CN106577683A - Herbicidal composition containing triafamone and benzobicylon - Google Patents

Herbicidal composition containing triafamone and benzobicylon Download PDF

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Publication number
CN106577683A
CN106577683A CN201611096985.8A CN201611096985A CN106577683A CN 106577683 A CN106577683 A CN 106577683A CN 201611096985 A CN201611096985 A CN 201611096985A CN 106577683 A CN106577683 A CN 106577683A
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China
Prior art keywords
benzobicylon
composition
grass amine
fluorine ketone
ketone sulphur
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CN201611096985.8A
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Inventor
毕亚玲
王曹阳
李鹏程
谷刚
金慧慧
唐梦莎
孟瑞瑞
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Anhui University of Science and Technology
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Anhui University of Science and Technology
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Priority to CN201611096985.8A priority Critical patent/CN106577683A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/661,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10Sulfones; Sulfoxides

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a herbicidal composition containing triafamone and benzobicylon. The herbicidal composition comprises a component A and a component B, wherein the component A is a mixture which comprises triafamone and benzobicylon; the component B is selected from one, two or more than two of a variety of recorded compounds, comprising bensulfuron methyl, pyrazosulfuron ethyl, cyclosulfamuron, ethoxysulfuron, cyclosulfamuron, cyhalofop-butyl, pyriminobac-methyl, 2,4-D,2-methyl-4chlorophenoxyacetic acid, propanamide, nitrofen, chlornitrofen, diuron, monuron, simazine, atrazine and prometryn. The herbicidal composition disclosed by the invention has an excellent herbicidal effect, and can effectively prevent and remove gramineous weeds, cyperaceous weeds and broadleaf weeds in paddy fields by applying pesticides once, and is further wide in weeding range and safe to rice for being a triafamone and benzobicylon compounded preparation.

Description

A kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon
Technical field
The present invention relates to weeding technique field, specially a kind of Herbicidal combination containing fluorine ketone sulphur grass amine and benzobicylon Thing.
Background technology
Fluorine ketone sulphur grass amine (triafamone) chemical name:N- { 2- [(4,6- dimethoxys -1,3,5-triazines -2- bases) carbonyls Base] -6- fluorobenzene } -1,1- difluoro-N-methyl Methanesulfomides.Fluorine ketone sulphur grass amine belongs to benzoic acid herbicide, is highly active second Acyl lactic acid synzyme (ALS) inhibitor, can be absorbed quickly after dispenser by the stem and leaf of weeds, and be conducted to whole plant, suppress to plant Thing separate living tissue grows, and so as to kill weeds, efficient, wide spectrum, consumption are extremely low, effectively prevent and kill off barnyard grass in paddy field and other grass family are miscellaneous Grass, the simultaneous barnyard grass controlled most of broad leaved weeds, some sedge weeds and produce resistance to other herbicides is such as:Barnyard grass, double fringes Ditch millet, rice Leersia Sw, Herba Digitariae, amur foxtail, northeast Tian Mao, wolf tail grass, special-shaped dried tuber, flat stalk grass, Herba monochoriae vaginaliss, Monochoria korsakowii, open country are kind The common most weeds of the rice terraces such as mushroom, Rhizoma Alismatis, Herba potamogetonis distincti, Flos Eriocauli, Herba Eleocharitis aciculariies, mexicana, Lindernia procumbens (Krock.) Phillcox..Bicyclic sulphur grass Ketone (benzobicyclon) is that the albinism rice terrace of the novel double-octane class of Japanese SDS biotech firms research and development is used Post-emergence herbicide, its exploitation code name is SB-500, and, to rice safety, being compatible with the environment property is preferable, to Fish, mammalss for the composition Animal low toxicity.The compound has bicyclic and diphenyl sulfide unique texture so that in rice terrace to Oryza sativa L. and the selectivity of weeds It is higher.Think that using between some herbicides can overcome or alleviated by crop medicine by our long-term field efficacy experiments Evil.Simultaneously as various herbicides are because of its chemical composition, the difference of physicochemical property, herbicide scope is also different.Some herbicides Herbicide scope is narrower, but has the action effect of uniqueness;The herbicidal spectrum of some herbicides is very wide, can simultaneously prevent and treat field various miscellaneous Grass.Field test shows, life-time service single herbicide not only easily produces resistance and poisoning, also soil environment can be caused compared with Big impact.The compounding of herbicide is widely regarded as one of important measures of herbicide reasonable employment, can reduce after compounding The generation of resistance, reduces poisoning of the herbicide to industrial crops, the impact to soil is reduced, so as to increase economic efficiency.Therefore We compound two kinds of effective ingredient of fluorine ketone sulphur grass amine and benzobicylon, to reaching the effect above.
The content of the invention
It is an object of the invention to provide a kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon, to solve The problem proposed in above-mentioned background technology.
For achieving the above object, the present invention provides following technical scheme:
A kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon, comprising composition A and composition B, wherein composition A For fluorine ketone sulphur grass amine and the mixture of benzobicylon composition;
Composition B is the compound of one, two or more selected from following described classes of compounds:Bensulfuron-methyl, Pyrazosulfuron, AC322140, ethoxysulfuron, grand cyclammonium sulphur, cyhalofop-butyl, KIH 6127, the chlorobenzene oxygen second of 2,4-D, 2- first -4 Acid, propionic acid amide., nitrofen, Mo 9 granular, diuron, 1,1-dimethyl-3-(p-chlorophenyl)urea, Simanex, atrazine, prometryn.
Preferably, the weight ratio of the fluorine ketone sulphur grass amine and benzobicylon is 1:0.1-1:100.
Preferably, the weight ratio of the composition A and composition B is 1:0.05-1:50.
Preferably, mixture at least also containing selected from antifreezing agent, anti-caking agent, surfactant, thickening agent, antifoaming agent and At least one agriculture chemistry adjuvant of filler.
Preferably, the antifreezing agent is selected from sodium phosphate, ammonium phosphate, sodium acetate, sodium metasilicate, magnesium sulfate, zinc sulfate and sulfur Sour calcium.
Preferably, the amount of the anti-caking agent is the 1%-2% of total formulation weight.
Preferably, the surfactant is polyalkylene oxide and their copolymer, and the amount of surfactant is preparation The 0.1%-0.6% of total amount.
A kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon according to the present invention can adopt following methods Prepare:
1) sample, composition A and composition B is pressed into 1:0.05-1:50 ratio is put in sand milling kettle, mixed grinding 2min- 5min, keeping temperature is 15 DEG C -25 DEG C, mix homogeneously;
2) will be stirred with adjuvant selected from the multiple agriculture chemistry of antifreezing agent, anti-caking agent, surfactant, antifoaming agent and filler 5min-10min is mixed, temperature is 15 DEG C -25 DEG C, is mixed and homogenization;
3) by step 2) in adjuvant be added to step 1) mixture in stir 2min-6min, be then ground into Powder, the particle diameter of sand milling to 90%-95% is less than 4 microns;
4) in step 3) addition scheduled volume thickening agent, then stir 10min-20min, temperature is 20 DEG C -40 DEG C, i.e., A kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon according to the present invention can be obtained.
The Herbicidal combinations of the present invention have excellent herbicidal effect, for example, can be used in disposably preventing and kill off in rice terrace The grassy weeds such as Herba Eleusines Indicae, Herba monochoriae vaginaliss.
Compared with prior art, the invention has the beneficial effects as follows:Herbicidal effect is excellent, can significantly improve and weeds are prevented Effect is controlled, especially there is specially good effect to rice terrace Herba Eleusines Indicae, Herba monochoriae vaginaliss, the grass family that dispenser once can be prevented and kill off effectively in rice terrace is miscellaneous Grass, sedge weed and broad leaved weed, can also expand weed control spectrum, and weeding scope is wide, delay Weed Resistance, fluorine ketone sulphur grass amine, double Preventive effect effect after ring sulphur oxadiazon and other reagents compoundings is substantially better than the imitation effect of single reagent, and the complex preparation is to water Rice safety.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
Embodiment 1
A kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon, comprising composition A and composition B, wherein composition A For fluorine ketone sulphur grass amine and the mixture of benzobicylon composition;
Composition B is the compound of one, two or more selected from following described classes of compounds:Bensulfuron-methyl, Pyrazosulfuron, AC322140, ethoxysulfuron, grand cyclammonium sulphur, cyhalofop-butyl, KIH 6127, the chlorobenzene oxygen second of 2,4-D, 2- first -4 Acid, propionic acid amide., nitrofen, Mo 9 granular, diuron, 1,1-dimethyl-3-(p-chlorophenyl)urea, Simanex, atrazine, prometryn.
The weight ratio of fluorine ketone sulphur grass amine and benzobicylon is 1:0.1.
The weight ratio of composition A and composition B is 1:0.05.
Mixture is at least also containing selected from antifreezing agent, anti-caking agent, surfactant, thickening agent, antifoaming agent and filler At least one agriculture chemistry adjuvant.
Antifreezing agent is selected from sodium phosphate, ammonium phosphate, sodium acetate, sodium metasilicate, magnesium sulfate, zinc sulfate and calcium sulfate.
The amount of anti-caking agent is the 1% of total formulation weight.
Surfactant is polyalkylene oxide and their copolymer, and the amount of surfactant is the 0.1% of preparation total amount.
A kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon, its preparation method is comprised the following steps:
1) sample, composition A and composition B is pressed into 1:0.05 ratio is put in sand milling kettle, mixed grinding 2min, keeping temperature For 15 DEG C, mix homogeneously;
2) will be stirred with adjuvant selected from the multiple agriculture chemistry of antifreezing agent, anti-caking agent, surfactant, antifoaming agent and filler 5min is mixed, temperature is 15 DEG C, is mixed and homogenization;
3) by step 2) in adjuvant be added to step 1) mixture in stir 2min, be then ground into powder, sand The particle diameter for being milled to 90%-95% is less than 4 microns;
4) in step 3) addition scheduled volume thickening agent, then stir 10min, temperature is 20 DEG C, you can obtain this A kind of bright Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon being related to.
Embodiment 2
A kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon, comprising composition A and composition B, wherein composition A For fluorine ketone sulphur grass amine and the mixture of benzobicylon composition;
Composition B is the compound of one, two or more selected from following described classes of compounds:Bensulfuron-methyl, Pyrazosulfuron, AC322140, ethoxysulfuron, grand cyclammonium sulphur, cyhalofop-butyl, KIH 6127, the chlorobenzene oxygen second of 2,4-D, 2- first -4 Acid, propionic acid amide., nitrofen, Mo 9 granular, diuron, 1,1-dimethyl-3-(p-chlorophenyl)urea, Simanex, atrazine, prometryn.
The weight ratio of fluorine ketone sulphur grass amine and benzobicylon is 1:1.
The weight ratio of composition A and composition B is 1:1.
Mixture is at least also containing selected from antifreezing agent, anti-caking agent, surfactant, thickening agent, antifoaming agent and filler At least one agriculture chemistry adjuvant.
Antifreezing agent is selected from sodium phosphate, ammonium phosphate, sodium acetate, sodium metasilicate, magnesium sulfate, zinc sulfate and calcium sulfate.
The amount of anti-caking agent is the 1.5% of total formulation weight.
Surfactant is polyalkylene oxide and their copolymer, and the amount of surfactant is the 0.4% of preparation total amount.
A kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon, its preparation method is comprised the following steps:
1) sample, composition A and composition B is pressed into 1:1 ratio is put in sand milling kettle, mixed grinding 3min, and keeping temperature is 20 DEG C, mix homogeneously;
2) will be stirred with adjuvant selected from the multiple agriculture chemistry of antifreezing agent, anti-caking agent, surfactant, antifoaming agent and filler 7min is mixed, temperature is 20 DEG C, is mixed and homogenization;
3) by step 2) in adjuvant be added to step 1) mixture in stir 4min, be then ground into powder, sand The particle diameter for being milled to 90%-95% is less than 4 microns;
4) in step 3) addition scheduled volume thickening agent, then stir 15min, temperature is 30 DEG C, you can obtain this A kind of bright Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon being related to.
Embodiment 3
A kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon, comprising composition A and composition B, wherein composition A For fluorine ketone sulphur grass amine and the mixture of benzobicylon composition;
Composition B is the compound of one, two or more selected from following described classes of compounds:Bensulfuron-methyl, Pyrazosulfuron, AC322140, ethoxysulfuron, grand cyclammonium sulphur, cyhalofop-butyl, KIH 6127, the chlorobenzene oxygen second of 2,4-D, 2- first -4 Acid, propionic acid amide., nitrofen, Mo 9 granular, diuron, 1,1-dimethyl-3-(p-chlorophenyl)urea, Simanex, atrazine, prometryn.
The weight ratio of fluorine ketone sulphur grass amine and benzobicylon is 1:100.
The weight ratio of composition A and composition B is 1:50.
Mixture is at least also containing selected from antifreezing agent, anti-caking agent, surfactant, thickening agent, antifoaming agent and filler At least one agriculture chemistry adjuvant.
Antifreezing agent is selected from sodium phosphate, ammonium phosphate, sodium acetate, sodium metasilicate, magnesium sulfate, zinc sulfate and calcium sulfate.
The amount of anti-caking agent is the 2% of total formulation weight.
Surfactant is polyalkylene oxide and their copolymer, and the amount of surfactant is the 0.6% of preparation total amount.
A kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon, its preparation method is comprised the following steps:
1) sample, composition A and composition B is pressed into 1:50 ratio is put in sand milling kettle, mixed grinding 5min, and keeping temperature is 25 DEG C, mix homogeneously;
2) will be stirred with adjuvant selected from the multiple agriculture chemistry of antifreezing agent, anti-caking agent, surfactant, antifoaming agent and filler 10min is mixed, temperature is 25 DEG C, is mixed and homogenization;
3) by step 2) in adjuvant be added to step 1) mixture in stir 6min, be then ground into powder, sand The particle diameter for being milled to 90%-95% is less than 4 microns;
4) in step 3) addition scheduled volume thickening agent, then stir 20min, temperature is 40 DEG C, you can obtain this A kind of bright Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon being related to.
In order to above three embodiment is further described into the present invention, specific examples below is set, but the present invention is absolutely It is non-to be only limited to following these embodiments.Percentage ratio is weight percentage in formula, and formulation examples are as follows:
Embodiment 4:10% fluorine ketone sulphur grass amine benzobicylon Herbicidal combinations
Embodiment 5:25% fluorine ketone sulphur grass amine benzobicylon Herbicidal combinations
Embodiment 6:10% fluorine ketone sulphur grass amine benzobicylon Herbicidal combinations
Embodiment 7:25% fluorine ketone sulphur grass amine benzobicylon Herbicidal combinations
Embodiment 8:10% fluorine ketone sulphur grass amine benzobicylon Herbicidal combinations
Embodiment 9:25% fluorine ketone sulphur grass amine benzobicylon Herbicidal combinations
Field efficacy pilot experimental technique, checking example of formulations 4-9 is below adopted to apply to rice terrace grass in land for growing field crops Section weeds and the preventive effect of broad leaved weed.
Fluorine ketone sulphur grass amine prevents and treats paddy field weed field control effectiveness test with benzobicylon Herbicidal combinations:
Test medicine:The complex composition of fluorine ketone sulphur grass amine and benzobicylon;
Controlled trial medicament 1:25% fluorine ketone sulphur grass amine suspending agent;
Controlled trial medicament 2:25% benzobicylon suspending agent;
Blank assay medicament:Clear water control treatment.
Using method:Experiment sparges each region, experimental plot by 15g/ mus, the 25g/ uniformly stem and leaf that is watered after 30L per mu Arranged using random district's groups, each is processed in triplicate, and experimental data is averaged.
Spraying time:On July 25th, 2016, in Oryza sativa L. 5-7 leaf phases, weeds in field 1-3 leaf phases, carry out stem and leaf and spray 1 time.
Dispenser place:Anhui Province Fengyang County
Investigation method and drug effect are calculated
Investigating weeds object is:The weeds such as barnyard grass, Semen Euphorbiae, Herba Digitariae, Herba monochoriae vaginaliss, Herba Eleusines Indicae, Herba Eleocharitis aciculariies, 15 after investigation My god, 40 days strain preventive effects and the fresh weight preventive effect of 40 days to weeds.
The fluorine ketone sulphur of table 1 grass amine and benzobicylon and different agents prevent and treat the test of pesticide effectiveness of paddy field weed
Test results and analysis:15g/ mus and 25g/ mus are pressed after fluorine ketone sulphur grass amine, benzobicylon and other composite reagents Consumption, carries out stem and leaf spraying treatment, has good preventive effect to paddy field weed Herba Eleusines Indicae, Herba monochoriae vaginaliss within 40 days after medicine, averagely Preventive effect is substantially better than single fluorine ketone sulphur grass amine herbicide and benzobicylon herbicide more than 89% under Isodose, high (25g/ mus) is more much better than the preventive effect of low dosage (15g/ mus) under dosage;Fluorine ketone sulphur grass amine, benzobicylon and other medicaments After compounding, the preventive effect of all embodiments grassy weed Herba Eleusines Indicae common to rice terrace and common broad leaved weed Herba monochoriae vaginaliss More than 86%, relative to fluorine ketone sulphur grass amine, two kinds of single doses of benzobicylon, complex preparation is high very to the preventive effect of two kinds of weeds It is many, both differences and its significantly, while complex preparation preventive effect of 40 days after medicine improves compared with the preventive effect of 15 days, It is little to the influential effect of preventive effect simultaneously for fluorine ketone sulphur grass amine, benzobicylon and which kind of composite reagent, it is seen then that compounding system Agent extends the lasting period, 15 days after medicine, observes within 40 days, does not find Oryza sativa L. dead seedling, yellowing leaf, growth by the poisoning phenomenon such as stagnant, It is each to process plant growth normally, illustrate that it is safe to the rice varieties tested.
To sum up field control effectiveness test result checking, Herbicidal combinations of the present invention containing fluorine ketone sulphur grass and benzobicylon, It is mainly used in preventing and kill off broad leaved weed, grassy weed and the sedge weed of rice terrace, and to Target crops safety, with single dose phase Than, Herbicidal combinations of the present invention have broad weed-killing spectrum, and ability to resist splash erosion is strong, and significantly, effective ingredient consumption is few for potentiation, Lasting period is longer, delays the obvious advantages such as the generation of herbicide resistance.The research and development and popularization of the present invention have great society's meaning Justice and environment protection significance.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding can carry out various changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention And modification, the scope of the present invention be defined by the appended.

Claims (7)

1. it is a kind of containing fluorine ketone sulphur grass amine and benzobicylon Herbicidal combinations, it is characterised in that:Comprising composition A and composition B, Wherein composition A is the mixture of fluorine ketone sulphur grass amine and benzobicylon composition;
Composition B is the compound of one, two or more selected from following described classes of compounds:Bensulfuron-methyl, pyrrole are phonetic Sulphur is grand, AC322140, ethoxysulfuron, grand cyclammonium sulphur, cyhalofop-butyl, KIH 6127, the chlorophenoxyacetic acid of 2,4-D, 2- first -4, third Amide, nitrofen, Mo 9 granular, diuron, 1,1-dimethyl-3-(p-chlorophenyl)urea, Simanex, atrazine, prometryn.
2. a kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon according to claim 1, its feature exists In:The weight ratio of the fluorine ketone sulphur grass amine and benzobicylon is 1:0.1-1:100.
3. a kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon according to claim 1, its feature exists In:The weight ratio of the composition A and composition B is 1:0.05-1:50.
4. a kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon according to claim 1, its feature exists In:Mixture at least also contains selected from antifreezing agent, anti-caking agent, surfactant, thickening agent, antifoaming agent and filler at least A kind of agriculture chemistry adjuvant.
5. a kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon according to claim 4, its feature exists In:The antifreezing agent is selected from sodium phosphate, ammonium phosphate, sodium acetate, sodium metasilicate, magnesium sulfate, zinc sulfate and calcium sulfate.
6. a kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon according to claim 4, its feature exists In:The amount of the anti-caking agent is the 1%-2% of total formulation weight.
7. a kind of Herbicidal combinations containing fluorine ketone sulphur grass amine and benzobicylon according to claim 4, its feature exists In:The surfactant is polyalkylene oxide and their copolymer, and the amount of surfactant is the 0.1%- of preparation total amount 0.6%.
CN201611096985.8A 2016-12-02 2016-12-02 Herbicidal composition containing triafamone and benzobicylon Pending CN106577683A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107136110A (en) * 2017-06-08 2017-09-08 南京红太阳股份有限公司 A kind of Herbicidal combinations and its application containing the bicyclic ketone of benzo and ethoxysulfuron
CN109463228A (en) * 2018-09-28 2019-03-15 湖南省植物保护研究所 A kind of method of non-pesticide control bakanae disease of rice
CN112931509A (en) * 2021-03-08 2021-06-11 合肥尚邦植保科技有限公司 Herbicide containing benzobicyclon and MCPA (dimethyl tetrachloro isooctyl ester)
CN114145302A (en) * 2021-11-29 2022-03-08 江苏省农业科学院 Weeding composition for preventing and removing weeds in rice and shrimp fields and application thereof

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CN101636085A (en) * 2007-02-19 2010-01-27 拜尔作物科学股份公司 Herbicidal compositions comprising difluoromethanesulfonylanilide and one or more herbicides
CN102186344A (en) * 2008-08-14 2011-09-14 拜尔农作物科学股份公司 Herbicidal combination comprising dimethoxy-triazinyl-substituted difluoromethane sulfonylanilides
WO2014033242A1 (en) * 2012-08-31 2014-03-06 Basf Se Use of an agrochemical composition with herbicidal action in rice
CN105494360A (en) * 2015-12-20 2016-04-20 北京燕化永乐生物科技股份有限公司 Compound herbicide

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1105023A (en) * 1992-03-18 1995-07-12 Sds生物技术株式会社 Substituted benzoyl cyclic enone, process for preparation, and herbicide
CN101636085A (en) * 2007-02-19 2010-01-27 拜尔作物科学股份公司 Herbicidal compositions comprising difluoromethanesulfonylanilide and one or more herbicides
CN102186344A (en) * 2008-08-14 2011-09-14 拜尔农作物科学股份公司 Herbicidal combination comprising dimethoxy-triazinyl-substituted difluoromethane sulfonylanilides
WO2014033242A1 (en) * 2012-08-31 2014-03-06 Basf Se Use of an agrochemical composition with herbicidal action in rice
CN105494360A (en) * 2015-12-20 2016-04-20 北京燕化永乐生物科技股份有限公司 Compound herbicide

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107136110A (en) * 2017-06-08 2017-09-08 南京红太阳股份有限公司 A kind of Herbicidal combinations and its application containing the bicyclic ketone of benzo and ethoxysulfuron
CN109463228A (en) * 2018-09-28 2019-03-15 湖南省植物保护研究所 A kind of method of non-pesticide control bakanae disease of rice
CN112931509A (en) * 2021-03-08 2021-06-11 合肥尚邦植保科技有限公司 Herbicide containing benzobicyclon and MCPA (dimethyl tetrachloro isooctyl ester)
CN114145302A (en) * 2021-11-29 2022-03-08 江苏省农业科学院 Weeding composition for preventing and removing weeds in rice and shrimp fields and application thereof

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