CN107836452B - Weeding composition containing triazasulam and application thereof - Google Patents

Weeding composition containing triazasulam and application thereof Download PDF

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Publication number
CN107836452B
CN107836452B CN201711095793.XA CN201711095793A CN107836452B CN 107836452 B CN107836452 B CN 107836452B CN 201711095793 A CN201711095793 A CN 201711095793A CN 107836452 B CN107836452 B CN 107836452B
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polyoxyethylene ether
percent
triazophone
evaluation
actual control
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CN107836452A (en
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彭学岗
赵德
张景远
刘娜
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Hunan academy of agricultural sciences
Institute For Pesticide Control Ministry Of Agriculture And Rural Areas
NATIONWIDE AGRICULTURAL TECHNOLOGY PROMOTION SERVICE CENTER
Qingdao Qingyuan Crop Science Co ltd
Guizhou University
Shandong Agricultural University
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Qingdao Kingagroot Chemical Compound Co Ltd
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Priority to CN201711095793.XA priority Critical patent/CN107836452B/en
Priority to CN202110266478.9A priority patent/CN112998022B/en
Priority to PCT/CN2017/112016 priority patent/WO2019090814A1/en
Publication of CN107836452A publication Critical patent/CN107836452A/en
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • A—HUMAN NECESSITIES
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
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    • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04—Aryloxy-acetic acids; Derivatives thereof
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    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A01N41/06—Sulfonic acid amides
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
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    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
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    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
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    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
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    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
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    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
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    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
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    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
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Abstract

The invention belongs to the field of pesticides, and particularly relates to a weeding composition containing triazophos-ethyl and application thereof. The composition comprises active ingredients A and B with effective weeding amount, wherein A is the triazophone, and B can be selected from one or more of the following compounds: VLCFA, PPO, PSII, ALS, microtubule assembly, HPPD, PDS, lipid synthesis, EPSPS, GS, PSI, DHP inhibitors and synthetic hormones. The composition can effectively prevent and kill barnyard grass, moleplant seed, descurainia sophia, caraway sinia, monochoria vaginalis, cyperus rotundus and other weeds in crop fields, and has the characteristics of expanding weed control spectrum, reducing application amount, being safe to crops, generating synergistic action, solving resistant weeds and the like.

Description

Weeding composition containing triazasulam and application thereof
Technical Field
The invention belongs to the field of pesticides, and particularly relates to a weeding composition containing triazophos-ethyl and application thereof.
Background
Chemical weeding is the most economic and effective means in preventing and removing weeds in farmlands, but the problems of drug resistance and resistance evolution of weeds and the like are easily caused by using a single variety or a single action mode of chemical herbicide continuously at a high dose for a long time.
The chemical structural formula of the triazophone is shown as
Figure GDA0001703049990000011
Belongs to HPPD enzyme inhibitor compounds, belongs to systemic conduction herbicides, can be absorbed by various ways such as leaves, roots and stems of weeds, and is not easy to cause green turning and relapse. The action mechanism of the compound is that the activity of key chromoenzyme for photosynthesis is controlled by inhibiting a plant body, so that the process of converting a substrate into the homogentisic acid is hindered, the normal synthesis of tocopherol and plastoquinone cannot be realized, the synthesis of carotenoid in a target body is influenced, the yellow and white leaves are caused, the normal operation of the photosynthesis in the plant body is influenced, and finally the plant body is completely dead.
The reasonable compounding or mixing of the herbicide compound has the advantages of expanding the weed spectrum, improving the control effect, delaying the occurrence and development of drug resistance and drug resistance of weeds and the like, and is one of the most effective methods for solving the problems. Therefore, the development of a weeding composition variety which has high safety and wide weed control spectrum, can produce synergistic effect and solve the problem of resistant weeds is urgently needed in production.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides a weeding composition containing triazophodim and application thereof. The composition can effectively prevent and kill barnyard grass, moleplant seed, descurainia sophia, caraway sinia, monochoria vaginalis, cyperus rotundus and other weeds in crop fields, and has the characteristics of expanding weed control spectrum, reducing application amount, being safe to crops, generating synergistic action, solving resistant weeds and the like.
A weeding composition containing triazophos-cotrione comprises an active ingredient A and an active ingredient B, wherein the active ingredient A is the triazophos-cotrione, and the active ingredient B can be selected from one or more of the following compounds:
(1) VLCFA inhibitors, metolachlor (CAS accession No. 178961-20-1), flufenacet (CAS accession No. 142459-58-3), alachlor (CAS accession No. 15299-99-7), xaflufen (CAS accession No. 447399-55-5), dimethenamid (CAS accession No. 87674-68-8), cafenstrole (CAS accession No. 125306-83-4), propisochlor (CAS accession No. 86763-47-5), diflufenican (CAS accession No. 67129-08-2), propachlor (CAS accession No. 1918-16-7), dinalin (CAS accession No. 106700-29-2);
(2) PPO inhibitors, fomesafen (CAS registry number: 72178-02-0), flumioxazin (CAS registry number: 103361-09-7), tiafenacil (CAS registry number: 1220411-29-9), saflufenacil (CAS registry number: 372137-35-4), pyraflufen (CAS registry number: 129630-19-9);
(3) PSII inhibitors atrazine (CAS registry number: 102029-43-6), terbutryn (CAS registry number: 886-50-0), ametryn (CAS registry number: 834-12-8), ipratron (CAS registry number: 4147-51-7), fenfluramine (CAS registry number: 845-52-3), diuron (CAS registry number: 1014-69-3), simazine (CAS registry number: 122-34-9), metribuzin (CAS registry number: 21087-64-9), ethiprole (CAS registry number: 64529-56-2), metamitron (CAS registry number: 41394-05-2), cyhalofop (CAS registry number: 21725-46-2), chlortoluron (CAS registry number: 45-48-9), diuron (CAS registry number: 330-54-1), Fluometuron (CAS accession No. 2164-17-2), linuron (CAS accession No. 330-55-2), buthiuron (CAS accession No. 34014-18-1), chlorsulfuron (CAS accession No. 1746-81-2), bromuron (CAS accession No. 3060-89-7), glufosinate (CAS accession No. 555-37-3), pyridazinol (CAS accession No. 40020-01-7), hexazinone (CAS accession No. 51235-04-2), isoethazine (CAS accession No. 22936-75-0), prodazine (CAS accession No. 1912-26-1), cyclamen (CAS accession No. 2164-08-1), terbacil (CAS accession No. 5902-51-2), methabenzthiaron (CAS accession No. 18691-97-9), Cyclosulfamuron (CAS registry No.: 1982-49-6), isooxanone (CAS registry No.: 55861-78-4), metoxuron (CAS registry No.: 19937-59-8), subtilin (CAS registry No.: 1982-47-4), trifluoxazine (CAS registry No.: 1258836-72-4), betalain (CAS registry No.: 13684-56-5), betanine (CAS registry No.: 13684-63-4);
(4) ALS inhibitors tribenuron-methyl (CAS accession No.: 101200-48-0), thifensulfuron-methyl (CAS accession No.: 79277-27-3), thiencarbazone-methyl (CAS accession No.: 317815-83-1), rimsulfuron (CAS accession No.: 122931-48-0), flucarbazone-methyl (CAS accession No.: 181274-17-9), mesosulfuron-methyl (CAS accession No.: 208465-21-8), nicosulfuron (CAS accession No.: 111991-09-4), foramsulfuron (CAS accession No.: 173159-57-4), flumetsulam (CAS accession No.: 98967-40-9), triafamone-sodium (CAS accession No.: 96525-23-4), cloransulam-methyl (CAS accession No.: 147150-35-4), pyroxsulam-methyl (CAS accession No.: 422556-08-9), Imazamox (CAS accession No. 114311-32-9), imazapic (CAS accession No. 104098-48-8), imazethapyr (CAS accession No. 81385-77-5), imazapyr (CAS accession No. 81334-34-1);
(5) microtubule assembly inhibitors, trifluralin (CAS accession number: 1582-09-8), dimethomorph (CAS accession number: 33629-47-9), ethambucil (CAS accession number: 55283-68-6), oryzalin (CAS accession number: 19044-88-3), flumetsulam (CAS accession number: 1861-40-1), thiabendazole (CAS accession number: 117718-60-2), norflurazone (CAS accession number: 23950-58-5), dichlorvos (CAS accession number: 1861-32-1), and phorate (CAS accession number: 36335-67-8);
(6) HPPD inhibitors sulcotrione (CAS registry number: 99105-77-8), topramezone (CAS registry number: 1992017-55-6), topramezone (CAS registry number: 365400-11-9), tolpyralate (CAS registry number: 1101132-67-5), fenquinotrione (CAS registry number: 1342891-70-6), isoxaflutole (CAS registry number: 141112-29-0);
(7) (iii) the PDS inhibitors flurtamone (CAS registry number: 61213-25-0), flurtamone (CAS registry number: 96525-23-4), diflufenican (CAS registry number: 83164-33-4), diflufenican (CAS registry number: 137641-05-5), beflubutamid (CAS registry number: 113614-08-7), norflurazon (CAS registry number: 27314-13-2), fluridone (CAS registry number: 59756-60-4);
(8) lipid synthesis (non-acetyl coenzyme A carboxylase) inhibitors, including prosulfocarb (CAS accession number: 52888-80-9), benfuresate (CAS accession number: 68505-69-1), ethofumesate (CAS accession number: 26225-79-6), triallate (CAS accession number: 2303-17-5), ethaboxam (CAS accession number: 28249-77-6), dichlorflufen (CAS accession number: 1929-77-7), butamolinate (CAS accession number: 2008-41-5), dichlormate (CAS accession number: 1134-23-2), penflufen (CAS accession number: 61432-55-1), penflufen (CAS accession number: 85785-20-2);
(9) synthetic hormones including fluroxypyr-meptyl ester (CAS accession No. 81406-37-3), triclopyr (CAS accession No. 55335-06-3), clopyralid (CAS accession No. 1702-17-6), picloram (CAS accession No. 1918-02-1), dicamba (CAS accession No. 1918-00-9), 2-methyl-4-chlorophenoxyacetic acid (CAS accession No. 94-74-6), 2-methyl-4-chlorophenoxyacetic acid thioester (CAS accession No. 25319-90-8), MCPB (CAS accession No. 94-81-5), 2-methyl-4-chlorophenoxypropionic acid (CAS accession No. 93-65-2), sodium 2-methyl-4-chlorophenoxyacetate (CAS accession No. 3653-48-3), Isooctyl 2-methyl-4-chlorophenoxyacetate (CAS registry number: 29450-45-1), butyl 2, 4-dichlorophenoxyacetate (CAS registry number: 94-80-4), isooctyl 2, 4-dichlorophenoxyacetate (CAS registry number: 25168-26-7), 2, 4-dichlorophenoxyacetic acid (CAS registry number: 94-75-7), 4- (2, 4-dichlorophenoxy) propionic acid (CAS registry number: 120-36-5), clomequinic acid (CAS registry number: 90717-03-6), 2-methyl-4-chlorobutyric acid (CAS registry number: 94-81-5), 2, 4-D-butyric acid (CAS registry number: 94-82-6);
(10) EPSPS inhibitors, phosphinothricin (CAS accession number: 81591-81-3);
(11) GS inhibitors include bialaphos (CAS registry No. 35597-43-4), glufosinate-ammonium (CAS registry No. 35597-44-5);
(12) PSI inhibitors paraquat (CAS registry number: 1910-42-5), diquat (CAS registry number: 6385-62-2);
(13) the DHP inhibitor is asulam (CAS accession number: 3337-71-1);
(14) others (CAS registry No.: 87818-31-3).
Wherein the weight ratio of A to B is 1:200-200:1, preferably 1:150-150:1, more preferably 1:120-120: 1; further, the weight ratio of A and B is 1:100-100:1, preferably 1:80-80:1, more preferably 1:50-50: 1; further, the weight ratio of A and B is 1:30 to 30:1, preferably 1:10 to 10:1, more preferably 1:5 to 5: 1.
The mass percentage of A, B in the weeding composition accounts for 1-95% of the total amount, and preferably 10-80%.
The weeding composition also comprises conventional auxiliaries which comprise a carrier and a surfactant.
The term "carrier" herein denotes an organic or inorganic, natural or synthetic substance. They facilitate the application of the active ingredient, the carrier being generally inert and must be agriculturally acceptable, in particular for the treated plant. The carrier may be a solid, such as a clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, or the like; or liquids such as water, alcohols, ketones, petroleum distillates, aromatic or waxy hydrocarbons, chlorinated hydrocarbons, liquefied gases, etc.
Surfactants may include emulsifying, dispersing or wetting agents, which may be ionic or non-ionic. Examples which may be mentioned are salts of polyacrylic acids, lignosulphonates, salts of phenolsulphonic or naphthalenesulphonic acids, polymers of ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols, in particular alkylphenols or arylphenols, sulphosuccinates, taurine derivatives, in particular taurine alkyl esters, and phosphoric esters of alcohols or polyhydroxyethylated phenols, alkylsulfonates, alkylarylsulphonates, alkylsulfates, lauryl ether sulphates, fatty alcohol sulphates, and sulphated hexadec, heptadeca-and octadecanols and sulphated fatty alcohol glycol ethers, and furthermore condensates of naphthalene or naphthalenesulphonic acids with phenol and formaldehyde, polyoxyethylene octylphenyl ether, ethoxylated isooctylphenol, octylphenol or nonylphenol, alkylphenyl polyglycol ethers, tributylphenyl polyglycol ether, tristearylphenyl polyglycol ether, polystearylphenyl polyglycol ether, Alkylaryl polyether alcohols, alcohol and fatty alcohol/ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers, ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal, sorbitol esters, lignosulfite waste liquors, and also proteins, denatured proteins, polysaccharides (e.g. methylcellulose), hydrophobically modified starches, polyvinyl alcohols, polycarboxylates, polyalkoxylates, polyvinylamines, polyvinylpyrrolidone and copolymers thereof. At least one surfactant is required to be present to facilitate dispersion of the active ingredients in water and to facilitate their proper application to the plant.
The compositions may also contain various other components such as protective colloids, binders, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants, and polymers.
The compositions of the present invention may be diluted or used directly by the user prior to use. The formulation can be prepared by conventional processing methods, i.e., mixing the active substance with a liquid solvent or solid carrier, and adding one or more surfactants such as dispersants, stabilizers, wetting agents, binders, defoamers, etc.
The specific preparation of the weeding composition is dispersible oil suspending agent, water suspending agent, suspending emulsion, wettable powder, missible oil, water dispersible granule (dry suspending agent), emulsion in water and microemulsion.
In short, the compositions of the present invention may be mixed with solid and liquid additives conventionally used in prior art formulations.
In addition, the combination of compounds A and B may be mixed with active substances known, for example, from the "encyclopedia of New agricultural chemical products, technology, China agricultural science and technology Press, 2010.9 and the references cited therein. For example, herbicidal active substances mentioned below (remarks: the name of the compound, or the generic name according to the International organization for standardization (ISO), or the chemical name, when appropriate with a code), acetochlor, butachlor, alachlor, propisochlor, metolachlor, s-metolachlor, pretilachlor, propachlor, butachlor, napropamide, R-laevo-napropamide, propanil, mefenacet, diphenoyl-oxamide, diflufenican, flumetsulam, bebutamid, dimethenamid, ethoxybenclamide, flufenacet, methoxyfenacet, metazachlor, isooxachlor, lofluvalinate, dimethenamid, butachlor, propisochlor, mefenamid, flucetochlor, propyzamide, dimethenamid, Terbutamid, dimethenamid, dimethachlor, norfluramine, trifoliamine, chlorantraniliprole, propyzamide, penflufen, napropamide, acetometazachlor, naproxen, fenacet, pyraflufen, metolachlor, clofenamide, butachlor, butamidin, fluazinam, atrazine, simazine, prometryn, cyanazine, simetryn, ametryn, prometryn, ipretryn, fluroxypyr, terbutryn, terbutazine, triazineon, cyhalofop, ganciclovir, prometryn, simazine, triazazine, dimethametrazine, isopentetryn, cycloprozine, terbutryn, sec-butyn, terbutaline, terbutryn, metolachlor, cyhalofop, metolachlor, prometryn, simazine, atrazine, dimethametryn, dimethametin, terbutryn, metolachlor, dimethachlor, dimethozin, atrazine, metolachloraz, metolachlor, metolac, Cyanuric acid, Indaziflam, chlorsulfuron, metsulfuron, bensulfuron-methyl, chlorimuron-ethyl, tribenuron-methyl, thifensulfuron-methyl, pyrazosulfuron-ethyl, mesosulfuron-methyl, iodosulfuron-methyl sodium, formamidosulfuron, cinosulfuron, triasulfuron, sulfometuron-methyl, nicosulfuron, ethametsulfuron-methyl, amidosulfuron, ethoxysulfuron, cyclosulfamuron-methyl, rimsulfuron, azimsulfuron-methyl, monosulfuron-methyl, primisulfuron-methyl, flusulfuron-methyl, flazasulfuron-methyl, propsulfuron-methyl, prosulfuron-methyl, trifloxysulfuron, triflusulfuron-methyl, metsulfuron-methyl, primisulfuron-methyl, propulsulfuron-methyl, propaferon-methyl, triflusulfuron-methyl, sulfometuron-methyl, pyrisulfuron-methyl, propalis-ethyl, thiuron-methyl, sulfometuron-methyl, sulfometuron-ethyl, sulfometuron-ethyl, sulfofluridone, sulfometuron-ethyl, sulfofluridone, sulfometuron, sulfo, Dicumyl ether, aclonifen, ethoxyfen-ethyl, bifenox, trifluoromethoxyfen, metoxyfen, trifluornitrofen, fluoroglycofen, fluridone, bifenox, dimethofen, fluazifop-butyl, Halosafen, chlortoluron, isoproturon, linuron, diuron, fenpropuron, fluometuron, methabenzthiazuron, benzuron, sulfosulfuron, clofenuron, tebuthiuron, clodinuron, meturon, metoxuron, bromuron, metoxuron, meturon, metoxuron, metoron, Betalain, asulam, tefurazone, avenacin, anilazine, chlorpropham, dichlofenamate, imazalil, cloropham, Carboxazole, chlorerprocarb, Fenasulam, BCPC, CPPC, Carbasulam, buticarb, thiobencarb, dimethenate, triallate, thiobencarb, dicofol, pyributicarb, chlochloate, dichlorfon, dodekafol, ethiofencarb, captan, prosulfocarb, thiobencarb, promethate, Isopolinate, Methiobencarb, 2, 4-chlorobutyl ester, 2 methyl 4-sodium chloride, 2, 4-chloroisooctyl ester, 2 methyl 4-chloroisooctyl ester, 2, 4-d sodium salt, 2, 4-dimethylxylyl ester, 2 methyl 4-chlorothioester, 2 methyl 4-chloropropionate, 2-methyl 4-chloropropionate, 2-4-chlorobutyric acid, 2-methyl 4-chlorobutyric acid, 2-chloro-4-methyl-butyric acid, 2, 4-chloro-4-methyl-4-chloro-butyric acid, 2-4-chloro-methyl-4-, 5-nasal discharge, 2,4, 5-nasal discharge propionic acid, 2,4, 5-nasal discharge butyric acid, 2-methyl-4-chloramine salt, dicamba, fenoxaprop-P-ethyl, varparvax, cyprosulfan, triclosan, dichlorfenac, metoclopramide, diclofop-p-ethyl, fluazifop-methyl, haloxyfop-p-ethyl, quizalofop-p-ethyl, fenoxaprop-p-ethyl, haloxyfop-ethyl, metamifop-ethyl, clomazone, benazol-ethyl, clodinafop-ethyl, oxyphenbutazone-ethyl, trifluoxime, isoxafen, paraquat, diquat, asulam, flutolfen, ethalfluron, terbufin, chloroethafluorin, mefenofos, benazol-p-ethyl, metocloprid, meprobamate, glufosinate, glyphosate, glufosinate, metocloprid, bensulam, glyphosate, bensulam, thiophosphoryl, piperazinone, bialaphos, bensulide, imazapyr, glufosinate, imazapyr, imazethapyr, imazaquin ammonium salt, imazapic, imazamethabenz ester, fluroxypyr, isooctyl fluroxypyr, clopyralid, picloram, triclopyr, dithiopyr, haloxydine, triclopyr, thiazopyr, aminopyralid, fluroxypyr, butoxyethyl triclopyr, Cliodinate, sethoxydim, cycloxydim, bentazone, metamitron, cycloxydim, benzone, tralkoxydim, metribuzin, amitridione, amibizin, bromoxynil, octanoyl nitrile, fenpropinil, pyrazoxynil, iodoxynil, haloxynil, haloxy, Oxypyr, Iodobonil, flumetsulam, florasulam, penoxsulam, sulfentrazone, cloransulam, diclosulam, pyroxsulam, fluroxypyr, bispyribac, pyribenzoxim, pyriminobac, pyrithiobac, bicyclophorione, mesotrione, sulcotrione, Tembotrione, Tefuryltrione, Bicyclopyrone, ketendidox, isoxaflutole, fenoxasulfofone, methiozolinin, ipropyr, pyraflufen, pyraflutole, pyroxaflutole, Pyroxasulfone, pyraflutole, Pyrasulfotole, pyraflutole, amicarbazone, flumiclazone, flumetsulam, mefenpyr, bensulam, bexathion, flumicloram, flumiclone, flumicloram, pyrazam, pyraflufenacetmol, pyraclofenacetmol, pyraclorac, pyraclofenap, flumiclone, flumicloram, flumicl, Terbenol, terbutal, penitrol, dinitrophenol, chloronitrophenol, dimethomorph, oxadiargyl, oxadiazon, pentoxazone, flumetsulam, mefenoxaprop, fentrazamide, fluazifop-ethyl, desmetryn, bromatrazine, dimetaluron, pyridaben, Pyridafol, quinclorac, clomazone, bentazon, pyridate, oxadiargyl, benazolin, clomazone, cumquat-ethyl, propyl isopropyl ether, clofenpropathrin, indangrone, sodium chlorate, dalapon, trichloroacetic acid, monochloroacetic acid, hexachloroacetone, tetrafluoropropionic acid, mefenpyr, bromophenol oxime, triazasum, pyrazole, flurtamone, benfuresafen, ethofencarbazone, pyrimethanil, clodinafol, flutolanilide, acrolein, mefenapyr, clodinil, pyraclonil, pyra, Metophenone, saflufenacil, chlorantraniliprole, trichloropropionic acid, Alorac, Diethamquat, Etnipromid, Iphrymam, Ipfancabazone, Thiencabazone-methyl, Pyrimisulfan, Chrerfluorazole, Tripropindan, Sulglycasin, Sumbellichler, Cambodhi, cyprodinic acid, thiocyananilide, cloquintocet, fencloquine, mequintocet, mefenapyr, mefenpyr, furazolidone, imazaquin, flufenpyr, isoxadifen, dichlormid, halauxin, halauxifen, DOWFAUD, UBH-509, D489, LS 82-556, KPP-300, NC-324, NC-330, DPX-218, DPX-N-89, TPOWN-0744, KIH-927, KIH-18-K-75, KC-3, KC-751, MBH-3, and PKH-751.
The herbicidal composition further includes a safener selected from one or more of isoxadifen (CAS registry number: 163520-33-0), cyprosulfamide (CAS registry number: 221667-31-8), mefenpyr (CAS registry number: 135590-91-9), cloquintocet (CAS registry number: 99607-70-2), gibberellic acid (CAS registry number: 77-06-5), furilazole (CAS registry number: 121776-33-8), mecamifen (CAS registry number: 129531-12-0).
The compositions of the invention can be applied by spraying to the foliage of the plants to be treated, i.e. to the weeds, in particular to surfaces which are harmful or susceptible to infestation by weeds which are harmful to the growth of the crop.
When the herbicidal composition of the present invention is applied, an unexpected synergistic effect is obtained, and the herbicidal activity is more remarkable than the expected sum of the activities using individual herbicides, and the activities of the individual herbicides alone. The synergistic effect is manifested by reduced application rates, a broader spectrum of weed control, and a faster and longer lasting herbicidal action, which are desirable in the practice of weed control. These new compositions are clearly superior to existing herbicides in terms of the properties described.
The herbicidal composition of the present invention also has the following advantages:
(1) the composition is environment-friendly, is easy to degrade in the environment, and is suitable for various crop fields.
(2) The weeding composition has low cost and convenient use, and has great economic and social benefits when being popularized and applied.
Detailed Description
The following examples are not intended to limit the invention, but merely to illustrate how the invention may be carried out. These examples show particularly significant effectiveness against certain weeds. Examples are as follows:
A) examples of the embodiments
1. 46% Triazolesulfonylfop-s-metolachlor suspoemulsion (6+40)
6 percent of triazophone, 40 percent of s-metolachlor, 5 percent of 150# solvent oil, 3 percent of phenethyl phenol polyoxyethylene ether sulfonate triethanolamine salt dispersant, 1 percent of phenethyl phenol polyoxyethylene ether, 2.5 percent of castor oil polyoxyethylene ether, 0.06 percent of xanthan gum, 5 percent of glycerol and water.
2. 22% Triazolesulfonylmefone-flufenacet suspension (12+10)
The composition is prepared by adding 12% of triazophone, 10% of flufenacet, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of propylene glycol block polyether dispersant, 1% of fatty alcohol polyoxyethylene ether, 0.18% of xanthan gum, 1.8% of magnesium aluminum silicate, 5% of glycerol and water.
3. 28% Triazolesulfonylzone-napropamide suspending agent (3+25)
3% of triazophone, 25% of alachlor, 5% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
4. 55% Triazolesulfonate-asulam water dispersible granule (2.25+52.75)
2.25 percent of triazophone, 52.75 percent of asulam, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
5. 32% Triazolesulfonylzone-pyraflufen-ethyl suspending agent (12+20)
12% of triazophone, 20% of Sulfuron pyrazoxazole, 5% of polycarboxylate dispersant, 2% of fatty alcohol-polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
6. 18% Triazolesulfonylmefone-dimethenamid dispersible oil suspension agent (3+15)
3% of triazophone, 15% of xylenol oxamine, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.6% of organobentonite, 1.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
7. 27% Triazolesulfonylmefone-cafenstrole suspension (12+15)
The composition is prepared by adding 12% of triazophone, 15% of cafenstrole, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water to balance.
8. 28% Triazolesulfonylmefone-propisochlor suspoemulsion (3+25)
3% of triazophone, 25% of propisochlor, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 2% of castor oil polyoxyethylene ether, 0.14% of xanthan gum, 5% of glycerol and water.
9. 31% Triazolesulfonylfop-metazachlor suspoemulsion (6+25)
6% of triazophone, 25% of metazachlor, 10% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.14% of xanthan gum, 5% of glycerol and water.
10. 41% Triazolesulfonone-propyzamide suspoemulsion (3+38)
3% of triazophone, 38% of propyzamide, 5% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.12% of xanthan gum, 5% of glycerol and water.
11. 43% Triazolesulfonylfop-fenacet suspoemulsion (3+40)
3% of triazophone, 40% of dimethenamid, 5% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.13% of xanthan gum, 5% of glycerol and water.
12. 9% Triazolesulfonylzone-fomesafen suspension (3+6)
3% of triazophone, 6% of fomesafen, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.22% of xanthan gum, 2.0% of magnesium aluminum silicate, 5% of glycerol and water.
13. 18% Triazolesulfonylfop-flumioxazin suspension (12+6)
12% of triazophone, 6% of flumioxazin, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.18% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
14. 28% Triazolesulfonyltolone-tiafenacil suspension (24+4)
24% of triazophone, 4% of tiafenacil, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
15. 12% Triazolesulfonylmefone-saflufenacil dispersible oil suspending agent (9+3)
9% of triazophone, 3% of saflufenacil, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 3.0% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
16. 10% Triazolesulfonylzone-pyraflufen dispersible oil suspension concentrate (9+1)
9% of triazophone, 1% of pyraflufen-ethyl, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
17. 50% Triazolesulfonylfonone-atrazine suspension (12+38)
12% of triazophone, 38% of atrazine, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol-polyoxyethylene ether, 0.08% of xanthan gum, 5% of glycerol and water.
18. 33% Triazolesulfonyluzolne terbutryn suspension (3+30)
3% of triazophone, 30% of terbutryn, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.14% of xanthan gum, 1.4% of magnesium aluminum silicate, 5% of glycerol and water.
19. 43% Triazolesulfonylfonone-ametryn suspension (3+40)
3% of triazophone, 40% of ametryn, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 5% of glycerol and water.
20. 53% Triazolesulfonyluzone-iprovalbumin suspension (3+50)
3% of triazophone, 50% of iprclean, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.06% of xanthan gum, 5% of glycerol and water.
21. 53% Triazolesulfonylzone-phytocide suspending agent (3+50)
3% of triazophone, 50% of fenfluramine, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol-polyoxyethylene ether, 0.06% of xanthan gum, 5% of glycerol and water.
22. 44% triazophone-diuron suspending agent (6+38)
6 percent of triazophone, 38 percent of dimethomorph, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.1 percent of xanthan gum, 0.5 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
23. 33% Triazolesulfonylmefone-simazine suspension (3+30)
3% of triazophone, 30% of simazine, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.14% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
24. 19% Triazolesulfonylfonone metribuzin suspending agent (4+15)
4% of triazophone, 15% of metribuzin, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.18% of xanthan gum, 2.0% of magnesium aluminum silicate, 5% of glycerol and water.
25. 30% Triazolesulfonylmefone-ethiziclomazone suspending agent (6+24)
6% of triazophone, 24% of ethizine, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
26. 67% triazophone-metamitron water dispersible granule (2+65)
2% of triazophone, 65% of metamitron, 8% of polycarboxylate dispersant, 6% of nekal, 1% of disintegrant polyvinyl alcohol, 5% of precipitated white carbon black and filler diatomite.
27. 28% Triazolesulfonylzone-cyanazine suspending agent (3+25)
3% of triazophone, 25% of cyanazine, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.8% of magnesium aluminum silicate, 5% of glycerol and water.
28. 53% Triazolesulfonylzone-chlortoluron suspending agent (3+50)
3% of triazophone, 50% of chlortoluron, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol-polyoxyethylene ether, 0.06% of xanthan gum, 5% of glycerol and water.
29. 36% Triazolesulfonylzone diuron suspending agent (6+30)
6 percent of triazophone, 30 percent of diuron, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.15 percent of xanthan gum, 1.5 percent of magnesium aluminum silicate, 5 percent of glycerol and water for complement.
30. 46% Triazolesulfonylzone-fluridone suspending agent (6+40)
6 percent of triazophone, 40 percent of fluometuron, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.1 percent of xanthan gum, 1.0 percent of magnesium aluminum silicate, 5 percent of glycerol and water for complement.
31. 28% Triazolesulfonylzone-linuron suspension (3+25)
3% of triazophone, 25% of linuron, 4% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
32. 33% Triazolesulfonylzone-buthiuron suspension concentrate (3+30)
3% of triazophone, 30% of buthiuron, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
33. 53% Triazolesulfonylzone-Chloruron suspension (3+50)
3% of triazophone, 50% of chlorsulfuron, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol-polyoxyethylene ether, 0.06% of xanthan gum, 5% of glycerol and water.
34. 39% Triazolesulfonylzone-bromogluron suspending agent (6+33)
6% of triazophone, 33% of bromogluron, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 5% of glycerol and water.
35. 67% Triazolesulfonylzone-glufosinate water dispersible granules (3+64)
3 percent of triazophoron, 64 percent of metsulfuron, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
36. 39% Triazolesulfonylzone-pyridazinol suspension (6+33)
6% of triazophone, 33% of pyridazinol, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 5% of glycerol and water.
37. 41% Triazolesulfonylfonone-hexazinone suspending agent (3+38)
3% of triazophone, 38% of hexazinone, 4% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 5% of glycerol and water.
38. 45% triazophone-isoamyl ethyne suspending agent (3+42)
3% of triazophone, 42% of isoamyl alcohol, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.08% of xanthan gum, 0.8% of magnesium aluminum silicate, 5% of glycerol and water.
39. 43% Triazolesulfonylfop-madzur suspension (3+40)
3% of triazophone, 40% of atrazine, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 5% of glycerol and water.
40. 46% Triazolesulfonylzone-cyclamate suspending agent (6+40)
6 percent of triazophone, 40 percent of cyclamate, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol-polyoxyethylene ether, 0.08 percent of xanthan gum, 0.5 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
41. 63% Triazolesulfonylzone-terbacil water dispersible granule (3+60)
3 percent of triazophone, 60 percent of terbacil, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
42. 26% Triazolesulfonylzone-methylthiosulfuron suspension (12+14)
12% of triazophone, 14% of metibolone, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.13% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
43. 63% Triazolesulfonylzone-cyclosulfamuron water dispersible granule (3+60)
3 percent of triazophone, 60 percent of cyclosulfamuron, 6 percent of polycarboxylate dispersant, 4 percent of sodium dodecyl sulfate, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
44. 36% Triazolesulfonylmefonone-isooxaron suspending agent (3+33)
3% of triazophone, 33% of isooxauron, 4% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.14% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
45. 70% triazophone-metoxuron water dispersible granule (3+67)
3 percent of triazophone, 67 percent of metoxuron, 5 percent of polycarboxylate dispersant, 5 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
46. 70% triazophone-subtilon water dispersible granule (3+67)
3 percent of triazophone, 67 percent of Sulfuron, 6 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
47. 32% Triazolesulfonylzone-trifluoxazine suspension (12+20)
12% of triazophone, 20% of trifluoxazine, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.14% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
48. 36% Triazolesulfonylmefone-desmedian suspension (4.5+31.5)
4.5 percent of triazophone, 31.5 percent of betaine, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.15 percent of xanthan gum, 1.5 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
49. 36% Triazolesulfonylzone-betanin suspending agent (4.5+31.5)
4.5 percent of triazophone, 31.5 percent of betaine, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.15 percent of xanthan gum, 1.5 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
50. 14% Triazolesulfonylzone-tribenuron-methyl dispersible oil suspending agent (12+2)
12% of triazophone, 2% of tribenuron-methyl, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
51. 14% Triazolesulfonylzone-thifensulfuron dispersible oil suspension concentrate (12+2)
12% of triazophone, 2% of thifensulfuron methyl, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
52. 15% Triazolesulfonone-thiencarbazone-methyl dispersible oil suspension concentrate (12+3)
12% of triazophone, 3% of thiencarbazone-methyl, 5% of calcium dodecylbenzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
53. 27% Triazolesulfonylzone-rimsulfuron dispersible oil-based suspension concentrate (24+3)
24% of triazophone, 3% of rimsulfuron, 5% of calcium dodecylbenzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.4% of organobentonite, 1.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
54. 15% Triazolesulfonylzone-flucarbazone-sodium dispersible oil suspension agent (12+3)
12% of triazophone, 3% of flucarbazone-sodium, 5% of calcium dodecylbenzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
55. 26% Triazolesulfonylmefonone-mesosulfuron dispersible oil suspension (24+2)
24% of triazophone, 2% of mesosulfuron, 5% of calcium dodecylbenzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
56. 16% Triazolesulfonylzone-nicosulfuron dispersible oil suspending agent (12+4)
12% of triazophone, 4% of nicosulfuron, 5% of calcium dodecylbenzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
57. 15% Triazolesulfonone-foramsulfuron dispersible oil suspending agent (12+3)
12% of triazophone, 3% of foramsulfuron, 5% of calcium dodecylbenzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
58. 15% Triazolesulfonylmefone-flumetsulam dispersible oil suspending agent (12+3)
12% of triazophone, 3% of flumetsulam, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.6% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
59. 29% Triazolesulfonylzone-fluoroketosulam dispersible oil suspending agent (24+5)
24% of triazophone, 5% of triafamone, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.0% of organobentonite, 0.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
60. 14% Triazolesulfonylmefonamide dispersible oil suspension concentrate (12+2)
12% of triazophone, 2% of cloransulam, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.6% of organobentonite, 2.0% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
61. 26% Triazolesulfonylmefonamide dispersible oil suspending agent (24+2)
24% of triazophone, 2% of pyroxsulam, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.0% of organobentonite, 1.0% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
62. 15% Triazolesulfonylmefone-imazapic dispersible oil suspending agent (12+3)
12% of triazophone, 3% of imazamox, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.2% of organobentonite, 1.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
63. 22% Triazolesulfonylclomazone-mebendazole nicotinic acid dispersible oil suspending agent (12+10)
12% of triazophone, 10% of mebendazole nicotinic acid, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.5% of organobentonite, 1.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
64. 19% Triazolesulfonylclomazone-imazethapyr dispersible oil suspending agent (12+7)
12% of triazophone, 7% of imazethapyr, 5% of calcium dodecylbenzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.4% of organobentonite, 1.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
65. 28% Triazolesulfonylzone-imazapyr dispersible oil suspension concentrate (3+25)
3% of triazophone, 25% of imazapyr, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.0% of organobentonite, 1.0% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
66. 42% Triazolesulfonylzone-trifluralin suspending agent (6+36)
6 percent of triazophone, 36 percent of trifluralin, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.08 percent of xanthan gum, 1.0 percent of magnesium aluminum silicate, 5 percent of glycerol and water for complement.
67. 39% Triazolesulfonylzone-dimethlyamine suspension (3+36)
3% of triazophone, 36% of dimetamine, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.1% of xanthan gum, 0.8% of magnesium aluminum silicate, 5% of glycerol and water.
68. 38% Triazolesulfonylzone-ethylbutenafine suspension (3+35)
3% of triazophone, 35% of ethambucol, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 5% of glycerol and water.
69. 28% Triazolesulfonylzone-amisulam suspension (3+25)
3% of triazophone, 25% of oryzalin, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
70. 35% Triazolesulfonylmefone-flumetsulam suspension (6+29)
6 percent of triazophone, 29 percent of flumetsulam, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.14 percent of xanthan gum, 1.5 percent of magnesium aluminum silicate, 5 percent of glycerol and water.
71. 39% Triazolesulfonylzone-thiazopyr suspension (6+33)
6% of triazophone, 33% of thiazopyr, 4% of phenethylphenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.12% of xanthan gum, 1.0% of magnesium aluminum silicate, 5% of glycerol and water.
72. 39% Triazolesulfonylmefone-naphalolate suspending agent (6+33)
6% of triazophone, 33% of naproxen, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.1% of xanthan gum, 1.0% of magnesium aluminum silicate, 5% of glycerol and water.
73. 53% Triazolesulfonone-dichlorvos suspension concentrate (3+50)
3% of triazophone, 50% of chlorthal, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.06% of xanthan gum, 0.5% of magnesium aluminum silicate, 5% of glycerol and water.
74. 58% Triazolesulfonylzone-pyrazophos suspension concentrate (3+55)
3% of triazophone, 55% of benfop-p-butyl, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol-polyoxyethylene ether, 0.05% of xanthan gum, 5% of glycerol and water.
75. 36% Triazolesulfonylfonone-sulcotrione suspension concentrate (6+30)
6% of triazophone, 30% of sulcotrione, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.12% of xanthan gum, 1.2% of magnesium aluminum silicate, 5% of glycerol and water.
76. 24% Triazolesulfonylmefone-topramezone suspending agent (12+12)
12% of triazophone, 12% of benzoxaflutole, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
77. 11% Triazolesulfonylfop-butyl pyrazole dispersible oil suspending agent (9+2)
9% of triazophone, 2% of Sulfonopyrazole, 5% of calcium dodecylbenzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.8% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
78. 32% Triazolesulfonylfonone-tolpyralate suspension (12+20)
12% of triazophone, 20% of tolpyrate, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.14% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
79. 32% Triazolesulfonylmefonone-fenquinotrione suspension (12+20)
12% of triazophone, 20% of fenquinotrione, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
80. 18% Triazolesulfonylfonone-isoxaflutole suspension (12+6)
12% of triazophone, 6% of isoxaflutole, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.17% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
81. 31% Triazolesulfonylfonone-fluorochloridone suspending agent (6+25)
6% of triazophone, 25% of flurochloridone, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
82. 22% Triazolesulfonylfonone-flurtamone suspension (12+10)
The composition comprises 12% of triazophone, 10% of flurtamone, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol-polyoxyethylene ether, 0.18% of xanthan gum, 1.6% of magnesium aluminum silicate, 5% of glycerol and water.
83. 30% Triazolesulfonylclomazone-diflufenican suspension (12+18)
12% of triazophone, 18% of diflufenican, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
84. 29% Triazolesulfonylclomazone-picolinafen suspension (12+17)
12% of triazophone, 17% of fluopicolide, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.15% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
85. 29% Triazolesulfonylmefone-beflubutamid suspension (12+17)
12% of triazophone, 17% of beflubutamid, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.16% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
86. 40% Triazolesulfonylzone-norflurazon suspending agent (3+37)
3% of triazophone, 37% of norflurazon, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.12% of xanthan gum, 1.2% of magnesium aluminum silicate, 5% of glycerol and water.
87. 52% triazophone-fluridone water dispersible granule (2+50)
2 percent of triazophone, 50 percent of fluridone, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
88. 46% Triazolesulfonylzone-prosulfocarb suspension emulsion (2+44)
2% of triazophone, 44% of prosulfocarb, 5% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.12% of xanthan gum, 5% of glycerol and water.
89. 50% Triazolesulfonate-Fucao yellow suspoemulsion (3+47)
3% of triazophone, 47% of furbenoxanil, 5% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.08% of xanthan gum, 5% of glycerol and water.
90. 29% Triazolesulfonate-Ethoxydim suspending agent (2.25+26.75)
2.25% of triazophone, 26.75% of ethofumesate, 10% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.12% of xanthan gum, 5% of glycerol and water.
91. 28% Triazolesulfonylmefone-triallate suspoemulsion (3+25)
3% of triazophone, 25% of triallate, 10% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.15% of xanthan gum, 5% of glycerol and water.
92. 35% Triazolesulfonylmefone-prosulfocarb suspoemulsion (3+32)
3% of triazophone, 32% of prosulfocarb, 5% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.15% of xanthan gum, 5% of glycerol and water.
93. 61% Triazolesulfonate-molinate water dispersible granules (3+58)
3% of triazophone, 58% of molinate, 8% of polycarboxylate dispersant, 6% of nekal, 1% of disintegrant polyvinyl alcohol, 5% of precipitated white carbon black and filler diatomite.
94. 32% Triazolesulfonylmefone-butate suspoemulsion (12+20)
The composition is prepared by adding 12% of triazophone, 20% of butachlor, 5% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.16% of xanthan gum, 5% of glycerol and water.
95. 32% Triazolesulfonone-Cytopramezone suspoemulsion (12+20)
The composition is prepared by adding 12% of triazophone, 20% of cyhalofop-butyl, 5% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.16% of xanthan gum, 5% of glycerol and water.
96. 36% Triazolesulfonone-pipindone suspoemulsion (3+33)
3% of triazophone, 33% of dimesna, 10% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.15% of xanthan gum, 5% of glycerol and water.
97. 70% triazophone-penflufen water dispersible granule (3+67)
3 percent of triazophone, 67 percent of penflufen, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
98. 28% Triazolesulfonylclomazone fluroxypyr isooctyl suspoemulsion (9+19)
9% of triazophone, 19% of fluroxypyr-meptyl, 20% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.12% of xanthan gum, 5% of glycerol and water.
99. 54% Triazolesulfonylclomazone-triclopyr water dispersible granule (2.25+51.75)
2.25 percent of triazophone, 51.75 percent of triclopyr, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
100. 21% Triazolesulfonylmefone-clopyralid dispersible oil suspending agent (9+12)
9% of triazophone, 12% of clopyralid, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 1.8% of organobentonite, 1.6% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
101. 43% Triazolesulfonylzone-picloram water dispersible granule (3+40)
3 percent of triazophone, 40 percent of picloram, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
102. 23% Triazolesulfonylmefone-dicamba dispersible oil suspending agent (9+14)
9% of triazophone, 14% of dicamba, 5% of calcium dodecylbenzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.0% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
103. 28% Triazolesulfonylclomazone-2-methyl-4-chlorophenoxyacetic acid water dispersible granule (9+19)
9 percent of triazophone, 19 percent of 2-methyl-4-chlorophenoxyacetic acid, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitation white carbon black and filler diatomite are complemented.
104. 28% Triazolesulfonylmefone-2-methyl-4-chloro-phenoxathiolester water dispersible granule (3+25)
3% of triazophone, 25% of 2-methyl-4-chloro-phenol ethyl thioester, 8% of polycarboxylate dispersant, 6% of nekal, 1% of disintegrant polyvinyl alcohol, 5% of precipitated silica and filler diatomite.
105. 26% Triazolesulfonylzone MCPB water dispersible granule (3+23)
3% of triazophone, 23% of MCPB, 8% of polycarboxylate dispersant, 6% of nekal, 1% of disintegrant polyvinyl alcohol, 5% of precipitated white carbon black and filler diatomite.
106. 25% triazophone-2-methyl-4-chlorophenoxypropionic acid water dispersible granule (3+22)
3 percent of triazophone, 22 percent of 2-methyl-4-chlorophenoxypropionic acid, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitation white carbon black and filler diatomite are complemented.
107. 25% triazophone-2-methyl-4-sodium chlorophenoxyacetate water dispersible granule (3+22)
3 percent of triazophone, 22 percent of sodium 2-methyl-4-chlorophenoxyacetate, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitation white carbon black and filler diatomite are complemented.
108. 35% Triazolesulfonylclomazone-2-methyl-4-chlorophenoxyacetic acid isooctyl suspoemulsion (3+32)
3% of triazophone, 32% of 2-methyl-4-chlorophenoxyacetic acid isooctyl ester, 5% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.12% of xanthan gum, 5% of glycerol and water.
109. 15% Triazolesulfonylclomazone-2, 4-dichlorophenoxyacetic acid butyl ester suspoemulsion (3+12)
3% of triazophone, 12% of 2, 4-dichlorophenoxyacetic acid butyl ester, 10% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.18% of xanthan gum, 5% of glycerol and water.
110. 17% Triazolesulfonylmefone-2, 4-dichlorophenoxyacetic acid isooctyl suspoemulsion (3+14)
3% of triazophone, 14% of 2, 4-dichlorophenoxyacetic acid isooctyl ester, 10% of 150# solvent oil, 3% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 2% of phenethyl phenol polyoxyethylene ether, 3% of castor oil polyoxyethylene ether, 0.22% of xanthan gum, 5% of glycerol and water.
111. 12% Triazolesulfonylclomazone-2, 4-dichlorophenoxyacetic acid dispersible oil suspending agent (3+9)
3% of triazophone, 9% of 2, 4-dichlorophenoxyacetic acid, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 3.0% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
112. 12% Triazolesulfonylclomazone-4- (2, 4-dichlorophenoxy) propionic acid dispersible oil suspending agent (3+9)
3% of triazophone, 9% of 4- (2, 4-dichlorophenoxy) propionic acid, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 3.0% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
113. 27% Triazolesulfonylmefone cloquintocet suspension (9+18)
9 percent of triazophone, 18 percent of cloquintocet, 4 percent of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5 percent of fatty alcohol polyoxyethylene ether, 0.18 percent of xanthan gum, 1.5 percent of magnesium aluminum silicate, 5 percent of glycerol and water for complement.
114. 28% Triazolesulfonylzone-cinmethylin suspension concentrate (24+4)
24% of triazophone, 4% of cycloheptane ether, 4% of phenethyl phenol polyoxyethylene ether phosphate triethanolamine salt dispersant, 1.5% of fatty alcohol polyoxyethylene ether, 0.14% of xanthan gum, 1.5% of magnesium aluminum silicate, 5% of glycerol and water.
115. 38% Triazolesulfonylzone-phosphinothricin water dispersible granule (1.5+36.5)
1.5 percent of triazophone, 36.5 percent of phosphinothricin, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
116. 30% Triazolesulfonylclomazone-bialaphos water dispersible granule (2.25+27.75)
2.25 percent of triazophone, 27.75 percent of bialaphos, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated silica and filler diatomite.
117. 35% Triazolesulfonylzone-refined glufosinate water dispersible granule (4.5+30.5)
4.5 percent of triazophone, 30.5 percent of refined glufosinate-ammonium, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
118. 45% triazophone paraquat water dispersible granule (4.5+40.5)
4.5 percent of triazophone, 40.5 percent of paraquat, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
119. 40% triazophone-diquat water dispersible granule (4.5+35.5)
4.5 percent of triazophone, 35.5 percent of diquat, 8 percent of polycarboxylate dispersant, 6 percent of nekal, 1 percent of disintegrant polyvinyl alcohol, 5 percent of precipitated white carbon black and filler diatomite.
120. 26% Triazolesulfonylmefone-2-methyl-4-chlorobutyric acid dispersible oil suspension agent (3+23)
3% of triazophone, 23% of 2-methyl-4-chlorobutyric acid, 5% of calcium dodecyl benzene sulfonate, 6% of nonylphenol polyoxyethylene ether, 4% of castor oil polyoxyethylene ether, 2.8% of organobentonite, 2.5% of fumed silica, 10% of No. 150 solvent oil and methyl oleate.
121. 20% Triazolesulfonylclomazone-2, 4-D-butyric acid dispersible oil suspension (4.5+15.5)
4.5 percent of triazophone, 15.5 percent of 2, 4-D butyric acid, 5 percent of calcium dodecyl benzene sulfonate, 6 percent of nonylphenol polyoxyethylene ether, 4 percent of castor oil polyoxyethylene ether, 2.8 percent of organic bentonite, 2.5 percent of fumed silica, 10 percent of No. 150 solvent oil and methyl oleate.
The processing equipment of the aqueous suspending agent comprises a mixing kettle, a colloid mill, a sand mill, a shearing machine and the like.
The processing process of the aqueous suspension agent comprises the steps of putting all materials into a mixing kettle, stirring and mixing the materials, passing the materials through a colloid mill, then entering a sand mill for three-stage sanding, finally uniformly shearing the materials in a shearing machine, transferring the materials to a storage tank for filling after the materials are qualified in test.
The processing equipment of the dispersible oil suspending agent comprises a mixing kettle, a colloid mill, a sand mill, a shearing machine and the like.
The dispersible oil suspending agent is prepared by putting all materials into a mixing kettle, stirring and mixing, passing through a colloid mill, entering a sand mill for three-stage sanding, finally shearing uniformly in a shearing machine, transferring to a storage tank for filling after passing the assay.
The water dispersible granule processing equipment comprises an air flow crusher, a colter type mixer, a basket type granulator, a drying box, a sieving machine and the like.
The water dispersible granule is prepared by uniformly mixing the materials, crushing the materials by airflow, adding water, kneading, granulating, drying and finally screening to obtain a finished product.
The above-mentioned suspension emulsion preparation equipment includes mixing kettle, colloid mill, sand mill and shearing machine.
The suspension emulsion is prepared by adding water phase material into a mixing kettle, stirring, grinding with colloid mill, grinding with sand mill for three-stage grinding, shearing uniformly in shearing machine, and transferring after qualified test; putting the oil phase material into a mixing kettle, adding solvent oil and an emulsifier, and stirring and dissolving uniformly; and then adding the water-phase material into a shearing kettle, slowly pumping the oil-phase material into the shearing kettle in a shearing state, pumping the material while shearing, continuously and uniformly shearing, transferring to a storage tank for filling after the test is qualified.
B) Test of drug efficacy
Spraying treatment of stems and leaves after seedling:
1) test conditions
1.1) test target
The descurainia sophia is collected from Shandong Taian, the barnyard grass is collected from Anhui Lujiang, the bovine chickweed is collected from Jiangsu Xinghua, the weeds are cultured by a pot culture method, a plastic nutrition pot with the diameter of 180 х 140mm is used for placing in an enamel tray, surface soil (4/5) which is collected from a farmland and is dried and sieved is filled in the enamel tray, the soil humidity is controlled to be 20% at the initial stage, weed seeds with full and uniform seeds are selected, the weed seeds are soaked in warm water with the temperature of 25 ℃ for 6 hours, the germination is accelerated in a biochemical incubator (dark) with the temperature of 28 ℃, the weed seeds which just expose to the white are evenly placed on the soil surface, and the soil is covered with the soil for 0.5-.
1.2) culture conditions
The method is carried out in a controllable sunlight greenhouse, the temperature is 20-30 ℃, the natural illumination is carried out, and the relative humidity is 57-72%.
The soil type is loam, the organic matter content is 1.63%, the pH value is 7.1, the alkaline hydrolysis nitrogen is 84.3mg/kg, the quick-acting phosphorus is 38.5mg/kg, and the quick-acting potassium is 82.1 mg/kg.
1.3), instrumentation
3WP-2000 model walking spray tower, Minn Jing agricultural machinery research institute of agricultural department. Ten thousandth electronic balance type GA10 (germany); ZDR2000 intelligent data recorder (hangzhou ze large instruments ltd); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument factory).
2) Design of experiments
2.1), reagents
2.1.1) test Agents
The desired active ingredient B was purchased from a reagent company and A was produced by this company.
The raw medicines are all diluted by using an emulsifier Tween-80 aqueous solution with the content of 0.1 percent and taking acetone as a solvent.
2.2) test treatment
2.2.1), dose setting
When determining the ratio or content of the component A and the component B, the main use purpose of the formula is also considered according to the action characteristics of the two medicaments and the measurement of toxicity and the like. On the basis of preliminary experiments, A, B active ingredients are respectively used singly and mixed in different amounts. Water without drug, containing the same solvent and emulsifier was used as a blank.
2.2.2), test repetition
Each treatment was repeated 4 times, 3 pots each time, 20 weed seeds were sown per pot, 60 plants each time.
2.3) treatment method
2.3.1), treatment time and number of times
The test was performed 1 time in total. And (3) thinning when the weeds are in the 2-leaf stage, keeping 15 weeds in each pot, keeping 45 weeds in each treatment, and then continuously culturing until the seeds of the descurainia sophia, the barnyard grass and the 3-leaf of the starwort are treated.
2.3.2), instruments and methods of use
Uniformly placing the cultured test material on a 0.5m area2Spraying stem and leaf with 3WP-2000 model walking spraying tower in 30 kg/ha amount. The spraying pressure is 0.3 MPa. And after all the liquid medicine is sprayed, closing the air valve, opening the spraying tower door after 30 seconds, and taking out the nutrition pot. Then the air valve is opened, 50mL of clean water is sprayed, and the liquid spraying pipe is cleaned.
3) Test method
The potting method is adopted. The weed cultivation is carried out according to 1.1 and the standard herbicide for indoor bioassay of pesticides. The application method is 2.3.2, and stem and leaf treatment method is adopted. After treatment, the cells were transferred to a greenhouse for conventional culture, and a 1-2cm water layer was maintained throughout the experiment.
4) Data investigation and statistical analysis
4.1) investigation method
The complete survival weed seedlings are cut off along the soil surface by a blade by adopting an absolute number survey method, and the fresh weight of the weeds is weighed by an analytical balance. For the weeds that have died, the fresh weight is zero.
4.2), investigation time and number of surveys
The investigation was carried out 20 days after the treatment, and the total number of the investigations was 1.
4.3), statistical analysis of data
The theoretical fresh weight inhibition rate (E0 ═ X + Y-X Y/100) of each treatment mixed combination is calculated by a Gowing method, and then compared with the actually measured inhibition rate (E), the combined action type of the two mixed combinations on the weeds is evaluated, and when the E-E0 value is more than 10 percent, the effect is synergistic, when the E-E0 value is less than-10 percent, the effect is antagonistic, and when the E-E0 value is between-10 percent and 10 percent, the effect is additive. And the optimal proportion is determined according to factors such as actual control effect, characteristics of the herbicide, balance of the formula and the like.
Wherein X is the fresh weight inhibition rate when the dosage of the active component A is P; y is the fresh weight inhibition rate of the active component B when the dosage is Q.
Soil sealing treatment:
1) test conditions
1.1) test target
The descurainia sophia is collected from Taian in Shandong, the barnyard grass is collected from Lujiang in Anhui, and the chickweed is collected from Jiangsu Xinghua.
1.2) culture conditions
The method is carried out in a controllable sunlight greenhouse, the temperature is 20-30 ℃, the natural illumination is carried out, and the relative humidity is 57-72%.
The soil type is loam, the organic matter content is 1.63%, the pH value is 7.1, the alkaline hydrolysis nitrogen is 84.3mg/kg, the quick-acting phosphorus is 38.5mg/kg, and the quick-acting potassium is 82.1 mg/kg. The test soil was quantitatively loaded at 3/4 points of the pot and then poured from the bottom of the pot to completely wet the soil to saturation. Uniformly and quantitatively broadcasting the pretreated weed seeds to be tested on the surface, covering soil of 0.5-2cm according to the size of the seeds, and reserving the weed seeds for 24 hours after sowing.
1.3), instrumentation
Ten thousandth electronic balance type GA10 (germany); ZDR2000 intelligent data recorder (hangzhou ze large instruments ltd); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument plant), pipettor and the like.
2) Design of experiments
2.1), reagents
2.1.1) test Agents
The required active ingredients B are all technical products sold in the market, and A is produced by the company.
The raw medicines are all diluted by using an emulsifier T-80 aqueous solution with the content of 0.1 percent by using acetone as a solvent.
2.2) test treatment
2.2.1), dose setting
When determining the ratio or content of the components A and the active component B, the main purpose of the formula should be considered in consideration of the action characteristics of the two medicaments and the toxicity thereof. On the basis of preliminary experiments, A, B active ingredients are respectively used singly and mixed in different amounts. Water without drug, containing the same solvent and emulsifier was used as a blank.
2.2.2), test repetition
Each treatment was repeated 4 times, 3 pots each time, and 30 weed seeds were sown in each pot.
2) Test method
Before treatment, the mixture was irrigated and a 1-2cm aqueous layer was maintained. Taking quantitative liquid medicine by a pipettor, and respectively carrying out irrigation treatment from low dosage to high dosage according to experimental design, wherein the treatment is repeated for 4 times each time; after treatment, the cells were transferred to a greenhouse for conventional culture, and a 1-2cm water layer was maintained throughout the experiment.
3) Data investigation and statistical analysis
The spray treatment is the same as the spray treatment of the stem leaves after seedling, so the detailed description is omitted.
The statistical results are shown in tables 1-121 below.
Table 1A evaluation of the actual control and combination of barnyard grass with s-metolachlor (soil treatment)
Figure GDA0001703049990000221
Table 2A evaluation of the actual control and combination of the action of blending with flufenacet on barnyard grass (soil treatment)
Figure GDA0001703049990000222
Figure GDA0001703049990000231
Table 3A evaluation of the actual control and combination of barnyard grass with fenacet (soil treatment)
Figure GDA0001703049990000232
Table 4A evaluation of actual control and combination of barnyard grass with asulam (stem leaf treatment)
Figure GDA0001703049990000233
TABLE 5 actual control and Combined action evaluation (soil treatment) of Echinochloa crusgalli by compounding with Sulfuron pyrazoxazole
Figure GDA0001703049990000234
TABLE 6A evaluation of the actual control and combination of pyributicarb with dimethenamid (soil treatment)
Figure GDA0001703049990000235
Figure GDA0001703049990000241
Table 7A evaluation of the actual control and combination of tare with cafenstrole (soil treatment)
Figure GDA0001703049990000242
Table 8A evaluation of actual control and Combined action of mixing with propisochlor on barnyard grass (soil treatment)
Figure GDA0001703049990000243
Table 9A evaluation of actual controlling effect and combined action of Bixicao mixed with metazachlor (soil treatment)
Figure GDA0001703049990000244
TABLE 10 evaluation of actual control and Combined action of pyributicarb when blended with pyributicarb (soil treatment)
Figure GDA0001703049990000245
Figure GDA0001703049990000251
Table 11A actual control and combined action evaluation (soil treatment) of barnyard grass with dimethomorph
Figure GDA0001703049990000252
Table 12A evaluation of the actual control and combination of descurainia sophia (soil treatment) with fomesafen
Figure GDA0001703049990000253
Table 13A evaluation of the actual control and combination of descurainia sophia (soil treatment) with flumioxazin
Figure GDA0001703049990000254
TABLE 14 evaluation of the actual control and combination of Artemisia scoparia mixed with TIAFENACIL (Stem and leaf treatment)
Figure GDA0001703049990000255
TABLE 15 evaluation of the actual control and combination of descurainia sophia (Stem and leaf treatment) with saflufenacil
Figure GDA0001703049990000256
Figure GDA0001703049990000261
TABLE 16 evaluation of actual control and combination of descurainia sophia (soil treatment) by mixing Bispyribac-sodium
Figure GDA0001703049990000262
TABLE 17 evaluation of actual control and Combined action of descurainia sophia in combination with atrazine
Figure GDA0001703049990000263
TABLE 18 evaluation of actual control and combination of descurainia sophia (soil treatment) by combination of terbutryn and terbuthylazine
Figure GDA0001703049990000264
TABLE 19 evaluation of actual control and Combined action of descurainia sophia in combination with ametryn (soil treatment)
Figure GDA0001703049990000265
TABLE 20 evaluation of the actual control and combination of the combination of isoproturon and isoproturon (soil treatment)
Figure GDA0001703049990000266
Figure GDA0001703049990000271
TABLE 21 evaluation of actual control and combined action of blending with phytocide on descurainia sophia (soil treatment)
Figure GDA0001703049990000272
TABLE 22 evaluation of actual control and combination of descurainia sophia (soil treatment) by mixing and pairing with dicetryn
Figure GDA0001703049990000273
TABLE 23 evaluation of actual control and combination of the combination of Ximajin with descurainia sophia (soil treatment)
Figure GDA0001703049990000274
TABLE 24 actual control and Combined action evaluation (soil treatment) of descurainia sophia mixed with metribuzin
Figure GDA0001703049990000275
Figure GDA0001703049990000281
TABLE 25 evaluation of actual control and Combined action of the Equisetum sophia mixed with ethimazone (soil treatment)
Figure GDA0001703049990000282
TABLE 26 evaluation of actual control and Combined action of the combination of metamitron and flixweed (soil treatment)
Figure GDA0001703049990000283
TABLE 27 evaluation of actual control and combination of descurainia sophia (soil treatment) by blending Cyhalofop-Citrari with Aconitum
Figure GDA0001703049990000284
TABLE 28 evaluation of actual control and Combined action of LvMALONG and LvMALONG on mule fly (soil treatment)
Figure GDA0001703049990000285
TABLE 29 evaluation of actual control and combination of descurainia sophia (soil treatment) by mixing and pairing with diuron
Figure GDA0001703049990000286
Figure GDA0001703049990000291
TABLE 30 evaluation of actual control and combination of descurainia sophia (soil treatment) by mixing and pairing with Fluoruron
Figure GDA0001703049990000292
TABLE 31 evaluation of actual control and combination of mulukhiya with mix of Rigulong (soil treatment)
Figure GDA0001703049990000293
TABLE 32 evaluation of actual control and Combined action of Thidiazuron and tarragon
Figure GDA0001703049990000294
TABLE 33 evaluation of actual control and combination of descurainia sophia (soil treatment) by mixing with Lugulong
Figure GDA0001703049990000295
Figure GDA0001703049990000301
TABLE 34 evaluation of actual control and combination of descurainia sophia (soil treatment) by mixing and pairing descurainia sophia with bromuron
Figure GDA0001703049990000302
TABLE 35 evaluation of actual control and Combined action of descurainia sophia in combination with Royal seed mix (soil treatment)
Figure GDA0001703049990000303
TABLE 36 evaluation of actual control and combination of Polygala sonchifolia with Pyridazinol (soil treatment)
Figure GDA0001703049990000304
TABLE 37 evaluation of actual control and combination of descurainia sophia (soil treatment) by blending with hexazinone
Figure GDA0001703049990000305
TABLE 38 evaluation of actual control and combination of descurainia sophia (soil treatment) by mixing and pairing together with isopentyi
Figure GDA0001703049990000311
TABLE 39A evaluation of actual control and combination of descurainia sophia (soil treatment) with the combination of Cadajin
Figure GDA0001703049990000312
TABLE 40 evaluation of actual control and combination of descurainia sophia (soil treatment) by blending with lenacil
Figure GDA0001703049990000313
TABLE 41 evaluation of actual control and combination of descurainia sophia (soil treatment) by combining Termedine with Tributine
Figure GDA0001703049990000314
TABLE 42 evaluation of actual control and combination of mullein by blending methabenzthiazuron and Mesothian (soil treatment)
Figure GDA0001703049990000315
Figure GDA0001703049990000321
TABLE 43 evaluation of actual control and combination of descurainia sophia by blending with Cycloduron (soil treatment)
Figure GDA0001703049990000322
TABLE 44 evaluation of actual control and combination of descurainia sophia (soil treatment) by blending with Isooxalong
Figure GDA0001703049990000323
TABLE 45 evaluation of actual control and combination of descurainia sophia (soil treatment) by compounding metoprolol with metoprolol
Figure GDA0001703049990000324
TABLE 46 evaluation of actual control and combination of the compounding of Kunlong and Kunlong for the sowing of Polygala sonchifolia (soil treatment)
Figure GDA0001703049990000325
TABLE 47 evaluation of actual control and combination of descurainia sophia (soil treatment) by compounding with Trifluazin
Figure GDA0001703049990000326
Figure GDA0001703049990000331
TABLE 48 evaluation of actual control and combination of Beechia sophia (stem and leaf treatment) by mixing with Betula alnoides
Figure GDA0001703049990000332
TABLE 49 evaluation of actual control and combination of descurainia sophia (stem and leaf treatment)
Figure GDA0001703049990000333
TABLE 50 evaluation of actual control and combination of descurainia sophia (soil treatment) by combining tribenuron-methyl
Figure GDA0001703049990000334
TABLE 51A evaluation of actual control and combination of Thifensulfuron methyl and flimsy descurainia (soil treatment)
Figure GDA0001703049990000335
TABLE 52 evaluation of actual control and combination of Thidiazuron and Thidiazuron on mulches
Figure GDA0001703049990000341
TABLE 53 evaluation of actual control and combination of Polygala sonchifolia with rimsulfuron
Figure GDA0001703049990000342
TABLE 54 evaluation of actual control and combination of Flucarbazone-sodium for descurainia sophia (soil treatment)
Figure GDA0001703049990000343
TABLE 55 evaluation of actual control and combination of Mesosulfuron-methyl for descurainia sophia (soil treatment)
Figure GDA0001703049990000344
TABLE 56 evaluation of actual control and combination of Miannianghao (soil treatment) with nicosulfuron
Figure GDA0001703049990000345
TABLE 57 evaluation of actual control and combination of descurainia sophia by compounding with foramsulfuron (soil treatment)
Figure GDA0001703049990000346
Figure GDA0001703049990000351
TABLE 58A evaluation of actual control and combination of descurainia sophia (soil treatment) with flumetsulam
Figure GDA0001703049990000352
TABLE 59 evaluation of the actual control and combination of descurainia sophia (soil treatment) by combination with Fomitodim-sodium
Figure GDA0001703049990000353
TABLE 60 evaluation of the actual control and combination of the combination of cloransulam-methyl with the evaluation of the actual control and combination of the action of descurainia sophia (soil treatment)
Figure GDA0001703049990000354
TABLE 61 evaluation of the actual control and combination of the Paecilomyces lactiflora (soil treatment) with pyroxsulam
Figure GDA0001703049990000355
TABLE 62 evaluation of actual control and combination of Michelia crenata (soil treatment) with imazamox mixture
Figure GDA0001703049990000356
Figure GDA0001703049990000361
TABLE 63 evaluation of the actual control and combination of the combination of Memidazolinin and Incarvillea sophia (soil treatment)
Figure GDA0001703049990000362
TABLE 64A evaluation of the actual control and combination of the combination of Hakka mother and imazethapyr (soil treatment)
Figure GDA0001703049990000363
TABLE 65A evaluation of the actual control and combination of descurainia sophia (soil treatment) with the Micaoqing
Figure GDA0001703049990000364
TABLE 66 actual control and Combined action evaluation (soil treatment) of barnyard grass by compounding with trifluralin
Figure GDA0001703049990000365
Figure GDA0001703049990000371
TABLE 67 actual control and Combined action evaluation (soil treatment) of barnyard grass by blending with Dilleamine
Figure GDA0001703049990000372
TABLE 68 actual control and combination evaluation of Echinochloa crusgalli by blending with Ethycyflufen (soil treatment)
Figure GDA0001703049990000373
TABLE 69 evaluation of actual control and Combined action of Echinochloa crusgalli with amisul-fondant mix
Figure GDA0001703049990000374
TABLE 70 evaluation of actual control and Combined action of cockspur grass by compounding with flumetsulam (soil treatment)
Figure GDA0001703049990000375
Figure GDA0001703049990000381
TABLE 71 evaluation of the actual control and combination of Echinochloate when blended with Thifenpyr (soil treatment)
Figure GDA0001703049990000382
TABLE 72 actual control and Combined action evaluation (soil treatment) of barnyard grass by blending with Naxate
Figure GDA0001703049990000383
TABLE 73 evaluation of actual control and combination of barnyard grass by blending with chlorthal (soil treatment)
Figure GDA0001703049990000384
TABLE 74 evaluation of actual control and combination of barnyard grass with Pythium irregulare mixture (soil treatment)
Figure GDA0001703049990000385
TABLE 75 evaluation of the actual control and Combined action of the Paecilomyces lactiflora (soil treatment) in combination with sulcotrione
Figure GDA0001703049990000391
TABLE 76A evaluation of the actual control and combination of descurainia sophia (soil treatment) with the combination of topramezone
Figure GDA0001703049990000392
TABLE 77 evaluation of the actual control and combination of descurainia sophia (Stem and leaf treatment) with Sulfonyloxalpyrazole combination
Figure GDA0001703049990000393
TABLE 78 evaluation of actual control and Combined action of tarcuraina sophia mixed with tolpyralate (soil treatment)
Figure GDA0001703049990000394
TABLE 79 evaluation of actual control and Combined action of fenquinotrione in combination with descurainia sophia (soil treatment)
Figure GDA0001703049990000395
Figure GDA0001703049990000401
TABLE 80 evaluation of the actual control and Combined action of the isoxaflutole mixture with descurainia sophia (soil treatment)
Figure GDA0001703049990000402
TABLE 81 evaluation of the actual control and Combined action of descurainia sophia mixed with flurochloridone (soil treatment)
Figure GDA0001703049990000403
TABLE 82 evaluation of the actual control and Combined action of the Furosen and Fufuulon mixture
Figure GDA0001703049990000404
TABLE 83 evaluation of actual control and combination of descurainia sophia (soil treatment) by combining diflufenican with Diflufenican
Figure GDA0001703049990000405
Figure GDA0001703049990000411
TABLE 84A evaluation of the actual control and combination of descurainia sophia (soil treatment) with fluroxypyr
Figure GDA0001703049990000412
TABLE 85 evaluation of the actual control and Combined action of descurainia sophia mixed with beflubutamid (soil treatment)
Figure GDA0001703049990000413
TABLE 86 evaluation of actual control and combined action of descurainia sophia mixed with norflurazon (soil treatment)
Figure GDA0001703049990000414
TABLE 87 evaluation of actual control and Combined action of descurainia sophia mixed with fluridone (soil treatment)
Figure GDA0001703049990000421
TABLE 88A evaluation of actual control and Combined action of barnyard grass in combination with prosulfocarb (soil treatment)
Figure GDA0001703049990000422
TABLE 89 evaluation of actual control and combination of cockspur grass by compounding with Furfurin (soil treatment)
Figure GDA0001703049990000423
TABLE 90 evaluation of the actual control and combination of the combination of Tefu grass and Artemisia scoparia (stem and leaf treatment)
Figure GDA0001703049990000424
TABLE 91A evaluation of actual control and Combined action of cockspur grass with Dicamba (soil treatment)
Figure GDA0001703049990000425
TABLE 92 evaluation of actual control and Combined action of cockspur grass with Mexican pellets (soil treatment)
Figure GDA0001703049990000426
Figure GDA0001703049990000431
TABLE 93 evaluation of actual control and Combined action of Binyao when it is mixed with Metronidazole (soil treatment)
Figure GDA0001703049990000432
TABLE 94 evaluation of actual control and combination of tare by compounding with butantte (soil treatment)
Figure GDA0001703049990000433
TABLE 95 evaluation of actual control and Combined action of Echinochloa against Echinochloa crusgalli by mixing with Dicidon (soil treatment)
Figure GDA0001703049990000434
TABLE 96A evaluation of actual control and Combined action of blending with Primeria championii (soil treatment)
Figure GDA0001703049990000435
Figure GDA0001703049990000441
TABLE 97 evaluation of actual control and Combined action of pennyroyal when it is mixed with pennyroyal
Figure GDA0001703049990000442
TABLE 98A evaluation of the actual control and combination of bovine chickweed when blended with fluroxypyr (Stem and leaf treatment)
Figure GDA0001703049990000443
TABLE 99A evaluation of the actual control and combination of bovine chickweed with triclopyr (stem and leaf treatment)
Figure GDA0001703049990000444
TABLE 100 actual control and combination evaluation of bovine chickweed by blending with clopyralid (stem and leaf treatment)
Figure GDA0001703049990000445
TABLE 101 actual prevention and combination evaluation of bovine chickweed by blending with Picloram (stem and leaf treatment)
Figure GDA0001703049990000446
Figure GDA0001703049990000451
TABLE 102A evaluation of actual control and Combined action of Dicamba on bovine chickweed (stem and leaf treatment)
Figure GDA0001703049990000452
TABLE 103 evaluation of the actual control and combination of descurainia sophia (Stem and leaf treatment) by mixing with 2-methyl-4-chlorophenoxyacetic acid
Figure GDA0001703049990000453
TABLE 104 evaluation of actual control and combination of descurainia sophia (Stem and leaf treatment) with 2-methyl-4-chlorophenol ethyl thioester mixture
Figure GDA0001703049990000454
TABLE 105 evaluation of the actual control and Combined action of the MCPB mixture of descurainia sophia (Stem and leaf treatment)
Figure GDA0001703049990000455
TABLE 106 evaluation of actual control and combination of descurainia sophia (stem and leaf treatment) by blending with 2-methyl-4-chlorophenoxypropionic acid
Figure GDA0001703049990000461
TABLE 107A evaluation of the actual control and combination of descurainia sophia (Stem and leaf treatment) in combination with 2-methyl-4-sodium chlorophenoxylate
Figure GDA0001703049990000462
TABLE 108 evaluation of the actual control and combination of the blend of isooctyl 2-methyl-4-chlorophenoxyacetate with descurainia sophia (Stem and leaf treatment)
Figure GDA0001703049990000463
TABLE 109A evaluation of the actual control and combination of descurainia sophia (stem and leaf treatment) with butyl 2, 4-Dichlorophenoxyacetate
Figure GDA0001703049990000464
TABLE 110A evaluation of the actual control and combination of descurainia sophia (stem and leaf treatment) when mixed with isooctyl 2, 4-dichlorophenoxyacetate
Figure GDA0001703049990000465
Figure GDA0001703049990000471
TABLE 111 evaluation of actual control and Combined action of descurainia sophia (Stem and leaf treatment) with 2, 4-Dichlorophenoxyacetic acid mixture
Figure GDA0001703049990000472
TABLE 112 evaluation of the actual control and combination of the 4- (2, 4-dichlorophenoxy) propionic acid mixture with descurainia sophia (stem and leaf treatment)
Figure GDA0001703049990000473
Table 113A mixing with Clinochoic acid evaluation of actual prevention and combination of descurainia sophia (Stem and leaf treatment)
Figure GDA0001703049990000474
TABLE 114A evaluation of actual control and combination of barnyard grass with cinmethylin (stem leaf treatment)
Figure GDA0001703049990000475
Figure GDA0001703049990000481
TABLE 115A evaluation of actual control and Combined action of Echinochloa crusgalli with phosphinothricin (Stem and leaf treatment)
Figure GDA0001703049990000482
TABLE 116A evaluation of actual control and combination of Bispica Binnipeg with bialaphos (stem leaf treatment)
Figure GDA0001703049990000483
TABLE 117A evaluation of actual control and combination of Echinochloa crusgalli with compounding of glufosinate ammonium (stem leaf treatment)
Figure GDA0001703049990000484
TABLE 118A evaluation of actual control and combination of barnyard grass with paraquat mixture (Stem and leaf treatment)
Figure GDA0001703049990000485
TABLE 119A evaluation of actual control and combination of barnyard grass with diquat (stem and leaf treatment)
Figure GDA0001703049990000486
Figure GDA0001703049990000491
TABLE 120A evaluation of the actual control and combination of descurainia sophia (stem and leaf treatment) with 2A 4 chlorobutyric acid
Figure GDA0001703049990000492
TABLE 121A evaluation of the actual control and combination of descurainia sophia (stem and leaf treatment) with 2, 4-D butyric acid
Figure GDA0001703049990000493
C) Demonstration of field
The herbicidal compositions prepared in examples 1) to 121) were used for field weed effect tests.
An exemplary popularization test was performed in the test point of the Kyoho chemical industry in 2016. The weeds in the field mainly comprise barnyard grass, moleplant seed, monochoria vaginalis, cyperus rotundus and the like.
The test method comprises the following steps:
soil treatment, before weed germination, a manual sprayer is used for adding water with the amount of 45 kg/667 m2The soil surface is uniformly sprayed.
Treating stems and leaves, namely, after the weeds are in the 3-4 leaf stage, manually spraying the weeds with a sprayer, and adding 30 kg of water per 667m2The stem and leaf are sprayed evenly.
The specific test agents and doses are detailed in table 122, with a cell area of 50 square meters, repeated 4 times per treatment. The control effect was examined 45 days after the application of the composition shown in Table 122.
Figure GDA0001703049990000494
Through a large number of tests and explorations, the invention unexpectedly discovers that the composition is used for preventing and killing barnyard grass, moleplant seed, descurainia sophia, chickweed, monochoria vaginalis, cyperus heterophylla and other weeds, has a surprising and unexpected synergistic effect, is more remarkable under a low dosage, can reduce the dosage and the pollution to the environment, is reasonably compounded to reduce the agricultural cost, is efficient for ALS and ACCase inhibitor resistant weeds, and has a good application prospect. Meanwhile, tests show that the herbicide composition shows good selectivity and excellent synergistic effect on lawns and crops such as wheat fields, corn fields, paddy fields, peanuts, sugarcane, sorghum, millet, potatoes, rape, soybeans, cotton, vegetables, bluegrass, tall fescue, zoysia japonica and the like, and can be developed into herbicide mixtures with wide market value.
Exemplary field Effect of the compounded compositions described in Table 122
Figure GDA0001703049990000511
Figure GDA0001703049990000521
Figure GDA0001703049990000531
Figure GDA0001703049990000541
Figure GDA0001703049990000551
Figure GDA0001703049990000561
Figure GDA0001703049990000571
Figure GDA0001703049990000581
Figure GDA0001703049990000591
Figure GDA0001703049990000601

Claims (10)

1. A weeding composition containing triazophos-cotrione, which is characterized by comprising an active ingredient A and an active ingredient B with herbicidally effective amounts, wherein the active ingredient A is the triazophos-cotrione, and the active ingredient B can be selected from one or more of the following compounds:
PSII inhibitors: fencijing and cyanazine;
wherein the weight ratio of A to B is 1:200-50: 1.
2. A herbicidal composition comprising mesotrione according to claim 1, wherein the weight ratio of a to B is from 1:150 to 30: 1.
3. A herbicidal composition comprising mesotrione according to claim 2, wherein the weight ratio of a to B is from 1:120 to 10: 1.
4. A herbicidal composition comprising mesotrione as claimed in claim 3, wherein the weight ratio of a to B is from 1:100 to 5: 1.
5. The weeding composition containing triazophodim according to any one of claims 1 to 4, wherein A and B are present in the weeding composition in an amount of 1-95% by weight.
6. The weeding composition containing triazophodim according to claim 5, wherein A and B are contained in the weeding composition in an amount of 10-80% by mass.
7. The weeding composition containing triazophodim according to any one of claims 1 to 4, further comprising a carrier and a surfactant.
8. The weeding composition containing mesotrione according to any one of claims 1 to 4, wherein the specific formulation of the weeding composition is dispersible oil suspension, aqueous suspension, suspoemulsion, wettable powder, emulsifiable concentrate, water dispersible granules, aqueous emulsion or microemulsion.
9. The herbicidal composition comprising mesotrione as claimed in any one of claims 1 to 4, wherein the herbicidal composition further comprises a safener selected from one or more of isoxadifen, cyprosulfamide, mefenpyr, cloquintocet, gibberellic acid, furilazole and metacamifen.
10. Use of the herbicidal composition comprising triazophorbine according to any one of claims 1 to 9 for the control of harmful weeds in crops of plants.
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CN108283185A (en) * 2018-04-05 2018-07-17 合肥红佳科技信息有限公司 A kind of Herbicidal combinations containing dichloroquinoline humulone
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CN116250539A (en) * 2018-12-14 2023-06-13 青岛清原化合物有限公司 Ternary weeding composition containing fenpyrazamine and application thereof
CN109497075B (en) * 2018-12-19 2021-12-07 青岛清原化合物有限公司 Ternary herbicidal composition containing trifludimoxazin and application thereof
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CN113387926B (en) * 2020-03-13 2023-12-12 沈阳中化农药化工研发有限公司 Heterocyclic carboxylic ester compound and application thereof as herbicide
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MX2023004334A (en) * 2020-10-15 2023-06-02 Adama Agan Ltd Herbicide mixture, herbicidal composition, method for preventing undesired vegetation and kit.
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