CN113057169B - Herbicidal composition containing bicyclopyrone and application thereof - Google Patents

Herbicidal composition containing bicyclopyrone and application thereof Download PDF

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CN113057169B
CN113057169B CN202110317652.8A CN202110317652A CN113057169B CN 113057169 B CN113057169 B CN 113057169B CN 202110317652 A CN202110317652 A CN 202110317652A CN 113057169 B CN113057169 B CN 113057169B
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polyoxyethylene ether
bicyclopyrone
evaluation
combination
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CN113057169A (en
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彭学岗
赵德
金涛
刘娜
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Hunan academy of agricultural sciences
Institute For Pesticide Control Ministry Of Agriculture And Rural Areas Secretariat Of Codex Alimentarius Commission On Pesticide Residues
NATIONWIDE AGRICULTURAL TECHNOLOGY PROMOTION SERVICE CENTER
Qingdao Qingyuan Crop Science Co ltd
Guizhou University
Shandong Agricultural University
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Qingdao Kingagroot Chemical Compound Co Ltd
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A01N33/20—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
    • A01N33/22—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • A—HUMAN NECESSITIES
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    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A01N41/06—Sulfonic acid amides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
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    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
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    • A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals

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Abstract

The invention belongs to the field of pesticides, and particularly relates to a herbicidal composition containing bicyclopyrone and application thereof. The composition comprises active ingredients A and B with herbicidally effective amounts, wherein A is bicyclopyrone, and B can be selected from one or more of the following compounds: VLCFA, PPO, PSII, ALS, PDS, DOXP, etc. The composition can effectively prevent and kill off the problems of weeds such as Japanese alopecurus, descurainia sophia, shepherd's purse, starwort, speedwell, cleavers, alopecurus, etc. in crop fields, and has the characteristics of expanding the weed control spectrum, reducing the application amount, being safe to crops, generating synergistic action, solving resistant weeds, etc.

Description

Herbicidal composition containing bicyclopyrone and application thereof
The application is a divisional application of a Chinese invention patent application with the application date of 2017, 11 and 9, and the application number of 201711095778.5, and the invention name of the invention is 'a herbicidal composition containing bicyclopyrone and application thereof'.
Technical Field
The invention belongs to the field of pesticides, and particularly relates to a herbicidal composition containing bicyclopyrone and application thereof.
Background
Chemical weeding is the most economic and effective means in preventing and removing weeds in farmlands, but the problems of drug resistance and resistance evolution of weeds and the like are easily caused by using a single variety or a single action mode of chemical herbicide continuously at a high dose for a long time.
The chemical structural formula of the bicyclopyrone is shown as
Figure BDA0002991828280000011
The compound belongs to an HPPD inhibitor, and the activity of HPPD enzyme is inhibited, so that the process of converting hydroxy pyruvic acid into homogentisate is hindered, thus leading to the abnormal synthesis of tocopherol and plastoquinone, influencing the synthesis of carotenoid in a target body, leading to the whitening of leaves, influencing the normal operation of photosynthesis in a plant body, and finally completely dying.
The reasonable compounding or mixing of the herbicide compound has the advantages of expanding the weed spectrum, improving the control effect, delaying the occurrence and development of drug resistance and drug resistance of weeds and the like, and is one of the most effective methods for solving the problems. Therefore, the development of a weeding composition variety which has high safety and wide weed control spectrum, can produce synergistic effect and solve the problem of resistant weeds is urgently needed in production.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides a herbicidal composition containing bicyclopyrone and application thereof. The composition can effectively prevent and kill off the problems of weeds such as Japanese alopecurus, descurainia sophia, shepherd's purse, starwort, speedwell, cleavers, alopecurus, etc. in crop fields, and has the characteristics of expanding the weed control spectrum, reducing the application amount, being safe to crops, generating synergistic action, solving resistant weeds, etc.
A weeding composition containing bicyclopyrone comprises a herbicidally effective amount of an active ingredient A and an active ingredient B, wherein the active ingredient A is bicyclopyrone, and the active ingredient B can be selected from one or more of the following compounds:
1) VLCFA inhibitors, butachlor (CAS registry No. 23184-66-9), anilofos (CAS registry No. 64249-01-0), dimethenamid (CAS registry No. 87674-68-8), fentrazamide (CAS registry No. 158237-07-1), triafamone (CAS registry No. 212201-70-2), cafenstrole (CAS registry No. 125306-83-4), mephos (CAS registry No. 24151-93-7), diflufenican (CAS registry No. 67129-08-2), propachlor (CAS registry No. 1918-16-7), pethoxamid (CAS registry No. 106700-29-2);
2) PPO inhibitors, oxyfluorfen (CAS accession No. 42874-03-3), fomesafen (CAS accession No. 72178-02-0), oxadiazon (CAS accession No. 19666-30-9), oxadiargyl (CAS accession No. 39807-15-3), sulfentrazone (CAS accession No. 122836-35-5), pyraclonil (CAS accession No. 158-15-2), flumioxazin (CAS accession No. 103361-09-7), pentoxazone (CAS accession No. 110956-75-7), tiafenacil (CAS accession No. 1220411-29-9), saflufenacil (CAS accession No. 372137-35-4);
3) PSII inhibitors, atrazine (CAS registry No. 102029-43-6), terbuthylazine (CAS registry No. 5915-41-3), ametryn (CAS registry No. 834-12-8), ipratron (CAS registry No. 4147-51-7), fenfluramine (CAS registry No. 845-52-3), diuron (CAS registry No. 1014-69-3), simazine (CAS registry No. 122-34-9), cyanazine (CAS registry No. 25-46-2), fluometuron (CAS registry No. 2164-21617-2), linuron (CAS registry No. 330-55-2), buthiuron (CAS registry No. 34014-18-1), cypermethron (CAS registry No. 42609-52-9), chlorsulfuron (CAS registry No. 1746-81-2), Bromuron (CAS accession No. 3060-89-7), glufosinate (CAS accession No. 555-37-3), pyridazinol (CAS accession No. 40020-01-7), hexazinone (CAS accession No. 51235-04-2), isoethazine (CAS accession No. 22936-75-0), madazine (CAS accession No. 1912-26-1), bromacil (CAS accession No. 314-40-9), lenacil (CAS accession No. 2164-08-1), terbacil (CAS accession No. 5902-51-2), methabenzthiazuron (CAS accession No. 91-97-9), cyclosulfamuron (CAS accession No. 1982-49-6), isooxauron (CAS accession No. 55861-78-4), metoxuron (CAS accession No. 19937-59-8), SUBTILON (CAS Reg.No.: 1982-47-4), Cyclopyroximate (CAS Reg.No.: 499231-24-2), pyridate (CAS Reg.No.: 55512-33-9), desmedipham (CAS Reg.No.: 13684-56-5), phenmedin (CAS Reg.No.: 13684-63-4), simetryn (CAS Reg.No.: 1014-70-6), diuron (CAS Reg.No.: 330-54-1), amicarbazone (CAS Reg.No.: 129909-90-6), metamitron (CAS Reg.No.: 41394-05-2), ethionamide (CAS Reg.No.: 64529-56-2);
4) ALS inhibitors such as pyrazosulfuron-ethyl (CAS accession No.: 93697-74-6), thiencarbazone-methyl (CAS accession No.: 317815-83-1), propyrisulfuron-methyl (CAS accession No.: 570415-88-2), azimsulfuron (CAS accession No.: 868680-84-6), rimsulfuron-methyl (CAS accession No.: 122931-48-0), ethoxysulfuron-methyl (CAS accession No.: 126801-58-9), pyriminosulfuron-methyl (CAS accession No.: 213464-77-8), nicosulfuron-methyl (CAS accession No.: 111991-09-4), foramsulfuron-methyl (CAS accession No.: 173159-57-4), triafamone-sodium (CAS accession No.: 96525-23-4), penoxsulam-219714-96-2), cloransulam-methyl (CAS accession No.: 147150-35-4), Imazamox (CAS accession No. 114311-32-9), imazapic (CAS accession No. 104098-48-8), imazethapyr (CAS accession No. 81385-77-5), imazapyr (CAS accession No. 81334-34-1), pyriminobac (CAS accession No. 147411-69-6);
5) microtubule assembly inhibitors: trifluralin (CAS accession number: 1582-09-8), butralin (CAS accession number: 33629-47-9), pendimethalin (CAS accession number: 40487-42-1), dimethomorph (CAS accession number: 33629-47-9), dithiopyr (CAS accession number: 97886-45-8), ethambucil (CAS accession number: 55283-68-6), oryzalin (CAS accession number: 19044-88-3), flumetsulam (CAS accession number: 1861-40-1), thiazopyr (CAS accession number: 117718-60-2), propaquilate (CAS accession number: 23950-58-5), dichlorvos (CAS accession number: 1861-32-1), and phorate (CAS accession number: 36335-67-8);
6) HPPD inhibitors, sulcotrione (CAS registry No.: 99105-77-8), mesotrione (CAS registry No.: 104206-82-8), tembotrione (CAS registry No.: 335104-84-2), mesotrione (CAS registry No.: 473278-76-1), benzobicyclon (CAS registry No.: 156963-66-5), lancotrione (CAS registry No.: 1486617-21-3), pyrazosulfuron-ethyl (CAS registry No.: 365400-11-9), pyrazolate (CAS registry No.: 58011-68-0), pyroxadim (CAS registry No.: 82692-44-2), tolpyralate (CAS registry No.: 1101132-67-5), fenquinolonone (CAS registry No.: 1342891-70-6), isoxaflutole (CAS registry No.: 141112-29-0);
7) (ii) PDS inhibitors, fluorochloridone (CAS registry No. 61213-25-0), flurtamone (CAS registry No. 96525-23-4), beflubutamid (CAS registry No. 113614-08-7), norflurazon (CAS registry No. 27314-13-2), and fluridone (CAS registry No. 59756-60-4);
8) DOXP inhibitors, clomazone (CAS registry number 81777-89-1);
9) lipid synthesis (non-acetyl coenzyme A carboxylase) inhibitors, including molinate (CAS accession number: 2212-67-1), diclofop (CAS accession number: 28249-77-6), benfuresate (CAS accession number: 68505-69-1), ethofumesate (CAS accession number: 26225-79-6), triallate (CAS accession number: 2303-17-5), ethaboxam (CAS accession number: 28249-77-6), molinate (CAS accession number: 1929-77-7), butate (CAS accession number: 2008-41-5), cycloate (CAS accession number: 1134-23-2), penflufen (CAS accession number: 61432-55-1), penflufen (CAS accession number: 85785-20-2);
10) synthetic hormones, quinclorac (CAS registry number: 84087-01-4), chloroquine (CAS registry number: 90717-03-6);
11) EPSPS inhibitors, phosphinothricin (CAS accession number: 81591-81-3);
12) GS inhibitors include bialaphos (CAS registry No. 35597-43-4), and glufosinate-ammonium (CAS registry No. 35597-44-5);
13) PSI inhibitors, paraquat (CAS registry number: 1910-42-5), diquat (CAS registry number: 6385-62-2);
14) DHP inhibitors sulforaphane (CAS accession number: 3337-71-1);
15) others, oxaziclomefone (CAS registry No.: 153197-14-9), cinmethylin (CAS registry No.: 87818-31-3).
Wherein the weight ratio of A to B is 1:200-200:1, preferably 1:150-150:1, more preferably 1:120-120: 1; further, the weight ratio of A and B is 1:100-100:1, preferably 1:80-80:1, more preferably 1:50-50: 1; further, the weight ratio of A and B is 1:30 to 30:1, preferably 1:10 to 10:1, more preferably 1:5 to 5: 1.
The mass percentage of A, B in the weeding composition accounts for 1-95% of the total amount, and preferably 10-80%.
The weeding composition also comprises conventional auxiliaries which comprise a carrier and a surfactant.
The term "carrier" herein denotes an organic or inorganic, natural or synthetic substance. They facilitate the application of the active ingredient, the carrier being generally inert and must be agriculturally acceptable, in particular for the treated plant. The carrier may be a solid, such as a clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, or the like; or liquids such as water, alcohols, ketones, petroleum distillates, aromatic or waxy hydrocarbons, chlorinated hydrocarbons, liquefied gases, etc.
Surfactants may include emulsifying, dispersing or wetting agents, which may be ionic or non-ionic. Examples which may be mentioned are salts of polyacrylic acids, lignosulphonates, salts of phenolsulphonic or naphthalenesulphonic acids, polymers of ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols, in particular alkylphenols or arylphenols, sulphosuccinates, taurine derivatives, in particular taurine alkyl esters, and phosphoric esters of alcohols or polyhydroxyethylated phenols, alkylsulfonates, alkylarylsulphonates, alkylsulfates, lauryl ether sulphates, fatty alcohol sulphates, and sulphated hexadec, heptadeca-and octadecanols and sulphated fatty alcohol glycol ethers, and furthermore condensates of naphthalene or naphthalenesulphonic acids with phenol and formaldehyde, polyoxyethylene octylphenyl ether, ethoxylated isooctylphenol, octylphenol or nonylphenol, alkylphenyl polyglycol ethers, tributylphenyl polyglycol ether, tristearylphenyl polyglycol ether, polystearylphenyl polyglycol ether, Alkylaryl polyether alcohols, alcohol and fatty alcohol/ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers, ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal, sorbitol esters, lignosulfite waste liquors, and also proteins, denatured proteins, polysaccharides (e.g. methylcellulose), hydrophobically modified starches, polyvinyl alcohols, polycarboxylates, polyalkoxylates, polyvinylamines, polyvinylpyrrolidone and copolymers thereof. At least one surfactant is required to be present to facilitate dispersion of the active ingredients in water and to facilitate their proper application to the plant.
The compositions may also contain various other components such as protective colloids, binders, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants, and polymers.
The compositions of the present invention may be diluted or used directly by the user prior to use. The formulation can be prepared by conventional processing methods, i.e., mixing the active substance with a liquid solvent or solid carrier, and adding one or more surfactants such as dispersants, stabilizers, wetting agents, binders, defoamers, etc.
The specific preparation of the weeding composition is dispersible oil suspending agent, water suspending agent, suspending emulsion, wettable powder, missible oil, water dispersible granule (dry suspending agent), emulsion in water and microemulsion.
In short, the compositions of the present invention may be mixed with solid and liquid additives conventionally used in prior art formulations.
In addition, the combination of compounds A and B may be mixed with active substances known, for example, from the "encyclopedia of New agricultural chemical products, technology, China agricultural science and technology Press, 2010.9 and the references cited therein. For example, herbicidal active substances mentioned below (remarks: the name of the compound, or the generic name according to the International organization for standardization (ISO), or the chemical name, when appropriate with a code), acetochlor, butachlor, alachlor, propisochlor, metolachlor, s-metolachlor, pretilachlor, propachlor, butachlor, napropamide, R-laevo-napropamide, propanil, mefenacet, diphenoyl-oxamide, diflufenican, flumetsulam, bebutamid, dimethenamid, ethoxybenclamide, flufenacet, methoxyfenacet, metazachlor, isooxachlor, lofluvalinate, dimethenamid, butachlor, propisochlor, mefenamid, flucetochlor, propyzamide, dimethenamid, penoxsulam, propyne, dimethenamid, terbutamid, dimethenamid, dimethachlor, norfluramine, trifoliamine, chlorantraniliprole, propyzamide, penflufen, napropamide, acetometazachlor, naproxen, fenacet, pyraflufen, metolachlor, clofenamide, butachlor, butamidin, fluazinam, atrazine, simazine, prometryn, cyanazine, simetryn, ametryn, prometryn, ipretryn, fluroxypyr, terbutryn, terbutazine, triazineon, cyhalofop, ganciclovir, prometryn, simazine, triazazine, dimethametrazine, isopentetryn, cycloprozine, terbutryn, sec-butyn, terbutaline, terbutryn, metolachlor, cyhalofop, metolachlor, prometryn, simazine, atrazine, dimethametryn, dimethametin, terbutryn, metolachlor, dimethachlor, dimethozin, atrazine, metolachloraz, metolachlor, metolachlorethan, metolachlor, atrazine, metolachlorethan, atrazine, metolachlor, atrazine, metolachlor, atrazine, metolachlorfenbutazine, metolachlor, metolachlorfenbutazine, atrazine, metolachlor, atrazine, metolachlor, atrazine, metolachlor, atrazine, metolachlor, Cyanuric acid, Indaziflam, chlorsulfuron, metsulfuron, bensulfuron-methyl, chlorimuron-ethyl, tribenuron-methyl, thifensulfuron-methyl, pyrazosulfuron-ethyl, mesosulfuron-methyl, iodosulfuron-methyl sodium, formamidosulfuron, cinosulfuron, triasulfuron, sulfometuron-methyl, nicosulfuron, ethametsulfuron-methyl, amidosulfuron, ethoxysulfuron, cyclosulfamuron-methyl, rimsulfuron, azimsulfuron-methyl, monosulfuron-methyl, primisulfuron-methyl, flusulfuron-methyl, flazasulfuron-methyl, propsulfuron-methyl, prosulfuron-methyl, trifloxysulfuron, triflusulfuron-methyl, metsulfuron-methyl, primisulfuron-methyl, propulsulfuron-methyl, propaferon-methyl, triflusulfuron-methyl, sulfometuron-methyl, pyrisulfuron-methyl, propalis-ethyl, thiuron-methyl, sulfometuron-methyl, sulfometuron-ethyl, sulfometuron-ethyl, sulfofluridone, sulfometuron-ethyl, sulfofluridone, sulfometuron-methyl, sulfofluridone, sulfometuron-ethyl, benfluridone, bensulfuron-ethyl, bensulfuron-methyl, bensulfuron-ethyl, bensulfuron-methyl, bensulfuron-ethyl, bensulfuron-methyl, ben, Dicumyl ether, aclonifen, ethoxyfen-ethyl, bifenox, trifluoromethoxyfen, metoxyfen, trifluornitrofen, fluoroglycofen, fluridone, bifenox, dimethofen, fluazifop-butyl, Halosafen, chlortoluron, isoproturon, linuron, diuron, fenpropuron, fluometuron, methabenzthiazuron, benzuron, sulfosulfuron, clofenuron, tebuthiuron, clodinuron, meturon, metoxuron, bromuron, metoxuron, meturon, metoxuron, metoron, metoxuron, metoron, Betalain, asulam, tefurazone, avenacin, anilazine, chlorpropham, dichlofenamate, imazalil, cloropham, Carboxazole, chlorerprocarb, Fenasulam, BCPC, CPPC, Carbasulam, buticarb, thiobencarb, dimethenate, triallate, thiobencarb, dicofol, pyributicarb, chlochloate, dichlorfon, dodekafol, ethiofencarb, captan, prosulfocarb, thiobencarb, promethate, Isopolinate, Methiobencarb, 2, 4-chlorobutyl ester, 2 methyl 4-sodium chloride, 2, 4-chloroisooctyl ester, 2 methyl 4-chloroisooctyl ester, 2, 4-d sodium salt, 2, 4-dimethylxylyl ester, 2 methyl 4-chlorothioester, 2 methyl 4-chloropropionate, 2-methyl 4-chloropropionate, 2-4-chlorobutyric acid, 2-methyl 4-chlorobutyric acid, 2-chloro-4-methyl-butyric acid, 2, 4-chloro-4-methyl-4-chloro-butyric acid, 2-4-chloro-methyl-4-butyric acid, 2-chloro-4-chloro-butyric acid, 2-chloro-4-methyl-4-2-chloro-4-butyric acid, 2-chloro-2-4-2-chloro-4-chloro-butyric acid, 2-chloro-4-2-4-chloro-2-chloro-butyric acid, 2-4-chloro-2-4-2-chloro-2-chloro-2-4-2-butyric acid, 2-chloro-2-chloro-4-chloro-4-2-4-chloro-butyric acid, 2-chloro-2-4-2-4-2-chloro-2-4-2-4-2-4-2-chloro-2-4-2-chloro-2-4-2-4-2-D-2-4-2-4-2-4-D-2, 5-nasal discharge, 2,4, 5-aldicacid, 2-methyl-4-chloramine salt, dicamba, imazapyr, varroa, cyprodinil, triclosan, amchlor, metocloprid, diclofop-p-butyl, fluazifop-p-butyl, haloxyfop-methyl, haloxyfop-p-butyl, quizalofop-p-ethyl, fenoxaprop-p-ethyl, propaquizafop-butyl, metamifop-ethyl, thiazoxafen-ethyl, clodinafop-ethyl, oxyphenbutan-ethyl, trifolox-oxime, isoxafen, paraquat, diquat, asulam, ethacrylfluron, ethalfluron, isopulfop-p-methyl, ciprofloxacin, propafen, ethalfluron-ethyl, haloxyfop-ethyl, chloroethafluorin, mefenap-ethyl, metocloprid, propaphorin, promethazine, metocloprid, fosinate, mephos-methyl, metocloprid, clofos, metocloprid, and methyl-p-methyl, Thiophosphoryl, piperazinone, bialaphos, bensulide, imazapyr, glufosinate, imazapyr, imazethapyr, imazaquin ammonium salt, imazapic, imazamethabenz ester, fluroxypyr, isooctyl fluroxypyr, clopyralid, picloram, triclopyr, dithiopyr, haloxydine, triclopyr, thiazopyr, aminopyralid, fluroxypyr, butoxyethyl triclopyr, Cliodinate, sethoxydim, cycloxydim, bentazone, metamitron, cycloxydim, benzone, tralkoxydim, metribuzin, amitridione, amibizin, bromoxynil, octanoyl nitrile, fenpropinil, pyrazoxynil, iodoxynil, haloxynil, and a, Oxypyr, Iodobonil, flumetsulam, florasulam, penoxsulam, sulfentrazone, cloransulam, diclosulam, pyroxsulam, fluroxypyr, bispyribac, pyribenzoxim, pyriminobac, pyrithiobac, bicyclophorione, mesotrione, sulcotrione, Tembotrione, Tefuryltrione, Bicyclopyrone, ketendidox, isoxaflutole, fenoxasulfofone, methiozolinin, ipropyr, pyraflufen, pyraflutole, pyroxaflutole, Pyroxasulfone, pyraflutole, Pyrasulfotole, pyraflutole, amicarbazone, flumiclazone, flumetsulam, mefenpyr, bensulam, bexathion, flumicloram, flumiclone, flumicloram, pyrazam, pyraflufenacetmol, pyraclofenacetmol, pyraclorac, pyraclofenap, flumiclone, flumicloram, Terbenol, terbutal, penitrol, dinitrophenol, chloronitrophenol, dimethomorph, oxadiargyl, oxadiazon, pentoxazone, flumetsulam, mefenoxaprop, fentrazamide, fluazifop-ethyl, desmetryn, bromatrazine, dimetaluron, pyridaben, Pyridafol, quinclorac, clomazone, bentazon, pyridate, oxadiargyl, benazolin, clomazone, cumquat-ethyl, propyl isopropyl ether, clofenpropathrin, indangrone, sodium chlorate, dalapon, trichloroacetic acid, monochloroacetic acid, hexachloroacetone, tetrafluoropropionic acid, mefenpyr, bromophenol oxime, triazasum, pyrazole, flurtamone, benfuresafen, ethofencarbazone, pyrimethanil, clodinafol, flutolanilide, acrolein, mefenapyr, clodinil, pyraclonil, metol, bensulam, clomazam, bensulam, clomazone, benflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenfluridone, benflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenflurbenfluridone, benfluridone, Metophenone, saflufenacil, chlorantraniliprole, trichloropropionic acid, Alorac, Diethamquat, Etnipromid, Iphrymam, Ipfancabazone, Thiencabazone-methyl, Pyrimisulfan, Chrerfluorazole, Tripropindan, Sulglycasin, Sumbellichler, Cambodhi, cyprodinic acid, thiocyananilide, cloquintocet, fencloquine, mequintocet, mefenapyr, mefenpyr, furazolidone, imazaquin, flufenpyr, isoxadifen, dichlormid, halauxin, halauxifen, DOWFAUD, UBH-509, D489, LS 82-556, KPP-300, NC-324, NC-330, DPX-218, DPX-N-89, TPOWN-0744, KIH-927, KIH-18-K-75, KC-3, KC-751, MBH-3, and PKH-751.
The herbicidal composition further includes a safener selected from one or more of isoxadifen (CAS registry number: 163520-33-0), cyprosulfamide (CAS registry number: 221667-31-8), mefenpyr (CAS registry number: 135590-91-9), cloquintocet (CAS registry number: 99607-70-2), gibberellic acid (CAS registry number: 77-06-5), furilazole (CAS registry number: 121776-33-8), mecamifen (CAS registry number: 129531-12-0).
The compositions of the invention can be applied by spraying to the foliage of the plants to be treated, i.e. to the weeds, in particular to surfaces which are harmful or susceptible to infestation by weeds which are harmful to the growth of the crop.
When the herbicidal composition of the present invention is applied, an unexpected synergistic effect is obtained, and the herbicidal activity is more remarkable than the expected sum of the activities using individual herbicides, and the activities of the individual herbicides alone. The synergistic effect is manifested by reduced application rates, a broader spectrum of weed control, and a faster and longer lasting herbicidal action, which are desirable in the practice of weed control. These new compositions are clearly superior to existing herbicides in terms of the properties described.
The herbicidal compositions according to the invention also have the following advantages:
(1) the composition is environment-friendly, is easy to degrade in the environment, and is suitable for various crop fields.
(2) The weeding composition has low cost and convenient use, and has great economic and social benefits when being popularized and applied.
Detailed Description
The following examples are not intended to limit the invention, but merely to illustrate how the invention may be carried out. These examples show particularly significant effectiveness against certain weeds. Examples are as follows:
A) examples of the embodiments
1. 28% of bicyclopyrone butachlor dispersible oil suspending agent (3+25)
3 percent of cyflutolrione, 25 percent of butachlor, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of nonylphenol polyoxyethylene ether, 4 percent of castor oil polyoxyethylene ether, 3.0 percent of organobentonite, 2.5 percent of fumed silica, 5 percent of No. 150 solvent oil and methyl oleate.
2. 30% Cyclopyraflutole-ethiprole suspending agent (6+24)
6 percent of bicyclopyrone, 24 percent of ethizine, 5 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2 percent of fatty alcohol polyoxyethylene ether, 0.16 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
3. 32% Cyclopyraflutole-anilofos suspoemulsion (12+20)
12% of cyflufenac, 20% of anilofos, 10% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 3% of phenethyl phenol polyoxyethylene ether, 2% of castor oil polyoxyethylene ether, 0.1% of xanthan gum, 5% of glycerol and water.
4. 18% of bicyclopyrone-dimethenamid dispersible oil suspension agent (3+15)
3% of cyflutolrione, 15% of xylenol oxamine, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica, 10% of soybean oil and methyl oleate.
5. 27% bicyclopyrone-fentrazamide suspension concentrate (12+15)
12% of cyflufenac, 15% of fentrazamide, 5% of polycarboxylate dispersant, 2% of fatty alcohol-polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
6. 29% Cyclopyraflutole-mefenacet suspension concentrate (12+17)
12% of cyflutolrione, 17% of triafamone, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.18% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
7. 27% bicyclopyrone-cafenstrole suspension (12+15)
12% of cyflufenac, 15% of cafenstrole, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.18% of xanthan gum, 1.8% of magnesium aluminum silicate, 5% of glycerol and water.
8. 28% Cyclopyraflutole-pipindoside dispersible oil suspension concentrate (3+25)
3% of bicyclopyrone, 25% of phosphorus piperate, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.2% of organobentonite, 1.2% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
9. 31% cyflufenac-metazachlor suspoemulsion (6+25)
6 percent of cyflutolrione, 25 percent of metazachlor, 20 percent of 150# solvent oil, 3 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2 percent of phenethyl phenol polyoxyethylene ether, 3 percent of castor oil polyoxyethylene ether, 0.1 percent of xanthan gum, 5 percent of glycerol and water.
10. 41% Cyclopyraflutole-propachlor suspoemulsion (3+38)
3% of bicyclopyrone, 38% of propyzamide, 10% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.08% of xanthan gum, 5% of glycerol and water.
11. 43% Cyclopyraflutole-pethoxamid suspension emulsion (3+40)
3% of cyflutolrione, 40% of dimethenamid, 15% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 3% of phenethyl phenol polyoxyethylene ether, 2% of castor oil polyoxyethylene ether, 0.04% of xanthan gum, 5% of glycerol and water.
12. 24% of bicyclopyrone-oxyfluorfen dispersible oil suspending agent (12+12)
12% of cyflufenac, 12% of oxyfluorfen, 6% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of fatty alcohol polyoxyethylene ether, 1.4% of organobentonite, 1.0% of fumed silica, 5% of soybean oil and methyl oleate.
13. 9% bicyclopyrone-fomesafen aqua (3+6)
3 percent of bicyclopyrone, 6 percent of fomesafen, 4 percent of dimethylamine, 15 percent of fatty alcohol-polyoxyethylene ether and water.
14. 52% Cyclopyraflutole-oxadiazon suspending agent (12+40)
12% of ciclopirox-fluridon, 40% of oxadiazon, 5% of polycarboxylate dispersant, 2% of naphthalenesulfonate dispersant, 2% of fatty alcohol-polyoxyethylene ether, 0.08% of xanthan gum, 1.0% of magnesium aluminum silicate, 5% of glycerol and water.
15. 18% of bicyclopyrone-oxadiargyl suspending agent (12+6)
12% of ciclopirox fluridon, 6% of oxadiargyl, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.22% of xanthan gum, 2.0% of magnesium aluminum silicate, 5% of glycerol and water.
16. 48% of bicyclopyrone-sulfentrazone suspending agent (12+36)
12 percent of cyflufenac, 36 percent of sulfentrazone, 4 percent of polycarboxylate dispersant, 1 percent of fatty alcohol-polyoxyethylene ether, 0.1 percent of xanthan gum, 1.0 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
17. 27% Cyclopyraflutole-pyraclonil suspension concentrate (12+15)
12% of bicyclopyrone, 15% of pyraclonil, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.18% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
18. 18% Cyclopyraflutole-flumioxazin dispersible oil suspending agent (12+6)
12% of cyhalofop-butyl, 6% of flumioxazin, 5% of calcium dodecyl benzene sulfonate, 7% of nonylphenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 1.5% of organobentonite, 1.2% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
19. 39% Cyclopyraflutole-pentoxazone suspending agent (12+27)
12% of ciclopirox-fluridon, 27% of cyclopentadione, 5% of polycarboxylate dispersant, 2% of fatty alcohol-polyoxyethylene ether, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 5% of glycerol and water.
20. 28% Cyclopyraflutole-tiafenacil suspension (24+4)
24% of ciclopirox-fluridon, 4% of tiafenacil, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
21. 12% bicyclopyrone and saflufenacil dispersible oil suspending agent (9+3)
9 percent of bicyclopyrone, 3 percent of saflufenacil, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of nonylphenol polyoxyethylene ether, 4 percent of castor oil polyoxyethylene ether, 3.0 percent of organobentonite, 2.5 percent of fumed silica, 10 percent of No. 150 solvent oil and methyl oleate.
22. 50% Cyclopyraflutole-atrazine suspension (12+38)
12% of bicyclopyrone, 38% of atrazine, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.07% of xanthan gum, 0.8% of magnesium aluminum silicate, 5% of glycerol and water for complement.
23. 36% Cyclopyraflutole-terbuthylazine suspension (6+30)
6 percent of bicyclopyrone, 30 percent of terbuthylazine, 5 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2 percent of fatty alcohol polyoxyethylene ether, 0.14 percent of xanthan gum, 1.5 percent of magnesium aluminum silicate, 5 percent of glycerol and water for complement.
24. 43% Cyclopyraflutole-ametryn suspension (3+40)
3% of cyflutolrione, 40% of ametryn, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
25. 53% Cyclopyraflutole-iprovalbumin suspension (3+50)
3 percent of ciclopirox-fluridon, 50 percent of iprclean, 5 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2 percent of fatty alcohol-polyoxyethylene ether, 0.06 percent of xanthan gum, 0.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
26. 53% Cyclopyraflutole-phytocide suspending agent (3+50)
3% of bicyclopyrone, 50% of fenfluramine, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.07% of xanthan gum, 0.6% of magnesium aluminum silicate, 5% of glycerol and water.
27. 44% bicyclopyrone-diuron suspending agent (6+38)
6 percent of bicyclopyrone, 38 percent of dimethomon, 5 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2 percent of fatty alcohol polyoxyethylene ether, 0.1 percent of xanthan gum, 1.0 percent of magnesium aluminum silicate, 5 percent of glycerol and water for complement.
28. 33% Cyclopyraflutole-simazine suspension (3+30)
3% of cyflutolrione, 30% of simazine, 5% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.17% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
29. 28% Cyclopyraflutole-cyanazine suspending agent (3+25)
3% of bicyclopyrone, 25% of cyanazine, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
30. 46% of bicyclopyrone-fluometuron suspension (6+40)
6 percent of bicyclopyrone, 40 percent of fluometuron, 5 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2 percent of fatty alcohol polyoxyethylene ether, 0.1 percent of xanthan gum, 1.0 percent of magnesium aluminum silicate, 5 percent of glycerol and water for complement.
31. 28% Cyclopyraflutole-linuron suspension (3+25)
3% of bicyclopyrone, 25% of linuron, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
32. 33% of bicyclopyrone-buthiuron suspension (3+30)
3% of bicyclopyrone, 30% of buthiuron, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
33. 28% Cyclopyraflutole-Shaplon suspending agent (3+25)
3% of bicyclopyrone, 25% of cypermethrin, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.18% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
34. 53% Cyclopyraflutole-chlorsulfuron suspending agent (3+50)
3% of bicyclopyrone, 50% of chlorsulfuron, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.06% of xanthan gum, 0.6% of magnesium aluminum silicate, 5% of glycerol and water.
35. 39% Cyclopyraflutole-bromogluron suspending agent (6+33)
6 percent of bicyclopyrone, 33 percent of bromouron, 5 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2 percent of fatty alcohol polyoxyethylene ether, 0.12 percent of xanthan gum, 1.2 percent of magnesium aluminum silicate, 5 percent of glycerol and water for complement.
36. 67% bicyclopyrone-cyhaloduron water dispersible granule (3+64)
3 percent of cyflutolrione, 64 percent of cyfluuron, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite are complemented.
37. 39% Cyclopyraflutole-pyridazinol suspension (6+33)
6% of cyflutolrione, 33% of pyridazinol, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.14% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
38. 41% Cyclopyraflutole-hexazinone suspending agent (3+38)
3% of cyflufenac, 38% of hexazinone, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.12% of xanthan gum, 1.2% of magnesium aluminum silicate, 5% of glycerol and water.
39. 45% bicyclopyrone-isopentyl ethyl suspension (3+42)
3 percent of bicyclopyrone, 42 percent of isoamyl detergent, 5 percent of polycarboxylate dispersant, 2 percent of fatty alcohol-polyoxyethylene ether, 0.1 percent of xanthan gum, 0.8 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
40. 43% Cyclopyraflutole-Oxydazine suspending agent (3+40)
3% of bicyclopyrone, 40% of atrazine, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.13% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
41. 60% Cyclopyraflutole-phenmedin suspension (2.25+57.75)
2.25 percent of bicyclopyrone, 57.75 percent of fluazifom, 3 percent of polycarboxylate dispersant, 1.5 percent of fatty alcohol-polyoxyethylene ether, 0.04 percent of xanthan gum, 0.4 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
42. 46% of bicyclopyrone-cyclamen suspension (6+40)
6% of cyflutolrione, 40% of cyhalofop-butyl, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.1% of xanthan gum, 0.8% of magnesium aluminum silicate, 5% of glycerol and water.
43. 63% Cyclopyraflutole-terbacil suspending agent (3+60)
3 percent of bicyclopyrone, 60 percent of terbacil, 4 percent of polycarboxylate dispersant, 2 percent of fatty alcohol-polyoxyethylene ether, 0.16 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
44. 26% cypioflutole-methabenzthiazuron suspension concentrate (12+14)
12% of cyflutolrione, 14% of metsulfuron-methyl, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.18% of xanthan gum, 1.8% of magnesium aluminum silicate, 5% of glycerol and water.
45. 63% cyflutole-cyclouron suspending agent (3+60)
3 percent of cyflutolrione, 60 percent of cyhalouron, 1.5 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2 percent of polycarboxylate dispersant, 0.04 percent of xanthan gum, 0.4 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
46. 33% Cyclopyraflutole-isoxolone suspending agent (3+33)
3% of ciclopirox-fluridon, 33% of isooxan, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
47. 70% bicyclopyrone-metoxuron water dispersible granule (3+67)
3 percent of cyflutolrione, 67 percent of metoxuron, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler bentonite are complemented.
48. 70% bicyclopyrone-cumylron water dispersible granule (3+67)
3 percent of cyflufenac, 67 percent of siduron, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
49. 14% of bicyclopyrone-pyrazosulfuron dispersible oil suspension concentrate (12+2)
12% of bicyclopyrone, 2% of pyrazosulfuron-ethyl, 5% of calcium dodecylbenzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.2% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
50. 14% Cyclopyraflutole-thiencarbazone-methyl dispersible oil suspension concentrate (12+2)
12% of cyflutolrione, 2% of thiencarbazone-methyl, 5% of calcium dodecyl benzene sulfonate, 7% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica, 5% of No. 150 solvent oil and methyl oleate.
51. 18% of bicyclopyrone-propyrisulfuron dispersible oil suspension concentrate (12+6)
12% of bicyclopyrone, 6% of propyrisulfuron, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica, 5% of No. 150 solvent oil and methyl oleate.
52. 19% Cyclopyraflutole-metazosulfuron dispersible oil-based suspension concentrate (12+7)
12% of cyflutolrione, 7% of metazosulfuron-methyl, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica, 5% of No. 150 solvent oil and methyl oleate.
53. 27% Cyclopyraflutole-rimsulfuron dispersible oil suspending agent (24+3)
24% of bicyclopyrone, 3% of rimsulfuron, 5% of calcium dodecylbenzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.2% of organobentonite, 0.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
54. 27% Cyclopyraflutole-ethoxysulfuron dispersible oil suspending agent (24+3)
24% of cyflutolrione, 3% of ethoxysulfuron, 5% of calcium dodecylbenzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.0% of organobentonite, 0.5% of fumed silica, 5% of No. 150 solvent oil and methyl oleate.
55. 17% Cyclopyraflutole-orthosulfamuron dispersible oil suspending agent (12+5)
12% of cyflutolrione, 5% of orthosulfamuron, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.5% of organobentonite, 1.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
56. 16% bicyclopyrone-nicosulfuron dispersible oil suspending agent (12+4)
12% of bicyclopyrone, 4% of nicosulfuron, 5% of calcium dodecylbenzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.5% of organobentonite, 1.5% of fumed silica, 5% of No. 150 solvent oil and methyl oleate.
57. 15% Cyclopyraflutole-foramsulfuron dispersible oil suspending agent (12+3)
12% of cyflutolrione, 3% of foramsulfuron, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.5% of organobentonite, 1.5% of fumed silica, 5% of No. 150 solvent oil and methyl oleate.
58. 29% Cyclopyraflutole-fluoroketosulam dispersible oil suspending agent (24+5)
24% of cyflutolrione, 5% of triafamone, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 0.8% of organobentonite, 10% of 150# solvent oil and methyl oleate.
59. 14% Cyclopyraflutole-penoxsulam dispersible oil suspending agent (12+2)
12 percent of cyflutolrione, 2 percent of penoxsulam, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of nonylphenol polyoxyethylene ether, 4 percent of castor oil polyoxyethylene ether, 1.8 percent of organobentonite, 1.5 percent of fumed silica, 5 percent of No. 150 solvent oil and methyl oleate.
60. 14% Cyclopyraflutole cloransulam dispersible oil suspending agent (12+2)
12% of cyflutolrione, 2% of cloransulam, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica, 5% of No. 150 solvent oil and methyl oleate.
61. 15% Cyclopyraflutole-aciclodinafop-propargyl dispersible oil suspending agent (12+3)
12% of ciclopirox-fluridon, 3% of imazamox, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.8% of organobentonite, 1.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
62. 22% Cyclopyraflutole-mebendazole nicotinic acid dispersible oil suspending agent (12+10)
12% of ciclopirox, 10% of mebendazole nicotinic acid, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.2% of organobentonite, 1.5% of fumed silica, 5% of No. 150 solvent oil and methyl oleate.
63. 19% Cyclopyraflutole-imazethapyr dispersible oil suspending agent (12+7)
12% of bicyclopyrone, 7% of imazethapyr, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 3.0% of organobentonite, 2.5% of fumed silica, 5% of No. 150 solvent oil and methyl oleate.
64. 28% Cyclopyraflutole-imazapyr aqua (3+25)
3 percent of bicyclopyrone, 25 percent of imazapyr, 12 percent of dimethylamine, 10 percent of fatty alcohol-polyoxyethylene ether and water.
65. 15% of bicyclopyrone-pyriminobac-methyl dispersible oil suspending agent (12+3)
12% of bicyclopyrone, 3% of pyriminobac-methyl, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.0% of organobentonite, 1.5% of fumed silica, 5% of No. 150 solvent oil and methyl oleate.
66. 42% Cyclopyraflutole-trifluralin suspending agent (6+36)
6 percent of bicyclopyrone, 36 percent of trifluralin, 5 percent of polycarboxylate dispersant, 2 percent of propylene glycol block polyether dispersant, 1.5 percent of fatty alcohol-polyoxyethylene ether, 0.08 percent of xanthan gum, 1.0 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
67. 33% bicyclopyrone butralin suspending agent (3+30)
3% of bicyclopyrone, 30% of butralin, 5% of polycarboxylate dispersant, 2% of propylene glycol block polyether dispersant, 1.5% of fatty alcohol-polyoxyethylene ether, 0.08% of xanthan gum, 1.0% of magnesium aluminum silicate, 5% of glycerol and water.
68. 46% Cyclopyraflutole-pendimethalin suspension (6+40)
6 percent of cyflufenac, 40 percent of pendimethalin, 5 percent of polycarboxylate dispersant, 2 percent of propylene glycol block polyether dispersant, 1.5 percent of fatty alcohol-polyoxyethylene ether, 0.08 percent of xanthan gum, 0.8 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
69. 39% Cyclopyraflutole-dimethomon suspension (3+36)
3% of ciclopirox, 36% of dimethomon, 5% of polycarboxylate dispersing agent, 2% of propylene glycol block polyether dispersing agent, 1.5% of fatty alcohol-polyoxyethylene ether, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 5% of glycerol and water.
70. 39% Cyclopyraflutole-dithiopyr suspending agent (6+33)
6 percent of ciclopirox, 33 percent of dithiopyr, 5 percent of polycarboxylate dispersant, 2 percent of propylene glycol block polyether dispersant, 1.5 percent of fatty alcohol-polyoxyethylene ether, 0.12 percent of xanthan gum, 1.2 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
71. 38% Cyclopyraflutole-ethylbutenafine suspension (3+35)
3% of cypioflutole, 35% of flutolanil, 5% of polycarboxylate dispersant, 2% of propylene glycol block polyether dispersant, 1.5% of fatty alcohol-polyoxyethylene ether, 0.12% of xanthan gum, 1.2% of magnesium aluminum silicate, 5% of glycerol and water.
72. 28% Cyclopyraflutole-amisulam suspension concentrate (3+25)
3% of ciclopirox-fluridon, 25% of oryzalin, 5% of polycarboxylate dispersant, 2% of propylene glycol block polyether dispersant, 1.5% of fatty alcohol-polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
73. 35% Cyclopyraflutole-flumioxazin suspending agent (6+29)
6 percent of cyflufenac, 29 percent of flumetsulam, 5 percent of polycarboxylate dispersant, 2 percent of propylene glycol block polyether dispersant, 1.5 percent of fatty alcohol-polyoxyethylene ether, 0.16 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
74. 39% Cyclopyraflutole-thiazopyr suspension concentrate (6+33)
6% of bicyclopyrone, 33% of thiazopyr, 5% of polycarboxylate dispersant, 2% of propylene glycol block polyether dispersant, 2% of fatty alcohol-polyoxyethylene ether, 0.18% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
75. 39% Cyclopyraflutole-Naxate suspension concentrate (6+33)
6% of bicyclopyrone, 33% of naproxen, 5% of polycarboxylate dispersant, 2% of propylene glycol block polyether dispersant, 2% of fatty alcohol-polyoxyethylene ether, 0.14% of xanthan gum, 1.2% of magnesium aluminum silicate, 5% of glycerol and water.
76. 53% Cyclopyraflutole-dichlorvos suspending agent (3+50)
3% of cypioflutole, 50% of dichlorvos, 5% of polycarboxylate dispersing agent, 2% of propylene glycol block polyether dispersing agent, 2% of fatty alcohol-polyoxyethylene ether, 0.05% of xanthan gum, 0.6% of magnesium aluminum silicate, 5% of glycerol and water.
77. 58% Cyclopyraflutole-pyrazophos suspension concentrate (3+55)
3% of bicyclopyrone, 55% of pyraflufen-ethyl, 5% of polycarboxylate dispersant, 2% of propylene glycol block polyether dispersant, 2% of fatty alcohol-polyoxyethylene ether, 0.04% of xanthan gum, 0.6% of magnesium aluminum silicate, 5% of glycerol and water.
78. 36% Cyclopyraflutole-sulcotrione suspending agent (6+30)
6 percent of bicyclopyrone, 30 percent of sulcotrione, 5 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2 percent of fatty alcohol-polyoxyethylene ether, 0.16 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
79. 21% Cyclopyraflutole-mesotrione suspension (12+9)
12% of bicyclopyrone, 9% of mesotrione, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.2% of xanthan gum, 2.0% of magnesium aluminum silicate, 5% of glycerol and water.
80. 18% Cyclopyraflutole-tembotrione suspending agent (12+6)
12% of cyflutolrione, 6% of tembotrione, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.18% of xanthan gum, 2.0% of magnesium aluminum silicate, 5% of glycerol and water.
81. 17% Cyclopyraflutole-benzofuranone suspension concentrate (12+5)
12% of bicyclopyrone, 5% of benzofuranone, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.18% of xanthan gum, 2.0% of magnesium aluminum silicate, 5% of glycerol and water.
82. 29% Cyclopyraflutole-benzobicyclon suspension (12+17)
12% of bicyclopyrone, 17% of bicyclosulfulone, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
83. 32% Cyclopyraflutole-lancotrione suspension (24+8)
24% of cypioflutole, 8% of lancotrione, 5% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
84. 11% Cyclopyraflutole-sulfonylopyrazole dispersible oil suspending agent (9+2)
9 percent of bicyclopyrone, 2 percent of sulfonylopyrazole, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of nonylphenol polyoxyethylene ether, 4 percent of castor oil polyoxyethylene ether, 2.8 percent of organobentonite, 2.8 percent of fumed silica, 5 percent of No. 150 solvent oil and methyl oleate.
85. 36% Cyclopyraflutole-pyrazole suspending agent (3+33)
3% of bicyclopyrone, 33% of pyrazolate, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.14% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
86. 33% Cyclopyraflutole-bicyclon suspending agent (3+30)
3% of bicyclopyrone, 30% of bicyclopyrone, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol-polyoxyethylene ether, 0.15% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
87. 32% Cyclopyraflutole tolpyralate suspension (12+20)
12% of bicyclopyrone, 20% of tolpyralate, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
88. 32% Cyclopyraflutole-fenquinotrione suspension (12+20)
12% of cyflufenac, 20% of fenquinotrione, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
89. 18% of bicyclopyrone-isoxaflutole suspending agent (12+6)
12% of bicyclopyrone, 6% of isoxaflutole, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.2% of xanthan gum, 1.8% of magnesium aluminum silicate, 5% of glycerol and water.
90. 31% cyflutole-fluorochloridone suspending agent (6+25)
6 percent of cyflufenac, 25 percent of flurochloridone, 5 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2 percent of fatty alcohol polyoxyethylene ether, 0.16 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
91. 22% Cycloflurtamone-flurtamone suspending agent (12+10)
12% of bicyclopyrone, 10% of flurtamone, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol-polyoxyethylene ether, 0.18% of xanthan gum, 2.0% of magnesium aluminum silicate, 5% of glycerol and water.
92. 29% Cyclopyraflutole-beflubutamid suspension (12+17)
12% of cyflufenac, 17% of beflubutamid, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.14% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
93. 40% bicyclopyrone-norflurazon suspending agent (3+37)
3% of bicyclopyrone, 37% of norflurazon, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.12% of xanthan gum, 1.2% of magnesium aluminum silicate, 5% of glycerol and water.
94. 52% bicyclopyrone-fluridone water dispersible granule (2+50)
2 percent of cyflutolrione, 50 percent of fluridone, 10 percent of polycarboxylate dispersant, 4 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 30 percent of precipitated white carbon black and filler diatomite are complemented.
95. 49% Cyclopyraflutole-clomazone suspension emulsion (6+43)
6 percent of bicyclopyrone, 43 percent of clomazone, 5 percent of 150# solvent oil, 3 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of phenethyl phenol polyoxyethylene ether, 3 percent of castor oil polyoxyethylene ether, 0.1 percent of xanthan gum, 5 percent of glycerol and water.
96. 53% Cyclopyraflutole-molinate suspoemulsion (3+50)
3% of cyflutolrione, 50% of molinate, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.06% of xanthan gum, 5% of glycerol and water.
97. 53% Cycloflurtamone-Hecaodan suspoemulsion (3+50)
3 percent of cyflutolrione, 50 percent of thiobencarb, 3 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of phenethyl phenol polyoxyethylene ether, 3 percent of castor oil polyoxyethylene ether, 0.05 percent of xanthan gum, 5 percent of glycerol and water.
98. 50% Cyclopyraflutole-furametpyr suspoemulsion (3+47)
3% of cyflutolrione, 47% of furbenoxa, 8% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.07% of xanthan gum, 5% of glycerol and water.
99. 30% Cyclopyraflutole-ethoxyfurazone suspension emulsion (3+27)
3 percent of cyflutolrione, 27 percent of ethofumesate, 10 percent of 150# solvent oil, 3 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of phenethyl phenol polyoxyethylene ether, 3 percent of castor oil polyoxyethylene ether, 0.1 percent of xanthan gum, 5 percent of glycerol and water.
100. 28% Cyclopyraflutole-triallate suspoemulsion (3+25)
3% of bicyclopyrone, 25% of triallate, 10% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.1% of xanthan gum, 5% of glycerol and water.
101. 35% Cyclopyraflutole-prosulfocarb suspoemulsion (3+32)
3% of bicyclopyrone, 32% of prosulfocarb, 8% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.1% of xanthan gum, 5% of glycerol and water.
102. 61% Cyclopyraflutole-molinate suspoemulsion (3+58)
3% of cyflutolrione, 58% of dichlorflufen, 3% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1% of phenethylphenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.04% of xanthan gum, 5% of glycerol and water.
103. 32% Cyclopyraflutole-butantte suspoemulsion (12+20)
12% of bicyclopyrone, 20% of butantp, 10% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.12% of xanthan gum, 5% of glycerol and water. 104. 32% Cyclopyraflutole-Cyclinide suspoemulsion (12+20)
12% of bicyclopyrone, 20% of cyhalofop-butyl, 10% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.12% of xanthan gum, 5% of glycerol and water. 105. 36% Cyclopyraflutole-pipindone suspension emulsion (3+33)
3% of bicyclopyrone, 33% of pipindone, 6% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.1% of xanthan gum, 5% of glycerol and water.
106. 35% Cyclopyraflutole-penfludol suspension emulsion (1.5+33.5)
1.5 percent of bicyclopyrone, 33.5 percent of penflufen, 6 percent of 150# solvent oil, 3 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2 percent of phenethyl phenol polyoxyethylene ether, 3 percent of castor oil polyoxyethylene ether, 0.1 percent of xanthan gum, 5 percent of glycerol and water.
107. 21% bicyclopyrone-quinclorac aqua (6+15)
6 percent of bicyclopyrone, 15 percent of quinclorac, 15 percent of monoisopropylamine, 10 percent of fatty alcohol-polyoxyethylene ether, 20 percent of glycol and water.
108. 30% Cyclopyraflutole clocloquintocet acid water suspending agent (12+18)
12% of ciclopirox fluridon, 18% of clomazone, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
109. 13% Cyclopyraflutole-oxaziclomefone suspending agent (9+4)
9% of bicyclopyrone, 4% of oxaziclomefone, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol-polyoxyethylene ether, 0.22% of xanthan gum, 1.8% of magnesium aluminum silicate, 5% of glycerol and water.
110. 28% Cyclopyraflutole-cinmethylin suspension concentrate (24+4)
24% of bicyclopyrone, 4% of cycloheptane ether, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.4% of magnesium aluminum silicate, 5% of glycerol and water for complement.
111. 38% of bicyclopyrone-phosphinothricin aqua (1.5+36.5)
1.5 percent of bicyclopyrone, 36.5 percent of phosphinothricin, 0.5 percent of dimethylamine, 15 percent of alkyl polyglycoside and water.
112. 30% bicyclopyrone-bialaphos aqua (2.25+27.75)
2.25 percent of bicyclopyrone, 27.75 percent of bialaphos, 1.2 percent of dimethylamine, 15 percent of fatty alcohol-polyoxyethylene ether and water.
113. 35% of bicyclopyrone-glufosinate-ammonium aqua (4.5+30.5)
4.5 percent of cyflutolrione, 30.5 percent of refined glufosinate, 5 percent of dimethylamine, 15 percent of alkyl polyglycoside and water.
114. 45% bicyclopyrone paraquat water agent (4.5+40.5)
4.5 percent of bicyclopyrone, 40.5 percent of paraquat, 5 percent of dimethylamine, 15 percent of alkyl polyglycoside and water.
115. 40% bicyclopyrone diquat aqua (4.5+35.5)
4.5 percent of bicyclopyrone, 35.5 percent of diquat, 5 percent of dimethylamine, 15 percent of alkyl polyglycoside and water.
116. 55% bicyclopyrone-asulam aqua (2.25+52.75)
2.25 percent of bicyclopyrone, 52.75 percent of asulam, 1.5 percent of dimethylamine, 10 percent of fatty alcohol-polyoxyethylene ether and water.
117. 37% of bicyclopyrone-simetryn suspending agent (6+31)
6 percent of bicyclopyrone, 31 percent of simetryn, 5 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2 percent of fatty alcohol polyoxyethylene ether, 0.12 percent of xanthan gum, 1.4 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
118. 33% Cyclopyraflutole-amicarbazone suspending agent (12+21)
12% of bicyclopyrone, 21% of amicarbazone, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.14% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
119. 60% bicyclopyrone-metamitron water dispersible granule (2+58)
2 percent of cyflutolanil, 58 percent of metamitron, 10 percent of polycarboxylate dispersant, 4 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 30 percent of precipitation white carbon black and filler diatomite are complemented.
120. 36% bicyclopyrone diuron suspending agent (6+30)
6 percent of bicyclopyrone, 30 percent of diuron, 5 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2 percent of fatty alcohol polyoxyethylene ether, 0.12 percent of xanthan gum, 1.4 percent of magnesium aluminum silicate, 5 percent of glycerol and water for complement.
121. 26% Cyclopyribenzone cycloprominate suspension (9+17)
9 percent of ciclopirox-fluridon, 17 percent of cyclopyromate, 5 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2 percent of fatty alcohol polyoxyethylene ether, 0.15 percent of xanthan gum, 1.6 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
122. 50% of bicyclopyrone and pyridate dispersible oil suspending agent (4.5+44.5)
4.5 percent of bicyclopyrone, 44.5 percent of pyridate, 5 percent of calcium dodecyl benzene sulfonate, 8 percent of nonylphenol polyoxyethylene ether, 6 percent of castor oil polyoxyethylene ether, 2.8 percent of organic bentonite, 2.5 percent of fumed silica, 15 percent of No. 150 solvent oil and methyl oleate.
123. 36% Cyclopyraflutole-betaine suspension concentrate (4.5+31.5)
4.5 percent of bicyclopyrone, 31.5 percent of betaine, 5 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2 percent of fatty alcohol polyoxyethylene ether, 0.12 percent of xanthan gum, 1.2 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
124. 36% Cyclopyraflutole-betanin suspending agent (4.5+31.5)
4.5 percent of bicyclopyrone, 31.5 percent of betanin, 5 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2 percent of fatty alcohol polyoxyethylene ether, 0.12 percent of xanthan gum, 1.2 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
The processing equipment of the aqueous suspending agent comprises a mixing kettle, a colloid mill, a sand mill, a shearing machine and the like.
The processing process of the aqueous suspension agent comprises the steps of putting all materials into a mixing kettle, stirring and mixing the materials, passing the materials through a colloid mill, then entering a sand mill for three-stage sanding, finally uniformly shearing the materials in a shearing machine, transferring the materials to a storage tank for filling after the materials are qualified in test.
The processing equipment of the dispersible oil suspending agent comprises a mixing kettle, a colloid mill, a sand mill, a shearing machine and the like.
The dispersible oil suspending agent is prepared by putting all materials into a mixing kettle, stirring and mixing, passing through a colloid mill, entering a sand mill for three-stage sanding, finally shearing uniformly in a shearing machine, transferring to a storage tank for filling after passing the assay.
The water aqua processing equipment comprises a mixing kettle, a shearing machine and the like.
The water aqua producing process includes mixing all the materials in a material mixing kettle, shearing in a shearing machine to form transparent liquid, testing and packing in a storage tank.
The water dispersible granule processing equipment comprises an air flow crusher, a colter type mixer, a basket type granulator, a drying box, a sieving machine and the like.
The water dispersible granule is prepared by uniformly mixing the materials, crushing the materials by airflow, adding water, kneading, granulating, drying and finally screening to obtain a finished product.
The above-mentioned suspension emulsion preparation equipment includes mixing kettle, colloid mill, sand mill and shearing machine.
The suspension emulsion is prepared by adding water phase material into a mixing kettle, stirring, grinding with colloid mill, grinding with sand mill for three-stage grinding, shearing uniformly in shearing machine, and transferring after qualified test; putting the oil phase material into a mixing kettle, adding solvent oil and an emulsifier, and stirring and dissolving uniformly; and then adding the water-phase material into a shearing kettle, slowly pumping the oil-phase material into the shearing kettle in a shearing state, pumping the material while shearing, continuously and uniformly shearing, transferring to a storage tank for filling after the test is qualified.
B) Test of drug efficacy
Spraying stem leaves after seedling:
1) test conditions
1.1) test target
The Japanese Aleurea victoria is collected from Jiangsu Xinghua, the Aleurea muscipula is collected from Shandong Taian, the weeds are cultured by a pot culture method, a plastic nutrition pot with the diameter of 180 х 140mm is used for placing in an enamel tray, surface soil (4/5) which is collected from a farmland and is air-dried and sieved is filled in the pot, the soil humidity is controlled to be 20 percent at the initial stage, weed seeds with full and uniform seeds are selected, the weed seeds are soaked for 6 hours in warm water with the temperature of 25 ℃, germination is accelerated in a biochemical incubator (dark) with the temperature of 28 ℃, the weed seeds which just expose white are evenly placed on the soil surface, and the soil is covered for 0.5-1cm according to the particle size of the seeds.
1.2) culture conditions
The method is carried out in a controllable sunlight greenhouse, the temperature is 20-30 ℃, the natural illumination is carried out, and the relative humidity is 57-72%. The soil type is loam, the organic matter content is 1.63%, the pH value is 7.1, the alkaline hydrolysis nitrogen is 84.3mg/kg, the quick-acting phosphorus is 38.5mg/kg, and the quick-acting potassium is 82.1 mg/kg.
1.3) instrumentation
3WP-2000 model walking spray tower, Minn Jing agricultural machinery research institute of agricultural department. Ten thousandth electronic balance type GA10 (germany); ZDR2000 intelligent data recorder (hangzhou ze large instruments ltd); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument factory).
2) Design of experiments
2.1), reagents
The desired active ingredient B was purchased from a reagent company and A was produced by this company.
The raw medicines are all diluted by using acetone as a solvent and using an emulsifier Tween-80 aqueous solution with the content of 0.1 percent as the existing dilution.
2.2) test treatment
2.2.1), dose setting
When determining the ratio or content of the component A and the component B, the main use purpose of the formula is also considered according to the action characteristics of the two medicaments and the measurement of toxicity and the like. On the basis of the preliminary experiments, A, B is respectively used for the single active ingredient and the mixed dosage in a table. Water without drug, containing the same solvent and emulsifier was used as a blank.
2.2.2), test repetition
Each treatment was repeated 4 times, 3 pots each time, 20 weed seeds were sown per pot, 60 plants each time.
2.3) treatment method
2.3.1), treatment time and number of times
The test was performed 1 time in total. And (3) thinning after the 2-leaf period of the weeds, keeping 15 plants of the weeds in each pot, keeping 45 plants in each treatment, and then continuously culturing until 1 heart of 3 leaves of the physalis alkekengi and 3 leaves of the physalis pubescens are treated.
2.3.2), instruments and methods of use
Uniformly placing the cultured test material on a 0.5m area2Spraying stem and leaf with 3WP-2000 model walking spraying tower in 30 kg/ha amount. The spraying pressure is 0.3 MPa. And after all the liquid medicine is sprayed, closing the air valve, opening the spraying tower door after 30 seconds, and taking out the nutrition pot. Then the air valve is opened, 50mL of clean water is sprayed, and the liquid spraying pipe is cleaned.
3) Test method
The potting method is adopted. The weed cultivation is carried out according to 1.1 and the standard herbicide for indoor bioassay of pesticides. The application method is 2.3.2, and stem and leaf treatment method is adopted. After treatment, the cells were transferred to a greenhouse for conventional culture, and a 1-2cm water layer was maintained throughout the experiment.
4) Data survey and statistical analysis
4.1) investigation method
The complete survival weed seedlings are cut off along the soil surface by a blade by adopting an absolute number survey method, and the fresh weight of the weeds is weighed by an analytical balance. For the weeds that have died, the fresh weight is zero.
4.2), investigation time and number of surveys
The investigation was carried out 20 days after the treatment, and the total number of the investigations was 1.
4.3), statistical analysis of data
The theoretical fresh weight inhibition rate (E0 ═ X + Y-X Y/100) of each treatment mixed combination is calculated by a Gowing method, and then compared with the actually measured inhibition rate (E), the combined action type of the two mixed combinations on the weeds is evaluated, and when the E-E0 value is more than 10 percent, the effect is synergistic, when the E-E0 value is less than-10 percent, the effect is antagonistic, and when the E-E0 value is between-10 percent and 10 percent, the effect is additive. And the optimal proportion is determined according to factors such as actual control effect, characteristics of the herbicide, balance of the formula and the like. Wherein X is the fresh weight inhibition rate when the dosage of the active component A is P; y is the fresh weight inhibition rate of the active component B when the dosage is Q.
Soil sealing treatment:
1) test conditions
1.1) test targets
Japanese Aleurites communis and Stellaria procumbens are collected from Jiangsu Xinghua, and Tankia songarica is collected from Shandong Taian.
1.2) culture conditions
The method is carried out in a controllable sunlight greenhouse, the temperature is 20-30 ℃, the natural illumination is carried out, and the relative humidity is 57-72%. The soil type is loam, the organic matter content is 1.63%, the pH value is 7.1, the alkaline hydrolysis nitrogen is 84.3mg/kg, the quick-acting phosphorus is 38.5mg/kg, and the quick-acting potassium is 82.1 mg/kg. The test soil was quantitatively loaded at 3/4 points of the pot and then poured from the bottom of the pot to completely wet the soil to saturation. Uniformly and quantitatively broadcasting the pretreated weed seeds to be tested on the surface, covering soil of 0.5-2cm according to the size of the seeds, and reserving the weed seeds for 24 hours after sowing.
1.3), instrumentation
A ten thousandth electronic balance (germany) type GA 10; ZDR2000 intelligent data recorder (hangzhou ze large instruments ltd); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument plant), pipettor and the like.
2) Design of experiments
2.1), reagents
The required active ingredients B are all commercial raw medicaments, and A is produced by the company.
The raw medicines are all diluted by using acetone as a solvent and using an emulsifier T-80 aqueous solution with the content of 0.1 percent as the current use.
2.2) test treatment
2.2.1), dose setting
When determining the ratio or content of the components A and the active component B, the main purpose of the formula should be considered in consideration of the action characteristics of the two medicaments and the toxicity thereof. On the basis of preliminary experiments, A, B active ingredients are respectively used singly and mixed in different amounts. Water without drug, containing the same solvent and emulsifier was used as a blank.
2.2.2), test repetition
Each treatment was repeated 4 times, 3 pots each time, and 30 weed seeds were sown in each pot.
2) Test method
Before treatment, the mixture was irrigated and a 1-2cm aqueous layer was maintained. Taking quantitative liquid medicine by a pipettor, and respectively carrying out irrigation treatment from low dosage to high dosage according to experimental design, wherein the treatment is repeated for 4 times each time; after treatment, the cells were transferred to a greenhouse for conventional culture, and a 1-2cm water layer was maintained throughout the test period.
3) Data investigation and statistical analysis
The spray treatment is the same as the spray treatment of the stem leaves after seedling, so the detailed description is omitted.
The statistical results are shown in tables 1-125 below.
TABLE 1 evaluation of the actual control and combination of the mixtures of butachlor and butachlor for Japanese rye
Figure BDA0002991828280000221
Table 2A evaluation of the actual control and combination of the Equisetum sophia (soil treatment) with the mixture of Equisetum
Figure BDA0002991828280000222
Table 3A evaluation of the actual control and combination of action (soil treatment) of the combination of anilofos with Aleurea japonica
Figure BDA0002991828280000223
Figure BDA0002991828280000231
Table 4A evaluation of actual control and combination of the Nissan Amur with dimethenamid (soil treatment)
Figure BDA0002991828280000232
Table 5A evaluation of the actual controlling effect and the combined action of the mixture of tetrazolyl oxamide on Nissan-Beech-Amur (soil treatment)
Figure BDA0002991828280000233
Table 6A evaluation of the actual controlling effect and the combined action of the mixture of tolfenugreek and triazacyclomide on Nissan-Beauveria-Temporaria (soil treatment)
Figure BDA0002991828280000234
Table 7A evaluation of the actual controlling effect and the combined action of the mixture of tolfentrazuril and metolachlor on Japanese wheat straw
Figure BDA0002991828280000241
Table 8A evaluation of actual controlling effect and combined action of blending with pipate on Nissan wheat straw (soil treatment)
Figure BDA0002991828280000242
Table 9A evaluation of the actual controlling effect and the combined action of the mixed pair of pyraflufen and alopecurus japonicus (soil treatment)
Figure BDA0002991828280000243
TABLE 10 evaluation of the actual control and combination of the phytoalexin combination with Chlorpyrim (soil treatment)
Figure BDA0002991828280000244
Figure BDA0002991828280000251
Table 11A evaluation of the actual control and combination of the incorporation of dimethenamid into Japanese rye (soil treatment)
Figure BDA0002991828280000252
Table 12A evaluation of the actual control and combination of descurainia sophia (soil treatment) with oxyfluorfen
Figure BDA0002991828280000253
TABLE 13 evaluation of the actual control and combination of descurainia sophia (soil treatment) by combining fomesafen with Fomesafen
Figure BDA0002991828280000254
TABLE 14 evaluation of the actual control and combination of descurainia sophia (soil treatment) with oxadiazon
Figure BDA0002991828280000255
Table 15A evaluation of the actual control and combination of the effects of descurainia sophia mixed with oxadiargyl (soil treatment)
Figure BDA0002991828280000261
TABLE 16 evaluation of the actual control and combination of descurainia sophia (soil treatment) by mixing with sulfentrazone
Figure BDA0002991828280000262
TABLE 17 evaluation of actual control and combination of Bixapyroxad and descurainia sophia (soil treatment)
Figure BDA0002991828280000263
Table 18A evaluation of the actual control and combination of descurainia sophia (soil treatment) with flumioxazin
Figure BDA0002991828280000264
TABLE 19A evaluation of the actual control and Combined action of the combination of pentoxazone with descurainia sophia (soil treatment)
Figure BDA0002991828280000271
TABLE 20 evaluation of the actual control and Combined action of the blend of Tiafenac with tara
Figure BDA0002991828280000272
TABLE 21 evaluation of the actual control and combination of descurainia sophia (Stem and leaf treatment) with saflufenacil
Figure BDA0002991828280000273
TABLE 22 evaluation of actual control and Combined action of tarragon with atrazine combination (soil treatment)
Figure BDA0002991828280000274
TABLE 23 evaluation of actual control and combination of descurainia sophia (soil treatment) by combination of Tedingjin and Tanzhijin
Figure BDA0002991828280000275
Figure BDA0002991828280000281
TABLE 24 evaluation of the actual control and Combined action of descurainia sophia in combination with ametryn (soil treatment)
Figure BDA0002991828280000282
TABLE 25 evaluation of actual control and combination of the combination of isoproturon and isoproturon (soil treatment)
Figure BDA0002991828280000283
TABLE 26 evaluation of actual control and combined action of blending with fenugreek (soil treatment)
Figure BDA0002991828280000284
TABLE 27 evaluation of actual control and combination of descurainia sophia (soil treatment) by mixing and pairing with Diphenyl
Figure BDA0002991828280000285
Figure BDA0002991828280000291
TABLE 28 evaluation of actual control and combination of the combination of Ximajin with descurainia sophia (soil treatment)
Figure BDA0002991828280000292
TABLE 29 evaluation of actual control and Combined action of descurainia sophia (soil treatment) with Cyhalozine
Figure BDA0002991828280000293
TABLE 30 evaluation of actual control and combination of descurainia sophia (soil treatment) by mixing and pairing with Fluoruron
Figure BDA0002991828280000294
TABLE 31 evaluation of actual control and combination of mulukhiya with mix of Rigulong (soil treatment)
Figure BDA0002991828280000295
Figure BDA0002991828280000301
TABLE 32 evaluation of actual control and Combined action of Thidiazuron and tarragon
Figure BDA0002991828280000302
TABLE 33 evaluation of actual control and combination of the combination of Shaplong and ground for the sowing of Polygala crotalarioides (soil treatment)
Figure BDA0002991828280000303
TABLE 34 evaluation of actual control and combination of descurainia sophia by mixing with Lugulong (soil treatment)
Figure BDA0002991828280000304
TABLE 35A evaluation of actual control and Combined action of descurainia sophia in combination with bromuron (soil treatment)
Figure BDA0002991828280000305
Figure BDA0002991828280000311
TABLE 36 evaluation of the actual control and Combined action of descurainia sophia (soil treatment) with the Robusta indica mixture
Figure BDA0002991828280000312
TABLE 37 evaluation of actual control and combination of Polygala sonchifolia with Pyridazinol (soil treatment)
Figure BDA0002991828280000313
TABLE 38 evaluation of actual control and combination of descurainia sophia (soil treatment) by blending and pairing with hexazinone
Figure BDA0002991828280000314
TABLE 39A evaluation of the actual control and combination of the combination with isopentyl and the combination of the combination with descurainia sophia (soil treatment)
Figure BDA0002991828280000315
Figure BDA0002991828280000321
TABLE 40 evaluation of actual control and Combined action of descurainia sophia (soil treatment) by mixing and pairing with Cadajin
Figure BDA0002991828280000322
TABLE 41 evaluation of actual control and combination of descurainia sophia (stem and leaf treatment)
Figure BDA0002991828280000323
TABLE 42 evaluation of actual control and combination of descurainia sophia (soil treatment) by blending with lenacil
Figure BDA0002991828280000324
TABLE 43 evaluation of actual control and Combined action of descurainia sophia mixed with triclopyr (soil treatment)
Figure BDA0002991828280000325
Figure BDA0002991828280000331
TABLE 44 evaluation of actual control and combination of the Miao Polygala combined with methabenzthiazuron (soil treatment)
Figure BDA0002991828280000332
TABLE 45 evaluation of actual control and combination of descurainia sophia (soil treatment) by blending with Cycloduron
Figure BDA0002991828280000333
TABLE 46 evaluation of actual control and combination of descurainia sophia (soil treatment) by blending with Isoxon
Figure BDA0002991828280000334
TABLE 47 evaluation of the actual control and combination of the compounding of Methylon and metoprolol on the sowing of Polygala crotalarioides (soil treatment)
Figure BDA0002991828280000335
TABLE 48 evaluation of actual control and combination of the combination of Kunlong and Kunlong for mule-stropharia
Figure BDA0002991828280000336
Figure BDA0002991828280000341
Table 49A evaluation of actual control and combination of descurainia sophia (soil treatment) with pyrazosulfuron-ethyl
Figure BDA0002991828280000342
TABLE 50 evaluation of actual control and combination of Thidiazuron and Thidiazuron on mulches
Figure BDA0002991828280000343
TABLE 51 evaluation of actual control and combination of promethasulfuron and descurainia sophia (soil treatment)
Figure BDA0002991828280000344
TABLE 52 evaluation of actual control and combination of the Oxyus sieboldii in combination with metazosulfuron
Figure BDA0002991828280000345
TABLE 53 evaluation of actual control and combination of Polygala sonchifolia with rimsulfuron
Figure BDA0002991828280000351
TABLE 54 evaluation of actual control and combination of descurainia sophia (soil treatment) by blending with Ethoxysulfuron
Figure BDA0002991828280000352
TABLE 55 evaluation of actual control and combination of Michialone for mulcher (soil treatment)
Figure BDA0002991828280000353
TABLE 56 evaluation of actual control and combination of Miannianghao (soil treatment) with nicosulfuron
Figure BDA0002991828280000354
TABLE 57 evaluation of actual controlling effect and Combined action of compounding with foramsulfuron on descurainia sophia (soil treatment)
Figure BDA0002991828280000355
TABLE 58A evaluation of the actual control and Combined action of the combination of Fondamide and Fluoroncarbazide (soil treatment)
Figure BDA0002991828280000356
Figure BDA0002991828280000361
Table 59A evaluation of actual control and combination of Polygala crotalarioides with penoxsulam (soil treatment)
Figure BDA0002991828280000362
TABLE 60 evaluation of the actual control and combination of the combination of cloransulam-methyl with the evaluation of the actual control and combination of the action of descurainia sophia (soil treatment)
Figure BDA0002991828280000363
Table 61A shows the evaluation of the actual control and the combined action of the Achillea alpina mixed with imazamox (soil treatment)
Figure BDA0002991828280000364
TABLE 62 evaluation of the actual control and Combined action of the combination of Emamectin benzoate and Aconitum Carpesii (soil treatment)
Figure BDA0002991828280000365
TABLE 63 evaluation of the actual control and combination of the combination of imazethapyr and imazethapyr (soil treatment)
Figure BDA0002991828280000371
TABLE 64A evaluation of the actual control and combination of descurainia sophia (soil treatment)
Figure BDA0002991828280000372
TABLE 65A evaluation of the actual control and combination of the Acronychia sophila Roxburgh with pyriminobac-methyl (soil treatment)
Figure BDA0002991828280000373
TABLE 66 evaluation of actual control and combination of the combination of trifluralin and Nissan Daimai (soil treatment)
Figure BDA0002991828280000374
TABLE 67 actual prevention and combination evaluation of the blending of butralin and butralin for Nissan wheat straw rope (soil treatment)
Figure BDA0002991828280000375
Figure BDA0002991828280000381
TABLE 68 evaluation of the actual control and Combined action of the mixture of pendimethalin and Dipendimethalin on Nissan foxtail (soil treatment)
Figure BDA0002991828280000382
TABLE 69 evaluation of actual control and combination of Dilleamine and Korea David (soil treatment)
Figure BDA0002991828280000383
TABLE 70 evaluation of the actual control and Combined action of the blending of dithiopyr with Nissan wheat straw (soil treatment)
Figure BDA0002991828280000384
TABLE 71 evaluation of actual control and combination of the combination of Ebenefalin and Fluoron (soil treatment)
Figure BDA0002991828280000391
TABLE 72 evaluation of actual control and combination of Nissan wheat-beauty with amisular mixture (soil treatment)
Figure BDA0002991828280000392
TABLE 73 evaluation of the actual control and combination of the mixtures of flumetsulam with Japanese rye grass (soil treatment)
Figure BDA0002991828280000393
TABLE 74 evaluation of actual control and combination of the combination of Thiacloprid and Thiacloprid (soil treatment)
Figure BDA0002991828280000394
Figure BDA0002991828280000401
TABLE 75 evaluation of actual control and Combined action of Nissan wheat straw (soil treatment) by blending with Naxate
Figure BDA0002991828280000402
TABLE 76 evaluation of actual control and Combined action of blending with chlorthal on Nissan wheat (soil treatment)
Figure BDA0002991828280000403
TABLE 77 evaluation of actual control and combination of the herbicide and phytol-P mixture for Nissan wheat
Figure BDA0002991828280000404
TABLE 78 evaluation of actual control and Combined action of the Paecilomyces japonica in combination with sulcotrione (soil treatment)
Figure BDA0002991828280000405
TABLE 79 evaluation of actual control and combination of Michialone and mesotrione on mullein (soil treatment)
Figure BDA0002991828280000411
TABLE 80 evaluation of actual control and combination of the combination of Cyclosultone and Tanshinon (soil treatment)
Figure BDA0002991828280000412
TABLE 81 evaluation of the actual control and Combined action of the combination of Fusulone and Polygala sonchifolia (soil treatment)
Figure BDA0002991828280000413
TABLE 82 evaluation of the actual control and Combined action of the combination of Doremone grass with Doremone
Figure BDA0002991828280000414
TABLE 83 evaluation of actual control and combination of Lancotrione in combination with Lancotrione for mullein (soil treatment)
Figure BDA0002991828280000421
TABLE 84A evaluation of actual control and Combined action of a mixture of Sulfolfen-pyrazole and Acronychia sophera (Stem and leaf treatment)
Figure BDA0002991828280000422
TABLE 85 evaluation of actual control and combination of descurainia sophia (soil treatment)
Figure BDA0002991828280000423
TABLE 86 evaluation of actual control and Combined action of Bicotrione-Bicotrione mixture on descurainia sophia (soil treatment)
Figure BDA0002991828280000424
TABLE 87 evaluation of actual control and Combined action of tarcuraina sophia mixed with tolpyralate (soil treatment)
Figure BDA0002991828280000425
Figure BDA0002991828280000431
TABLE 88A evaluation of the actual control and Combined action of fenquinotrione in combination with descurainia sophia (soil treatment)
Figure BDA0002991828280000432
TABLE 89 evaluation of the actual control and Combined action of isoxaflutole in combination with descurainia sophia (soil treatment)
Figure BDA0002991828280000433
TABLE 90A evaluation of the actual control and Combined action of descurainia sophia mixed with flurochloridone (soil treatment)
Figure BDA0002991828280000434
TABLE 91A evaluation of the actual control and Combined action of descurainia sophia mixed with flurtamone (soil treatment)
Figure BDA0002991828280000441
TABLE 92 evaluation of the actual control and combination of descurainia sophia (soil treatment) with beflubutamid
Figure BDA0002991828280000442
TABLE 93 evaluation of actual control and Combined action of descurainia sophia mixed with norflurazon (soil treatment)
Figure BDA0002991828280000443
TABLE 94 evaluation of the actual control and combination of descurainia sophia (soil treatment) by combination of Scutellaria baicalensis Georgi and Scutellaria baicalensis Georgi
Figure BDA0002991828280000444
TABLE 95 evaluation of actual control and combination of the action of clomazone and clomazone in combination (soil treatment)
Figure BDA0002991828280000445
Figure BDA0002991828280000451
TABLE 96 evaluation of actual control and combination of the blending of molinate and Nissan wheat
Figure BDA0002991828280000452
TABLE 97 evaluation of the actual control and combination of the blending of Dolabella foenum-graecum with Hecaodan (soil treatment)
Figure BDA0002991828280000453
TABLE 98A evaluation of the actual control and combination of the mixes with Fucao yellow on Nissan Daimai (soil treatment)
Figure BDA0002991828280000454
TABLE 99A evaluation of the actual control and combination of the Oxyflower Florida and the combination of the Oxyflower Florida with the evaluation of the actual control and combination of the descurainia sophia (Stem and leaf treatment)
Figure BDA0002991828280000455
TABLE 100 evaluation of the actual control and Combined action of the combination of Michelia Nigri with Dicamba (soil treatment)
Figure BDA0002991828280000456
Figure BDA0002991828280000461
TABLE 101A evaluation of the actual control and combined action of the Nissan wheat straw-stalk blends with the herbicide
Figure BDA0002991828280000462
TABLE 102A evaluation of actual control and combined action of mixed phytocide on Nissan wheat straw
Figure BDA0002991828280000463
TABLE 103 evaluation of actual control and combination of Dingcao and Dingcao mixture for Nissan wheat straw rope (soil treatment)
Figure BDA0002991828280000464
TABLE 104 evaluation of actual control and combination of environmental control of Nissan wheat straw for Nissan wheat straw (soil treatment)
Figure BDA0002991828280000465
Figure BDA0002991828280000471
TABLE 105 evaluation of actual control and Combined action of the mixture of pipindone and pipindone on Nissan wheat
Figure BDA0002991828280000472
TABLE 106 evaluation of actual control and combination of the combination of penflufen and penflufen on Nissan wheat
Figure BDA0002991828280000473
TABLE 107A evaluation of actual control and Combined action of Caragana dichlorica in combination with Quinclorac (soil treatment)
Figure BDA0002991828280000474
Table 108A evaluation of actual control and Combined action of Michelia sophia when it was mixed with chloroquinolinic acid (Stem and leaf treatment)
Figure BDA0002991828280000475
TABLE 109A evaluation of the actual control and Combined action of the oxaziclomefone-clomefone mixture (Stem and leaf treatment)
Figure BDA0002991828280000481
TABLE 110 evaluation of the actual control and combination of the combination of Bispberry and cinmethylin (soil treatment)
Figure BDA0002991828280000482
TABLE 111 evaluation of actual control and Combined action of descurainia sophia (Stem and leaf treatment) with the combination of Sulfothiaphosphine
Figure BDA0002991828280000483
TABLE 112 evaluation of the actual control and combination of the combination of Bialanylphosphine and Descurainia sophia (Stem and leaf treatment)
Figure BDA0002991828280000484
TABLE 113 evaluation of actual prevention and combination of descurainia sophia (stem and leaf treatment) with glufosinate-ammonium
Figure BDA0002991828280000485
TABLE 114 evaluation of actual control and combination of descurainia sophia (stem and leaf treatment) by blending with Paraquat
Figure BDA0002991828280000491
TABLE 115A evaluation of actual control and Combined action of descurainia sophia in combination with diquat (Stem and leaf treatment)
Figure BDA0002991828280000492
TABLE 116A evaluation of the actual control and combination of the Nissan Amur by blending with asulam (stem and leaf treatment)
Figure BDA0002991828280000493
TABLE 117A evaluation of actual control and combination of descurainia sophia (soil treatment) with Simplex combination of West grass
Figure BDA0002991828280000494
TABLE 118A evaluation of the actual control and Combined action of the amicarbazone-pair descurainia (soil treatment)
Figure BDA0002991828280000495
Figure BDA0002991828280000501
TABLE 119A evaluation of the actual control and combined action of the combination of metamitron and flixweed (soil treatment)
Figure BDA0002991828280000502
Table 120A evaluation of actual control and combination of descurainia sophia (soil treatment)
Figure BDA0002991828280000503
Table 121A evaluation of the actual control and Combined action of Artemisia scoparia mixed with cyclopyrinate (stem leaf treatment)
Figure BDA0002991828280000504
TABLE 122A evaluation of the actual control and combination of DAKOUTE with DAGAO (stem and leaf treatment)
Figure BDA0002991828280000505
Figure BDA0002991828280000511
TABLE 123A evaluation of the actual control and combination of Bian-bang for descurainia sophia (stem and leaf treatment)
Figure BDA0002991828280000512
TABLE 124A evaluation of actual control and combination of descurainia sophia (stem and leaf treatment)
Figure BDA0002991828280000513
C) Demonstration of field
The herbicidal compositions prepared in examples 1) to 124) were used for field weed effect tests.
An exemplary popularization test was performed in the test point of the Kyoho chemical industry in 2016. The weeds in the fields mainly comprise shepherd's purse, chickweed, speedwell, cleavers, alopecurus japonicus, alopecurus, beckmannia syzigachne and the like.
The test method comprises the following steps:
soil treatment, before weed germination, a manual sprayer is used for adding water with the amount of 45 kg/667 m2The soil surface is uniformly sprayed.
Treating stems and leaves, namely, after the weeds are in the 3-4 leaf stage, manually spraying the weeds with a sprayer, and adding 30 kg of water per 667m2The stem and leaf are sprayed evenly.
The details of the test agents and doses are shown in table 125, with a cell area of 50 square meters, repeated 4 times per treatment. The control effect 45 days after application is shown in Table 125.
Figure BDA0002991828280000521
Through a large number of tests and explorations, the invention unexpectedly discovers that the composition is used for preventing and killing weeds such as capsella bursa-pastoris, caraway bulrush, speedwell, cleavers, alopecurus japonicus, beckmark, beckmark grass, descurainia crenata and the like, has a surprising and unexpected synergistic effect, is more obvious under low dosage, can reduce the dosage and reduce the pollution to the environment, is reasonably compounded and reduces the agricultural cost, is efficient to ALS and ACCase inhibitor resistant weeds, and has a good application prospect. Meanwhile, tests show that the herbicide composition shows good selectivity and excellent synergistic effect on lawns and crops such as wheat fields, corn fields, paddy fields, peanuts, sugarcane, sorghum, millet, potatoes, rape, soybeans, cotton, vegetables, bluegrass, tall fescue, zoysia japonica and the like, and can be developed into herbicide mixtures with wide market value.
Table 125 exemplary field Effect of the compounded compositions
Figure BDA0002991828280000531
Figure BDA0002991828280000541
Figure BDA0002991828280000551
Figure BDA0002991828280000561
Figure BDA0002991828280000571
Figure BDA0002991828280000581
Figure BDA0002991828280000591
Figure BDA0002991828280000601
Figure BDA0002991828280000611

Claims (10)

1. A weeding composition containing bicyclopyrone is characterized in that the active ingredient consists of an active ingredient A and an active ingredient B with herbicidally effective amounts, wherein the active ingredient A is bicyclopyrone, and the active ingredient B is selected from one of the following compounds: tiafenacil, saflufenacil;
when the active ingredient B is saflufenacil, the weight ratio of A to B is 1:20-100: 1;
when the active ingredient B is tiafenacil, the weight ratio of A to B is 1:2-100: 1.
2. A herbicidal composition comprising bicyclopyrone according to claim 1,
when the active ingredient B is saflufenacil, the weight ratio of A to B is 1:10-80: 1;
when the active ingredient B is tiafenacil, the weight ratio of A to B is 1:5-80: 1.
3. A herbicidal composition comprising bicyclopyrone according to claim 1,
when the active ingredient B is saflufenacil, the weight ratio of A to B is 1:5-50: 1;
when the active ingredient B is tiafenacil, the weight ratio of A to B is 5:1-50: 1.
4. The herbicidal composition containing bicyclopyrone according to claim 1,
when the active ingredient B is saflufenacil, the weight ratio of A to B is 5:1-30: 1;
when the active ingredient B is tiafenacil, the weight ratio of A to B is 10:1-30: 1.
5. A herbicidal composition containing bicyclopyrone according to any one of claims 1 to 4, characterized in that the mass percentages of A and B in the herbicidal composition are 1 to 95% of the total amount.
6. A herbicidal composition containing bicyclopyrone according to claim 5, characterized in that the mass percentages of A and B in the herbicidal composition are 10-80% of the total amount.
7. A herbicidal composition comprising bicyclopyrone according to any one of claims 1 to 4, characterized in that it further comprises a carrier and/or a surfactant.
8. The herbicidal composition containing bicyclopyrone as claimed in any one of claims 1 to 4, wherein the specific formulation of the herbicidal composition is dispersible oil suspension, aqueous suspension, suspoemulsion, wettable powder, emulsifiable concentrate, water dispersible granule, aqueous emulsion or microemulsion.
9. A herbicidal composition comprising ciclopirox, according to any one of claims 1 to 4, characterized in that the herbicidal composition further comprises a safener selected from one or more of isoxadifen, cyprosulfamide, mefenpyr, cloquintocet, gibberellic acid, furilazole, mecamifen.
10. Use of a herbicidal composition comprising bicyclopyrone as claimed in any one of claims 1 to 9 for the control of the harmful weed descurainia sophia in crops.
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