CN104542662A - Weeding composition containing amicarbazone, fluroxypyr and nicosulfuron - Google Patents

Weeding composition containing amicarbazone, fluroxypyr and nicosulfuron Download PDF

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Publication number
CN104542662A
CN104542662A CN201410785011.5A CN201410785011A CN104542662A CN 104542662 A CN104542662 A CN 104542662A CN 201410785011 A CN201410785011 A CN 201410785011A CN 104542662 A CN104542662 A CN 104542662A
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CN
China
Prior art keywords
fluroxypyr
nicosulfuron
amicarbazone
herbicidal combinations
weed
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Pending
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CN201410785011.5A
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Chinese (zh)
Inventor
吴泽伟
冷忠国
陈佛祥
张志伟
王礼文
朱刚
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Guangdong Zhongxun Agri Science Corp
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Guangdong Zhongxun Agri Science Corp
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Priority to CN201410785011.5A priority Critical patent/CN104542662A/en
Publication of CN104542662A publication Critical patent/CN104542662A/en
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Abstract

The invention relates to a weeding composition containing amicarbazone, fluroxypyr and nicosulfuron. The weeding composition comprises the amicarbazone, the fluroxypyr and the nicosulfuron as effective components, wherein the ratio of parts by weight of the amicarbazone to the fluroxypyr to the nicosulfuron is (1-5):(1-5):(1-5). The weeding composition has a synergistic interaction, and the effects of preventing and removing annual weeds are obviously superior to the effects of single use of each component; furthermore, the weeding spectrum is expanded, meanwhile, the dosage is reduced, the generation of drug resistance of weeds is delayed, and the environmental pollution is relieved.

Description

Herbicidal combinations containing amicarbazone and fluroxypyr and nicosulfuron
Technical field
The present invention relates to a kind of Herbicidal combinations containing amicarbazone and fluroxypyr and nicosulfuron, is with amicarbazone, fluroxypyr and nicosulfuron for active ingredient, for control of maize field annual weed.
Background technology
Chemical method weeding is agriculturally one of Main Means controlling weeds.In recent years, because some weed killer herbicide kind large area are used alone, a lot of weeds have been caused to develop immunity to drugs.Meanwhile, grass when weeds occur is mutually complicated, and multiple weeds are mixed raw, and single variety weed killer herbicide uses can not solve farmland weed, all can show defect in a certain respect and limitation.Variety classes weed killer herbicide mixture, have herbicidal spectrum wide, promote actual effect, delay herbicide resistance, time and labour saving advantage.
Amicarbazone belongs to triazolineone weed killer herbicide, efficient to broad leaved weeds such as Chenopodiaceae, Amaranthaceae, piemarkers, after susceptible weeds absorbs this medicine, destroys chlorophyllous formation by suppressing Single-chip microcomputer dual oxide enzyme, and the weeds chlorosis that causes being injured is withered.
Fluroxypyr is steroids inner sucting conduction type herbicide after seedling, is absorbed by plants very soon after medicine, makes sensitive plant occur the reaction of classical hormones class weed killer herbicide, plant deformity, distortion, finally withered.
Nicosulfuron belongs to sulfonylurea herbicide, efficient corn herbicide, and nicosulfuron uses after low dosage bud, effectively can prevent and kill off multiple annual gramineous weed in corn field, fraction broad leaved weed and sedge weed.It is absorbed rapidly by leaf and root, and conducted rapidly by xylem and phloem, by the synthesis suppressing acetolactate synthestase to stop branched-chain amino acid, use rear weeds to stop growing immediately, 4 ~ 5 days young leaves fade, downright bad, and progressively expand to whole plant, plant death in 20 ~ 25 days after process under general condition.Corn has good drug resistance to this medicine, occurs temporary transient chlorisis or slight hypoevolutism, but generally can recover rapidly and the not underproduction after process.
Variety classes weed killer herbicide mixture, have herbicidal spectrum wide, promote actual effect, delay herbicide resistance, time and labour saving advantage.Being screened by formulation of pesticide, can effectively improve actual control efficiency, reduce dosage, reduce costs, delay the generation of herbicide resistance, is the important means that agricultural synthesis is administered.The recipe determination of the present inventor to amicarbazone, fluroxypyr and nicosulfuron conducts in-depth research, find that amicarbazone, fluroxypyr and nicosulfuron carry out mixture, synergistic effect is had to corn field annual weed in certain mixed ratio scope, after further study, the present invention is completed.
Summary of the invention
The object of the invention is to solve in prior art to farmland weed develop immunity to drugs problem and actual control efficiency poor, provide a kind of efficient, low toxicity, quick-acting are good and the lasting period is long, are conducive to the composition pesticide of the farmland weed comprehensive regulation.Particularly for broad leaved weed, comparatively serious corn field occurs, the active ingredient amicarbazone in Herbicidal combinations of the present invention and fluroxypyr strengthen the control efficiency to broad leaved weed greatly.On this basis, then add nicosulfuron and then effectively can prevent and treat most of grassy weed.
Technical scheme: a kind of corn field postemergence weed control composition, active ingredient is amicarbazone, fluroxypyr, nicosulfuron, the ratio of weight and number of amicarbazone, fluroxypyr and nicosulfuron is 1 ~ 5:1 ~ 5:1 ~ 5, the weight summation percentage by weight in the composition of amicarbazone, fluroxypyr and nicosulfuron is 5% ~ 95%, and all the other are agriculturally acceptable insecticides adjuvant.
Described Herbicidal combinations according to well known to a person skilled in the art method, can be selected suitable pesticidal preparations auxiliary element, can be processed into the application forms that the applicable agricultural productions such as suspending agent, oil-suspending agent, water dispersible granules, wetting powder use.
The auxiliary element that the present invention uses comprises wetting agent, stabilizing agent, dispersant, disintegrant, thickener, pH adjusting agent, defoamer, antifreezing agent, filler etc., be all auxiliary agent conventional in Pesticide formulation, concrete composition and consumption are determined by test according to recipe requirements.
Herbicidal combinations provided by the invention, is applicable to corn field seedling rear defence except annual weed.
The frequency of administration of Herbicidal combinations provided by the invention and amount of application change with crops, weeds, weather condition and have small variations, can by the object using suitable dosage reach effectively control.
Product described in the invention can the form of finished product preparation provide, and namely in composition, each material mixes, and the composition of composition also can the form of single dose provide, and directly mixes in tank or bucket, be then diluted to required concentration before using.
Herbicidal combinations provided by the invention has following beneficial effect:
1, Herbicidal combinations provided by the invention, obvious synergy or summation action is shown in certain ratio range, the control efficiency of composition to weeds is significantly improved than single dose, reduce the using dosage of agricultural chemicals, decrease times for spraying, reduce drug cost, decrease the adverse effect of agricultural chemicals to ecotope.
2, Herbicidal combinations provided by the invention, the combination of three kinds of effective ingredients, expands herbicidal spectrum, and a drug can solve weed problem, compensate for defect when single dose uses and limitation.
3, Herbicidal combinations provided by the invention, three kinds of effective ingredient mechanism of action are not quite identical, can overcome the shortcoming that long-term single use easily produces resistance, extend the service life of medicament, to the comprehensive regulation important in inhibiting of Weed Resistance.
4, Herbicidal combinations provided by the invention, drug effect plays rapidly, and the lasting period is long, and use cost is low, easy to use, time saving and energy saving, and it applies huge economic benefit and social benefit.
Example of formulations 1:24% amicarbazone fluroxypyr nicosulfuron suspending agent.
Above-mentioned formula is pulverized in proportion in advance, then adds in sand mill and grind, the obtained 24% amicarbazone fluroxypyr nicosulfuron suspending agent of allotment after high shear mixing.
Example of formulations 2:34% amicarbazone fluroxypyr nicosulfuron dispersibles oil-suspending agent.
By above-mentioned formula Central Plains medicine, solvent, emulsifiers dissolve uniformly oil phase; Under high velocity agitation, the obtained 34% amicarbazone fluroxypyr nicosulfuron of mixing dispersibles oil-suspending agent.
Example of formulations 3:40% amicarbazone fluroxypyr nicosulfuron wetting powder.
Mix entering in blender after above-mentioned formula in proportion coarse crushing, more namely obtain 40% amicarbazone fluroxypyr nicosulfuron wetting powder after air-flow crushing.
Example of formulations 4:40% amicarbazone fluroxypyr water dispersible granule of nicosulfuron.
By above-mentioned formula dry pulverization process, granulation, drying, the obtained 40% amicarbazone fluroxypyr water dispersible granule of nicosulfuron of screening preparation in proportion.
Field control effectiveness test embodiment 1: prevent and kill off corn field annual weed field control effectiveness test.
Reagent agent and dispenser dosage:
(1) 24% amicarbazone fluroxypyr nicosulfuron suspending agent (12% amicarbazone: 9% fluroxypyr: 3% nicosulfuron), every mu of preparation consumption 133 grams (1#).
(2) 34% amicarbazone fluroxypyr nicosulfurons dispersible oil-suspending agent (20% amicarbazone: 10% fluroxypyr: 4% nicosulfuron), every mu of preparation consumption 100 grams (2#).
(3) 40% amicarbazone fluroxypyr nicosulfuron wetting powders (20% amicarbazone: 15% fluroxypyr: 5% nicosulfuron), every mu of preparation consumption 80 grams (3#).
(4) 40% amicarbazone fluroxypyr water dispersible granule of nicosulfuron (20% amicarbazone: 16% fluroxypyr: 4% nicosulfuron), every mu of preparation consumption 100 grams (4#).
Contrast medicament and dispenser dosage:
(5) 70% amicarbazone water dispersible granules, every mu of preparation consumption 28 grams (5#).
(6) 20% fluroxypyr missible oil, every mu of preparation consumption 66 grams (6#).
(7) 4% nicosulfuron oil-suspending agents, every mu of preparation consumption 100 grams (7#).
Test site: Jiyang County, Jinan City, Shandong Province.
Subjects and method:
The main grass in field is mutually: lady's-grass, green foxtail, kitchen garden, Siberian cocklebur, lamb's-quarters.In corn 3 ~ 5 leaf phase, weeds 3 ~ 4 leaf phase, by this Herbicidal combinations according to above-mentioned every mu of preparation consumption, every mu is watered 30 liters and carries out the even cauline leaf spraying in full field.
Result of the test: in table 1.As can be seen from the test results: the average preventive effect of Herbicidal combinations of the present invention to corn field annual weed reaches more than 90%, significantly better than the single dose of contrast, synergistic effect is remarkable, and expands herbicidal spectrum, and quick-acting and lasting period are obviously better than single dose.Duration of test, has no corn and occurs symptom of chemical damage, and Herbicidal combinations of the present invention, to corn safety, affects without the underproduction.
Table 1, prevent and kill off corn field annual weed field control effectiveness test result (after medicine 21 days).

Claims (4)

1. one kind contains the Herbicidal combinations of amicarbazone and fluroxypyr and nicosulfuron, it is characterized in that: active ingredient is amicarbazone, fluroxypyr, nicosulfuron, the ratio of weight and number of amicarbazone, fluroxypyr and nicosulfuron is 1 ~ 5:1 ~ 5:1 ~ 5, and the weight summation percentage by weight in the composition of amicarbazone, fluroxypyr and nicosulfuron is 5% ~ 95%.
2. a kind of Herbicidal combinations containing amicarbazone and fluroxypyr and nicosulfuron according to claim 1, is characterized in that: described Herbicidal combinations also contains pesticidal preparations auxiliary element, to make the application forms of applicable agricultural use.
3. a kind of Herbicidal combinations containing amicarbazone and fluroxypyr and nicosulfuron according to claim 2, is characterized in that: its formulation is the one in suspending agent, oil-suspending agent, water dispersible granules, wetting powder.
4. a kind of Herbicidal combinations containing amicarbazone and fluroxypyr and nicosulfuron according to claim 1 is used for corn field seedling rear defence except the application in annual weed.
CN201410785011.5A 2014-12-16 2014-12-16 Weeding composition containing amicarbazone, fluroxypyr and nicosulfuron Pending CN104542662A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104920381A (en) * 2015-06-19 2015-09-23 陕西上格之路生物科学有限公司 Ternary weeding composite comprising amicarbazone
CN106577715A (en) * 2016-11-01 2017-04-26 广东中迅农科股份有限公司 Pesticide composition containing benzene oxazole fluridon, nicosulfuron and fluroxypyr

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1425297A (en) * 2001-12-12 2003-06-25 马韵升 Nicosulfuron herbicide composition
CN101530103A (en) * 2009-04-27 2009-09-16 陕西上格之路生物科学有限公司 Herbicide composition
CN101940218A (en) * 2010-09-13 2011-01-12 尹小根 Nicosulfuron and fluroxypyr-containing herbicidal composition
CN102283231A (en) * 2011-06-21 2011-12-21 王从爱 Oil suspending agent composition containing nicosulfuron and fluroxypyr
CN102835411A (en) * 2012-09-27 2012-12-26 广西田园生化股份有限公司 Ultralow-volume liquor containing amicarbazone
CN103120174A (en) * 2013-02-06 2013-05-29 吉林省八达农药有限公司 Weed killer composition

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1425297A (en) * 2001-12-12 2003-06-25 马韵升 Nicosulfuron herbicide composition
CN101530103A (en) * 2009-04-27 2009-09-16 陕西上格之路生物科学有限公司 Herbicide composition
CN101940218A (en) * 2010-09-13 2011-01-12 尹小根 Nicosulfuron and fluroxypyr-containing herbicidal composition
CN102283231A (en) * 2011-06-21 2011-12-21 王从爱 Oil suspending agent composition containing nicosulfuron and fluroxypyr
CN102835411A (en) * 2012-09-27 2012-12-26 广西田园生化股份有限公司 Ultralow-volume liquor containing amicarbazone
CN103120174A (en) * 2013-02-06 2013-05-29 吉林省八达农药有限公司 Weed killer composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104920381A (en) * 2015-06-19 2015-09-23 陕西上格之路生物科学有限公司 Ternary weeding composite comprising amicarbazone
CN106577715A (en) * 2016-11-01 2017-04-26 广东中迅农科股份有限公司 Pesticide composition containing benzene oxazole fluridon, nicosulfuron and fluroxypyr

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Application publication date: 20150429