CN107372551A - A kind of Herbicidal combinations and its application of the humulone of sulphur containing triazole and pyridazine compound - Google Patents

A kind of Herbicidal combinations and its application of the humulone of sulphur containing triazole and pyridazine compound Download PDF

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Publication number
CN107372551A
CN107372551A CN201710744235.5A CN201710744235A CN107372551A CN 107372551 A CN107372551 A CN 107372551A CN 201710744235 A CN201710744235 A CN 201710744235A CN 107372551 A CN107372551 A CN 107372551A
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China
Prior art keywords
humulone
herbicidal combinations
pyridazine compound
sulphur containing
containing triazole
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CN201710744235.5A
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CN107372551B (en
Inventor
连磊
张景远
彭学岗
刘娜
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Qingdao Qing Yuan Compound Co Ltd
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Qingdao Qing Yuan Compound Co Ltd
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Priority to CN201710744235.5A priority Critical patent/CN107372551B/en
Priority to PCT/CN2017/112010 priority patent/WO2019037313A1/en
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention belongs to pesticide field, and in particular to a kind of Herbicidal combinations and its application of the humulone of sulphur containing triazole and pyridazine compound.The Herbicidal combinations include the active components A and active component B of herbicidally effective amount, wherein, active components A is triazole sulphur humulone, and B is pyridazine compound, selected from pyridate or cyclopyrimorate.Said composition can effectively prevent and kill off the weed problems such as black nightshade in rice terrace, moleplant seed, rice barnyard grass, barnyard grass, have the characteristics that to expand herbicide controlling spectrum, reduce amount of application, to crop safety, synergistic effect can be produced and solve resistant weed.

Description

A kind of Herbicidal combinations and its application of the humulone of sulphur containing triazole and pyridazine compound
Technical field
The invention belongs to pesticide field, and in particular to a kind of Herbicidal combinations of the humulone of sulphur containing triazole and pyridazine compound And its application.
Background technology
Chemical weed control is means the most economical and effective during farmland weed is prevented and kill off, but uses list for a long time continuous high dose The chemical herbicide of one kind or the single mode of action, the problems such as easily causing weeds resistance and resistance evolution.
Triazole sulphur humulone chemical structural formula isIt is the rice terrace after seedling stem newly researched and developed The HPPD inhibitor class herbicide of leaf processing, has excellent bioactivity, can effectively prevent and kill off a variety of malignant weeds of rice terrace.
Pyridate chemical structural formula isIt is a kind of selective herbicide after seedling.Stem Absorbed after leaf processing by leaf rapidly, hinder photosynthetic Hill reaction, grass cutting blade is turned yellow and is stopped growing, withered and cause Extremely.Broad leaved weed is prevented and kill off suitable for cereal crops such as wheat, rice, corns, especially to clearvers, Amaranthus retroflexus and some undergraduate courses Weeds have had preventive effect good.
Compound cyclopyrimorate (test code number H-965) structural formula isIt is The pyridazine class herbicide of Mitsui KCC exploitation, is Inhibitors of photosystem II.Its initiative is based on grass of rattling away Special (pyridate) and it is derived up to careless ether (credazine) structure.
The reasonable compounding or mixture of herbicidal compounds, which have, to be expanded weeds spectrum, improves preventive effect, delays weeds resistance Property and it is drug-fast generation with development the advantages that, be one of maximally efficient method to solve the above problems.Therefore in production urgently Safe, broad weed-killing spectrum need to be developed, synergistic effect can be produced and solves the problems, such as the Herbicidal combinations kind of resistant weed.
The content of the invention
To solve the above-mentioned problems in the prior art, the present invention provides a kind of humulone of sulphur containing triazole and pyridazine class chemical combination The Herbicidal combinations of thing and its application.It is miscellaneous that said composition can effectively prevent and kill off black nightshade in the crop fields, moleplant seed, rice barnyard grass, barnyard grass etc. Careless problem, have expand herbicide controlling spectrum, reduce amount of application, to crop safety, synergistic effect can be produced and solve resistant weed etc. Feature.
A kind of Herbicidal combinations of the humulone of sulphur containing triazole and pyridazine compound, include the active components A of herbicidally effective amount With active component B, wherein, active components A is triazole sulphur humulone, and B is pyridazine compound, selected from pyridate or cyclopyrimorate。
Wherein, A and B weight ratio is 1:120-120:1, preferably 1:100-100:1；Further, A and B weight ratio For 1:80-80:1, preferably 1:50-50:1；Further, A and B weight ratio is 1:20-20:1, preferably 1:10-10:1, more It is preferred that 1:5-5:1.
A, B weight/mass percentage composition account for the 1-95% of total amount, preferably 10-80% in the Herbicidal combinations.
Conven-tional adjuvants are also included in the Herbicidal combinations, the conven-tional adjuvants include carrier, surfactant.
Term " carrier " herein represents a kind of organic or inorganic, natural or synthetic material.They contribute to activity The administration of composition, the carrier are usually inert and must be agriculturally acceptable, and particularly processed plant is received. Carrier can be solid, such as clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer；Or liquid Body, such as water, alcohols, ketone, petroleum distillate, aromatic hydrocarbons or wax hydrocarbon, chlorohydrocarbon, liquefied gas.
Surfactant may include emulsifying agent, dispersant or wetting agent, and it can be ionic or nonionic.It can carry And example be the salt of polyacrylic acid, lignosulfonates, phenolsulfonic acid or naphthalene sulfonic acids salt, oxirane and aliphatic alcohol or Polymer, sulfosuccinic acid with aliphatic acid or with aliphatic amine and fortified phenol (particularly alkylphenol or aryl phenol) Phosphate, the alkyl of salt, taurine derivatives (particularly taurine alkane fat) and the phenol of alcohol phosphate or multi-hydroxy ethyl Sulfonate, alkylaryl sulfonates, alkyl sulfate, lauryl ether sulfate, aliphatic alcohol sulfate, and sulphation 16-, 17-and octadecanol and sulphated fatty alcohol glycol ether, in addition with the condensation of naphthalene or naphthalene sulfonic acids and phenol and formaldehyde Thing, NONIN HS 240, ethoxylated isooctyl-phenol, octyl phenol or nonyl phenol, alkyl phenyl polyglycol ether, three fourths Base phenyl polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol, alcohol and fatty alcohol/ethylene oxide contracting Compound, ethoxylated castor oil, polyoxyethylene alkyl ether, ethoxylation polyoxypropylene, laruyl alcohol polyglycol ether acetal, sorb Alcohol ester, lignin sulfite waste liquor, and protein, albuminate, polysaccharide (such as methylcellulose), Hydrophobic Modified Starch, Polyvinyl alcohol, polycarboxylate, poly-alkoxyl compound, polyvinylamine, polyvinylpyrrolidone and its copolymer.At least need one kind Surfactant is present, to be advantageous to scattered in water of active component and be advantageous to enable them to correctly be applied to plant.
Above-mentioned composition also contains various other components, such as protecting colloid, adhesive, thickener, thixotropic agent, infiltration Agent, stabilizer, chelating agent, dyestuff, colouring agent and polymer.
The composition of the present invention can be used by user before use through dilution or directly.It, which is prepared, to be added by common Work method prepare, i.e., after active material is mixed with liquid flux or solid carrier, add surfactant such as dispersant, surely Determine the one or more in agent, wetting agent, adhesive, defoamer etc..
The specific preparation of the Herbicidal combinations be dispersible oil-suspending agent, aqueous suspension agent, suspension emulsion, wettable powder, Missible oil, water dispersible granules (dry suspending agent), aqueous emulsion, microemulsion.
In brief, composition of the invention can be with conventional use of solid and liquid addition in the formula of prior art Agent mixes.
In addition, the composition of the composition and compound A and cyclopyrimorate of compound A and pyridate can be with Mixed with following active material, such as《World pesticide new varieties technology is complete works of》, Scientia Agricultura Sinica technology publishing house, 2010.9 With the known substance in document incorporated herein.Such as herbicidal activity material mentioned below, (remarks：The title of compound, It is either according to the common name of International Organization for standardization (ISO) or is chemical name have code name when appropriate)：Second grass Amine, butachlor, alachlor, propisochlor, isopropyl methoxalamine, S-metolachlor, pretilachlor, propachlor, kecaoan, naphthalene propionyl The left-handed naphthalene propionyl grass amine of careless amine, R-, propanil, mefenacet, diphenamide, diflufenican, N-alpha-chloroacetyl-N-isopropyl-o ethylaniline, fluorine butyryl grass Amine, bromobutide, dimethenamid, dimethenamidP, ethobenzanid, flufenacet, thenylchlor, pyrrole grass Amine, isoxaben, flampropMmethyl, flampropMisopropyl, allidochlor, pethoxamid, chloranocryl, the grass of ring third Amine, mefluidide, monalide, delachlor, prynachlor, terbuchlor, xylachlor, dimethachlor, amine of taking to the greenwood, Front three ring grass amine, clomeprop, propyzamide, valeryl benzene grass amine, the careless amine of card, suffer, three rings match careless amine, butylene grass Amine, tebutam, benzyl grass amine, quinone duckweed amine, dichlofluanid, naproanilide, acetyl alachlor, quinclorac, fenacet, pyrrole cyanogen grass amine, benzene More grams of grass is dead, chlorothiamid, chlorine phthalimide, fourth amidine amine, fluorine metazachlor, atrazine, Simanex, prometryn, cyanatryn, symetryne, Ametryn, propazine, dipropetryn, SSH-108, terbutryn, Garagard, triaziflam, cyprazine, proglinazine, trietazine, flutter Go out net logical, Gesadrual, nitrine, desmetryn, dimethametryn, third blue or green Tianjin of ring, green bristlegrass of going out Tianjin, another Ding Jin, Zhong Dingtong, Te Dingtong, methoxy Third is net, cyanatryn, ipazine, chlorazine, atraton, weed eradication are logical, radix glycyrrhizae Tianjin, cyanuric acid, Indaziflam, green sulphur are grand, first Sulphur is grand, bensulfuron-methyl, chlorimuron, tribenuron-methyl, thifensulfuron methyl, pyrazosulfuron, mesosulfuron, iodosulfuron-methyl-sodium, formyl Amino Sulfometuron Methyl, cinosulfuron, triasulfuron, sulfometuronmethyl, nicosulfuron, ethametsulfuron, amidosulfuron, ethoxysulfuron, ring Third Sulfometuron Methyl, rimsulfuron, azimsulfuron, pyridine ethyl methyl, monosulfmeturon, single phonetic sulphur ester, flucarbazone, flupyrsulfuron-methyl-sodium, Fluorine pyrazosulfuron, oxasulfuron, imazosulfuron, primisulfuronmethyl, procarbazone, prosulfuron, Sulfosulfuron, trifluoro pyridine Sulphur is grand, triflusulfuronmethyl, tritosulfuron, metsulfuron-methyl sodium salt, flucetosulfuron, Sulfonylurea, orthosulfamuron, Propyrisulfuron (promazine Sulfometuron Methyl), piperazine pyrazosulfuron, acifluorfen, fomesafen, lactofen, second carboxylic AKH7088, Oxyfluorfen, Mo 9 granular, aclonifen, ethoxyfen-ethyl, bifenox, fluoroform grass ether, methoxy weeding Ether, fluorodifen, fluorination nitrofen, fluorine furan grass ether, nitrofen, first grass ether, diformazan grass ether, fluorine lactazone grass ether, AKH7088 ester, Halosafen, chlortoluron, isoproturon, linuron, diuron, Sha flutter grand, fluometuron, benzthiazuron, methabenzthiazuron, cumyluron, Ethidimuron, isouron, terbufos benzthiazuron, buturon, bromax, methyldymron, phenobenzuron, methoxy daimuron, metobromuron, first Oxygen is grand, afesin, telvar, Tupersan, fenuron, fluorine sulphur are grand, neburea, chloroxifenidium, herban, isonoruron, Alipur-O, Thiazfluron, tebuthiuron, difenoxuron, to fluon, methylamine methabenz thiazuron, Long Caote, front three isourea, dimefuron, Monisouron, Anisuron, Methiuron, Chloreturon, four fluon, phenmedipham, phenmedipham-ethyl ester, desmedipham, the spirit of sulphur grass, special grass Spirit, oatax, Chem hoe, chlorpropham, benzyl dichloride grass ester, swep, chlorbufam, Carboxazole, Chlorprocarb, Fenasulam, BCPC, CPPC, Carbasulam, Ding Caote, benthiocarb, vernolate, molinate, tri-allate, dimepiperate, dogstail Fear, pyributicarb, cycloate, Avadex, bactericide, the careless spy of second sulphur, orbencarb, pebulate, prosulfocarb, tiocarbazil, sulfuric acid, Dimexan, Isopolinate, Methiobencarb, 2,4- d butyl ester, the chlorine sodium of 2 first 4, the different monooctyl ester of 2,4- drops, the chlorine of 2 first 4 are different pungent Ester, 2,4- drops sodium salt, 2,4- drops dimethylamine salt, the chloroethene thioesters of 2 first 4, the chlorine of 2 first 4,2,4- drops propionic acid, high 2,4- drops propionate, 2, 4- Embutoxs, Vi par, Vi par salt, Thistrol, 2,4,5- tears, 2,4,5- tears propionic acid, 2,4,5- tears fourths Acid, the chloramines salt of 2 first 4, Mediben, erbon, Fenac, match pine, trichlorobenzoic acid, chloramben, methoxy trichlorobenzoic acid, dogstail Spirit, fluazifop, efficient fluazifop, haloxyfop-P-methyl, efficient haloxyfop, quizalofop-ethyl, Quizalotop-ethyl, oxazole dogstail Spirit, fenoxapropPethyl, propaquizafop, cyhalofop-butyl, metamifop, clodinafop-propargyl, diclofop-methyl thiazole, chloroazifoppropynyl, the standing grain of hydroxyl penta spirit, Trifluoro dogstail oxime, isoxapyrifop, paraquat, diquat dibromide, oryzalin, ethalfluralin, isopropalin, nitralin, the fluorine of ring third Spirit, prodiamine, benfluralin, fluchloraline, the spirit of amino second fluorine, dipropalin, chloroethene dipropalin, Methalpropalin, Third nitre phenol, glyphosate, Sha barnyard grass phosphine, glufosinate-ammonium, amiprophos-methyl, sulphosate, piperazine grass phosphine, bialaphos, bensulide, butamifos, Creeping weed phosphorus, cut down ridge phosphorus, double first amiprophos, dow crabgrass killer, imazapyr, imazethapyr, imazaquin, imazamox, first Oxygen Imazethapyr ammonium salt, AC 263222, miaow grass ester, fluroxypyr, the different monooctyl ester of fluroxypyr, clopyralid, ammonia Chloropyridine acid, trichlopyr, dithiopyr, halogen grass are determined, phenolate trichloropyridine, thiazopyr, fluridone, chlorine Fampridine are sour, Diflufenzopyr, triclopyr butoxyethyl ester, Cliodinate, sethoxydim, clethodim, cycloxydim, alloxydimsodium, ring benzene grass Ketone, butroxydim, tralkoxydim, tepraloxydim, Buthidazole, metribuzin, hexazinone, metamitron, ethiozin, Ametridione, Amibuzin, Brominal, bromoxynil octanoate, ioxynil octanoate, ioxynil, dichlobenil, diphenatril, polybenzobisoxazole Oxalic acid dinitrile, chloroxynil, Iodobonil, Flumetsulam, florasulam, penoxsuam, metosulam, cloransulammethyl, Diclosulam, pyroxsulam, fluorine straw colour, bispyribac-sodium, pyribenzoxim, pyriftalid, KIH 6127, pyrithiobacsodium, bicyclic sulphur It is humulone, mesotrione, sulphur humulone, Tembotrione, Tefuryltrione, Bicyclopyrone, Ketodpiradox, different Oxazole humulone, isoxachlorotole, Fenoxasulfone, Methiozolin, fluazolate, pyraflufen-ethyl, pyrazolate, wild swallow Withered, pyrazoxyfen, benzofenap, pyrrole chlorine grass amine, Pyrasulfotole, topramezone, Pyroxasulfone, cafenstrole, fluorine amine grass Azoles, Amrol, amicarbazone, azafenidin, profluazone, sulfentrazone, Bencarbazone, benzfendizone, fluorine third are phonetic Careless ester, bromacil, isoprocil, lenacil, terbacil, Flupropacil, cinidon-ethyl, Flumiclorac pentyl, flumioxazin, Alkynes grass amine, phthalein benzyl oxide, Flumezin, pentachlorophenol (sodium), dinoseb, dinoterb, dinoterb acetate, dinosam, Chemox PE, chlorine nitre phenol, Medinoterb acetate, Di Lete, oxadiargyl, oxadiazon, pentoxazone, profluazol, fluthiacet, fentrazamide, fluorine Pyridazine grass ester, pyrazon, brompyrazon, diformazan reach careless volt, Kusakira, careless pyridazone, grass and rattled away pine, norflurazon, Pyridafol, dichloro Quinolinic acid, quinmerac, Bentazon, pyridate, oxaziclomefone, benazolin, clomazone, cinmethylin, iso-propyl-ester nitrofen, Propyl-ester nitorfen, indanofan, sodium chlorate, Dalapon, trichloroacetic acid, monochloroacetic acid, hexachloroacetone, tetrafluoro propionic acid, herbage are fast, bromine phenol Oxime, triazole sulphur, kill azoles, flurtamone, benfuresate, ethofumesate, phonetic careless amine, chlorine phthalandione, fluorochloridone, barnyard grass, methacrylaldehyde, Bentranil, tridiphane, Bidisin, thiadiazoles grass amine, phenisopham, hydroxyl humulone, dioxybenzone, benzene flumetsulam, chlorine acyl grass phosphine, three Chloropropionic acid, Alorac, Diethamquat, Etnipromid, Iprymidam, Ipfencarbazone, Thiencarbazone- Methyl, Pyrimisulfan, Chlorflurazole, Tripropindan, Sulglycapin, first sulphur nitralin, Cambendichlor, the pyrimidine acid of ring third, rodethanii, benoxacor, fenclorim, flurazole, fenchlorazole, the careless quinoline of solution, oxabetrinil, MG191, cyometrinil, DKA_24, mefenpyrdiethyl, furilazole, fluxofenim, isoxadifen, allyl dichloride amine, fluorine Chloropyridine ester, DOW chlorine fluorine pyridine ester, UBH-509, D489, LS 82-556, KPP-300, NC-324, NC-330, KH-218, DPX-N8189、SC-0744、DOWCO535、DK-8910、V-53482、PP-600、MBH-001、KIH-9201、ET-751、 KIH-6127 and KIH-2023.
The Herbicidal combinations further comprise safener, and it is selected from isoxadifen, cymolsulfamide, pyrrole Azoles cloquitocet_mexyl, cloquintocetmexyl, gibberellic acid, furilazole and N- (2-2 methoxybenzoyls base) -4- [(methylaminocarbonyl) ammonia Base] one or more in benzsulfamide.
The composition of the present invention can be applied on pending plant leaf blade by the method for spraying, that is, is applied to weeds, On the surface that the weed infestation or easy invasion being particularly harmful on plant growth influence.
When applying the Herbicidal combinations of the present invention, unexpected synergistic effect is obtained, and activity of weeding ratio makes It is individually active more notable with the expected summation of the activity of single herbicide, and single herbicide.Synergistic effect shows as applying Measure reduction, broader weeds distribution spectrum, herbicide effect faster, it is more longlasting, these characteristics are needed for Weeds distribution practice process Want.For described characteristic, these new compositions are significantly superior to existing herbicide.
The Herbicidal combinations of the present invention, which also have, to be had the advantage that：
(1) composition of the invention is environmentally friendly to be easy to degrade in the environment, suitable for various crop field.
(2) Herbicidal combinations cost of the invention is low, easy to use, and its popularization and application has huge economic benefit and society Benefit.
(3) compared with prior art, Herbicidal combinations of the present invention can prevent and kill off non-resistance grassy weed, and and can is prevented Except producing the barnyard grass of resistance, black nightshade and the grassy weed such as moleplant seed that resistance is produced to ACCase inhibitor to ALS inhibitor, It is the effective scheme of Weed Resistance management.
Embodiment
The following example not limits the present invention, and is used only to how the explanation present invention realizes.For some miscellaneous Grass, these embodiments show especially significant validity.It is exemplified below：
A) embodiment --- A compounds with pyridate
Cream preparation
Being formulated composition is：
Embodiment 1)+7% polyoxyethylene nonyl phenyl of+7% calcium dodecyl benzene sulfonate of+20% cyclohexanone of 4%A+16% pyridates Vinethene+150# aromatic solvent naphthas are supplied
Embodiment 2)+5% calcium dodecyl benzene sulfonate of+25% cyclopentanone of 6%A+24% pyridates+10% phenethyl phenol gather Oxygen vinethene+100# aromatic solvent naphthas are supplied
The process equipment of above-mentioned missible oil：Vavuum pump, batching kettle, storage tank.
The process of above-mentioned missible oil：All materials are put into batching kettle, for stirring and dissolving to fully transparent, chemical examination is qualified Afterwards, it is filling to be transferred to storage tank.
Microemulsion formulation
Being formulated composition is：
Embodiment 3)+8% maleic di-sec-octyl sodium sulfonate of+10% isooctanol of+20% cyclohexanone of 4%A+16% pyridates The phenethyl phenol polyethenoxy ether formaldehyde resin condensation product of+8% phenethyl phenol polyethenoxy ether+4%+water is supplied
Embodiment 4)+6% maleic di-sec-octyl sodium sulfonate of+8% isooctanol of+15% cyclohexanone of 3%A+12% pyridates+ The phenethyl phenol polyethenoxy ether formaldehyde resin condensation product of 10% phenethyl phenol polyethenoxy ether+4%+water is supplied
Above-mentioned microemulsion process equipment：Vavuum pump, batching kettle, storage tank.
Above-mentioned microemulsion process：Active compound and solvent are put into batching kettle, stirring and dissolving to fully transparent, Zhi Houjia Enter emulsifying agent, stir, finally plus water, stir fully transparent to solution, after chemical examination is qualified, it is filling to be transferred to storage tank.
Water and milk agent formulation
Being formulated composition is：
Embodiment 5)+3% phenethyl phenol polyoxyethylene of+15% cyclohexanone+15%200# solvent naphthas of 3%A+12% pyridates The xanthans+3% of+3% castor oil polyoxyethylene ether of+4% phenethyl phenol polyethenoxy ether of ether phosphate triethanolamine salt+0.2% Ethylene glycol+water is supplied
Embodiment 6)+3% phenethyl phenol polyoxyethylene of+25% cyclohexanone+15%200# solvent naphthas of 5%A+20% pyridates The xanthans+3% of+3% castor oil polyoxyethylene ether of+5% phenethyl phenol polyethenoxy ether of ether phosphate triethanolamine salt+0.1% Ethylene glycol+water is supplied
Above-mentioned aqueous emulsion process equipment：Vavuum pump, batching kettle, storage tank, cutting kettle.
Above-mentioned aqueous emulsion process：Active compound and solvent are put into batching kettle, stirring and dissolving to fully transparent, Zhi Houjia Enter emulsifying agent, be stirred for oil phase, ethylene glycol, defoamer and water are pumped into cutting kettle afterwards, finally under shearing condition, Oil phase is slowly pumped into cutting kettle, after whole materials are pumped into, continues to shear 1 hour, after chemical examination is qualified, is transferred to storage tank filling Dress.
Aqueous suspension agent preparation
Being formulated composition is：
Embodiment 7)+2% fat of+3% polycarboxylic acid salt dispersant+3%EO-PO block polyethers of 4.5%A+18% pyridates + 5% glycerine of aluminium-magnesium silicate of+0.2% xanthans of fat alcohol APEO+1.5%+water is supplied.
Embodiment 8) fat of+4% polycarboxylic acid salt dispersant+4%EO-PO block polyethers of 6%A+24% pyridates+2% + 5% glycerine of aluminium-magnesium silicate of+0.15% xanthans of alcohol APEO+1.5%+water is supplied.
Above-mentioned aqueous suspension agent process equipment：Mixing kettle, colloid mill, sand mill, cutter etc..
Above-mentioned aqueous suspension agent process：By all materials put into mixing kettle in, after being stirred cross colloid mill, it is laggard Enter sand mill three-level sanding, finally sheared in cutter uniformly, after chemical examination is qualified, it is filling to be transferred to storage tank.
Dispersible oil-suspending agent preparation
Being formulated composition is：
Embodiment 9)+4% castor of+7% aliphatic acid polyethenoxy ether of+5% calcium dodecyl benzene sulfonate of 4%A+16% pyridates Fumed silica+10%150# the solvent naphthas of+2.5% organobentonite of sesame oil APEO+2.0%+methyl oleate is mended Foot.
Embodiment 10)+7% aliphatic acid polyethenoxy ether of+4% calcium dodecyl benzene sulfonate of 6.5%A+26% pyridates+ Fumed silica+20%200# the solvent naphthas of+2.5% organobentonite of 4% castor oil polyoxyethylene ether+1.5%+oleic acid first Ester is supplied.
Embodiment 11)+6% NPE+4% of+6% calcium dodecyl benzene sulfonate of 8%A+32% pyridates The organobentonite of castor oil polyoxyethylene ether+2.5%+40%200# solvent naphthas+methyl oleate is supplied.
Embodiment 12)+7% aliphatic acid polyethenoxy ether+4% of+6% calcium dodecyl benzene sulfonate of 5%A+20% pyridates Organobentonite+100# the solvent naphthas of castor oil polyoxyethylene ether+0.5% are supplied.
Above-mentioned dispersible oil-suspending agent process equipment：Mixing kettle, colloid mill, sand mill, cutter etc..
Above-mentioned dispersible oil-suspending agent process：All materials are put into mixing kettle, colloid mill is crossed after being stirred, Enter sand mill three-level sanding afterwards, finally sheared in cutter uniformly, after chemical examination is qualified, it is filling to be transferred to storage tank.
Wettable powder formulation
Being formulated composition is：
Embodiment 13) 4%A+16% pyridates+10% naphthalenesulfonate dispersant+25% precipitation method of+5% pull open powder are white Carbon black+diatomite is supplied
Embodiment 14)+5% lauryl sodium sulfate+30% of+10% naphthalenesulfonate dispersant of 6%A+24% pyridates Precipitated silica+calcined kaolin is supplied
Above-mentioned wettable powder process equipment：Mechanical crusher, airslide disintegrating mill.
Above-mentioned wettable powder process：Active compound, auxiliary agent, white carbon, kaolin etc. are put into mechanical crusher, it Airslide disintegrating mill is crossed afterwards, it is standby after sample examination is qualified.
Water-dispersible grain agent formulation
Being formulated composition is：
Embodiment 15)+1% poly- second of disintegrant of+6% pull open powder of+10% polycarboxylic acid salt's dispersant of 3%A+12% pyridates The precipitated silica of enol+25%+filler diatomite is supplied.
Embodiment 16)+15% polycarboxylic acid salt's dispersant of 5%A+20% pyridates+4% lauryl sodium sulfate+1% collapse + 30% precipitated silica of solution agent polyvinyl alcohol+filler calcined kaolin is supplied.
Above-mentioned water dispersible granules process equipment：Airslide disintegrating mill, coulter type mixer, basket comminutor, drying box, screening Machine etc..
Above-mentioned water dispersible granules process：Above-mentioned material was well mixed air-flow crushing, adds water to enter to mediate granulation, it After dry, final sizing obtains finished product.
B) embodiment --- A and cyclopyrimorate is compounded
Cream preparation
Being formulated composition is：
Embodiment 17)+7% DBSA of 3%A+3%cyclopyrimorate+10%N- methyl pyrrolidones The phenethyl phenol polyethenoxy ether formaldehyde resin condensation product+150# aromatic solvent naphthas of the AEO of calcium+7%+3% are supplied
Embodiment 18)+8% nonyl of+7% calcium dodecyl benzene sulfonate of 5%A+5%cyclopyrimorate+20% cyclohexanone The phenethyl phenol polyethenoxy ether formaldehyde resin condensation product+150# aromatic solvent naphthas of base phenol polyethenoxy ether+2.5% are supplied
The process equipment of above-mentioned missible oil：Vavuum pump, batching kettle, storage tank.
The process of above-mentioned missible oil：All materials are put into batching kettle, for stirring and dissolving to fully transparent, chemical examination is qualified Afterwards, it is filling to be transferred to storage tank.
Microemulsion formulation
Being formulated composition is：
Embodiment 19)+8% maleic di-secondary of+10% n-octyl alcohol of 5%A+5%cyclopyrimorate+25% cyclohexanone The phenethyl phenol polyethenoxy ether formaldehyde resin condensation product of the phenethyl phenol polyethenoxy ether of dioctyl sodium sulfosuccinate+8%+2%+water is supplied
Embodiment 20)+6% maleic di-secondary of+8% isooctanol of 8%A+8%cyclopyrimorate+25% cyclopentanone is pungent The phenethyl phenol polyethenoxy ether formaldehyde resin condensation product of+10% phenethyl phenol polyethenoxy ether of ester sodium sulfonate+4%+water is supplied
Above-mentioned microemulsion process equipment：Vavuum pump, batching kettle, storage tank.
Above-mentioned microemulsion process：Active compound and solvent are put into batching kettle, stirring and dissolving to fully transparent, Zhi Houjia Enter emulsifying agent, stir, finally plus water, stir fully transparent to solution, after chemical examination is qualified, it is filling to be transferred to storage tank.
Water and milk agent formulation
Being formulated composition is：
Embodiment 21)+3% phenethyl of 4%A+4%cyclopyrimorate+15% cyclohexanone+15%200# solvent naphthas The castor oil polyoxyethylene ether+0.2% of+3% phenethyl phenol polyethenoxy ether of phenol polyethenoxy ether phosphate triethanolamine salt+3% The ethylene glycol of xanthans+3%+water is supplied
Embodiment 22)+3% phenethyl of 5%A+5%cyclopyrimorate+25% cyclohexanone+15%200# solvent naphthas The castor oil polyoxyethylene ether+0.1% of+4% phenethyl phenol polyethenoxy ether of phenol polyethenoxy ether phosphate triethanolamine salt+3% The ethylene glycol of xanthans+3%+water is supplied
Above-mentioned aqueous emulsion process equipment：Vavuum pump, batching kettle, storage tank, cutting kettle.
Above-mentioned aqueous emulsion process：Active compound and solvent are put into batching kettle, stirring and dissolving to fully transparent, Zhi Houjia Enter emulsifying agent, be stirred for oil phase, ethylene glycol, defoamer and water are pumped into cutting kettle afterwards, finally under shearing condition, Oil phase is slowly pumped into cutting kettle, after whole materials are pumped into, continues to shear 1 hour, after chemical examination is qualified, is transferred to storage tank filling Dress.
Aqueous suspension agent preparation
Being formulated composition is：
Embodiment 23) 4.5%A+4.5%cyclopyrimorate+3% polycarboxylic acid salt's dispersant+3%EO-PO blocks + 5% glycerine of aluminium-magnesium silicate of+0.2% xanthans of the AEO of polyethers+2%+1.5%+water is supplied.
Above-mentioned aqueous suspension agent process equipment：Mixing kettle, colloid mill, sand mill, cutter etc..
Above-mentioned aqueous suspension agent process：By all materials put into mixing kettle in, after being stirred cross colloid mill, it is laggard Enter sand mill three-level sanding, finally sheared in cutter uniformly, after chemical examination is qualified, it is filling to be transferred to storage tank.
Dispersible oil-suspending agent preparation
Being formulated composition is：
Embodiment 24)+7% polyoxyethylene nonyl phenyl second of 4%A+4%cyclopyrimorate+5% calcium dodecyl benzene sulfonates + 2.5% fumed silica of organobentonite of+4% castor oil polyoxyethylene ether of alkene ether+3.0%+methyl oleate is supplied.
Embodiment 25)+7% aliphatic acid polyoxy second of 6%A+6%cyclopyrimorate+4% calcium dodecyl benzene sulfonates Fumed silica+5%200# the solvent naphthas of+2.8% organobentonite of+4% castor oil polyoxyethylene ether of alkene ether+1.5%+oil Sour methyl esters is supplied.
Embodiment 26)+6% fatty alcohol polyoxy second of 8%A+8%cyclopyrimorate+6% calcium dodecyl benzene sulfonates Organobentonite+5%200# the solvent naphthas of+4% castor oil polyoxyethylene ether of alkene ether+2.5%+methyl oleate is supplied.
Embodiment 27)+7% aliphatic acid polyoxy of 12%A+12%cyclopyrimorate+6% calcium dodecyl benzene sulfonates Organobentonite+10%150# the solvent naphthas of the castor oil polyoxyethylene ether of vinethene+4%+1.5%+methyl oleate is supplied.
Above-mentioned dispersible oil-suspending agent process equipment：Mixing kettle, colloid mill, sand mill, cutter etc..
Above-mentioned dispersible oil-suspending agent process：All materials are put into mixing kettle, colloid mill is crossed after being stirred, Enter sand mill three-level sanding afterwards, finally sheared in cutter uniformly, after chemical examination is qualified, it is filling to be transferred to storage tank.
Wettable powder formulation
Being formulated composition is：
Embodiment 28)+4% pull open powder of 10%A+10%cyclopyrimorate+10% naphthalenesulfonates dispersant+ 15% precipitated silica+diatomite is supplied
Embodiment 29)+5% dodecane of 15%A+15%cyclopyrimorate+10% lignin sulfonates dispersant + 20% precipitated silica of base sodium sulphate+calcined kaolin is supplied
Above-mentioned wettable powder process equipment：Mechanical crusher, airslide disintegrating mill.
Above-mentioned wettable powder process：Active compound, auxiliary agent, white carbon, kaolin etc. are put into mechanical crusher, it Airslide disintegrating mill is crossed afterwards, it is standby after sample examination is qualified.
Water-dispersible grain agent formulation
Being formulated composition is：
Embodiment 30)+6% pull open powder+1% of 12%A+12%cyclopyrimorate+10% polycarboxylic acid salts dispersant + 15% precipitated silica of disintegrant polyvinyl alcohol+filler diatomite is supplied.
Embodiment 31)+4% dodecyl sulphur of 20%A+20%cyclopyrimorate+15% polycarboxylic acid salts dispersant + 20% precipitated silica of the sour disintegrant of sodium+1% polyvinyl alcohol+filler calcined kaolin is supplied.
Above-mentioned water dispersible granules process equipment：Airslide disintegrating mill, coulter type mixer, basket comminutor, drying box, screening Machine etc..
Above-mentioned water dispersible granules process：Above-mentioned material was well mixed air-flow crushing, adds water to enter to mediate granulation, it After dry, final sizing obtains finished product.
C) the test of pesticide effectiveness
After seedling cauline leaf spraying treatment：
1) experimental condition
1.1), for trying target
Barnyard grass (Echinochloa crusgalli) picks up from Changsha County in Hunan province's rice terrace, rice barnyard grass (Echinochloa Phyllopogon (stapf) Koss.) Heilungkiang Hulin City is picked up from, moleplant seed (Leptochloa chinensis) picks up from Hubei Huangmei County, black nightshade (Solanum nigrum L.) collection Shandong Huangdao District, above-mentioned weeds use pot-culture method culture, with 180 х 140mm plastic nutrition bowls, are placed in enamel tray, built-in that the topsoil (at 4/5) for backing through and air-drying sieving, soil are adopted from farmland Humidity controls 20% initial stage, selects the homogeneous weed seed of full seed, is soaked 6 hours with 25 DEG C of warm water, in 28 DEG C of lifes Change vernalization in incubator (dark), the weed seed just to have showed money or valuables one carries unintentionally is uniformly placed in soil surface, according to seed particle size size Then earthing 0.5-1cm.
1.2), condition of culture
Carried out in controllable heliogreenhouse, 20~30 DEG C of temperature, natural lighting, relative humidity 57%~72%.
Soil types is loam, the content of organic matter 1.63%, pH=7.1, alkali-hydrolyzable nitrogen 84.3mg/kg, rapid available phosphorus 38.5mg/kg, available potassium 82.1mg/kg.
1.3), instrument and equipment
3WP-2000 type walking spray towers, Nanjing Agricultural Machinery Inst., Ministry of Agriculture.GA10 type a ten thousandth electronics day Flat (Germany)；ZDR2000 intelligent datas recorder (Hangzhou Ze great Instrument Ltd.)；SPX type Intelligent biochemistry incubators (Ningbo South of the River instrument plant).
2) experimental design
2.1), reagent
2.1.1), test medicine
Required active component B is bought by Reagent Company, and A produces for our company.
Active compound uses acetone as solvent, is diluted with the aqueous solution of 0.1% emulsifier tween of content -80, current existing dilution.
2.2), test process
2.2.1), dosage is set
It is determined that A and active component B are matched or during contents, should be weighed from the action character of two kinds of medicaments and its virulence etc., It is also contemplated that the main application target of the formula.This research is on the basis of prerun early stage, if A, B activity composition are alone and mix Dosage is shown in Table lattice respectively.Blank control is used as using the water without medicament, containing same solvent and emulsifying agent.
2.2.2), experiment repeats
Often processing is repeated 4 times, and often handles 3 basins every time, and per basin, sowing weed seed 20, often handles totally 60 plants.
2.3), processing mode
2.3.1), processing time and number
Experiment shares medicine 1 time.Treat the heart stage of 3 leaf of weeds 1, thinning, keep 15 plants of weeds in per basin, often processing retains 45 plants, Then proceed to cultivate to barnyard grass, rice barnyard grass, the heart stage of 4 leaf of moleplant seed 1, black nightshade 6-7 leaf phases and handled.
2.3.2), using apparatus and administrated method
Cultured examination material is uniformly placed in area 0.5m2Platform on, with 3WP-2000 type walking spray tower stems Foliar spray mist, spouting liquid is based on 30 kilograms/hectare.Atomisation pressure 0.3MPa.After whole liquid medicine jets are complete, air valve is closed, after 30 seconds, Spraying pyller is opened, takes out nutritive cube.Then air valve is opened, sprays clear water 50mL, cleans sparge pipe.
3) test method
Using pot-culture method.Weeds culture is shown in 1.1, reference《Farm-chemical indoor determination test rule herbicide》Carry out.With Prescription method is shown in 2.3.2, using cauline leaf process method.Greenhouse cellar culture is moved into after processing, 1-2cm water is remained during experiment Layer.
4) data survey and statistical analysis
4.1), investigation method
Using absolute number investigation method, the survival whole strain seedling of weeds is cut off along soil surface with blade, is weighed with assay balance Weeds fresh weight.It is based on zero by fresh weight for dead weeds.
4.2), control time and number
Investigate within 20 days after processing, investigate 1 time altogether.
4.3), data statistic analysis
The theoretical fresh weight inhibition (E0=X+Y-X*Y/100) of each processing hybrid combining, Ran Houyu are calculated with Gowing methods Actual measurement inhibiting rate (E) compares, the two mixed synergy type to weeds of evaluation, is that synergy is made when E-E0 values are more than 10% With, less than -10% be antagonism, be addition between -10%~10%.It is and special according to actual preventive effect and herbicide The factors such as point, the balance being formulated determine optimum proportioning.
X is fresh weight inhibition when active components A dosage is P in formula；Y is that fresh weight when active component B dosages are Q suppresses Rate.
Statistical result see the table below 1-26, wherein, for material black nightshade of having a try (6-7 leaf phases), moleplant seed (heart stage of 4 leaf 1), rice barnyard grass (4 The heart stage of leaf 1), barnyard grass (heart stage of 4 leaf 1) cauline leaf spraying treatment, after experiment 7 days statistics fresh weight preventive effect.
The A of table 1 is with pyridate mixture to the actual preventive effect of black nightshade and synergy evaluation (Gowing)
The A of table 2 is with pyridate mixture to the actual preventive effect of weeds and synergy evaluation (Gowing)
The A of table 3 is with pyridate mixture to the actual preventive effect of weeds and synergy evaluation (Gowing)
The A of table 4 is with pyridate mixture to the actual preventive effect of weeds and synergy evaluation (Gowing)
The A of table 5 is with pyridate mixture to the actual preventive effect of weeds and synergy evaluation (Gowing)
The A of table 6 is with pyridate mixture to the actual preventive effect of weeds and synergy evaluation (Gowing)
The A of table 7 is with pyridate mixture to the actual preventive effect of weeds and synergy evaluation (Gowing)
The A of table 8 is with pyridate mixture to the actual preventive effect of weeds and synergy evaluation (Gowing)
The A of table 9 is with pyridate mixture to the actual preventive effect of weeds and synergy evaluation (Gowing)
The A of table 10 is with pyridate mixture to the actual preventive effect of weeds and synergy evaluation (Gowing)
The A of table 11 is with pyridate mixture to the actual preventive effect of black nightshade and synergy evaluation (Gowing)
The A of table 12 is with pyridate mixture to the actual preventive effect of black nightshade and synergy evaluation (Gowing)
The A of table 13 is with pyridate mixture to the actual preventive effect of black nightshade and synergy evaluation (Gowing)
The A of table 14 is with pyridate mixture to the actual preventive effect of black nightshade and synergy evaluation (Gowing)
The A of table 15 is with pyridate mixture to the actual preventive effect of black nightshade and synergy evaluation (Gowing)
The A of table 16 is with cyclopyrimorate mixtures to the actual preventive effect of black nightshade and synergy evaluation (Gowing)
The A of table 17 is with cyclopyrimorate mixtures to the actual preventive effect of weeds and synergy evaluation (Gowing)
The A of table 18 is with cyclopyrimorate mixtures to the actual preventive effect of weeds and synergy evaluation (Gowing)
The A of table 19 is with cyclopyrimorate mixtures to the actual preventive effect of weeds and synergy evaluation (Gowing)
The A of table 20 is with cyclopyrimorate mixtures to the actual preventive effect of weeds and synergy evaluation (Gowing)
The A of table 21 is with cyclopyrimorate mixtures to the actual preventive effect of weeds and synergy evaluation (Gowing)
The A of table 22 is with cyclopyrimorate mixtures to the actual preventive effect of weeds and synergy evaluation (Gowing)
The A of table 23 is with cyclopyrimorate mixtures to the actual preventive effect of black nightshade and synergy evaluation (Gowing)
The A of table 24 is with cyclopyrimorate mixtures to the actual preventive effect of black nightshade and synergy evaluation (Gowing)
The A of table 25 is with cyclopyrimorate mixtures to the actual preventive effect of black nightshade and synergy evaluation (Gowing)
The A of table 26 is with cyclopyrimorate mixtures to the actual preventive effect of black nightshade and synergy evaluation (Gowing)
D) field demonstration
Utilize embodiment 1) -31) made from herbicidal composition prevent and kill off paddy field weed experiment.
Exemplary promote is carried out in 4 testing sites of Changsha morning rice region within 2016 to test.
Test method：After the heart of 3 leaf of rice 1, the weeds 3-4 leaf phases, hand sprayer, 30 kilograms/667m of the amount of being watered2, use Cauline leaf spraying even spraying, specific test medicine and dosage refer to table 5 and table 6,50 square metres of plot area, and often processing repeats 4 It is secondary.45 days investigation preventive effects are shown in Table 5 and table 6 after dispenser.
The A of table 5 and pyridate complex composition field demonstration effect situation
The A of table 6 and cyclopyrimorate complex compositions field demonstration effect situation
By lot of experiments and exploration, it is an unexpected discovery of the invention that the composition prevents and kill off grass for rice terrace after seedling Section weeds, there is surprising, unexpected synergistic effect, especially to grassy weeds such as barnyard grass, moleplant seeds, crack rice The broad leaved weedses such as the Cyperaceaes such as nutgrass flatsedge, Monochoria vaginalis, Eclipta prostrata have particularly evident synergistic effect, and this synergistic effect is at low dose The lower performance of amount is more notable, can reduce dosage, and to rice safety, reduce the pollution to environment, and rationally compounding reduces Agricultural cost, it is efficient to ALS, ACCase inhibitor resistant weed, there is good application prospect.Simultaneously by test in wheat The lawns such as field, corn field, soybean, cotton, vegetables, annual bluegrass, Festuca Arundinacea, Korea lawn grass and crop show good selectivity and excellent Different synergistic effect, the herbicide combination product of extensive market value can be developed into.

Claims (10)

1. the Herbicidal combinations of a kind of humulone of sulphur containing triazole and pyridazine compound, it is characterised in that including herbicidally effective amount Active components A and active component B, wherein, active components A is triazole sulphur humulone, and B is pyridazine compound, selected from pyridate or cyclopyrimorate。
2. the Herbicidal combinations of a kind of humulone of sulphur containing triazole according to claim 1 and pyridazine compound, its feature exist In A and B weight ratio are 1:120-120:1, preferably 1:100-100:1.
3. the Herbicidal combinations of a kind of humulone of sulphur containing triazole according to claim 2 and pyridazine compound, its feature exist In A and B weight ratio are 1:80-80:1, preferably 1:50-50:1.
4. the Herbicidal combinations of a kind of humulone of sulphur containing triazole according to claim 3 and pyridazine compound, its feature exist In A and B weight ratio are 1:20-20:1, preferably 1:10-10:1, more preferably 1:5-5:1.
5. the Herbicidal combination of a kind of humulone of sulphur containing triazole and pyridazine compound according to Claims 1-4 any one Thing, it is characterised in that A and B weight/mass percentage composition accounts for the 1-95% of total amount in the Herbicidal combinations.
6. the Herbicidal combinations of a kind of humulone of sulphur containing triazole according to claim 5 and pyridazine compound, its feature exist In A and B weight/mass percentage composition accounts for the 10-80% of total amount in the Herbicidal combinations.
7. the Herbicidal combination of a kind of humulone of sulphur containing triazole and pyridazine compound according to claim 1 to 6 any one Thing, it is characterised in that also include carrier, surfactant in the Herbicidal combinations.
8. the Herbicidal combination of a kind of humulone of sulphur containing triazole and pyridazine compound according to claim 1 to 6 any one Thing, it is characterised in that the specific preparation of the Herbicidal combinations is dispersible oil-suspending agent, aqueous suspension agent, suspension emulsion, wettable Pulvis, missible oil, water dispersible granules, aqueous emulsion or microemulsion.
9. the Herbicidal combination of a kind of humulone of sulphur containing triazole and pyridazine compound according to claim 1 to 6 any one Thing, it is characterised in that the Herbicidal combinations further comprise safener, and it is selected from isoxadifen, cymene sulphur Acid amides, mefenpyrdiethyl, cloquintocetmexyl, gibberellic acid, furilazole and N- (2-2 methoxybenzoyls base) -4- [(methylaminos Carbonyl) amino] one or more in benzsulfamide.
10. the Herbicidal combinations of the humulone of sulphur containing triazole and pyridazine compound as described in claim 1 to 9 any one are being prevented and treated Application in crop on injurious weed.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020124531A1 (en) * 2018-12-19 2020-06-25 青岛清原化合物有限公司 Ternary herbicidal composition containing cyclopyrimorate and application thereof
WO2022068377A1 (en) * 2020-09-30 2022-04-07 青岛清原化合物有限公司 Binary herbicidal composition and use thereof
CN115088725A (en) * 2021-08-16 2022-09-23 吉林省八达农药有限公司 Weeding composition and preparation method thereof

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CN105503728A (en) * 2015-12-31 2016-04-20 青岛清原化合物有限公司 Pyrazole compounds or salts thereof and preparation method thereof, and weedicide composition and application thereof

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CN105503728A (en) * 2015-12-31 2016-04-20 青岛清原化合物有限公司 Pyrazole compounds or salts thereof and preparation method thereof, and weedicide composition and application thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020124531A1 (en) * 2018-12-19 2020-06-25 青岛清原化合物有限公司 Ternary herbicidal composition containing cyclopyrimorate and application thereof
WO2022068377A1 (en) * 2020-09-30 2022-04-07 青岛清原化合物有限公司 Binary herbicidal composition and use thereof
CN114304165A (en) * 2020-09-30 2022-04-12 青岛清原化合物有限公司 Binary weeding composition and application thereof
CN114304165B (en) * 2020-09-30 2023-07-07 青岛清原化合物有限公司 Binary weeding composition and application thereof
CN115088725A (en) * 2021-08-16 2022-09-23 吉林省八达农药有限公司 Weeding composition and preparation method thereof

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