CN112931509A - Herbicide containing benzobicyclon and MCPA (dimethyl tetrachloro isooctyl ester) - Google Patents
Herbicide containing benzobicyclon and MCPA (dimethyl tetrachloro isooctyl ester) Download PDFInfo
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- CN112931509A CN112931509A CN202110251669.8A CN202110251669A CN112931509A CN 112931509 A CN112931509 A CN 112931509A CN 202110251669 A CN202110251669 A CN 202110251669A CN 112931509 A CN112931509 A CN 112931509A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
- A01N39/04—Aryloxy-acetic acids; Derivatives thereof
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Abstract
The herbicide containing the benzobicyclon and the methoxone isooctyl is a suspending agent in the dosage form of 5-85% of active ingredients, 5-15% of auxiliary agents and 10-80% of deionized water, wherein the auxiliary agents are polyoxyethylene ether sulfate, a stabilizing agent, a regulator, an organic silicon defoaming agent and glycol. The invention utilizes the synthesized polyoxyethylene ether sulfate as the wetting dispersant, utilizes the excellent wetting property, the solubilizing property and the emulsifying power of the wetting dispersant, solves the problem of reduced effect caused by agglomeration, delamination and precipitation of the herbicide suspending agent due to long-term storage, and improves the long-term stability of the herbicide suspending agent.
Description
Technical Field
The invention belongs to the technical field of pesticides, and particularly relates to a herbicide containing benzobicyclon and MCPA.
Background
The bicyclsulcotrione is a herbicide with broad-spectrum selectivity and long lasting period for preventing and killing weeds in a direct seeding field and a transplanting field of rice. The benzobicylon has a dicyclic structure and a diphenyl sulfide structure, has strong soil adsorption, and can inhibit HPPD to influence the synthesis of plastoquinone, and the plastoquinone can act on Phytoene Dehydrogenase (PDS) to finally influence the biosynthesis of carotenoid to whiten leaves. Its advantages are long acting period.
The methoxone isooctyl ester is synthesized by methoxone and isooctyl ester, is a selective hormone type herbicide, has strong systemic conductivity, is mainly used for treating stems and leaves after seedlings, and the medicament passes through cuticle and cytoplasmic membrane, is suitable for broad leaf weeds and cyperaceae weeds, such as gynura divaricata, chenopodium album, polygonum, amaranth, purslane, xanthium sibiricum, aralia elata, monochoria vaginalis, field horsetail and felt, but has no effect on gramineous weeds, and the medicinal effect can be greatly reduced in the environment below 18 ℃.
With the continuous use of pesticides, target crops are easy to generate drug resistance, the effective dose of the pesticides is gradually increased, and the environmental and food safety problems caused by pesticide residues are increasingly serious. In the prior art, two or more than two active ingredients are combined for use, so that the weeding effect is improved, and meanwhile, the weeding composition has the positive characteristics of prolonging the application period, reducing the dosage, reducing the phytotoxicity, reducing the residue, delaying the occurrence and development of drug resistance and the like. Herbicide compounding or compounding is one of the most effective ways to solve the above problems.
Therefore, the invention provides the herbicide containing the benzobicyclon and the MCPA, so that the actions of the benzobicyclon and MCPA are cooperated and cooperated, the generation of drug resistance of an action substance is slowed down, and the action effect of the herbicide is improved.
Disclosure of Invention
The invention aims to provide a herbicide containing benzobicyclon and MCPA-isooctyl ester, which solves the problems of low herbicide effect and easy generation of drug resistance of the herbicide.
The invention is solved by the following technical scheme:
the active ingredients of the herbicide are the bicyclsulcotrione and the MCPA, and the mass ratio of the bicyclsulcotrione to the MCPA is 1-10: 0.1-1.5.
Furthermore, the herbicide containing the bicyclotrione and the methoxone isooctyl is a suspending agent and is prepared by 5-85% of active ingredients, 5-15% of auxiliary agents and 10-80% of deionized water.
Furthermore, the auxiliary agent is a mixture of polyoxyethylene ether sulfate, a stabilizer, a blending agent, an organic silicon defoaming agent and ethylene glycol in any ratio.
Further, the preparation method of the herbicide containing the bicyclohepatrione and the methoxone isooctyl ester comprises the following steps:
step one, uniformly mixing the benzobicyclon, the methoxone isooctyl ester, the polyoxyethylene ether sulfate, the stabilizer, the organic silicon defoamer, the glycol and the deionized water in a stirrer, and transferring the mixture to a shearing kettle for shearing to obtain a sheared mixed material;
step two: and D, transferring the mixed material obtained in the step I to a sand mill for sanding until the particle size of the material is smaller than 5 micrometers, adding a conditioning agent, continuing sanding until the particle size of the material is 2-3 micrometers, and thus obtaining the herbicide containing the bicyclosulfuron and the MCPA.
Further, the stabilizer is one or a mixture of several of epoxidized soybean oil and epoxidized linseed oil in any ratio.
Further, the regulator is one or a mixture of several of organic bentonite, xanthan gum, polyvinyl alcohol and magnesium aluminum silicate in any ratio.
Further, the polyoxyethylene ether sulfate is prepared by the following steps:
grinding sulfamic acid and urea, drying in a vacuum drying oven at 50-70 ℃ for 20-30h, and cooling to room temperature for later use;
and B: b, adding the sulfamic acid, the urea and the polyoxyethylene ether treated in the step A, stirring and reacting for 5-15min at 40-55 ℃, heating to 100-120 ℃, continuing to react for 2-4h, cooling to 90 ℃, and adding deionized water for hydrolysis to obtain a crude product;
and C: and D, dissolving the crude product obtained in the step B in absolute ethyl alcohol, stirring and ultrasonically treating the mixture, filtering the mixture to remove inorganic small molecules, removing the absolute ethyl alcohol from the filtrate through a rotary evaporator, and repeating the operation for 3 times to obtain the polyoxyethylene ether sulfate.
Further, the polyoxyethylene ether is one or a mixture of several of styryl phenol polyoxyethylene ether, stearic acid polyoxyethylene ether and fatty alcohol polyoxyethylene ether in any ratio.
Further, polyoxyethylene ether: sulfamic acid: the mass ratio of the deionized water is 80-100:25-30: 2.5-4.
The invention has the beneficial effects that:
1. the herbicide is formed by compounding the bicyclsulcotrione and the methoxone isooctyl ester, the characteristics of strong soil adsorption, broad spectrum selectivity and long lasting period of the bicyclsulcotrione are utilized, the methoxone isooctyl ester is superposed to be suitable for broadleaf weeds and cyperaceae weeds, so that the herbicide formed by compounding has strong systemic conductivity and soil sealing property, the methoxone isooctyl ester has no effect on the gramineae weeds, but the bicyclsulcotrione has an effect on the gramineae weeds, and the weeding spectrum of the herbicide formed by compounding is widened;
2. the invention utilizes the synthesized polyoxyethylene ether sulfate as the wetting dispersant, utilizes the excellent wetting property, the solubilizing property and the emulsifying power of the wetting dispersant, solves the problem of reduced effect caused by agglomeration, delamination and precipitation of the herbicide suspending agent due to long-term storage, and improves the long-term stability of the herbicide suspending agent.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
the active ingredients of the herbicide are the bicyclohepatrione and the methoxone isooctyl ester, and the mass ratio of the bicyclohepatrione to the methoxone isooctyl ester is 7: 0.4.
The herbicide containing the benzobicyclon and the methoxone isooctyl ester is a suspending agent and is prepared from 15% of active ingredients, 8% of auxiliary agents and 77% of deionized water, wherein the 8% of auxiliary agents are 2% of polyoxyethylene ether sulfate, 2% of stabilizing agents, 1.5% of regulating agents, 1.5% of organic silicon defoaming agents and 1% of ethylene glycol, the stabilizing agents are obtained by mixing epoxidized soybean oil and epoxidized linseed oil according to the mass ratio of 1:1, and the regulating agents are obtained by mixing organic bentonite and xanthan gum according to the mass ratio of 1: 1.
The preparation method of the herbicide containing the bicyclohepatrione and the methoxone isooctyl ester comprises the following steps:
step one, uniformly mixing the benzobicyclon, the methoxone isooctyl ester, the polyoxyethylene ether sulfate, the stabilizer, the organic silicon defoamer, the glycol and the deionized water in a stirrer, and transferring the mixture to a shearing kettle for shearing to obtain a sheared mixed material;
step two: and D, transferring the mixed material obtained in the step I to a sand mill for sanding until the particle size of the material is smaller than 5 micrometers, adding a conditioning agent, continuing sanding until the particle size of the material is 2 micrometers, and thus obtaining the herbicide containing the dicylon-cotrione and the methoxone isooctyl ester.
Wherein, the polyoxyethylene ether sulfate is prepared by the following steps:
grinding sulfamic acid and urea, drying in a vacuum drying oven at 50 ℃ for 20 hours, and cooling to room temperature for later use, wherein the polyoxyethylene ether is styrylphenol polyoxyethylene ether;
and B: and B, putting the sulfamic acid, the urea and the polyethenoxy ether treated in the step A into a reaction kettle, stirring and reacting for 15min at 55 ℃, heating to 120 ℃, continuing to react for 3h, cooling to 90 ℃, adding deionized water for hydrolysis to obtain a crude product, wherein the polyoxyethylene ether: sulfamic acid: deionized water polyoxyethylene ether: sulfamic acid: the mass ratio of the deionized water to the deionized water is 80:25: 2.5;
and C: and D, dissolving the crude product obtained in the step B in absolute ethyl alcohol, stirring and ultrasonically treating the mixture, filtering the mixture to remove inorganic small molecules, removing the absolute ethyl alcohol from the filtrate through a rotary evaporator, and repeating the operation for 3 times to obtain the styrylphenol polyoxyethylene ether sulfate.
Example 2:
the active ingredients of the herbicide are the bicyclsulcotrione and the MCPA, and the mass ratio of the bicyclsulcotrione to the MCPA is 8: 1.
The herbicide containing the benzobicyclon and the MCPA is a suspending agent and is prepared from 25% of active ingredients, 10% of auxiliaries and 65% of deionized water, wherein the 10% of auxiliaries are 3% of polyoxyethylene ether sulfate, 2.5% of stabilizing agent, 2% of regulator, 1.5% of organic silicon defoamer and 1% of glycol, the stabilizing agent is prepared by mixing epoxidized soybean oil and epoxidized linseed oil according to the mass ratio of 1:1, and the regulator is prepared by mixing organic bentonite and xanthan gum according to the mass ratio of 1: 1.
The preparation method of the herbicide containing the bicyclohepatrione and the methoxone isooctyl ester comprises the following steps:
step one, uniformly mixing the benzobicyclon, the methoxone isooctyl ester, the polyoxyethylene ether sulfate, the stabilizer, the organic silicon defoamer, the glycol and the deionized water in a stirrer, and transferring the mixture to a shearing kettle for shearing to obtain a sheared mixed material;
step two: and D, transferring the mixed material obtained in the step I to a sand mill for sanding until the particle size of the material is smaller than 5 micrometers, adding a conditioning agent, continuing sanding until the particle size of the material is 2 micrometers, and thus obtaining the herbicide containing the dicylon-cotrione and the methoxone isooctyl ester.
Wherein, the polyoxyethylene ether sulfate is prepared by the following steps:
grinding sulfamic acid and urea, drying in a vacuum drying oven at 50 ℃ for 20 hours, and cooling to room temperature for later use, wherein the polyoxyethylene ether is stearic acid polyoxyethylene ether;
and B: and B, putting the sulfamic acid, the urea and the polyoxyethylene ether treated in the step A into a reaction kettle, stirring and reacting for 15min at 55 ℃, heating to 120 ℃, continuing to react for 3h, cooling to 90 ℃, adding deionized water for hydrolysis to obtain a crude product, wherein the polyoxyethylene ether: sulfamic acid: the mass ratio of deionized water added is 90:28: 3.
And C: and D, dissolving the crude product obtained in the step B in absolute ethyl alcohol, stirring and ultrasonically treating the mixture, filtering the mixture to remove inorganic small molecules, removing the absolute ethyl alcohol from the filtrate through a rotary evaporator, and repeating the operation for 3 times to obtain the stearic acid polyoxyethylene ether sulfate.
Example 3:
the active ingredients of the herbicide are the bicyclsulcotrione and the MCPA, and the mass ratio of the bicyclsulcotrione to the MCPA is 9: 2.
The herbicide containing the benzobicyclon and the methoxone isooctyl ester is a suspending agent and is prepared from 45% of active ingredients, 15% of an auxiliary agent and 40% of deionized water, wherein the 15% of the auxiliary agent is 4.5% of polyoxyethylene ether sulfate, 3.5% of a stabilizer, 3% of a regulator, 2.5% of an organic silicon defoamer and 1.5% of glycol, the stabilizer is prepared by mixing epoxidized soybean oil and epoxidized linseed oil according to the mass ratio of 1:1, and the regulator is prepared by mixing bentonite and xanthan gum according to the mass ratio of 1: 1.
The preparation method of the herbicide containing the bicyclohepatrione and the methoxone isooctyl ester comprises the following steps:
step one, uniformly mixing the benzobicyclon, the methoxone isooctyl ester, the polyoxyethylene ether sulfate, the stabilizer, the organic silicon defoamer, the glycol and the deionized water in a stirrer, and transferring the mixture to a shearing kettle for shearing to obtain a sheared mixed material;
step two: and D, transferring the mixed material obtained in the step I to a sand mill for sanding until the particle size of the material is smaller than 5 micrometers, adding a conditioning agent, continuing sanding until the particle size of the material is 2 micrometers, and thus obtaining the herbicide containing the dicylon-cotrione and the methoxone isooctyl ester.
Wherein, the polyoxyethylene ether sulfate is prepared by the following steps:
grinding sulfamic acid and urea, drying in a vacuum drying oven at 50 ℃ for 20 hours, and cooling to room temperature for later use, wherein the polyoxyethylene ether is fatty alcohol-polyoxyethylene ether;
and B: and B, putting the sulfamic acid, the urea and the polyoxyethylene ether treated in the step A into a reaction kettle, stirring and reacting for 15min at 55 ℃, heating to 120 ℃, continuing to react for 3h, cooling to 90 ℃, adding deionized water for hydrolysis to obtain a crude product, wherein the polyoxyethylene ether: sulfamic acid: the mass ratio of the deionized water is 100:30: 4;
and C: and D, dissolving the crude product obtained in the step B in absolute ethyl alcohol, stirring and ultrasonically treating the mixture, filtering the mixture to remove inorganic micromolecules, removing the absolute ethyl alcohol from the filtrate through a rotary evaporator, and repeating the operation for 3 times to obtain the benzene fatty alcohol-polyoxyethylene ether sulfate.
Comparative example 1:
a herbicide containing benzobicyclon contains benzobicyclon as active component.
The herbicide containing the benzobicyclon is a suspending agent and is prepared from 15% of active ingredients, 8% of auxiliary agents and 77% of deionized water, wherein the 8% of auxiliary agents are 2% of polyoxyethylene ether sulfate, 2% of stabilizing agents, 1.5% of regulating agents, 1.5% of organic silicon defoaming agents and 1% of glycol, the stabilizing agents are prepared by mixing epoxidized soybean oil and epoxidized linseed oil according to the mass ratio of 1:1, and the regulating agents are prepared by mixing bentonite and xanthan gum according to the mass ratio of 1: 1.
The preparation method of the herbicide containing the benzobicyclon comprises the following steps:
step one, uniformly mixing the benzobicyclon, polyoxyethylene ether sulfate, the stabilizer, the organic silicon defoamer, ethylene glycol and deionized water in a stirrer, and transferring the mixture to a shearing kettle for shearing to obtain a sheared mixed material;
step two: and D, transferring the mixed material obtained in the step I to a sand mill for sanding until the particle size of the material is smaller than 5 micrometers, adding a conditioning agent, continuing sanding until the particle size of the material is 2 micrometers, and thus obtaining the herbicide containing the benzobicyclon.
Wherein, the polyoxyethylene ether sulfate is prepared by the following steps:
grinding sulfamic acid and urea, drying in a vacuum drying oven at 50 ℃ for 20 hours, and cooling to room temperature for later use, wherein the polyoxyethylene ether is styrylphenol polyoxyethylene ether;
and B: and B, putting the sulfamic acid, the urea and the polyethenoxy ether treated in the step A into a reaction kettle, stirring and reacting for 15min at 55 ℃, heating to 120 ℃, continuing to react for 3h, cooling to 90 ℃, adding deionized water for hydrolysis to obtain a crude product, wherein the polyoxyethylene ether: sulfamic acid: deionized water polyoxyethylene ether: sulfamic acid: the mass ratio of the deionized water to the deionized water is 80:25: 2.5;
and C: and D, dissolving the crude product obtained in the step B in absolute ethyl alcohol, stirring and ultrasonically treating the mixture, filtering the mixture to remove inorganic small molecules, removing the absolute ethyl alcohol from the filtrate through a rotary evaporator, and repeating the operation for 3 times to obtain the styrylphenol polyoxyethylene ether sulfate.
Comparative example 2:
a herbicide containing methoxone isooctyl ester, the active component of the herbicide is methoxone isooctyl ester.
The herbicide containing the methoxone isooctyl ester is a suspending agent and is prepared from 25% of active ingredients, 10% of auxiliary agents and 65% of deionized water, wherein the 10% of auxiliary agents comprise 3% of polyoxyethylene ether sulfate, 2.5% of stabilizing agents, 2% of regulating agents, 1.5% of organic silicon defoaming agents and 1% of glycol, the stabilizing agents are obtained by mixing epoxidized soybean oil and epoxidized linseed oil according to the mass ratio of 1:1, and the regulating agents are obtained by mixing organic bentonite and xanthan gum according to the mass ratio of 1: 1.
The preparation method of the herbicide containing the methoxone isooctyl ester comprises the following steps:
uniformly mixing methoxone isooctyl ester, polyoxyethylene ether sulfate, a stabilizer, an organic silicon defoamer, glycol and deionized water in a stirrer, and transferring the mixture to a shearing kettle for shearing to obtain a sheared mixed material;
step two: and D, transferring the mixed material obtained in the step I to a sand mill for sanding until the particle size of the material is smaller than 5 micrometers, adding a conditioning agent, continuing sanding until the particle size of the material is 2 micrometers, and thus obtaining the herbicide containing the methoxone isooctyl ester.
Wherein, the polyoxyethylene ether sulfate is prepared by the following steps:
grinding sulfamic acid and urea, drying in a vacuum drying oven at 50 ℃ for 20 hours, and cooling to room temperature for later use, wherein the polyoxyethylene ether is stearic acid polyoxyethylene ether;
and B: and B, putting the sulfamic acid, the urea and the polyoxyethylene ether treated in the step A into a reaction kettle, stirring and reacting for 15min at 55 ℃, heating to 120 ℃, continuing to react for 3h, cooling to 90 ℃, adding deionized water for hydrolysis, and obtaining a crude product, wherein the polyoxyethylene ether: sulfamic acid: the mass ratio of the deionized water to the deionized water is 90:28: 3;
and C: and D, dissolving the crude product obtained in the step B in absolute ethyl alcohol, stirring and ultrasonically treating the mixture, filtering the mixture to remove inorganic small molecules, removing the absolute ethyl alcohol from the filtrate through a rotary evaporator, and repeating the operation for 3 times to obtain the stearic acid polyoxyethylene ether sulfate.
Comparative example 3:
the active ingredients of the herbicide are the bicyclsulcotrione and the MCPA, and the mass ratio of the bicyclsulcotrione to the MCPA is 9: 2.
A herbicide containing benzobicyclon and MCPA is a suspending agent and is prepared from 45% of active ingredients, 15% of an auxiliary agent and 40% of deionized water, wherein the 15% of the auxiliary agent is 4.5% of polyoxyethylene sorbitan monostearate, 3.5% of a stabilizer, 3% of a regulator, 2.5% of an organic silicon defoaming agent and 1.5% of ethylene glycol, the stabilizer is prepared by mixing epoxidized soybean oil and epoxidized linseed oil according to a mass ratio of 1:1, and the regulator is prepared by mixing bentonite and xanthan gum according to a mass ratio of 1: 1.
The preparation method of the herbicide containing the bicyclohepatrione and the methoxone isooctyl ester comprises the following steps:
step one, uniformly mixing benzobicyclon, methoxone isooctyl ester, fatty alcohol-polyoxyethylene ether, a stabilizer, an organic silicon defoamer, glycol and deionized water in a stirrer, and transferring to a shearing kettle for shearing to obtain a sheared mixed material;
step two: and D, transferring the mixed material obtained in the step I to a sand mill for sanding until the particle size of the material is smaller than 5 micrometers, adding a conditioning agent, continuing sanding until the particle size of the material is 2 micrometers, and thus obtaining the herbicide containing the dicylon-cotrione and the methoxone isooctyl ester.
The results of the experiments of examples 1 to 3 and comparative examples 1 to 2 were conducted on 5 wheat test plots, and the gas control means and the wheat varieties used in the 5 wheat test plots were the same, and the herbicidal effects after 30 days were observed to obtain the following data.
From the above data, it can be seen that the herbicide containing the two components of the benzobicylon and the methoxone isooctyl ester has better herbicidal effect than the herbicide containing the single component of the benzobicylon or the methoxone isooctyl ester.
The herbicides obtained in example 3 and comparative example 3 were placed in a ventilated environment at 18 ℃ and the stability of the herbicide was observed after 180 days, and the results showed that the herbicide obtained in example 3 did not have significant caking and delamination, and that the herbicide obtained in comparative example 3 showed weak delamination, indicating that the suspending agent herbicide obtained by adding polyoxyethylene ether sulfate was more stable than the suspending agent herbicide obtained by adding fatty alcohol polyoxyethylene ether.
In the description herein, references to the description of "one embodiment," "an example," "a specific example" or the like are intended to mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The foregoing is merely exemplary and illustrative of the principles of the present invention and various modifications, additions and substitutions of the specific embodiments described herein may be made by those skilled in the art without departing from the principles of the present invention or exceeding the scope of the claims set forth herein.
Claims (8)
1. The herbicide containing the bicyclohepatrione and the methoxone isooctyl ester is characterized in that the active ingredients of the herbicide are the bicyclohepatrione and the methoxone isooctyl ester, and the mass ratio of the bicyclohepatrione to the methoxone isooctyl ester is 1-10: 0.1-1.5.
2. The herbicide containing the bicyclosulfuron and the methoxone isooctyl ester as claimed in claim 1, wherein the herbicide containing the bicyclosulfuron and the methoxone isooctyl ester is a suspending agent, and is prepared from 5-85% of active ingredients, 5-15% of auxiliary agents and 10-80% of deionized water.
3. The herbicide containing the benzobicyclon and the methoxone isooctyl ester as claimed in claim 2, wherein the adjuvant is a mixture of polyoxyethylene ether sulfate, a stabilizer, a regulator, a silicone defoamer and glycol in any ratio.
4. The herbicide containing benzobicyclon and methoxone isooctyl ester as claimed in claim 1, wherein the herbicide containing benzobicyclon and methoxone isooctyl ester is prepared by a process comprising the steps of:
step one, uniformly mixing the benzobicyclon, the methoxone isooctyl ester, the polyoxyethylene ether sulfate, the stabilizer, the organic silicon defoamer, the glycol and the deionized water in a stirrer, and transferring the mixture to a shearing kettle for shearing to obtain a sheared mixed material;
step two: and D, transferring the mixed material obtained in the step I to a sand mill for sanding until the particle size of the material is smaller than 5 micrometers, adding a conditioning agent, continuing sanding until the particle size of the material is 2-3 micrometers, and thus obtaining the herbicide containing the bicyclosulfuron and the MCPA.
5. The herbicide containing benzobicyclon and methoxone isooctyl ester as claimed in claim 3, wherein the stabilizer is one or more of epoxidized soybean oil and epoxidized linseed oil; the modifier is one or a mixture of several of organic bentonite, xanthan gum, polyvinyl alcohol and magnesium aluminum silicate in any ratio.
6. The herbicide containing benzobicyclon and methoxone isooctyl ester as claimed in claim 3, wherein said polyoxyethylene ether sulfate is prepared by the steps of:
grinding sulfamic acid and urea, drying in a vacuum drying oven at 50-70 ℃ for 20-30h, and cooling to room temperature for later use;
and B: b, putting the sulfamic acid, the urea and the polyoxyethylene ether treated in the step A into a reaction kettle, stirring and reacting for 5-15min at 40-55 ℃, heating to 100-120 ℃, continuing to react for 2-4h, cooling to 90 ℃, and adding deionized water for hydrolysis to obtain a crude product;
and C: and D, dissolving the crude product obtained in the step B in absolute ethyl alcohol, stirring and ultrasonically treating, removing the absolute ethyl alcohol from the filtrate through a rotary evaporator, and repeating the operation for 3 times to obtain the polyoxyethylene ether sulfate.
7. The herbicide containing benzobicyclon and methoxone isooctyl ester as claimed in claim 6, wherein the polyoxyethylene ether is one or a mixture of styrylphenol polyoxyethylene ether, stearic acid polyoxyethylene ether and fatty alcohol polyoxyethylene ether in any ratio.
8. The herbicide containing benzobicyclon and methoxone isooctyl ester as claimed in claim 6, wherein the ratio of polyoxyethylene ether: sulfamic acid: the mass ratio of the deionized water is 80-100:25-30: 2.5-4.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110251669.8A CN112931509A (en) | 2021-03-08 | 2021-03-08 | Herbicide containing benzobicyclon and MCPA (dimethyl tetrachloro isooctyl ester) |
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| CN202110251669.8A CN112931509A (en) | 2021-03-08 | 2021-03-08 | Herbicide containing benzobicyclon and MCPA (dimethyl tetrachloro isooctyl ester) |
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| CN202110251669.8A Pending CN112931509A (en) | 2021-03-08 | 2021-03-08 | Herbicide containing benzobicyclon and MCPA (dimethyl tetrachloro isooctyl ester) |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101328141A (en) * | 2007-06-19 | 2008-12-24 | 浙江工商大学 | Preparation of alkyl phenol polyethenoxy ether sodium sulfate |
| CN106577683A (en) * | 2016-12-02 | 2017-04-26 | 安徽科技学院 | Herbicidal composition containing triafamone and benzobicylon |
| CN109042689A (en) * | 2018-08-26 | 2018-12-21 | 孟州传奇生物科技有限公司 | A kind of built herbicide for rice field composition |
| CN109042675A (en) * | 2018-07-21 | 2018-12-21 | 青岛清原化合物有限公司 | Ternary weeding composition and its application comprising HPPD inhibitor class herbicide |
-
2021
- 2021-03-08 CN CN202110251669.8A patent/CN112931509A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101328141A (en) * | 2007-06-19 | 2008-12-24 | 浙江工商大学 | Preparation of alkyl phenol polyethenoxy ether sodium sulfate |
| CN106577683A (en) * | 2016-12-02 | 2017-04-26 | 安徽科技学院 | Herbicidal composition containing triafamone and benzobicylon |
| CN109042675A (en) * | 2018-07-21 | 2018-12-21 | 青岛清原化合物有限公司 | Ternary weeding composition and its application comprising HPPD inhibitor class herbicide |
| CN109042689A (en) * | 2018-08-26 | 2018-12-21 | 孟州传奇生物科技有限公司 | A kind of built herbicide for rice field composition |
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Application publication date: 20210611 |