.5mg/kg, available potassium 82.1mg/kg.
1.3), instrument and equipment
3WP-2000 type walking spray towers, Nanjing Agricultural Machinery Inst., Ministry of Agriculture.GA10 type a ten thousandth electronics day Flat (Germany)；ZDR2000 intelligent datas recorder (Hangzhou Ze great Instrument Ltd.)；SPX type Intelligent biochemistry incubators (Ningbo South of the River instrument plant).
2) experimental design
2.1), reagent
2.1.1), test medicine
Required active component B is bought by Reagent Company, and A produces for our company.
Active compound uses acetone as solvent, is diluted with the aqueous solution of 0.1% emulsifier tween of content -80, current existing dilution.
2.2), test process
2.2.1), dosage is set
It is determined that A and active component B are matched or during contents, should be weighed from the action character of two kinds of medicaments and its virulence etc., It is also contemplated that the main application target of the formula.This research is on the basis of prerun early stage, if A, B activity composition are alone and mix Dosage is shown in Table lattice respectively.Blank control is used as using the water without medicament, containing same solvent and emulsifying agent.
2.2.2), experiment repeats
Often processing is repeated 4 times, and often handles 3 basins every time, and per basin, sowing weed seed 20, often handles totally 60 plants.
2.3), processing mode
2.3.1), processing time and number
Experiment shares medicine 1 time.Treat the leaf phase of weeds 2, thinning, keep 15 plants of weeds in per basin, often processing retains 45 plants, then Continue culture to Descurainia sophia, barnyard grass, the leaf of ox chickweed 3 to be handled.
2.3.2), using apparatus and administrated method
Cultured examination material is uniformly placed in area 0.5m2Platform on, with 3WP-2000 type walking spray tower stems Foliar spray mist, spouting liquid is based on 30 kilograms/hectare.Atomisation pressure 0.3MPa.After whole liquid medicine jets are complete, air valve is closed, after 30 seconds, Spraying pyller is opened, takes out nutritive cube.Then air valve is opened, sprays clear water 50mL, cleans sparge pipe.
3) test method
Using pot-culture method.Weeds culture is shown in 1.1, reference《Farm-chemical indoor determination test rule herbicide》Carry out.With Prescription method is shown in 2.3.2, using cauline leaf process method.Greenhouse cellar culture is moved into after processing, 1-2cm water is remained during experiment Layer.
4) data survey and statistical analysis
4.1), investigation method
Using absolute number investigation method, the survival whole strain seedling of weeds is cut off along soil surface with blade, is weighed with assay balance Weeds fresh weight.It is based on zero by fresh weight for dead weeds.
4.2), control time and number
Investigate within 20 days after processing, investigate 1 time altogether.
4.3), data statistic analysis
The theoretical fresh weight inhibition (E0=X+Y-X*Y/100) of each processing hybrid combining, Ran Houyu are calculated with Gowing methods Actual measurement inhibiting rate (E) compares, the two mixed synergy type to weeds of evaluation, is that synergy is made when E-E0 values are more than 10% With, less than -10% be antagonism, be addition between -10%~10%.It is and special according to actual preventive effect and herbicide The factors such as point, the balance being formulated determine optimum proportioning.
X is fresh weight inhibition when active components A dosage is P in formula；Y is that fresh weight when active component B dosages are Q suppresses Rate.
Closed soil treatment:
1) experimental condition
1.1), for trying target
Descurainia sophia picks up from Taian Shandong, and barnyard grass picks up from Lujiang, Anhui, and ox chickweed picks up from Jiangsu Xinghua.
1.2), condition of culture
Carried out in controllable heliogreenhouse, 20~30 DEG C of temperature, natural lighting, relative humidity 57%~72%.
Soil types is loam, the content of organic matter 1.63%, pH=7.1, alkali-hydrolyzable nitrogen 84.3mg/kg, rapid available phosphorus 38.5mg/kg, available potassium 82.1mg/kg.Experiment soil is quantitatively filled at the 3/4 of basin alms bowl, is then poured from basin alms bowl bottom, is made soil Earth moistens to saturation state completely.By pretreatment for examination weed seed, equal and quantitative broadcasts sowing surface, according to seed size earthing 0.5-2cm, after planting 24 hours standby.
1.3), instrument and equipment
GA10 type a ten thousandth electronic balances (Germany)；ZDR2000 intelligent datas recorder (the limited public affairs of the big instrument in Hangzhou pool Department)；SPX type Intelligent biochemistries incubator (Ningbo south of the River instrument plant), pipettor etc..
2) experimental design
2.1), reagent
2.1.1), test medicine
Required active component B is commercially available active compound, and A produces for our company.
Active compound uses acetone as solvent, is diluted with the emulsifying agent T-80 aqueous solution of content 0.1%, current existing dilution.
2.2), test process
2.2.1), dosage is set
, should be from the action character of two kinds of medicaments and its virulence etc. it is determined that when A and active component B each groups distribution ratio or content Weigh, it is also contemplated that the main application target of the formula.This research is on the basis of prerun early stage, if A, B activity composition are alone And mixing dosage is shown in Table lattice respectively.Blank control is used as using the water without medicament, containing same solvent and emulsifying agent.
2.2.2), experiment repeats
Often processing is repeated 4 times, and often handles 3 basins every time, the sowing weed seed 30 per basin.
2) test method
Before processing is poured, and keeps 1-2cm water layers.Quantitative liquid medicine is taken with pipettor, according to experimental design from low dosage to height Dosage carries out pouring processing, 4 repetitions per treatment respectively；Greenhouse cellar culture is moved into after processing, is remained during experiment 1-2cm water layers.
3) data survey and statistical analysis
It is identical with after seedling cauline leaf spraying treatment, therefore repeat no more.
Statistical result see the table below 1-125.
Table 1A is with S-metolachlor mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 2A is with flufenacet mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 3A is with napropamide mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 4A is with the clever mixture of sulphur grass to the actual preventive effect of barnyard grass and synergy evaluation (cauline leaf process)
Table 5A is with sulfone pyrrole grass azoles mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 6A is with xylenol grass amine mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 7A is with cafenstrole mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 8A is with propisochlor mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 9A is with metazachlor mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 10A is with propachlor mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 11A is with pethoxamid mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 12A is with fomesafen mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 13A is with flumioxazin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 14A is with tiafenacil mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 15A is with benzene flumetsulam mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 16A is with pyraflufen-ethyl mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 17A is with atrazine mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 18A is with terbutryn mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 19A is with ametryn mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 20A is with dipropetryn mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 21A is with the net mixture of evil grass to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 22A is with desmetryn mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 23A is with Simanex mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 24A is with metribuzin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 25A is with ethiozin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 26A is with metamitron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 27A is with cyanazine mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 28A is with chlortoluron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 29A is with diuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 30A is with fluometuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 31A is with linuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 32A is with tebuthiuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 33A is with afesin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 34A is with metobromuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 35A is with neburea mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 36A is with alcohol pyridazines mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 37A is with hexazinone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 38A is with dimethametryn mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 39A is with trietazine mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 40A is with lenacil mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 41A is with terbacil mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 42A is with methabenzthiazuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 43A is with Tupersan mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The table 44A grand mixtures of Yu Yi Evil are to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 45A is with metoxuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 46A is with chloroxifenidium mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 47A is with trifluoro grass piperazine mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 48A is with desmedipham mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 49A is with phenmedipham mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 50A is with tribenuron-methyl mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 51A is with thifensulfuronmethyl mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 52A is with the grand mixture of thiophene ketone sulphur to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 53A is with rimsulfuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 54A is with flucarbazone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 55A is with mesosulfuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 56A is with nicosulfuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 57A is with foramsulfuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 58A is with Flumetsulam mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 59A is with fluorine ketone sulphur grass amine mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 60A is with cloransulammethyl mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 61A is with pyroxsulam mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 62A is with imazamox mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 63A is with AC 263222 mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 64A is with imazethapyr mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 65A is with Arsenal mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 66A is with trefanocide mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 67A is with Amex820 mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 68A is with ethalfluralin mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 69A is with oryzalin mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 70A is with benfluralin mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 71A is with thiazopyr mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 72A is with pronamide mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 73A is with chlorthal mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 74A is with butamifos mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 75A is with sulphur humulone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 76A is with lancotrione mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 77A is with benzene azoles fluorine humulone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 78A is with sulphonyl grass pyrazoles mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 79A is with tolpyralate mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 80A is with fenquinotrione mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 81A Yu isoxaflutoles mixtures are to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 82A is with fluorochloridone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 83A is with flurtamone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 84A is with diflufenican mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 85A is with fluorine pyrrole acyl grass amine mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 86A is with beflubutamid mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 87A is with norflurazon mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 88A is with fluridone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 89A and the actual preventive effect of barnyard grass of prosulfocarb mixture pair and synergy evaluation (soil treatment)
Table 90A is with benfuresate mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 91A is with ethofumesate mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 92A is with tri-allate mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 93A is with benthiocarb mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 94A is with vernolate mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 95A is with the special mixture of fourth grass to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 96A is with cycloate mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 97A is with dimepiperate mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 98A is with esprocarb mixture to the actual preventive effect of barnyard grass and synergy evaluation (soil treatment)
Table 99A is evaluated (at cauline leaf the actual preventive effect of ox chickweed and synergy with the different monooctyl ester mixture of fluroxypyr Reason)
Table 100A is with trichlopyr mixture to the actual preventive effect of ox chickweed and synergy evaluation (cauline leaf process)
Table 101A is with clopyralid mixture to the actual preventive effect of ox chickweed and synergy evaluation (cauline leaf process)
Table 102A is with picloram mixture to the actual preventive effect of ox chickweed and synergy evaluation (cauline leaf process)
Table 103A is with Mediben mixture to the actual preventive effect of ox chickweed and synergy evaluation (cauline leaf process)
Table 104A evaluates (cauline leaf with 2-methyl-4-chlorophenoxyacetic acid mixture to the actual preventive effect of Descurainia sophia and synergy Processing)
Table 105A evaluates (stem with 2- methyl -4- chlorophenols second thioesters mixture to the actual preventive effect of Descurainia sophia and synergy Leaf processing)
Table 106A is with MCPB mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 107A evaluates (cauline leaf with 2- methyl -4- chlorine phenoxy propionic acid mixtures to the actual preventive effect of Descurainia sophia and synergy Processing)
Table 108A evaluates (stem with 2-methyl-4-chlorophenoxyacetic acid sodium mixture to the actual preventive effect of Descurainia sophia and synergy Leaf processing)
Table 109A is evaluated the actual preventive effect of Descurainia sophia and synergy with the different monooctyl ester mixture of 2-methyl-4-chlorophenoxyacetic acid (cauline leaf process)
Table 110A and 2,4- dichlorobenzene oxygen butyl acetate mixture evaluate (cauline leaf to the actual preventive effect of Descurainia sophia and synergy Processing)
Table 111A and the different monooctyl ester mixture of 2,4- dichlorphenoxyacetic acid evaluate (stem to the actual preventive effect of Descurainia sophia and synergy Leaf processing)
Table 112A is evaluated (at cauline leaf the actual preventive effect of Descurainia sophia and synergy with 2,4 dichloro benzene ethoxyacetic acid mixture Reason)
Table 113A evaluates (stem with 4- (2,4 dichloro benzene epoxide) propionic acid mixtures to the actual preventive effect of Descurainia sophia and synergy Leaf processing)
Table 114A is with quinmerac mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 115A is with cinmethylin mixture to the actual preventive effect of barnyard grass and synergy evaluation (cauline leaf process)
Table 116A is with sulphosate mixture to the actual preventive effect of barnyard grass and synergy evaluation (cauline leaf process)
Table 117A is with bialaphos mixture to the actual preventive effect of barnyard grass and synergy evaluation (cauline leaf process)
Table 118A is with smart glufosinate-ammonium mixture to the actual preventive effect of barnyard grass and synergy evaluation (cauline leaf process)
Table 119A is with paraquat mixture to the actual preventive effect of barnyard grass and synergy evaluation (cauline leaf process)
Table 120A is with diquat dibromide mixture to the actual preventive effect of barnyard grass and synergy evaluation (cauline leaf process)
Table 121A is with Thistrol mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 122A is with 2,4- Embutoxs mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
C) field demonstration
Utilize embodiment 1) -122) made from herbicidal composition carry out weeds in field effect test.
Exemplary promote is carried out in Jiangsu Xinghua testing site within 2016 to test.The weeds that field occurs mainly have:Barnyard grass, thousand Gold, Monochoria vaginalis, difformed galingale herb etc..
Test method:
Soil treatment:Before weeds germinate, hand sprayer, 45 kilograms/667m of the amount of being watered2, it is uniform using soil surface Spraying.
Cauline leaf process:Treat that weeds are in 3-4 leaf phases, hand sprayer, 30 kilograms/667m of the amount of being watered2, sprayed using cauline leaf Even spraying.
Specific test medicine and dosage refer to table 123,50 square metres of plot area, and often processing is repeated 4 times.45 days after dispenser Investigation preventive effect is shown in Table 123.
By lot of experiments and exploration, it is an unexpected discovery of the invention that the composition is used to prevent and kill off barnyard grass, moleplant seed, broadcast The weeds such as ma wormwood artemisia, ox chickweed, Monochoria vaginalis, difformed galingale herb, there is surprising, unexpected synergistic effect, this synergy Act under low dosage and show more notable, dosage can be reduced, reduce the pollution to environment, and rationally compounding reduce it is agricultural Cost, it is efficient to ALS, ACCase inhibitor resistant weed, there is good application prospect.Simultaneously by test wheat paddock, Corn field, rice terrace, peanut, sugarcane, sorghum, millet, potato, rape, soybean, cotton, vegetables, annual bluegrass, Festuca Arundinacea, knot The lawns such as thread grass and crop show good selectivity and excellent synergistic effect, can develop into the weeding of extensive market value Agent mixture.
The field demonstration effect situation of complex composition described in table 123

Claims (10)

1. a kind of Herbicidal combinations of the humulone of sulphur containing triazole, it is characterised in that active components A and activity including herbicidally effective amount Composition B, wherein, active components A is triazole sulphur humulone, and active component B may be selected from the one or more of following compound：
(1) VLCFA inhibitor：It is S-metolachlor, flufenacet, napropamide, sulfone pyrrole grass azoles, xylenol grass amine, cafenstrole, different Pretilachlor, metazachlor, propachlor, pethoxamid；
(2) PPO inhibitor：Fomesafen, flumioxazin, tiafenacil, benzene flumetsulam, pyraflufen-ethyl；
(3) PSII inhibitor：Atrazine, terbutryn, ametryn, dipropetryn, evil grass are net, desmetryn, Simanex, metribuzin, second Metribuzin, metamitron, cyanazine, chlortoluron, diuron, fluometuron, linuron, tebuthiuron, afesin, metobromuron, grass are not Grand, alcohol pyridazines, hexazinone, dimethametryn, trietazine, lenacil, terbacil, methabenzthiazuron, Tupersan, Yi Evil are grand, methoxy Grand, chloroxifenidium, trifluoro grass piperazine, desmedipham, phenmedipham；
(4) ALS inhibitor：Tribenuron-methyl, thifensulfuronmethyl, thiophene ketone sulphur are grand, rimsulfuron, flucarbazone, mesosulfuron, the phonetic sulphur of cigarette Grand, foramsulfuron, Flumetsulam, fluorine ketone sulphur grass amine, cloransulammethyl, pyroxsulam, imazamox, first imidazoles cigarette Acid, imazethapyr, Arsenal；
(5) microtubules inhibitor：Trefanocide, Amex820, ethalfluralin, oryzalin, benfluralin, thiazopyr, pronamide, Chlorthal, butamifos；
(6) HPPD inhibitor：Sulphur humulone, lancotrione, benzene azoles fluorine humulone, sulphonyl grass pyrazoles, tolpyralate, Fenquinotrione, isoxaflutoles；
(7) PDS inhibitor：Fluorochloridone, flurtamone, diflufenican, fluorine pyrrole acyl grass amine, beflubutamid, norflurazon, fluorine pyridine Humulone；
(8) lipid synthesis (non-acetyl-CoA carboxylase) inhibitor：Prosulfocarb, benfuresate, ethofumesate, tri-allate, herbicide Pellet, herbicide enemy, Ding Caote, cycloate, dimepiperate, esprocarb；
(9) synthetic hormone class：The different monooctyl ester of fluroxypyr, trichlopyr, clopyralid, picloram, wheat straw Fear, 2-methyl-4-chlorophenoxyacetic acid, the chloro- phenol second thioesters of 2- methyl -4-, MCPB, 2- methyl -4- chlorine phenoxy propionic acid, 2- first Base -4-chlorophenoxyacetic acid sodium, the different monooctyl ester of 2-methyl-4-chlorophenoxyacetic acid, 2,4 dichloro benzene ethoxyacetic acid butyl ester, 2,4 dichloro benzene The different monooctyl ester of fluoroacetic acid, 2,4 dichlorophenoxyacetic acid, 4- (2,4 dichloro benzene epoxide) propionic acid, quinmerac, Thistrol, 2, 4- Embutoxs；
(10) EPSPS inhibitor：Sulphosate；
(11) GS inhibitor：Bialaphos, smart glufosinate-ammonium；
(12) PSI inhibitor：Paraquat, diquat dibromide；
(13) DHP inhibitor：Sulphur grass spirit；
(14) other：Cinmethylin.
A kind of 2. Herbicidal combinations of humulone of sulphur containing triazole according to claim 1, it is characterised in that A and B weight ratio For 1: 200-200: 1, preferably 1: 150-150: 1.
A kind of 3. Herbicidal combinations of humulone of sulphur containing triazole according to claim 2, it is characterised in that A and B weight ratio For 1: 100-100: 1, preferably 1: 50-50: 1.
A kind of 4. Herbicidal combinations of humulone of sulphur containing triazole according to claim 3, it is characterised in that A and B weight ratio For 1: 30-30: 1, preferably 1: 10-10: 1.
A kind of 5. Herbicidal combinations of humulone of sulphur containing triazole according to Claims 1-4 any one, it is characterised in that A and B weight/mass percentage composition accounts for the 1-95% of total amount in the Herbicidal combinations.
A kind of 6. Herbicidal combinations of humulone of sulphur containing triazole according to claim 5, it is characterised in that the Herbicidal combination A and B weight/mass percentage composition accounts for the 10-80% of total amount in thing.
A kind of 7. Herbicidal combinations of humulone of sulphur containing triazole according to claim 1 to 6 any one, it is characterised in that Also include carrier, surfactant in the Herbicidal combinations.
A kind of 8. Herbicidal combinations of humulone of sulphur containing triazole according to claim 1 to 6 any one, it is characterised in that The specific preparation of the Herbicidal combinations is dispersible oil-suspending agent, aqueous suspension agent, suspension emulsion, wettable powder, missible oil, moisture Shot agent, aqueous emulsion or microemulsion.
A kind of 9. Herbicidal combinations of humulone of sulphur containing triazole according to claim 1 to 6 any one, it is characterised in that The Herbicidal combinations further comprise safener, and it is selected from isoxadifen, cyprosulfamide, mefenpyrdiethyl, solution One or more in malicious quinoline, gibberellic acid, furilazole, metcamifen.
10. the Herbicidal combinations of the humulone of sulphur containing triazole injurious weed in crop is prevented and treated as described in claim 1 to 9 any one On application.
CN201711095793.XA 2017-11-09 2017-11-09 Weeding composition containing triazasulam and application thereof Active CN107836452B (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN202110266478.9A CN112998022B (en) 2017-11-09 2017-11-09 Weeding composition containing triazasulam and application thereof
CN201711095793.XA CN107836452B (en) 2017-11-09 2017-11-09 Weeding composition containing triazasulam and application thereof
PCT/CN2017/112016 WO2019090814A1 (en) 2017-11-09 2017-11-21 Weeding composition with triazole sulcotrione and application thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711095793.XA CN107836452B (en) 2017-11-09 2017-11-09 Weeding composition containing triazasulam and application thereof

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN202110266478.9A Division CN112998022B (en) 2017-11-09 2017-11-09 Weeding composition containing triazasulam and application thereof

Publications (2)

Publication Number Publication Date
CN107836452A true CN107836452A (en) 2018-03-27
CN107836452B CN107836452B (en) 2021-03-05

Family

ID=61682542

Family Applications (2)

Application Number Title Priority Date Filing Date
CN202110266478.9A Active CN112998022B (en) 2017-11-09 2017-11-09 Weeding composition containing triazasulam and application thereof
CN201711095793.XA Active CN107836452B (en) 2017-11-09 2017-11-09 Weeding composition containing triazasulam and application thereof

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CN202110266478.9A Active CN112998022B (en) 2017-11-09 2017-11-09 Weeding composition containing triazasulam and application thereof

Country Status (2)

Country Link
CN (2) CN112998022B (en)
WO (1) WO2019090814A1 (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108283185A (en) * 2018-04-05 2018-07-17 合肥红佳科技信息有限公司 A kind of Herbicidal combinations containing dichloroquinoline humulone
CN108432769A (en) * 2018-05-08 2018-08-24 江西正邦生物化工有限责任公司 A kind of composition pesticide of humulone containing quinoline and benzene flumetsulam
CN109006854A (en) * 2018-11-01 2018-12-18 山东省农业科学院植物保护研究所 A kind of binary herbicidal composition and its preparation and the application of humulone containing quinoline and mesosulfuron
CN109105381A (en) * 2018-11-01 2019-01-01 山东省农业科学院植物保护研究所 A kind of binary herbicidal composition and its preparation and the application of humulone containing quinoline and flucarbazone
CN109452300A (en) * 2019-01-11 2019-03-12 安徽省农业科学院植物保护与农产品质量安全研究所 A kind of ternary weeding composition and its application containing halosulfuronmethyl
CN109479888A (en) * 2018-12-19 2019-03-19 青岛清原化合物有限公司 Ternary weeding composition and its application comprising cyclopyrimorate
CN109497075A (en) * 2018-12-19 2019-03-22 青岛清原化合物有限公司 Ternary weeding composition and its application comprising trifludimoxazin
CN109526973A (en) * 2018-12-14 2019-03-29 青岛清原化合物有限公司 Ternary weeding composition and its application comprising sulfone pyrrole grass azoles
CN111820225A (en) * 2019-04-22 2020-10-27 江苏清原农冠杂草防治有限公司 Herbicidal composition containing 3-aryl-6-trifluoromethylpyridazinol compound and application thereof
CN113387926A (en) * 2020-03-13 2021-09-14 沈阳中化农药化工研发有限公司 Heterocyclic carboxylic ester compound and application thereof as herbicide
WO2022068377A1 (en) * 2020-09-30 2022-04-07 青岛清原化合物有限公司 Binary herbicidal composition and use thereof
WO2022078494A1 (en) * 2020-10-15 2022-04-21 安道麦阿甘有限公司 Herbicide mixture, herbicidal composition, method for preventing undesired vegetation and kit

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023233367A1 (en) * 2022-06-03 2023-12-07 Adama Agan Ltd. Herbicidal mixtures for crop protection
WO2024002741A1 (en) * 2022-06-29 2024-01-04 Basf Se Herbicidal mixtures comprising l-glufosinate or its salt and a second herbicide

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106946783A (en) * 2017-04-19 2017-07-14 青岛清原化合物有限公司 Triazole sulphur humulone C crystal form and its production and use
CN106977458A (en) * 2017-04-19 2017-07-25 青岛清原化合物有限公司 Amorphous state triazole sulphur humulone and its production and use
CN107033086A (en) * 2017-04-19 2017-08-11 青岛清原化合物有限公司 Triazole sulphur humulone B crystal form and its production and use

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105724390B (en) * 2016-04-28 2017-12-22 青岛清原抗性杂草防治有限公司 A kind of herbicide composition for paddy fields and its application
CN106922676A (en) * 2017-03-10 2017-07-07 合肥星宇化学有限责任公司 Ring sulphur ketone and triazole sulphur humulone complex herbicidal composition and its preparation and application
CN106879598A (en) * 2017-03-26 2017-06-23 滁州学院 Composition pesticide and its application of a kind of humulone of sulphur containing triazole and fluroxypyr
CN113180051A (en) * 2017-09-19 2021-07-30 青岛清原抗性杂草防治有限公司 Weeding composition containing triazasulam and application thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106946783A (en) * 2017-04-19 2017-07-14 青岛清原化合物有限公司 Triazole sulphur humulone C crystal form and its production and use
CN106977458A (en) * 2017-04-19 2017-07-25 青岛清原化合物有限公司 Amorphous state triazole sulphur humulone and its production and use
CN107033086A (en) * 2017-04-19 2017-08-11 青岛清原化合物有限公司 Triazole sulphur humulone B crystal form and its production and use

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108283185A (en) * 2018-04-05 2018-07-17 合肥红佳科技信息有限公司 A kind of Herbicidal combinations containing dichloroquinoline humulone
CN108432769A (en) * 2018-05-08 2018-08-24 江西正邦生物化工有限责任公司 A kind of composition pesticide of humulone containing quinoline and benzene flumetsulam
CN109006854A (en) * 2018-11-01 2018-12-18 山东省农业科学院植物保护研究所 A kind of binary herbicidal composition and its preparation and the application of humulone containing quinoline and mesosulfuron
CN109105381A (en) * 2018-11-01 2019-01-01 山东省农业科学院植物保护研究所 A kind of binary herbicidal composition and its preparation and the application of humulone containing quinoline and flucarbazone
WO2020118754A1 (en) * 2018-12-14 2020-06-18 青岛清原化合物有限公司 Ternary weeding composition containing pyroxasulfone and use thereof
CN109526973A (en) * 2018-12-14 2019-03-29 青岛清原化合物有限公司 Ternary weeding composition and its application comprising sulfone pyrrole grass azoles
CN109497075A (en) * 2018-12-19 2019-03-22 青岛清原化合物有限公司 Ternary weeding composition and its application comprising trifludimoxazin
CN109479888A (en) * 2018-12-19 2019-03-19 青岛清原化合物有限公司 Ternary weeding composition and its application comprising cyclopyrimorate
CN109452300A (en) * 2019-01-11 2019-03-12 安徽省农业科学院植物保护与农产品质量安全研究所 A kind of ternary weeding composition and its application containing halosulfuronmethyl
CN111820225A (en) * 2019-04-22 2020-10-27 江苏清原农冠杂草防治有限公司 Herbicidal composition containing 3-aryl-6-trifluoromethylpyridazinol compound and application thereof
CN111820225B (en) * 2019-04-22 2022-04-05 江苏清原农冠杂草防治有限公司 Herbicidal composition containing 3-aryl-6-trifluoromethylpyridazinol compound and application thereof
CN113387926A (en) * 2020-03-13 2021-09-14 沈阳中化农药化工研发有限公司 Heterocyclic carboxylic ester compound and application thereof as herbicide
CN113387926B (en) * 2020-03-13 2023-12-12 沈阳中化农药化工研发有限公司 Heterocyclic carboxylic ester compound and application thereof as herbicide
WO2022068377A1 (en) * 2020-09-30 2022-04-07 青岛清原化合物有限公司 Binary herbicidal composition and use thereof
WO2022078494A1 (en) * 2020-10-15 2022-04-21 安道麦阿甘有限公司 Herbicide mixture, herbicidal composition, method for preventing undesired vegetation and kit

Also Published As

Publication number Publication date
WO2019090814A1 (en) 2019-05-16
CN107836452B (en) 2021-03-05
CN112998022A (en) 2021-06-22
CN112998022B (en) 2021-09-21

Similar Documents

Publication Publication Date Title
CN107836452A (en) A kind of Herbicidal combinations of humulone of sulphur containing triazole and its application
CN107810963A (en) A kind of Herbicidal combinations of the fluorine of pyrrole containing ring humulone and its application
CN107646848A (en) A kind of Herbicidal combinations of humulone containing polybenzobisoxazole and its application
CN109042675A (en) Ternary weeding composition and its application comprising HPPD inhibitor class herbicide
CN105503728B (en) Pyrazole compounds or salts thereof and preparation method thereof, and weedicide composition and application thereof
CN107568230A (en) A kind of Herbicidal combinations of humulone of sulphur containing triazole and its application
CN108157374A (en) A kind of ternary weeding composition and its application
CN107311980A (en) A kind of pyrazolone compound or its salt, intermediate
CN107629035A (en) A kind of pyrazolone compound or its salt, herbicidal composition and purposes
CN108703144A (en) A kind of ternary weeding composition containing ring pyrrole fluorine humulone and its application
CN106455569A (en) Use of 3-isoxazolidinones compounds as selective herbicides
CN109526973A (en) Ternary weeding composition and its application comprising sulfone pyrrole grass azoles
CN109497075A (en) Ternary weeding composition and its application comprising trifludimoxazin
CN109535070A (en) Pyridine oxygroup carboxylic ester derivative and preparation method thereof, Herbicidal combinations and application
CN107517978A (en) A kind of ternary weeding composition and its application of the humulone of sulphur containing triazole and anilofos
CN107897191A (en) A kind of Herbicidal combinations of the fluorine of azoles containing benzene humulone and its application
CN108586357A (en) Substituted pyrimidine formoxyl 9 oxime derivate and preparation method thereof, Herbicidal combinations and application
CN103889217A (en) Pesticidal compositions with enhanced active ingredient retention in pest control zones
CN105399674B (en) Pyrazole compound or salt thereof, and preparation method, herbicide composition and application thereof
CN109438333A (en) A kind of pyridine oxygroup carboxylic ester derivative and preparation method thereof, Herbicidal combinations and application
CN107372551A (en) A kind of Herbicidal combinations and its application of the humulone of sulphur containing triazole and pyridazine compound
CN105994354A (en) Compound weeding composition containing cyclic bicyclopyrone and using method of composition
CN109329286B (en) Binary Herbicidal combinations and its application comprising HPPD inhibitor class herbicide
CN107674025A (en) A kind of 4 benzoylpyrazole class compounds and its preparation method and application
CN107759581A (en) Substituted benzoyl isoxazole class compound or its dynamic isomer, salt, preparation method, Herbicidal combinations and application

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant