CN113142217B - Ternary herbicidal composition containing HPPD inhibitor herbicide and application thereof - Google Patents

Ternary herbicidal composition containing HPPD inhibitor herbicide and application thereof Download PDF

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CN113142217B
CN113142217B CN202110408478.8A CN202110408478A CN113142217B CN 113142217 B CN113142217 B CN 113142217B CN 202110408478 A CN202110408478 A CN 202110408478A CN 113142217 B CN113142217 B CN 113142217B
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polyoxyethylene ether
topramezone
shows
ethyl
bicyclopyrone
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CN113142217A (en
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彭学岗
赵德
金涛
刘娜
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Qingdao Kingagroot Chemical Compound Co Ltd
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Qingdao Kingagroot Chemical Compound Co Ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
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    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
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    • A01N33/18—Nitro compounds
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    • A01N33/22—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
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    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
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    • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04—Aryloxy-acetic acids; Derivatives thereof
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
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    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
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    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
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    • A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring
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    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
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    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
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    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals

Abstract

The invention belongs to the field of pesticides, and particularly relates to a ternary weeding composition containing HPPD inhibitor herbicides and application thereof. The ternary herbicidal composition comprising herbicidally effective amounts of active ingredients A, B and C, wherein A is selected from one or more of the following HPPD inhibitor-based herbicide compounds: derivatives such as topramezone, bicyclopyrone and/or salts/esters thereof; b is selected from one or more of the following compounds: topramezone, mesotrione, tembotrione and/or their salt/ester derivatives; c is selected from one or more of the following compounds: pretilachlor, butachlor, mefenacet, anilofos and the like and/or derivatives thereof/esters and the like. The composition can effectively prevent and kill off weeds in crop fields such as cardamine hirsute, chickweed, shepherd's purse, chickweed, cleavers, alopecurus davidii, alopecurus japonicus, beckmann syzigachne and the like, and has the characteristics of expanding weed control spectrum, reducing application amount, being safe to crops, generating synergistic effect, solving resistant weeds and the like.

Description

Ternary herbicidal composition containing HPPD inhibitor herbicide and application thereof
The application is a divisional application of a Chinese invention patent application with the application date of 2018, 07, 21 and the application number of 201810806889.0, and the invention is named as 'a ternary weeding composition containing an HPPD inhibitor herbicide and application thereof'.
Technical Field
The invention belongs to the field of pesticides, and particularly relates to a ternary weeding composition containing HPPD inhibitor herbicides and application thereof.
Background
Chemical weeding is the most economic and effective means in preventing and removing weeds in farmlands, but the problems of drug resistance and resistance evolution of weeds and the like are easily caused by using a single variety or a single action mode of chemical herbicide continuously at a high dose for a long time.
The chemical structural formula of the diazole
Figure BDA0003023230580000011
The HPPD inhibitor herbicide is a newly developed HPPD inhibitor herbicide for treating stems and leaves after seedling emergence in a wheat field, has excellent biological activity, and can effectively prevent and kill various malignant weeds in the wheat field.
The chemical structural formula of the bicyclopyrone is shown as
Figure BDA0003023230580000012
The compound belongs to an HPPD inhibitor, and the activity of HPPD enzyme is inhibited, so that the process of converting hydroxy pyruvic acid into homogentisate is hindered, thus leading to the abnormal synthesis of tocopherol and plastoquinone, influencing the synthesis of carotenoid in a target body, leading to the whitening of leaves, influencing the normal operation of photosynthesis in a plant body, and finally completely dying.
The reasonable compounding or mixing of the herbicide compound has the advantages of expanding the weed spectrum, improving the control effect, delaying the occurrence and development of drug resistance and drug resistance of weeds and the like, and is one of the most effective methods for solving the problems. Therefore, the development of a weeding composition variety which has high safety and wide weed control spectrum, can produce synergistic effect and solve the problem of resistant weeds is urgently needed in production.
Disclosure of Invention
In order to solve the above problems in the prior art, the present invention provides a ternary herbicidal composition comprising HPPD inhibitor herbicides and use thereof. The composition can effectively prevent and kill off weeds in crop fields such as cardamine hirsute, chickweed, shepherd's purse, chickweed, cleavers, alopecurus davidii, alopecurus japonicus, beckmann syzigachne and the like, and has the characteristics of expanding weed control spectrum, reducing application amount, being safe to crops, generating synergistic effect, solving resistant weeds and the like.
A ternary herbicidal composition comprising an HPPD inhibitor herbicide comprising a herbicidally effective amount of an active ingredient A, an active ingredient B and an active ingredient C, wherein,
the active ingredient A is selected from one or more of the following HPPD inhibitor herbicide compounds: derivatives such as topramezone (CAS number: 1622908-18-2), bicyclopyrone (CAS number: 1855929-45-1) and/or salts/esters thereof;
the active ingredient B is selected from one or more of the following compounds: derivatives such as topramezone (CAS number: 210631-68-8), mesotrione (CAS number: 104206-82-8), tembotrione (CAS number: 335104-84-2), isoxaflutole (CAS number: 141112-29-0), bicyclosulfoncotrione (CAS number: 156963-66-5), triazophorione (CAS number: 1911613-97-2), topramezone (CAS number: 1992017-55-6) and/or salts/esters thereof;
the active ingredient C is selected from one or more of the following compounds: (1) VLCFA inhibitors: pretilachlor (CAS number: 51218-49-6), butachlor (CAS number: 23184-66-9), mefenacet (CAS number: 73250-68-7), anilofos (CAS number: 64249-01-0); (2) microtubule assembly inhibitors: butralin (CAS number: 33629-47-9); (3) PPO inhibitors: oxadiazon (CAS number: 19666-30-9), pyraclonil (CAS number: 158353-15-2), oxyfluorfen (CAS number: 42874-03-3); (4) PSII inhibitors: isoproturon (CAS number: 34123-59-6), simetryn (CAS number: 1014-70-6); (5) a DOXP inhibitor: clomazone (CAS number: 81777-89-1); (5) hormones: 2 methyl-4-chloro (CAS number: 94-74-6), quinclorac (CAS number: 84087-01-4), chlorofluoropyridinate (CAS number: 1390661-72-9); (6) ALS inhibitors: penoxsulam (CAS number: 219714-96-2); (7) lipid synthesis (non-ACC) inhibitors: molinate (CAS number: 2212-67-1), thiobencarb (CAS number: 28249-77-6) and/or salts/esters thereof and other derivatives.
In the context of the present specification, if the abbreviated forms of the common name of the active compounds are used, all customary derivatives, such as esters and salts, and also isomers, in particular optical isomers, in particular one or more commercially available forms, are included in each case. If the generic name denotes esters or salts, all other customary derivatives, such as other esters and salts, free acids and neutral compounds, and also isomers, in particular optical isomers, in particular one or more commercially available forms, are also included in each case. The chemical name given for a compound means at least one compound covered by the generic name, with compounds generally being preferred. In the case of sulfonamides, such as sulfonylureas, salts also include those formed by exchange of cations with hydrogen atoms in the sulfonamide group. For example, 2-methyl-4-chloro derivatives include, but are not limited to: 2 methyl 4 chloro sodium salt, potassium salt, dimethyl ammonium salt, isopropyl amine salt, etc., and 2 methyl 4 chloromethyl ester, ethyl ester, isooctyl ester, ethyl thioester, etc.
In the context of the present invention, the salts of the compounds are preferably in the form of the respective alkali metal, alkaline earth metal or ammonium salts, preferably in the form of the respective alkali metal salts, more preferably in the form of the respective sodium or potassium salts, most preferably in the form of the respective sodium salts.
A. The weight ratio of B to C is 1-500: 0.1-100: 1-5000 and 5-300: 0.5-80: 5-4000; preferably 10-250: 0.7-50: 10-3000 and 20-200: 1-30: 30-2000; more preferably 30-150: 3-20: 50-1000 and 40-120: 5-15: 100-800; further preferably 50-100: 7-12: 200-600 and 60-80: 8-10: 300-500.
The mass percentage of A, B and C in the weeding composition accounts for 1-95 percent of the total amount, and preferably 10-80 percent.
The weeding composition also comprises conventional auxiliaries which comprise a carrier and a surfactant.
The term "carrier" herein denotes an organic or inorganic, natural or synthetic substance. They facilitate the application of the active ingredient, the carrier being generally inert and must be agriculturally acceptable, in particular for the treated plant. The carrier may be a solid, such as a clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, or the like; or liquids such as water, alcohols, ketones, petroleum distillates, aromatic or waxy hydrocarbons, chlorinated hydrocarbons, liquefied gases, etc.
Surfactants may include emulsifying, dispersing or wetting agents, which may be ionic or non-ionic. Examples which may be mentioned are salts of polyacrylic acids, lignosulphonates, salts of phenolsulphonic or naphthalenesulphonic acids, polymers of ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols, in particular alkylphenols or arylphenols, sulphosuccinates, taurine derivatives, in particular taurine alkyl esters, and phosphoric esters of alcohols or polyhydroxyethylated phenols, alkylsulfonates, alkylarylsulphonates, alkylsulfates, lauryl ether sulphates, fatty alcohol sulphates, and sulphated hexadec, heptadeca-and octadecanols and sulphated fatty alcohol glycol ethers, and furthermore condensates of naphthalene or naphthalenesulphonic acids with phenol and formaldehyde, polyoxyethylene octylphenyl ether, ethoxylated isooctylphenol, octylphenol or nonylphenol, alkylphenyl polyglycol ethers, tributylphenyl polyglycol ether, tristearylphenyl polyglycol ether, polystearylphenyl polyglycol ether, Alkylaryl polyether alcohols, alcohol and fatty alcohol/ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers, ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal, sorbitol esters, lignosulfite waste liquors, and also proteins, denatured proteins, polysaccharides (e.g. methylcellulose), hydrophobically modified starches, polyvinyl alcohols, polycarboxylates, polyalkoxylates, polyvinylamines, polyvinylpyrrolidone and copolymers thereof. At least one surfactant is required to be present to facilitate dispersion of the active ingredients in water and to facilitate their proper application to the plant.
The compositions may also contain various other components such as protective colloids, binders, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants, and polymers.
In addition, the ternary compositions of the invention may be mixed with active substances known, for example, from the encyclopedia of New agricultural chemical products in the world, the national agricultural science and technology Press, 2010.9 and the references cited therein. For example, herbicidal active substances mentioned below (remarks: the name of the compound, or the generic name according to the International organization for standardization (ISO), or the chemical name, when appropriate with a code), acetochlor, butachlor, alachlor, propisochlor, metolachlor, s-metolachlor, pretilachlor, propachlor, butachlor, napropamide, R-laevo-napropamide, propanil, mefenacet, diphenoyl-oxamide, diflufenican, flumetsulam, bebutamid, dimethenamid, ethoxybenclamide, flufenacet, methoxyfenacet, metazachlor, isooxachlor, lofluvalinate, dimethenamid, butachlor, propisochlor, mefenamid, flucetochlor, propyzamide, dimethenamid, penoxsulam, propyne, dimethenamid, terbutamid, dimethenamid, dimethachlor, norfluramine, trifoliamine, chlorantraniliprole, propyzamide, penflufen, napropamide, acetometazachlor, naproxen, fenacet, pyraflufen, metolachlor, clofenamide, butachlor, butamidin, fluazinam, atrazine, simazine, prometryn, cyanazine, simetryn, ametryn, prometryn, ipretryn, fluroxypyr, terbutryn, terbutazine, triazineon, cyhalofop, ganciclovir, prometryn, simazine, triazazine, dimethametrazine, isopentetryn, cycloprozine, terbutryn, sec-butyn, terbutaline, terbutryn, metolachlor, cyhalofop, metolachlor, prometryn, simazine, atrazine, dimethametryn, dimethametin, terbutryn, metolachlor, dimethachlor, dimethozin, atrazine, metolachloraz, metolachlor, metolachlorethan, metolachlor, atrazine, metolachlorethan, atrazine, metolachlor, atrazine, metolachlor, atrazine, metolachlorfenbutazine, metolachlor, metolachlorfenbutazine, atrazine, metolachlor, atrazine, metolachlor, atrazine, metolachlor, atrazine, metolachlor, Cyanuric acid, Indaziflam, chlorsulfuron, metsulfuron, bensulfuron-methyl, chlorimuron-ethyl, tribenuron-methyl, thifensulfuron-methyl, pyrazosulfuron-ethyl, mesosulfuron-methyl, iodosulfuron-methyl sodium, formamidosulfuron, cinosulfuron, triasulfuron, sulfometuron-methyl, nicosulfuron, ethametsulfuron-methyl, amidosulfuron, ethoxysulfuron, cyclosulfamuron-methyl, rimsulfuron, azimsulfuron-methyl, monosulfuron-methyl, primisulfuron-methyl, flusulfuron-methyl, flazasulfuron-methyl, propsulfuron-methyl, prosulfuron-methyl, trifloxysulfuron, triflusulfuron-methyl, metsulfuron-methyl, primisulfuron-methyl, propulsulfuron-methyl, propaferon-methyl, triflusulfuron-methyl, sulfometuron-methyl, pyrisulfuron-methyl, propalis-ethyl, thiuron-methyl, sulfometuron-methyl, sulfometuron-ethyl, sulfometuron-ethyl, sulfofluridone, sulfometuron-ethyl, sulfofluridone, sulfometuron-methyl, sulfofluridone, sulfometuron-ethyl, benfluridone, bensulfuron-ethyl, bensulfuron-methyl, bensulfuron-ethyl, bensulfuron-methyl, bensulfuron-ethyl, bensulfuron-methyl, ben, Dicumyl ether, aclonifen, ethoxyfen-ethyl, bifenox, trifluoromethoxyfen, metoxyfen, trifluornitrofen, fluoroglycofen, fluridone, bifenox, dimethofen, fluazifop-butyl, Halosafen, chlortoluron, isoproturon, linuron, diuron, fenpropuron, fluometuron, methabenzthiazuron, benzuron, sulfosulfuron, clofenuron, tebuthiuron, clodinuron, meturon, metoxuron, bromuron, metoxuron, meturon, metoxuron, metoron, metoxuron, metoron, Betalain, asulam, tefurazol, avenacalin, anilazine, chlorpropham, dichlofenamate, imazalil, cloropham, Carboxazole, chlorerprocarb, Fenasulam, BCPC, CPPC, Carbasulam, buticarb, thiobencarb, dimethenate, triallate, dichloropetalum, ethiofen, prosulfocarb, cloquintocet, prosulfocarb, dichloropetalum, dichloropetalate, dichloropetal, 2-methyl-4-chloropropionate, 2-methyl-4-chlorobutyric acid, 2,4, 5-nasal discharge propionic acid, 2,4, 5-nasal discharge butyric acid, 2-methyl-4-chloroamine salt, dicamba, woollen boom, varparvax, cypress, triclosan, dichlorfenamic acid, metoclopramide, diclofop-p-ethyl, haloxyfop-methyl, haloxyfop-ethyl, quizalofop-p-ethyl, fenoxaprop-p-ethyl, cyhalofop-butyl, fenoxaprop-p-ethyl, cloroph-ethyl, haloxyfop-ethyl, trifoliate-ethyl, clomazone, paraquat, dixyl, asulam, flutolon, isoproturon, chlorothalofop-ethyl, cyhalofop-p-ethyl, propafen-ethyl, butyfen-ethyl, fluroxypyr, metalaxyl, propafen, propaferin, benfop-p, and, Glyphosate, anilofos, glufosinate, sulfosate, piperaphos, bialaphos, bensulide, imazapyr, mepyrazine, varroa, amifostine, glufosinate, imazethapyr ammonium salt, imazethapyr, imazamethabenz ester, fluroxypyr, isooctyl fluroxypyr, clopyralid, picloram, triclopyr, dithiopyr, haloxyfen, triclopyr, thiazopyr, flurazinone, aminopyralid, flurazone, diflufenzopyr, butoxyethyl triclopyr, ciodinate, sethoxydim, clethodim, thiacet, sethoxydim, clethodim, carfenflurazone, buthiazole, metribuzin, carfenflurazone, metamitron, fenflurazone, fenpyr, benzone, iodoxynil, bromoxynil, isoflurazone, isofluroxypyr, bensulam, isofluroxypyr, clomazone, isofluroxyphenbutazone, clomazone, haloxynil, clomazone, haloxynil, clomazone, haloxynil, clomazone, haloxynil, clomazone, haloxynil, clomazone, haloxynil, clomazone, and so, pyroxynil, and so-type, and so, Ioxynil, dichlobenil, tolfenacet, pyraclonil, Iodobonil, flumetsulam, florasulam, penoxsulam, sulfentrazone, cloransulam, diclosulam, pyroxsulam, fluralin, bispyribac, pyribenzoxim, pyriminobac-methyl, pyrithiobac-methyl, bicyclosulfuron, mesotrione, Tembotrione, Tefuryltrione, Bicyclopyrone, ketoxydipradox, isoxaflutole, fenoxasulfolane, Methiozolin, isopyrafen, pyraflufen, pyraflutole, pyrazotocide, pyraclonil, pyraclofenacetone, flumetsulcotrione, flumetsulam, fenflurazole, fentrazachlor, amicarbazone, fentrazachlor, pyrazachlor, pyraclonil, flumicloram, flumioxazone, fenflurazole, flumicloram, bexapyroxadim, flumicloram, bexadim, flumicloram, benfluroram, flumicloram, benfluroram, flumicloram, benfluroram, bensul, Phthalidyl ether, Flumezin, pentachlorophenol (sodium), dinol, terbenol, terbutal, pendimethalin, dinitrophenol, chloronitrophenol, dimethomorph, oxadiargyl, oxadiazon, pentoxazone, flumetsulam, mefenoxaprop-p-ethyl, tetrazolyl amine, fluridazin, oxamyl, bromamine, dimethenamid, pyridaben, pyridate, pyrirfalol, quinclorac, bentazone, pyridate, oxaziclorac, benazolin, clomazone, clomeptyl, isoprox, iprodione, propamocarb, cumylfen, indoxacarb, sodium chlorate, dalton, dalapon, trichloroacetic acid, monochloroacetone, hexachloroacetone, tetrafluoropropionic acid, pasture, bromophenol oxime, triazoxide, fentrazol, furamethon, fursulam, ethon, benfurazolin, pyrimethanil, clorac, clodinafop, clorac, cumquat, cumarone, clorac, Thidiazuron, alantin, hydroxybenone, metophenone, saflufenacil, dichlorophosphoric, trichloropropionic acid, Alorac, Diethamquat, Etnipromid, Iphridam, Ipfancarbazone, Thiencarbazone-methyl, Pyrimisulfan, Chlorflurflurazone, Tripropindan, Sulglycapin, Sumbelanoline, Campandichlor, Cytopyrimidic acid, thiocyananilide, clethodim, fenclorim, cloquintocet, mequintocet, oxaziclomex, oxabetrinil, pyroxaglim, furazolidone, imazaquin, isoxadifen, dichlormid, halauxin, halauxifen, DOWF, UBH-509, D489, LS 82-556, KPP-300, NC-324, NC-330, KH-218, DPX-N8189, SC-0744, DOWCO535, DK-8910, V-53482, PP-600, MBH-001, KIH-9201, ET-751, KIH-6127 and KIH-2023.
The herbicidal composition further comprises at least one safener selected from the group consisting of:
a) dichlorophenyl pyrazoline-3-carboxylic acid (S1) compounds, preferred compounds are, for example, ethyl 1- (2, 4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl-2-pyrazoline-3-carboxylate (S1-1 mefenpyr-diethyl, PM, p. 594-595), and related compounds described, for example, in WO91/07874 and PM (p. 594-595).
b) Dichlorophenyl pyrazole carboxylic acid derivatives, preferred compounds are, for example, ethyl 1- (2, 4-dichlorophenyl) -5-methylpyrazole-3-carboxylate (S1-2), ethyl 1- (2, 4-dichlorophenyl) -5-isopropylpyrazole-3-carboxylate (S1-3), ethyl 1- (2, 4-dichlorophenyl) -5- (1, 1-dimethyl-ethyl) pyrazole-3-carboxylate (S1-4), ethyl 1- (2, 4-dichlorophenyl) -5-phenylpyrazole-3-carboxylate (S1-5), and related compounds as described in EP-A-333131 and EP-A-269806.
c) Triazole carboxylic acids (S1) and preferred compounds are, for example, fenchlorazole (fenchlorazole), i.e. ethyl 1- (2, 4-dichlorophenyl) -5-trichloromethyl- (1H) -1,2, 4-triazole-3-carboxylate (S1-6) and related compounds (see EP-A-174562 and EP-A-346620).
d) 5-benzyl-or 5-phenyl-2-isoxazoline-3-carboxylic acids or 5, 5-diphenyl-2-isoxazoline-3-carboxylic acids, preferred compounds being, for example, ethyl 5- (2, 4-dichlorobenzyl) -2-isoxazoline-3-carboxylate (S1-7) or ethyl 5-phenyl-2-isoxazoline-3-carboxylate (S1-8) and related compounds described in WO91/08202, or ethyl 5, 5-diphenyl-2-isoxazoline-3-carboxylate (S1-9, isoxadifen-ethyl)) or 5 described in the patent application (WO-A-95/07897), n-propyl 5-diphenyl-2-isoxazoline-3-carboxylate (S1-10) or ethyl 5- (4-fluorophenyl) -5-phenyl-2-isoxazoline-3-carboxylate (S1-11).
e) 8-Quinolinyloxyacetic acids (S2) of the class of compounds, preferably 1-methylhexan-1-yl (5-chloro-8-quinolinyloxy) acetate (S2-1, cloquintocet-mexyl), such as PM (p. 195-), (1, 3-dimethylbut-1-yl) (5-chloro-8-quinolinyloxy) acetate (S2-2), 4-allyloxybutyl (5-chloro-8-quinolinyloxy) acetate (S2-3), 1-allyloxypropan-2-yl (5-chloro-8-quinolinyloxy) acetate (S2-4), (ethyl 5-chloro-8-quinolinyloxy) acetate (S2-5), (methyl 5-chloro-8-quinolinyloxy) acetate (S2-6), allyl (5-chloro-8-quinolinyloxy) acetate (S2-7), 2- (2-propyleneiminoyloxy) -1-ethyl (5-chloro-8-quinolinyloxy) acetate (S2-8), 2-oxopropan-1-yl (5-chloro-8-quinolinyloxy) acetate (S2-9), and related compounds described in EP-A-86750, EP-A-94349 and EP-A-191736 or EP-A-0492366.
f) (5-chloro-8-quinolinoxy) propanedioic acid-based compounds, preferred compounds are, for example, diethyl (5-chloro-8-quinolinoxy) malonate, (diallyl (5-chloro-8-quinolinoxy) malonate, (methylethyl (5-chloro-8-quinolinoxy) -malonate and related compounds described in EP-A-0582198.
g) Phenoxyacetic acid, phenoxypropionic acid or aromatic carboxylic acids, such as 2, 4-dichlorophenoxyacetic acid (and esters) (2,4-D), 4-chloro-2-methylphenoxypropionate (2-methyl-4-chloropropionic acid (mecoprop)), MCPA or 3, 6-dichloro-2-methoxybenzoic acid (and esters) (dicamba).
h) Pyrimidines, such as fenclorim (PM, page 386-387) (═ 4, 6-dichloro-2-phenylpyrimidine),
i) dichloroacetamide-based active compounds, which are frequently used as pre-emergence safeners (soil-working safeners), for example "dichloroallylamine (dichlormid)" (PM, page 270-271) (═ N, N-diallyl-2, 2-dichloroacetamide), "AR-29148" (-3-dichloroacetyl-2, 2, 5-trimethyl-1, 3-oxazolidinone from Stauffer), "benoxacor" (PM, page 74-75) (-4-dichloroacetyl-3, 4-dihydro-3-methyl-2H-1, 4-benzoxazine), "APPG-1292" (-N-allyl-N [ (1, 3-dioxolan-2-yl) -methyl ] dichloroacetamide, from PPG Industries), "ADK-24" (═ N-allyl-N- [ (allylaminocarbonyl) -methyl ] -dichloroacetamide, from Sagro-Chem), "AAD-67" or "AMON 4660" (═ 3-dichloroacetyl-1-oxa-3-aza-spiro [4,5] decane, from nitrkemia or Monsanto), "diclonon" or "ABAS 145138" or "ala b 145138" (═ 3-dichloroacetyl-2, 5, 5-trimethyl-1, 3-diazabicyclo [4.3.0] nonane, from BASF), and "furilazol" or "AMON 13900" (see PM, 482-483) ((RS) -3-dichloroacetyl-5- (2-furyl) -2, 2-dimethyloxazolidinone),
j) dichloroacetone derivative-based active compounds, for example, "AMG 191" (CAS registry No. 96420-72-3) (═ 2-dichloromethyl-2-methyl-1, 3-dioxolane, available from Nitrokemia),
k) oxyimino compounds as active compounds, which are referred to as seed dressing materials, for example "oxabetrinil" (PM, page 689) (═ Z) -1, 3-dioxolan-2-ylmethoxyimino (phenyl) acetonitrile), which in seed dressing is referred to as safener in order to prevent damage to metolachlor (metallachlor), "fluoroxyfen" (PM, page 467 468) (═ 1- (4-chlorophenyl) -2,2, 2-trifluoro-1-ethanone O- (1, 3-dioxolan-2-ylmethyl) -oxime, which in seed dressing is referred to as safener in order to prevent damage to metolachlor (metallachlor), and "cyanohydrin" or "a-CGA-43089" (PM, page 983) ((Z) -cyanomethoxyimino (phenyl) acetonitrile), which is called safener in seed dressing, to prevent the damage of metolachlor (metolachlor),
l) Thiazolecarboxylic acid ester active compounds, which are known as seed dressing materials, for example "flurazon" (PM, p. 450. 451), (-2-chloro-4-trifluoromethyl-1, 3-thiazole-5-carboxylic acid benzyl ester), which are known as safeners in seed dressing to prevent damage to alachlor (alachlor) and metolachlor,
m) active compounds of the naphthalenedicarboxylic acid derivative class, which are known as seed dressings, for example "naphthalic anhydride" (PM, pp 1009-1010) (═ 1, 8-naphthalic anhydride), which are known as safeners in corn seed dressings to prevent damage to thiocarbamate herbicides,
n) chromanoic acid derivatives such as "ACL 304415" (CAS registry No. 31541-57-8) (═ 2-84-carboxychroman-4-yl) acetic acid available from american cyanamid),
o) active compounds which, in addition to herbicidal action on harmful plants, also have safener action on crop plants, for example "penetryn (dimerate)" or "AMY-93" (PM, p.302-303) (═ S-1-methyl-1-phenylethylpiperidine-1-thiocarboxylate), "diuron (daimuron)" or "ASK 23" (PM, p.247) (═ 1- (1-methyl-1-phenylethyl) -3-p-tolylureｃA), "cumyluron (cumyluron)", "jc 940" (═ 3- (2-chlorophenylmethyl) -1- (1-methyl-1-phenyl-ethyl) ureｃA, see JP- ｃA-60087254), "benzophenone (methaxyphenon)" or "ANK 049" (═ 3,3' -dimethyl-4-methoxy-benzophenone), "CSB" (═ 1-bromo-4- (chloromethylsulfonyl) benzene) (CAS registry No. 54091-06-4, available from Kumiai).
The safener is preferably one or more of isoxadifen (CAS: 163520-33-0), cyprosulfamide (CAS: 221667-31-8), mefenpyr (CAS: 135590-91-9), cloquintocet (CAS: 99607-70-2), gibberellic acid (CAS: 7-06-5), furilazole (CAS: 121776-33-8) and metacamifen (CAS: 129531-12-0).
The compositions of the present invention may be diluted or used directly by the user prior to use. The formulation can be prepared by conventional processing methods, i.e., mixing the active substance with a liquid solvent or solid carrier, and adding one or more surfactants such as dispersants, stabilizers, wetting agents, binders, defoamers, etc.
The specific preparation of the weeding composition is dispersible oil suspending agent, water suspending agent, suspending emulsion, wettable powder, missible oil, water dispersible granule (dry suspending agent), emulsion in water and microemulsion.
In short, the compositions of the present invention may be mixed with solid and liquid additives conventionally used in prior art formulations.
The invention also provides application of the ternary weeding composition in controlling weeds in crops; and to provide a method of controlling unwanted plant growth comprising applying the ternary herbicidal composition to plants, parts of plants, plant seeds or areas where plants grow, preferably for the selective control of weeds in crops.
In addition, the compositions according to the invention can be applied by spraying to the foliage of the plants to be treated, i.e. to the weeds, in particular to surfaces which are harmful or susceptible to infestation by weeds which are harmful to the growth of the crop.
When the herbicidal compositions of the present invention are applied, unexpected synergistic effects are obtained and the herbicidal activity is more pronounced than the expected sum of the activities using the individual herbicides and the activity of either individually or in combination of any two of the herbicides. The synergistic effect is manifested by reduced application rates, a broader spectrum of weed control, and a faster and longer lasting herbicidal action, which are desirable in the practice of weed control. These new compositions are clearly superior to existing herbicides in terms of the properties described, achieving reduced use and being more environmentally friendly.
The synergistic herbicidal composition of the invention also has the following advantages:
(1) the composition is environment-friendly, is easy to degrade in the environment, and is suitable for various crop fields.
(2) The weeding composition has low cost and convenient use, and has great economic and social benefits when being popularized and applied.
Detailed Description
The following examples are not intended to limit the invention, but merely to illustrate how the invention may be carried out. These examples show particularly significant effectiveness against certain weeds. Examples are as follows:
A) examples of the embodiments
1. Suspending agent of topramezone, topramezone and pretilachlor (4+3+30)
4% of carfentrazone-ethyl, 3% of topramezone, 30% of pretilachlor, 3% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 4% of castor oil polyoxyethylene ether, 2% of butanol block polyether, 0.12% of xanthan gum, 1.2% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
2. Dispersible oil suspending agent containing topramezone, topramezone and butachlor (2+1.5+30)
2% of carfentrazone-ethyl, 1.5% of carfentrazone-ethyl, 30% of butachlor, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 5% of castor oil-polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica, 5% of 100# solvent oil and methyl oleate
3. Water suspending agent of topramezone, topramezone and mefenacet (4+3+30)
4% oxadiazon, 3% topramezone, 30% mefenacet, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.12% xanthan gum, 1.3% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
4. Dispersible oil suspension agent containing carfentrazone-ethyl, topramezone and anilofos (4+3+15)
4% of carfentrazone-ethyl, 3% of carfentrazone-ethyl, 15% of anilofos, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 5% of castor oil-polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica, 5% of 100# solvent oil and methyl oleate
5. Dispersible oil suspension agent containing carfentrazone-ethyl, topramezone and butralin (2+1.5+24)
2% of carfentrazone-ethyl, 1.5% of carfentrazone-ethyl, 24% of butralin, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 5% of castor oil-polyoxyethylene ether, 2.6% of organic bentonite, 2.5% of fumed silica, 20% of 100# solvent oil and methyl oleate
6. Water suspension agent of topramezone, topramezone and oxadiazon (4+3+30)
4% oxadiazon, 3% topramezone, 30% oxadiazon, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% xanthan gum, 0.8% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
7. Bixaflutole + topramezone + isoproturon (4+3+45) water dispersible granules
4% oxadiazon, 3% topramezone, 45% isoproturon, 10% naphthalenesulfonate dispersant, 2% polycarboxylate dispersant, 4% sodium lauryl sulfate, 10% precipitated silica, 1% polyvinyl alcohol and kaolin to balance
8. Dispersible oil suspension agent containing carfentrazone-ethyl, topramezone and pyraclonil (4+3+14)
4% of carfentrazone-ethyl, 3% of carfentrazone-ethyl, 14% of carfentrazone-ethyl, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 5% of castor oil-polyoxyethylene ether, 1.3% of organic bentonite, 1.2% of fumed silica, 6% of 100# solvent oil and methyl oleate
9. Dispersible oil suspension agent containing carfentrazone-ethyl, topramezone and oxyfluorfen (4+3+12)
4% of carfentrazone-ethyl, 3% of carfentrazone-ethyl, 12% of oxyfluorfen, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 5% of castor oil-polyoxyethylene ether, 1.6% of organobentonite, 1.6% of fumed silica, 6% of 100# solvent oil and methyl oleate
10. Dispersible oil suspension agent containing topramezone, topramezone and clomazone (4+3+16)
4% of carfentrazone-ethyl, 3% of topramezone, 16% of clomazone, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 5% of castor oil-polyoxyethylene ether, 1.6% of organic bentonite, 1.6% of fumed silica, 6% of 100# solvent oil and methyl oleate
11. Dispersible oil suspension agent containing carfentrazone-ethyl, topramezone and 2-methyl-4-chloro (4+3+18)
4% of carfentrazone-ethyl, 3% of carfentrazone-ethyl, 18% of 2-methyl-4-chloro, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 5% of castor oil-polyoxyethylene ether, 1.2% of organic bentonite, 1.2% of fumed silica, 6% of 100# solvent oil and methyl oleate
12. Water suspending agent of topramezone, topramezone and simetryn (2+1.5+30)
2% of carfentrazone-ethyl, 1.5% of carfentrazone-ethyl, 30% of simetryn, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.14% of xanthan gum, 1.2% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
13. Bixaflutole + topramezone + quinclorac (4+3+25) water suspension agent
4% of carfentrazone-ethyl, 3% of topramezone, 25% of quinclorac, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.14% of xanthan gum, 1.5% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
14. Dispersible oil suspension agent containing topramezone, topramezone and penoxsulam (4+3+2)
4% of carfentrazone-ethyl, 3% of carfentrazone-ethyl, 2% of penoxsulam, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 5% of castor oil-polyoxyethylene ether, 3.0% of organobentonite, 2.5% of fumed silica, 6% of 100# solvent oil and methyl oleate
15. Dispersible oil suspending agent containing carfentrazone-ethyl, topramezone and fluroxypyr-meptyl (4+3+1)
4% of carfentrazone-ethyl, 3% of carfentrazone-ethyl, 1% of chlorofluoropyridyl ester, 5% of calcium dodecyl benzene sulfonate, 6% of fatty alcohol-polyoxyethylene ether, 5% of castor oil-oxyethylene ether, 3.0% of organobentonite, 2.5% of fumed silica, 6% of 100# solvent oil and methyl oleate
16. Dispersible oil suspending agent containing carfentrazone-ethyl, topramezone and molinate (1+0.75+50)
1% of diconazole, 0.75% of topramezone, 50% of molinate, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organic bentonite, 2.5% of fumed silica and methyl oleate
17. Dispersible oil suspending agent containing diconazole, topramezone and thiobencarb (1+0.75+50)
1% of diconazole, 0.75% of topramezone, 50% of thiobencarb, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organic bentonite, 2.5% of fumed silica and methyl oleate
18. Dispersible oil suspension agent containing topramezone, mesotrione and pretilachlor (4+10+30)
4% of diazolidinone, 10% of mesotrione, 30% of pretilachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 2.5% of organobentonite, 2.5% of fumed silica and methyl oleate
19. Dispersible oil suspension agent containing topramezone, mesotrione and butachlor (2+5+30)
2% of diazolidinone, 5% of mesotrione, 30% of butachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.5% of organobentonite, 2.5% of fumed silica and methyl oleate
20. Water suspension agent of topramezone, mesotrione and mefenacet (4+10+30)
4% oxadiazon, 10% mesotrione, 30% mefenacet, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% xanthan gum, 0.8% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
21. Dispersible oil suspension agent of diconazole, mesotrione and anilofos (4+10+15)
4% of diazole, 10% of mesotrione, 15% of anilofos, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 2.5% of organic bentonite, 2.5% of fumed silica, 10% of 100# solvent oil and methyl oleate
22. Dispersible oil suspension agent containing topramezone, mesotrione and butralin (2+5+24)
2% of diazolidinone, 5% of mesotrione, 24% of butralin, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.5% of organobentonite, 2.5% of fumed silica, 20% of 100# solvent oil and methyl oleate
23. Water suspension agent of topramezone, mesotrione and oxadiazon (4+10+30)
4% diazolecotone, 10% mesotrione, 30% oxadiazon, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% xanthan gum, 0.8% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
24. Water dispersible granule of topramezone, mesotrione and isoproturon (4+10+45)
The balance of 4% diazole, 10% mesotrione, 45% isoproturon, 10% naphthalenesulfonate dispersant, 2% polycarboxylate dispersant, 4% sodium lauryl sulfate, 10% precipitated silica, 1% polyvinyl alcohol and kaolin
25. Dispersible oil suspension agent containing carfentrazone-ethyl, mesotrione and pyraclonil (4+10+14)
4% of carfentrazone-ethyl, 10% of mesotrione, 14% of pyraclonil, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.0% of organobentonite, 1.0% of fumed silica, 5% of 100# solvent oil and methyl oleate
26. Dispersible oil suspension agent containing topramezone, mesotrione and oxyfluorfen (4+10+12)
4% of diazole, 10% of mesotrione, 12% of oxyfluorfen, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.6% of organic bentonite, 1.6% of fumed silica, 15% of 100# solvent oil and methyl oleate
27. Dispersible oil suspension agent containing topramezone, mesotrione and clomazone (4+10+16)
4% of diazolidinone, 10% of mesotrione, 16% of clomazone, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 0.8% of organic bentonite, 5% of 100# solvent oil and methyl oleate
28. Dispersible oil suspending agent containing topramezone, mesotrione and 2-methyl-4-chloro (4+10+18)
4% of diazolidinone, 10% of mesotrione, 18% of 2-methyl-4-chloro compound, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 0.6% of organic bentonite, 15% of 100# solvent oil and methyl oleate
29. Water suspension agent of topramezone, mesotrione and simetryn (2+5+30)
2% diazole, 5% mesotrione, 30% simetryn, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% xanthan gum, 1.2% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
30. Water suspension agent of topramezone, mesotrione and quinclorac (4+10+25)
4% diazole, 10% mesotrione, 25% quinclorac, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% xanthan gum, 1.0% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
31. Dispersible oil suspension agent containing topramezone, mesotrione and penoxsulam (4+10+2)
4% of carfentrazone-ethyl, 10% of mesotrione, 2% of penoxsulam, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organobentonite, 1.6% of fumed silica, 5% of 100# solvent oil and methyl oleate
32. Dispersible oil suspending agent containing carfentrazone-ethyl, mesotrione and fluroxypyr-meptyl (4+10+1)
4% of diazolidinone, 10% of mesotrione, 1% of chlorofluoropyridine ester, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 2.0% of organobentonite, 1.6% of fumed silica, 5% of 100# solvent oil and methyl oleate
33. Dispersible oil suspending agent containing diconazole, mesotrione and molinate (1+2.5+50)
1% of diazole, 2.5% of mesotrione, 50% of molinate, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organic bentonite, 2.0% of fumed silica and methyl oleate
34. Dispersible oil suspending agent containing diconazole, mesotrione and thiodan (1+2.5+50)
1% of diazole, 2.5% of mesotrione, 50% of molinate, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organic bentonite, 2.0% of fumed silica and methyl oleate
35. Dispersible oil suspension agent containing topramezone, tembotrione and pretilachlor (4+6+30)
4% of diazole, 6% of tembotrione, 30% of pretilachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organobentonite, 2.0% of fumed silica and methyl oleate
36. Dispersible oil suspension agent containing topramezone, tembotrione and butachlor (2+3+30)
2% of diazole, 3% of tembotrione, 30% of butachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organobentonite, 2.0% of fumed silica and methyl oleate
37. Water suspension agent of topramezone, tembotrione and mefenacet (4+6+30)
4% oxadiazon, 6% tembotrione, 30% mefenacet, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% xanthan gum, 1.0% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
38. Dispersible oil suspension agent containing carfentrazone-ethyl, tembotrione and anilofos (4+6+15)
4% of diazole, 6% of tembotrione, 15% of anilofos, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organobentonite, 2.0% of fumed silica, 12% of 100# solvent oil and methyl oleate
39. Dispersible oil suspension agent containing topramezone, tembotrione and butralin (2+3+24)
2% of diazole, 3% of tembotrione, 24% of butralin, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organic bentonite, 2.0% of fumed silica, 20% of 100# solvent oil and methyl oleate
40. Water suspension agent of topramezone, tembotrione and oxadiazon (4+6+30)
4% diazole, 6% tembotrione, 30% oxadiazon, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% xanthan gum, 1.0% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
41. Bixaflutole + tembotrione + isoproturon (4+6+45) water dispersible granule
4% oxadiazon, 6% tembotrione, 45% isoproturon, 10% naphthalenesulfonate dispersant, 2% polycarboxylate dispersant, 4% sodium lauryl sulfate, 10% precipitated silica, 1% polyvinyl alcohol and kaolin to balance
42. Dispersible oil suspension agent containing carfentrazone-ethyl, tembotrione and pyraclonil (4+6+14)
4% of carfentrazone-ethyl, 6% of tembotrione, 14% of pyraclonil, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 0.8% of organic bentonite, 10% of 100# solvent oil and methyl oleate
43. Dispersible oil suspending agent containing topramezone, tembotrione and oxyfluorfen (4+6+12)
4% of diazole, 6% of tembotrione, 12% of oxyfluorfen, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.2% of organic bentonite, 1.2% of fumed silica, 10% of 100# solvent oil and methyl oleate
44. Dispersible oil suspension agent containing topramezone, tembotrione and clomazone (4+6+16)
4% of diazole, 6% of tembotrione, 16% of clomazone, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 0.8% of organic bentonite, 10% of 100# solvent oil and methyl oleate
45. Dispersible oil suspension agent containing topramezone, tembotrione and 2-methyl-4-chloro (4+6+18)
4% of diazole, 6% of tembotrione, 18% of 2-methyl-4-chloro compound, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 0.6% of organic bentonite, 10% of 100# solvent oil and methyl oleate
46. Water suspension agent of topramezone, tembotrione and simetryn (2+3+30)
2% of carfentrazone-ethyl, 3% of tembotrione, 30% of simetryn, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.12% of xanthan gum, 1.2% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
47. Water suspension agent of topramezone, tembotrione and quinclorac (4+6+25)
4% of carfentrazone-ethyl, 6% of tembotrione, 25% of quinclorac, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.12% of xanthan gum, 1.2% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
48. Dispersible oil suspension agent containing topramezone, tembotrione and penoxsulam (4+6+2)
4% of carfentrazone-ethyl, 6% of tembotrione, 2% of penoxsulam, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organobentonite, 2.0% of fumed silica, 10% of 100# solvent oil and methyl oleate
49. Dispersible oil suspending agent containing carfentrazone-ethyl, tembotrione and fluroxypyridine (4+6+1)
4% of diazole, 6% of tembotrione, 1% of chlorofluoropyridine ester, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 2.5% of organic bentonite, 2.0% of fumed silica, 10% of 100# solvent oil and methyl oleate
50. Dispersible oil suspending agent containing topramezone, tembotrione and molinate (1+1.5+50)
1% of diazole, 1.5% of tembotrione, 50% of molinate, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organic bentonite, 2.0% of fumed silica and methyl oleate
51. Dispersible oil suspending agent containing diconazole, tembotrione and benthiocarb (1+1.5+50)
1% of diazole, 1.5% of tembotrione, 50% of thiobencarb, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organic bentonite, 2.0% of fumed silica and methyl oleate
52. Dispersible oil suspension agent containing topramezone, isoxaflutole and pretilachlor (4+6+30)
4% of diazolidinone, 6% of isoxaflutole, 30% of pretilachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 2.0% of organobentonite, 2.0% of fumed silica and methyl oleate
53. Dispersible oil suspension agent containing topramezone, isoxaflutole and butachlor (2+3+30)
2% of diconazole, 3% of isoxaflutole, 30% of butachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organobentonite, 2.0% of fumed silica and methyl oleate
54. Water suspension agent of topramezone, isoxaflutole and mefenacet (4+6+30)
4% oxadiazon, 6% isoxaflutole, 30% mefenacet, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% xanthan gum, 1.0% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
55. Dispersible oil suspension agent containing carfentrazone-ethyl, isoxaflutole and anilofos (4+6+15)
4% of diazolidinone, 6% of isoxaflutole, 15% of anilofos, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 2.5% of organobentonite, 2.0% of fumed silica, 12% of 100# solvent oil and methyl oleate
56. Dispersible oil suspension agent containing topramezone, isoxaflutole and butralin (2+3+24)
2% of carfentrazone-ethyl, 3% of isoxaflutole, 24% of butralin, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organobentonite, 2.0% of fumed silica, 20% of 100# solvent oil and methyl oleate
57. Water suspension agent of topramezone, isoxaflutole and oxadiazon (4+6+30)
4% oxadiazon, 6% isoxaflutole, 30% oxadiazon, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% xanthan gum, 1.0% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
58. Water dispersible granule of topramezone, isoxaflutole and isoproturon (4+6+45)
4% oxadiazon, 6% isoxaflutole, 45% isoproturon, 10% naphthalenesulfonate dispersant, 2% polycarboxylate dispersant, 4% sodium lauryl sulfate, 10% precipitated silica, 1% polyvinyl alcohol, and kaolin to balance
59. Dispersible oil suspension agent containing carfentrazone-ethyl, isoxaflutole and pyraclonil (4+6+14)
4% of carfentrazone-ethyl, 6% of isoxaflutole, 14% of carfentrazone-ethyl, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 0.8% of organic bentonite, 10% of 100# solvent oil and methyl oleate
60. Dispersible oil suspension agent containing carfentrazone-ethyl, isoxaflutole and oxyfluorfen (4+6+12)
4% of carfentrazone-ethyl, 6% of isoxaflutole, 12% of oxyfluorfen, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organobentonite, 2.0% of fumed silica, 15% of 100# solvent oil and methyl oleate
61. Dispersible oil suspension agent containing topramezone, isoxaflutole and clomazone (4+6+16)
4% of diazole, 6% of isoxaflutole, 16% of clomazone, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.5% of organic bentonite, 1.5% of fumed silica, 5% of 100# solvent oil and methyl oleate
62. Dispersible oil suspension agent containing topramezone, isoxaflutole and 2-methyl-4-chloro (4+6+18)
4% of diazolidinone, 6% of isoxaflutole, 18% of 2-methyl-4-chloro compound, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.0% of organobentonite, 0.8% of fumed silica, 5% of 100# solvent oil and methyl oleate
63. Water suspension agent of topramezone, isoxaflutole and simetryn (2+3+30)
2% of carfentrazone-ethyl, 3% of isoxaflutole, 30% of simetryn, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.14% of xanthan gum, 1.4% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
64. Bixaflutole, isoxaflutole and quinclorac (4+6+25) aqueous suspension
4% oxadiazon, 6% isoxaflutole, 25% quinclorac, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.14% xanthan gum, 1.4% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
65. Dispersible oil suspension agent containing topramezone, isoxaflutole and penoxsulam (4+6+2)
4% of carfentrazone-ethyl, 6% of isoxaflutole, 2% of penoxsulam, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.5% of organobentonite, 2.0% of fumed silica, 5% of 100# solvent oil and methyl oleate
66. Dispersible oil suspending agent containing carfentrazone-ethyl, isoxaflutole and fluroxypyr-meptyl (4+6+1)
4% of diazolidinone, 6% of isoxaflutole, 1% of chlorofluoropyridine ester, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 2.5% of organobentonite, 2.0% of fumed silica, 5% of 100# solvent oil and methyl oleate
67. Dispersible oil suspending agent containing diconazole, isoxaflutole and molinate (1+1.5+50)
1% of diazolidinone, 1.5% of isoxaflutole, 50% of molinate, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 2.5% of organic bentonite, 2.0% of fumed silica and methyl oleate
68. Dispersible oil suspension agent containing diconazole, isoxaflutole and thiobencarb (1+1.5+50)
1% of diconazole, 1.5% of isoxaflutole, 50% of thiobena, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.5% of organic bentonite, 2.0% of fumed silica and methyl oleate
69. Dispersible oil suspension agent containing topramezone, benzobicyclon and pretilachlor (4+20+30)
4% of carfentrazone-ethyl, 20% of bicyclsulcotrione, 30% of pretilachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.8% of organobentonite, 1.8% of fumed silica and methyl oleate
70. Dispersible oil suspension agent containing topramezone, bicyclosulfuron and butachlor (1+5+15)
1% of carfentrazone-ethyl, 5% of bicyclsulcotrione, 15% of butachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.5% of organobentonite, 2.0% of fumed silica and methyl oleate
71. Water dispersible granule of topramezone, benzobicyclon and mefenacet (4+20+30)
4% of topramezone, 20% of dicumulone, 30% of mefenacet, 10% of naphthalenesulfonate dispersant, 2% of polycarboxylate dispersant, 4% of sodium dodecyl sulfate, 10% of precipitated silica, 1% of polyvinyl alcohol and kaolin
72. Dispersible oil suspension agent containing carfentrazone-ethyl, benzobicyclon and anilofos (4+20+15)
4% of carfentrazone-ethyl, 20% of benzobicyclon, 15% of anilofos, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 1.5% of organobentonite, 1.5% of fumed silica, 12% of 100# solvent oil and methyl oleate
73. Dispersible oil suspension agent containing carfentrazone-ethyl, bicyclosulfulone and butralin (2+10+24)
2% of carfentrazone-ethyl, 10% of bicyclosulfuron, 24% of butralin, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organobentonite, 2.0% of fumed silica, 20% of 100# solvent oil and methyl oleate
74. Water dispersible granule of topramezone, benzobicyclon and oxadiazon (4+20+30)
4% of topramezone, 20% of dicumulone, 30% of oxadiazon, 10% of naphthalenesulfonate dispersant, 2% of polycarboxylate dispersant, 4% of sodium dodecyl sulfate, 10% of precipitated silica, 1% of polyvinyl alcohol and kaolin
75. Water suspension agent of topramezone, benzobicyclon and isoproturon (2+10+22.5)
2% diazolecotone + 10% bicyclosulfotone + 22.5% isoproturon + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.15% xanthan gum + 1.5% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
76. Water suspension agent of topramezone, dicumulone and pyraclonil (4+20+14)
4% of carfentrazone-ethyl, 20% of bicyclsulcotrione, 14% of carfentrazone-ethyl, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.15% of xanthan gum, 1.5% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
77. Dispersible oil suspension agent containing carfentrazone-ethyl, bicyclsulcotrione and oxyfluorfen (4+20+12)
4% of carfentrazone-ethyl, 20% of bicyclosulfuron, 12% of oxyfluorfen, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.6% of organic bentonite, 1.6% of fumed silica, 15% of 100# solvent oil and methyl oleate
78. Water suspension agent of topramezone, bicyclosulfuron and clomazone (4+20+16)
4% of carfentrazone-ethyl, 20% of bicyclosulfrione, 16% of clomazone, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
79. Water suspension agent of topramezone, bicyclosulfuron and 2-methyl-4-chloro (4+20+18)
4% diazolecotone, 20% bicyclosulfotone, 18% 2-methyl-4-chloro, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.15% xanthan gum, 1.5% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
80. Dispersible oil suspension agent containing carfentrazone-ethyl, bicyclsulcotrione and simetryn (1+5+15)
1% of carfentrazone-ethyl, 5% of bicyclsulcotrione, 15% of simetryn, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.6% of organobentonite, 1.6% of fumed silica, 10% of 100# solvent oil and methyl oleate
81. Water suspension agent of topramezone, benzobicyclon and quinclorac (4+20+25)
4% of carfentrazone-ethyl, 20% of bicyclosulfrione, 25% of quinclorac, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.07% of xanthan gum, 0.7% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
82. Dispersible oil suspension agent containing topramezone, bicyclosulfuron and penoxsulam (4+20+2)
4% of carfentrazone-ethyl, 20% of bicyclosulfuron, 2% of penoxsulam, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.4% of organic bentonite, 1.0% of fumed silica, 10% of 100# solvent oil and methyl oleate
83. Dispersible oil suspending agent containing carfentrazone-ethyl, bicyclosulfulone and chloropyridyl ester (4+20+1)
4% of carfentrazone-ethyl, 20% of bicyclosulfrione, 1% of chlorofluoropyridyl ester, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 1.4% of organobentonite, 1.0% of fumed silica, 10% of 100# solvent oil and methyl oleate
84. Dispersible oil suspension agent containing carfentrazone-ethyl, bicyclsulcotrione and molinate (1+5+50)
1% of carfentrazone-ethyl, 5% of bicyclosulfuron, 50% of molinate, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organobentonite, 2.5% of fumed silica and methyl oleate
85. Dispersible oil suspension agent containing diconazole, dicylodim and benthiocarb (1+5+50)
1% of diazolidinone, 5% of bicyclsulcotrione, 50% of thiobena, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 3.0% of organic bentonite, 2.5% of fumed silica and methyl oleate
86. Dispersible oil suspension agent containing topramezone, triazophone and pretilachlor (4+12+30)
4% of diazolidinone, 12% of triazophone, 30% of pretilachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organobentonite, 1.5% of fumed silica and methyl oleate
87. Dispersible oil suspension agent containing topramezone, triazophone and butachlor (2+6+30)
2% of diazolidinone, 6% of triazophone, 30% of butachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organobentonite, 2.0% of fumed silica and methyl oleate
88. Water suspension agent of topramezone, triazophone and mefenacet (4+12+30)
4% oxadiazon, 12% triazophone, 30% mefenacet, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.07% xanthan gum, 1.0% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
89. Dispersible oil suspension agent containing topramezone, triazophos and anilofos (4+12+15)
4% of diazole, 12% of triazophone, 15% of anilofos, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organobentonite, 2.0% of fumed silica, 12% of 100# solvent oil and methyl oleate
90. Dispersible oil suspension agent containing topramezone, triazophone and butralin (2+6+24)
2% of diazolidinone, 6% of triazophone, 24% of butralin, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organobentonite, 2.0% of fumed silica, 12% of 100# solvent oil and methyl oleate
91. Water suspension agent of topramezone, triazophone and oxadiazon (4+12+30)
4% diazolecotone, 12% triazophone, 30% oxadiazon, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.07% xanthan gum, 0.8% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
92. Dispersible oil suspension agent containing topramezone, triazophone and isoproturon (2+6+22.5)
2% of diazole, 6% of triazophone, 22.5% of isoproturon, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organic bentonite, 2.0% of fumed silica, 12% of 100# solvent oil and methyl oleate to complement
93. Dispersible oil suspension agent containing carfentrazone-ethyl, triazophone and pyraclonil (4+12+14)
4% of carfentrazone-ethyl, 12% of triazophone, 14% of pyraclonil, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 0.6% of organic bentonite, 10% of 100# solvent oil and methyl oleate
94. Dispersible oil suspension agent containing topramezone, triazophone and oxyfluorfen (4+12+12)
4% of diazole, 12% of triazophone, 12% of oxyfluorfen, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 0.6% of organic bentonite, 15% of 100# solvent oil and methyl oleate
95. Water suspension agent of topramezone, triazophone and clomazone (4+12+16)
4% of topramezone, 12% of triazophone, 16% of clomazone, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.14% of xanthan gum, 1.4% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
96. Water suspension agent of topramezone, triazophone and 2-methyl-4-chloro (4+12+18)
4% diazolecotone + 12% triazophone + 18% 2 methyl 4 chloro + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.15% xanthan gum + 1.5% magnesium aluminium silicate + 0.1% defoamer + 3% ethylene glycol + water
97. Water suspension agent of topramezone, triazophone and simetryn (2+6+30)
2% diazole, 6% triazophone, 30% simetryn, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.16% xanthan gum, 1.6% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
98. Water suspension agent of topramezone, triazophone and quinclorac (4+12+25)
4% diazole, 12% triazophone, 25% quinclorac, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.16% xanthan gum, 1.6% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
99. Dispersible oil suspension agent containing topramezone, triazophone and penoxsulam (4+12+2)
4% of carfentrazone-ethyl, 12% of triazophone, 2% of penoxsulam, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.5% of organobentonite, 1.5% of fumed silica, 10% of 100# solvent oil and methyl oleate
100. Dispersible oil suspending agent containing carfentrazone-ethyl, triazophone and fluroxypyr ester (4+12+1)
4% of diazole, 12% of triazophone, 1% of fluroxypyridine ester, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.2% of organic bentonite, 2.0% of fumed silica, 10% of 100# solvent oil and methyl oleate
101. Dispersible oil suspension agent containing topramezone, triazophone and molinate (1+3+50)
1% of diazole, 3% of triazophone, 50% of molinate, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organic bentonite, 2.0% of fumed silica and methyl oleate
102. Dispersible oil suspension agent containing diconazole, triazophone and benthiocarb (1+3+50)
1% of diazolidinone, 3% of triazophone, 50% of thiobena, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organic bentonite, 2.0% of fumed silica and methyl oleate
103. Dispersible oil suspension agent containing topramezone, topramezone and pretilachlor (4+12+30)
4% of diazolidinone, 12% of benzoxaflutole, 30% of pretilachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 2.0% of organobentonite, 2.0% of fumed silica and methyl oleate
104. Dispersible oil suspension agent containing topramezone, topramezone and butachlor (2+6+30)
2% of carfentrazone-ethyl, 6% of benzoxaflutole, 30% of butachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organobentonite, 2.0% of fumed silica and methyl oleate
105. Water suspending agent of topramezone, topramezone and mefenacet (4+12+30)
4% of carfentrazone-ethyl, 12% of benzoxaflutole, 30% of mefenacet, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% of xanthan gum, 0.6% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
106. Dispersible oil suspension agent containing carfentrazone-ethyl, benzoxaflutole and anilofos (4+12+15)
4% of carfentrazone-ethyl, 12% of benzoxaflutole, 15% of anilofos, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organobentonite, 2.0% of fumed silica, 12% of 100# solvent oil and methyl oleate
107. Dispersible oil suspension agent containing carfentrazone-ethyl, topramezone and butralin (2+6+24)
2% of carfentrazone-ethyl, 6% of benzoxaflutole, 24% of butralin, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organobentonite, 2.0% of fumed silica, 20% of 100# solvent oil and methyl oleate
108. Water suspension agent of topramezone, topramezone and oxadiazon (4+12+30)
4% of carfentrazone-ethyl, 12% of benzoxaflutole, 30% of oxadiazon, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% of xanthan gum, 0.8% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
109. Dispersible oil suspending agent containing topramezone, topramezone and isoproturon (2+6+22.5)
2% of diazolidinone, 6% of benzoxaflutole, 22.5% of isoproturon, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 0.5% of organic bentonite, 10% of 100# solvent oil and methyl oleate
110. Dispersible oil suspension agent containing carfentrazone-ethyl, topramezone and pyraclonil (4+12+14)
4% of carfentrazone-ethyl, 12% of benzoxaflutole, 14% of carfentrazone-ethyl, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 0.8% of organic bentonite, 10% of 100# solvent oil and methyl oleate
111. Dispersible oil suspension agent containing carfentrazone-ethyl, topramezone and oxyfluorfen (4+12+12)
4% of carfentrazone-ethyl, 12% of benzoxaflutole, 12% of oxyfluorfen, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.4% of organobentonite, 1.2% of fumed silica, 15% of 100# solvent oil and methyl oleate
112. Water suspension agent of topramezone, topramezone and clomazone (4+12+16)
4% of topramezone, 12% of topramezone, 16% of clomazone, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
113. Water suspending agent of topramezone, topramezone and 2-methyl-4-chloro (4+12+18)
4% oxadiazon, 12% benzoxaflutole, 18% 2-methyl-4-chloro, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.15% xanthan gum, 1.5% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
114. Water suspending agent of topramezone, topramezone and simetryn (2+6+30)
2% of carfentrazone-ethyl, 6% of benzoxaflutole, 30% of simetryn, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
115. Water suspending agent of topramezone, topramezone and quinclorac (4+12+25)
4% of carfentrazone-ethyl, 12% of benzoxaflutole, 25% of quinclorac, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
116. Dispersible oil suspension agent containing topramezone, topramezone and penoxsulam (4+12+2)
4% of carfentrazone-ethyl, 12% of carfentrazone-ethyl, 2% of penoxsulam, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.4% of organobentonite, 1.2% of fumed silica, 10% of 100# solvent oil and methyl oleate
117. Dispersible oil suspending agent containing carfentrazone-ethyl, topramezone and fluroxypyr-meptyl (4+12+1)
4% of diazole, 12% of benzoxaflutole, 1% of chlorofluoropyridine ester, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 1.4% of organic bentonite, 1.2% of fumed silica, 10% of 100# solvent oil and methyl oleate
118. Dispersible oil suspension agent containing carfentrazone-ethyl, topramezone and molinate (1+3+50)
1% of diazole, 3% of benzoxaflutole, 50% of molinate, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organic bentonite, 2.0% of fumed silica and methyl oleate
119. Dispersible oil suspension agent containing diconazole, topramezone and thiobencarb (1+3+50)
1% of diazole, 3% of benzoxaflutole, 50% of thiobena, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organic bentonite, 2.0% of fumed silica and methyl oleate
120. Cyclopyraflutole, topramezone and pretilachlor (9+3+30) dispersible oil suspending agent
9 percent of bicyclopyrone, 3 percent of topramezone, 30 percent of pretilachlor, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 2.5 percent of organobentonite, 2.0 percent of fumed silica and methyl oleate
121. Cyclopyraflutole, topramezone and butachlor (4.5+1.5+30) dispersible oil suspending agent
4.5 percent of bicyclopyrone, 1.5 percent of topramezone, 30 percent of butachlor, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 2.5 percent of organobentonite, 2.0 percent of fumed silica and methyl oleate
122. Cyclopyraflutole, topramezone, mefenacet (9+3+30) water suspension agent
9% of bicyclopyrone, 3% of topramezone, 30% of mefenacet, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
123. Cyclopyraflutole, topramezone and anilofos (9+3+15) dispersible oil suspending agent
9% of ciclopirox-fluridon, 3% of topramezone, 15% of anilofos, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 2.0% of organobentonite, 2.0% of fumed silica, 12% of 100# solvent oil and methyl oleate
124. Cyclopyraflutole, topramezone and butralin (4.5+1.5+24) dispersible oil suspending agent
4.5% of bicyclopyrone, 1.5% of topramezone, 24% of butralin, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.5% of organobentonite, 2.0% of fumed silica, 20% of 100# solvent oil and methyl oleate
125. Cyclopyraflutole, topramezone and oxadiazon (9+3+30) water suspension
9% of bicyclopyrone, 3% of topramezone, 30% of oxadiazon, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
126. Cyclopyraflutole, topramezone and isoproturon (9+3+45) water dispersible granules
9% of bicyclopyrone, 3% of topramezone, 45% of isoproturon, 10% of naphthalenesulfonate dispersant, 2% of polycarboxylate dispersant, 4% of sodium dodecyl sulfate, 10% of precipitated silica, 1% of polyvinyl alcohol and kaolin
127. Cyclopyraflutole, topramezone and pyraclonil (9+3+14) dispersible oil suspending agent
9% of bicyclopyrone, 3% of topramezone, 14% of pyraclonil, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica, 8% of 100# solvent oil and methyl oleate
128. Cyclopyraflutole, topramezone and oxyfluorfen (9+3+12) dispersible oil suspending agent
9% of bicyclopyrone, 3% of topramezone, 12% of oxyfluorfen, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organobentonite, 2.0% of fumed silica, 12% of 100# solvent oil and methyl oleate
129. Cyclopyraflutole, topramezone and clomazone (9+3+16) dispersible oil suspending agent
9% of bicyclopyrone, 3% of topramezone, 16% of clomazone, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.0% of organobentonite, 1.0% of fumed silica, 6% of 100# solvent oil and methyl oleate
130. Cyclopyraflutole, topramezone and 2-methyl-4-chloro (9+3+18) dispersible oil suspending agent
9% of bicyclopyrone, 3% of topramezone, 18% of 2-methyl-4-chloro compound, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.0% of organobentonite, 1.0% of fumed silica, 6% of 100# solvent oil and methyl oleate
131. Cyclopyraflutole, topramezone and simetryn (4.5+1.5+30) water suspension agent
4.5% of bicyclopyrone, 1.5% of topramezone, 30% of simetryn, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.14% of xanthan gum, 1.4% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
132. Cyclopyraflutole, topramezone and quinclorac (9+3+25) water suspension agent
9% of bicyclopyrone, 3% of topramezone, 25% of quinclorac, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.12% of xanthan gum, 1.4% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
133. Cyclopyraflutole, topramezone and penoxsulam (9+3+2) dispersible oil suspending agent
9% of bicyclopyrone, 3% of topramezone, 2% of penoxsulam, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.2% of organobentonite, 1.5% of fumed silica, 6% of 100# solvent oil and methyl oleate
134. Cyclopyraflutole, topramezone and fluroxypyr ester (9+3+1) dispersible oil suspending agent
9% of bicyclopyrone, 3% of topramezone, 1% of fluroxypyr-meptyl, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.2% of organobentonite, 1.5% of fumed silica, 6% of 100# solvent oil and methyl oleate
135. Cyclopentifluorulone, topramezone and molinate (2.25+0.75+50) dispersible oil suspending agent
2.25 percent of bicyclopyrone, 0.75 percent of topramezone, 50 percent of molinate, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 3.0 percent of organobentonite, 2.5 percent of fumed silica and methyl oleate
136. Cycloflurtamone, topramezone and thiobencarb (2.25+0.75+50) dispersible oil suspending agent
2.25 percent of bicyclopyrone, 0.75 percent of topramezone, 50 percent of thiobencarb, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 3.0 percent of organobentonite, 2.5 percent of fumed silica and methyl oleate
137. Cyclopyraflutole, mesotrione and pretilachlor (9+10+30) dispersible oil suspending agent
9% of bicyclopyrone, 10% of mesotrione, 30% of pretilachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica and methyl oleate
138. Cyclopyraflutole, mesotrione and butachlor (4.5+5+30) dispersible oil suspending agent
4.5% of cyflutolrione, 5% of mesotrione, 30% of butachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organobentonite, 1.5% of fumed silica and methyl oleate
139. Cyclopyraflutole, mesotrione, mefenacet (9+10+30) water suspension agent
9% of bicyclopyrone, 10% of mesotrione, 30% of mefenacet, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.05% of xanthan gum, 0.4% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
140. Cyclopyraflutole, mesotrione, anilofos (9+10+15) dispersible oil suspending agent
9% of cyflutolrione, 10% of mesotrione, 15% of anilofos, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 2.0% of organobentonite, 1.5% of fumed silica, 12% of 100# solvent oil and methyl oleate
141. Cyclopyraflutole, mesotrione and butralin (4.5+5+24) dispersible oil suspending agent
4.5% of bicyclopyrone, 5% of mesotrione, 24% of butralin, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 2.0% of organobentonite, 1.5% of fumed silica, 20% of 100# solvent oil and methyl oleate
142. Cyclopyraflutole, mesotrione and oxadiazon (9+10+30) water suspension
9% of bicyclopyrone, 10% of mesotrione, 30% of oxadiazon, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.05% of xanthan gum, 0.4% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
143. Cyclopyraflutole + mesotrione + isoproturon (4.5+5+22.5) water suspension
4.5% of bicyclopyrone, 5% of mesotrione, 22.5% of isoproturon, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.14% of xanthan gum, 1.4% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
144. Cyclopyraflutole, mesotrione and pyraclonil (9+10+14) dispersible oil suspending agent
9 percent of bicyclopyrone, 10 percent of mesotrione, 14 percent of pyraclonil, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.5 percent of organic bentonite, 10 percent of 100# solvent oil and methyl oleate
145. Cyclopyraflutole, mesotrione and oxyfluorfen (9+10+12) dispersible oil suspending agent
9% of bicyclopyrone, 10% of mesotrione, 12% of oxyfluorfen, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica, 12% of 100# solvent oil and methyl oleate
146. Cyclopyraflutole, mesotrione, clomazone (9+10+16) and clomazone water suspension agent
9% of bicyclopyrone, 10% of mesotrione, 16% of clomazone, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.14% of xanthan gum, 1.4% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
147. Cyclopyraflutole, mesotrione and 2-methyl-4-chloro (9+10+18) aqueous suspension
9% of bicyclopyrone, 10% of mesotrione, 18% of 2-methyl-4-chloro compound, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.14% of xanthan gum, 1.4% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
148. Cyclopyraflutole, mesotrione and simetryn (4.5+5+30) water suspension agent
4.5% of bicyclopyrone, 5% of mesotrione, 30% of simetryn, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
149. Cyclopyraflutole, mesotrione and quinclorac (9+10+25) water suspension agent
9% of bicyclopyrone, 10% of mesotrione, 25% of quinclorac, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% of xanthan gum, 0.5% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
150. Cyclopyraflutole, mesotrione, penoxsulam (9+10+2) dispersible oil suspending agent
9% of bicyclopyrone, 10% of mesotrione, 2% of penoxsulam, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica, 8% of 100# solvent oil and methyl oleate
151. Cyclopyraflutole, mesotrione and fluroxypyr meptyl (9+10+1) dispersible oil suspending agent
9% of bicyclopyrone, 10% of mesotrione, 1% of fluroxypyridine ester, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica, 8% of 100# solvent oil and methyl oleate
152. Cyclopyraflutole, mesotrione and molinate (2.25+2.5+50) dispersible oil suspending agent
2.25% of cyflutolrione, 2.5% of mesotrione, 50% of molinate, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.8% of organobentonite, 2.5% of fumed silica and methyl oleate
153. Cyclopyraflutole, mesotrione and thiodan (2.25+2.5+50) dispersible oil suspending agent
2.25% of cyflutolrione, 2.5% of mesotrione, 50% of thiobencarb, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.8% of organobentonite, 2.5% of fumed silica and methyl oleate
154. Cyclopyraflutole, tembotrione and pretilachlor (9+6+30) dispersible oil suspending agent
9 percent of cyflufenac, 6 percent of tembotrione, 30 percent of pretilachlor, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.8 percent of organobentonite, 1.5 percent of fumed silica and methyl oleate
155. Cyclopyraflutole, tembotrione and butachlor (4.5+3+30) dispersible oil suspending agent
4.5% of cyflufenac, 3% of tembotrione, 30% of butachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica and methyl oleate
156. Cyclopyraflutole, tembotrione, mefenacet (9+6+30) water suspension agent
9% of bicyclopyrone, 6% of tembotrione, 30% of mefenacet, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% of xanthan gum, 0.8% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
157. Cyclopyraflutole, tembotrione, anilofos (9+6+15) dispersible oil suspending agent
9% of cyflutolrione, 6% of tembotrione, 15% of anilofos, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica, 12% of 100# solvent oil and methyl oleate
158. Cyclopyraflutole, tembotrione and butralin (4.5+3+24) dispersible oil suspending agent
4.5% of cyflufenac, 3% of tembotrione, 24% of butralin, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.5% of organic bentonite, 2.5% of fumed silica, 20% of 100# solvent oil and methyl oleate
159. Cyclopyraflutole + tembotrione + oxadiazon (9+6+30) water suspension
9% of bicyclopyrone, 6% of tembotrione, 30% of oxadiazon, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% of xanthan gum, 0.8% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of glycol and water
160. Cyclopyraflutole, tembotrione and isoproturon (4.5+3+22.5) dispersible oil suspending agent
4.5 percent of cyflufenac, 3 percent of tembotrione, 22.5 percent of isoproturon, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.5 percent of organobentonite, 10 percent of 100# solvent oil and methyl oleate
161. Cyclopyraflutole, tembotrione and pyraclonil (9+6+14) dispersible oil suspending agent
9 percent of bicyclopyrone, 6 percent of tembotrione, 14 percent of pyraclonil, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.8 percent of organic bentonite, 10 percent of 100# solvent oil and methyl oleate
162. Cyclopyraflutole, tembotrione and oxyfluorfen (9+6+12) dispersible oil suspending agent
9% of bicyclopyrone, 6% of tembotrione, 12% of oxyfluorfen, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica, 12% of 100# solvent oil and methyl oleate
163. Cyclopyraflutole, tembotrione, clomazone and clomazone (9+6+16) dispersible oil suspending agent
9 percent of cyflutolrione, 6 percent of tembotrione, 16 percent of clomazone, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.8 percent of organic bentonite, 8 percent of 100# solvent oil and methyl oleate
164. Cyclopyraflutole + tembotrione + 2-methyl-4-chloro (9+6+18) aqueous suspension
9% of bicyclopyrone, 6% of tembotrione, 18% of 2-methyl-4-chloro, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.15% of xanthan gum, 1.5% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
165. Cyclopyraflutole, tembotrione and simetryn (4.5+3+30) water suspension agent
4.5% of bicyclopyrone, 3% of tembotrione, 30% of simetryn, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.12% of xanthan gum, 1.0% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
166. Cyclopyraflutole, tembotrione and quinclorac (9+6+25) aqueous suspension
9% of bicyclopyrone, 6% of tembotrione, 25% of quinclorac, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of glycol and water
167. Cyclopyraflutole, tembotrione and penoxsulam (9+6+2) dispersible oil suspending agent
9% of cyflutolrione, 6% of tembotrione, 2% of penoxsulam, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica, 8% of 100# solvent oil and methyl oleate
168. Cyclopyraflutole, tembotrione and fluroxypyridine (9+6+1) dispersible oil suspending agent
9% of cyflutolrione, 6% of tembotrione, 1% of fluroxypyridine ester, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica, 8% of 100# solvent oil and methyl oleate
169. Cyclopyraflutole, tembotrione and molinate (2.25+1.5+50) dispersible oil suspending agent
2.25% of cyflutolrione, 1.5% of tembotrione, 50% of molinate, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.8% of organobentonite, 2.5% of fumed silica and methyl oleate
170. Cycloflurtamone, tembotrione and benthiocarb (2.25+1.5+50) dispersible oil suspending agent
2.25% of cyflutolrione, 1.5% of tembotrione, 50% of thiobencarb, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.8% of organobentonite, 2.5% of fumed silica and methyl oleate
171. Cyclopyraflutole, isoxaflutole and pretilachlor (9+6+30) dispersible oil suspending agent
9 percent of bicyclopyrone, 6 percent of isoxaflutole, 30 percent of pretilachlor, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.8 percent of organobentonite, 1.5 percent of fumed silica and methyl oleate
172. Cyclopyraflutole, isoxaflutole and butachlor (4.5+3+30) dispersible oil suspending agent
4.5% of bicyclopyrone, 3% of isoxaflutole, 30% of butachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.5% of organobentonite, 2.5% of fumed silica and methyl oleate
173. Cyclopyraflutole, isoxaflutole, mefenacet (9+6+30) water suspension agent
9% of bicyclopyrone, 6% of isoxaflutole, 30% of mefenacet, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% of xanthan gum, 1.0% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
174. Cyclopyraflutole, isoxaflutole, anilofos (9+6+15) dispersible oil suspending agent
9% of ciclopirox-fluridon, 6% of isoxaflutole, 15% of anilofos, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.0% of organobentonite, 2.0% of fumed silica, 12% of 100# solvent oil and methyl oleate
175. Cyclopyraflutole, isoxaflutole and butralin (4.5+3+24) dispersible oil suspending agent
4.5% of bicyclopyrone, 3% of isoxaflutole, 24% of butralin, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organobentonite, 2.0% of fumed silica, 20% of 100# solvent oil and methyl oleate
176. Cyclopyraflutole, isoxaflutole and oxadiazon (9+6+30) water suspension
9% of bicyclopyrone, 6% of isoxaflutole, 30% of oxadiazon, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% of xanthan gum, 1.0% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
177. Cyclopyraflutole, isoxaflutole and isoproturon (4.5+3+22.5) dispersible oil suspending agent
4.5 percent of bicyclopyrone, 3 percent of isoxaflutole, 22.5 percent of isoproturon, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.6 percent of organobentonite, 10 percent of 100# solvent oil and methyl oleate
178. Cyclopyraflutole, isoxaflutole and pyraclonil (9+6+14) dispersible oil suspending agent
9 percent of bicyclopyrone, 6 percent of isoxaflutole, 14 percent of pyraclonil, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.8 percent of organic bentonite, 10 percent of 100# solvent oil and methyl oleate
179. Cyclopyraflutole, isoxaflutole and oxyfluorfen (9+6+12) dispersible oil suspending agent
9% of bicyclopyrone, 6% of isoxaflutole, 12% of oxyfluorfen, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.0% of organobentonite, 1.0% of fumed silica, 12% of 100# solvent oil and methyl oleate
180. Cyclopyraflutole, isoxaflutole, clomazone (9+6+16) dispersible oil suspending agent
9 percent of bicyclopyrone, 6 percent of isoxaflutole, 16 percent of clomazone, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.8 percent of organic bentonite, 8 percent of 100# solvent oil and methyl oleate
181. Cyclopyraflutole + isoxaflutole + 2-methyl-4-chloro (9+6+18) water suspension agent
9% of bicyclopyrone, 6% of isoxaflutole, 18% of 2-methyl-4-chloro, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.14% of xanthan gum, 1.5% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
182. Cyclopyraflutole, isoxaflutole and simetryn (4.5+3+30) water suspension agent
4.5% of bicyclopyrone, 3% of isoxaflutole, 30% of simetryn, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.14% of xanthan gum, 1.2% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
183. Cyclopyraflutole, isoxaflutole and quinclorac (9+6+25) water suspension agent
9% of bicyclopyrone, 6% of isoxaflutole, 25% of quinclorac, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of glycol and water
184. Cyclopyraflutole, isoxaflutole, penoxsulam (9+6+2) dispersible oil suspending agent
9% of bicyclopyrone, 6% of isoxaflutole, 2% of penoxsulam, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.6% of organobentonite, 1.5% of fumed silica, 8% of 100# solvent oil and methyl oleate
185. Cyclopyraflutole, isoxaflutole and fluroxypyr-meptyl (9+6+1) dispersible oil suspending agent
9% of bicyclopyrone, 6% of isoxaflutole, 1% of fluroxypyridine ester, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.6% of organobentonite, 1.5% of fumed silica, 8% of 100# solvent oil and methyl oleate
186. Cyclopyraflutole, isoxaflutole and molinate (2.25+1.5+50) dispersible oil suspending agent
2.25% of cyflutolrione, 1.5% of isoxaflutole, 50% of molinate, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica and methyl oleate
187. Cycloflurtamone, isoxaflutole and thiobencarb (2.25+1.5+50) dispersible oil suspending agent
2.25% of cyflutolrione, 1.5% of isoxaflutole, 50% of thiobena, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica and methyl oleate
188. Cyclopyraflutole, bicyclsulcotrione and pretilachlor (9+20+30) dispersible oil suspending agent
9% of bicyclopyrone, 20% of bicyclosulfuron, 30% of pretilachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 0.6% of organic bentonite and methyl oleate
189. Cyclopyraflutole, bicyclosulfulone and butachlor (2.25+5+15) dispersible oil suspending agent
2.25% of bicyclopyrone, 5% of bicyclosulfuron, 15% of butachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica and methyl oleate
190. Cyclopyraflutole + benzobicyclon + mefenacet (9+20+30) water suspension agent
9% of diflufenican, 20% of bicyclsulcotrione, 30% of mefenacet, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
191. Cyclopyraflutole, benzobicyclon and anilofos (9+20+15) dispersible oil suspending agent
9% of bicyclopyrone, 20% of bicyclosulfuron, 15% of anilofos, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 0.6% of organobentonite, 12% of 100# solvent oil and methyl oleate
192. Cyclopyraflutole, bicyclosulfulone and butralin (4.5+10+24) dispersible oil suspending agent
4.5% of bicyclopyrone, 10% of bicyclosulfrione, 24% of butralin, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.5% of organobentonite, 2% of fumed silica, 20% of 100# solvent oil and methyl oleate
193. Cyclopyraflutole, bicyclosulfulone and oxadiazon (9+20+30) water dispersible granules
9% of bicyclopyrone, 20% of bicyclosulfuron, 30% of oxadiazon, 10% of naphthalenesulfonate dispersant, 2% of polycarboxylate dispersant, 4% of sodium dodecyl sulfate, 10% of precipitated silica, 1% of polyvinyl alcohol and kaolin
194. Cyclopyraflutole + benzobicyclon + isoproturon (4.5+10+22.5) water suspension agent
4.5% of bicyclopyrone, 10% of bicyclosulfulone, 22.5% of isoproturon, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.13% of xanthan gum, 1.4% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
195. Cyclopyraflutole, bicyclosulfulone and pyraclonil (9+20+14) water suspension agent
9% of bicyclopyrone, 20% of bicyclosulfulone, 14% of pyraclonil, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% of xanthan gum, 0.8% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
196. Cyclopyraflutole, bicyclosulfulone and oxyfluorfen (9+20+12) suspending agent
9% of bicyclopyrone, 20% of bicyclosulfrione, 12% of oxyfluorfen, 15% of 100# solvent oil, 3% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 4% of castor oil polyoxyethylene ether, 2% of butanol block polyether, 0.1% of xanthan gum, 0.8% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
197. Cyclopyraflutole, bicyclosulfulone and clomazone (9+20+16) aqueous suspension
9% of bicyclopyrone, 20% of bicyclosulfrione, 16% of clomazone, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% of xanthan gum, 0.8% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of glycol and water
198. Cyclopyraflutole + benzobicyclon + 2-methyl-4-chloro (9+20+18) water suspension agent
9% of bicyclopyrone, 20% of bicyclosulfrione, 18% of 2-methyl-4-chloro, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% of xanthan gum, 0.8% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
199. Cyclopyraflutole, bicyclosulfulone and simetryn (2.25+5+15) water suspension agent
2.25% of bicyclopyrone, 5% of bicyclosulfulone, 15% of simetryn, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.18% of xanthan gum, 1.8% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
200. Cyclopyraflutole + benzobicyclon + quinclorac (9+20+25) water suspension agent
9% of bicyclopyrone, 20% of bicyclosulfrione, 25% of quinclorac, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% of xanthan gum, 0.8% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of glycol and water
201. Cyclopyraflutole, bicyclsulcotrione, penoxsulam (9+20+2) dispersible oil suspending agent
9 percent of bicyclopyrone, 20 percent of bicyclosulfuron, 2 percent of penoxsulam, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.6 percent of organobentonite, 10 percent of 100# solvent oil and methyl oleate
202. Cyclopyraflutole, bicyclosulfulone and fluroxypyr-meptyl (9+20+1) dispersible oil suspending agent
9% of bicyclopyrone, 20% of bicyclosulfuron, 1% of fluroxypyridine ester, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 0.6% of organobentonite, 10% of 100# solvent oil and methyl oleate
203. Cyclopyraflutole, bicyclosulfulone and molinate (2.25+5+50) dispersible oil suspending agent
2.25% of cyflutolrione, 5% of bicyclophorione, 50% of molinate, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica and methyl oleate
204. Cyclopyraflutole, bicyclosulfulone and benthiocarb (2.25+5+50) dispersible oil suspending agent
2.25% of cyflutolrione, 5% of bicyclosulfrione, 50% of thiobencarb, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica and methyl oleate
205. Cyclopyraflutole, triazophone and pretilachlor (9+12+30) dispersible oil suspending agent
9% of cyflutolrione, 12% of triazophone, 30% of pretilachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica and methyl oleate
206. Cyclopyraflutole, triazophone and butachlor (2.25+3+15) dispersible oil suspending agent
2.25% of cyflufenac, 3% of triazophone, 15% of butachlor, 5% of calcium dodecylbenzenesulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica and methyl oleate
207. Cyclopyraflutole, triazophone and mefenacet (9+12+30) aqueous suspension
9% of bicyclopyrone, 12% of triazophone, 30% of mefenacet, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.04% of xanthan gum, 0.5% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
208. Cyclopyraflutole, triazophone and anilofos (9+12+15) dispersible oil suspending agent
9% of ciclopirox, 12% of triazophone, 15% of anilofos, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.6% of organobentonite, 1.5% of fumed silica, 12% of 100# solvent oil and methyl oleate
209. Cyclopyraflutole, triazophone and butralin (4.5+6+24) dispersible oil suspending agent
4.5% of bicyclopyrone, 6% of triazophone, 24% of butralin, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica, 20% of 100# solvent oil and methyl oleate
210. Cyclopyraflutole, triazophodim and oxadiazon (9+12+30) water suspension
9% of bicyclopyrone, 12% of triazophone, 30% of oxadiazon, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.04% of xanthan gum, 0.5% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
211. Cyclopyraflutole, triazophodim and isoproturon (4.5+6+22.5) water suspension
4.5% ciclopirox-flurtamone + 6% triazophone + 22.5% isoproturon + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.14% xanthan gum + 1.5% magnesium aluminium silicate + 0.1% defoamer + 3% ethylene glycol + water
212. Cyclopyraflutole, triazophone and pyraclonil (9+12+14) aqueous suspension
9% of bicyclopyrone, 12% of triazophone, 14% of pyraclonil, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.14% of xanthan gum, 1.5% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
213. Cyclopyraflutole, triazophone and oxyfluorfen (9+12+12) dispersible oil suspending agent
9% of bicyclopyrone, 12% of triazophone, 12% of oxyfluorfen, 5% of calcium dodecylbenzenesulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.6% of organobentonite, 1.5% of fumed silica, 12% of 100# solvent oil and methyl oleate
214. Cyclopyraflutole, triazophone and clomazone (9+12+16) aqueous suspension
9% of bicyclopyrone, 12% of triazophone, 16% of clomazone, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.12% of xanthan gum, 1.4% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
215. Cyclopyraflutole, triazophone and 2-methyl-4-chloro (9+12+18) aqueous suspension
9% of bicyclopyrone, 12% of triazophone, 18% of 2-methyl-4-chloro, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
216. Cyclopyraflutole, triazophone and simetryn (2.25+3+15) dispersible oil suspending agent
2.25% of bicyclopyrone, 3% of triazophone, 15% of simetryn, 5% of calcium dodecylbenzenesulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.6% of organobentonite, 1.5% of fumed silica, 8% of 100# solvent oil and methyl oleate
217. Cyclopyraflutole, triazophone and quinclorac (9+12+25) water suspension
9% of ciclopirox-fluridon, 12% of triazophone, 25% of quinclorac, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.06% of xanthan gum, 0.6% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
218. Cyclopyraflutole, triazophone and penoxsulam (9+12+2) dispersible oil suspending agent
9 percent of bicyclopyrone, 12 percent of triazophone, 2 percent of penoxsulam, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.6 percent of organobentonite, 10 percent of 100# solvent oil and methyl oleate
219. Cyclopyraflutole, triazophodim and fluroxypyr ester (9+12+1) dispersible oil suspending agent
9% of bicyclopyrone, 12% of triazophone, 1% of fluroxypyridine ester, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.2% of organobentonite, 1.2% of fumed silica, 10% of 100# solvent oil and methyl oleate
220. Cyclopyraflutole, triazophone and molinate (2.25+3+50) dispersible oil suspending agent
2.25% of cyflutolrione, 3% of triazophone, 50% of molinate, 5% of calcium dodecylbenzenesulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organobentonite, 2.5% of fumed silica and methyl oleate
221. Cyclopyraflutole, triazophone and benthiocarb (2.25+3+50) dispersible oil suspending agent
2.25% of cyflutolrione, 3% of triazophone, 50% of thiobena, 5% of calcium dodecylbenzenesulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organobentonite, 2.5% of fumed silica and methyl oleate
222. Cyclopyraflutole, topramezone and pretilachlor (9+12+30) dispersible oil suspending agent
9% of bicyclopyrone, 12% of benzoxaflutole, 30% of pretilachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.5% of organobentonite, 1.5% of fumed silica and methyl oleate
223. Cyclopyraflutole, topramezone and butachlor (2.25+3+15) dispersible oil suspending agent
2.25% of bicyclopyrone, 3% of benzoxaflutole, 15% of butachlor, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.5% of organobentonite, 2.5% of fumed silica and methyl oleate
224. Cyclopyraflutole, topramezone and mefenacet (9+12+30) water suspension agent
9% of bicyclopyrone, 12% of benzoxaflutole, 30% of mefenacet, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.09% of xanthan gum, 1.0% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
225. Cyclopyraflutole, benzoxaflutole and anilofos (9+12+15) dispersible oil suspending agent
9% of ciclopirox, 12% of benzoxaflutole, 15% of anilofos, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-oxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica, 12% of 100# solvent oil and methyl oleate
226. Cyclopyraflutole, topramezone and butralin (4.5+6+24) dispersible oil suspending agent
4.5% of bicyclopyrone, 6% of benzoxaflutole, 24% of butralin, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 2.5% of organobentonite, 1.5% of fumed silica, 20% of 100# solvent oil and methyl oleate
227. Cyclopyraflutole, topramezone and oxadiazon (9+12+30) water suspension
9% of bicyclopyrone, 12% of benzoxaflutole, 30% of oxadiazon, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.04% of xanthan gum, 0.5% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
228. Cyclopyraflutole, topramezone and isoproturon (4.5+6+22.5) water suspension agent
4.5% bicyclopyrone + 6% benzoxaflutole + 22.5% isoproturon + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.4% magnesium aluminium silicate + 0.1% defoamer + 3% ethylene glycol + water
229. Cyclopyraflutole, topramezone and pyraclonil (9+12+14) water suspension agent
9% of bicyclopyrone, 12% of benzoxaflutole, 14% of pyraclonil, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.14% of xanthan gum, 1.4% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
230. Cyclopyraflutole, topramezone and oxyfluorfen (9+12+12) dispersible oil suspending agent
9% of bicyclopyrone, 12% of benzoxaflutole, 12% of oxyfluorfen, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica, 12% of 100# solvent oil and methyl oleate
231. Cyclopyraflutole, topramezone and clomazone (9+12+16) aqueous suspension
9% of bicyclopyrone, 12% of benzoxaflutole, 16% of clomazone, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.14% of xanthan gum, 1.4% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
232. Cyclopyraflutole, topramezone and 2-methyl-4-chloro (9+12+18) aqueous suspension
9% of bicyclopyrone, 12% of benzoxaflutole, 18% of 2-methyl-4-chloro, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.12% of xanthan gum, 1.2% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
233. Cyclopyraflutole, topramezone and simetryn (2.25+3+15) water suspension agent
2.25% of bicyclopyrone, 3% of benzoxaflutole, 15% of simetryn, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.12% of xanthan gum, 1.2% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
234. Cyclopyraflutole, topramezone and quinclorac (9+12+25) water suspension agent
9% of bicyclopyrone, 12% of benzoxaflutole, 25% of quinclorac, 5% of polycarboxylate, 2% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.07% of xanthan gum, 0.8% of magnesium aluminum silicate, 0.1% of defoaming agent, 3% of ethylene glycol and water
235. Cyclopyraflutole, topramezone and penoxsulam (9+12+2) dispersible oil suspending agent
9 percent of bicyclopyrone, 12 percent of benzoxaflutole, 2 percent of penoxsulam, 5 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 0.8 percent of organobentonite, 10 percent of 100# solvent oil and methyl oleate
236. Cyclopyraflutole, topramezone and fluroxypyr-meptyl (9+12+1) dispersible oil suspending agent
9% of bicyclopyrone, 12% of benzoxaflutole, 1% of fluroxypyr-meptyl, 5% of calcium dodecylbenzenesulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 1.6% of organobentonite, 1.5% of fumed silica, 10% of 100# solvent oil and methyl oleate
237. Cyclopentifluorulone, topramezone and molinate (2.25+3+50) dispersible oil suspending agent
2.25% of cyflutolrione, 3% of benzoxaflutole, 50% of molinate, 5% of calcium dodecyl benzene sulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organobentonite, 2.5% of fumed silica and methyl oleate
238. Cyclopentifluorulone, topramezone and thiobencarb (2.25+3+50) dispersible oil suspending agent
2.25% of cyflutolrione, 3% of benzoxaflutole, 50% of thiobena, 5% of calcium dodecylbenzenesulfonate, 5% of fatty alcohol-polyoxyethylene ether, 6% of castor oil-polyoxyethylene ether, 3.0% of organobentonite, 2.5% of fumed silica and methyl oleate
The processing equipment of the aqueous suspending agent comprises: mixing kettles, colloid mills, sand mills, shearing machines and the like.
The processing process of the aqueous suspending agent comprises the following steps: putting all materials into a mixing kettle, stirring and mixing, passing through a colloid mill, then entering a sand mill for three-stage sand milling, finally uniformly shearing in a shearing machine, and transferring to a storage tank for filling after the test is qualified.
The processing equipment of the dispersible oil suspending agent comprises the following steps: mixing kettles, colloid mills, sand mills, shearing machines and the like.
The processing process of the dispersible oil suspending agent comprises the following steps: putting all materials into a mixing kettle, stirring and mixing, passing through a colloid mill, then entering a sand mill for three-stage sand milling, finally uniformly shearing in a shearing machine, and transferring to a storage tank for filling after the test is qualified.
The above suspoemulsion processing equipment: mixing kettle, colloid mill, sand mill, shearing machine, shearing kettle.
The processing process of the suspoemulsion comprises the following steps: putting part of the materials into a mixing kettle, stirring and mixing the materials, then passing the materials through a colloid mill, then entering a sand mill for three-stage sanding, and after the materials are qualified, putting the materials into a shearing kettle for later use to obtain water-phase materials; and then putting the residual raw medicine and the solvent into a mixing kettle, stirring and dissolving until the mixture is completely transparent, then adding the emulsifier, uniformly stirring to form an oil phase, then starting a shearing machine, slowly pumping the oil phase into the shearing kettle in a shearing state, pumping all materials into the shearing kettle, continuing shearing for 1 hour, transferring the materials into a storage tank after the materials are qualified in assay, and filling.
The water dispersible granule processing equipment comprises: jet mills, coulter mixers, basket granulators, drying ovens, screening machines, and the like.
The processing process of the water dispersible granule comprises the following steps: the materials are uniformly mixed, crushed by airflow, added with water, kneaded, granulated, dried and finally screened to obtain the finished product.
B) Test of drug efficacy
Soil sealing treatment:
1) test conditions
1.1) test target
Cardamine hirsuta L, chickweed (Stellaria media) were collected from Jiangsu Xinghua.
1.2) culture conditions
The weeds are cultivated by a pot culture method. Placing a 180 х 140mm plastic nutrition pot in an enamel tray, collecting air-dried and sieved surface soil (4/5) from farmland, controlling soil humidity at 20% in the initial stage, selecting weed seeds with full and uniform seeds, soaking in 25 deg.C warm water for 6 hr, accelerating germination in 28 deg.C biochemical incubator (dark), placing the weed seeds just exposed to the white on the surface of the soil, and covering with soil of 0.7 cm. The treated medicament is placed in a controllable sunlight greenhouse for culture, and a certain amount of water is periodically added into an enamel tray to keep the soil moist.
The method is carried out in a controllable sunlight greenhouse at the temperature of 18-30 ℃ under natural illumination and with the relative humidity of 57-72%. The soil type is loam, the organic matter content is 1.63%, the pH value is 7.1, the alkaline hydrolysis nitrogen is 84.3mg/kg, the quick-acting phosphorus is 38.5mg/kg, and the quick-acting potassium is 82.1 mg/kg.
1.3), instrumentation
3WP-2000 model walking spray tower, Minn Jing agricultural machinery research institute of agricultural department. Ten thousandth electronic balance of GA110 type (germany); ZDR2000 intelligent data recorder (hangzhou ze large instruments ltd); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument factory).
2) Design of experiments
2.1), reagents
The required active ingredients of bicyclopyrone, topramezone, triazophone and topramezone are produced by the company, and others are purchased from the reagent company. The raw medicines are all diluted by using an emulsifier T-80 aqueous solution with the content of 0.1 percent by using acetone as a solvent.
2.2) test treatment
2.2.1), dose setting
When determining the ratio or content of each component, the main purpose of the formula should be considered in consideration of the action characteristics of the three agents and the toxicity thereof. The study is based on preliminary examination in the early stage and sets single use and mixed use amount. Water without drug, containing the same solvent and emulsifier was used as a blank.
2.2.2), test repetition
Each treatment was repeated 4 times, 3 pots each time, 20 weed seeds were sown per pot, 60 plants each time.
2.3) treatment method
2.3.1), treatment time and number of times
The test was performed 1 time in total, 24 hours after sowing.
2.3.2), instruments and methods of use
Uniformly placing the cultured test material on a 0.5m area2The soil surface layer is sprayed by a 3WP-2000 model walking type spraying tower, and the liquid spraying amount is 450 kg/hectare. The spraying pressure is 0.3 MPa. And after all the liquid medicine is sprayed, closing the air valve, opening the spraying tower door after 30 seconds, and taking out the nutrition pot. Then the air valve is opened, 50mL of clean water is sprayed, and the liquid spraying pipe is cleaned.
3) Test method
The potting method is adopted. The weed cultivation is carried out according to 1.2 and the standard herbicide for indoor bioassay of pesticides. The application method is shown in 2.3.2, and a soil treatment method is adopted.
4) Data investigation and statistical analysis
4.1) investigation method
The living weed seedlings were cut off by absolute number survey along the soil surface with a blade, and the fresh weight of the weeds was weighed with an analytical balance. For the weeds that have died, the fresh weight is zero.
4.2), investigation time and number of surveys
The investigation was carried out 15 days after the treatment, and was carried out 1 time in total.
4.3), statistical analysis of data
The combination action type of any two or the mixture of the two and the three on the weeds is evaluated by a Colby method.
And (5) cutting green tissues on each treatment ground in 15 days, weighing by adopting an electronic balance, and calculating the actual survival rate: e (%) × 100 (fresh weight of weeds in treatment area/fresh weight of weeds in control area) × 100
The theoretical weed survival rate calculation formula is as follows: e0 (%) ═ X Y/100 (binary mixed use)
Wherein X represents the survival rate of weeds A at a dose of P, Y represents the survival rate of weeds B at a dose of Q, E0 represents the theoretical survival rate of weeds A + B at a dose of (P + Q), and E represents the actual survival rate of weeds for each treatment.
E0(％)＝X×Y×Z×…×N/100(n-1)(use of three or more elements)
X, Y, Z, N in the formula respectively represents the actual survival rates of n single agents, and n is the number of varieties of the compound herbicide.
When E0-E is more than 10%, the synergistic effect is generated; when E0-E < -10%, antagonism is indicated; when E0-E is within. + -. 10%, it is indicated that an additive effect is produced.
The statistical results of the actual control effect and combined action evaluation (soil treatment) of the mixed components on weeds are shown in tables 1-238, and when A is the topramezone, the test material is cardamine hirsute; when A is the bicyclopyrone, the test material is chickweed.
Table 1A shows carfentrazone-ethyl, B shows carfentrazone-ethyl, and C shows pretilachlor
Figure BDA0003023230580000261
Figure BDA0003023230580000271
Table 2A shows carfentrazone-ethyl, B shows topramezone, and C shows butachlor
Figure BDA0003023230580000272
Table 3A shows carfentrazone-ethyl, B shows carfentrazone-ethyl, and C shows mefenacet
Figure BDA0003023230580000273
Table 4A shows carfentrazone-ethyl, B shows carfentrazone-ethyl, and C shows anilofos
Figure BDA0003023230580000274
Figure BDA0003023230580000281
Table 5A shows carfentrazone-ethyl, B shows carfentrazone-ethyl, and C shows butralin
Figure BDA0003023230580000282
Table 6A shows carfentrazone-ethyl, B shows carfentrazone-ethyl, and C shows oxadiazon
Figure BDA0003023230580000283
Figure BDA0003023230580000291
Table 7A shows carfentrazone-ethyl, B shows carfentrazone-ethyl, and C shows isoproturon
Figure BDA0003023230580000292
Table 8A shows carfentrazone-ethyl, B shows carfentrazone-ethyl, and C shows carfentrazone-ethyl
Figure BDA0003023230580000293
Table 9A shows carfentrazone-ethyl, B shows carfentrazone-ethyl, and C shows oxyfluorfen
Figure BDA0003023230580000294
Figure BDA0003023230580000301
Table 10A shows carfentrazone-ethyl, B shows topramezone, and C shows clomazone
Figure BDA0003023230580000302
Table 11A shows carfentrazone-ethyl, B shows carfentrazone-ethyl, and C shows 2-methyl-4-chloro
Figure BDA0003023230580000303
Table 12A is carfentrazone-ethyl, B is topramezone, and C is simetryn
Figure BDA0003023230580000311
Table 13A shows carfentrazone-ethyl, B shows carfentrazone-ethyl, and C shows quinclorac
Figure BDA0003023230580000312
Table 14A shows carfentrazone-ethyl, B shows topramezone, and C shows penoxsulam
Figure BDA0003023230580000313
Figure BDA0003023230580000321
Table 15A shows carfentrazone-ethyl, B shows carfentrazone-ethyl, and C shows fluroxypyr meptyl
Figure BDA0003023230580000322
Table 16A shows carfentrazone-ethyl, B shows topramezone, and C shows molinate
Figure BDA0003023230580000323
Table 17A shows carfentrazone-ethyl, B shows topramezone, and C shows thiodan
Figure BDA0003023230580000324
Figure BDA0003023230580000331
Table 18A shows topramezone, B mesotrione, and C pretilachlor
Figure BDA0003023230580000332
Table 19A shows topramezone, B mesotrione, and C butachlor
Figure BDA0003023230580000333
Figure BDA0003023230580000341
Table 20A shows carfentrazone-ethyl, B shows mesotrione, and C shows mefenacet
Figure BDA0003023230580000342
Table 21A shows carfentrazone, B shows mesotrione, and C shows anilofos
Figure BDA0003023230580000343
Table 22A shows carfentrazone-ethyl, B shows mesotrione, and C shows butralin
Figure BDA0003023230580000344
Figure BDA0003023230580000351
Table 23A shows topramezone, B mesotrione, and C oxadiazon
Figure BDA0003023230580000352
Table 24A shows carfentrazone, B mesotrione, and C isoproturon
Figure BDA0003023230580000353
Figure BDA0003023230580000361
Table 25A shows carfentrazone, B mesotrione, and C pyraclonil
Figure BDA0003023230580000362
Table 26A shows carfentrazone-ethyl, B shows mesotrione, and C shows oxyfluorfen
Figure BDA0003023230580000363
Table 27A shows topramezone, B mesotrione, and C clomazone
Figure BDA0003023230580000364
Figure BDA0003023230580000371
Table 28A shows topramezone, B shows mesotrione, and C shows 2-methyl-4-chloro
Figure BDA0003023230580000372
Table 29A shows carfentrazone-ethyl, B shows mesotrione, and C shows simetryn
Figure BDA0003023230580000373
Figure BDA0003023230580000381
Table 30A shows carfentrazone-ethyl, B mesotrione, and C quinclorac
Figure BDA0003023230580000382
Table 31A shows carfentrazone-ethyl, B shows mesotrione, and C shows penoxsulam
Figure BDA0003023230580000383
Table 32A shows carfentrazone, B mesotrione, and C fluroxypyr meptyl
Figure BDA0003023230580000384
Figure BDA0003023230580000391
Table 33A shows carfentrazone, B mesotrione, and C molinate
Figure BDA0003023230580000392
Table 34A shows carfentrazone, B mesotrione, and C thiodan
Figure BDA0003023230580000393
Table 35A shows topramezone, B tembotrione, and C pretilachlor
Figure BDA0003023230580000401
Table 36A shows topramezone, B shows tembotrione, and C shows butachlor
Figure BDA0003023230580000402
TABLE 37A is topramezone, B is tembotrione, C is mefenacet
Figure BDA0003023230580000403
Figure BDA0003023230580000411
TABLE 38A is topramezone, B is tembotrione, C is anilofos
Figure BDA0003023230580000412
Table 39A shows carfentrazone-ethyl, B shows tembotrione, and C shows butralin
Figure BDA0003023230580000413
Table 40A shows carfentrazone-ethyl, B shows tembotrione, and C shows oxadiazon
Figure BDA0003023230580000421
Table 41A shows carfentrazone-ethyl, B shows tembotrione, and C shows isoproturon
Figure BDA0003023230580000422
Table 42A shows carfentrazone-ethyl, B shows tembotrione, and C shows pyraclonil
Figure BDA0003023230580000423
Figure BDA0003023230580000431
Table 43A shows carfentrazone-ethyl, B shows tembotrione, and C shows oxyfluorfen
Figure BDA0003023230580000432
Table 44A shows carfentrazone-ethyl, B shows tembotrione, and C shows clomazone
Figure BDA0003023230580000433
Table 45A shows carfentrazone-ethyl, B shows tembotrione, and C shows 2-methyl-4-chloro
Figure BDA0003023230580000441
Table 46A shows carfentrazone-ethyl, B shows tembotrione, and C shows simetryn
Figure BDA0003023230580000442
Table 47A shows carfentrazone-ethyl, B shows tembotrione, and C shows quinclorac
Figure BDA0003023230580000443
Figure BDA0003023230580000451
Table 48A shows carfentrazone-ethyl, B shows tembotrione, and C shows penoxsulam
Figure BDA0003023230580000452
Table 49A shows carfentrazone-ethyl, B shows tembotrione, and C shows fluroxypyridine
Figure BDA0003023230580000453
Table 50A shows carfentrazone-ethyl, B shows tembotrione, and C shows molinate
Figure BDA0003023230580000454
Figure BDA0003023230580000461
TABLE 51A Bixaflutole, B tembotrione, C diclofop-methyl
Figure BDA0003023230580000462
Table 52A shows carfentrazone-ethyl, B shows isoxaflutole, and C shows pretilachlor
Figure BDA0003023230580000463
TABLE 53A for topramezone, B for isoxaflutole, C for butachlor
Figure BDA0003023230580000471
Table 54A shows carfentrazone-ethyl, B shows isoxaflutole, and C shows mefenacet
Figure BDA0003023230580000472
TABLE 55A is topramezone, B is isoxaflutole, C is anilofos
Figure BDA0003023230580000473
Figure BDA0003023230580000481
TABLE 56A is topramezone, B is isoxaflutole, C is butralin
Figure BDA0003023230580000482
Table 57A shows carfentrazone, B shows isoxafluzone, and C shows oxadiazon
Figure BDA0003023230580000483
TABLE 58A for topramezone, B for isoxaflutole, C for isoproturon
Figure BDA0003023230580000491
Table 59A shows carfentrazone-ethyl, B shows isoxafluzone-ethyl, and C shows pyraclonil
Figure BDA0003023230580000492
TABLE 60A Bixaflutole, B isoxaflutole, C oxyfluorfen
Figure BDA0003023230580000493
Figure BDA0003023230580000501
TABLE 61A is topramezone, B is isoxaflutole, and C is clomazone
Figure BDA0003023230580000502
TABLE 62A for topramezone, B for isoxaflutole, C for 2-methyl-4-chloro
Figure BDA0003023230580000503
Table 63A shows carfentrazone-ethyl, B shows isoxaflutole, and C shows simetryn
Figure BDA0003023230580000511
TABLE 64A is carfentrazone-ethyl, B is isoxaflutole, C is quinclorac
Figure BDA0003023230580000512
Table 65A shows carfentrazone-ethyl, B shows isoxaflutole, and C shows penoxsulam
Figure BDA0003023230580000513
Figure BDA0003023230580000521
TABLE 66A is carfentrazone, B is isoxaflutole, C is fluroxypyr meptyl
Figure BDA0003023230580000522
TABLE 67A for carfentrazone-ethyl, B for isoxaflutole, C for molinate
Figure BDA0003023230580000523
Table 68A shows carfentrazone, B shows isoxaflutole, and C shows thiobencarb
Figure BDA0003023230580000524
Figure BDA0003023230580000531
TABLE 69A for topramezone, B for mesotrione, C for pretilachlor
Figure BDA0003023230580000532
Table 70A shows carfentrazone-ethyl, B shows benzobicyclon, and C shows butachlor
Figure BDA0003023230580000533
Table 71A shows carfentrazone-ethyl, B shows benzobicyclon, and C shows mefenacet
Figure BDA0003023230580000541
TABLE 72A for topramezone, B for mesotrione, C for anilofos
Figure BDA0003023230580000542
Table 73A is carfentrazone-ethyl, B is mesotrione, C is butralin
Figure BDA0003023230580000543
Figure BDA0003023230580000551
Table 74A shows carfentrazone, B shows benzobicyclon, and C shows oxadiazon
Figure BDA0003023230580000552
Table 75A shows carfentrazone, B shows benzobicyclon, and C shows isoproturon
Figure BDA0003023230580000553
TABLE 76A for carfentrazone-ethyl, B for mesotrione, C for pyraclonil
Figure BDA0003023230580000561
Table 77A shows carfentrazone-ethyl, B shows benzobicyclon, and C shows oxyfluorfen
Figure BDA0003023230580000562
TABLE 78A for topramezone, B for mesotrione, and C for clomazone
Figure BDA0003023230580000563
Figure BDA0003023230580000571
TABLE 79A for topramezone, B for mesotrione, and C for 2-methyl-4-chloro
Figure BDA0003023230580000572
Table 80A shows carfentrazone-ethyl, B shows benzobicyclon, and C shows simetryn
Figure BDA0003023230580000573
Table 81A shows carfentrazone-ethyl, B shows benzobicyclon and C shows quinclorac
Figure BDA0003023230580000581
Table 82A shows carfentrazone-ethyl, B shows benzobicyclon, and C shows penoxsulam
Figure BDA0003023230580000582
TABLE 83A is carfentrazone-ethyl, B is mesotrione, C is fluroxypyr meptyl
Figure BDA0003023230580000583
Figure BDA0003023230580000591
TABLE 84A for carfentrazone-ethyl, B for mesotrione, and C for molinate
Figure BDA0003023230580000592
Table 85A shows carfentrazone, B shows benzobicyclon, and C shows thiobencarb
Figure BDA0003023230580000593
TABLE 86A is topramezone, B is tembotrione, C is pretilachlor
Figure BDA0003023230580000594
Figure BDA0003023230580000601
TABLE 87A is topramezone, B is tembotrione, C is butachlor
Figure BDA0003023230580000602
TABLE 88A is topramezone, B is mesotrione, C is mefenacet
Figure BDA0003023230580000603
Figure BDA0003023230580000611
TABLE 89A for topramezone, B for tembotrione, C for anilofos
Figure BDA0003023230580000612
Table 90A shows carfentrazone-ethyl, B shows tembotrione, and C shows butralin
Figure BDA0003023230580000613
Table 91A shows topramezone, B shows topramezone, and C shows oxadiazon
Figure BDA0003023230580000614
Figure BDA0003023230580000621
TABLE 92A for topramezone, B for tembotrione, and C for isoproturon
Figure BDA0003023230580000622
TABLE 93A for topramezone, B for tembotrione, C for pyraclonil
Figure BDA0003023230580000623
Figure BDA0003023230580000631
TABLE 94A Bixaflutole, B triazophone, C Oxifluorfen
Figure BDA0003023230580000632
TABLE 95A for topramezone, B for tembotrione, and C for clomazone
Figure BDA0003023230580000633
TABLE 96A for topramezone, B for tembotrione, C for 2-methyl-4-chloro
Figure BDA0003023230580000634
Figure BDA0003023230580000641
Table 97A shows carfentrazone-ethyl, B shows tembotrione, and C shows simetryn
Figure BDA0003023230580000642
TABLE 98A is topramezone, B is tembotrione, and C is quinclorac
Figure BDA0003023230580000643
Figure BDA0003023230580000651
Table 99A shows carfentrazone-ethyl, B is tembotrione, and C is penoxsulam
Figure BDA0003023230580000652
Table 100A shows carfentrazone-ethyl, B shows tembotrione, and C shows fluroxypyr meptyl
Figure BDA0003023230580000653
Table 101A shows carfentrazone, B shows tembotrione, and C shows molinate
Figure BDA0003023230580000654
Figure BDA0003023230580000661
Table 102A shows carfentrazone, B shows tembotrione, and C shows thiodan
Figure BDA0003023230580000662
Table 103A shows carfentrazone-ethyl, B shows carfentrazone-ethyl, and C shows pretilachlor
Figure BDA0003023230580000663
Table 104A shows carfentrazone, B shows carfentrazone-ethyl, and C shows butachlor
Figure BDA0003023230580000671
Table 105A shows carfentrazone-ethyl, B shows carfentrazone-ethyl, and C shows mefenacet
Figure BDA0003023230580000672
Table 106A shows carfentrazone, B shows benzoxaflutole, and C shows anilofos
Figure BDA0003023230580000673
Figure BDA0003023230580000681
TABLE 107A is carfentrazone, B is topramezone, C is butralin
Figure BDA0003023230580000682
Table 108A shows carfentrazone, B shows carfentrazone-ethyl, and C shows carfentrazone-ethyl
Figure BDA0003023230580000683
Table 109A shows carfentrazone, B shows benzoxaflutole, and C shows isoproturon
Figure BDA0003023230580000691
Table 110A shows carfentrazone-ethyl, B shows benzoxaflutole, and C shows carfentrazone-ethyl
Figure BDA0003023230580000692
Table 111A shows carfentrazone-ethyl, B shows carfentrazone-ethyl, and C shows oxyfluorfen
Figure BDA0003023230580000693
Figure BDA0003023230580000701
TABLE 112A is topramezone, B is topramezone, C is clomazone
Figure BDA0003023230580000702
TABLE 113A for carfentrazone-ethyl, B for carfentrazone-ethyl, C for 2-methyl-4-chloro
Figure BDA0003023230580000703
Table 114A shows carfentrazone-ethyl, B shows carfentrazone-ethyl, and C shows simetryn
Figure BDA0003023230580000711
TABLE 115A is carfentrazone, B is carfentrazone-ethyl, C is quinclorac
Figure BDA0003023230580000712
Table 116A shows carfentrazone-ethyl, B shows carfentrazone-ethyl, and C shows penoxsulam
Figure BDA0003023230580000713
Figure BDA0003023230580000721
TABLE 117A is carfentrazone, B is carfentrazone-ethyl, C is fluroxypyr meptyl
Figure BDA0003023230580000722
Table 118A shows carfentrazone, B shows carfentrazone-ethyl, and C shows molinate
Figure BDA0003023230580000723
Table 119A shows carfentrazone, B shows benzoxaflutole, and C shows thiobencarb
Figure BDA0003023230580000724
Figure BDA0003023230580000731
Table 120A shows bicyclopyrone, B topramezone and C pretilachlor
Figure BDA0003023230580000732
Table 121A shows bicyclopyrone, B topramezone and C butachlor
Figure BDA0003023230580000733
Figure BDA0003023230580000741
Table 122A shows bicyclopyrone, B shows topramezone, and C shows mefenacet
Figure BDA0003023230580000742
TABLE 123A is ciclopirox, B is topramezone, C is anilofos
Figure BDA0003023230580000743
Table 124A shows bicyclopyrone, B shows topramezone, and C shows butralin
Figure BDA0003023230580000744
Figure BDA0003023230580000751
Table 125A shows bicyclopyrone, B shows topramezone, and C shows oxadiazon
Figure BDA0003023230580000752
Table 126A shows bicyclopyrone, B topramezone and C isoproturon
Figure BDA0003023230580000753
Figure BDA0003023230580000761
TABLE 127A is bicyclopyrone, B is topramezone, C is pyraclonil
Figure BDA0003023230580000762
Table 128A shows bicyclopyrone, B shows topramezone, and C shows oxyfluorfen
Figure BDA0003023230580000763
TABLE 129A bicyclopyrone, B topramezone, C clomazone
Figure BDA0003023230580000764
Figure BDA0003023230580000771
Table 130A shows bicyclopyrone, B topramezone and C2-methyl-4-chloro
Figure BDA0003023230580000772
Table 131A shows bicyclopyrone, B shows topramezone and C shows simetryn
Figure BDA0003023230580000773
Figure BDA0003023230580000781
TABLE 132A is bicyclopyrone, B is topramezone, C is quinclorac
Figure BDA0003023230580000782
Table 133A shows bicyclopyrone, B Topramezone and C penoxsulam
Figure BDA0003023230580000783
Table 134A shows bicyclopyrone, B topramezone and C fluroxypyr meptyl
Figure BDA0003023230580000784
Figure BDA0003023230580000791
TABLE 135A for cyflufenac, B for topramezone, and C for molinate
Figure BDA0003023230580000792
TABLE 136A is bicyclopyrone, B is topramezone, C is thiobencarb
Figure BDA0003023230580000793
TABLE 137A is bicyclopyrone, B is mesotrione, C is pretilachlor
Figure BDA0003023230580000801
Table 138A shows bicyclopyrone, B mesotrione, and C butachlor
Figure BDA0003023230580000802
TABLE 139A is bicyclopyrone, B is mesotrione, C is mefenacet
Figure BDA0003023230580000803
Figure BDA0003023230580000811
Table 140A shows bicyclopyrone, B mesotrione, and C anilofos
Figure BDA0003023230580000812
TABLE 141A is bicyclopyrone, B is mesotrione, C is butralin
Figure BDA0003023230580000813
Table 142A shows bicyclopyrone, B mesotrione, and C oxadiazon
Figure BDA0003023230580000821
TABLE 143A for bicyclopyrone, B for mesotrione, and C for isoproturon
Figure BDA0003023230580000822
TABLE 144A for bicyclopyrone, B for mesotrione, C for pyraclonil
Figure BDA0003023230580000823
Figure BDA0003023230580000831
TABLE 145A is bicyclopyrone, B is mesotrione, C is oxyfluorfen
Figure BDA0003023230580000832
Table 146A shows bicyclopyrone, B mesotrione, and C clomazone
Figure BDA0003023230580000833
Table 147A shows bicyclopyrone, B mesotrione, and C2-methyl-4-chloro
Figure BDA0003023230580000841
TABLE 148A is bicyclopyrone, B is mesotrione, and C is simetryn
Figure BDA0003023230580000842
TABLE 149A Topirazone, B mesotrione, C Quinclorac
Figure BDA0003023230580000843
Figure BDA0003023230580000851
Table 150A shows bicyclopyrone, B mesotrione, and C penoxsulam
Figure BDA0003023230580000852
Table 151A shows bicyclopyrone, B mesotrione and C fluroxypyr meptyl
Figure BDA0003023230580000853
TABLE 152A is cyflufenan, B is mesotrione, and C is molinate
Figure BDA0003023230580000861
Table 153A shows cyflutolone, B mesotrione, and C thiobencarb
Figure BDA0003023230580000862
TABLE 154A is bicyclopyrone, B is tembotrione, C is pretilachlor
Figure BDA0003023230580000863
Figure BDA0003023230580000871
TABLE 155A for bicyclopyrone, B for tembotrione, C for butachlor
Figure BDA0003023230580000872
TABLE 156A is bicyclopyrone, B is tembotrione, C is mefenacet
Figure BDA0003023230580000873
TABLE 157A is ciclopirox, B is tembotrione, C is anilofos
Figure BDA0003023230580000881
Table 158 shows bicyclopyrone, B tembotrione, and C butralin
Figure BDA0003023230580000882
TABLE 159A is ciclopirox, B is tembotrione, C is oxadiazon
Figure BDA0003023230580000883
Figure BDA0003023230580000891
TABLE 160A is bicyclopyrone, B is tembotrione, C is isoproturon
Figure BDA0003023230580000892
Table 161A shows bicyclopyrone, B tembotrione, and C pyraclonil
Figure BDA0003023230580000893
TABLE 162A is bicyclopyrone, B is tembotrione, C is oxyfluorfen
Figure BDA0003023230580000901
TABLE 163A is bicyclopyrone, B is tembotrione, C is clomazone
Figure BDA0003023230580000902
TABLE 164A is bicyclopyrone, B is tembotrione, C is 2-methyl-4-chloro
Figure BDA0003023230580000903
Figure BDA0003023230580000911
Table 165A shows bicyclopyrone, B shows tembotrione, and C shows simetryn
Figure BDA0003023230580000912
TABLE 166A is bicyclopyrone, B is tembotrione, C is quinclorac
Figure BDA0003023230580000913
TABLE 167A for bicyclopyrone, B for tembotrione, and C for penoxsulam
Figure BDA0003023230580000921
TABLE 168A is bicyclopyrone, B is tembotrione, C is fluroxypyr meptyl
Figure BDA0003023230580000922
TABLE 169A is cyflufenac, B is tembotrione, C is molinate
Figure BDA0003023230580000923
Figure BDA0003023230580000931
Table 170A shows bicyclopyrone, B shows tembotrione, and C shows thiodan
Figure BDA0003023230580000932
TABLE 171A is bicyclopyrone, B is isoxaflutole, C is pretilachlor
Figure BDA0003023230580000933
TABLE 172A for bicyclopyrone, B for isoxaflutole, C for butachlor
Figure BDA0003023230580000941
TABLE 173A is bicyclopyrone, B is isoxaflutole, C is mefenacet
Figure BDA0003023230580000942
TABLE 174A shows bicyclopyrone, B isoxaflutole, C anilofos
Figure BDA0003023230580000943
Figure BDA0003023230580000951
TABLE 175A is bicyclopyrone, B is isoxaflutole, C is butralin
Figure BDA0003023230580000952
TABLE 176A is bicyclopyrone, B is isoxaflutole, C is oxadiazon
Figure BDA0003023230580000953
TABLE 177A is bicyclopyrone, B is isoxaflutole, C is isoproturon
Figure BDA0003023230580000961
TABLE 178A is bicyclopyrone, B is isoxaflutole, C is pyraclonil
Figure BDA0003023230580000962
TABLE 179A is bicyclopyrone, B is isoxaflutole, C is oxyfluorfen
Figure BDA0003023230580000963
Figure BDA0003023230580000971
Table 180A shows bicyclopyrone, B isoxaflutole, and C clomazone
Figure BDA0003023230580000972
TABLE 181A is bicyclopyrone, B is isoxaflutole, C is 2-methyl-4-chloro
Figure BDA0003023230580000973
TABLE 182A is bicyclopyrone, B is isoxaflutole, and C is simetryn
Figure BDA0003023230580000981
TABLE 183A is bicyclopyrone, B is isoxaflutole, C is quinclorac
Figure BDA0003023230580000982
TABLE 184A for bicyclopyrone, B for isoxaflutole, and C for penoxsulam
Figure BDA0003023230580000983
Figure BDA0003023230580000991
TABLE 185A is bicyclopyrone, B is isoxaflutole, C is fluroxypyr meptyl
Figure BDA0003023230580000992
TABLE 186A is ciclopirox, B is isoxaflutole, C is molinate
Figure BDA0003023230580000993
Table 187A is bicyclopyrone, B is isoxaflutole, and C is thiobencarb
Figure BDA0003023230580000994
Figure BDA0003023230580001001
Table 188A shows bicyclopyrone, B bicyclosulfotone, and C pretilachlor
Figure BDA0003023230580001002
TABLE 189A for bicyclopyrone, B for bicyclosulfulone, and C for butachlor
Figure BDA0003023230580001003
Figure BDA0003023230580001011
Table 190A shows bicyclopyrone, B shows bicyclophorione, and C shows mefenacet
Figure BDA0003023230580001012
TABLE 191A is ciclopirox, B is mesotrione, C is anilofos
Figure BDA0003023230580001013
TABLE 192A is bicyclopyrone, B is bicyclosulfotone, C is butralin
Figure BDA0003023230580001014
Figure BDA0003023230580001021
TABLE 193A is bicyclopyrone, B is bicyclosulfulone, and C is oxadiazon
Figure BDA0003023230580001022
Table 194A shows bicyclopyrone, B bicyclosulfotone, and C isoproturon
Figure BDA0003023230580001023
Figure BDA0003023230580001031
TABLE 195A is bicyclopyrone, B is bicyclosulfulone, and C is pyraclonil
Figure BDA0003023230580001032
Table 196A shows bicyclopyrone, B shows bicyclosulfuron and C shows oxyfluorfen
Figure BDA0003023230580001033
TABLE 197A is bicyclopyrone, B is bicyclosulfuron, and C is clomazone
Figure BDA0003023230580001034
Figure BDA0003023230580001041
TABLE 198A bicyclopyrone, B bicyclosulfulone, C2-methyl-4-chloro
Figure BDA0003023230580001042
TABLE 199A is bicyclopyrone, B is bicyclosulfotone, and C is simetryn
Figure BDA0003023230580001043
Figure BDA0003023230580001051
Table 200A shows bicyclopyrone, B bicyclosulfotone, and C quinclorac
Figure BDA0003023230580001052
Table 201A shows bicyclopyrone, B shows bicyclosulfotone, and C shows penoxsulam
Figure BDA0003023230580001053
Table 202A shows bicyclopyrone, B bicyclosulfotone, and C fluroxypyr meptyl
Figure BDA0003023230580001054
Figure BDA0003023230580001061
Table 203A shows bicyclopyrone, B bicyclosulfulone, and C molinate
Figure BDA0003023230580001062
Table 204A shows bicyclopyrone, B shows bicyclosulfulone, and C shows thiobencarb
Figure BDA0003023230580001063
Figure BDA0003023230580001071
Table 205A shows bicyclopyrone, B triazophone, and C pretilachlor
Figure BDA0003023230580001072
Table 206A shows bicyclopyrone, B triazophone, and C butachlor
Figure BDA0003023230580001073
Table 207A shows bicyclopyrone, B shows triazophone, and C shows mefenacet
Figure BDA0003023230580001074
Figure BDA0003023230580001081
Table 208A shows bicyclopyrone, B triazophone, and C anilofos
Figure BDA0003023230580001082
Table 209A shows bicyclopyrone, B shows triazophone, and C shows butralin
Figure BDA0003023230580001083
Table 210A shows bicyclopyrone, B triazophodim, and C oxadiazon
Figure BDA0003023230580001091
Table 211A shows bicyclopyrone, B triazophodim, and C isoproturon
Figure BDA0003023230580001092
Table 212A shows bicyclopyrone, B triazophone, and C pyraclonil
Figure BDA0003023230580001093
Figure BDA0003023230580001101
Table 213A shows bicyclopyrone, B triazophone, and C oxyfluorfen
Figure BDA0003023230580001102
Table 214A shows bicyclopyrone, B triazophone, and C clomazone
Figure BDA0003023230580001103
Table 215A shows bicyclopyrone, B triazophone, and C2-methyl-4-chloro
Figure BDA0003023230580001111
Table 216A shows bicyclopyrone, B triazophone, and C simetryn
Figure BDA0003023230580001112
Table 217A shows bicyclopyrone, B triazophone, and C quinclorac
Figure BDA0003023230580001113
Figure BDA0003023230580001121
Table 218A shows bicyclopyrone, B triazophone, and C penoxsulam
Figure BDA0003023230580001122
TABLE 219A is ciclopirox, B is tembotrione, C is fluroxypyr
Figure BDA0003023230580001123
Table 220A shows bicyclopyrone, B triazophone, and C molinate
Figure BDA0003023230580001131
TABLE 221A is ciclopirox, B is tembotrione, C is thiobencarb
Figure BDA0003023230580001132
TABLE 222A is bicyclopyrone, B is topramezone, C is pretilachlor
Figure BDA0003023230580001133
Figure BDA0003023230580001141
Table 223A shows bicyclopyrone, B shows topramezone, and C shows butachlor
Figure BDA0003023230580001142
Table 224A shows bicyclopyrone, B shows topramezone, and C shows mefenacet
Figure BDA0003023230580001143
Table 225A shows bicyclopyrone, B shows benzoxaflutole, and C shows anilofos
Figure BDA0003023230580001151
Table 226A shows bicyclopyrone, B shows topramezone, and C shows butralin
Figure BDA0003023230580001152
TABLE 227A is bicyclopyrone, B is topramezone, C is oxadiazon
Figure BDA0003023230580001153
Figure BDA0003023230580001161
TABLE 228A is bicyclopyrone, B is topramezone, C is isoproturon
Figure BDA0003023230580001162
TABLE 229A is bicyclopyrone, B is topramezone, C is pyraclonil
Figure BDA0003023230580001163
Table 230A shows bicyclopyrone, B shows topramezone, and C shows oxyfluorfen
Figure BDA0003023230580001171
TABLE 231A bicyclopyrone, B topramezone, C clomazone and C clomazone
Figure BDA0003023230580001172
TABLE 232A is bicyclopyrone, B is topramezone, C is 2-methyl-4-chloro
Figure BDA0003023230580001173
Figure BDA0003023230580001181
Table 233A shows bicyclopyrone, B shows topramezone, and C shows simetryn
Figure BDA0003023230580001182
TABLE 234A is bicyclopyrone, B is topramezone, C is quinclorac
Figure BDA0003023230580001183
TABLE 235A is bicyclopyrone, B is topramezone, C is penoxsulam
Figure BDA0003023230580001191
TABLE 236A is bicyclopyrone, B is topramezone, C is fluroxypyr meptyl
Figure BDA0003023230580001192
TABLE 237A is cyflufenac, B is topramezone, C is molinate
Figure BDA0003023230580001193
Figure BDA0003023230580001201
Table 238A is bicyclopyrone, B is topramezone, C is thiobencarb
Figure BDA0003023230580001202
Note: e (A): observed fresh weight survival rate for component A treatment at a given dose
E (B): observed fresh weight survival for component B treatment at a given dose
E (C): observed fresh weight survival for component C treatment at a given dose
E (A + B): the measured fresh weight survival rate of the component A and the component B which are mixed in a binary way under the given dosage
E (A + C): the measured fresh weight survival rate of the component A and the component C mixed in a binary way under the given dosage
E (B + C): the measured fresh weight survival rate of the component B and the component C mixed in a binary way under the given dosage
E (A + B + C): the observed fresh weight survival rate of the three-component mixture of the component A, B, C at a given dosage
E0(A + B + C): theoretical fresh weight survival rate of ternary combination of component A, B, C at given dose
E0((A + B) + C): theoretical fresh weight survival rate for a binary blend of component A, B as a whole with component C at a given dose
E0((A + C) + B): theoretical fresh weight survival rate for a binary blend of component A, C as a whole with component B at a given dose
E0(A + (B + C)): theory of binary admixture of component B, C as a whole with component A at a given dosageFresh weight survival rate C) field demonstration
The herbicidal compositions prepared in examples 1) to 238) were used for field weed effect tests.
An exemplary popularization test was performed in 2017 at the Anhui Tianchang test point. The weeds in the field are mainly: capsella bursa-pastoris, Stellaria arvensis, cleavers, Aleurites communis, Aleurites japonica, beckmannia syzigachne and the like.
Test methods (soil treatment): before weed germination, a manual sprayer is used for adding water with the amount of 45 kg/667 m2The soil surface is uniformly sprayed. The specific test agents and dosages are detailed in table 239, the cell area is 50 square meters, and each treatment is repeated 4 times. The control effect was investigated 45 days after the application of the composition as shown in Table 239.
Figure BDA0003023230580001211
Exemplary field Effect of the compounded composition set forth in Table 239
Figure BDA0003023230580001212
Figure BDA0003023230580001221
Figure BDA0003023230580001231
Figure BDA0003023230580001241
Figure BDA0003023230580001251
Figure BDA0003023230580001261
Figure BDA0003023230580001271
Figure BDA0003023230580001281
Figure BDA0003023230580001291
Figure BDA0003023230580001301
Figure BDA0003023230580001311
Through a large number of tests and explorations, the invention unexpectedly discovers that the composition has a surprising and unexpected synergistic effect when used for preventing and killing weeds such as shepherd's purse, caraway marigold, cleavers, alopecurus davidii, alopecurus japonicus, beckmannia syzigachziana and the like, the synergistic effect is more obvious under a low dosage, the dosage can be reduced, the pollution to the environment is reduced, the agricultural cost is reduced through reasonable compounding, the composition is efficient on ALS and ACCase inhibitor resistant weeds, and the application prospect is good. Meanwhile, the herbicide composition shows good selectivity and excellent synergistic effect on lawns and crops such as wheat fields, corn fields, paddy fields, peanuts, sugarcane, sorghum, millet, potatoes, rapes, soybeans, cotton, vegetables, bluegrass, tall fescue, zoysia japonica and the like of conventional varieties and gene editing varieties through testing, and can be developed into herbicide mixtures with wide market values.

Claims (15)

1. A ternary herbicidal composition comprising an HPPD inhibitor herbicide, comprising a herbicidally effective amount of an active ingredient A, an active ingredient B and an active ingredient C, wherein,
the active ingredient A is selected from one of the following HPPD inhibitor herbicide compounds: (ii) topramezone;
the active ingredient B is selected from one of the following compounds: topramezone, mesotrione, tembotrione, isoxaflutole, benzobicyclon, triazophone, topramezone;
the active ingredient C is selected from one of the following compounds: pretilachlor, butachlor;
when C is pretilachlor, the weight ratio of A, B to C is 1-100: 0.1-30: 100-500;
when the C is butachlor, the weight ratio of A, B to C is 1-100: 0.1-30: 200-1000;
when B is topramezone, C is not pretilachlor.
2. The ternary herbicidal composition comprising an HPPD inhibitor-type herbicide according to claim 1, characterized in that,
when C is pretilachlor, the weight ratio of A, B to C is 5-80: 0.5-20: 100-500;
when the C is butachlor, the weight ratio of A, B to C is 5-80: 0.5-20: 200-1000.
3. The ternary herbicidal composition comprising an HPPD inhibitor-type herbicide according to claim 1, characterized in that,
when C is pretilachlor, the weight ratio of A, B to C is 10-60: 0.7-15: 100-500;
when the C is butachlor, the weight ratio of A, B to C is 10-60: 0.7-15: 600-800.
4. The ternary herbicidal composition comprising an HPPD inhibitor-type herbicide according to claim 1, characterized in that,
when C is pretilachlor, the weight ratio of A, B to C is 20-50: 1-12: 200-300;
when the C is butachlor, the weight ratio of A, B to C is 20-50: 1-12: 600-800.
5. The ternary herbicidal composition comprising an HPPD inhibitor-type herbicide according to claim 1, characterized in that,
when C is pretilachlor, the weight ratio of A, B to C is 30-40: 3-7: 200-300;
when the C is butachlor, the weight ratio of A, B to C is 30-40: 3-7: 600-800.
6. The ternary herbicidal composition comprising an HPPD inhibitor-type herbicide according to claim 1, characterized in that,
when the B is topramezone and the C is butachlor, the weight ratio of A, B to C is 10-60: 0.7-5: 200-1000;
when the B is mesotrione and the C is pretilachlor, the weight ratio of A, B to C is 10-60: 1-10: 100-500;
when the B is mesotrione and the C is butachlor, the weight ratio of A, B to C is 10-60: 1-10: 200-1000;
when B is tembotrione or isoxaflutole and C is pretilachlor, the weight ratio of A, B to C is 10-60: 1-7: 100-500;
when B is tembotrione or isoxaflutole and C is butachlor, the weight ratio of A, B to C is 10-60: 1-7: 200-1000;
when the B is the benzobicyclon and the C is pretilachlor, the weight ratio of A, B to C is 10-60: 5-20: 100-500;
when the B is the bicyclsulcotrione and the C is the butachlor, the weight ratio of the A, B to the C is 10-60: 5-20: 200-1000;
when the B is the triazophorbine or the topramezone and the C is the pretilachlor, the weight ratio of A, B to C is 10-60:
3-12:100～500；
when the B is the triazophorbine or the topramezone and the C is the butachlor, the weight ratio of A, B to the C is 10-60: 3-12: 200-1000.
7. A ternary herbicidal composition comprising an HPPD inhibitor herbicide according to any one of claims 1 to 6, characterized in that the mass percentage of A, B and C in the herbicidal composition is 1 to 95% of the total.
8. A ternary herbicidal composition comprising an HPPD inhibitor herbicide according to claim 7, characterized in that the mass percentage of A, B and C in the herbicidal composition is 10 to 80% of the total.
9. A ternary herbicidal composition comprising an HPPD inhibitor-type herbicide according to any one of claims 1 to 6, characterized in that conventional adjuvants are also included in the herbicidal composition.
10. A ternary herbicidal composition comprising a HPPD inhibitor herbicide according to claim 9, characterized in that said conventional adjuvants comprise carriers, surfactants.
11. Ternary herbicidal composition comprising a herbicide of the HPPD inhibitor class according to any of the claims 1 to 6, characterized in that it further comprises at least one safener.
12. A ternary herbicidal composition comprising a herbicide belonging to the HPPD inhibitor class according to any one of claims 1 to 6, characterized in that the specific formulation of the herbicidal composition is dispersible oil-suspendable agent, water-suspendable agent, suspoemulsion, wettable powder, emulsifiable concentrate, water dispersible granules, aqueous emulsion or microemulsion.
13. Use of a ternary herbicidal composition comprising an HPPD inhibitor herbicide according to any one of claims 1 to 12 for controlling weeds in crops of plants.
14. A method of controlling unwanted plant growth, comprising applying a ternary herbicidal composition comprising a HPPD inhibitor-based herbicide according to any one of claims 1 to 12 to a plant, to a plant part, to a plant seed or to an area where a plant is growing.
15. The method of claim 14, for selectively controlling weeds in a crop.
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