CN107897191A - A kind of Herbicidal combinations of the fluorine of azoles containing benzene humulone and its application - Google Patents

A kind of Herbicidal combinations of the fluorine of azoles containing benzene humulone and its application Download PDF

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Publication number
CN107897191A
CN107897191A CN201711096672.7A CN201711096672A CN107897191A CN 107897191 A CN107897191 A CN 107897191A CN 201711096672 A CN201711096672 A CN 201711096672A CN 107897191 A CN107897191 A CN 107897191A
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China
Prior art keywords
humulone
benzene azoles
fluorine
grass
azoles fluorine
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CN201711096672.7A
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Chinese (zh)
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CN107897191B (en
Inventor
彭学岗
赵德
刘娜
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Shandong Qingyuan Agricultural Crop Science Co.,Ltd.
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Qingdao Qing Yuan Compound Co Ltd
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Priority to CN201711096672.7A priority Critical patent/CN107897191B/en
Priority to MX2020004852A priority patent/MX2020004852A/en
Priority to PCT/CN2017/112019 priority patent/WO2019090817A1/en
Publication of CN107897191A publication Critical patent/CN107897191A/en
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    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34
    • A01N57/04—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34 containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
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Abstract

The invention belongs to pesticide field, and in particular to a kind of Herbicidal combinations of the fluorine of azoles containing benzene humulone and its application.It is benzene azoles fluorine humulone that the Herbicidal combinations, which include the active components A of herbicidally effective amount and active ingredient B, A, and B may be selected from the one or more of following compound：VLCFA, PPO, PSII, ALS, microtubules, HPPD, PDS, lipid synthesis, EPSPS, GS, PSI, DHP inhibitor class and synthetic hormone class etc..Said composition can effectively prevent and kill off the weed problems such as Descurainia sophia in the crop fields, ox chickweed, have the characteristics that to expand herbicide controlling spectrum, reduce amount of application, to crop safety, synergistic effect can be produced and solve resistant weed.

Description

A kind of Herbicidal combinations of the fluorine of azoles containing benzene humulone and its application
Technical field
The invention belongs to pesticide field, and in particular to a kind of Herbicidal combinations of the fluorine of azoles containing benzene humulone and its application.
Background technology
Chemical weed control is means the most economical and effective during farmland weed is prevented and kill off, but uses list for a long time continuous high dose The chemical herbicide of one kind or the single mode of action, the problems such as be easy to causeing weeds drug resistance and resistance evolution.
Benzene azoles fluorine humulone chemical structural formula isIt is the corn field after seedling stem newly researched and developed The HPPD inhibitor class herbicide of leaf processing, has excellent bioactivity, can effectively prevent and kill off a variety of malignant weeds of corn field.
The reasonable compounding or mixture of herbicidal compounds, which have, to be expanded weeds spectrum, improves preventive effect, delays weeds drug resistance Property and it is drug-fast generation with development the advantages that, be one of maximally efficient method to solve the above problems.Therefore in production urgently Safe, broad weed-killing spectrum need to be developed, synergistic effect can be produced and solves the problems, such as the Herbicidal combinations kind of resistant weed.
The content of the invention
To solve the above-mentioned problems in the prior art, the present invention provides a kind of Herbicidal combinations of the fluorine of azoles containing benzene humulone And its application.Said composition can effectively prevent and kill off the weed problems such as Descurainia sophia in the crop fields, ox chickweed, have expand herbicide controlling spectrum, Reduce amount of application, to crop safety, synergistic effect can be produced and the features such as solve resistant weed.
A kind of Herbicidal combinations of the fluorine of azoles containing benzene humulone, including the active components A of herbicidally effective amount and active ingredient B, its In, active components A is benzene azoles fluorine humulone, and active ingredient B may be selected from the one or more of following compound:
1) VLCFA inhibitor class:Pretilachlor (CAS accession number:51218-49-6), mefenacet (CAS accession number: 73250-68-7), sulfone pyrrole grass azoles (CAS accession number:447399-55-5), anilofos (CAS accession number:64249-01-0), diformazan Phenol grass amine (CAS accession number:87674-68-8), fentrazamide (CAS accession number:158237-07-1), three azole amide (CAS Accession number:212201-70-2), cafenstrole (CAS accession number:125306-83-4), piperophos (CAS accession number:24151-93- 7), metazachlor (CAS accession number:67129-08-2), propachlor (CAS accession number:1918-16-7), (CAS is logged in pethoxamid Number:106700-29-2)；
2) PPO inhibitor class:Fomesafen (CAS accession number:72178-02-0), Evil humulones (CAS accession number: 19666-30-9), oxadiargyl (CAS accession number:39807-15-3), pyraclonil (CAS accession number:158353-15-2)、 Flumioxazin (CAS accession number:103361-09-7), Huan Wu Evil humulones (CAS accession number:110956-75-7)、 Tiafenacil (CAS accession number:1220411-29-9), pyraflufen-ethyl (CAS accession number:129630-19-9)；
3) PSII inhibitor class:Symetryne (CAS accession number:1014-70-6), terbutryn (CAS accession number:886-50- 0), dipropetryn (CAS accession number:4147-51-7), net (the CAS accession number of evil grass:845-52-3), desmetryn (CAS accession number: 1014-69-3), ethiozin (CAS accession number:64529-56-2), metamitron (CAS accession number:41394-05-2), cyanogen grass Tianjin (CAS accession number:21725-46-2), fluometuron (CAS accession number:2164-17-2), tebuthiuron (CAS accession number:34014- 18-1), Sha flutters grand (CAS accession number:42609-52-9), afesin (CAS accession number:1746-81-2), (CAS is logged in metobromuron Number:3060-89-7), neburea (CAS accession number:555-37-3), alcohol pyridazines (CAS accession number:40020-01-7), isoamyl second Only (CAS accession number:22936-75-0), trietazine (CAS accession number:1912-26-1), bromacil (CAS accession number:314-40- 9), lenacil (CAS accession number:2164-08-1), terbacil (CAS accession number:5902-51-2), (CAS is logged in methabenzthiazuron Number:18691-97-9), Tupersan (CAS accession number:1982-49-6) grand (the CAS accession number of, Yi Evil:55861-78-4), methoxy Grand (CAS accession number:19937-59-8), chloroxifenidium (CAS accession number:1982-47-4), trifluoro grass piperazine (CAS accession number: 1258836-72-4), cyclopyrimorate (CAS accession number:499231-24-2), propanil (CAS accession number:709-98- 8), pyridate (CAS accession number:55512-33-9), desmedipham (CAS accession number:13684-56-5), (CAS is logged in phenmedipham Number:13684-63-4)；
4) ALS inhibitor class:Pyrazosulfuron (CAS accession number:93697-74-6), grand (the CAS accession number of thiophene ketone sulphur: 317815-83-1), promazine Sulfometuron Methyl (CAS accession number:570415-88-2), piperazine pyrazosulfuron (CAS accession number:868680- 84-6), ethoxysulfuron (CAS accession number:126801-58-9), orthosulfamuron (CAS accession number:213464-77-8), fluorine ketone Sulphur grass amine (CAS accession number:96525-23-4), penoxsuam (CAS accession number:219714-96-2), cloransulammethyl (CAS Accession number:147150-35-4)), imazamox (CAS accession number:114311-32-9), AC 263222 (CAS accession number: 104098-48-8), imazethapyr (CAS accession number:81385-77-5), Arsenal (CAS accession number:81334-34-1), it is phonetic Careless ether (CAS accession number:147411-69-6)；
5) microtubules inhibitor class:Trefanocide (CAS accession number:1582-09-8), butralin (CAS accession number: 33629-47-9), pendimethalin (CAS accession number:40487-42-1), Amex820 (CAS accession number:33629-47-9), fluorine sulphur Fixed (the CAS accession number of grass:97886-45-8), ethalfluralin (CAS accession number:55283-68-6), (CAS is logged in oryzalin Number:19044-88-3), benfluralin (CAS accession number:1861-40-1), thiazopyr (CAS accession number:117718-60-2), by grass Special (CAS accession number:23950-58-5), chlorthal (CAS accession number:1861-32-1), butamifos (CAS accession number:36335- 67-8)；
6) HPPD inhibitor class:Sulphur humulone (CAS accession number:99105-77-8), mesotrione (CAS accession number: 104206-82-8), topramezone (CAS accession number:210631-68-8), ring sulphur ketone (CAS accession number:335104-84-2), fluorine Benzofenap (CAS accession number:352010-68-5), furans sulphur humulone (CAS accession number:473278-76-1), benzobicylon (CAS accession number:156963-66-5), lancotrione (CAS accession number:1486617-21-3), (CAS is stepped on sulphonyl grass pyrazoles Record number:365400-11-9), pyrazolate (CAS accession number:58011-68-0), benzofenap (CAS accession number:82692-44-2)、 Tolpyralate (CAS accession number:1101132-67-5), fenquinotrione (CAS accession number:1342891-70-6)；
7) PDS inhibitor class:Fluorochloridone (CAS accession number:61213-25-0), flurtamone (CAS accession number:96525- 23-4), beflubutamid (CAS accession number:113614-08-7), norflurazon (CAS accession number:27314-13-2), fluridone (CAS accession number:59756-60-4)；
8) lipid synthesis (non-acetyl-CoA carboxylase) inhibitor class:Prosulfocarb (CAS accession number:52888-80-9), standing grain Grass enemy's (CAS accession number:2212-67-1), benthiocarb (CAS accession number:28249-77-6), benfuresate (CAS accession number: 68505-69-1), ethofumesate (CAS accession number:26225-79-6), tri-allate (CAS accession number:2303-17-5), herbicide Red (CAS accession number:28249-77-6), vernolate (CAS accession number:1929-77-7), Ding Caote (CAS accession number:2008- 41-5), cycloate (CAS accession number:1134-23-2), dimepiperate (CAS accession number:61432-55-1), (CAS is logged in esprocarb Number:85785-20-2)；
9) synthetic hormone class:Dichloro quinolinic acid (CAS accession number:84087-01-4), quinmerac (CAS accession number: 90717-03-6), picloram (CAS accession number:1918-02-1), chlorine fluorine pyridine ester (CAS accession number:1390661-72- 9), 2-methyl-4-chlorophenoxyacetic acid (CAS accession number:94-74-6), chloro- phenol second thioesters (the CAS accession number of 2- methyl -4-: 25319-90-8), 2- methyl -4- chlorine phenoxy propionic acid (CAS accession number:93-65-2), 2-methyl-4-chlorophenoxyacetic acid sodium (CAS Accession number:3653-48-3), the different monooctyl ester of 2-methyl-4-chlorophenoxyacetic acid (CAS accession number:29450-45-1), 2,4- dichloro-benzenes Fluoroacetic acid butyl ester (CAS accession number:94-80-4), the different monooctyl ester of 2,4- dichlorphenoxyacetic acids (CAS accession number:25168-26-7)、4- (2,4 dichloro benzene epoxide) propionic acid (CAS accession number:120-36-5), Thistrol (CAS accession number:94-81-5), 2,4- drops Butyric acid (CAS accession number:94-82-6)；
10) EPSPS inhibitor class:Sulphosate (CAS accession number:81591-81-3)；
11) GS inhibitor class:Bialaphos (CAS accession number:35597-43-4), smart glufosinate-ammonium (CAS accession number: 35597-44-5)；
12) PSI inhibitor class:Paraquat (CAS accession number:1910-42-5)；
13) DHP inhibitor class:Clever (the CAS accession number of sulphur grass:3337-71-1)；
14) other:Oxaziclomefone (CAS accession number:153197-14-9), cinmethylin (CAS accession number:87818-31- 3)。
Wherein, the weight ratio of A and B is 1:200-200:1, preferably 1:150-150:1, more preferably 1:120-120:1；Into one The weight ratio of step ground, A and B are 1:100-100:1, preferably 1:80-80:1, more preferably 1:50-50:1；Further, A and B Weight ratio be 1:30-30:1, preferably 1:10-10:1, more preferably 1:5-5:1.
The mass percentage of A, B account for the 1-95% of total amount, preferably 10-80% in the Herbicidal combinations.
Conven-tional adjuvants are also included in the Herbicidal combinations, the conven-tional adjuvants include carrier, surfactant.
Term " carrier " herein represents a kind of organic or inorganic, natural or synthetic material.They contribute to activity The administration of component, the carrier are usually inert and must be agriculturally acceptable, and particularly processed plant is received. Carrier can be solid, such as clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer；Or liquid Body, such as water, alcohols, ketone, petroleum distillate, aromatic hydrocarbons or wax hydrocarbon, chlorohydrocarbon, liquefied gas.
Surfactant may include emulsifying agent, dispersant or wetting agent, it can be ionic or non-ionic.It can carry And example be the salt of polyacrylic acid, lignosulfonates, phenolsulfonic acid or naphthalene sulfonic acids salt, ethylene oxide and aliphatic alcohol or Polymer, sulfosuccinic acid with aliphatic acid or with aliphatic amine and fortified phenol (particularly alkylphenol or aryl phenol) Phosphate, the alkyl of salt, taurine derivatives (particularly taurine alkane fat) and the phenol of alcohol phosphate or multi-hydroxy ethyl Sulfonate, alkylaryl sulfonates, alkyl sulfate, lauryl ether sulfate, aliphatic alcohol sulfate, and sulphation 16-, 17-and octadecanol and sulphated fatty alcohol glycol ether, in addition with the condensation of naphthalene or naphthalene sulfonic acids and phenol and formaldehyde Thing, NONIN HS 240, ethoxylated isooctyl-phenol, octyl phenol or nonyl phenol, alkyl phenyl polyglycol ether, three fourths Base phenyl polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol, alcohol and fatty alcohol/ethylene oxide contracting Compound, ethoxylated castor oil, polyoxyethylene alkyl ether, ethoxylation polyoxypropylene, laruyl alcohol polyglycol ether acetal, sorb Alcohol ester, lignin sulfite waste liquor, and protein, albuminate, polysaccharide (such as methylcellulose), Hydrophobic Modified Starch, Polyvinyl alcohol, polycarboxylate, poly-alkoxyl compound, polyvinylamine, polyvinylpyrrolidone and its copolymer.At least need one kind Surfactant exists, to be conducive to active ingredient in water scattered and be conducive to enable them to correctly be applied to plant.
Above-mentioned composition also contains various other components, such as protecting colloid, adhesive, thickener, thixotropic agent, infiltration Agent, stabilizer, chelating agent, dyestuff, colouring agent and polymer.
The composition of the present invention can be used through dilution or directly before use by user.It, which is prepared, to be added by common Work method prepare, i.e., after active material is mixed with liquid flux or solid carrier, add surfactant such as dispersant, surely Determine the one or more in agent, wetting agent, adhesive, defoamer etc..
The specific preparation of the Herbicidal combinations for dispersible oil-suspending agent, aqueous suspension agent, suspension emulsion, wettable powder, Missible oil, water dispersible granules (dry suspending agent), aqueous emulsion, microemulsion.
In brief, composition of the invention can be with conventional use of solid and liquid addition in the formula of the prior art Agent mixes.
In addition, the composition of the composition and compound A and cyclopyrimorate of compound A and pyridate can be with Mixed with following active material, such as《World pesticide new varieties technology is complete works of》, Scientia Agricultura Sinica technology publishing house, 2010.9 With the known substance in document incorporated herein.Such as herbicidal activity material mentioned below, (remarks:The title of compound, It is either according to the common name of International Organization for standardization (ISO) or is chemical name have code name when appropriate):Second grass Amine, butachlor, alachlor, propisochlor, isopropyl methoxalamine, S-metolachlor, pretilachlor, propachlor, kecaoan, naphthalene propionyl The left-handed naphthalene propionyl grass amine of careless amine, R-, propanil, mefenacet, diphenamide, diflufenican, N-alpha-chloroacetyl-N-isopropyl-o ethylaniline, fluorine butyryl grass Amine, bromobutide, dimethenamid, dimethenamidP, ethobenzanid, flufenacet, thenylchlor, pyrrole grass Amine, isoxaben, flampropMmethyl, flampropMisopropyl, allidochlor, pethoxamid, chloranocryl, the grass of ring third Amine, mefluidide, monalide, delachlor, prynachlor, terbuchlor, xylachlor, dimethachlor, amine of taking to the greenwood, The careless amine of front three ring grass amine, clomeprop, propyzamide, valeryl benzene grass amine, card, suffer, the careless amine of tricyclic match, butylene grass Amine, tebutam, benzyl grass amine, quinone duckweed amine, dichlofluanid, naproanilide, acetyl alachlor, quinclorac, fenacet, pyrrole cyanogen grass amine, benzene More grams of grass is dead, chlorothiamid, chlorine phthalimide, fourth amidine amine, fluorine metazachlor, atrazine, Simanex, prometryn, cyanatryn, symetryne, Ametryn, propazine, dipropetryn, flur, terbutryn, Garagard, triaziflam, cyprazine, proglinazine, trietazine, flutter Go out net logical, Gesadrual, nitrine, desmetryn, dimethametryn, the blue or green Tianjin of ring third, green bristlegrass of going out Tianjin, another Ding Jin, Zhong Dingtong, Te Dingtong, methoxy Third is net, cyanatryn, ipazine, chlorazine, atraton, weed eradication are led to, radix glycyrrhizae Tianjin, cyanuric acid, Indaziflam, green sulphur are grand, first Sulphur is grand, bensulfuron-methyl, chlorimuron, tribenuron-methyl, thifensulfuron methyl, pyrazosulfuron, mesosulfuron, iodosulfuron-methyl-sodium, formyl Amino Sulfometuron Methyl, cinosulfuron, triasulfuron, sulfometuronmethyl, nicosulfuron, ethametsulfuron, amidosulfuron, ethoxysulfuron, ring Third Sulfometuron Methyl, rimsulfuron, azimsulfuron, pyridine ethyl methyl, monosulfmeturon, single phonetic sulphur ester, flucarbazone, flupyrsulfuron-methyl-sodium, Fluorine pyrazosulfuron, oxasulfuron, imazosulfuron, primisulfuronmethyl, procarbazone, prosulfuron, Sulfosulfuron, trifluoro pyridine Sulphur is grand, triflusulfuronmethyl, tritosulfuron, metsulfuron-methyl sodium salt, flucetosulfuron, Sulfonylurea, orthosulfamuron, Propyrisulfuron (promazine Sulfometuron Methyl), piperazine pyrazosulfuron, acifluorfen, fomesafen, lactofen, second carboxylic Fluofazone, Oxyfluorfen, Mo 9 granular, aclonifen, ethoxyfen-ethyl, bifenox, fluoroform grass ether, methoxy weeding Ether, fluorodifen, fluorination nitrofen, fluorine furan grass ether, nitrofen, first grass ether, diformazan grass ether, fluorine lactazone grass ether, fluofazone ester, Halosafen, chlortoluron, isoproturon, linuron, diuron, Sha flutter grand, fluometuron, benzthiazuron, methabenzthiazuron, cumyluron, Ethidimuron, isouron, terbufos benzthiazuron, buturon, bromax, methyldymron, phenobenzuron, methoxy daimuron, metobromuron, first Oxygen is grand, afesin, telvar, Tupersan, fenuron, fluorine sulphur are grand, neburea, chloroxifenidium, herban, isonoruron, Alipur-O, Thiazfluron, tebuthiuron, difenoxuron, to fluon, methylamine methabenz thiazuron, Long Caote, front three isourea, dimefuron, Monisouron, Anisuron, Methiuron, Chloreturon, four fluon, phenmedipham, phenmedipham-ethyl ester, desmedipham, the spirit of sulphur grass, special grass Spirit, oatax, Chem hoe, chlorpropham, benzyl dichloride grass ester, swep, chlorbufam, Carboxazole, Chlorprocarb, Fenasulam, BCPC, CPPC, Carbasulam, Ding Caote, benthiocarb, vernolate, molinate, tri-allate, dimepiperate, dogstail Fear, pyributicarb, cycloate, Avadex, bactericide, the careless spy of second sulphur, orbencarb, pebulate, prosulfocarb, tiocarbazil, sulfuric acid, Dimexan, Isopolinate, Methiobencarb, 2,4- d butyl ester, 2 first, 4 chlorine sodium, the different monooctyl ester of 2,4- drops, 2 first, 4 chlorine are different pungent Ester, 2,4- drops sodium salt, 2,4- drops dimethylamine salt, 2 first, 4 chloroethene thioesters, 2 first, 4 chlorine, 2,4- drops propionic acid, high 2,4- drops propionate, 2, 4- Embutoxs, Vi par, Vi par salt, Thistrol, 2,4,5- tears, 2,4,5- tears propionic acid, 2,4,5- tears fourths Acid, 2 first, 4 chloramines salt, Mediben, erbon, Fenac, match pine, trichlorobenzoic acid, chloramben, methoxy trichlorobenzoic acid, dogstail Spirit, fluazifop, efficient fluazifop, haloxyfop-P-methyl, efficient haloxyfop, quizalofop-ethyl, Quizalotop-ethyl, oxazole dogstail Spirit, fenoxapropPethyl, propaquizafop, cyhalofop-butyl, metamifop, clodinafop-propargyl, diclofop-methyl thiazole, chloroazifoppropynyl, penta standing grain of hydroxyl spirit, Trifluoro dogstail oxime, isoxapyrifop, paraquat, diquat dibromide, oryzalin, ethalfluralin, isopropalin, nitralin, the third fluorine of ring Spirit, prodiamine, benfluralin, fluchloraline, the spirit of amino second fluorine, dipropalin, chloroethene dipropalin, Methalpropalin, Third nitre phenol, glyphosate, Sha barnyard grass phosphine, glufosinate-ammonium, amiprophos-methyl, sulphosate, piperazine grass phosphine, bialaphos, bensulide, butamifos, Creeping weed phosphorus, cut down ridge phosphorus, double first amiprophos, dow crabgrass killer, imazapyr, imazethapyr, imazaquin, imazamox, first Oxygen Imazethapyr ammonium salt, AC 263222, miaow grass ester, fluroxypyr, the different monooctyl ester of fluroxypyr, clopyralid, ammonia Chloropyridine acid, trichlopyr, dithiopyr, halogen grass are determined, phenolate trichloropyridine, thiazopyr, fluridone, chlorine Fampridine are sour, Diflufenzopyr, triclopyr butoxyethyl ester, Cliodinate, sethoxydim, clethodim, cycloxydim, alloxydimsodium, ring benzene grass Ketone, butroxydim, tralkoxydim, tepraloxydim, Buthidazole, metribuzin, hexazinone, metamitron, ethiozin, Ametridione, Amibuzin, Brominal, bromoxynil octanoate, ioxynil octanoate, ioxynil, dichlobenil, diphenatril, polybenzobisoxazole Oxalic acid dinitrile, chloroxynil, Iodobonil, Flumetsulam, florasulam, penoxsuam, metosulam, cloransulammethyl, Diclosulam, pyroxsulam, fluorine straw colour, bispyribac-sodium, pyribenzoxim, pyriftalid, KIH 6127, pyrithiobacsodium, bicyclic sulphur It is humulone, mesotrione, sulphur humulone, Tembotrione, Tefuryltrione, Bicyclopyrone, Ketodpiradox, different Oxazole humulone, isoxachlorotole, Fenoxasulfone, Methiozolin, fluazolate, pyraflufen-ethyl, pyrazolate, wild swallow Withered, pyrazoxyfen, benzofenap, pyrrole chlorine grass amine, Pyrasulfotole, topramezone, Pyroxasulfone, cafenstrole, fluorine amine grass Azoles, Amrol, amicarbazone, azafenidin, profluazone, sulfentrazone, Bencarbazone, benzfendizone, fluorine third are phonetic Careless ester, bromacil, isoprocil, lenacil, terbacil, Flupropacil, cinidon-ethyl, Flumiclorac pentyl, flumioxazin, Alkynes grass amine, phthalein benzyl oxide, Flumezin, pentachlorophenol (sodium), dinoseb, dinoterb, dinoterb acetate, dinosam, Chemox PE, chlorine nitre phenol, Medinoterb acetate, Di Lete, oxadiargyl, oxadiazon, pentoxazone, profluazol, fluthiacet, fentrazamide, fluorine Pyridazine grass ester, pyrazon, brompyrazon, diformazan reach careless volt, Kusakira, grass pyridazone, grass and rattle away pine, norflurazon, Pyridafol, dichloro Quinolinic acid, quinmerac, Bentazon, pyridate, oxaziclomefone, benazolin, clomazone, cinmethylin, iso-propyl-ester nitrofen, Propyl-ester nitorfen, indanofan, sodium chlorate, Dalapon, trichloroacetic acid, monochloroacetic acid, hexachloroacetone, tetrafluoro propionic acid, herbage are fast, bromine phenol Oxime, triazole sulphur, kill azoles, flurtamone, benfuresate, ethofumesate, phonetic careless amine, chlorine phthalandione, fluorochloridone, barnyard grass, methacrylaldehyde, Bentranil, tridiphane, Bidisin, thiadiazoles grass amine, phenisopham, hydroxyl humulone, dioxybenzone, benzene flumetsulam, chlorine acyl grass phosphine, three Chloropropionic acid, Alorac, Diethamquat, Etnipromid, Iprymidam, Ipfencarbazone, Thiencarbazone- Methyl, Pyrimisulfan, Chlorflurazole, Tripropindan, Sulglycapin, first sulphur nitralin, Cambendichlor, the third pyrimidine acid of ring, rodethanii, benoxacor, fenclorim, flurazole, fenchlorazole, the careless quinoline of solution, oxabetrinil, Oxalane, cyometrinil, desorpenic, mefenpyrdiethyl, furilazole, fluxofenim, isoxadifen, allyl dichloride amine, fluorine Chloropyridine ester, DOW chlorine fluorine pyridine ester, UBH-509, D489, LS82-556, KPP-300, NC-324, NC-330, KH-218, DPX-N8189、SC-0744、DOWCO535、DK-8910、V-53482、PP-600、MBH-001、KIH-9201、ET-751、 KIH-6127 and KIH-2023.
The Herbicidal combinations further comprise safener, it is selected from isoxadifen (CAS accession number:163520-33- 0), cyprosulfamide (CAS accession number:221667-31-8), mefenpyrdiethyl (CAS accession number:135590-91-9), solve Malicious quinoline (CAS accession number:99607-70-2), gibberellic acid (CAS accession number:77-06-5), furilazole (CAS accession number: 121776-33-8), metcamifen (CAS accession number:One or more in 129531-12-0).
The composition of the present invention can be applied on pending plant leaf blade by the method for spraying, that is, is applied to weeds, On the surface that the weed infestation or easy invasion being particularly harmful on plant growth influence.
When applying the Herbicidal combinations of the present invention, unexpected synergistic effect is obtained, and activity of weeding ratio makes It is individually active more notable with the expected summation of the activity of single herbicide, and single herbicide.Synergistic effect shows as applying Measure reductions, broader weeds distribution spectrum, herbicide effect faster, it is more longlasting, these characteristics are required in Weeds distribution practice process Want.For described characteristic, these new compositions are significantly superior to existing herbicide.
The Herbicidal combinations of the present invention, which also have, to be had the advantage that:
(1) composition of the invention is environmentally friendly to be easy to degrade in the environment, suitable for various crop field.
(2) Herbicidal combinations cost of the invention is low, easy to use, its popularization and application has huge economic benefit and society Benefit.
Embodiment
The following example not limits the present invention, and is used only to how the explanation present invention realizes.For some miscellaneous Grass, these embodiments show especially significant validity.It is exemplified below:
A) embodiment
1st, 42% benzene azoles fluorine humulone pretilachlor suspension emulsion (12+30)
+ 3% phenethyl phenol polyethenoxy ether sulphonic acid ester triethanolamine dipersant of 12%+30% pretilachlor of benzene azoles fluorine humulone + 0.12%+5% glycerine of xanthans of+2.5% castor oil polyoxyethylene ether of+1% phenethyl phenol polyethenoxy ether+water is supplied.
2nd, 42% benzene azoles fluorine humulone mefenacet suspending agent (12+30)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+30% mefenacet of benzene azoles fluorine humulone + 1.5%+5% glycerine of aluminium-magnesium silicate of+0.13% xanthans of the fatty alcohol polyoxyethylene ether of powder+1.5%+water is supplied.
3rd, 32% benzene azoles fluorine humulone sulfone pyrrole grass azole suspending agents (12+20)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of+20% sulfone pyrrole grass azoles of 12% benzene azoles fluorine humulone disperses + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of agent+1.5%+water is supplied.
4th, 32% benzene azoles fluorine humulone anilofos suspension emulsion (12+20)
+ 3% phenethyl phenol polyethenoxy ether sulphonic acid ester triethanolamine dipersant of 12%+20% anilofos of benzene azoles fluorine humulone + 0.14%+5% glycerine of xanthans of+2.5% castor oil polyoxyethylene ether of+1% phenethyl phenol polyethenoxy ether+water is supplied.
5th, the 18% benzene azoles fluorine humulone dispersible oil-suspending agent of xylenol grass amine (3+15)
+ 6% nonylphenol polyoxyethylene ether of+15%+5% calcium dodecyl benzene sulfonate of xylenol grass amine of 3% benzene azoles fluorine humulone+ + 1.5% fumed silica+10%150# solvent naphthas of+2.0% organobentonite of 4% castor oil polyoxyethylene ether+oleic acid first Ester is supplied.
6th, 27% benzene azoles fluorine humulone fentrazamide suspending agent (12+15)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+15% fentrazamide of benzene azoles fluorine humulone + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of powder+1.5%+water is supplied.
7th, 29% benzene azoles fluorine humulone, three azole amide suspending agent (12+17)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+17% three azole amide of benzene azoles fluorine humulone + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of powder+1.5%+water is supplied.
8th, 27% benzene azoles fluorine humulone cafenstrole suspending agent (12+15)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 12%+15% cafenstrole of benzene azoles fluorine humulone + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of+1.5% fatty alcohol polyoxyethylene ether+water is supplied.
9th, the 28% benzene azoles dispersible oil-suspending agent of fluorine humulone piperophos (3+25)
+ 6% nonylphenol polyoxyethylene ether+4% of 3%+5% calcium dodecyl benzene sulfonate of benzene azoles fluorine+25% piperophos of humulone + 1.0% fumed silica+10%150# solvent naphthas of the organobentonite of castor oil polyoxyethylene ether+1.0%+methyl oleate Supply.
10th, 31% benzene azoles fluorine humulone metazachlor suspension emulsion (6+25)
+ 3% phenethyl phenol polyethenoxy ether sulphonic acid ester triethanolamine salt of 6%+25% metazachlor of benzene azoles fluorine humulone disperses + 0.15%+5% glycerine of xanthans of+2.5% castor oil polyoxyethylene ether of the phenethyl phenol polyethenoxy ether of agent+1%+water is supplied.
11st, 41% benzene azoles fluorine humulone propachlor suspension emulsion (3+38)
+ 3% phenethyl phenol polyethenoxy ether sulphonic acid ester triethanolamine dipersant of 3%+38% propachlor of benzene azoles fluorine humulone+ + 0.12%+5% glycerine of xanthans of+2.5% castor oil polyoxyethylene ether of 1% phenethyl phenol polyethenoxy ether+water is supplied.
12nd, 43% benzene azoles fluorine humulone pethoxamid suspension emulsion (3+40)
+ 3% phenethyl phenol polyethenoxy ether sulphonic acid ester triethanolamine dipersant of 3%+40% pethoxamid of benzene azoles fluorine humulone+ + 0.12%+5% glycerine of xanthans of+2.5% castor oil polyoxyethylene ether of 1% phenethyl phenol polyethenoxy ether+water is supplied.
13rd, 9% benzene azoles fluorine humulone fomesafen suspending agent (3+6)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 3%+6% fomesafen of benzene azoles fluorine humulone disperses + 2.0%+5% glycerine of aluminium-magnesium silicate of+0.22% xanthans of the fatty alcohol polyoxyethylene ether of agent+1.5%+water is supplied.
14th, 52% benzene azoles fluorine Cao Tong Evil humulones suspending agents (12+40)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 12%+40% Evil humulones of benzene azoles fluorine humulone + 0.6%+5% glycerine of aluminium-magnesium silicate of+0.06% xanthans of+1.5% fatty alcohol polyoxyethylene ether+water is supplied.
15th, 18% benzene azoles fluorine humulone oxadiargyl suspending agent (12+6)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+6% oxadiargyl of benzene azoles fluorine humulone + 1.8%+5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of the fatty alcohol polyoxyethylene ether of powder+1.5%+water is supplied.
16th, 27% benzene azoles fluorine humulone pyraclonil suspending agent (12+15)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 12%+25% pyraclonil of benzene azoles fluorine humulone disperses + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of agent+1.5%+water is supplied.
17th, the 18% benzene azoles dispersible oil-suspending agent of fluorine humulone flumioxazin (12+6)
+ 6% nonylphenol polyoxyethylene ether of 12%+5% calcium dodecyl benzene sulfonate of benzene azoles fluorine+6% flumioxazin of humulone+ + 1.5% fumed silica+10%150# solvent naphthas of+1.8% organobentonite of 4% castor oil polyoxyethylene ether+oleic acid first Ester is supplied.
18th, 39% benzene azoles fluorine humulone Huan Wu Evil humulones suspending agents (12+27)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12% penta Evil humulones of benzene azoles fluorine+27% ring of humulone + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of powder+1.5%+water is supplied.
19th, 28% benzene azoles fluorine humulone tiafenacil suspending agents (24+4)
24% benzene azoles fluorine humulone+4%tiafenacil+4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinities + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of powder+1.5%+water is supplied.
20th, the 10% benzene azoles dispersible oil-suspending agent of fluorine humulone pyraflufen-ethyl (9+1)
+ 4% castor of 9%+6% nonylphenol polyoxyethylene ether of benzene azoles fluorine humulone+5% calcium dodecyl benzene sulfonate of+1% pyraflufen-ethyl + 2.5% fumed silica+10%150# solvent naphthas of+3.0% organobentonite of sesame oil polyoxyethylene ether+methyl oleate is mended Foot.
21st, 43% benzene azoles fluorine humulone symetryne suspending agent (12+31)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 12%+31% symetryne of benzene azoles fluorine humulone + 1.2%+5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of+1.5% fatty alcohol polyoxyethylene ether+water is supplied.
22nd, 33% benzene azoles fluorine humulone terbutryn suspending agent (3+30)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+30% terbutryn of benzene azoles fluorine humulone+ + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
23rd, 53% benzene azoles fluorine humulone dipropetryn suspending agent (3+50)
+ 3% phenethyl phenol polyethenoxy ether phosphoric acid of 3%+2% polycarboxylate salt dispersant of benzene azoles fluorine+50% dipropetryn of humulone + 0.06%+5% glycerine of xanthans of+1.5% fatty alcohol polyoxyethylene ether of ester triethanolamine dipersant+water is supplied.
24th, the careless net suspension agent (3+50) of 53% benzene azoles fluorine humulone evil
3% benzene azoles fluorine humulone+50% evil grass+3% phenethyl phenol polyethenoxy ether phosphoric acid of net+2% polycarboxylate salt dispersant + 0.06%+5% glycerine of xanthans of+1.5% fatty alcohol polyoxyethylene ether of ester triethanolamine dipersant+water is supplied.
25th, 44% benzene azoles fluorine humulone desmetryn suspending agent (6+38)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+38% desmetryn of benzene azoles fluorine humulone+ + 1.2%+5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
26th, 30% benzene azoles fluorine humulone ethiozin suspending agent (6+24)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 6%+24% ethiozin of benzene azoles fluorine humulone disperses + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of agent+1.5%+water is supplied.
27th, 67% benzene azoles fluorine humulone metamitron water dispersible granules (2+65)
+ 1% disintegrant of 2%+6% pull open powder of benzene azoles fluorine humulone+5% polycarboxylic acid salt's dispersant of+65% metamitron gathers The precipitated silica of vinyl alcohol+5%+filler diatomite is supplied.
28th, 28% benzene azoles fluorine humulone cyanazine suspending agent (3+25)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+25% cyanazine of benzene azoles fluorine humulone+ + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
29th, 46% benzene azoles fluorine humulone fluometuron suspending agent (6+40)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+40% fluometuron of benzene azoles fluorine humulone+ + 0.6%+5% glycerine of aluminium-magnesium silicate of+0.08% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
30th, 33% benzene azoles fluorine humulone tebuthiuron suspending agent (3+30)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+30% tebuthiuron of benzene azoles fluorine humulone+ + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
31st, 28% benzene azoles fluorine humulone Sha flutters grand suspending agent (3+25)
+ 25% Sha of 3% benzene azoles fluorine humulone flutter grand+4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant+ + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
32nd, 53% benzene azoles fluorine humulone afesin suspending agent (3+50)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+50% afesin of benzene azoles fluorine humulone+ + 0.6%+5% glycerine of aluminium-magnesium silicate of+0.06% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
33rd, 39% benzene azoles fluorine humulone metobromuron suspending agent (6+33)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+33% metobromuron of benzene azoles fluorine humulone+ + 1.5%+5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
34th, 67% benzene azoles fluorine humulone neburea water dispersible granules (3+64)
+ 1% poly- second of disintegrant of 3%+6% pull open powder of benzene azoles fluorine humulone+5% polycarboxylic acid salt's dispersant of+64% neburea The precipitated silica of enol+5%+filler diatomite is supplied.
35th, 39% benzene azoles fluorine humulone alcohol pyridazines suspending agent (6+33)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+33% alcohol pyridazines of benzene azoles fluorine humulone+ + 1.4%+5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
36th, 45% benzene azoles fluorine humulone dimethametryn suspending agent (3+42)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 3%+42% dimethametryn of benzene azoles fluorine humulone disperses + 1.2%+5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of the fatty alcohol polyoxyethylene ether of agent+1.5%+water is supplied.
37th, 43% benzene azoles fluorine humulone trietazine suspending agent (3+40)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+40% trietazine of benzene azoles fluorine humulone+ + 1.3%+5% glycerine of aluminium-magnesium silicate of+0.13% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
38th, 60% benzene azoles fluorine humulone bromacil water dispersible granules (2.25+57.75)
+ 6% pull open powder+1% of 2.25%+6% polycarboxylic acid salt's dispersant of benzene azoles fluorine+57.75% bromacil of humulone is disintegrated + 5% precipitated silica of agent polyvinyl alcohol+filler diatomite is supplied.
39th, 46% benzene azoles fluorine humulone lenacil suspending agent (6+40)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+40% lenacil of benzene azoles fluorine humulone+ + 1.0%+5% glycerine of aluminium-magnesium silicate of+0.1% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
40th, 63% benzene azoles fluorine humulone terbacil water dispersible granules (3+60)
+ 1% poly- second of disintegrant of 3%+6% pull open powder of benzene azoles fluorine humulone+6% polycarboxylic acid salt's dispersant of+60% terbacil The precipitated silica of enol+5%+filler diatomite is supplied.
41st, 26% benzene azoles fluorine humulone methabenzthiazuron suspending agent (12+14)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+14% methabenzthiazuron of benzene azoles fluorine humulone + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of powder+1.5%+water is supplied.
42nd, 63% benzene azoles fluorine humulone Tupersan water dispersible granules (3+60)
+ 1% poly- second of disintegrant of 3%+6% pull open powder of benzene azoles fluorine humulone+8% polycarboxylic acid salt's dispersant of+60% Tupersan The precipitated silica of enol+5%+filler diatomite is supplied.
43rd, the 36% benzene azoles fluorine grand suspending agents of humulone Yi Evil (3+33)
+ 33% different grand+4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersants of Evil of 3% benzene azoles fluorine humulone+ + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
44th, 70% benzene azoles fluorine humulone metoxuron water dispersible granules (3+67)
+ 1% poly- second of disintegrant of 3%+5% pull open powder of benzene azoles fluorine humulone+5% polycarboxylic acid salt's dispersant of+67% metoxuron The precipitated silica of enol+5%+filler diatomite is supplied.
45th, 70% benzene azoles fluorine humulone chloroxifenidium water dispersible granules (3+67)
+ 1% poly- second of disintegrant of 3%+5% pull open powder of benzene azoles fluorine humulone+4% polycarboxylic acid salt's dispersant of+67% chloroxifenidium The precipitated silica of enol+5%+filler diatomite is supplied.
46th, 32% benzene azoles fluorine humulone trifluoro grass piperazine suspending agent (12+20)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 12%+20% trifluoro grass piperazine of benzene azoles fluorine humulone disperses + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of agent+1.5%+water is supplied.
47th, 26% benzene azoles fluorine humulone cyclopyrimorate suspending agents (9+17)
9% benzene azoles fluorine humulone+17%cyclopyrimorate+4% phenethyl phenol polyethenoxy ether phosphate triethanolamines + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of dipersant+1.5%+water is supplied.
48th, 50% benzene azoles fluorine humulone propanil water dispersible granules (1.5+48.5)
+ 1% disintegrant of 1.5%+6% pull open powder of benzene azoles fluorine humulone+8% polycarboxylic acid salt's dispersant of+48.5% propanil gathers The precipitated silica of vinyl alcohol+5%+filler diatomite is supplied.
49th, 49% benzene azoles fluorine humulone pyridate suspending agent (4.5+44.5)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 4.5%+44.5% pyridate of benzene azoles fluorine humulone + 0.08%+5% glycerine of xanthans of the fatty alcohol polyoxyethylene ether of powder+1.5%+water is supplied.
50th, 36% benzene azoles fluorine humulone desmedipham suspending agent (4.5+31.5)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 4.5%+31.5% desmedipham of benzene azoles fluorine humulone + 1.3%+5% glycerine of aluminium-magnesium silicate of+0.13% xanthans of the fatty alcohol polyoxyethylene ether of powder+1.5%+water is supplied.
51st, 36% benzene azoles fluorine humulone phenmedipham suspending agent (4.5+31.5)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 4.5%+31.5% phenmedipham of benzene azoles fluorine humulone + 1.3%+5% glycerine of aluminium-magnesium silicate of+0.13% xanthans of the fatty alcohol polyoxyethylene ether of powder+1.5%+water is supplied.
52nd, the 14% benzene azoles dispersible oil-suspending agent of fluorine humulone pyrazosulfuron (12+2)
+ 6% nonylphenol polyoxyethylene ether of 12%+5% calcium dodecyl benzene sulfonate of benzene azoles fluorine+2% pyrazosulfuron of humulone+ + 2.5% fumed silica+10%150# solvent naphthas of+2.8% organobentonite of 4% castor oil polyoxyethylene ether+oleic acid first Ester is supplied.
53rd, the 15% grand dispersible oil-suspending agent (12+3) of benzene azoles fluorine humulone thiophene ketone sulphur
Grand+4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of+3% thiophene ketone sulphur of 12% benzene azoles fluorine humulone disperses + 1.8%+5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of the fatty alcohol polyoxyethylene ether of agent+1.5%+water is supplied.
54th, the 18% benzene azoles fluorine dispersible oil-suspending agent of humulone promazine Sulfometuron Methyl (12+6)
+ 6% nonylphenol polyoxyethylene ether of 12%+5% calcium dodecyl benzene sulfonate of benzene azoles fluorine+6% promazine Sulfometuron Methyl of humulone+ + 1.8% fumed silica+10%150# solvent naphthas of+1.8% organobentonite of 4% castor oil polyoxyethylene ether+oleic acid first Ester is supplied.
55th, the 19% benzene azoles fluorine dispersible oil-suspending agent of humulone piperazine pyrazosulfuron (12+7)
+ 6% nonylphenol polyoxyethylene ether of 12%+5% calcium dodecyl benzene sulfonate of benzene azoles fluorine+7% piperazine pyrazosulfuron of humulone+ + 1.8% fumed silica+10%150# solvent naphthas of+1.8% organobentonite of 4% castor oil polyoxyethylene ether+oleic acid first Ester is supplied.
56th, the 27% benzene azoles dispersible oil-suspending agent of fluorine humulone ethoxysulfuron (24+3)
+ 6% nonylphenol polyoxyethylene ether of 24%+5% calcium dodecyl benzene sulfonate of benzene azoles fluorine+3% ethoxysulfuron of humulone+ + 1.0% fumed silica+10%150# solvent naphthas of+1.4% organobentonite of 4% castor oil polyoxyethylene ether+oleic acid first Ester is supplied.
57th, the 17% benzene azoles dispersible oil-suspending agent of fluorine humulone orthosulfamuron (12+5)
+ 6% nonylphenol polyoxyethylene ether of 12%+5% calcium dodecyl benzene sulfonate of benzene azoles fluorine+5% orthosulfamuron of humulone+ + 1.8% fumed silica+10%150# solvent naphthas of+1.8% organobentonite of 4% castor oil polyoxyethylene ether+oleic acid first Ester is supplied.
58th, the 29% benzene azoles fluorine humulone fluorine ketone dispersible oil-suspending agent of sulphur grass amine (24+5)
+ 6% nonylphenol polyoxyethylene ether of+5%+5% calcium dodecyl benzene sulfonate of fluorine ketone sulphur grass amine of 24% benzene azoles fluorine humulone+ + 0.5% fumed silica+10%150# solvent naphthas of+1.0% organobentonite of 4% castor oil polyoxyethylene ether+oleic acid first Ester is supplied.
59th, the 14% benzene azoles dispersible oil-suspending agent of fluorine humulone penoxsuam (12+2)
+ 6% nonylphenol polyoxyethylene ether of 12%+5% calcium dodecyl benzene sulfonate of benzene azoles fluorine+2% penoxsuam of humulone+ + 2.5% fumed silica+10%150# solvent naphthas of+2.5% organobentonite of 4% castor oil polyoxyethylene ether+oleic acid first Ester is supplied.
60th, the 14% benzene azoles dispersible oil-suspending agent of fluorine humulone cloransulammethyl (12+2)
+ 6% nonylphenol polyoxyethylene ether of 12%+5% calcium dodecyl benzene sulfonate of benzene azoles fluorine+2% cloransulammethyl of humulone+ + 2.5% fumed silica+10%150# solvent naphthas of+2.5% organobentonite of 4% castor oil polyoxyethylene ether+oleic acid first Ester is supplied.
61st, the 15% benzene azoles dispersible oil-suspending agent of fluorine humulone imazamox (12+3)
+ 6% nonylphenol polyoxyethylene ether of 12%+5% calcium dodecyl benzene sulfonate of benzene azoles fluorine+3% imazamox of humulone+ + 2.5% fumed silica+10%150# solvent naphthas of+2.5% organobentonite of 4% castor oil polyoxyethylene ether+oleic acid first Ester is supplied.
62nd, the 22% benzene azoles dispersible oil-suspending agent of fluorine humulone AC 263222 (12+10)
+ 6% nonylphenol polyoxyethylene ether of 12%+5% calcium dodecyl benzene sulfonate of benzene azoles fluorine+10% AC 263222 of humulone + 1.5% fumed silica+10%150# solvent naphthas of+1.8% organobentonite of+4% castor oil polyoxyethylene ether+oleic acid Methyl esters is supplied.
63rd, the 19% benzene azoles dispersible oil-suspending agent of fluorine humulone imazethapyr (12+7)
+ 6% nonylphenol polyoxyethylene ether of 12%+5% calcium dodecyl benzene sulfonate of benzene azoles fluorine+7% imazethapyr of humulone+ + 1.5% fumed silica+10%150# solvent naphthas of+2.0% organobentonite of 4% castor oil polyoxyethylene ether+oleic acid first Ester is supplied.
64th, the 28% benzene azoles dispersible oil-suspending agent of fluorine humulone Arsenal (3+25)
+ 6% nonylphenol polyoxyethylene ether+4% of 3%+5% calcium dodecyl benzene sulfonate of benzene azoles fluorine+25% Arsenal of humulone + 1.0% fumed silica+10%150# solvent naphthas of the organobentonite of castor oil polyoxyethylene ether+1.0%+methyl oleate Supply.
65th, the 15% benzene azoles dispersible oil-suspending agent of fluorine humulone KIH 6127 (12+3)
+ 6% nonylphenol polyoxyethylene ether+4% of 12%+5% calcium dodecyl benzene sulfonate of benzene azoles fluorine+3% KIH 6127 of humulone + 1.5% fumed silica+10%150# solvent naphthas of the organobentonite of castor oil polyoxyethylene ether+2.2%+methyl oleate Supply.
66th, 42% benzene azoles fluorine humulone trefanocide suspending agent (6+36)
+ 3% phenethyl phenol polyethenoxy ether phosphoric acid of 6%+2% polycarboxylate salt dispersant of benzene azoles fluorine+36% trefanocide of humulone + 5% glycerine of+0.6% aluminium-magnesium silicate of ester triethanolamine dipersant+0.1% xanthans of+1.5% fatty alcohol polyoxyethylene ether+ Water is supplied.
67th, 33% benzene azoles fluorine humulone butralin suspending agent (3+30)
+ 3% phenethyl phenol polyethenoxy ether phosphoric acid of 3%+2% polycarboxylate salt dispersant of benzene azoles fluorine+30% butralin of humulone + 5% glycerine of+1.4% aluminium-magnesium silicate of ester triethanolamine dipersant+0.14% xanthans of+1.5% fatty alcohol polyoxyethylene ether + water is supplied.
68th, 46% benzene azoles fluorine humulone pendimethalin suspension (6+40)
+ 3% phenethyl phenol polyethenoxy ether phosphorus of 6%+2% polycarboxylate salt dispersant of benzene azoles fluorine+40% pendimethalin of humulone + 0.6% aluminium-magnesium silicate+5% of+0.1% xanthans of acid esters triethanolamine+1.5% fatty alcohol polyoxyethylene ether of dipersant the third three Alcohol+water is supplied.
69th, 39% benzene azoles fluorine humulone Amex820 suspending agent (3+36)
+ 3% phenethyl phenol polyethenoxy ether phosphoric acid of 3%+2% polycarboxylate salt dispersant of benzene azoles fluorine+36% Amex820 of humulone + 5% glycerine of+1.0% aluminium-magnesium silicate of ester triethanolamine dipersant+0.1% xanthans of+1.5% fatty alcohol polyoxyethylene ether+ Water is supplied.
70th, 39% benzene azoles fluorine humulone dithiopyr suspending agent (6+33)
+ 3% phenethyl phenol polyethenoxy ether phosphorus of 6%+2% polycarboxylate salt dispersant of benzene azoles fluorine+33% dithiopyr of humulone + 1.2% aluminium-magnesium silicate+5% of+0.1% xanthans of acid esters triethanolamine+1.5% fatty alcohol polyoxyethylene ether of dipersant the third three Alcohol+water is supplied.
71st, 38% benzene azoles fluorine humulone ethalfluralin suspending agent (3+35)
+ 3% phenethyl phenol polyethenoxy ether of 3%+2% polycarboxylate salt dispersant of benzene azoles fluorine+35% ethalfluralin of humulone + 1.2% aluminium-magnesium silicate+5% third of+0.1% xanthans of phosphate triethanolamine+1.5% fatty alcohol polyoxyethylene ether of dipersant Triol+water is supplied.
72nd, 28% benzene azoles fluorine humulone oryzalin suspending agent (3+25)
+ 3% phenethyl phenol polyethenoxy ether phosphorus of 3%+2% polycarboxylate salt dispersant of benzene azoles fluorine+25% oryzalin of humulone + 1.2% aluminium-magnesium silicate+5% of+0.12% xanthans of acid esters triethanolamine+1.5% fatty alcohol polyoxyethylene ether of dipersant the third three Alcohol+water is supplied.
73rd, 35% benzene azoles fluorine humulone benfluralin suspending agent (6+29)
+ 3% phenethyl phenol polyethenoxy ether phosphoric acid of 6%+2% polycarboxylate salt dispersant of benzene azoles fluorine+29% benfluralin of humulone + 5% glycerine of+1.2% aluminium-magnesium silicate of ester triethanolamine dipersant+0.12% xanthans of+1.5% fatty alcohol polyoxyethylene ether + water is supplied.
74th, 39% benzene azoles fluorine humulone thiazopyr suspending agent (6+33)
+ 3% phenethyl phenol polyethenoxy ether phosphoric acid of 6%+2% polycarboxylate salt dispersant of benzene azoles fluorine+33% thiazopyr of humulone + 5% glycerine of+1.2% aluminium-magnesium silicate of ester triethanolamine dipersant+0.1% xanthans of+1.5% fatty alcohol polyoxyethylene ether+ Water is supplied.
75th, 39% benzene azoles fluorine humulone pronamide suspending agent (6+33)
+ 3% phenethyl phenol polyethenoxy ether phosphoric acid of 6%+2% polycarboxylate salt dispersant of benzene azoles fluorine+33% pronamide of humulone + 5% glycerine of+1.2% aluminium-magnesium silicate of ester triethanolamine dipersant+0.12% xanthans of+1.5% fatty alcohol polyoxyethylene ether + water is supplied.
76th, 53% benzene azoles fluorine humulone Chlorthal suspension agent (3+50)
+ 3% phenethyl phenol polyethenoxy ether phosphoric acid of 3%+2% polycarboxylate salt dispersant of benzene azoles fluorine+50% chlorthal of humulone + 5% glycerine of+0.6% aluminium-magnesium silicate of ester triethanolamine dipersant+0.1% xanthans of+1.5% fatty alcohol polyoxyethylene ether+ Water is supplied.
77th, 58% benzene azoles fluorine humulone butamifos water dispersible granules (3+55)
+ 1% poly- second of disintegrant of 3%+6% pull open powder of benzene azoles fluorine humulone+8% polycarboxylic acid salt's dispersant of+55% butamifos The precipitated silica of enol+5%+filler diatomite is supplied.
78th, 36% benzene azoles fluorine humulone sulphur humulone suspending agent (6+30)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 6%+30% sulphur humulone of benzene azoles fluorine humulone+ + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
79th, 21% benzene azoles fluorine humulone mesotrione suspending agent (12+9)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 12%+9% mesotrione of benzene azoles fluorine humulone disperses + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of agent+1.5%+water is supplied.
80th, 16% benzene azoles fluorine humulone topramezone suspending agent (12+4)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 12%+4% topramezone of benzene azoles fluorine humulone disperses + 2.0%+5% glycerine of aluminium-magnesium silicate of+0.2% xanthans of the fatty alcohol polyoxyethylene ether of agent+1.5%+water is supplied.
81st, 18% benzene azoles fluorine humulone ring sulphur ketone suspending agent (12+6)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 12%+6% ring sulphur ketone of benzene azoles fluorine humulone+ + 1.8%+5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
82nd, 18% benzene azoles fluorine humulone fluorine benzofenap suspending agent (12+6)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 12%+6% fluorine benzofenap of benzene azoles fluorine humulone disperses + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of the fatty alcohol polyoxyethylene ether of agent+1.5%+water is supplied.
83rd, 17% benzene azoles fluorine humulone furans sulphur humulone suspending agent (12+5)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+5% furans sulphur humulone of benzene azoles fluorine humulone + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of the fatty alcohol polyoxyethylene ether of powder+1.5%+water is supplied.
84th, 29% benzene azoles fluorine humulone benzobicylon suspending agent (12+17)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+17% benzobicylon of benzene azoles fluorine humulone + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of powder+1.5%+water is supplied.
85th, 32% benzene azoles fluorine humulone lancotrione suspending agents (24+8)
24% benzene azoles fluorine humulone+8%lancotrione+4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinities + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of powder+1.5%+water is supplied.
86th, the 11% benzene azoles fluorine humulone dispersible oil-suspending agent of sulphonyl grass pyrazoles (9+2)
+ 6% nonylphenol polyoxyethylene ether of+2%+5% calcium dodecyl benzene sulfonate of sulphonyl grass pyrazoles of 9% benzene azoles fluorine humulone+ + 2.5% fumed silica+10%150# solvent naphthas of+2.5% organobentonite of 4% castor oil polyoxyethylene ether+oleic acid first Ester is supplied.
87th, 36% benzene azoles fluorine humulone pyrazolate suspending agent (3+33)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+33% pyrazolate of benzene azoles fluorine humulone+ + 1.4%+5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
88th, 33% benzene azoles fluorine humulone benzofenap suspending agent (3+30)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+30% benzofenap of benzene azoles fluorine humulone+ + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
89th, 32% benzene azoles fluorine humulone tolpyralate suspending agents (12+20)
12% benzene azoles fluorine humulone+20%tolpyralate+4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salts + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of dispersant+1.5%+water is supplied.
90th, 32% benzene azoles fluorine humulone fenquinotrione suspending agents (12+20)
12% benzene azoles fluorine humulone+20%fenquinotrione+4% phenethyl phenol polyethenoxy ether phosphate triethanolamines + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of dipersant+1.5%+water is supplied.
91st, 31% benzene azoles fluorine humulone fluorochloridone suspending agent (6+25)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 6%+25% fluorochloridone of benzene azoles fluorine humulone disperses + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of agent+1.5%+water is supplied.
92nd, 22% benzene azoles fluorine humulone flurtamone suspending agent (12+10)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 12%+10% flurtamone of benzene azoles fluorine humulone + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of+1.5% fatty alcohol polyoxyethylene ether+water is supplied.
93rd, 29% benzene azoles fluorine humulone beflubutamid suspending agent (12+17)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 12%+17% beflubutamid of benzene azoles fluorine humulone + 1.5%+5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of the fatty alcohol polyoxyethylene ether of powder+1.5%+water is supplied.
94th, 40% benzene azoles fluorine humulone norflurazon suspending agent (3+37)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 3%+37% norflurazon of benzene azoles fluorine humulone+ + 1.4%+5% glycerine of aluminium-magnesium silicate of+0.14% xanthans of 1.5% fatty alcohol polyoxyethylene ether+water is supplied.
95th, 52% benzene azoles fluorine humulone fluridone water dispersible granules (2+50)
+ 1% disintegrant of 2%+6% pull open powder of benzene azoles fluorine humulone+8% polycarboxylic acid salt's dispersant of+50% fluridone gathers The precipitated silica of vinyl alcohol+5%+filler diatomite is supplied.
96th, 46% benzene azoles fluorine humulone prosulfocarb suspension emulsion (2+44)
+ 3% phenethyl phenol polyethenoxy ether sulphonic acid ester triethanolamine dipersant of 2%+44% prosulfocarb of benzene azoles fluorine humulone+ + 0.12%+5% glycerine of xanthans of+2.5% castor oil polyoxyethylene ether of 1% phenethyl phenol polyethenoxy ether+water is supplied.
97th, 53% benzene azoles fluorine humulone molinate suspension emulsion (3+50)
+ 3% phenethyl phenol polyethenoxy ether sulphonic acid ester triethanolamine dipersant of 3%+50% molinate of benzene azoles fluorine humulone+ + 0.05%+5% glycerine of xanthans of+2.5% castor oil polyoxyethylene ether of 1% phenethyl phenol polyethenoxy ether+water is supplied.
98th, 53% benzene azoles fluorine humulone benthiocarb suspension emulsion (3+50)
+ 3% phenethyl phenol polyethenoxy ether sulphonic acid ester triethanolamine dipersant of 3%+50% benthiocarb of benzene azoles fluorine humulone+ + 0.06%+5% glycerine of xanthans of+2.5% castor oil polyoxyethylene ether of 1% phenethyl phenol polyethenoxy ether+water is supplied.
99th, 50% benzene azoles fluorine humulone benfuresate suspension emulsion (3+47)
+ 3% phenethyl phenol polyethenoxy ether sulphonic acid ester triethanolamine dipersant of 3%+47% benfuresate of benzene azoles fluorine humulone+ + 0.08%+5% glycerine of xanthans of+2.5% castor oil polyoxyethylene ether of 1% phenethyl phenol polyethenoxy ether+water is supplied.
100th, 29% benzene azoles fluorine humulone ethofumesate suspension emulsion (2.25+26.75)
2.25%+3% phenethyl phenol polyethenoxy ether sulphonic acid ester of benzene azoles fluorine+26.75% ethofumesate of humulone, three ethanol + 5% glycerine of+0.15% xanthans of amine salt dispersant+2.5% castor oil polyoxyethylene ether of+1% phenethyl phenol polyethenoxy ether + water is supplied.
101st, 28% benzene azoles fluorine humulone tri-allate suspension emulsion (3+25)
+ 3% phenethyl phenol polyethenoxy ether sulphonic acid ester triethanolamine dipersant of 3%+25% tri-allate of benzene azoles fluorine humulone+ + 0.15%+5% glycerine of xanthans of+2.5% castor oil polyoxyethylene ether of 1% phenethyl phenol polyethenoxy ether+water is supplied.
102nd, 35% benzene azoles fluorine humulone benthiocarb suspension emulsion (3+32)
+ 3% phenethyl phenol polyethenoxy ether sulphonic acid ester triethanolamine dipersant of 3%+32% benthiocarb of benzene azoles fluorine humulone+ + 0.15%+5% glycerine of xanthans of+2.5% castor oil polyoxyethylene ether of 1% phenethyl phenol polyethenoxy ether+water is supplied.
103rd, 61% benzene azoles fluorine humulone vernolate water dispersible granules (3+58)
+ 1% poly- second of disintegrant of 3%+6% pull open powder of benzene azoles fluorine humulone+8% polycarboxylic acid salt's dispersant of+58% vernolate The precipitated silica of enol+5%+filler diatomite is supplied.
104th, the special suspension emulsion (12+20) of 32% benzene azoles fluorine humulone fourth grass
Special+3% phenethyl phenol polyethenoxy ether sulphonic acid ester triethanolamine dipersant of+20% fourth of 12% benzene azoles fluorine humulone grass + 0.15%+5% glycerine of xanthans of+2.5% castor oil polyoxyethylene ether of+1% phenethyl phenol polyethenoxy ether+water is supplied.
105th, 32% benzene azoles fluorine humulone cycloate suspension emulsion (12+20)
+ 3% phenethyl phenol polyethenoxy ether sulphonic acid ester triethanolamine dipersant of 12%+20% cycloate of benzene azoles fluorine humulone + 0.16%+5% glycerine of xanthans of+2.5% castor oil polyoxyethylene ether of+1% phenethyl phenol polyethenoxy ether+water is supplied.
106th, 36% benzene azoles fluorine humulone dimepiperate suspension emulsion (3+33)
+ 3% phenethyl phenol polyethenoxy ether sulphonic acid ester triethanolamine dipersant of 3%+33% dimepiperate of benzene azoles fluorine humulone+ + 0.15%+5% glycerine of xanthans of+2.5% castor oil polyoxyethylene ether of 1% phenethyl phenol polyethenoxy ether+water is supplied.
107th, 70% benzene azoles fluorine humulone esprocarb water dispersible granules (3+67)
+ 1% poly- second of disintegrant of 3%+6% pull open powder of benzene azoles fluorine humulone+6% polycarboxylic acid salt's dispersant of+67% esprocarb The precipitated silica of enol+5%+filler diatomite is supplied.
108th, 21% benzene azoles fluorine humulone Dichloroquinolinic acid suspending agent (6+15)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 6%+15% dichloro quinolinic acid of benzene azoles fluorine humulone + 18%+5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of the fatty alcohol polyoxyethylene ether of powder+1.5%+water is supplied.
109th, 43% benzene azoles fluorine humulone picloram water dispersible granules (3+40)
+ 1% disintegrant of 3%+6% pull open powder of benzene azoles fluorine humulone+5% polycarboxylic acid salt's dispersant of+40% picloram The precipitated silica of polyvinyl alcohol+5%+filler diatomite is supplied.
110th, the 11% benzene azoles fluorine humulone dispersible oil-suspending agent of chlorine fluorine pyridine ester (9+2)
+ 6% nonylphenol polyoxyethylene ether of+2%+5% calcium dodecyl benzene sulfonate of chlorine fluorine pyridine ester of 9% benzene azoles fluorine humulone+ + 2.5% fumed silica+10%150# solvent naphthas of+2.8% organobentonite of 4% castor oil polyoxyethylene ether+oleic acid first Ester is supplied.
111st, 28% benzene azoles fluorine humulone 2-methyl-4-chlorophenoxyacetic acid suspension emulsion (9+19)
9% benzene azoles fluorine humulone+19%2- methyl-three second of the phenethyl phenol polyethenoxy ether of 4-chlorophenoxyacetic acid+3% sulphonic acid ester + 0.12% xanthans+5% of+2.5% castor oil polyoxyethylene ether of+1% phenethyl phenol polyethenoxy ether of hydramine dipersant the third three Alcohol+water is supplied.
112nd, the 28% chloro- phenol second thioesters water dispersible granules (3+25) of benzene azoles fluorine humulone 2- methyl -4-
3% chloro-+8% polycarboxylic acid salt's dispersants+6% of phenol second thioesters of benzene azoles fluorine humulone+25%2- methyl -4- pull open + 5% precipitated silica of the disintegrant polyvinyl alcohol of powder+1%+filler diatomite is supplied.
113rd, 25% benzene azoles fluorine humulone 2- methyl -4- chlorine phenoxy propionic acid water dispersible granules (3+22)
+ 6% pull open powder of 3%+8% polycarboxylic acid salt's dispersant of benzene azoles fluorine humulone+22%2- methyl -4- chlorine phenoxy propionic acids+ 1%+5% precipitated silica of disintegrant polyvinyl alcohol+filler diatomite is supplied.
114th, 25% benzene azoles fluorine humulone 2-methyl-4-chlorophenoxyacetic acid sodium water dispersible granules (3+22)
3% benzene azoles fluorine humulone+22%2- methyl -+6% pull open powder of+8% polycarboxylic acid salt's dispersant of 4-chlorophenoxyacetic acid sodium + 1%+5% precipitated silica of disintegrant polyvinyl alcohol+filler diatomite is supplied.
115th, the 35% different monooctyl ester suspension emulsion (3+32) of benzene azoles fluorine humulone 2-methyl-4-chlorophenoxyacetic acid
The 3% benzene azoles fluorine humulone+32%2- methyl-different phenethyl phenol polyethenoxy ether of monooctyl ester+3% sulfonic acid of 4-chlorophenoxyacetic acid + 0.15% xanthans of+2.5% castor oil polyoxyethylene ether of ester triethanolamine+1% phenethyl phenol polyethenoxy ether of dipersant+ 5% glycerine+water is supplied.
116th, 15% benzene azoles fluorine humulone 2,4 dichlorophenoxyacetic acid butyl ester suspension emulsion (3+12)
+ 3% phenethyl phenol polyethenoxy ether sulphonic acid ester three of 3% benzene azoles fluorine humulone+12%2,4- dichlorobenzene oxygen butyl acetates + 0.22% xanthans+5% third of+2.5% castor oil polyoxyethylene ether of+1% phenethyl phenol polyethenoxy ether of ethanolamine salt dispersant Triol+water is supplied.
117th, 17% benzene azoles fluorine humulone 2, the different monooctyl ester suspension emulsion (3+14) of 4- dichlorphenoxyacetic acids
3% benzene azoles fluorine humulone+14%2, the different phenethyl phenol polyethenoxy ether of monooctyl ester+3% sulphonic acid ester of 4- dichlorphenoxyacetic acids + 0.22% xanthans+5% of+2.5% castor oil polyoxyethylene ether of+1% phenethyl phenol polyethenoxy ether of triethanolamine dipersant Glycerine+water is supplied.118th, the 12% benzene azoles fluorine humulone 4- dispersible oil-suspending agents of (2,4 dichloro benzene epoxide) propionic acid (3+9)
+ 6% nonyl phenol of 3% benzene azoles fluorine humulone+9%4- (2,4 dichloro benzene epoxide) calcium dodecyl benzene sulfonate of propionic acid+5% + 2.5% fumed silica+10%150# of+2.8% organobentonite of the castor oil polyoxyethylene ether of polyoxyethylene ether+4% is molten Agent oil+methyl oleate is supplied.
119th, 27% benzene azoles fluorine humulone quinmerac suspending agent (9+18)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salinity of 9%+18% quinmerac of benzene azoles fluorine humulone + 1.6%+5% glycerine of aluminium-magnesium silicate of+0.16% xanthans of the fatty alcohol polyoxyethylene ether of powder+1.5%+water is supplied.
120th, 13% benzene azoles fluorine Cao Tong oxaziclomefones suspending agents (9+4)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine dipersant of 9%+4% oxaziclomefone of benzene azoles fluorine humulone + 1.8%+5% glycerine of aluminium-magnesium silicate of+0.18% xanthans of+1.5% fatty alcohol polyoxyethylene ether+water is supplied.
121st, 28% benzene azoles fluorine humulone cinmethylin suspending agent (24+4)
+ 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 24%+4% cinmethylin of benzene azoles fluorine humulone disperses + 1.2%+5% glycerine of aluminium-magnesium silicate of+0.12% xanthans of the fatty alcohol polyoxyethylene ether of agent+1.5%+water is supplied.
122nd, 38% benzene azoles fluorine humulone sulphosate water dispersible granules (1.5+36.5)
+ 1% disintegrant of 1.5%+6% pull open powder of benzene azoles fluorine humulone+8% polycarboxylic acid salt's dispersant of+36.5% sulphosate The precipitated silica of polyvinyl alcohol+5%+filler diatomite is supplied.
123rd, 30% benzene azoles fluorine humulone bialaphos water dispersible granules (2.25+27.75)
+ 6% pull open powder+1% of 2.25%+8% polycarboxylic acid salt's dispersant of benzene azoles fluorine+27.75% bialaphos of humulone collapses + 5% precipitated silica of solution agent polyvinyl alcohol+filler diatomite is supplied.
124th, 35% benzene azoles fluorine humulone essence glufosinate-ammonium water dispersible granules (4.5+30.5)
Smart+6% pull open powder+1% of the polycarboxylic acid salt of glufosinate-ammonium+8% dispersant of 4.5% benzene azoles fluorine humulone+30.5% is disintegrated + 5% precipitated silica of agent polyvinyl alcohol+filler diatomite is supplied.
125th, 45% benzene azoles fluorine humulone paraquat water dispersible granules (4.5+40.5)
+ 1% disintegrant of 4.5%+6% pull open powder of benzene azoles fluorine humulone+8% polycarboxylic acid salt's dispersant of+40.5% paraquat The precipitated silica of polyvinyl alcohol+5%+filler diatomite is supplied.
126th, 55% benzene azoles fluorine humulone sulphur grass Lingshui Spring dispersible granule (2.25+52.75)
Clever+8% polycarboxylic acid salt's dispersant+6% pull open powder+1% disintegration of+52.75% sulphur of 2.25% benzene azoles fluorine humulone grass + 5% precipitated silica of agent polyvinyl alcohol+filler diatomite is supplied.
127th, the 26% benzene azoles dispersible oil-suspending agent of fluorine humulone Thistrol (3+23)
+ 6% nonylphenol polyoxyethylene ether of 3%+5% calcium dodecyl benzene sulfonate of benzene azoles fluorine+23%2 mcpb 2 of humulone+ + 2.5% fumed silica+10%150# solvent naphthas of+2.8% organobentonite of 4% castor oil polyoxyethylene ether+oleic acid first Ester is supplied.
128th, 20% benzene azoles fluorine humulone 2, the dispersible oil-suspending agent of 4- Embutoxs (4.5+15.5)
4.5% benzene azoles fluorine humulone+15.5%2 ,+6% polyoxyethylene nonyl phenyl second of+5% calcium dodecyl benzene sulfonate of 4- Embutoxs + 2.5% fumed silica+10%150# solvent naphthas of+2.8% organobentonite of+4% castor oil polyoxyethylene ether of alkene ether+ Methyl oleate is supplied.
Above-mentioned suspension emulsion process equipment:Mixing kettle, colloid mill, sand mill, cutter etc..
Above-mentioned suspension emulsion process:Aqueous-phase material material is put into mixing kettle, colloid mill is crossed after being stirred, is entered afterwards Sand mill three-level sanding, finally shears uniformly in cutter, is shifted after chemical examination is qualified spare；Oil phase material is put into mixing kettle In, add solvent naphtha and emulsifying agent, stirring and dissolving are uniform；Aqueous-phase material material is added in cutting kettle afterwards, and under shearing condition, Oil phase material is slowly pumped into cutting kettle, is sheared in Chou Liao, continues shearing uniformly, after chemical examination is qualified, is transferred to storage tank filling Dress.
Above-mentioned aqueous suspension agent process equipment:Mixing kettle, colloid mill, sand mill, cutter etc..
Above-mentioned aqueous suspension agent process:By all materials put into mixing kettle in, after being stirred cross colloid mill, it is laggard Enter sand mill three-level sanding, finally sheared in cutter uniformly, after chemical examination is qualified, it is filling to be transferred to storage tank.
Above-mentioned dispersible oil-suspending agent process equipment:Mixing kettle, colloid mill, sand mill, cutter etc..
Above-mentioned dispersible oil-suspending agent process:All materials are put into mixing kettle, colloid mill is crossed after being stirred, Enter sand mill three-level sanding afterwards, finally sheared in cutter uniformly, after chemical examination is qualified, it is filling to be transferred to storage tank.
Above-mentioned water dispersible granules process equipment:Airslide disintegrating mill, coulter type mixer, basket comminutor, drying box, screening Machine etc..
Above-mentioned water dispersible granules process:Above-mentioned material was uniformly mixed air-flow crushing, adds water to enter to mediate granulation, it After dry, final sizing obtains finished product.
B) the test of pesticide effectiveness
After seedling cauline leaf spraying treatment:
1) experimental condition
1.1), for trying target
Ox chickweed picks up from Jiangsu Xinghua, and Descurainia sophia picks up from Taian Shandong.Above-mentioned weeds use pot-culture method culture, with 180 х 140mm plastic nutrition bowls, are placed in enamel tray, built-in that the topsoil (at 4/5) for backing through and air-drying sieving, soil are adopted from farmland Humidity is controlled 20% initial stage, selects the homogeneous weed seed of full seed, with 25 DEG C of warm water soak 6 it is small when, in 28 DEG C of lifes Change vernalization in incubator (dark), the weed seed just to have showed money or valuables one carries unintentionally is uniformly placed in soil surface, according to seed particle size size Then earthing 0.5-1cm.
1.2), condition of culture
Carried out in controllable heliogreenhouse, 20~30 DEG C of temperature, natural lighting, relative humidity 57%~72%.
Soil types is loam, the content of organic matter 1.63%, pH=7.1, alkali-hydrolyzable nitrogen 84.3mg/kg, rapid available phosphorus 38.5mg/kg, available potassium 82.1mg/kg.
1.3), instrument and equipment
3WP-2000 type walking spray towers, Nanjing Agricultural Machinery Inst., Ministry of Agriculture.GA10 type a ten thousandth electronics day Flat (Germany)；ZDR2000 intelligent datas recorder (Hangzhou Ze great Instrument Ltd.)；SPX type Intelligent biochemistry incubators (Ningbo Jiangnan instrument plant).
2) experimental design
2.1), reagent
2.1.1), test medicine
Required active ingredient B is bought by Reagent Company, and A produces for our company.
Active compound uses acetone as solvent, is diluted with -80 aqueous solution of 0.1% emulsifier tween of content, current existing dilution.
2.2), test process
2.2.1), dosage is set
Match or during content, should be weighed from the action character of two kinds of medicaments and its virulence etc. in definite A and active ingredient B, It is also contemplated that the main application target of the formula.This research is on the basis of prerun early period, if A, B activity component are alone and mix Dosage is shown in Table lattice respectively.Blank control is used as using the water without medicament, containing same solvent and emulsifying agent.
2.2.2), experiment repeats
Often processing is repeated 4 times, and often handles 3 basins every time, and per basin, sowing weed seed 20, often handles totally 60 plants.
2.3), processing mode
2.3.1), processing time and number
Experiment shares medicine 1 time.Treat the 2 leaf phase of weeds, thinning, keep 15 plants of weeds in per basin, often processing retains 45 plants, then Continue culture to ox chickweed, 3 leaf of Descurainia sophia to be handled.
2.3.2), using apparatus and administrated method
Cultured examination material is uniformly placed in area 0.5m2Platform on, with 3WP-2000 type walking spray tower stems Foliar spray mist, spouting liquid is based on 30 kilograms/hectare.Atomisation pressure 0.3MPa.After whole liquid medicine jets are complete, air valve is closed, after 30 seconds, Spraying pyller is opened, takes out nutritive cube.Then air valve is opened, sprays clear water 50mL, cleans sparge pipe.
3) test method
Using pot-culture method.Weeds culture is shown in 1.1, reference《Farm-chemical indoor determination test rule herbicide》Carry out.With Prescription method is shown in 2.3.2, using cauline leaf process method.Greenhouse cellar culture is moved into after processing, 1-2cm water is remained during experiment Layer.
4) data survey and statistical analysis
4.1), investigation method
Using absolute number investigation method, the survival whole strain seedling of weeds is cut off along soil surface with blade, is weighed with assay balance Weeds fresh weight.It is based on zero by fresh weight for dead weeds.
4.2), control time and number
Investigate within 20 days after processing, investigate 1 time altogether.
4.3), data statistic analysis
The theoretical fresh weight inhibition (E0=X+Y-X*Y/100) of each processing hybrid combining, Ran Houyu are calculated with Gowing methods Actual measurement inhibiting rate (E) compares, the two mixed synergy type to weeds of evaluation, makees when E-E0 values are more than 10% for synergy With, less than -10% be antagonism, be addition between -10%~10%.It is and special according to actual preventive effect and herbicide The factors such as point, the balance being formulated determine optimum proportioning.
X is fresh weight inhibition when active components A dosage is P in formula；Y is that fresh weight when active ingredient B dosages are Q suppresses Rate.
Closed soil treatment:
1) experimental condition
1.1), for trying target
Ox chickweed picks up from Jiangsu Xinghua, and Descurainia sophia picks up from Taian Shandong.
1.2), condition of culture
Carried out in controllable heliogreenhouse, 20~30 DEG C of temperature, natural lighting, relative humidity 57%~72%.
Soil types is loam, the content of organic matter 1.63%, pH=7.1, alkali-hydrolyzable nitrogen 84.3mg/kg, rapid available phosphorus 38.5mg/kg, available potassium 82.1mg/kg.Experiment soil is quantitatively filled at the 3/4 of basin alms bowl, is then poured from basin alms bowl bottom, is made soil Earth is moistened to saturation state completely.By pretreatment for examination weed seed, equal and quantitative broadcasts sowing surface, according to seed size earthing 0.5-2cm, it is spare when after planting 24 is small.
1.3), instrument and equipment
GA10 type a ten thousandth electronic balances (Germany)；ZDR2000 intelligent datas recorder (the limited public affairs of the big instrument in Hangzhou pool Department)；SPX type Intelligent biochemistries incubator (Ningbo Jiangnan instrument plant), pipettor etc..
2) experimental design
2.1), reagent
2.1.1), test medicine
Required active ingredient B is commercially available active compound, and A produces for our company.
Active compound uses acetone as solvent, is diluted with 0.1% emulsifying agent T-80 aqueous solutions of content, current existing dilution.
2.2), test process
2.2.1), dosage is set
, should be from the action character of two kinds of medicaments and its virulence etc. in definite A and when active ingredient B each groups distribution ratio or content Weigh, it is also contemplated that the main application target of the formula.This research is on the basis of prerun early period, if A, B activity component are alone And mixing dosage is shown in Table lattice respectively.Blank control is used as using the water without medicament, containing same solvent and emulsifying agent.
2.2.2), experiment repeats
Often processing is repeated 4 times, and often handles 3 basins every time, the sowing weed seed 30 per basin.
2) test method
Before processing is poured, and keeps 1-2cm water layers.Quantitative liquid medicine is taken with pipettor, according to experimental design from low dosage to height Dosage carries out pouring processing, 4 repetitions per treatment respectively；Greenhouse cellar culture is moved into after processing, is remained during experiment 1-2cm water layers.
3) data survey and statistical analysis
Identical with after seedling cauline leaf spraying treatment, so it will not be repeated.
Statistical result see the table below 1-126.
Table 1A is with pretilachlor mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 2A is with mefenacet mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 3A is with sulfone pyrrole grass azoles mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 4A is with anilofos mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 5A is with xylenol grass amine mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 6A is with fentrazamide mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 7A and three azole amide mixtures are to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 8A is with cafenstrole mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 9A is with piperophos mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 10A is with metazachlor mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 11A is with propachlor mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 12A is with pethoxamid mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 13A is with fomesafen mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 14A Yu Evil humulones mixtures are to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 15A is with oxadiargyl mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 16A is with pyraclonil mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 17A is with flumioxazin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 18A is with Huan Wu Evil humulones mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 19A is with tiafenacil mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 20A is with pyraflufen-ethyl mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 21A is with symetryne mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 22A is with terbutryn mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 23A is with dipropetryn mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 24A is with the net mixture of evil grass to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 25A is with desmetryn mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 26A is with ethiozin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 27A is with metamitron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 28A is with cyanazine mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 29A is with fluometuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 30A is with tebuthiuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 31A flutters grand mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment) with Sha
Table 32A is with afesin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 33A is with metobromuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 34A is with neburea mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 35A is with alcohol pyridazines mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 36A is with dimethametryn mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 37A is with trietazine mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 38A is with bromacil mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 39A is with lenacil mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 40A is with terbacil mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 41A is with methabenzthiazuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 42A is with Tupersan mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
The table 43A grand mixtures of Yu Yi Evil are to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 44A is with metoxuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 45A is with chloroxifenidium mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 46A is with trifluoro grass piperazine mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 47A is with cyclopyrimorate mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 48A is with propanil mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 49A is with pyridate mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 50A is with desmedipham mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 51A is with phenmedipham mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 52A is with pyrazosulfuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 53A is with the grand mixture of thiophene ketone sulphur to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 54A is with promazine Sulfometuron Methyl mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 55A is with piperazine pyrazosulfuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 56A is with ethoxysulfuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 57A is with orthosulfamuron mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 58A is with fluorine ketone sulphur grass amine mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 59A is with penoxsuam mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 60A is with cloransulammethyl mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 61A is with imazamox mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 62A is with AC 263222 mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 63A is with imazethapyr mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 64A is with Arsenal mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 65A is with KIH 6127 mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 66A is with trefanocide mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 67A is with butralin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 68A is with pendimethalin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 69A is with Amex820 mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 70A is with dithiopyr mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 71A is with ethalfluralin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 72A is with oryzalin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 73A is with benfluralin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 74A is with thiazopyr mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 75A is with pronamide mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 76A is with chlorthal mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 77A is with butamifos mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 78A is with sulphur humulone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 79A is with mesotrione mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 80A is with topramezone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 81A is with ring sulphur ketone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 82A is with fluorine benzofenap mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 83A is with furans sulphur humulone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 84A is with benzobicylon mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 85A is with lancotrione mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 86A is with sulphonyl grass pyrazoles mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 87A is with pyrazolate mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 88A is with benzofenap mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 89A is with tolpyralate mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 90A is with fenquinotrione mixtures to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 91A is with fluorochloridone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 92A is with flurtamone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 93A is with beflubutamid mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 94A is with norflurazon mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 95A is with fluridone mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 96A is with prosulfocarb mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 97A is with molinate mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 98A is with benthiocarb mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 99A is with benfuresate mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 100A is with ethofumesate mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 101A is with tri-allate mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 102A is with benthiocarb mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 103A is with vernolate mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 104A is with the special mixture of fourth grass to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 105A is with cycloate mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 106A is with dimepiperate mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 107A is with esprocarb mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 108A is with dichloro quinolinic acid mixture to the actual preventive effect of ox chickweed and synergy evaluation (soil treatment)
Table 109A is with picloram mixture to the actual preventive effect of ox chickweed and synergy evaluation (cauline leaf process)
Table 110A is with chlorine fluorine pyridine ester mixture to the actual preventive effect of ox chickweed and synergy evaluation (cauline leaf process)
Table 111A evaluates (cauline leaf with 2-methyl-4-chlorophenoxyacetic acid mixture to the actual preventive effect of Descurainia sophia and synergy Processing)
Table 112A evaluates (stem with the chloro- phenol second thioesters mixtures of 2- methyl -4- to the actual preventive effect of Descurainia sophia and synergy Leaf processing)
Table 113A evaluates (cauline leaf with 2- methyl -4- chlorine phenoxy propionic acid mixtures to the actual preventive effect of Descurainia sophia and synergy Processing)
Table 114A evaluates (stem with 2-methyl-4-chlorophenoxyacetic acid sodium mixture to the actual preventive effect of Descurainia sophia and synergy Leaf processing)
Table 115A evaluates the actual preventive effect of Descurainia sophia and synergy with the different monooctyl ester mixture of 2-methyl-4-chlorophenoxyacetic acid (cauline leaf process)
Table 116A and 2,4- dichlorobenzene oxygen butyl acetate mixture evaluate (cauline leaf to the actual preventive effect of Descurainia sophia and synergy Processing)
Table 117A and the different monooctyl ester mixture of 2,4- dichlorphenoxyacetic acid evaluate (stem to the actual preventive effect of Descurainia sophia and synergy Leaf processing)
Table 118A evaluates (stem with 4- (2,4 dichloro benzene epoxide) propionic acid mixtures to the actual preventive effect of Descurainia sophia and synergy Leaf processing)
Table 119A is with quinmerac mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 120A Yu oxaziclomefones mixtures are to the actual preventive effect of Descurainia sophia and synergy evaluation (soil treatment)
Table 121A is with cinmethylin mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 122A is with sulphosate mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 123A is with bialaphos mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 124A is with smart glufosinate-ammonium mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 125A is with paraquat mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 126A is with the clever mixture of sulphur grass to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 127A is with Thistrol mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
Table 128A is with 2,4- Embutoxs mixture to the actual preventive effect of Descurainia sophia and synergy evaluation (cauline leaf process)
C) field demonstration
Utilize embodiment 1) -128) made from herbicidal composition carry out weeds in field effect test.
Exemplary promote is carried out in Jiangsu Xinghua testing site within 2016 to test.The weeds that field occurs mainly have:Descurainia sophia, Shepherd's purse, ox chickweed, Yin Du indian rorippa herbs etc..
Test method:
Soil treatment:Before weeds germinate, hand sprayer, 45 kilograms/667m of the amount of being watered2, it is uniform using soil surface Spraying.
Cauline leaf process:Treat that weeds are in 3-4 leaf phases, hand sprayer, 30 kilograms/667m of the amount of being watered2, sprayed using cauline leaf Even spraying.
Specific test medicine and dosage refer to table 129,50 square metres of plot area, and often processing is repeated 4 times.45 days after dispenser Investigation preventive effect is shown in Table 129.
By a large number of experiments and exploration, it is an unexpected discovery of the invention that the composition is used to prevent and kill off Descurainia sophia, shepherd's purse, ox The weeds such as chickweed, Yin Du indian rorippa herbs, have surprising, unexpected synergistic effect, this synergistic effect is under low dosage Performance is more notable, can reduce dosage, reduces the pollution to environment, and rationally compounding reduces agricultural cost, to ALS, ACCase inhibitor resistant weeds are efficient, have good application prospect.At the same time by test in wheat paddock, corn field, rice The lawns such as field, peanut, sugarcane, sorghum, millet, potato, rape, soybean, cotton, vegetables, annual bluegrass, Festuca Arundinacea, Korea lawn grass Good selectivity and excellent synergistic effect are shown with crop, can develop into the herbicide combination product of extensive market value.
The field demonstration effect situation of complex composition described in table 129

Claims (10)

1. a kind of Herbicidal combinations of the fluorine of azoles containing benzene humulone, it is characterised in that active components A and activity including herbicidally effective amount Component B, wherein, active components A is benzene azoles fluorine humulone, and active ingredient B may be selected from the one or more of following compound：
1) VLCFA inhibitor class：Pretilachlor, mefenacet, sulfone pyrrole grass azoles, anilofos, xylenol grass amine, fentrazamide, Three azole amides, cafenstrole, piperophos, metazachlor, propachlor, pethoxamid；
2) PPO inhibitor class：Fomesafen, Evil humulones, oxadiargyl, pyraclonil, flumioxazin, Huan Wu Evil grass Ketone, tiafenacil, pyraflufen-ethyl；
3) PSII inhibitor class：Symetryne, terbutryn, dipropetryn, evil grass are net, desmetryn, ethiozin, metamitron, cyanogen grass Tianjin, fluometuron, tebuthiuron, Sha flutter grand, afesin, metobromuron, neburea, alcohol pyridazines, dimethametryn, trietazine, bromacil, ring Grass is fixed, terbacil, methabenzthiazuron, Tupersan, Yi Evil are grand, metoxuron, chloroxifenidium, trifluoro grass piperazine, cyclopyrimorate, Propanil, pyridate, desmedipham, phenmedipham；
4) ALS inhibitor class：Pyrazosulfuron, thiophene ketone sulphur are grand, promazine Sulfometuron Methyl, piperazine pyrazosulfuron, ethoxysulfuron, phonetic aniline sulphur Grand, fluorine ketone sulphur grass amine, penoxsuam, cloransulammethyl, imazamox, AC 263222, imazethapyr, Arsenal, KIH 6127；
5) microtubules inhibitor class：Trefanocide, butralin, pendimethalin, Amex820, dithiopyr, ethalfluralin, ammonia sulphur Happy spirit, benfluralin, thiazopyr, pronamide, chlorthal, butamifos；
6) HPPD inhibitor class：Sulphur humulone, mesotrione, topramezone, ring sulphur ketone, fluorine benzofenap, furans sulphur humulone, bicyclic sulphur Humulone, lancotrione, sulphonyl grass pyrazoles, pyrazolate, benzofenap, tolpyralate, fenquinotrione；
7) PDS inhibitor class：Fluorochloridone, flurtamone, beflubutamid, norflurazon, fluridone；
8) lipid synthesis (non-acetyl-CoA carboxylase) inhibitor class：Prosulfocarb, molinate, benthiocarb, benfuresate, ethoxy furan Straw colour, tri-allate, benthiocarb, vernolate, Ding Caote, cycloate, dimepiperate, esprocarb；
9) synthetic hormone class：Dichloro quinolinic acid, quinmerac, picloram, chlorine fluorine pyridine ester, 2- methyl -4- chlorobenzene oxygen The chloro- phenol second thioesters of acetic acid, 2- methyl -4-, 2- methyl -4- chlorine phenoxy propionic acid, 2-methyl-4-chlorophenoxyacetic acid sodium, 2- methyl - The different monooctyl ester of 4-chlorophenoxyacetic acid, 2,4 dichlorophenoxyacetic acid butyl ester, the different monooctyl ester of 2,4 dichlorophenoxyacetic acid, 4- (2,4 dichloro benzenes Epoxide) propionic acid, Thistrol, 2,4- Embutoxs；
10) EPSPS inhibitor class：Sulphosate；
11) GS inhibitor class：Bialaphos, smart glufosinate-ammonium；
12) PSI inhibitor class：Paraquat；
13) DHP inhibitor class：Sulphur grass spirit；
14) other：Oxaziclomefone, cinmethylin.
A kind of 2. Herbicidal combinations of the fluorine of azoles containing benzene humulone according to claim 1, it is characterised in that the weight ratio of A and B For 1:200-200:1, preferably 1:150-150:1.
A kind of 3. Herbicidal combinations of the fluorine of azoles containing benzene humulone according to claim 2, it is characterised in that the weight ratio of A and B For 1:100-100:1, preferably 1:50-50:1.
A kind of 4. Herbicidal combinations of the fluorine of azoles containing benzene humulone according to claim 3, it is characterised in that the weight ratio of A and B For 1:30-30:1, preferably 1:10-10:1.
A kind of 5. Herbicidal combinations of the fluorine of azoles containing benzene humulone according to any one of claims 1 to 4, it is characterised in that The mass percentage of A and B accounts for the 1-95% of total amount in the Herbicidal combinations.
A kind of 6. Herbicidal combinations of the fluorine of azoles containing benzene humulone according to claim 5, it is characterised in that the Herbicidal combination The mass percentage of A and B accounts for the 10-80% of total amount in thing.
A kind of 7. Herbicidal combinations of the fluorine of azoles containing benzene humulone according to claim 1 to 6 any one, it is characterised in that Carrier, surfactant are further included in the Herbicidal combinations.
A kind of 8. Herbicidal combinations of the fluorine of azoles containing benzene humulone according to claim 1 to 6 any one, it is characterised in that The specific preparation of the Herbicidal combinations is dispersible oil-suspending agent, aqueous suspension agent, suspension emulsion, wettable powder, missible oil, moisture Shot agent, aqueous emulsion or microemulsion.
A kind of 9. Herbicidal combinations of the fluorine of azoles containing benzene humulone according to claim 1 to 6 any one, it is characterised in that The Herbicidal combinations further comprise safener, it is selected from isoxadifen, cymolsulfamide, pyrazoles solution grass Ester, cloquintocetmexyl, gibberellic acid, furilazole and N- (2-2 methoxybenzoyls base) -4- [(methylaminocarbonyl) amino] benzene sulphur One or more in acid amides.
10. the Herbicidal combinations of the fluorine of azoles containing benzene humulone injurious weed in crop is prevented as described in claim 1 to 9 any one On application.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020019430A1 (en) * 2018-07-21 2020-01-30 青岛清原化合物有限公司 Ternary herbicidal composition containing hppd inhibitor herbicide and use thereof
CN110973141A (en) * 2019-12-25 2020-04-10 河北省农林科学院粮油作物研究所 Weeding composition, weeding preparation and application thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114586797B (en) * 2020-12-03 2023-09-01 青岛清原作物科学有限公司 Ternary weeding composition containing bentazone and rimsulfuron and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8778836B2 (en) * 2004-04-06 2014-07-15 Bayer Cropscience Lp Herbicidal compositions
CN105230629A (en) * 2015-11-17 2016-01-13 青岛清原抗性杂草防治有限公司 Synergic weeding composition
CN106259352A (en) * 2016-08-12 2017-01-04 泰安市农业科学研究院 A kind of cornfield weeding composition and application thereof

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105503728B (en) * 2015-12-31 2017-03-22 青岛清原化合物有限公司 Pyrazole compounds or salts thereof and preparation method thereof, and weedicide composition and application thereof
CN105831123B (en) * 2016-04-15 2018-01-23 青岛清原抗性杂草防治有限公司 A kind of cornfield weeding composition and its application
CN106135220A (en) * 2016-06-22 2016-11-23 泰安市农业科学研究院 A kind of cornfield weeding composition
CN106259401A (en) * 2016-08-02 2017-01-04 泰安市农业科学研究院 A kind of cornfield weeding composition and application thereof
CN106577715A (en) * 2016-11-01 2017-04-26 广东中迅农科股份有限公司 Pesticide composition containing benzene oxazole fluridon, nicosulfuron and fluroxypyr
CN106966983B (en) * 2017-05-02 2019-07-02 青岛清原化合物有限公司 Amorphous state benzene azoles fluorine humulone and its preparation method and application
CN107311930B (en) * 2017-07-13 2019-05-03 青岛清原化合物有限公司 Polybenzobisoxazole humulone B crystal form and its preparation method and application

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8778836B2 (en) * 2004-04-06 2014-07-15 Bayer Cropscience Lp Herbicidal compositions
CN105230629A (en) * 2015-11-17 2016-01-13 青岛清原抗性杂草防治有限公司 Synergic weeding composition
CN106259352A (en) * 2016-08-12 2017-01-04 泰安市农业科学研究院 A kind of cornfield weeding composition and application thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
买买提艾力等: "冬麦田播娘蒿防除效果比较试验总结", 《新疆农业科技》 *
孙建伟等: "氰草津防除小麦田播娘蒿效果初报", 《河南农业科学》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020019430A1 (en) * 2018-07-21 2020-01-30 青岛清原化合物有限公司 Ternary herbicidal composition containing hppd inhibitor herbicide and use thereof
CN110973141A (en) * 2019-12-25 2020-04-10 河北省农林科学院粮油作物研究所 Weeding composition, weeding preparation and application thereof

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