CN107517978A - A kind of ternary weeding composition and its application of the humulone of sulphur containing triazole and anilofos - Google Patents
A kind of ternary weeding composition and its application of the humulone of sulphur containing triazole and anilofos Download PDFInfo
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- CN107517978A CN107517978A CN201710747920.3A CN201710747920A CN107517978A CN 107517978 A CN107517978 A CN 107517978A CN 201710747920 A CN201710747920 A CN 201710747920A CN 107517978 A CN107517978 A CN 107517978A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
- A01N43/42—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
- A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
- A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
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Abstract
The invention belongs to pesticide field, and in particular to a kind of ternary weeding composition and its application of the humulone of sulphur containing triazole and anilofos.The ternary weeding composition includes active components A, B and the C of herbicidally effective amount, wherein, active components A is triazole sulphur humulone, B is anilofos, one kind that C is flutterred in grand, prometryn and amicarbazone selected from dichloro quinolinic acid, propanil, bentazone, pyridate, cyclopyrimorate, symetryne, isoproturon, Sha.Said composition can effectively prevent and kill off the weed problems such as lady's-grass, barnyard grass, moleplant seed, difformed galingale herb, rice barnyard grass, have the characteristics that to expand herbicide controlling spectrum, reduce amount of application, to crop safety, synergistic effect can be produced and solve resistant weed.
Description
Technical field
The invention belongs to pesticide field, and in particular to the ternary weeding composition of a kind of humulone of sulphur containing triazole and anilofos and
It is applied.
Background technology
Chemical weed control is means the most economical and effective during farmland weed is prevented and kill off, but uses list for a long time continuous high dose
The chemical herbicide of one kind or the single mode of action, the problems such as easily causing weeds resistance and resistance evolution.
Triazole sulphur humulone chemical structural formula isIt is the rice terrace after seedling stem newly researched and developed
The HPPD inhibitor class herbicide of leaf processing, has excellent bioactivity, can effectively prevent and kill off a variety of malignant weeds of rice terrace.
Compound anilofos category organic phosphates selective inner-adsorption conduction-type herbicide.Inhaled by the young shoot and subterranean stem of plant
Receive, suppress Tom Clancy Splinter Cell stretching, extension, make weeds young leaves be not easy to extract out, growth stops, last withered.Can effectively it prevent and kill off in 3 leaf phases
Barnyard grass and sedge weed, to rice safety.
The reasonable compounding or mixture of herbicidal compounds, which have, to be expanded weeds spectrum, improves preventive effect, delays weeds resistance
Property and it is drug-fast generation with development the advantages that, be one of maximally efficient method to solve the above problems.Therefore in production urgently
Safe, broad weed-killing spectrum need to be developed, synergistic effect can be produced and solves the problems, such as the Herbicidal combinations kind of resistant weed.
The content of the invention
To solve the above-mentioned problems in the prior art, the present invention provides the three of a kind of humulone of sulphur containing triazole and anilofos
First Herbicidal combinations and its application, said composition can effectively prevent and kill off the weeds such as lady's-grass, barnyard grass, moleplant seed, difformed galingale herb, rice barnyard grass and ask
Topic, have the characteristics that to expand herbicide controlling spectrum, reduction amount of application, to crop safety, synergistic effect can be produced and solve resistant weed.
A kind of ternary weeding composition of the humulone of sulphur containing triazole and anilofos, including the active components A of herbicidally effective amount, B
And C, wherein, active components A is triazole sulphur humulone, and B is anilofos, C be selected from dichloro quinolinic acid, propanil, bentazone, pyridate,
(structural formula is cyclopyrimorate), symetryne, isoproturon, Sha flutter grand, prometryn and amine
One kind in azoles humulone.
Wherein, A, B and C weight ratio are 0.5-50:1-50:0.5-300, preferably 0.5-30:5-40:1-200, more preferably
1-30:5-30:5-100, further preferred 1-20:10-30:10-50.
A, the weight of B and dichloro quinolinic acid ratio is 1-20:5-30:5-30；
A, the weight of B and propanil ratio is 0.5-20:5-30:10-200；
A, the weight of B and bentazone ratio is 0.5-30:5-30:10-200；
A, the weight of B and pyridate ratio is 0.5-20:5-30:5-100；
A, B and cyclopyrimorate weight ratio is 1-30:5-35:1-50；
A, the weight of B and isoproturon ratio is 0.5-20:10-40:1-30；
A, the weight of B and amicarbazone ratio is 1-30:5-30:0.5-30；
A, it is 1-30 that B and Sha, which flutter grand weight ratio,:5-30:5-300；
A, the weight of B and symetryne ratio is 1-30:5-30:1-40；
A, the weight of B and prometryn ratio is 1-30:5-30:1-40.
A, B and C weight/mass percentage composition account for the 1-95% of total amount, preferably 10-80% in the Herbicidal combinations.
Conven-tional adjuvants are also included in the Herbicidal combinations, the conven-tional adjuvants include carrier, surfactant.
Term " carrier " herein represents a kind of organic or inorganic, natural or synthetic material.They contribute to activity
The administration of composition, the carrier are usually inert and must be agriculturally acceptable, and particularly processed plant is received.
Carrier can be solid, such as clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer；Or liquid
Body, such as water, alcohols, ketone, petroleum distillate, aromatic hydrocarbons or wax hydrocarbon, chlorohydrocarbon, liquefied gas.
Surfactant may include emulsifying agent, dispersant or wetting agent, and it can be ionic or nonionic.It can carry
And example be the salt of polyacrylic acid, lignosulfonates, phenolsulfonic acid or naphthalene sulfonic acids salt, oxirane and aliphatic alcohol or
Polymer, sulfosuccinic acid with aliphatic acid or with aliphatic amine and fortified phenol (particularly alkylphenol or aryl phenol)
Phosphate, the alkyl of salt, taurine derivatives (particularly taurine alkane fat) and the phenol of alcohol phosphate or multi-hydroxy ethyl
Sulfonate, alkylaryl sulfonates, alkyl sulfate, lauryl ether sulfate, aliphatic alcohol sulfate, and sulphation 16-,
17-and octadecanol and sulphated fatty alcohol glycol ether, in addition with the condensation of naphthalene or naphthalene sulfonic acids and phenol and formaldehyde
Thing, NONIN HS 240, ethoxylated isooctyl-phenol, octyl phenol or nonyl phenol, alkyl phenyl polyglycol ether, three fourths
Base phenyl polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol, alcohol and fatty alcohol/ethylene oxide contracting
Compound, ethoxylated castor oil, polyoxyethylene alkyl ether, ethoxylation polyoxypropylene, laruyl alcohol polyglycol ether acetal, sorb
Alcohol ester, lignin sulfite waste liquor, and protein, albuminate, polysaccharide (such as methylcellulose), Hydrophobic Modified Starch,
Polyvinyl alcohol, polycarboxylate, poly-alkoxyl compound, polyvinylamine, polyvinylpyrrolidone and its copolymer.At least need one kind
Surfactant is present, to be advantageous to scattered in water of active component and be advantageous to enable them to correctly be applied to plant.
Above-mentioned composition also contains various other components, such as protecting colloid, adhesive, thickener, thixotropic agent, infiltration
Agent, stabilizer, chelating agent, dyestuff, colouring agent and polymer.
The composition of the present invention can be used by user before use through dilution or directly.It, which is prepared, to be added by common
Work method prepare, i.e., after active material is mixed with liquid flux or solid carrier, add surfactant such as dispersant, surely
Determine the one or more in agent, wetting agent, adhesive, defoamer etc..
The specific preparation of the Herbicidal combinations is dispersible oil-suspending agent, aqueous suspension agent, suspension emulsion, missible oil, moisture dissipate
Granula (dry suspending agent), aqueous emulsion, microemulsion.
In brief, composition of the invention can be with conventional use of solid and liquid addition in the formula of prior art
Agent mixes.
In addition, the composition of compound triazole sulphur humulone, anilofos and active component C can mix with following active material
Close, such as《World pesticide new varieties technology is complete works of》, Scientia Agricultura Sinica technology publishing house, 2010.9 and document incorporated herein
In known substance.Such as herbicidal activity material mentioned below, (remarks：The title of compound, or to be marked according to the world
The common name of standardization tissue (ISO), or be chemical name, have code name when appropriate)：Acetochlor, butachlor, first grass
The left-handed naphthalene of amine, propisochlor, isopropyl methoxalamine, S-metolachlor, pretilachlor, propachlor, kecaoan, naphthalene propionyl grass amine, R-
Propionyl grass amine, propanil, mefenacet, diphenamide, diflufenican, N-alpha-chloroacetyl-N-isopropyl-o ethylaniline, beflubutamid, bromobutide,
Dimethenamid, dimethenamidP, ethobenzanid, flufenacet, thenylchlor, metazachlor, isoxaben, efficiently
Flamprop methyl ester, flampropMisopropyl, allidochlor, pethoxamid, chloranocryl, ring pretilachlor, mefluidide, oenanthyl
Careless amine, delachlor, prynachlor, terbuchlor, xylachlor, dimethachlor, amine of taking to the greenwood, front three ring grass amine, chloroformyl
Careless amine, propyzamide, valeryl benzene grass amine, the careless amine of card, suffer, three rings match careless amine, butenachlor, tebutam, benzyl grass amine, quinone
Duckweed amine, dichlofluanid, naproanilide, acetyl alachlor, quinclorac, fenacet, pyrrole cyanogen grass amine, benzene grass more grams of dead, chlorothiamid, chlorine phthaleins
Imines, fourth amidine amine, fluorine metazachlor, atrazine, Simanex, prometryn, cyanatryn, symetryne, ametryn, propazine, dipropetryn,
SSH-108, terbutryn, Garagard, triaziflam, cyprazine, proglinazine, trietazine, prometon, Gesadrual, nitrine are net, enemy
Careless net, dimethametryn, third blue or green Tianjin of ring, green bristlegrass of going out Tianjin, another Ding Jin, Zhong Dingtong, Te Dingtong, methoxy third are net, cyanatryn, ipazine, can
Happy Tianjin, atraton, weed eradication are logical, radix glycyrrhizae Tianjin, cyanuric acid, Indaziflam, green sulphur are grand, metsulfuron-methyl, bensulfuron-methyl, the phonetic Huang of chlorine
Grand, tribenuron-methyl, thifensulfuron methyl, pyrazosulfuron, mesosulfuron, iodosulfuron-methyl-sodium, formamido group Sulfometuron Methyl, cinosulfuron, ether
Tribenuron-methyl, sulfometuronmethyl, nicosulfuron, ethametsulfuron, amidosulfuron, ethoxysulfuron, AC322140, rimsulfuron, four
Azoles Sulfometuron Methyl, pyridine ethyl methyl, monosulfmeturon, single phonetic sulphur ester, flucarbazone, flupyrsulfuron-methyl-sodium, fluorine pyrazosulfuron, the phonetic sulphur of epoxy
Grand, imazosulfuron, primisulfuronmethyl, procarbazone, prosulfuron, Sulfosulfuron, trifloxysulfuron, triflusulfuronmethyl, trifluoro
Metsulfuron-methyl, metsulfuron-methyl sodium salt, flucetosulfuron, Sulfonylurea, orthosulfamuron, Propyrisulfuron (promazine Sulfometuron Methyl),
Piperazine pyrazosulfuron, acifluorfen, fomesafen, lactofen, fluoroglycofen-ethyl, Oxyfluorfen, Mo 9 granular, benzene grass
Ether, ethoxyfen-ethyl, bifenox, fluoroform grass ether, chlomethoxyfen, fluorodifen, fluorination nitrofen, fluorine furan grass
Ether, nitrofen, first grass ether, diformazan grass ether, fluorine lactazone grass ether, AKH7088 ester, Halosafen, chlortoluron, isoproturon, linuron,
Diuron, Sha flutter grand, fluometuron, benzthiazuron, methabenzthiazuron, cumyluron, ethidimuron, isouron, terbufos benzthiazuron, alkynes grass
It is grand, bromax, methyldymron, phenobenzuron, methoxy daimuron, metobromuron, metoxuron, afesin, telvar, Tupersan, non-
Grass it is grand, fluorine sulphur is grand, neburea, chloroxifenidium, herban, isonoruron, Alipur-O, thiazfluron, tebuthiuron, difenoxuron, to fluon,
Methylamine methabenz thiazuron, Long Caote, front three isourea, dimefuron, Monisouron, Anisuron, Methiuron, Chloreturon,
The careless spirit of four fluon, phenmedipham, phenmedipham-ethyl ester, desmedipham, sulphur, terbucarb, oatax, Chem hoe, chlorpropham, benzyl dichloride
Careless ester, swep, chlorbufam, Carboxazole, Chlorprocarb, Fenasulam, BCPC, CPPC, Carbasulam, fourth
Careless spy, benthiocarb, vernolate, molinate, tri-allate, dimepiperate, esprocarb, pyributicarb, cycloate, Avadex, bactericide, second
Sulphur grass spy, orbencarb, pebulate, prosulfocarb, tiocarbazil, sulfuric acid, dimexan, Isopolinate, Methiobencarb,
2,4- d butyl esters, the chlorine sodium of 2 first 4, the different monooctyl ester of 2,4- drops, the different monooctyl ester of the chlorine of 2 first 4,2,4- drops sodium salt, 2,4- drops dimethylamine salt, 2 first 4
Chloroethene thioesters, the chlorine of 2 first 4,2,4- drops propionic acid, high 2,4- drops propionate, 2,4- Embutoxs, Vi par, Vi par salt,
Thistrol, 2,4,5- tears, 2,4,5- tears propionic acid, 2,4,5- tears butyric acid, the chloramines salt of 2 first 4, Mediben, erbon, cut down grass
Gram, match pine, trichlorobenzoic acid, chloramben, methoxy trichlorobenzoic acid, diclofop-methyl, fluazifop, efficient fluazifop, fluorine pyrrole
First standing grain is clever, efficient haloxyfop, quizalofop-ethyl, Quizalotop-ethyl, fenoxaprop-P, fenoxapropPethyl, propaquizafop, cyanogen fluorine grass
Ester, metamifop, clodinafop-propargyl, diclofop-methyl thiazole, chloroazifoppropynyl, the spirit of the standing grain of hydroxyl penta, trifluoro dogstail oxime, isoxapyrifop, paraquat, enemy
Careless fast, oryzalin, ethalfluralin, isopropalin, nitralin, profluralin, prodiamine, benfluralin, chloroethene fluorine
Spirit, the spirit of amino second fluorine, dipropalin, chloroethene dipropalin, Methalpropalin, the third nitre phenol, glyphosate, Sha barnyard grass phosphine, glufosinate-ammonium, first
Base amiprophos, sulphosate, piperazine grass phosphine, bialaphos, bensulide, butamifos, creeping weed phosphorus, cut down ridge phosphorus, double first amiprophos, Cao Te
Phosphorus, imazapyr, imazethapyr, imazaquin, imazamox, imazamox ammonium salt, AC 263222, miaow grass
The different monooctyl ester of ester, fluroxypyr, fluroxypyr, clopyralid, picloram, trichlopyr, fluorine sulphur grass
Fixed, halogen grass is determined, phenolate trichloropyridine, thiazopyr, fluridone, chlorine Fampridine acid, diflufenzopyr, trichlopyr butoxy second
Ester, Cliodinate, sethoxydim, clethodim, cycloxydim, alloxydimsodium, clefoxidim, butroxydim, tralkoxydim, tepraloxydim,
Buthidazole, metribuzin, hexazinone, metamitron, ethiozin, Ametridione, Amibuzin, Brominal, decoyl
Brominal, ioxynil octanoate, ioxynil, dichlobenil, diphenatril, pyraclonil, chloroxynil, Iodobonil, flumetsulam
Amine, florasulam, penoxsuam, metosulam, cloransulammethyl, diclosulam, pyroxsulam, fluorine straw colour, double grass
Ether, pyribenzoxim, pyriftalid, KIH 6127, pyrithiobacsodium, benzobicylon, mesotrione, sulphur humulone,
Tembotrione, Tefuryltrione, Bicyclopyrone, Ketodpiradox, isoxaflutole, isoxachlorotole,
Fenoxasulfone, Methiozolin, fluazolate, pyraflufen-ethyl, pyrazolate, difenzoquat, pyrazoxyfen, benzofenap, pyrrole chlorine
Careless amine, Pyrasulfotole, topramezone, Pyroxasulfone, cafenstrole, flupoxam, Amrol, amicarbazone, azoles
Pyridine humulone, profluazone, sulfentrazone, Bencarbazone, benzfendizone, butafenacil, bromacil, isoprocil, ring
Careless pyridine, terbacil, Flupropacil, cinidon-ethyl, Flumiclorac pentyl, flumioxazin, alkynes grass amine, phthalein benzyl oxide,
Flumezin, pentachlorophenol (sodium), dinoseb, dinoterb, dinoterb acetate, dinosam, Chemox PE, chlorine nitre phenol, medinoterb acetate, Di Lete,
Oxadiargyl, oxadiazon, pentoxazone, profluazol, fluthiacet, fentrazamide, flufenpyrethyl, herbicide
Quick, brompyrazon, diformazan reach careless volt, Kusakira, careless pyridazone, grass and rattled away pine, norflurazon, Pyridafol, dichloro quinolinic acid, chloromethane quinoline
Quinoline acid, Bentazon, pyridate, oxaziclomefone, benazolin, clomazone, cinmethylin, iso-propyl-ester nitrofen, propyl-ester nitorfen, indenes grass
Ketone, sodium chlorate, Dalapon, trichloroacetic acid, monochloroacetic acid, hexachloroacetone, tetrafluoro propionic acid, herbage are fast, bromofenoxim, triazole sulphur, go out
Kill azoles, flurtamone, benfuresate, ethofumesate, phonetic careless amine, chlorine phthalandione, fluorochloridone, barnyard grass, methacrylaldehyde, bentranil, weed eradication
Ring, Bidisin, thiadiazoles grass amine, phenisopham, hydroxyl humulone, dioxybenzone, benzene flumetsulam, chlorine acyl grass phosphine, chloropon,
Alorac、Diethamquat、Etnipromid、Iprymidam、Ipfencarbazone、Thiencarbazone-methyl、
Pyrimisulfan, Chlorflurazole, Tripropindan, Sulglycapin, first sulphur nitralin,
Cambendichlor, the pyrimidine acid of ring third, rodethanii, benoxacor, fenclorim, flurazole, fenchlorazole, the careless quinoline of solution, oxabetrinil,
MG191, cyometrinil, DKA_24, mefenpyrdiethyl, furilazole, fluxofenim, isoxadifen, allyl dichloride amine, fluorine
Chloropyridine ester, DOW chlorine fluorine pyridine ester, UBH-509, D489, LS 82-556, KPP-300, NC-324, NC-330, KH-218,
DPX-N8189、SC-0744、DOWCO535、DK-8910、V-53482、PP-600、MBH-001、KIH-9201、ET-751、
KIH-6127 and KIH-2023.
The Herbicidal combinations further comprise safener, and it is selected from isoxadifen, cymolsulfamide, pyrrole
Azoles cloquitocet_mexyl, cloquintocetmexyl, gibberellic acid, furilazole and N- (2-2 methoxybenzoyls base) -4- [(methylaminocarbonyl) ammonia
Base] one or more in benzsulfamide.
The composition of the present invention can be applied on pending plant leaf blade by the method for spraying, that is, is applied to weeds,
On the surface that the weed infestation or easy invasion being particularly harmful on plant growth influence.
When applying the ternary weeding composition of the present invention, its activity of weeding any binary combination relative to single dose and wherein
Thing obtains unexpected synergistic effect.It is embodied in amount of application reduction, broader weeds distribution spectrum, herbicide effect more
It hurry up, be more longlasting, these characteristics are required in Weeds distribution practice process.For described characteristic, these Combination novas
Thing is significantly superior to existing herbicide.
The Herbicidal combinations of the present invention, which also have, to be had the advantage that：
(1) composition of the invention is environmentally friendly to be easy to degrade in the environment, suitable for various crop.
(2) Herbicidal combinations cost of the invention is low, easy to use, and its popularization and application has huge economic benefit and society
Benefit.
(3) compared with prior art, Herbicidal combinations of the present invention can prevent and kill off resistance lady's-grass, barnyard grass, moleplant seed, abnormal shape
The weeds such as nutgrass flatsedge, rice barnyard grass, it is the effective scheme of resistant weed management.
Embodiment
The following example not limits the present invention, and is used only to how the explanation present invention realizes.For some miscellaneous
Grass, these embodiments show especially significant validity.It is exemplified below：
A, embodiment
1.1 triazoles+anilofos+dichloro quinolinic acid
Suspension emulsion formula forms：
Embodiment 1)+4% benzene of 6%+10% dichloro quinolinic acid+10%100# solvent naphthas of+12% anilofos of triazole sulphur humulone
+ 2% AEO of ethyl phenol polyoxyethylene ether phosphate triethanolamine salt+1%EO-PO block polyethers+0.2% is yellow
+ 5% glycerine of the aluminium-magnesium silicate of virgin rubber+2%+water is supplied.
Dispersible oil-suspending agent formula forms：
Embodiment 2)+4% calcium dodecyl benzene sulfonate of 9%+15% dichloro quinolinic acid of triazole sulphur+18% anilofos of humulone+
Organobentonite+10%150# the solvent naphthas of+5% castor oil polyoxyethylene ether of 7% aliphatic acid polyethenoxy ether+2%+methyl oleate
Supply.
Wettable powder agent prescription forms：
Embodiment 3)+8% naphthalenesulfonate dispersant of 12%+20% dichloro quinolinic acid of triazole sulphur+24% anilofos of humulone+
6%+25% precipitated silica of pull open powder+diatomite is supplied.
Water-dispersible grain agent prescription forms：
Embodiment 4)+12% polycarboxylic acid salt's dispersant of 9%+15% dichloro quinolinic acid of triazole sulphur+18% anilofos of humulone+
+ 5% precipitated silica of disintegrant polyvinyl alcohol of 6% pull open powder+1%+filler calcined kaolin is supplied.
1.2 triazoles+anilofos+propanil
Emulsifiable concentrate formulation forms：
Embodiment 5)+5% DBSA of 3%+20% cyclopentanone of triazole sulphur humulone+10% propanil of+5% anilofos
NPE+100# the aromatic solvent naphthas of calcium+7% are supplied.
Micro-emulsion formulation forms：
Embodiment 6) 3% triazole sulphur humulone+10% propanil of+5% anilofos+10% isooctanol+8% of+30% cyclopentanone is suitable
The phenethyl phenol polyethenoxy ether formaldehyde resin condensation product of+8% phenethyl phenol polyethenoxy ether of butylene di-sec-octyl sodium sulfonate+2%+
Water is supplied.
Water emulsion formula forms：
Embodiment 7)+20% cyclohexanone+15%200# solvent naphthas of 2%+6.5% propanil of triazole sulphur+3.5% anilofos of humulone
The castor oil polyoxy second of+3%+2% phenethyl phenol polyethenoxy ether of phenethyl phenol polyethenoxy ether phosphate triethanolamine salt+3%
+ 3% ethylene glycol of xanthans of alkene ether+0.2%+water is supplied.
Suspension emulsion formula forms：
Embodiment 8)+4% phenethyl phenol of 6%+20% propanil+10%100# solvent naphthas of+10% anilofos of triazole sulphur humulone
The xanthans of+2% NPE of polyoxyethylene ether phosphate triethanolamine salt+1%EO-PO block polyethers+0.2%+
2%+5% glycerine of aluminium-magnesium silicate+water is supplied.
Dispersible oil-suspending agent formula forms：
Embodiment 9)+8% nonyl of 6%+6% calcium dodecyl benzene sulfonate of triazole sulphur humulone+20% propanil of+10% anilofos
The decyl amide of+2.5% organobentonite+10%200# solvent naphthas of the castor oil polyoxyethylene ether of phenol polyethenoxy ether+3%+15%+oil
Sour methyl esters is supplied.
Wettable powder agent prescription forms：
Embodiment 10) 6%+20% propanil of triazole sulphur+10% anilofos of humulone+10% naphthalenesulfonate dispersant+5% draw
The precipitated silica of powder+25%+diatomite is opened to supply.
Water-dispersible grain agent prescription forms：
Embodiment 11)+10% polycarboxylic acid salt's dispersant+4% ten of 6%+20% propanil of triazole sulphur+10% anilofos of humulone
+ 30% precipitated silica of the disintegrant polyethylene glycol of sodium dialkyl sulfate+1%+filler calcined kaolin is supplied.
1.3 triazoles+anilofos+bentazone
Suspension emulsion formula forms：
Embodiment 12)+4% phenethyl of 2%+15% bentazone+10%100# solvent naphthas of+6% anilofos of triazole sulphur humulone
The xanthans of+2% AEO of phenol polyethenoxy ether phosphate triethanolamine salt+2%EO-PO block polyethers+0.2%
+ 2%+5% glycerine of aluminium-magnesium silicate+water is supplied.
Dispersible oil-suspending agent formula forms：
Embodiment 13)+4% calcium dodecyl benzene sulfonate+7% of 4%+30% bentazone of triazole sulphur+12% anilofos of humulone
Organobentonite+10%150# the solvent naphthas of the castor oil polyoxyethylene ether of aliphatic acid polyethenoxy ether+5%+2%+methyl oleate is mended
Foot.
Wettable powder agent prescription forms：
Embodiment 14)+10% naphthalenesulfonate dispersant+6% of 4%+30% bentazone of triazole sulphur+12% anilofos of humulone
The precipitated silica of pull open powder+10%+diatomite is supplied.
Water-dispersible grain agent prescription forms：
Embodiment 15)+12% polycarboxylic acid salt's dispersant+6% of 4%+30% bentazone of triazole sulphur+12% anilofos of humulone
+ 5% precipitated silica of the disintegrant polyvinyl alcohol of pull open powder+1%+filler calcined kaolin is supplied.
1.4 triazoles+anilofos+pyridate
Emulsifiable concentrate formulation forms：
Embodiment 16)+6% detergent alkylate of 4%+20% cyclopentanone of triazole sulphur humulone+15% pyridate of+10% anilofos
NPE+100# the aromatic solvent naphthas of sulfoacid calcium+10% are supplied.
Micro-emulsion formulation forms：
Embodiment 17)+10% cyclohexanone of 2%+20% cyclopentanone of triazole sulphur humulone+7.5% pyridate of+5% anilofos+
The phenethyl phenol polyethenoxy ether formaldehyde resin of 8%+8% phenethyl phenol polyethenoxy ether of maleic di-sec-octyl sodium sulfonate+2% contracts
Compound+water is supplied.
Water emulsion formula forms：
Embodiment 18)+20% cyclohexanone+15%200# solvents of 2%+7.5% pyridate of triazole sulphur+5% anilofos of humulone
The oily castor oil polyoxy of+3%+2% phenethyl phenol polyethenoxy ether of phenethyl phenol polyethenoxy ether phosphate triethanolamine salt+3%
+ 3% ethylene glycol of the xanthans of vinethene+0.2%+water is supplied.
Suspension emulsion formula forms：
Embodiment 19)+4% phenethyl of 8%+30% pyridate+20%100# solvent naphthas of+20% anilofos of triazole sulphur humulone
The xanthans of+2% NPE of phenol polyethenoxy ether phosphate triethanolamine salt+3%EO-PO block polyethers+0.2%
+ 2%+5% glycerine of aluminium-magnesium silicate+water is supplied.
Dispersible oil-suspending agent formula forms：
Embodiment 20)+6% calcium dodecyl benzene sulfonate+8% of 4%+15% pyridate of triazole sulphur+10% anilofos of humulone
The caprinoyl of+2.5% organobentonite+20%200# solvent naphthas of the castor oil polyoxyethylene ether of NPE+3%+15%
Amine+methyl oleate is supplied.
Wettable powder agent prescription forms：
Embodiment 21)+10% naphthalenesulfonate dispersant+5% of 4%+15% pyridate of triazole sulphur+10% anilofos of humulone
The precipitated silica of pull open powder+35%+diatomite is supplied.
Water-dispersible grain agent prescription forms：
Embodiment 22)+10% polycarboxylic acid salt's dispersant+4% of 4%+15% pyridate of triazole sulphur+10% anilofos of humulone
+ 30% precipitated silica of the disintegrant polyethylene glycol of lauryl sodium sulfate+1%+filler calcined kaolin is supplied.
1.5 triazoles+anilofos+symetryne
Suspension emulsion formula forms：
Embodiment 23)+4% phenethyl of 9%+15% symetryne+10%100# solvent naphthas of+18% anilofos of triazole sulphur humulone
The xanthans of+2% AEO of phenol polyethenoxy ether phosphate triethanolamine salt+2%EO-PO block polyethers+0.2%
+ 2%+5% glycerine of aluminium-magnesium silicate+water is supplied.
Dispersible oil-suspending agent formula forms：
Embodiment 24)+4% calcium dodecyl benzene sulfonate+7% of 6%+10% symetryne of triazole sulphur+12% anilofos of humulone
Organobentonite+10%150# the solvent naphthas of the castor oil polyoxyethylene ether of aliphatic acid polyethenoxy ether+5%+2%+methyl oleate is mended
Foot.
Wettable powder agent prescription forms：
Embodiment 25)+10% naphthalenesulfonate dispersant+6% of 6%+10% symetryne of triazole sulphur+12% anilofos of humulone
The precipitated silica of pull open powder+25%+diatomite is supplied.
Water-dispersible grain agent prescription forms：
Embodiment 26)+12% polycarboxylic acid salt's dispersant+6% of 6%+10% symetryne of triazole sulphur+12% anilofos of humulone
+ 25% precipitated silica of the disintegrant polyvinyl alcohol of pull open powder+1%+filler calcined kaolin is supplied.
1.6 triazoles+anilofos+isoproturon
Suspension emulsion formula forms：
Embodiment 27)+4% benzene second of 12%+10% isoproturon+15%100# solvent naphthas of+16% anilofos of triazole sulphur humulone
The xanthan of+3% castor oil polyoxyethylene ether of base phenol polyethenoxy ether phosphate triethanolamine salt+2%EO-PO block polyethers+0.2%
+ 5% glycerine of the aluminium-magnesium silicate of glue+2%+water is supplied.
Dispersible oil-suspending agent formula forms：
Embodiment 28)+7% fat of 6%+4% calcium dodecyl benzene sulfonate of triazole sulphur humulone+5% isoproturon of+8% anilofos
Organobentonite+10%150# the solvent naphthas of+5% castor oil polyoxyethylene ether of fat acid APEO+2%+methyl oleate is supplied.
Wettable powder agent prescription forms：
Embodiment 29)+10% naphthalenesulfonate dispersant of 12%+10% isoproturon of triazole sulphur+16% anilofos of humulone+
6%+25% precipitated silica of pull open powder+diatomite is supplied.
Water-dispersible grain agent prescription forms：
Embodiment 30) 6%+5% isoproturon of triazole sulphur+8% anilofos of humulone+12% polycarboxylic acid salt's dispersant+6% draw
+ 25% precipitated silica of the disintegrant polyvinyl alcohol of powder+1%+filler calcined kaolin is opened to supply.
1.7 triazoles+anilofos+Sha flutters grand
Suspension emulsion formula forms：
Embodiment 31) 6%+12% anilofos of triazole sulphur humulone+12% Sha flutter the grand phenethyl of+15%100# solvent naphthas+4%
The xanthans of+3% castor oil polyoxyethylene ether of phenol polyethenoxy ether phosphate triethanolamine salt+2%EO-PO block polyethers+0.2%
+ 2%+5% glycerine of aluminium-magnesium silicate+water is supplied.
Dispersible oil-suspending agent formula forms：
Embodiment 32) 6%+12% anilofos of triazole sulphur humulone+12% Sha flutter grand+4% calcium dodecyl benzene sulfonate+7%
Organobentonite+10%150# the solvent naphthas of the castor oil polyoxyethylene ether of aliphatic acid polyethenoxy ether+5%+2%+methyl oleate is mended
Foot.
Wettable powder agent prescription forms：
Embodiment 33) 9%+18% anilofos of triazole sulphur humulone+18% Sha flutter grand+10% naphthalenesulfonate dispersant+6%
The precipitated silica of pull open powder+25%+diatomite is supplied.
Water-dispersible grain agent prescription forms：
Embodiment 34) 6%+12% anilofos of triazole sulphur humulone+12% Sha flutter grand+12% polycarboxylic acid salt dispersant+6%
+ 25% precipitated silica of the disintegrant polyvinyl alcohol of pull open powder+1%+filler calcined kaolin is supplied.
1.8 triazoles+anilofos+prometryn
Suspension emulsion formula forms：
Embodiment 35)+3% phenethyl of 8%+20% prometryn+15%100# solvent naphthas of+20% anilofos of triazole sulphur humulone
The xanthans of+3% castor oil polyoxyethylene ether of phenol polyethenoxy ether phosphate triethanolamine salt+2%EO-PO block polyethers+0.2%
+ 2%+5% glycerine of aluminium-magnesium silicate+water is supplied.
Dispersible oil-suspending agent formula forms：
Embodiment 36)+4% calcium dodecyl benzene sulfonate+7% of 4%+10% prometryn of triazole sulphur+10% anilofos of humulone
Organobentonite+10%150# the solvent naphthas of the castor oil polyoxyethylene ether of aliphatic acid polyethenoxy ether+5%+2%+methyl oleate is mended
Foot.
Wettable powder agent prescription forms：
Embodiment 37)+8% naphthalenesulfonate dispersant+5% of 8%+20% prometryn of triazole sulphur+20% anilofos of humulone
The precipitated silica of pull open powder+25%+diatomite is supplied.
Water-dispersible grain agent prescription forms：
Embodiment 38)+10% polycarboxylic acid salt's dispersant+5% of 8%+20% prometryn of triazole sulphur+20% anilofos of humulone
+ 25% precipitated silica of the disintegrant polyvinyl alcohol of pull open powder+1%+filler calcined kaolin is supplied.
1.9 triazoles+anilofos+amicarbazone
Suspension emulsion formula forms：
Embodiment 39)+3% benzene second of 6%+2% amicarbazone+15%100# solvent naphthas of+12% anilofos of triazole sulphur humulone
The xanthan of+3% castor oil polyoxyethylene ether of base phenol polyethenoxy ether phosphate triethanolamine salt+2%EO-PO block polyethers+0.2%
+ 5% glycerine of the aluminium-magnesium silicate of glue+2%+water is supplied.
Dispersible oil-suspending agent formula forms：
Embodiment 40)+4% calcium dodecyl benzene sulfonate+7% of 9%+3% amicarbazone of triazole sulphur+18% anilofos of humulone
Fume colloidal silica+the 10%150# of+2% organobentonite of the castor oil polyoxyethylene ether of aliphatic acid polyethenoxy ether+4%+1.5%
Solvent naphtha+methyl oleate is supplied.
Wettable powder agent prescription forms：
Embodiment 41)+10% naphthalenesulfonate dispersant of 12%+4% amicarbazone of triazole sulphur+24% anilofos of humulone+
6%+25% precipitated silica of pull open powder+diatomite is supplied.
Water-dispersible grain agent prescription forms：
Embodiment 42)+10% polycarboxylic acid salt's dispersant of 6%+2% amicarbazone of triazole sulphur+12% anilofos of humulone+
+ 30% precipitated silica of disintegrant polyvinyl alcohol of 5% pull open powder+1%+filler calcined kaolin is supplied.
1.10 triazoles+anilofos+cyclopyrimorate
Emulsifiable concentrate formulation forms：
Embodiment 43)+15% anilofos+10%cyclopyrimorate+20% cyclopentanone+6% of 4% triazole sulphur humulone
NPE+100# the aromatic solvent naphthas of calcium dodecyl benzene sulfonate+10% are supplied.
Micro-emulsion formulation forms：
Embodiment 44)+6% anilofos+7.5%cyclopyrimorate+20% cyclopentanone+10% of 3% triazole sulphur humulone
The phenethyl phenol polyethenoxy ether first of+8% phenethyl phenol polyethenoxy ether of the maleic di-sec-octyl sodium sulfonate of cyclohexanone+8%+2%
Urea formaldehyde condensation product+water is supplied.
Water emulsion formula forms：
Embodiment 45)+5% anilofos+7.5%cyclopyrimorate+20% cyclohexanone+15% of 2% triazole sulphur humulone
The castor of+3%+2% phenethyl phenol polyethenoxy ether of phenethyl phenol polyethenoxy ether phosphate triethanolamine salt of 200# solvent naphthas+3%
+ 3% ethylene glycol of xanthans of sesame oil APEO+0.2%+water is supplied.
Suspension emulsion formula forms：
Embodiment 46)+20% anilofos+30%cyclopyrimorate+20%100# solvent naphthas of 8% triazole sulphur humulone+
The NPE of 4% phenethyl phenol polyethenoxy ether phosphate triethanolamine salt+3%EO-PO block polyethers+2%+
+ 5% glycerine of aluminium-magnesium silicate of 0.2% xanthans+2%+water is supplied.
Dispersible oil-suspending agent formula forms：
Embodiment 47)+15% anilofos+10%cyclopyrimorate+6% detergent alkylate sulphurs of 4% triazole sulphur humulone
Sour organobentonite+20%200# the solvent naphthas of+3% castor oil polyoxyethylene ether of the NPE of calcium+8%+2.5%+
15% decyl amide+methyl oleate is supplied.
Wettable powder agent prescription forms：
Embodiment 48)+10% anilofos+15%cyclopyrimorate+10% naphthalenesulfonates of 4% triazole sulphur humulone
+ 35% precipitated silica of the pull open powder of dispersant+5%+diatomite is supplied.
B, the test of pesticide effectiveness
After seedling cauline leaf spraying treatment：
1) experimental condition
1.1), for trying target
Lady's-grass (Cyperus difformis) picks up from Lianyungang of Jiangsu, barnyard grass (Echinochloa crusgalli) is picked up from
Jiangxi Poyang rice terrace, moleplant seed (Leptochloa chinensis) pick up from Jiashan of Zhejiang, difformed galingale herb (Cyperus
Difformis L.) collection Hubei Gongan County, rice barnyard grass (Echinochloa phyllopogon (stapf) Koss.) pick up from black dragon
River Hulin City, above-mentioned weeds use pot-culture method culture, with 180 х 140mm plastic nutrition bowls, are placed in enamel tray, it is built-in from
The topsoil (at 4/5) for backing through and air-drying sieving is adopted in farmland, and soil moisture controls 20% initial stage, and it is homogeneous to select full seed
Weed seed, soaked 6 hours with 25 DEG C of warm water, the vernalization in 28 DEG C of biochemical cultivation cases (dark), the weeds that will have just showed money or valuables one carries unintentionally
Seed is uniformly placed in soil surface, according to seed particle size size and then earthing 0.5-1cm.
1.2), condition of culture
Carried out in controllable heliogreenhouse, 20~30 DEG C of temperature, natural lighting, relative humidity 57%~72%.
Soil types is loam, the content of organic matter 1.63%, pH=7.1, alkali-hydrolyzable nitrogen 84.3mg/kg, rapid available phosphorus
38.5mg/kg, available potassium 82.1mg/kg.
1.3), instrument and equipment
3WP-2000 type walking spray towers, Nanjing Agricultural Machinery Inst., Ministry of Agriculture.GA10 type a ten thousandth electronics day
Flat (Germany)；ZDR2000 intelligent datas recorder (Hangzhou Ze great Instrument Ltd.)；SPX type Intelligent biochemistry incubators (Ningbo
South of the River instrument plant).
2) experimental design
2.1), reagent
2.1.1), test medicine
Required active components A is produced for our company, and other are bought by Reagent Company.
Active compound uses acetone as solvent, is diluted with the emulsifying agent T-80 aqueous solution of content 0.1%, current existing dilution.
2.2), test process
2.2.1), dosage is set
It is determined that active component proportioning or during content, should be weighed from the action character of medicament and its virulence etc., it is also contemplated that
The main application target of the formula.This research is on the basis of prerun early stage, if active component is alone and mixing dosage is shown in respectively
Form.Blank control is used as using the water without medicament, containing same solvent and emulsifying agent.
2.2.2), experiment repeats
Often processing is repeated 4 times, and often handles 3 basins every time, and per basin, sowing weed seed 20, often handles totally 60 plants.
2.3), processing mode
2.3.1), processing time and number
Experiment shares medicine 1 time.Treat the heart stage of 3 leaf of weeds 1, thinning, keep 15 plants of weeds in per basin, often processing retains 45 plants,
Culture is then proceeded to barnyard grass, rice barnyard grass, moleplant seed, the heart stage of 4 leaf of lady's-grass 1, the leaf phase of difformed galingale herb 4 uniform cauline leaf spraying treatment.
2.3.2), using apparatus and administrated method
Cultured examination material is uniformly placed in area 0.5m2Platform on, with 3WP-2000 type walking spray tower stems
Foliar spray mist, spouting liquid is based on 30 kilograms/hectare.Atomisation pressure 0.3MPa.After whole liquid medicine jets are complete, air valve is closed, after 30 seconds,
Spraying pyller is opened, takes out nutritive cube.Then air valve is opened, sprays clear water 50ml, cleans sparge pipe.
3) test method
Using pot-culture method.Weeds culture is shown in 1.1, reference《Farm-chemical indoor determination test rule herbicide》Carry out.With
Prescription method is shown in 2.3.2, using cauline leaf process method.Greenhouse cellar culture is moved into after processing, 1-2cm water is remained during experiment
Layer.
4), data survey and statistical analysis
4.1), investigation method
Using absolute number investigation method, the survival whole strain seedling of weeds is cut off along soil surface with blade, is weighed with assay balance
Weeds fresh weight.It is based on zero by fresh weight for dead weeds.
4.2), control time and number
Investigate within 15 days after processing, investigate 1 time altogether.
4.3), data statistic analysis
Examined with Colby methods, evaluation any both and the mixed synergy type to weeds of three.
Clip respectively handles ground chlorenchyma during 15d, using scales/electronic balance weighing, calculates actual survival rate：E (%)=
(treatment region weeds fresh weight/check plot weeds fresh weight) × 100
Theoretical weeds survival rate calculation formula is：E0 (%)=X × Y/100 (Binary mixture)
In formula X represent dosage as P when A weeds survival rate, Y represent dosage as Q when B weeds survival rate, E0 represent use
Measure for (P+Q) when A+B theoretical weeds survival rate, E represents the actual weeds survival rate of each processing.
E0 (%)=X × Y × Z × ... × N/100(n-1)(ternary and the above are used with)
X, Y, Z, N represent the actual survival rate of n kind single doses respectively in formula, and n is complex weedicide kind quantity.
Work as E0-E>When 10%, illustrate to produce synergistic effect；Work as E0-E<When -10%, illustrate to produce antagonism；Work as E0-E
Between ± 10% when, illustrate produce summation action.
Statistical result see the table below 1-42：
Table 1A, B and dichloro quinolinic acid mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Note：A+B+C theoretical survival rate is calculated except 10000 by the product of the actual survival rate of 3 kinds of single doses, similarly hereinafter.
Table 2A, B and dichloro quinolinic acid mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 3A, B and dichloro quinolinic acid mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 4A, B and dichloro quinolinic acid mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 5A, B and dichloro quinolinic acid mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 6A, B and propanil mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 7A, B and propanil mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 8A, B and propanil mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 9A, B and propanil mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 10A, B and propanil mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 11A, B and bentazone mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 12A, B and bentazone mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 13A, B and bentazone mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 14A, B and bentazone mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 15A, B and pyridate mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 16A, B and pyridate mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 17A, B and pyridate mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 18A, B and pyridate mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 19A, B and cyclopyrimorate mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 20A, B and cyclopyrimorate mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 21A, B and cyclopyrimorate mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 22A, B and cyclopyrimorate mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 23A, B and isoproturon mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 24A, B and isoproturon mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 25A, B and isoproturon mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 26A, B and isoproturon mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 27A, B and amicarbazone mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 28A, B and amicarbazone mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 29A, B and amicarbazone mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 30A, B and amicarbazone mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 31A, B and Sha flutter grand mixture to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 32A, B and Sha flutter grand mixture to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 33A, B and Sha flutter grand mixture to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 34A, B and Sha flutter grand mixture to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 35A, B and symetryne mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 36A, B and symetryne mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 37A, B and symetryne mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 38A, B and symetryne mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 39A, B and prometryn mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 40A, B and prometryn mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 41A, B and prometryn mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
Table 42A, B and prometryn mixture are to the actual preventive effect of weeds and synergy evaluation (Colby)
C, field demonstration
Utilize embodiment 1) -48) made from herbicidal composition prevent and kill off paddy field weed experiment.
Exemplary promote is carried out in 4 testing sites of Changsha morning rice region within 2016 to test.
Test method：After the heart of 3 leaf of rice 1, the weeds 3-4 leaf phases, hand sprayer, 30 kilograms/667m of the amount of being watered2, use
Cauline leaf spraying even spraying, specific test medicine and dosage refer to table 43-52,50 square metres of plot area, and often processing repeats 4
It is secondary.45 days investigation preventive effects are shown in Table 43-52 after dispenser.
The field demonstration effect situation of table 43 (A+ anilofos+dichloro quinolinic acid)
The field demonstration effect situation of table 44 (A+ anilofos+propanil)
The field demonstration effect situation of table 45 (A+ anilofos+bentazone)
The field demonstration effect situation of table 46 (A+ anilofos+pyridate)
The field demonstration effect situation of table 47 (A+ anilofos+symetryne)
The field demonstration effect situation of table 48 (A+ anilofos+isoproturon)
The field demonstration effect situation of table 49 (A+ anilofos+Sha flutters grand)
The field demonstration effect situation of table 50 (A+ anilofos+prometryn)
The field demonstration effect situation of table 51 (A+ anilofos+amicarbazone)
The field demonstration effect situation of table 52 (A+ anilofos+cyclopyrimorate)
By lot of experiments and exploration, it is an unexpected discovery of the invention that the composition for rice terrace after seedling prevent and kill off barnyard grass,
The weeds such as moleplant seed, cyperus iria, Monochoria vaginalis, Eclipta prostrata, there is surprising, unexpected synergistic effect, it is especially right
The grassy weeds such as lady's-grass, barnyard grass, moleplant seed have particularly evident synergistic effect, and this synergistic effect shows under low dosage
It is more notable, dosage can be reduced, reduces the pollution to environment, and rationally compounding reduces agricultural cost, to ALS, ACCase
Inhibitor resistant weed is efficient, has good application prospect.Simultaneously by test wheat paddock, corn field, soybean, cotton,
The lawns such as vegetables, annual bluegrass, Festuca Arundinacea, Korea lawn grass and crop show good selectivity and excellent synergistic effect, Ke Yikai
Send out into the herbicide combination product of extensive market value.
Claims (10)
- A kind of 1. ternary weeding composition of humulone of sulphur containing triazole and anilofos, it is characterised in that the work including herbicidally effective amount Property composition A, B and C, wherein, active components A is triazole sulphur humulone, and B is anilofos, C be selected from dichloro quinolinic acid, propanil, weed eradication One kind that pine, pyridate, cyclopyrimorate, symetryne, isoproturon, Sha are flutterred in grand, prometryn and amicarbazone.
- 2. a kind of Herbicidal combinations according to claim 1, it is characterised in that A, B and C weight ratio are 0.5-50:1- 50:0.5-300, preferably 0.5-30:5-40:1-200.
- 3. a kind of Herbicidal combinations according to claim 2, it is characterised in that A, B and C weight ratio are 1-30:5-30: 5-100, preferably 1-20:10-30:10-50.
- A kind of 4. Herbicidal combinations according to claim 1, it is characterised in thatA, the weight of B and dichloro quinolinic acid ratio is 1-20:5-30:5-30；A, the weight of B and propanil ratio is 0.5-20:5-30:10-200；A, the weight of B and bentazone ratio is 0.5-30:5-30:10-200；A, the weight of B and pyridate ratio is 0.5-20:5-30:5-100；A, B and cyclopyrimorate weight ratio is 1-30:5-35:1-50；A, the weight of B and isoproturon ratio is 0.5-20:10-40:1-30；A, the weight of B and amicarbazone ratio is 1-30:5-30:0.5-30；A, it is 1-30 that B and Sha, which flutter grand weight ratio,:5-30:5-300；A, the weight of B and symetryne ratio is 1-30:5-30:1-40；A, the weight of B and prometryn ratio is 1-30:5-30:1-40.
- A kind of 5. Herbicidal combinations according to Claims 1-4 any one, it is characterised in that the Herbicidal combinations Middle A, B and C weight/mass percentage composition account for the 1-95% of total amount.
- 6. a kind of Herbicidal combinations according to claim 5, it is characterised in that A, B and C matter in the Herbicidal combinations Amount percentage composition accounts for the 10-80% of total amount.
- A kind of 7. Herbicidal combinations according to claim 1 to 6 any one, it is characterised in that the Herbicidal combinations In also include carrier, surfactant.
- A kind of 8. Herbicidal combinations according to claim 1 to 7 any one, it is characterised in that the Herbicidal combinations Specific preparation be dispersible oil-suspending agent, aqueous suspension agent, suspension emulsion, missible oil, water dispersible granules, aqueous emulsion or microemulsion.
- 9. the Herbicidal combination of a kind of humulone of sulphur containing triazole and pyridazine compound according to claim 1 to 8 any one Thing, it is characterised in that the Herbicidal combinations further comprise safener, and it is selected from isoxadifen, cymene sulphur Acid amides, mefenpyrdiethyl, cloquintocetmexyl, gibberellic acid, furilazole and N- (2-2 methoxybenzoyls base) -4- [(methylaminos Carbonyl) amino] one or more in benzsulfamide.
- 10. application of the Herbicidal combinations in crop is prevented and treated on injurious weed as described in claim 1 to 9 any one.
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| CN201710747920.3A CN107517978B (en) | 2017-08-28 | 2017-08-28 | Ternary weeding composition containing triazophos-clomazone and anilofos and application thereof |
| PCT/CN2017/112011 WO2019041582A1 (en) | 2017-08-28 | 2017-11-21 | Ternary weeding composition containing triazole sulcotrione and anilofos and application thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109287632A (en) * | 2018-09-26 | 2019-02-01 | 广西田园生化股份有限公司 | A kind of oil base pesticidal preparations enhancer composition and its application |
| CN109479888A (en) * | 2018-12-19 | 2019-03-19 | 青岛清原化合物有限公司 | Ternary weeding composition and its application comprising cyclopyrimorate |
| WO2019148849A1 (en) * | 2018-02-01 | 2019-08-08 | 青岛清原化合物有限公司 | Ternary herbicidal composition and use thereof |
| CN114586797A (en) * | 2020-12-03 | 2022-06-07 | 青岛清原抗性杂草防治有限公司 | Ternary weeding composition containing bentazone and rimsulfuron and application thereof |
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|---|---|---|---|---|
| US20020004457A1 (en) * | 1998-11-10 | 2002-01-10 | Nevill David John | Herbicidal composition |
| CN106946783A (en) * | 2017-04-19 | 2017-07-14 | 青岛清原化合物有限公司 | Triazole sulphur humulone C crystal form and its production and use |
| CN106977458A (en) * | 2017-04-19 | 2017-07-25 | 青岛清原化合物有限公司 | Amorphous state triazole sulphur humulone and its production and use |
| CN107033086A (en) * | 2017-04-19 | 2017-08-11 | 青岛清原化合物有限公司 | Triazole sulphur humulone B crystal form and its production and use |
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2017
- 2017-08-28 CN CN201710747920.3A patent/CN107517978B/en active Active
- 2017-11-21 WO PCT/CN2017/112011 patent/WO2019041582A1/en active Application Filing
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020004457A1 (en) * | 1998-11-10 | 2002-01-10 | Nevill David John | Herbicidal composition |
| CN106946783A (en) * | 2017-04-19 | 2017-07-14 | 青岛清原化合物有限公司 | Triazole sulphur humulone C crystal form and its production and use |
| CN106977458A (en) * | 2017-04-19 | 2017-07-25 | 青岛清原化合物有限公司 | Amorphous state triazole sulphur humulone and its production and use |
| CN107033086A (en) * | 2017-04-19 | 2017-08-11 | 青岛清原化合物有限公司 | Triazole sulphur humulone B crystal form and its production and use |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019148849A1 (en) * | 2018-02-01 | 2019-08-08 | 青岛清原化合物有限公司 | Ternary herbicidal composition and use thereof |
| CN109287632A (en) * | 2018-09-26 | 2019-02-01 | 广西田园生化股份有限公司 | A kind of oil base pesticidal preparations enhancer composition and its application |
| CN109479888A (en) * | 2018-12-19 | 2019-03-19 | 青岛清原化合物有限公司 | Ternary weeding composition and its application comprising cyclopyrimorate |
| WO2020124531A1 (en) * | 2018-12-19 | 2020-06-25 | 青岛清原化合物有限公司 | Ternary herbicidal composition containing cyclopyrimorate and application thereof |
| CN114586797A (en) * | 2020-12-03 | 2022-06-07 | 青岛清原抗性杂草防治有限公司 | Ternary weeding composition containing bentazone and rimsulfuron and application thereof |
| CN114586797B (en) * | 2020-12-03 | 2023-09-01 | 青岛清原作物科学有限公司 | Ternary weeding composition containing bentazone and rimsulfuron and application thereof |
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| WO2019041582A1 (en) | 2019-03-07 |
| CN107517978B (en) | 2020-06-30 |
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