CN107897191B - Weeding composition containing topramezone and application thereof - Google Patents

Weeding composition containing topramezone and application thereof Download PDF

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Publication number
CN107897191B
CN107897191B CN201711096672.7A CN201711096672A CN107897191B CN 107897191 B CN107897191 B CN 107897191B CN 201711096672 A CN201711096672 A CN 201711096672A CN 107897191 B CN107897191 B CN 107897191B
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Prior art keywords
percent
benzoxaflutole
polyoxyethylene ether
evaluation
combination
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CN201711096672.7A
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CN107897191A (en
Inventor
彭学岗
赵德
刘娜
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Shandong Qingyuan Agricultural Crop Science Co.,Ltd.
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Qingdao Kingagroot Chemical Compound Co Ltd
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Priority to CN201711096672.7A priority Critical patent/CN107897191B/en
Priority to MX2020004852A priority patent/MX2020004852A/en
Priority to PCT/CN2017/112019 priority patent/WO2019090817A1/en
Publication of CN107897191A publication Critical patent/CN107897191A/en
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    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34
    • A01N57/04—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having alternatively specified atoms bound to the phosphorus atom and not covered by a single one of groups A01N57/10, A01N57/18, A01N57/26, A01N57/34 containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals

Abstract

The invention belongs to the field of pesticides, and particularly relates to a herbicidal composition containing topramezone and application thereof. The weeding composition comprises an active ingredient A and an active ingredient B which are used in a herbicidally effective amount, wherein A is topramezone, and B can be selected from one or more of the following compounds: VLCFA, PPO, PSII, ALS, microtubule assembly, HPPD, PDS, lipid synthesis, EPSPS, GS, PSI, DHP inhibitors and synthetic hormones. The composition can effectively prevent and kill weed problems such as descurainia sophia and caraway primula in crop fields, and has the characteristics of expanding weed control spectrum, reducing application amount, being safe to crops, generating synergistic effect, solving resistant weeds and the like.

Description

Weeding composition containing topramezone and application thereof
Technical Field
The invention belongs to the field of pesticides, and particularly relates to a herbicidal composition containing topramezone and application thereof.
Background
Chemical weeding is the most economic and effective means in preventing and removing weeds in farmlands, but the problems of drug resistance and resistance evolution of weeds and the like are easily caused by using a single variety or a single action mode of chemical herbicide continuously at a high dose for a long time.
The chemical structural formula of the benzoxaflutole is
Figure BDA0001462377920000011
The HPPD inhibitor herbicide is a newly developed HPPD inhibitor herbicide for treating stems and leaves after seedling emergence in the corn field, has excellent biological activity, and can effectively prevent and kill various malignant weeds in the corn field.
The reasonable compounding or mixing of the herbicide compound has the advantages of expanding the weed spectrum, improving the control effect, delaying the occurrence and development of drug resistance and drug resistance of weeds and the like, and is one of the most effective methods for solving the problems. Therefore, the development of a weeding composition variety which has high safety and wide weed control spectrum, can produce synergistic effect and solve the problem of resistant weeds is urgently needed in production.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides a herbicidal composition containing carfentrazone-ethyl and application thereof. The composition can effectively prevent and kill weed problems such as descurainia sophia and caraway primula in crop fields, and has the characteristics of expanding weed control spectrum, reducing application amount, being safe to crops, generating synergistic effect, solving resistant weeds and the like.
A herbicidal composition containing carfentrazone-ethyl, comprising a herbicidally effective amount of an active ingredient A and an active ingredient B, wherein the active ingredient A is carfentrazone-ethyl, and the active ingredient B can be selected from one or more of the following compounds:
1) class of VLCFA inhibitors: pretilachlor (CAS accession No. 51218-49-6), mefenacet (CAS accession No. 73250-68-7), xaflufen (CAS accession No. 447399-55-5), anilofos (CAS accession No. 64249-01-0), xylenolicamide (CAS accession No. 87674-68-8), fentrazamide (CAS accession No. 158237-07-1), triafamoxafen (CAS accession No. 212201-70-2), cafenstrole (CAS accession No. 125306-83-4), mepiquat (CAS accession No. 24151-93-7), praziquat (CAS accession No. 67129-08-2), propachlor (CAS accession No. 1918-16-7), dinhlor (CAS accession No. 106700-29-2);
2) PPO inhibitors, fomesafen (CAS registry number: 72178-02-0), oxadiazon (CAS registry number: 19666-30-9), oxadiargyl (CAS registry number: 39807-15-3), pyraclonil (CAS registry number: 158353-15-2), flumioxazin (CAS registry number: 103361-09-7), pentoxazone (CAS registry number: 110956-75-7), tiafenacil (CAS registry number: 1220411-29-9), pyraflufen (CAS registry number: 129630-19-9);
3) PSII inhibitors including simetryn (CAS accession number: 1014-70-6), terbutryn (CAS accession number: 886-50-0), ipratropium (CAS accession number: 4147-51-7), fenflurazine (CAS accession number: 845-52-3), diuron (CAS accession number: 1014-69-3), ethiozin (CAS accession number: 64529-56-2), metamitron (CAS accession number: 41394-05-2), cyanazine (CAS accession number: 21725-46-2), fluometuron (CAS accession number: 2164-17-2), buthiuron (CAS accession number: 34014-18-1), cypermethron (CAS accession number: 42609-52-9), chlorsulfuron (CAS accession number: 1746-81-2), bromuron (CAS accession number: 3060-89-7), Metrafenone (CAS accession No.: 555-37-3), pyridazinol (CAS accession No.: 40020-01-7), isopentazidine (CAS accession No.: 22936-75-0), madazine (CAS accession No.: 1912-26-1), bromacil (CAS accession No.: 314-40-9), lenacil (CAS accession No.: 2164-08-1), terbacil (CAS accession No.: 5902-51-2), methabenzthiazone (CAS accession No.: 18691-97-9), cyclosulfamuron (CAS accession No.: 1982-49-6), isooxanone (CAS accession No.: 55861-78-4), metoxuron (CAS accession No.: 19937-59-8), subtillon (CAS accession No.: 1982-47-4), trifluoxazine (CAS accession No.: 1258836-72-4), cyclopyrinate (CAS registry No. 499231-24-2), propanil (CAS registry No. 709-98-8), pyridate (CAS registry No. 55512-33-9), betalain (CAS registry No. 13684-56-5), betanin (CAS registry No. 13684-63-4);
4) ALS inhibitors such as pyrazosulfuron-ethyl (CAS accession No.: 93697-74-6), thiencarbazone-methyl (CAS accession No.: 317815-83-1), propyrisulfuron (CAS accession No.: 570415-88-2), metazosulfuron (CAS accession No.: 868680-84-6), ethoxysulfuron (CAS accession No.: 126801-58-9), pyriminosulfuron (CAS accession No.: 213464-77-8), triafamone-sodium (CAS accession No.: 96525-23-4), penoxsulam (CAS accession No.: 219714-96-2), cloransulam-methyl (CAS accession No.: 147150-35-4)), imazapyr (CAS accession No.: 114311-32-9), imazapyr (CAS accession No.: 104098-48-8), imazethapyr (CAS accession No.: 81385-77-5), Imazapyr (CAS registry number 81334-34-1), pyriminobac (CAS registry number 147411-69-6);
5) microtubule assembly inhibitors: trifluralin (CAS accession number: 1582-09-8), butralin (CAS accession number: 33629-47-9), pendimethalin (CAS accession number: 40487-42-1), dimethomorph (CAS accession number: 33629-47-9), dithiopyr (CAS accession number: 97886-45-8), ethambucil (CAS accession number: 55283-68-6), oryzalin (CAS accession number: 19044-88-3), flumetsulam (CAS accession number: 1861-40-1), thiazopyr (CAS accession number: 117718-60-2), propathyl (CAS accession number: 23950-58-5), dichlorosol (CAS accession number: 1861-32-1), and phorate (CAS accession number: 36335-67-8);
6) HPPD inhibitors: sulcotrione (CAS registry number: 99105-77-8), mesotrione (CAS registry number: 104206-82-8), topramezone (CAS registry number: 210631-68-8), tembotrione (CAS registry number: 335104-84-2), flurtamone (CAS registry number: 352010-68-5), benzofuranone (CAS registry number: 473278-76-1), bicyclophorione (CAS registry number: 156963-66-5), lancotrione (CAS registry number: 1486617-21-3), pyrazosulfuron-ethyl (CAS registry number: 365400-11-9), pyrazolate (CAS registry number: 58011-68-0), pyroxene (CAS registry number: 82692-44-2), tolpyralate (CAS registry number: 1101132-67-5), benzoquinotrione (CAS registry number: 1342891-70-6);
7) PDS inhibitors, fluorochloridone (CAS registry number 61213-25-0), flurtamone (CAS registry number 96525-23-4), beflubutamid (CAS registry number 113614-08-7), norflurazon (CAS registry number 27314-13-2), and fluridone (CAS registry number 59756-60-4);
8) lipid synthesis (non-acetyl-coa carboxylase) inhibitors: prosulfocarb (CAS registry number: 52888-80-9), molinate (CAS registry number: 2212-67-1), diclofop (CAS registry number: 28249-77-6), furbengal (CAS registry number: 68505-69-1), ethofumesate (CAS registry number: 26225-79-6), triallate (CAS registry number: 2303-17-5), prosulfocarb (CAS registry number: 28249-77-6), dichlorfon (CAS registry number: 1929-77-7), butantte (CAS registry number: 2008-41-5), dichlorfon (CAS registry number: 1134-23-2), pipindone (CAS registry number: 61432-55-1), penflufen (CAS registry number: 85785-20-2);
9) synthetic hormones, quinclorac (CAS accession number: 84087-01-4), chloroquine (CAS accession number: 90717-03-6), picloram (CAS accession number: 1918-02-1), chlorofluoropyridine (CAS accession number: 1390661-72-9), 2-methyl-4-chlorophenoxyacetic acid (CAS accession number: 94-74-6), 2-methyl-4-chlorophenoxyacetic acid thioester (CAS accession number: 25319-90-8), 2-methyl-4-chlorophenoxypropionic acid (CAS accession number: 93-65-2), sodium 2-methyl-4-chlorophenoxyacetate (CAS accession number: 3653-48-3), isooctyl 2-methyl-4-chlorophenoxyacetate (CAS accession number: 29450-45-1), Butyl 2, 4-dichlorophenoxyacetate (CAS registry number: 94-80-4), isooctyl 2, 4-dichlorophenoxyacetate (CAS registry number: 25168-26-7), 4- (2, 4-dichlorophenoxy) propionic acid (CAS registry number: 120-36-5), 2-methyl-4-chlorobutyric acid (CAS registry number: 94-81-5), 2, 4-d-butyric acid (CAS registry number: 94-82-6);
10) EPSPS inhibitors, phosphinothricin (CAS accession number: 81591-81-3);
11) GS inhibitors include bialaphos (CAS registry No. 35597-43-4), and glufosinate-ammonium (CAS registry No. 35597-44-5);
12) PSI inhibitors paraquat (CAS registry number: 1910-42-5);
13) DHP inhibitors sulforaphane (CAS accession number: 3337-71-1);
14) others, oxaziclomefone (CAS registry No.: 153197-14-9), cinmethylin (CAS registry No.: 87818-31-3).
Wherein the weight ratio of A to B is 1:200-200:1, preferably 1:150-150:1, more preferably 1:120-120: 1; further, the weight ratio of A and B is 1:100-100:1, preferably 1:80-80:1, more preferably 1:50-50: 1; further, the weight ratio of A and B is 1:30 to 30:1, preferably 1:10 to 10:1, more preferably 1:5 to 5: 1.
The mass percentage of A, B in the weeding composition accounts for 1-95% of the total amount, and preferably 10-80%.
The weeding composition also comprises conventional auxiliaries which comprise a carrier and a surfactant.
The term "carrier" herein denotes an organic or inorganic, natural or synthetic substance. They facilitate the application of the active ingredient, the carrier being generally inert and must be agriculturally acceptable, in particular for the treated plant. The carrier may be a solid, such as a clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, or the like; or liquids such as water, alcohols, ketones, petroleum distillates, aromatic or waxy hydrocarbons, chlorinated hydrocarbons, liquefied gases, etc.
Surfactants may include emulsifying, dispersing or wetting agents, which may be ionic or non-ionic. Examples which may be mentioned are salts of polyacrylic acids, lignosulphonates, salts of phenolsulphonic or naphthalenesulphonic acids, polymers of ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols, in particular alkylphenols or arylphenols, sulphosuccinates, taurine derivatives, in particular taurine alkyl esters, and phosphoric esters of alcohols or polyhydroxyethylated phenols, alkylsulfonates, alkylarylsulphonates, alkylsulfates, lauryl ether sulphates, fatty alcohol sulphates, and sulphated hexadec, heptadeca-and octadecanols and sulphated fatty alcohol glycol ethers, and furthermore condensates of naphthalene or naphthalenesulphonic acids with phenol and formaldehyde, polyoxyethylene octylphenyl ether, ethoxylated isooctylphenol, octylphenol or nonylphenol, alkylphenyl polyglycol ethers, tributylphenyl polyglycol ether, tristearylphenyl polyglycol ether, polystearylphenyl polyglycol ether, Alkylaryl polyether alcohols, alcohol and fatty alcohol/ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers, ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal, sorbitol esters, lignosulfite waste liquors, and also proteins, denatured proteins, polysaccharides (e.g. methylcellulose), hydrophobically modified starches, polyvinyl alcohols, polycarboxylates, polyalkoxylates, polyvinylamines, polyvinylpyrrolidone and copolymers thereof. At least one surfactant is required to be present to facilitate dispersion of the active ingredients in water and to facilitate their proper application to the plant.
The compositions may also contain various other components such as protective colloids, binders, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants, and polymers.
The compositions of the present invention may be diluted or used directly by the user prior to use. The formulation can be prepared by conventional processing methods, i.e., mixing the active substance with a liquid solvent or solid carrier, and adding one or more surfactants such as dispersants, stabilizers, wetting agents, binders, defoamers, etc.
The specific preparation of the weeding composition is dispersible oil suspending agent, water suspending agent, suspending emulsion, wettable powder, missible oil, water dispersible granule (dry suspending agent), emulsion in water and microemulsion.
In short, the compositions of the present invention may be mixed with solid and liquid additives conventionally used in prior art formulations.
In addition, the combination of compound a and pyridate and the combination of compound a and cycloprominate may be mixed with active substances known, for example, from "technical universe of new agricultural chemicals", chinese agro-scientific and technical press, 2010.9 and the references cited therein. For example, herbicidal active substances mentioned below (remarks: the name of the compound, or the generic name according to the International organization for standardization (ISO), or the chemical name, when appropriate with a code), acetochlor, butachlor, alachlor, propisochlor, metolachlor, s-metolachlor, pretilachlor, propachlor, butachlor, napropamide, R-laevo-napropamide, propanil, mefenacet, diphenoyl-oxamide, diflufenican, flumetsulam, bebutamid, dimethenamid, ethoxybenclamide, flufenacet, methoxyfenacet, metazachlor, isooxachlor, lofluvalinate, dimethenamid, butachlor, propisochlor, mefenamid, flucetochlor, propyzamide, dimethenamid, penoxsulam, propyne, dimethenamid, terbutamid, dimethenamid, dimethachlor, norfluramine, trifoliamine, chlorantraniliprole, propyzamide, penflufen, napropamide, acetometazachlor, naproxen, fenacet, pyraflufen, metolachlor, clofenamide, butachlor, butamidin, fluazinam, atrazine, simazine, prometryn, cyanazine, simetryn, ametryn, prometryn, ipretryn, fluroxypyr, terbutryn, terbutazine, triazineon, cyhalofop, ganciclovir, prometryn, simazine, triazazine, dimethametrazine, isopentetryn, cycloprozine, terbutryn, sec-butyn, terbutaline, terbutryn, metolachlor, cyhalofop, metolachlor, prometryn, simazine, atrazine, dimethametryn, dimethametin, terbutryn, metolachlor, dimethachlor, dimethozin, atrazine, metolachloraz, metolachlor, metolachlorethan, metolachlor, atrazine, metolachlorethan, atrazine, metolachlor, atrazine, metolachlor, atrazine, metolachlorfenbutazine, metolachlor, metolachlorfenbutazine, atrazine, metolachlor, atrazine, metolachlor, atrazine, metolachlor, atrazine, metolachlor, Cyanuric acid, Indaziflam, chlorsulfuron, metsulfuron, bensulfuron-methyl, chlorimuron-ethyl, tribenuron-methyl, thifensulfuron-methyl, pyrazosulfuron-ethyl, mesosulfuron-methyl, iodosulfuron-methyl sodium, formamidosulfuron, cinosulfuron, triasulfuron, sulfometuron-methyl, nicosulfuron, ethametsulfuron-methyl, amidosulfuron, ethoxysulfuron, cyclosulfamuron-methyl, rimsulfuron, azimsulfuron-methyl, monosulfuron-methyl, primisulfuron-methyl, flusulfuron-methyl, flazasulfuron-methyl, propsulfuron-methyl, prosulfuron-methyl, trifloxysulfuron, triflusulfuron-methyl, metsulfuron-methyl, primisulfuron-methyl, propulsulfuron-methyl, propaferon-methyl, triflusulfuron-methyl, sulfometuron-methyl, pyrisulfuron-methyl, propalis-ethyl, thiuron-methyl, sulfometuron-methyl, sulfometuron-ethyl, sulfometuron-ethyl, sulfofluridone, sulfometuron-ethyl, sulfofluridone, sulfometuron-methyl, sulfofluridone, sulfometuron-ethyl, benfluridone, bensulfuron-ethyl, bensulfuron-methyl, bensulfuron-ethyl, bensulfuron-methyl, bensulfuron-ethyl, bensulfuron-methyl, ben, Dicumyl ether, aclonifen, ethoxyfen-ethyl, bifenox, trifluoromethoxyfen, metoxyfen, trifluornitrofen, fluoroglycofen, fluridone, bifenox, dimethofen, fluazifop-butyl, Halosafen, chlortoluron, isoproturon, linuron, diuron, fenpropuron, fluometuron, methabenzthiazuron, benzuron, sulfosulfuron, clofenuron, tebuthiuron, clodinuron, meturon, metoxuron, bromuron, metoxuron, meturon, metoxuron, metoron, metoxuron, metoron, Betalain, asulam, tefurazone, avenacin, anilazine, chlorpropham, dichlofenamate, imazalil, cloropham, Carboxazole, chlorerprocarb, Fenasulam, BCPC, CPPC, Carbasulam, buticarb, thiobencarb, dimethenate, triallate, thiobencarb, dicofol, pyributicarb, chlochloate, dichlorfon, dodekafol, ethiofencarb, captan, prosulfocarb, thiobencarb, promethate, Isopolinate, Methiobencarb, 2, 4-chlorobutyl ester, 2 methyl 4-sodium chloride, 2, 4-chloroisooctyl ester, 2 methyl 4-chloroisooctyl ester, 2, 4-d sodium salt, 2, 4-dimethylxylyl ester, 2 methyl 4-chlorothioester, 2 methyl 4-chloropropionate, 2-methyl 4-chloropropionate, 2-4-chlorobutyric acid, 2-methyl 4-chlorobutyric acid, 2-chloro-4-methyl-butyric acid, 2, 4-chloro-4-methyl-4-chloro-butyric acid, 2-4-chloro-methyl-4-butyric acid, 2-chloro-4-chloro-butyric acid, 2-chloro-4-methyl-4-2-chloro-4-butyric acid, 2-chloro-2-4-2-chloro-4-chloro-butyric acid, 2-chloro-4-2-4-chloro-2-chloro-butyric acid, 2-4-chloro-2-4-2-chloro-2-chloro-2-4-2-butyric acid, 2-chloro-2-chloro-4-chloro-4-2-4-chloro-butyric acid, 2-chloro-2-4-2-4-2-chloro-2-4-2-4-2-4-2-chloro-2-4-2-chloro-2-4-2-4-2-D-2-4-2-4-2-4-D-2, 5-nasal discharge, 2,4, 5-nasal discharge propionic acid, 2,4, 5-nasal discharge butyric acid, 2-methyl-4-chloramine salt, dicamba, fenoxaprop-P-ethyl, varparvax, cyprosulfan, triclosan, dichlorfenac, metoclopramide, diclofop-p-ethyl, fluazifop-methyl, haloxyfop-p-ethyl, quizalofop-p-ethyl, fenoxaprop-p-ethyl, haloxyfop-ethyl, metamifop-ethyl, clomazone, benazol-ethyl, clodinafop-ethyl, oxyphenbutazone-ethyl, trifluoxime, isoxafen, paraquat, diquat, asulam, flutolfen, ethalfluron, terbufin, chloroethafluorin, mefenofos, benazol-p-ethyl, metocloprid, meprobamate, glufosinate, glyphosate, glufosinate, metocloprid, bensulam, glyphosate, bensulam, benfop-p-ethyl, bensulam, bensulin, bensulam, benazolin, benfluralin-p-ethyl, benazolin, benfluralin, benazolin, benfluralin-p-methyl, benfluralin-p-ethyl, benfluralin, Thiophosphoryl, piperazinone, bialaphos, bensulide, imazapyr, glufosinate, imazapyr, imazethapyr, imazaquin ammonium salt, imazapic, imazamethabenz ester, fluroxypyr, isooctyl fluroxypyr, clopyralid, picloram, triclopyr, dithiopyr, haloxydine, triclopyr, thiazopyr, aminopyralid, fluroxypyr, butoxyethyl triclopyr, Cliodinate, sethoxydim, cycloxydim, bentazone, metamitron, cycloxydim, benzone, tralkoxydim, metribuzin, amitridione, amibizin, bromoxynil, octanoyl nitrile, fenpropinil, pyrazoxynil, iodoxynil, haloxynil, and a, Oxypyr, Iodobonil, flumetsulam, florasulam, penoxsulam, sulfentrazone, cloransulam, diclosulam, pyroxsulam, fluroxypyr, bispyribac, pyribenzoxim, pyriminobac, pyrithiobac, bicyclophorione, mesotrione, sulcotrione, Tembotrione, Tefuryltrione, Bicyclopyrone, ketendidox, isoxaflutole, fenoxasulfofone, methiozolinin, ipropyr, pyraflufen, pyraflutole, pyroxaflutole, Pyroxasulfone, pyraflutole, Pyrasulfotole, pyraflutole, amicarbazone, flumiclazone, flumetsulam, mefenpyr, bensulam, bexathion, flumicloram, flumiclone, flumicloram, pyrazam, pyraflufenacetmol, pyraclofenacetmol, pyraclorac, pyraclofenap, flumiclone, flumicloram, Terbenol, terbutal, penitrol, dinitrophenol, chloronitrophenol, dimethomorph, oxadiargyl, oxadiazon, pentoxazone, flumetsulam, mefenoxaprop, fentrazamide, fluazifop-ethyl, desmetryn, bromatrazine, dimetaluron, pyridaben, Pyridafol, quinclorac, clomazone, bentazon, pyridate, oxadiargyl, benazolin, clomazone, cumquat-ethyl, propyl isopropyl ether, clofenpropathrin, indangrone, sodium chlorate, dalapon, trichloroacetic acid, monochloroacetic acid, hexachloroacetone, tetrafluoropropionic acid, mefenpyr, bromophenol oxime, triazasum, pyrazole, flurtamone, benfuresafen, ethofencarbazone, pyrimethanil, clodinafol, flutolanilide, acrolein, mefenapyr, clodinil, pyraclonil, metol, bensulam, clomazam, bensulam, clomazone, benflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenfluridone, benflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenfluridone, benfluridone, Metophenone, saflufenacil, chlorantraniliprole, trichloropropionic acid, Alorac, Diethamquat, Etnipromid, Iphrymam, Ipfancabazone, Thiencabazone-methyl, Pyrimisulfan, Chrerfluorazole, Tripropindan, Sulglycasin, Sumbellichler, Cambodhi, cyprodinic acid, thiocyananilide, cloquintocet, fencloquine, mequintocet, mefenpyr, mefenapyr, mefenpyr, furazol, imazaquin, flufenpyr, dichlofenac, dichlormid, halauxin, halauxifen, DOWFAUD, UBH-509, D489, 82-556, KPP-300, NC-324, NC-330, DPX-218, DPX-N-0789, KI-35-K-75, KIH-H-7, KC-3-H-751, KIH-3-H-75, and KIH-3-H-3-H-751.
The herbicidal composition further includes a safener selected from one or more of isoxadifen (CAS registry number: 163520-33-0), cyprosulfamide (CAS registry number: 221667-31-8), mefenpyr (CAS registry number: 135590-91-9), cloquintocet (CAS registry number: 99607-70-2), gibberellic acid (CAS registry number: 77-06-5), furilazole (CAS registry number: 121776-33-8), mecamifen (CAS registry number: 129531-12-0).
The compositions of the invention can be applied by spraying to the foliage of the plants to be treated, i.e. to the weeds, in particular to surfaces which are harmful or susceptible to infestation by weeds which are harmful to the growth of the crop.
When the herbicidal composition of the present invention is applied, an unexpected synergistic effect is obtained, and the herbicidal activity is more remarkable than the expected sum of the activities using individual herbicides, and the activities of the individual herbicides alone. The synergistic effect is manifested by reduced application rates, a broader spectrum of weed control, and a faster and longer lasting herbicidal action, which are desirable in the practice of weed control. These new compositions are clearly superior to existing herbicides in terms of the properties described.
The herbicidal composition of the present invention also has the following advantages:
(1) the composition is environment-friendly, is easy to degrade in the environment, and is suitable for various crop fields.
(2) The weeding composition has low cost and convenient use, and has great economic and social benefits when being popularized and applied.
Detailed Description
The following examples are not intended to limit the invention, but merely to illustrate how the invention may be carried out. These examples show particularly significant effectiveness against certain weeds. Examples are as follows:
A) examples of the embodiments
1. 42% benzoxaflutole pretilachlor suspoemulsion (12+30)
12% of benzoxaflutole, 30% of pretilachlor, 3% of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1% of phenethyl phenol polyoxyethylene ether, 2.5% of castor oil polyoxyethylene ether, 0.12% of xanthan gum, 5% of glycerol and water.
2. 42% benzoxaflutole mefenacet suspension concentrate (12+30)
12% of benzoxaflutole, 30% of mefenacet, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.13% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
3. 32% benzoxaflutole-sultopyr suspension concentrate (12+20)
12 percent of benzoxaflutole, 20 percent of sulfonepyrazoxazole, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.16 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
4. 32% benzoxaflutole-anilofos suspoemulsion (12+20)
12% of benzoxaflutole, 20% of anilofos, 3% of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1% of phenethyl phenol polyoxyethylene ether, 2.5% of castor oil polyoxyethylene ether, 0.14% of xanthan gum, 5% of glycerol and water.
5. 18% benzoxaflutole-xylenol oxamine dispersible oil suspending agent (3+15)
3% of benzoxaflutole, 15% of xylenol oxamine, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.0% of organobentonite, 1.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
6. 27% benzoxaflutole-fentrazamide suspending agent (12+15)
12 percent of benzoxaflutole, 15 percent of fentrazamide, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.16 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
7. 29% benzoxaflutole-triafamone suspending agent (12+17)
12% of benzoxaflutole, 17% of triazolam, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
8. 27% benzoxaflutole-cafenstrole suspending agent (12+15)
12% of benzoxaflutole, 15% of cafenstrole, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
9. 28% benzoxaflutole-piphos dispersible oil suspending agent (3+25)
3% of benzoxaflutole, 25% of piperafos, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.0% of organobentonite, 1.0% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
10. 31% benzoxaflutole-metazachlor suspoemulsion (6+25)
6 percent of benzoxaflutole, 25 percent of metazachlor, 3 percent of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1 percent of phenethyl phenol polyoxyethylene ether, 2.5 percent of castor oil polyoxyethylene ether, 0.15 percent of xanthan gum, 5 percent of glycerol and water.
11. 41% benzoxaflutole-propachlor suspoemulsion (3+38)
3% of benzoxaflutole, 38% of propachlor, 3% of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1% of phenethyl phenol polyoxyethylene ether, 2.5% of castor oil polyoxyethylene ether, 0.12% of xanthan gum, 5% of glycerol and water.
12. 43% benzoxaflutole-pethoxamid suspoemulsion (3+40)
3% of benzoxaflutole, 40% of dimethenamid, 3% of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1% of phenethyl phenol polyoxyethylene ether, 2.5% of castor oil polyoxyethylene ether, 0.12% of xanthan gum, 5% of glycerol and water.
13. 9% benzoxaflutole-fomesafen suspending agent (3+6)
3 percent of benzoxaflutole, 6 percent of fomesafen, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.22 percent of xanthan gum, 2.0 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
14. 52% benzoxaflutole-oxadiazon suspending agent (12+40)
12% of benzoxaflutole, 40% of oxadiazon, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.06% of xanthan gum, 0.6% of magnesium aluminum silicate, 5% of glycerol and water.
15. 18% benzoxaflutole-oxadiargyl suspending agent (12+6)
12% of benzoxaflutole, 6% of oxadiargyl, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.18% of xanthan gum, 1.8% of magnesium aluminum silicate, 5% of glycerol and water.
16. 27% benzoxaflutole-pyraclonil suspending agent (12+15)
12% of benzoxaflutole, 25% of pyraclonil, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
17. 18% benzoxaflutole-flumioxazin dispersible oil suspending agent (12+6)
12% of benzoxaflutole, 6% of flumioxazin, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
18. 39% benzoxaflutole-pentoxazone suspending agent (12+27)
12% of benzoxaflutole, 27% of pentoxazone, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
19. 28% benzoxaflutole tiafenacil suspension (24+4)
24% of benzoxaflutole, 4% of tiafenacil, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
20. 10% benzoxaflutole-pyraflufen dispersible oil suspension concentrate (9+1)
9 percent of benzoxaflutole, 1 percent of pyraflufen-ethyl, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of nonylphenol polyoxyethylene ether, 4 percent of castor oil polyoxyethylene ether, 3.0 percent of organobentonite, 2.5 percent of fumed silica, 10 percent of No. 150 solvent oil and methyl oleate.
21. 43% benzoxaflutole-simetryn suspending agent (12+31)
12% of benzoxaflutole, 31% of simetryn, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.12% of xanthan gum, 1.2% of magnesium aluminum silicate, 5% of glycerol and water.
22. 33% benzoxaflutole-terbutryn suspending agent (3+30)
3 percent of benzoxaflutole, 30 percent of terbutryn, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.16 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
23. 53% benzoxaflutole iprovale suspending agent (3+50)
3 percent of benzoxaflutole, 50 percent of iprclean, 2 percent of polycarboxylate dispersant, 3 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.06 percent of xanthan gum, 5 percent of glycerol and water.
24. 53% benzoxaflutole-phytocide suspending agent (3+50)
3% of benzoxaflutole, 50% of fenfluramine, 2% of polycarboxylate dispersant, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.06% of xanthan gum, 5% of glycerol and water.
25. 44% benzoxaflutole-diuron suspending agent (6+38)
6 percent of benzoxaflutole, 38 percent of dimethomon, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.12 percent of xanthan gum, 1.2 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
26. 30% benzoxaflutole-ethiziclomefone suspending agent (6+24)
6 percent of benzoxaflutole, 24 percent of ethiprole, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol-polyoxyethylene ether, 0.16 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
27. 67% benzoxaflutole-metamitron water dispersible granule (2+65)
2 percent of benzoxaflutole, 65 percent of metamitron, 5 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
28. 28% benzoxaflutole-cyanazine suspending agent (3+25)
3 percent of benzoxaflutole, 25 percent of cyanazine, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.16 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
29. 46% benzoxaflutole-fluometuron suspending agent (6+40)
6 percent of benzoxaflutole, 40 percent of fluometuron, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.08 percent of xanthan gum, 0.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
30. 33% benzoxaflutole-buthiuron suspension concentrate (3+30)
3% of benzoxaflutole, 30% of buthiuron, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
31. 28% benzoxaflutole-Shaplon suspending agent (3+25)
3 percent of benzoxaflutole, 25 percent of cypermethrin, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.16 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
32. 53% benzoxaflutole-chlorsulfuron suspending agent (3+50)
3 percent of benzoxaflutole, 50 percent of chlorsulfuron, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.06 percent of xanthan gum, 0.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
33. 39% benzoxaflutole-bromogluron suspending agent (6+33)
6 percent of benzoxaflutole, 33 percent of bromogluron, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.15 percent of xanthan gum, 1.5 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
34. 67% benzoxaflutole-dazomet water dispersible granule (3+64)
3 percent of benzoxaflutole, 64 percent of stephania, 5 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
35. 39% benzoxaflutole-pyridazinol suspending agent (6+33)
6 percent of benzoxaflutole, 33 percent of pyridazinol, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.14 percent of xanthan gum, 1.4 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
36. 45% benzoxaflutole-isoamyl ethrin suspending agent (3+42)
3 percent of benzoxaflutole, 42 percent of isoamyl alcohol, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.12 percent of xanthan gum, 1.2 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
37. 43% benzoxaflutole-madazine suspending agent (3+40)
3 percent of benzoxaflutole, 40 percent of atrazine, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.13 percent of xanthan gum, 1.3 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
38. 60% benzoxaflutole-weeding water dispersible granule (2.25+57.75)
2.25 percent of benzoxaflutole, 57.75 percent of bromacil, 6 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
39. 46% benzoxaflutole-cyclamen suspension concentrate (6+40)
6 percent of benzoxaflutole, 40 percent of cyclamen, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol-polyoxyethylene ether, 0.1 percent of xanthan gum, 1.0 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
40. 63% benzoxaflutole-terbacil water dispersible granule (3+60)
3 percent of benzoxaflutole, 60 percent of terbacil, 6 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
41. 26% benzoxaflutole-methabenzthiazuron suspension concentrate (12+14)
12% of benzoxaflutole, 14% of methabenzthiazuron, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
42. 63% benzoxaflutole-cyclosulfamuron water dispersible granule (3+60)
3 percent of benzoxaflutole, 60 percent of cyclosulfamuron, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
43. 36% benzoxaflutole-isoxolone suspending agent (3+33)
3 percent of benzoxaflutole, 33 percent of isooxauron, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.14 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
44. 70% benzoxaflutole-metoxuron water dispersible granule (3+67)
3 percent of benzoxaflutole, 67 percent of metoxuron, 5 percent of polycarboxylate dispersant, 5 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
45. 70% benzoxaflutole-subtilon water dispersible granule (3+67)
3 percent of benzoxaflutole, 67 percent of siduron, 4 percent of polycarboxylate dispersant, 5 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
46. 32% benzoxaflutole-trifluoxazine suspending agent (12+20)
12% of benzoxaflutole, 20% of trifluoxazine, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
47. 26% benzoxaflutole cycloprozole suspension (9+17)
9 percent of benzoxaflutole, 17 percent of cyclopyromate, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.16 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
48. 50% benzoxaflutole-propanil water dispersible granule (1.5+48.5)
1.5 percent of benzoxaflutole, 48.5 percent of propanil, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated silica and filler diatomite.
49. 49% benzoxaflutole-pyridate suspending agent (4.5+44.5)
4.5 percent of benzoxaflutole, 44.5 percent of pyridate, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.08 percent of xanthan gum, 5 percent of glycerol and water.
50. 36% benzoxaflutole-desmedipham suspension concentrate (4.5+31.5)
4.5 percent of benzoxaflutole, 31.5 percent of betaine, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.13 percent of xanthan gum, 1.3 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
51. 36% benzoxaflutole-phenmedine suspending agent (4.5+31.5)
4.5 percent of benzoxaflutole, 31.5 percent of betanin, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.13 percent of xanthan gum, 1.3 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
52. 14% benzoxaflutole-pyrazosulfuron dispersible oil suspension agent (12+2)
The composition is prepared by supplementing 12% of benzoxaflutole, 2% of pyrazosulfuron-ethyl, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.8% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
53. 15% benzoxaflutole-thiencarbazone-methyl dispersible oil suspending agent (12+3)
12% of benzoxaflutole, 3% of thiencarbazone-methyl, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.18% of xanthan gum, 1.8% of magnesium aluminum silicate, 5% of glycerol and water.
54. 18% benzoxaflutole-promethamsulfuron dispersible oil suspending agent (12+6)
12% of benzoxaflutole, 6% of propyrisulfuron, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.8% of organobentonite, 1.8% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
55. 19% benzoxaflutole-metazosulfuron dispersible oil suspension concentrate (12+7)
12% of benzoxaflutole, 7% of metazosulfuron, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.8% of organobentonite, 1.8% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
56. 27% benzoxaflutole-ethoxysulfuron dispersible oil suspending agent (24+3)
24% of benzoxaflutole, 3% of ethoxysulfuron, 5% of calcium dodecylbenzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.4% of organobentonite, 1.0% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
57. 17% benzoxaflutole-orthosulfamuron dispersible oil suspending agent (12+5)
12% of benzoxaflutole, 5% of orthosulfamuron, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.8% of organobentonite, 1.8% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
58. 29% benzoxaflutole-triafamone dispersible oil suspending agent (24+5)
24% of benzoxaflutole, 5% of triafamone, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.0% of organobentonite, 0.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
59. 14% benzoxaflutole-penoxsulam dispersible oil suspending agent (12+2)
The composition is prepared by supplementing 12% of benzoxaflutole, 2% of penoxsulam, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.5% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
60. 14% benzoxaflutole cloransulam dispersible oil suspending agent (12+2)
12% of benzoxaflutole, 2% of cloransulam, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.5% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
61. 15% benzoxaflutole-imazamox dispersible oil suspending agent (12+3)
12% of benzoxaflutole, 3% of imazamox, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.5% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
62. 22% benzoxaflutole-mebendazole nicotinic acid dispersible oil suspending agent (12+10)
12% of benzoxaflutole, 10% of mebendazole nicotinic acid, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
63. 19% benzoxaflutole-imazethapyr dispersible oil suspending agent (12+7)
12% of benzoxaflutole, 7% of imazethapyr, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.0% of organobentonite, 1.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
64. 28% benzoxaflutole-imazapyr dispersible oil suspending agent (3+25)
3% of benzoxaflutole, 25% of imazapyr, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.0% of organobentonite, 1.0% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
65. 15% benzoxaflutole-pyriminobac-methyl dispersible oil suspending agent (12+3)
The composition is prepared by supplementing 12% of benzoxaflutole, 3% of pyriminobac, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.2% of organobentonite, 1.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
66. 42% benzoxaflutole-trifluralin suspending agent (6+36)
6 percent of benzoxaflutole, 36 percent of trifluralin, 2 percent of polycarboxylate dispersant, 3 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.1 percent of xanthan gum, 0.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
67. 33% benzoxaflutole-butralin suspending agent (3+30)
3 percent of benzoxaflutole, 30 percent of butralin, 2 percent of polycarboxylate dispersant, 3 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.14 percent of xanthan gum, 1.4 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
68. 46% benzoxaflutole-pendimethalin suspension (6+40)
6 percent of benzoxaflutole, 40 percent of pendimethalin, 2 percent of polycarboxylate dispersant, 3 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.1 percent of xanthan gum, 0.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
69. 39% benzoxaflutole-dimethomon suspending agent (3+36)
3% of benzoxaflutole, 36% of dimetamine, 2% of polycarboxylate dispersant, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 5% of glycerol and water.
70. 39% benzoxaflutole-dithiopyr suspending agent (6+33)
6 percent of benzoxaflutole, 33 percent of dithiopyr, 2 percent of polycarboxylate dispersant, 3 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.1 percent of xanthan gum, 1.2 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
71. 38% benzoxaflutole-ethylbutenafine suspending agent (3+35)
3 percent of benzoxaflutole, 35 percent of ethambucol, 2 percent of polycarboxylate dispersant, 3 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.1 percent of xanthan gum, 1.2 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
72. 28% benzoxaflutole-amisulpride suspending agent (3+25)
3 percent of benzoxaflutole, 25 percent of sulfamethoxazole, 2 percent of polycarboxylate dispersant, 3 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.12 percent of xanthan gum, 1.2 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
73. 35% benzoxaflutole-flumetsulam suspending agent (6+29)
6 percent of benzoxaflutole, 29 percent of flumetsulam, 2 percent of polycarboxylate dispersant, 3 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.12 percent of xanthan gum, 1.2 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
74. 39% benzoxaflutole-thiazopyr suspension concentrate (6+33)
6 percent of benzoxaflutole, 33 percent of thiazopyr, 2 percent of polycarboxylate dispersant, 3 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.1 percent of xanthan gum, 1.2 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
75. 39% benzoxaflutole-naproxen suspending agent (6+33)
6 percent of benzoxaflutole, 33 percent of naproxen, 2 percent of polycarboxylate dispersant, 3 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.12 percent of xanthan gum, 1.2 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
76. 53% benzoxaflutole-chlorthal suspending agent (3+50)
3 percent of benzoxaflutole, 50 percent of dichlorvos, 2 percent of polycarboxylate dispersant, 3 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.1 percent of xanthan gum, 0.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
77. 58% benzoxaflutole-pyrazophos water dispersible granule (3+55)
3 percent of benzoxaflutole, 55 percent of fenpyrad, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
78. 36% benzoxaflutole-sulcotrione suspending agent (6+30)
6 percent of benzoxaflutole, 30 percent of sulcotrione, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.16 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
79. 21% benzoxaflutole mesotrione suspension concentrate (12+9)
12% of benzoxaflutole, 9% of mesotrione, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
80. 16% benzoxaflutole-topramezone suspending agent (12+4)
12% of benzoxaflutole, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.2% of xanthan gum, 2.0% of magnesium aluminum silicate, 5% of glycerol and water.
81. 18% benzoxaflutole-tembotrione suspending agent (12+6)
12% of benzoxaflutole, 6% of tembotrione, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.18% of xanthan gum, 1.8% of magnesium aluminum silicate, 5% of glycerol and water.
82. 18% benzoxaflutole-fluroxypyr suspension (12+6)
12% of benzoxaflutole, 6% of fluroxypyr, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.18% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
83. 17% benzoxaflutole-benzofuranone suspending agent (12+5)
12% of benzoxaflutole, 5% of benzoxaflutole, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.18% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
84. 29% benzoxaflutole-benzobicyclon suspending agent (12+17)
12% of benzoxaflutole, 17% of benzoxaflutole, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
85. 32% benzoxaflutole lancotrione suspension (24+8)
24% of benzoxaflutole, 8% of lancotrione, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
86. 11% benzoxaflutole-sulfonylopyrazole dispersible oil suspending agent (9+2)
9 percent of benzoxaflutole, 2 percent of sulfonylopyrazole, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of nonylphenol polyoxyethylene ether, 4 percent of castor oil polyoxyethylene ether, 2.5 percent of organobentonite, 2.5 percent of fumed silica, 10 percent of No. 150 solvent oil and methyl oleate.
87. 36% benzoxaflutole-pyrazole special suspending agent (3+33)
3% of benzoxaflutole, 33% of pyrazolate, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.14% of xanthan gum, 1.4% of magnesium aluminum silicate, 5% of glycerol and water.
88. 33% benzoxaflutole-bicyclon suspending agent (3+30)
3% of benzoxaflutole, 30% of bicyclon, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
89. 32% benzoxaflutole tolpyralate suspension (12+20)
12% of benzoxaflutole, 20% of tolpyralate, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
90. 32% benzoxaflutole fenquinotrione suspension (12+20)
12% of benzoxaflutole, 20% of fenquinotrione, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
91. 31% benzoxaflutole-fluorochloridone suspending agent (6+25)
6 percent of benzoxaflutole, 25 percent of flurochloridone, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.16 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
92. 22% benzoxaflutole-flurtamone suspending agent (12+10)
12% of benzoxaflutole, 10% of flurtamone, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
93. 29% benzoxaflutole-beflubutamid suspension (12+17)
12% of benzoxaflutole, 17% of beflubutamid, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
94. 40% benzoxaflutole-norflurazon suspending agent (3+37)
3 percent of benzoxaflutole, 37 percent of norflurazon, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.14 percent of xanthan gum, 1.4 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
95. 52% benzoxaflutole-fluridone water dispersible granule (2+50)
2 percent of benzoxaflutole, 50 percent of fluazifop-butyl, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
96. 46% benzoxaflutole-prosulfocarb suspension emulsion (2+44)
2% of benzoxaflutole, 44% of prosulfocarb, 3% of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1% of phenethyl phenol polyoxyethylene ether, 2.5% of castor oil polyoxyethylene ether, 0.12% of xanthan gum, 5% of glycerol and water.
97. 53% benzoxaflutole-molinate suspoemulsion (3+50)
3% of benzoxaflutole, 50% of molinate, 3% of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1% of phenethyl phenol polyoxyethylene ether, 2.5% of castor oil polyoxyethylene ether, 0.05% of xanthan gum, 5% of glycerol and water.
98. 53% benzoxaflutole-thiobencarb suspoemulsion (3+50)
3% of benzoxaflutole, 50% of thiobencarb, 3% of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1% of phenethyl phenol polyoxyethylene ether, 2.5% of castor oil polyoxyethylene ether, 0.06% of xanthan gum, 5% of glycerol and water.
99. 50% benzoxaflutole-furbengal suspension emulsion (3+47)
3% of benzoxaflutole, 47% of furbenoxan, 3% of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1% of phenethyl phenol polyoxyethylene ether, 2.5% of castor oil polyoxyethylene ether, 0.08% of xanthan gum, 5% of glycerol and water.
100. 29% benzoxaflutole-ethofumesate yellow suspoemulsion (2.25+26.75)
2.25 percent of benzoxaflutole, 26.75 percent of ethofumesate, 3 percent of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1 percent of phenethyl phenol polyoxyethylene ether, 2.5 percent of castor oil polyoxyethylene ether, 0.15 percent of xanthan gum, 5 percent of glycerol and water.
101. 28% benzoxaflutole-triallate suspoemulsion (3+25)
3% of benzoxaflutole, 25% of triallate, 3% of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1% of phenethyl phenol polyoxyethylene ether, 2.5% of castor oil polyoxyethylene ether, 0.15% of xanthan gum, 5% of glycerol and water.
102. 35% benzoxaflutole-prosulfocarb suspoemulsion (3+32)
3% of benzoxaflutole, 32% of prosulfocarb, 3% of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1% of phenethyl phenol polyoxyethylene ether, 2.5% of castor oil polyoxyethylene ether, 0.15% of xanthan gum, 5% of glycerol and water.
103. 61% benzoxaflutole-molinate water dispersible granule (3+58)
3 percent of benzoxaflutole, 58 percent of molinate, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
104. 32% benzoxaflutole-butantte suspoemulsion (12+20)
12% of benzoxaflutole, 20% of butachlor, 3% of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1% of phenethyl phenol polyoxyethylene ether, 2.5% of castor oil polyoxyethylene ether, 0.15% of xanthan gum, 5% of glycerol and water.
105. 32% benzoxaflutole-cyclometaldehyde suspoemulsion (12+20)
12% of benzoxaflutole, 20% of cyhalofop-butyl, 3% of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1% of phenethyl phenol polyoxyethylene ether, 2.5% of castor oil polyoxyethylene ether, 0.16% of xanthan gum, 5% of glycerol and water.
106. 36% benzoxaflutole-pipindone suspoemulsion (3+33)
3% of benzoxaflutole, 33% of pipindone, 3% of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1% of phenethyl phenol polyoxyethylene ether, 2.5% of castor oil polyoxyethylene ether, 0.15% of xanthan gum, 5% of glycerol and water.
107. 70% benzoxaflutole-penflufen water dispersible granule (3+67)
3 percent of benzoxaflutole, 67 percent of penflufen, 6 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
108. 21% benzoxaflutole-quinclorac suspending agent (6+15)
6 percent of benzoxaflutole, 15 percent of quinclorac, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol-polyoxyethylene ether, 0.18 percent of xanthan gum, 18 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
109. 43% benzoxaflutole-picloram water dispersible granule (3+40)
3 percent of benzoxaflutole, 40 percent of picloram, 5 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
110. 11% benzoxaflutole-fluroxypyridine ester dispersible oil suspending agent (9+2)
9 percent of benzoxaflutole, 2 percent of chlorofluoropyridine ester, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of nonylphenol polyoxyethylene ether, 4 percent of castor oil polyoxyethylene ether, 2.8 percent of organobentonite, 2.5 percent of fumed silica, 10 percent of No. 150 solvent oil and methyl oleate.
111. 28% benzoxaflutole.2-methyl-4-chlorophenoxyacetic acid suspoemulsion (9+19)
9 percent of benzoxaflutole, 19 percent of 2-methyl-4-chlorophenoxyacetic acid, 3 percent of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1 percent of phenethyl phenol polyoxyethylene ether, 2.5 percent of castor oil polyoxyethylene ether, 0.12 percent of xanthan gum, 5 percent of glycerol and water.
112. 28% benzoxaflutole.2-methyl-4-chloro-phenoxathion water dispersible granule (3+25)
3 percent of benzoxaflutole, 25 percent of 2-methyl-4-chloro-phenol ethyl thioester, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated silica and filler diatomite.
113. 25% benzoxaflutole-2-methyl-4-chlorophenoxypropionic acid water dispersible granule (3+22)
3 percent of benzoxaflutole, 22 percent of 2-methyl-4-chlorophenoxypropionic acid, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated silica and filler diatomite.
114. 25% benzoxaflutole-2-methyl-4-sodium chlorophenoxyacetate water dispersible granule (3+22)
3 percent of benzoxaflutole, 22 percent of 2-methyl-4-chlorophenoxy sodium acetate, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated silica and filler diatomite.
115. 35% benzoxaflutole-2-methyl-4-chlorophenoxyacetic acid isooctyl suspension emulsion (3+32)
3 percent of benzoxaflutole, 32 percent of 2-methyl-4-chlorophenoxyacetic acid isooctyl ester, 3 percent of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1 percent of phenethyl phenol polyoxyethylene ether, 2.5 percent of castor oil polyoxyethylene ether, 0.15 percent of xanthan gum, 5 percent of glycerol and water.
116. 15% benzoxaflutole-2, 4-dichlorophenoxyacetic acid butyl ester suspoemulsion (3+12)
3 percent of benzoxaflutole, 12 percent of 2, 4-dichlorphenoxyacetic acid butyl ester, 3 percent of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1 percent of phenethyl phenol polyoxyethylene ether, 2.5 percent of castor oil polyoxyethylene ether, 0.22 percent of xanthan gum, 5 percent of glycerol and water.
117. 17% benzoxaflutole-2, 4-dichlorophenoxyacetic acid isooctyl suspoemulsion (3+14)
3 percent of benzoxaflutole, 14 percent of 2, 4-dichlorophenoxyacetic acid isooctyl ester, 3 percent of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1 percent of phenethyl phenol polyoxyethylene ether, 2.5 percent of castor oil polyoxyethylene ether, 0.22 percent of xanthan gum, 5 percent of glycerol and water. 118. 12% benzoxaflutole-4- (2, 4-dichlorophenoxy) propionic acid dispersible oil suspending agent (3+9)
3 percent of benzoxaflutole, 9 percent of 4- (2, 4-dichlorophenoxy) propionic acid, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of nonylphenol polyoxyethylene ether, 4 percent of castor oil polyoxyethylene ether, 2.8 percent of organic bentonite, 2.5 percent of fumed silica, 10 percent of No. 150 solvent oil and methyl oleate.
119. 27% benzoxaflutole clocloquintocet acid suspending agent (9+18)
9 percent of benzoazolofloxacin, 18 percent of clotrimazone acid, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.16 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
120. 13% benzoxaflutole-oxaziclomefone suspending agent (9+4)
9 percent of benzoxaflutole, 4 percent of oxaziclomefone, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol-polyoxyethylene ether, 0.18 percent of xanthan gum, 1.8 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
121. 28% benzoxaflutole-cinmethylin suspension concentrate (24+4)
24% of benzoxaflutole, 4% of cycloheptane ether, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.12% of xanthan gum, 1.2% of magnesium aluminum silicate, 5% of glycerol and water.
122. 38% benzoxaflutole-phosphinothricin water dispersible granule (1.5+36.5)
1.5 percent of benzoxaflutole, 36.5 percent of phosphinothricin, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
123. 30% benzoxaflutole-bialaphos water dispersible granule (2.25+27.75)
2.25 percent of benzoxaflutole, 27.75 percent of bialaphos, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated silica and filler diatomite.
124. 35% benzoxaflutole-refined glufosinate water dispersible granule (4.5+30.5)
4.5 percent of benzoxaflutole, 30.5 percent of refined glufosinate-ammonium, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitation white carbon black and filler diatomite.
125. 45% benzoxaflutole-paraquat water dispersible granule (4.5+40.5)
4.5 percent of benzoxaflutole, 40.5 percent of paraquat, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated silica and filler diatomite.
126. 55% benzoxaflutole-asulam water dispersible granule (2.25+52.75)
2.25 percent of benzoxaflutole, 52.75 percent of asulam, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated silica and filler diatomite.
127. 26% benzoxaflutole-2-methyl-4-chlorobutyric acid dispersible oil suspending agent (3+23)
3 percent of benzoxaflutole, 23 percent of 2-methyl-4-chlorobutyric acid, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of nonylphenol polyoxyethylene ether, 4 percent of castor oil polyoxyethylene ether, 2.8 percent of organobentonite, 2.5 percent of fumed silica, 10 percent of No. 150 solvent oil and methyl oleate.
128. 20% benzoxaflutole-2, 4-D butyric acid dispersible oil suspending agent (4.5+15.5)
4.5 percent of benzoxaflutole, 15.5 percent of 2, 4-D-butyric acid, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of nonylphenol polyoxyethylene ether, 4 percent of castor oil polyoxyethylene ether, 2.8 percent of organic bentonite, 2.5 percent of fumed silica, 10 percent of No. 150 solvent oil and methyl oleate.
The above-mentioned suspension emulsion preparation equipment includes mixing kettle, colloid mill, sand mill and shearing machine.
The suspension emulsion is prepared by adding water phase material into a mixing kettle, stirring, grinding with colloid mill, grinding with sand mill for three-stage grinding, shearing uniformly in shearing machine, and transferring after qualified test; putting the oil phase material into a mixing kettle, adding solvent oil and an emulsifier, and stirring and dissolving uniformly; and then adding the water-phase material into a shearing kettle, slowly pumping the oil-phase material into the shearing kettle in a shearing state, pumping the material while shearing, continuously and uniformly shearing, transferring to a storage tank for filling after the test is qualified.
The processing equipment of the aqueous suspending agent comprises a mixing kettle, a colloid mill, a sand mill, a shearing machine and the like.
The processing process of the aqueous suspension agent comprises the steps of putting all materials into a mixing kettle, stirring and mixing the materials, passing the materials through a colloid mill, then entering a sand mill for three-stage sanding, finally uniformly shearing the materials in a shearing machine, transferring the materials to a storage tank for filling after the materials are qualified in test.
The processing equipment of the dispersible oil suspending agent comprises a mixing kettle, a colloid mill, a sand mill, a shearing machine and the like.
The dispersible oil suspending agent is prepared by putting all materials into a mixing kettle, stirring and mixing, passing through a colloid mill, entering a sand mill for three-stage sanding, finally shearing uniformly in a shearing machine, transferring to a storage tank for filling after passing the assay.
The water dispersible granule processing equipment comprises an air flow crusher, a colter type mixer, a basket type granulator, a drying box, a sieving machine and the like.
The water dispersible granule is prepared by uniformly mixing the materials, crushing the materials by airflow, adding water, kneading, granulating, drying and finally screening to obtain a finished product.
B) Test of drug efficacy
Spraying treatment of stems and leaves after seedling:
1) test conditions
1.1) test target
The starwort is collected from Jiangsu Xinghua, and the descurainia sophia is collected from Shandong Taian. The weeds are cultured by a pot culture method, plastic nutrition bowls with the size of 180 х 140mm are placed in an enamel tray, surface soil (4/5) which is collected from a farmland and is dried and sieved is filled in the enamel tray, the soil humidity is controlled to be 20% at the initial stage, weed seeds with full and uniform seeds are selected, the weed seeds are soaked in warm water with the temperature of 25 ℃ for 6 hours, germination is accelerated in a biochemical incubator (dark) with the temperature of 28 ℃, the weed seeds which are just exposed to the white are uniformly placed on the surface of the soil, and then the enamel tray is covered with 0.5-1cm of soil according to the particle size of the seeds.
1.2) culture conditions
The method is carried out in a controllable sunlight greenhouse, the temperature is 20-30 ℃, the natural illumination is carried out, and the relative humidity is 57-72%.
The soil type is loam, the organic matter content is 1.63%, the pH value is 7.1, the alkaline hydrolysis nitrogen is 84.3mg/kg, the quick-acting phosphorus is 38.5mg/kg, and the quick-acting potassium is 82.1 mg/kg.
1.3), instrumentation
3WP-2000 model walking spray tower, Minn Jing agricultural machinery research institute of agricultural department. Ten thousandth electronic balance type GA10 (germany); ZDR2000 intelligent data recorder (hangzhou ze large instruments ltd); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument factory).
2) Design of experiments
2.1), reagents
2.1.1) test Agents
The desired active ingredient B was purchased from a reagent company and A was produced by this company.
The raw medicines are all diluted by using an emulsifier Tween-80 aqueous solution with the content of 0.1 percent and taking acetone as a solvent.
2.2) test treatment
2.2.1), dose setting
When determining the ratio or content of the component A and the component B, the main use purpose of the formula is also considered according to the action characteristics of the two medicaments and the measurement of toxicity and the like. On the basis of preliminary experiments, A, B active ingredients are respectively used singly and mixed in different amounts. Water without drug, containing the same solvent and emulsifier was used as a blank.
2.2.2), test repetition
Each treatment was repeated 4 times, 3 pots each time, 20 weed seeds were sown per pot, 60 plants each time.
2.3) treatment method
2.3.1), treatment time and number of times
The test was performed 1 time in total. And (3) thinning after the 2-leaf stage of the weeds, keeping 15 weeds in each pot, keeping 45 weeds in each treatment, and then continuously culturing until the 3 leaves of the caraway of the cattle and the descurainia sophia are treated.
2.3.2), instruments and methods of use
Uniformly placing the cultured test material on a 0.5m area2Spraying stem and leaf with 3WP-2000 model walking spraying tower in 30 kg/ha amount. The spraying pressure is 0.3 MPa. And after all the liquid medicine is sprayed, closing the air valve, opening the spraying tower door after 30 seconds, and taking out the nutrition pot. Then the air valve is opened, 50mL of clean water is sprayed, and the liquid spraying pipe is cleaned.
3) Test method
The potting method is adopted. The weed cultivation is carried out according to 1.1 and the standard herbicide for indoor bioassay of pesticides. The application method is 2.3.2, and stem and leaf treatment method is adopted. After treatment, the cells were transferred to a greenhouse for conventional culture, and a 1-2cm water layer was maintained throughout the experiment.
4) Data investigation and statistical analysis
4.1) investigation method
The complete survival weed seedlings are cut off along the soil surface by a blade by adopting an absolute number survey method, and the fresh weight of the weeds is weighed by an analytical balance. For the weeds that have died, the fresh weight is zero.
4.2), investigation time and number of surveys
The investigation was carried out 20 days after the treatment, and the total number of the investigations was 1.
4.3), statistical analysis of data
The theoretical fresh weight inhibition rate (E0 ═ X + Y-X Y/100) of each treatment mixed combination is calculated by a Gowing method, and then compared with the actually measured inhibition rate (E), the combined action type of the two mixed combinations on the weeds is evaluated, and when the E-E0 value is more than 10 percent, the effect is synergistic, when the E-E0 value is less than-10 percent, the effect is antagonistic, and when the E-E0 value is between-10 percent and 10 percent, the effect is additive. And the optimal proportion is determined according to factors such as actual control effect, characteristics of the herbicide, balance of the formula and the like.
Wherein X is the fresh weight inhibition rate when the dosage of the active component A is P; y is the fresh weight inhibition rate of the active component B when the dosage is Q.
Soil sealing treatment:
1) test conditions
1.1) test target
The starwort is collected from Jiangsu Xinghua, and the descurainia sophia is collected from Shandong Taian.
1.2) culture conditions
The method is carried out in a controllable sunlight greenhouse, the temperature is 20-30 ℃, the natural illumination is carried out, and the relative humidity is 57-72%.
The soil type is loam, the organic matter content is 1.63%, the pH value is 7.1, the alkaline hydrolysis nitrogen is 84.3mg/kg, the quick-acting phosphorus is 38.5mg/kg, and the quick-acting potassium is 82.1 mg/kg. The test soil was quantitatively loaded at 3/4 points of the pot and then poured from the bottom of the pot to completely wet the soil to saturation. Uniformly and quantitatively broadcasting the pretreated weed seeds to be tested on the surface, covering soil of 0.5-2cm according to the size of the seeds, and reserving the weed seeds for 24 hours after sowing.
1.3), instrumentation
Ten thousandth electronic balance type GA10 (germany); ZDR2000 intelligent data recorder (hangzhou ze large instruments ltd); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument plant), pipettor and the like.
2) Design of experiments
2.1), reagents
2.1.1) test Agents
The required active ingredients B are all technical products sold in the market, and A is produced by the company.
The raw medicines are all diluted by using an emulsifier T-80 aqueous solution with the content of 0.1 percent by using acetone as a solvent.
2.2) test treatment
2.2.1), dose setting
When determining the ratio or content of the components A and the active component B, the main purpose of the formula should be considered in consideration of the action characteristics of the two medicaments and the toxicity thereof. On the basis of preliminary experiments, A, B active ingredients are respectively used singly and mixed in different amounts. Water without drug, containing the same solvent and emulsifier was used as a blank.
2.2.2), test repetition
Each treatment was repeated 4 times, 3 pots each time, and 30 weed seeds were sown in each pot.
2) Test method
Before treatment, the mixture was irrigated and a 1-2cm aqueous layer was maintained. Taking quantitative liquid medicine by a pipettor, and respectively carrying out irrigation treatment from low dosage to high dosage according to experimental design, wherein the treatment is repeated for 4 times each time; after treatment, the cells were transferred to a greenhouse for conventional culture, and a 1-2cm water layer was maintained throughout the experiment.
3) Data investigation and statistical analysis
The spray treatment is the same as the spray treatment of the stem leaves after seedling, so the detailed description is omitted.
The statistical results are shown in tables 1-126 below.
TABLE 1 evaluation of the actual control and Combined action of descurainia sophia mixed with pretilachlor (soil treatment)
Figure BDA0001462377920000231
Table 2A evaluation of actual control and combination of the blend with mefenacet for the mullein (soil treatment)
Figure BDA0001462377920000232
Table 3A evaluation of the actual control and combination of the Achillea alpina mixed and paired with Sulfoxaden (soil treatment)
Figure BDA0001462377920000233
Table 4A evaluation of the actual control and combination of the action of the combination of anilofos with descurainia sophia (soil treatment)
Figure BDA0001462377920000234
Figure BDA0001462377920000241
TABLE 5 evaluation of actual control and combination of descurainia sophia (soil treatment) by blending with dimethenamid
Figure BDA0001462377920000242
TABLE 6 evaluation of the actual control and combination of the combination of Teucrium odoratum with fentrazamide (soil treatment)
Figure BDA0001462377920000243
Table 7A evaluation of the actual control and combination of descurainia sophia (soil treatment) with triafamone
Figure BDA0001462377920000244
TABLE 8 evaluation of the actual control and combination of descurainia sophia (soil treatment) with the mix of cafenstrole
Figure BDA0001462377920000251
TABLE 9 evaluation of actual control and Combined action of descurainia sophia mixed with pipate (soil treatment)
Figure BDA0001462377920000252
Table 10A evaluation of the actual control and combination of the action of descurainia sophia mixed with metazachlor (soil treatment)
Figure BDA0001462377920000253
TABLE 11 evaluation of actual control and combination of descurainia sophia (soil treatment) by blending with Conyzamide
Figure BDA0001462377920000254
Figure BDA0001462377920000261
Table 12A evaluation of the actual control and combination of mugwort with dimethenamid (soil treatment)
Figure BDA0001462377920000262
TABLE 13 evaluation of the actual control and combination of descurainia sophia (soil treatment) by combining fomesafen with Fomesafen
Figure BDA0001462377920000263
TABLE 14 evaluation of the actual control and combination of descurainia sophia (soil treatment) with oxadiazon
Figure BDA0001462377920000264
Table 15A evaluation of the actual control and combination of the effects of descurainia sophia mixed with oxadiargyl (soil treatment)
Figure BDA0001462377920000265
TABLE 16 evaluation of the actual control and combination of Bixapyroxad and Bixapyroxad in combination for descurainia sophia (soil treatment)
Figure BDA0001462377920000271
Table 17 evaluation of the actual control and combination of descurainia sophia (soil treatment) with flumioxazin
Figure BDA0001462377920000272
Table 18A evaluation of actual control and combination of descurainia sophia (soil treatment) with pentoxazone
Figure BDA0001462377920000273
TABLE 19 evaluation of the actual control and Combined action of the blend of Tiafenac with tara
Figure BDA0001462377920000274
TABLE 20 evaluation of the actual control and combination of descurainia sophia (stem and leaf treatment) by the combination of Bispyribac-sodium and Bispyribac-sodium
Figure BDA0001462377920000275
Figure BDA0001462377920000281
TABLE 21 evaluation of actual control and combination of descurainia sophia (soil treatment) with Simmondsia chinensis
Figure BDA0001462377920000282
TABLE 22 evaluation of actual control and combination of descurainia sophia (soil treatment) by combination of terbutryn and terbuthylazine
Figure BDA0001462377920000283
TABLE 23 evaluation of actual control and combination of the combination of isoproturon and isoproturon (soil treatment)
Figure BDA0001462377920000284
TABLE 24 evaluation of actual control and combined action of blending with fenugreek (soil treatment)
Figure BDA0001462377920000285
Figure BDA0001462377920000291
TABLE 25 evaluation of actual control and combination of descurainia sophia (soil treatment) by mixing and pairing with dicetryn
Figure BDA0001462377920000292
TABLE 26 evaluation of actual control and Combined action of the Equisetum sophia mixed with ethimazone (soil treatment)
Figure BDA0001462377920000293
TABLE 27 evaluation of actual control and Combined action of the combination of metamitron and flixweed (soil treatment)
Figure BDA0001462377920000294
TABLE 28 evaluation of actual control and Combined action of descurainia sophia mixed with cyanazine (soil treatment)
Figure BDA0001462377920000295
Figure BDA0001462377920000301
TABLE 29 evaluation of actual control and combination of descurainia sophia (soil treatment) by mixing and pairing with Fluoruron
Figure BDA0001462377920000302
TABLE 30 evaluation of actual control and Combined action of Thidiazuron and tarragon (soil treatment)
Figure BDA0001462377920000303
TABLE 31 evaluation of actual control and combination of the combination of Shaplong and ground for the purpose of descurainia sophia (soil treatment)
Figure BDA0001462377920000304
TABLE 32 evaluation of actual control and combination of descurainia sophia by compounding with Lugulong (soil treatment)
Figure BDA0001462377920000305
Figure BDA0001462377920000311
TABLE 33 evaluation of actual control and combination of descurainia sophia (soil treatment) by blending and pairing descurainia sophia with bromuron
Figure BDA0001462377920000312
TABLE 34 evaluation of actual control and combination of descurainia sophia (soil treatment) by mixing and pairing with Conyza blinii
Figure BDA0001462377920000313
TABLE 35 evaluation of actual control and combination of Polygala sonchifolia with Pyridazinol (soil treatment)
Figure BDA0001462377920000314
TABLE 36 evaluation of actual control and combination of descurainia sophia (soil treatment) by mixing and pairing together with isopentyi
Figure BDA0001462377920000315
Figure BDA0001462377920000321
TABLE 37A evaluation of actual control and combination of descurainia sophia (soil treatment) with the combination of Cadajin
Figure BDA0001462377920000322
TABLE 38 evaluation of actual control and combination of descurainia sophia (stem and leaf treatment)
Figure BDA0001462377920000323
TABLE 39A evaluation of actual control and combined action of descurainia sophia (soil treatment)
Figure BDA0001462377920000324
TABLE 40 evaluation of actual control and Combined action of descurainia sophia mixed with triclopyr (soil treatment)
Figure BDA0001462377920000325
TABLE 41 evaluation of actual control and combination of descurainia sophia (soil treatment) by blending with Methylphenethiol
Figure BDA0001462377920000331
TABLE 42 evaluation of actual control and combination of descurainia sophia by mixing with Cyclocuron (soil treatment)
Figure BDA0001462377920000332
TABLE 43 evaluation of actual control and combination of descurainia sophia by blending with Isooxalong (soil treatment)
Figure BDA0001462377920000333
TABLE 44 evaluation of actual control and combined action of compounding metoprolol on descurainia sophia (soil treatment)
Figure BDA0001462377920000334
TABLE 45 evaluation of actual control and combination of descurainia sophia (soil treatment) by blending with Kunlong
Figure BDA0001462377920000335
Figure BDA0001462377920000341
TABLE 46 evaluation of actual control and combination of descurainia sophia by compounding with trifluoxazine (soil treatment)
Figure BDA0001462377920000342
TABLE 47A evaluation of the actual control and Combined action of Artemisia scoparia mixed with cyclopyrinate (stem leaf treatment)
Figure BDA0001462377920000343
TABLE 48 evaluation of the actual control and combination of the combination of Diplophanthus sophistica with propanil (stem and leaf treatment)
Figure BDA0001462377920000344
TABLE 49 actual prevention and combination evaluation of descurainia sophia (stem and leaf treatment)
Figure BDA0001462377920000345
Figure BDA0001462377920000351
TABLE 50 evaluation of actual control and combination of Beechia sophia (stem and leaf treatment) by mixing with Betula alnoides
Figure BDA0001462377920000352
TABLE 51 evaluation of actual control and combination of descurainia sophia (stem and leaf treatment) by blending with Begonine
Figure BDA0001462377920000353
TABLE 52 evaluation of actual control and combination of Bingnian (soil treatment) with pyrazosulfuron-ethyl
Figure BDA0001462377920000354
TABLE 53 evaluation of actual control and combination of Thidiazuron and Thidiazuron on mulches
Figure BDA0001462377920000355
TABLE 54 evaluation of actual control and combination of promethasulfuron and descurainia sophia (soil treatment)
Figure BDA0001462377920000361
TABLE 55 evaluation of actual control and combination of the Oxyus sieboldii with the mixture of metazosulfuron
Figure BDA0001462377920000362
TABLE 56 actual prevention and combination evaluation of descurainia sophia (soil treatment) by blending Ethoxysulfuron
Figure BDA0001462377920000363
TABLE 57 evaluation of actual controlling effect and combination of the compounding of orthosulfamuron to descurainia sophia (soil treatment)
Figure BDA0001462377920000364
TABLE 58 evaluation of the actual control and combination of the Fondaparinux Tridentati with Fluoroketosulam (soil treatment)
Figure BDA0001462377920000365
Table 59A evaluation of actual control and combination of Polygala crotalarioides with penoxsulam (soil treatment)
Figure BDA0001462377920000371
TABLE 60 evaluation of the actual control and combination of the combination of cloransulam-methyl with the evaluation of the actual control and combination of the action of descurainia sophia (soil treatment)
Figure BDA0001462377920000372
Table 61A shows the evaluation of the actual control and the combined action of the Achillea alpina mixed with imazamox (soil treatment)
Figure BDA0001462377920000373
TABLE 62 evaluation of the actual control and combination of the combination of Memidazolinin and Incarvillea sophia (soil treatment)
Figure BDA0001462377920000374
TABLE 63 evaluation of the actual control and combination of mullein (soil treatment) by combination of imazethapyr and imazethapyr
Figure BDA0001462377920000375
Figure BDA0001462377920000381
TABLE 64A evaluation of the actual control and combination of descurainia sophia (soil treatment)
Figure BDA0001462377920000382
TABLE 65A evaluation of the actual control and combination of the Acronychia sophila Roxburgh with pyriminobac-methyl (soil treatment)
Figure BDA0001462377920000383
TABLE 66 evaluation of actual control and combination of descurainia sophia (soil treatment) by combination of Floren and Floren
Figure BDA0001462377920000384
TABLE 67 evaluation of actual control and Combined action of Securainia sophia mixed with butralin (soil treatment)
Figure BDA0001462377920000385
Figure BDA0001462377920000391
TABLE 68 evaluation of actual control and combination of descurainia sophia (soil treatment) by combination of pendimethalin and pendimethalin
Figure BDA0001462377920000392
TABLE 69 evaluation of the actual control and combination of descurainia sophia (soil treatment) by combination with Dilleamine
Figure BDA0001462377920000393
TABLE 70 evaluation of actual control and Combined action of descurainia sophia (soil treatment) with dithiopyr mixture
Figure BDA0001462377920000394
TABLE 71 evaluation of actual control and combination of descurainia sophia (soil treatment) by mixing and pairing of Ethycyflufen and Ethycyflufen
Figure BDA0001462377920000395
Figure BDA0001462377920000401
TABLE 72 evaluation of actual control and combination of the combination of Miao Polygala combined with oryzalin (soil treatment)
Figure BDA0001462377920000402
Table 73A evaluation of the actual control and combination of descurainia sophia (soil treatment) with flumetsulam
Figure BDA0001462377920000403
TABLE 74 evaluation of actual control and combination of the combination of Thiacloprid and Thiacloprid for descurainia sophia (soil treatment)
Figure BDA0001462377920000404
TABLE 75 evaluation of actual control and combination of descurainia sophia (soil treatment) by mixing with Nacao
Figure BDA0001462377920000411
TABLE 76A evaluation of actual control and combined action of descurainia sophia mixed with chlorthal (soil treatment)
Figure BDA0001462377920000412
TABLE 77 evaluation of actual control and combination of descurainia sophia (soil treatment) with Pythium irregulare
Figure BDA0001462377920000413
TABLE 78 evaluation of actual control and Combined action of the Paecilomyces japonica in combination with sulcotrione (soil treatment)
Figure BDA0001462377920000414
TABLE 79 evaluation of actual control and combination of Michialone and mesotrione on mullein (soil treatment)
Figure BDA0001462377920000421
TABLE 80 evaluation of the actual control and Combined action of Baphicacanthes cusia (soil treatment) with topramezone
Figure BDA0001462377920000422
TABLE 81 evaluation of actual control and combination of the combination of Cyclosultone and Tanshinon (soil treatment)
Figure BDA0001462377920000423
TABLE 82 evaluation of the actual control and Combined action of the fluroxypyr and fluroxypyr mixture (soil treatment)
Figure BDA0001462377920000424
TABLE 83 evaluation of actual control and combination of Fusulcotrione mixture with descurainia sophia (soil treatment)
Figure BDA0001462377920000425
Figure BDA0001462377920000431
TABLE 84A evaluation of the actual control and combination of descurainia sophia (soil treatment) with the Paulodim mixture
Figure BDA0001462377920000432
TABLE 85 evaluation of actual control and combination of Lancotrione in combination with Lancotrione for mullein (soil treatment)
Figure BDA0001462377920000433
TABLE 86 actual prevention and combination evaluation of descurainia sophia (Stem and leaf treatment) by combining Sulfonyloxalpyrazole
Figure BDA0001462377920000434
TABLE 87 evaluation of actual control and combination of descurainia sophia by blending Pyrazolate (soil treatment)
Figure BDA0001462377920000435
Figure BDA0001462377920000441
TABLE 88 actual prevention and combination evaluation (soil treatment) of Polyflutolone-Bifone-Miyao
Figure BDA0001462377920000442
TABLE 89 evaluation of actual control and combination of tarcuraina sophia (soil treatment) by combination of tolpyralate and tolpyralate
Figure BDA0001462377920000443
TABLE 90A evaluation of the actual control and Combined action of fenquinotrione in combination with descurainia sophia (soil treatment)
Figure BDA0001462377920000444
TABLE 91A evaluation of the actual control and Combined action of descurainia sophia mixed with flurochloridone (soil treatment)
Figure BDA0001462377920000445
Figure BDA0001462377920000451
TABLE 92 evaluation of the actual control and combination of descurainia sophia (soil treatment) with flurtamone combination
Figure BDA0001462377920000452
TABLE 93 evaluation of the actual control and Combined action of descurainia sophia mixed with beflubutamid (soil treatment)
Figure BDA0001462377920000453
TABLE 94 evaluation of actual control and combined action of descurainia sophia in combination with norflurazon (soil treatment)
Figure BDA0001462377920000454
TABLE 95 evaluation of the actual control and combination of descurainia sophia (soil treatment) by combination of Scutellaria baicalensis Georgi and Scutellaria baicalensis Georgi
Figure BDA0001462377920000461
TABLE 96 evaluation of actual control and combination of mullein (soil treatment) by mixing with prosperous curtism
Figure BDA0001462377920000462
TABLE 97 evaluation of actual control and combination of mullein by blending with molinate (soil treatment)
Figure BDA0001462377920000463
TABLE 98A evaluation of actual control and combined action of blending with Hecaodan on descurainia sophia (soil treatment)
Figure BDA0001462377920000464
TABLE 99A evaluation of the actual control and combination of the Fucao Huangmixxing for the mullein (soil treatment)
Figure BDA0001462377920000465
TABLE 100A evaluation of the actual control and combination of the combination of Bingnian Hay (stem and leaf treatment) with Oxyfur grass
Figure BDA0001462377920000471
Table 101A evaluation of actual control and combination of Miao Polygala (soil treatment) by blending Miao with Dicamba
Figure BDA0001462377920000472
Table 102A evaluation of actual control and combination of descurainia sophia (soil treatment)
Figure BDA0001462377920000473
TABLE 103A evaluation of actual control and combined action of Miao Polygala (soil treatment) with Micaodi
Figure BDA0001462377920000474
Table 104A evaluation of actual control and combination of mullein (soil treatment) with Dingcao specific combination
Figure BDA0001462377920000475
Figure BDA0001462377920000481
TABLE 105 evaluation of actual control and combined action of blending with Cyclomedicide for descurainia sophia (soil treatment)
Figure BDA0001462377920000482
TABLE 106 evaluation of actual control and Combined action of Paeonia lactiflora (soil treatment) in combination with pipindow
Figure BDA0001462377920000483
TABLE 107A evaluation of actual control and combination of descurainia sophia (soil treatment) in combination with pennyroyal
Figure BDA0001462377920000484
TABLE 108 evaluation of actual control and Combined action of bovine chickweed when blended with Quinclorac (soil treatment)
Figure BDA0001462377920000485
Figure BDA0001462377920000491
TABLE 109A evaluation of actual control and Combined action of Caragana dichotoma when blended with Picloram (Stem and leaf treatment)
Figure BDA0001462377920000492
TABLE 110 evaluation of actual control and combination of Caragana dichotoma by blending with Chlorofluoropyridyl ester (Stem and leaf treatment)
Figure BDA0001462377920000493
TABLE 111 evaluation of actual control and Combined action of descurainia sophia (Stem and leaf treatment) with 2-methyl-4-chlorophenoxyacetic acid mixture
Figure BDA0001462377920000494
TABLE 112 evaluation of actual control and combination of descurainia sophia (Stem and leaf treatment) with 2-methyl-4-chloro-phenol ethyl thioester mixture
Figure BDA0001462377920000495
Figure BDA0001462377920000501
TABLE 113 evaluation of actual control and Combined action of the combination of 2-methyl-4-chlorophenoxypropionic acid with descurainia sophia (Stem and leaf treatment)
Figure BDA0001462377920000502
TABLE 114A evaluation of the actual control and combination of descurainia sophia (stem and leaf treatment) when it is mixed with 2-methyl-4-sodium chlorophenoxylate
Figure BDA0001462377920000503
TABLE 115A evaluation of the actual control and combination of the blend with 2-methyl-4-chlorophenoxyacetic acid isooctyl ester for descurainia sophia (Stem and leaf treatment)
Figure BDA0001462377920000504
TABLE 116A evaluation of the actual control and combination of descurainia sophia (stem and leaf treatment) with butyl 2, 4-Dichlorophenoxyacetate
Figure BDA0001462377920000505
Figure BDA0001462377920000511
TABLE 117A evaluation of the actual control and combination of descurainia sophia (stem and leaf treatment) when mixed with isooctyl 2, 4-dichlorophenoxyacetate
Figure BDA0001462377920000512
TABLE 118A evaluation of the actual control and combination of descurainia sophia (stem and leaf treatment) with 4- (2, 4-dichlorophenoxy) propionic acid mixture
Figure BDA0001462377920000513
TABLE 119A evaluation of the actual control and combination of the combination of cloquintocet-meyeri (soil treatment)
Figure BDA0001462377920000514
Table 120A evaluation of actual control and Combined action of Oxazin-Temminck on descurainia (soil treatment)
Figure BDA0001462377920000515
Figure BDA0001462377920000521
TABLE 121A evaluation of the actual control and combination of the combination of cyclovirobuxine and Artemisia scoparia (stem and leaf treatment)
Figure BDA0001462377920000522
TABLE 122A evaluation of the actual control and Combined action of descurainia sophia (Stem and leaf treatment) in combination with phosphinothricin
Figure BDA0001462377920000523
TABLE 123 evaluation of the actual control and combination of descurainia sophia (stem and leaf treatment) with bialaphos mixture
Figure BDA0001462377920000524
TABLE 124A evaluation of actual control and combination of descurainia sophia (stem and leaf treatment) with glufosinate-ammonium
Figure BDA0001462377920000525
TABLE 125A evaluation of actual control and combination of descurainia sophia (stem and leaf treatment)
Figure BDA0001462377920000526
Figure BDA0001462377920000531
TABLE 126 evaluation of actual control and Combined action of descurainia sophia (stem and leaf treatment) with the combination of asulam
Figure BDA0001462377920000532
TABLE 127A evaluation of the actual control and combination of descurainia sophia (stem and leaf treatment) with 2A 4 chlorobutyric acid mixture
Figure BDA0001462377920000533
TABLE 128A evaluation of actual control and Combined action of descurainia sophia mixed with 2, 4-D-butyric acid (Stem and leaf treatment)
Figure BDA0001462377920000534
C) Demonstration of field
The herbicidal compositions prepared in examples 1) to 128) were used for field weed effect tests.
An exemplary popularization test was performed in the test point of the Kyoho chemical industry in 2016. The weeds generated in the field mainly comprise descurainia sophia, shepherd's purse, starwort, Indian rorippa herb and the like.
The test method comprises the following steps:
soil treatment, before weed germination, a manual sprayer is used for adding water with the amount of 45 kg/667 m2The soil surface is uniformly sprayed.
Treating stems and leaves, namely, after the weeds are in the 3-4 leaf stage, manually spraying the weeds with a sprayer, and adding 30 kg of water per 667m2The stem and leaf are sprayed evenly.
The specific test agents and dosages are detailed in table 129, the cell area is 50 square meters, and each treatment is repeated 4 times. The control effect was examined 45 days after application of the composition, as shown in Table 129.
Figure BDA0001462377920000541
Through a large number of tests and explorations, the invention unexpectedly discovers that the composition is used for preventing and killing weeds such as descurainia sophia, shepherd's purse, starwort, Indian rorippa herb and the like, has a surprising and unexpected synergistic effect, has more remarkable synergistic effect under low dosage, can reduce the dosage and reduce the pollution to the environment, is reasonably compounded to reduce the agricultural cost, has high efficiency on ALS and ACCase inhibitor resistant weeds, and has good application prospect. Meanwhile, tests show that the herbicide composition shows good selectivity and excellent synergistic effect on lawns and crops such as wheat fields, corn fields, paddy fields, peanuts, sugarcane, sorghum, millet, potatoes, rape, soybeans, cotton, vegetables, bluegrass, tall fescue, zoysia japonica and the like, and can be developed into herbicide mixtures with wide market value.
Exemplary field Effect of the compounded compositions described in Table 129
Figure BDA0001462377920000551
Figure BDA0001462377920000561
Figure BDA0001462377920000571
Figure BDA0001462377920000581
Figure BDA0001462377920000591
Figure BDA0001462377920000601
Figure BDA0001462377920000611
Figure BDA0001462377920000621
Figure BDA0001462377920000631
Figure BDA0001462377920000641
Figure BDA0001462377920000651
Figure BDA0001462377920000661

Claims (12)

1. A herbicidal composition containing benzoxaflutole, which is characterized by comprising an active ingredient A and an active ingredient B with herbicidally effective amounts, wherein the active ingredient A is the benzoxaflutole, and the active ingredient B can be selected from one or more of the following compounds: desmedipham and desmedipham; wherein the weight ratio of A to B is 1:200-30: 1.
2. The herbicidal composition comprising carfentrazone-ethyl according to claim 1, wherein the weight ratio of a to B is 1:150 to 30: 1.
3. The herbicidal composition comprising carfentrazone-ethyl according to claim 2, wherein the weight ratio of A to B is 1:100 to 20: 1.
4. The herbicidal composition comprising carfentrazone-ethyl according to claim 3, wherein the weight ratio of A to B is 1:50 to 10: 1.
5. The herbicidal composition comprising carfentrazone-ethyl according to claim 4, wherein the weight ratio of A to B is 1:30 to 5: 1.
6. The herbicidal composition comprising carfentrazone-ethyl according to claim 5, wherein the weight ratio of A to B is 1:10 to 1: 1.
7. The herbicidal composition containing carfentrazone-ethyl according to claim 1, wherein the mass percentage of A and B in the herbicidal composition accounts for 1-95% of the total amount.
8. The herbicidal composition containing carfentrazone-ethyl according to claim 7, wherein the mass percentage of A and B in the herbicidal composition accounts for 10 to 80 percent of the total amount.
9. The herbicidal composition comprising carfentrazone-ethyl according to any one of claims 1 to 8, wherein the herbicidal composition further comprises a carrier and a surfactant.
10. The herbicidal composition containing carfentrazone-ethyl according to any one of claims 1 to 8, wherein the specific formulation of the herbicidal composition is dispersible oil suspension, aqueous suspension, suspoemulsion, wettable powder, emulsifiable concentrate, water dispersible granule, aqueous emulsion or microemulsion.
11. A herbicidal composition comprising carfentrazone-ethyl according to any one of claims 1 to 8, characterized in that the herbicidal composition further comprises a safener selected from one or more of isoxadifen, p-cymene sulfonamide, mefenpyr-diethyl, cloquintocet-mexyl, furazol and N- (2-methoxybenzoyl) -4- [ (methylaminocarbonyl) amino ] benzenesulfonamide.
12. Use of the herbicidal composition comprising carfentrazone-ethyl according to any one of claims 1 to 11 for controlling harmful weeds in crops of plants.
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CN114586797B (en) * 2020-12-03 2023-09-01 青岛清原作物科学有限公司 Ternary weeding composition containing bentazone and rimsulfuron and application thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8778836B2 (en) * 2004-04-06 2014-07-15 Bayer Cropscience Lp Herbicidal compositions

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105230629B (en) * 2015-11-17 2017-04-19 青岛清原农冠抗性杂草防治有限公司 Synergic weeding composition
CN105503728B (en) * 2015-12-31 2017-03-22 青岛清原化合物有限公司 Pyrazole compounds or salts thereof and preparation method thereof, and weedicide composition and application thereof
CN105831123B (en) * 2016-04-15 2018-01-23 青岛清原抗性杂草防治有限公司 A kind of cornfield weeding composition and its application
CN106135220A (en) * 2016-06-22 2016-11-23 泰安市农业科学研究院 A kind of cornfield weeding composition
CN106259401A (en) * 2016-08-02 2017-01-04 泰安市农业科学研究院 A kind of cornfield weeding composition and application thereof
CN106259352A (en) * 2016-08-12 2017-01-04 泰安市农业科学研究院 A kind of cornfield weeding composition and application thereof
CN106577715A (en) * 2016-11-01 2017-04-26 广东中迅农科股份有限公司 Pesticide composition containing benzene oxazole fluridon, nicosulfuron and fluroxypyr
CN106966983B (en) * 2017-05-02 2019-07-02 青岛清原化合物有限公司 Amorphous state benzene azoles fluorine humulone and its preparation method and application
CN107311930B (en) * 2017-07-13 2019-05-03 青岛清原化合物有限公司 Polybenzobisoxazole humulone B crystal form and its preparation method and application

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8778836B2 (en) * 2004-04-06 2014-07-15 Bayer Cropscience Lp Herbicidal compositions

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