CN111820225A - Herbicidal composition containing 3-aryl-6-trifluoromethylpyridazinol compound and application thereof - Google Patents
Herbicidal composition containing 3-aryl-6-trifluoromethylpyridazinol compound and application thereof Download PDFInfo
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- CN111820225A CN111820225A CN201911317895.0A CN201911317895A CN111820225A CN 111820225 A CN111820225 A CN 111820225A CN 201911317895 A CN201911317895 A CN 201911317895A CN 111820225 A CN111820225 A CN 111820225A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen
- A01N35/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen containing a carbon-to-nitrogen double bond
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- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
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- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
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- A—HUMAN NECESSITIES
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
- A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
- A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- A—HUMAN NECESSITIES
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- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
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- A—HUMAN NECESSITIES
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- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
Abstract
The invention belongs to the field of pesticides, and particularly relates to a weeding composition containing a 3-aryl-6-trifluoromethyl pyridazinol compound and application thereof. The weeding composition comprises an active ingredient A and an active ingredient B with herbicidally effective amounts, wherein the active ingredient A is selected from one or more than two compounds shown in a general formula I:
x represents an unsubstituted or substituted aryl group; preferably A is
Description
The application is a divisional application of Chinese patent application with the application date of 2019, 22/04, the application number of 201910323603.8 and the name of 'herbicidal composition containing trifluoromethylpyridazinol compounds and application thereof'.
Technical Field
The invention belongs to the field of pesticides, and particularly relates to a weeding composition containing a 3-aryl-6-trifluoromethyl pyridazinol compound and application thereof.
Background
Chemical weeding is the most economic and effective means in preventing and removing weeds in farmlands, but the problems of drug resistance and resistance evolution of weeds and the like are easily caused by using a single variety or a single action mode of chemical herbicide continuously at a high dose for a long time. The reasonable compounding or mixing of the herbicide compound has the advantages of expanding the weed spectrum, improving the control effect, delaying the occurrence and development of drug resistance and drug resistance of weeds and the like, and is one of the most effective methods for solving the problems. For example, patent CN1543455A describes a herbicidal composition containing 3-phenoxy-4-pyridazinol derivatives, and there is still a need for the development of a herbicidal composition having high safety, broad herbicidal spectrum, synergistic effect and solving the problem of resistant weeds.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides a weeding composition containing a 3-aryl-6-trifluoromethyl pyridazinol compound and application thereof. The composition can effectively prevent and kill off the problems of weeds such as chenopodium quinoa, green setaria viridis, Japanese pennywort herb, wild oat, Amaranthus retroflexus, barnyard grass and the like in crop fields, and has the characteristics of expanding a weed control spectrum, reducing the application amount, generating a synergistic effect, solving resistant weeds and the like.
A herbicidal composition comprising 3-aryl-6-trifluoromethylpyridazinol compounds comprising a herbicidally effective amount of an active ingredient A and an active ingredient B, wherein,
the active ingredient A is selected from one or more than two compounds shown in a general formula I:
x represents an unsubstituted or substituted aryl group;
the active ingredient B is selected from one or more of the following compounds and salts/esters thereof:
(1) HPPD inhibitors: sulcotrione (A)CAS number 99105-77-8), mesotrione (CAS number 104206-82-8), topramezone (CAS number 210631-68-8), tembotrione (CAS number 335104-84-2), flurtamone (CAS number 352010-68-5), benzoxaflutole (CAS number 473278-76-1), bicyclosulfatone (CAS number 156963-66-5), diconazole (CAS number 1622908-18-2), ciclopirox (CAS number 1855929-45-1), triazophorione (CAS number 1911613-97-2), topramezone (CAS number 1992017-55-6), fenpyrazazole (CAS number 365400-11-9), pyrazote (CAS number 58011-68-0), pyroxaflutole (CAS number 82692-44-2), tolpyrate (CAS number: 1101132-67-5), fenquinotrione (CAS number: 1342891-70-6), isoxaflutole (CAS number: 141112-29-0), penflufen (CAS number: 71561-11-0),
(2) (ii) a PDS inhibitor: flurtamone (CAS number: 61213-25-0), flurtamone (CAS number: 96525-23-4), diflufenican (CAS number: 83164-33-4), diflufenican (CAS number: 137641-05-5), beflubutamid (CAS number: 113614-08-7), norflurazon (CAS number: 27314-13-2), and fluridone (CAS number: 59756-60-4);
(3) a DOXP inhibitor: clomazone (CAS number: 81777-89-1), bixlozone (CAS number: 81777-95-9);
(4) ALS inhibitors: tribenuron-methyl (CAS number: 101200-48-0), thifensulfuron-methyl (CAS number: 79277-27-3), bensulfuron-methyl (CAS number: 83055-99-6), pyrazosulfuron-ethyl (CAS number: 93697-74-6), thiencarbazone-methyl (CAS number: 317815-83-1), halosulfuron-methyl (CAS number: 100784-20-1), propyrisulfuron (CAS number: 570415-88-2), metazosulfuron-methyl (CAS number: 868680-84-6), rimsulfuron-methyl (CAS number: 122931-48-0), ethoxysulfuron (CAS number: 126801-58-9), pyriminosulfuron-methyl (CAS number: 213464-77-8), flucarbazone-methyl (CAS number: 181274-17-9), mesosulfuron-methyl (CAS number: 208465-21-8), nicosulfuron (CAS number: 111991-09-4), Foramsulfuron (CAS number: 173159-57-4), flumetsulam (CAS number: 98967-40-9), triafamone (CAS number: 874195-61-6), penoxsulam (CAS number: 219714-96-2), cloransulam-methyl (CAS number: 147150-35-4), pyroxsulam (CAS number: 422556-08-9), imazamox (CAS number: 114311-32-9), imazapic (CAS number: 104098-48-8), imazethapyr (CAS number: 81385-77-5), imazapyr (CAS number: 81334-34-1), pyriminobac (CAS number: 147411-69-6), florasulam (CAS number: 145701-23-1), pyribenzoxim (CAS number: 135186-78-6), pyribenzoxim (CAS number: 168088-61-7), Tribenuron-methyl (CAS number: 145026-81-9), imazethapyr (CAS number: 81335-77-5), chlorsulfuron (CAS number: 64902-72-3), cinosulfuron (CAS number: 94593-91-6), cyclosulfamuron (CAS number: 136849-15-5), amidosulfuron (CAS number: 120923-37-7), triasulfuron (CAS number: 82097-50-5), iodosulfuron-methyl sodium salt (CAS number: 144550-36-7), flupyrsulfuron (CAS number: 144740-54-5), flucetosulfuron (CAS number: 412928-75-7), metsulfuron (CAS number: 74223-64-6), triflusulfuron (CAS number: 142469-14-5), sulfosulfuron (CAS number: 141776-32-1), pyrazosulfuron (CAS number: 122548-33-8), Bispyribac-sodium (CAS number: 125401-92-5), and sulfentrazone (CAS number: 139528-85-1);
(5) ACCase inhibitors: clodinafop-propargyl (CAS number: 105512-06-9), pinoxaden (CAS number: 243973-20-8), clethodim (CAS number: 99129-21-2), sethoxydim (CAS number: 74051-80-2), quizalofop-p-ethyl (CAS number: 100646-51-3), tralkoxydim (CAS number: 87820-88-0), fluazifop-p-butyl (CAS number: 69806-50-4), haloxyfop-R (CAS number: 72619-32-0), diclofop-p-methyl (CAS number: 51338-27-3), fenoxaprop-p-ethyl (CAS number: 113158-40-0), cyhalofop-butyl (CAS number: 122008-85-9), clethodim (CAS number: 139001-49-3), metamifop (CAS number: 256412-89-2), oxadiargyl (CAS number: 111479-05-1);
(6) PPO inhibitors: fluroxypyr ether (CAS number: 42874-03-3), fomesafen (CAS number: 72178-02-0), oxadiazon (CAS number: 19666-30-9), oxadiargyl (CAS number: 39807-15-3), sulfentrazone (CAS number: 122836-35-5), pyraclonil (CAS number: 158353-15-2), flumioxazin (CAS number: 103361-09-7), pentoxazone (CAS number: 110956-75-7), tiafenacil (CAS number: 1220411-29-9), saflufenacil (CAS number: 372137-35-4), pyraflufen (CAS number: 129630-19-9), carfentrazone (CAS number: 128621-72-7), butafenacil ester (CAS number: 134605-64-4), fluroxypyr ether ethyl ester (CAS number: 131086-42-5), Fluoroglycofen-ethyl (CAS No. 77501-60-1), fluoroglycofen-ethyl (CAS No. 50594-66-6), triflumimoxazin (CAS No. 1258836-72-4), and azinam-methyl (CAS No. 117337-19-6);
(7) PSII inhibitors: atrazine (CAS number: 1912-24-9), prometryn (CAS number: 7287-19-6), simetryn (CAS number: 1014-70-6), terbuthylazine (CAS number: 5915-41-3), terbutryn (CAS number: 886-50-0), ametryn (CAS number: 834-12-8), ipratropium (CAS number: 4147-51-7), fenflurazine (CAS number: 845-52-3), prometryn (CAS number: 1014-69-3), simazine (CAS number: 122-34-9), metribuzin (CAS number: 87-21064-9), ethiprole (CAS number: 64529-56-2), amicarbazone (CAS number: 129909-90-6), metribuzin (CAS number: 41394-05-2), cyanazine (CAS number: 21725-46-2), Chlortoluron (CAS number: 15545-48-9), isoproturon (CAS number: 34123-59-6), diuron (CAS number: 330-54-1), fluometuron (CAS number: 2164-17-2), linuron (CAS number: 330-55-2), buthiuron (CAS number: 34014-18-1), cypermethron (CAS number: 42609-52-9), chlortoluron (CAS number: 1746-81-2), bromuron (CAS number: 3060-89-7), endothel (CAS number: 555-37-3), pyridazinol (CAS number: 40020-01-7), hexazinone (CAS number: 51235-04-2), isoethazine (CAS number: 22936-75-0), prodrazine (CAS number: 1912-26-1), bromacil (CAS number: 314-40-9), Cyclinadine (CAS number: 2164-08-1), terbacil (CAS number: 5902-51-2), methabenzthiazuron (CAS number: 18691-97-9), cyclosulfamuron (CAS number: 1982-49-6), isoxaben (CAS number: 55861-78-4), metoxuron (CAS number: 19937-59-8), cumuron (CAS number: 1982-47-4), trifluoxazine (CAS number: 1258836-72-4), cyclopyromate (CAS number: 499231-24-2), propanil (CAS number: 709-98-8), pyridate (CAS number: 55512-33-9), betalain (CAS number: 13684-56-5), betanin (CAS number: 13684-63-4), bentazone (CAS number: 25057-89-0), bromoxynil octanoate (CAS number: 1689-99-2), Bromoxynil (CAS number: 1689-84-5), ioxynil (CAS number: 1689-83-4);
(8) microtubule assembly inhibitors: trifluralin (CAS number: 1582-09-8), butralin (CAS number: 33629-47-9), pendimethalin (CAS number: 40487-42-1), dithiopyr (CAS number: 97886-45-8), ethambucil (CAS number: 55283-68-6), oryzalin (CAS number: 19044-88-3), flumetsulam (CAS number: 1861-40-1), thiabendazole (CAS number: 117718-60-2), propaquilate (CAS number: 23950-58-5), dichlorvos (CAS number: 1861-32-1) and phorate (CAS number: 36335-67-8);
(9) microtubule combination inhibitors: diacyl-amine (CAS number: 16118-49-3);
(10) VLCFA inhibitors: acetochlor (CAS number: 34256-82-1), butachlor (CAS number: 23184-66-9), pretilachlor (CAS number: 51218-49-6), metolachlor (CAS number: 87392-12-9), mefenacet (CAS number: 73250-68-7), s-metolachlor (CAS number: 178961-20-1), flufenacet (CAS number: 142459-58-3), alachlor (CAS number: 15299-99-7), pyriflufen (CAS number: 447399-55-5), anilofol (CAS number: 64249-01-0), xylenol oxamine (CAS number: 87674-68-8), fentrazamide (CAS number: 158237-07-1), triafamone (CAS number: 212201-70-2), cafenstrole (CAS number: 125306-83-4), Mepiquat chloride (CAS number: 24151-93-7), propisochlor (CAS number: 86763-47-5), alachlor (CAS number: 15972-60-8), diflufenican (CAS number: 67129-08-2), propachlor (CAS number: 1918-16-7), dimethenamid (CAS number: 106700-29-2);
(11) lipid synthesis (non-acetyl-coa carboxylase) inhibitors: prosulfocarb (CAS number: 52888-80-9), molinate (CAS number: 2212-67-1), prosulfocarb (CAS number: 28249-77-6), benfuresate (CAS number: 68505-69-1), ethofumesate (CAS number: 26225-79-6), triallate (CAS number: 2303-17-5), dichlorfon (CAS number: 1929-77-7), butamolide (CAS number: 2008-41-5), dichlorfon (CAS number: 1134-23-2), pennisetum (CAS number: 61432-55-1) and penflun (CAS number: 85785-20-2);
(12) synthesis of hormones: quinclorac (CAS number: 84087-01-4), fluroxypyr (CAS number: 69377-81-7), fluroxypyr-meptyl (CAS number: 81406-37-3), fluroxypyr (CAS number: 943831-98-9), triclopyr (CAS number: 55335-06-3), clopyralid (CAS number: 1702-17-6), picloram (CAS number: 1918-02-1), aminopyralid (CAS number: 150114-71-9), dicamba (CAS number: 1918-00-9), fluroxypyr (CAS number: 1390661-72-9), 2-methyl-4-chlorophenoxyacetic acid (CAS number: 94-74-6), 2-methyl-4-chloro-phenothiolester (CAS number: 25319-90-8), MCPB (CAS number: 94-81-5), 2-methyl-4-chlorophenoxypropionic acid (CAS number: 93-65-2), sodium 2-methyl-4-chlorophenoxyacetate (CAS number: 3653-48-3), isooctyl 2-methyl-4-chlorophenoxyacetate (CAS number: 29450-45-1), butyl 2, 4-dichlorophenoxyacetate (CAS number: 94-80-4), isooctyl 2, 4-dichlorophenoxyacetate (CAS number: 25168-26-7), 2, 4-dichlorophenoxyacetic acid (CAS number: 94-75-7), chloroquinolinic acid (CAS number: 90717-03-6), 2-methyl-4 chlorodimethylammonium salt (CAS number: 2039-46-5), 2, 4-dichlorpropionic acid (CAS number: 120-36-5), 2, 4-D-butyric acid (CAS number: 94-82-6), benazolin (CAS number: 25059-80-7), aminocyclopyrachlor (CAS number: 858956-08-8);
(13) EPSPS inhibitors: glyphosate (CAS number: 1071-83-6), phosphinothricin (CAS number: 81591-81-3);
(14) a GS inhibitor: glufosinate-ammonium (CAS number: 77182-82-2), bialaphos (CAS number: 35597-43-4), and glufosinate-ammonium (CAS number: 35597-44-5);
(15) PSI inhibitors paraquat (CAS number: 1910-42-5), diquat (CAS number: 6385-62-2);
(16) DHP inhibitors: asulam (CAS number: 3337-71-1);
(17) cellulose synthesis inhibitors: triazinyl flumioxazin (CAS number: 131475-57-5), indexazin (CAS number: 950782-86-2);
(18) other herbicides: oxaziclomefone (CAS number: 153197-14-9), cinmethylin (CAS number: 87818-31-3), indanthrone (CAS number: 133220-30-1), quinclorac (CAS number: 130901-36-8), quintocet (CAS number: 1639426-14-4), prosulfuron (CAS number: 99485-76-4), imazalone (CAS number: 150-68-5), tetflupyrlomet (CAS number: 2053901-33-8).
Preferably, X represents phenyl or pyrazolyl, unsubstituted or substituted by at least one group selected from C1-C6 alkyl, halo C1-C6 alkyl, cyano, halogen, C1-C6 alkoxy, C1-C6 alkylcarbonyl.
More preferably, X represents
Namely the active ingredient A is
In the context of the present specification, if the abbreviated forms of the common name of the active compounds are used, all customary derivatives, such as esters and salts, and also isomers, in particular optical isomers, in particular one or more commercially available forms, are included in each case. If the generic name denotes esters or salts, all other customary derivatives, such as other esters and salts, free acids and neutral compounds, and also isomers, in particular optical isomers, in particular one or more commercially available forms, are also included in each case. The chemical name given for a compound means at least one compound covered by the generic name, with compounds generally being preferred. In the case of sulfonamides, such as sulfonylureas, salts also include those formed by exchange of cations with hydrogen atoms in the sulfonamide group. For example, 2-methyl-4-chloro derivatives include, but are not limited to: 2 methyl 4 chloro sodium salt, potassium salt, dimethyl ammonium salt, isopropyl amine salt, etc., and 2 methyl 4 chloromethyl ester, ethyl ester, isooctyl ester, ethyl thioester, etc.; 2,4-D derivatives include, but are not limited to: 2,4-D salts such as sodium salt, potassium salt, dimethylammonium salt, triethanolamine salt, isopropylamine salt, choline and the like, and 2,4-D esters such as methyl ester, ethyl ester, butyl ester, isooctyl ester and the like.
In the context of the present invention, the salts of the compounds are preferably in the form of the respective alkali metal, alkaline earth metal or ammonium salts, preferably in the form of the respective alkali metal salts, more preferably in the form of the respective sodium or potassium salts, most preferably in the form of the respective sodium salts.
A. The weight ratio of B is 1: 1000-200: 1 and 1: 600-150: 1; preferably 1: 500-100: 1 and 1: 400-80: 1; more preferably 1: 300-60: 1 and 1: 200-50: 1; further preferably 1: 100-30: 1 and 1: 50-20: 1; further preferred are 1:20 to 10:1, 1:10 to 5:1 and 1:5 to 1: 1.
The mass percentage of A, B in the weeding composition accounts for 1-95% of the total amount, and preferably 10-80%.
The weeding composition also comprises conventional auxiliaries which comprise a carrier and a surfactant.
The term "carrier" herein denotes an organic or inorganic, natural or synthetic substance. They facilitate the application of the active ingredient, the carrier being generally inert and must be agriculturally acceptable, in particular for the treated plant. The carrier may be a solid, such as a clay, natural or synthetic silicate, silica, resin, wax, solid fertilizer, or the like; or liquids such as water, alcohols, ketones, petroleum distillates, aromatic or waxy hydrocarbons, chlorinated hydrocarbons, liquefied gases, etc.
Surfactants may include emulsifying, dispersing or wetting agents, which may be ionic or non-ionic. Examples which may be mentioned are salts of polyacrylic acids, lignosulphonates, salts of phenolsulphonic or naphthalenesulphonic acids, polymers of ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines and substituted phenols, in particular alkylphenols or arylphenols, sulphosuccinates, taurine derivatives, in particular taurine alkyl esters, and phosphoric esters of alcohols or polyhydroxyethylated phenols, alkylsulfonates, alkylarylsulphonates, alkylsulfates, lauryl ether sulphates, fatty alcohol sulphates, and sulphated hexadec, heptadeca-and octadecanols and sulphated fatty alcohol glycol ethers, and furthermore condensates of naphthalene or naphthalenesulphonic acids with phenol and formaldehyde, polyoxyethylene octylphenyl ether, ethoxylated isooctylphenol, octylphenol or nonylphenol, alkylphenyl polyglycol ethers, tributylphenyl polyglycol ether, tristearylphenyl polyglycol ether, polystearylphenyl polyglycol ether, Alkylaryl polyether alcohols, alcohol and fatty alcohol/ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers, ethoxylated polyoxypropylene, lauryl alcohol polyglycol ether acetal, sorbitol esters, lignosulfite waste liquors, and also proteins, denatured proteins, polysaccharides (e.g. methylcellulose), hydrophobically modified starches, polyvinyl alcohols, polycarboxylates, polyalkoxylates, polyvinylamines, polyvinylpyrrolidone and copolymers thereof. At least one surfactant is required to be present to facilitate dispersion of the active ingredients in water and to facilitate their proper application to the plant.
The compositions may also contain various other components such as protective colloids, binders, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants, and polymers.
In addition, the composition of the present invention can be mixed with the following active substances, for example, known substances in "the world Wide Specification of New agricultural chemical products", the Chinese agricultural science and technology Press, 2010.9 and the references cited therein. For example, herbicidal active substances mentioned below (remarks: the name of the compound, or the generic name according to the International organization for standardization (ISO), or the chemical name, when appropriate with a code), acetochlor, butachlor, alachlor, propisochlor, metolachlor, s-metolachlor, pretilachlor, propachlor, butachlor, napropamide, R-laevo-napropamide, propanil, mefenacet, diphenoyl-oxamide, diflufenican, flumetsulam, bebutamid, dimethenamid, ethoxybenclamide, flufenacet, methoxyfenacet, metazachlor, isooxachlor, lofluvalinate, dimethenamid, butachlor, propisochlor, mefenamid, flucetochlor, propyzamide, dimethenamid, Terbutamid, dimethenamid, dimethachlor, norfluramine, trifoliamine, chlorantraniliprole, propyzamide, penflufen, napropamide, acetometazachlor, naproxen, fenacet, pyraflufen, metolachlor, clofenamide, butachlor, butamidin, fluazinam, atrazine, simazine, prometryn, cyanazine, simetryn, ametryn, prometryn, ipretryn, fluroxypyr, terbutryn, terbutazine, triazineon, cyhalofop, ganciclovir, prometryn, simazine, triazazine, dimethametrazine, isopentetryn, cycloprozine, terbutryn, sec-butyn, terbutaline, terbutryn, metolachlor, cyhalofop, metolachlor, prometryn, simazine, atrazine, dimethametryn, dimethametin, terbutryn, metolachlor, dimethachlor, dimethozin, atrazine, metolachloraz, metolachlor, metolac, Cyanuric acid, Indaziflam, chlorsulfuron, metsulfuron, bensulfuron-methyl, chlorimuron-ethyl, tribenuron-methyl, thifensulfuron-methyl, pyrazosulfuron-ethyl, mesosulfuron-methyl, iodosulfuron-methyl sodium, formamidosulfuron, cinosulfuron, triasulfuron, sulfometuron-methyl, nicosulfuron, ethametsulfuron-methyl, amidosulfuron, ethoxysulfuron, cyclosulfamuron-methyl, rimsulfuron, azimsulfuron-methyl, monosulfuron-methyl, primisulfuron-methyl, flusulfuron-methyl, flazasulfuron-methyl, propsulfuron-methyl, prosulfuron-methyl, trifloxysulfuron, triflusulfuron-methyl, metsulfuron-methyl, primisulfuron-methyl, propulsulfuron-methyl, propaferon-methyl, triflusulfuron-methyl, sulfometuron-methyl, pyrisulfuron-methyl, propalis-ethyl, thiuron-methyl, sulfometuron-methyl, sulfometuron-ethyl, sulfometuron-ethyl, sulfofluridone, sulfometuron-ethyl, sulfofluridone, sulfometuron, sulfo, Dicumyl ether, aclonifen, ethoxyfen-ethyl, bifenox, trifluoromethoxyfen, metoxyfen, trifluornitrofen, fluoroglycofen, fluridone, bifenox, dimethofen, fluazifop-butyl, Halosafen, chlortoluron, isoproturon, linuron, diuron, fenpropuron, fluometuron, methabenzthiazuron, benzuron, sulfosulfuron, clofenuron, tebuthiuron, clodinuron, meturon, metoxuron, bromuron, metoxuron, meturon, metoxuron, metoron, Betalain, asulam, tefurazol, avenacalin, anilazine, chlorpropham, dichlofenamate, imazalil, cloropham, Carboxazole, chlorerprocarb, Fenasulam, BCPC, CPPC, Carbasulam, buticarb, thiobencarb, dimethenate, triallate, dichloropetalum, ethiofen, prosulfocarb, cloquintocet, prosulfocarb, dichloropetalum, dichloropetalate, dichloropetal, 2-methyl-4-chloropropionate, 2-methyl-4-chlorobutyric acid, 2,4, 5-nasal discharge propionic acid, 2,4, 5-nasal discharge butyric acid, 2-methyl-4-chloroamine salt, dicamba, woollen boom, varparvax, cypress, triclosan, dichlorfenamic acid, metoclopramide, diclofop-p-ethyl, haloxyfop-methyl, haloxyfop-ethyl, quizalofop-p-ethyl, fenoxaprop-p-ethyl, cyhalofop-butyl, fenoxaprop-p-ethyl, cloroph-ethyl, haloxyfop-ethyl, trifoliate-ethyl, clomazone, paraquat, dixyl, asulam, flutolon, isoproturon, chlorothalofop-ethyl, cyhalofop-p-ethyl, propafen-ethyl, butyfen-ethyl, fluroxypyr, metalaxyl, propafen, propaferin, propafen, glyphosate, anilofos, glufosinate, sulfosate, piperaphos, bialaphos, bensulide, imazapyr, mepyrazine, varroa, amifostine, glufosinate, imazethapyr ammonium salt, imazethapyr, imazamethabenz ester, fluroxypyr, isooctyl fluroxypyr, clopyralid, picloram, triclopyr, dithiopyr, haloxyfen, triclopyr, thiazopyr, flurazinone, aminopyralid, flurazone, diflufenzopyr, butoxyethyl triclopyr, ciodinate, sethoxydim, clethodim, thiacet, sethoxydim, clethodim, carfenflurazone, buthiazole, metribuzin, carfenflurazone, metamitron, fenflurazone, fenpyr, benzone, iodoxynil, bromoxynil, isoflurazone, isofluroxypyr, bensulam, isofluroxypyr, clomazone, ioxynil, dichlobenil, tolfenacet, pyraclonil, Iodobonil, flumetsulam, florasulam, penoxsulam, sulfentrazone, cloransulam, diclosulam, pyroxsulam, fluralin, bispyribac, pyribenzoxim, pyriminobac-methyl, pyrithiobac-methyl, bicyclosulfuron, mesotrione, Tembotrione, Tefuryltrione, Bicyclopyrone, ketoxydipradox, isoxaflutole, fenoxasulfolane, Methiozolin, isopyrafen, pyraflufen, pyraflutole, pyrazotocide, pyraclonil, pyraclofenacetone, flumetsulcotrione, flumetsulam, fenflurazole, fentrazachlor, amicarbazone, fentrazachlor, pyrazachlor, pyraclonil, flumicloram, flumioxazone, fenflurazole, flumicloram, bexapyroxadim, flumicloram, bexadim, flumicloram, benfluroram, flumicl, Phthalidyl ether, Flumezin, pentachlorophenol (sodium), dinol, terbenol, terbutal, pendimethalin, dinitrophenol, chloronitrophenol, dimethomorph, oxadiargyl, oxadiazon, pentoxazone, flumetsulam, mefenoxaprop-p-ethyl, tetrazolyl amine, fluridazin, oxamyl, bromamine, dimethenamid, pyridaben, pyridate, pyrirfalol, quinclorac, bentazone, pyridate, oxaziclorac, benazolin, clomazone, clomeptyl, isoprox, iprodione, propamocarb, cumylfen, indoxacarb, sodium chlorate, dalton, dalapon, trichloroacetic acid, monochloroacetone, hexachloroacetone, tetrafluoropropionic acid, pasture, bromophenol oxime, triazoxide, fentrazol, furamethon, fursulam, ethon, benfurazolin, pyrimethanil, clorac, clodinafop, clorac, cumquat, cumarone, clorac, Thidiazuron, alantin, hydroxybenone, metophenone, saflufenacil, dichlorophosphoric, trichloropropionic acid, Alorac, Diethamquat, Etnipromid, Iphridam, Ipfancarbazone, Thiencarbazone-methyl, Pyrimisulfan, Chlorflurflurazone, Tripropindan, Sulglycapin, Sumbelanoline, Campandichlor, Cytopyrimidic acid, thiocyananilide, clethodim, fenclorim, cloquintocet, mequintocet, oxaziclomex, oxabetrinil, pyroxaglim, furazolidone, imazaquin, isoxadifen, dichlormid, halauxin, halauxifen, DOWF, UBH-509, D489, LS 82-556, KPP-300, NC-324, NC-330, KH-218, DPX-N8189, SC-0744, DOWCO535, DK-8910, V-53482, PP-600, MBH-001, KIH-9201, ET-751, KIH-6127 and KIH-2023.
The herbicidal composition further comprises at least one safener selected from the group consisting of:
a) dichlorophenyl pyrazoline-3-carboxylic acid (S1) compounds, preferred compounds are, for example, ethyl 1- (2, 4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl-2-pyrazoline-3-carboxylate (S1-1 mefenpyr-diethyl, PM, p. 594-595), and related compounds described, for example, in WO91/07874 and PM (p. 594-595).
b) Dichlorophenyl pyrazole carboxylic acid derivatives, preferred compounds are, for example, ethyl 1- (2, 4-dichlorophenyl) -5-methylpyrazole-3-carboxylate (S1-2), ethyl 1- (2, 4-dichlorophenyl) -5-isopropylpyrazole-3-carboxylate (S1-3), ethyl 1- (2, 4-dichlorophenyl) -5- (1, 1-dimethyl-ethyl) pyrazole-3-carboxylate (S1-4), ethyl 1- (2, 4-dichlorophenyl) -5-phenylpyrazole-3-carboxylate (S1-5), and related compounds as described in EP-A-333131 and EP-A-269806.
c) Triazole carboxylic acids (S1) and preferred compounds are, for example, fenchlorazole (fenchlorazole), i.e. ethyl 1- (2, 4-dichlorophenyl) -5-trichloromethyl- (1H) -1,2, 4-triazole-3-carboxylate (S1-6) and related compounds (see EP-A-174562 and EP-A-346620).
d) 5-benzyl-or 5-phenyl-2-isoxazoline-3-carboxylic acids or 5, 5-diphenyl-2-isoxazoline-3-carboxylic acids, preferred compounds being, for example, ethyl 5- (2, 4-dichlorobenzyl) -2-isoxazoline-3-carboxylate (S1-7) or ethyl 5-phenyl-2-isoxazoline-3-carboxylate (S1-8) and related compounds described in WO91/08202, or ethyl 5, 5-diphenyl-2-isoxazoline-3-carboxylate (S1-9, isoxadifen-ethyl)) or 5 described in the patent application (WO-A-95/07897), n-propyl 5-diphenyl-2-isoxazoline-3-carboxylate (S1-10) or ethyl 5- (4-fluorophenyl) -5-phenyl-2-isoxazoline-3-carboxylate (S1-11).
e) 8-Quinolinyloxyacetic acids (S2) of the class of compounds, preferably 1-methylhexan-1-yl (5-chloro-8-quinolinyloxy) acetate (S2-1, cloquintocet-mexyl), such as PM (p. 195-), (1, 3-dimethylbut-1-yl) (5-chloro-8-quinolinyloxy) acetate (S2-2), 4-allyloxybutyl (5-chloro-8-quinolinyloxy) acetate (S2-3), 1-allyloxypropan-2-yl (5-chloro-8-quinolinyloxy) acetate (S2-4), (ethyl 5-chloro-8-quinolinyloxy) acetate (S2-5), (methyl 5-chloro-8-quinolinyloxy) acetate (S2-6), allyl (5-chloro-8-quinolinyloxy) acetate (S2-7), 2- (2-propyleneiminoyloxy) -1-ethyl (5-chloro-8-quinolinyloxy) acetate (S2-8), 2-oxopropan-1-yl (5-chloro-8-quinolinyloxy) acetate (S2-9), and related compounds described in EP-A-86750, EP-A-94349 and EP-A-191736 or EP-A-0492366.
f) (5-chloro-8-quinolinoxy) propanedioic acid-based compounds, preferred compounds are, for example, diethyl (5-chloro-8-quinolinoxy) malonate, (diallyl (5-chloro-8-quinolinoxy) malonate, (methylethyl (5-chloro-8-quinolinoxy) -malonate and related compounds described in EP-A-0582198.
g) Phenoxyacetic acid, phenoxypropionic acid or aromatic carboxylic acids, such as 2, 4-dichlorophenoxyacetic acid (and esters) (2,4-D), 4-chloro-2-methylphenoxypropionate (2-methyl-4-chloropropionic acid (mecoprop)), MCPA or 3, 6-dichloro-2-methoxybenzoic acid (and esters) (dicamba).
h) Pyrimidines, such as fenclorim (PM, page 386-387) (═ 4, 6-dichloro-2-phenylpyrimidine),
i) dichloroacetamide-based active compounds, which are frequently used as pre-emergence safeners (soil-working safeners), for example "dichloroallylamine (dichlormid)" (PM, page 270-271) (═ N, N-diallyl-2, 2-dichloroacetamide), "AR-29148" (-3-dichloroacetyl-2, 2, 5-trimethyl-1, 3-oxazolidinone from Stauffer), "benoxacor" (PM, page 74-75) (-4-dichloroacetyl-3, 4-dihydro-3-methyl-2H-1, 4-benzoxazine), "APPG-1292" (-N-allyl-N [ (1, 3-dioxolan-2-yl) -methyl ] dichloroacetamide, from PPGIndustries), "ADK-24" (═ N-allyl-N- [ (allylaminocarbonyl) -methyl ] -dichloroacetamide, from Sagro-Chem), "AAD-67" or "AMON 4660" (═ 3-dichloroacetyl-1-oxa-3-aza-spiro [4,5] decane, from Nitrokemia or Monsanto), "diclonon" or "ABAS 145138" or "ala 145138" ((═ 3-dichloroacetyl-2, 5, 5-trimethyl-1, 3-diazabicyclo [4.3.0] nonane, from BASF), and "furilazol" or "AMON 13900" (see PM, 482 483) ((RS) -3-dichloroacetyl-5- (2-furyl) -2, 2-dimethyloxazolidone),
j) dichloroacetone derivative-based active compounds, for example, "AMG 191" (CAS registry No. 96420-72-3) (═ 2-dichloromethyl-2-methyl-1, 3-dioxolane, available from Nitrokemia),
k) oxyimino compounds as active compounds, which are referred to as seed dressing materials, for example "oxabetrinil" (PM, page 689) (═ Z) -1, 3-dioxolan-2-ylmethoxyimino (phenyl) acetonitrile), which in seed dressing is referred to as safener in order to prevent damage to metolachlor (metallachlor), "fluoroxyfen" (PM, page 467 468) (═ 1- (4-chlorophenyl) -2,2, 2-trifluoro-1-ethanone O- (1, 3-dioxolan-2-ylmethyl) -oxime, which in seed dressing is referred to as safener in order to prevent damage to metolachlor (metallachlor), and "cyanohydrin" or "a-CGA-43089" (PM, page 983) ((Z) -cyanomethoxyimino (phenyl) acetonitrile), which is called safener in seed dressing, to prevent the damage of metolachlor (metolachlor),
l) Thiazolecarboxylic acid ester active compounds, which are known as seed dressing materials, for example "flurazon" (PM, p. 450. 451), (-2-chloro-4-trifluoromethyl-1, 3-thiazole-5-carboxylic acid benzyl ester), which are known as safeners in seed dressing to prevent damage to alachlor (alachlor) and metolachlor,
m) active compounds of the naphthalenedicarboxylic acid derivative class, which are known as seed dressings, for example "naphthalic anhydride" (PM, pp 1009-1010) (═ 1, 8-naphthalic anhydride), which are known as safeners in corn seed dressings to prevent damage to thiocarbamate herbicides,
n) chromanoic acid derivatives such as "ACL 304415" (CAS registry No. 31541-57-8) (═ 2-84-carboxychroman-4-yl) acetic acid available from american cyanamid),
o) active compounds which, in addition to herbicidal action on harmful plants, also have safener action on plants, for example "penetryn (dimerate)" or "AMY-93" (PM, p.302-303) (═ S-1-methyl-1-phenylethylpiperidine-1-thiocarboxylate), "diuron (daimuron)" or "ASK 23" (PM, p.247) (═ 1- (1-methyl-1-phenylethyl) -3-p-tolylureｃA), "cumyluron (cumyluron)", "jc-940" ((3- (2-chlorophenylmethyl) -1- (1-methyl-1-phenyl-ethyl) ureｃA, see JP- ｃA-60087254), "benzophenone (methoxyphenon)" or "ANK 049" (═ 3,3' -dimethyl-4-methoxy-benzophenone), "CSB" (═ 1-bromo-4- (chloromethylsulfonyl) benzene) (CAS registry No. 54091-06-4, available from Kumiai).
The safener is preferably one or more of isoxadifen (CAS: 163520-33-0), cyprosulfamide (CAS: 221667-31-8), mefenpyr (CAS: 135590-91-9), cloquintocet (CAS: 99607-70-2), gibberellic acid (CAS: 7-06-5), furilazole (CAS: 121776-33-8) and metacamifen (CAS: 129531-12-0).
The compositions of the present invention may be diluted or used directly by the user prior to use. The formulation can be prepared by conventional processing methods, i.e., mixing the active substance with a liquid solvent or solid carrier, and adding one or more surfactants such as dispersants, stabilizers, wetting agents, binders, defoamers, etc.
The specific preparation of the weeding composition is dispersible oil suspending agent, water suspending agent, suspending emulsion, wettable powder, missible oil, water dispersible granule (dry suspending agent), emulsion in water and microemulsion.
In short, the compositions of the present invention may be mixed with solid and liquid additives conventionally used in prior art formulations.
The invention also provides an application of the weeding composition in weed control; and to provide a method of controlling unwanted plant growth comprising applying the herbicidal composition to a plant, part of a plant, plant seed, or area where a plant is growing.
In addition, the compositions according to the invention can be applied by spraying to the foliage of the plants to be treated, i.e. to the weeds, in particular to surfaces infested or susceptible to infestation by weeds.
When the herbicidal composition of the present invention is applied, an unexpected synergistic effect is obtained, and the herbicidal activity is more remarkable than the expected sum of the activities using individual herbicides, and the activities of the individual herbicides. The synergistic effect is manifested by reduced application rates, a broader spectrum of weed control, and a faster and longer lasting herbicidal action, which are desirable in the practice of weed control. These new compositions are clearly superior to existing herbicides in terms of the properties described, achieving reduced use and being more environmentally friendly.
The synergistic herbicidal composition of the invention also has the following advantages:
(1) the composition of the invention is environment-friendly and is easy to degrade in the environment.
(2) The weeding composition has low cost and convenient use, and has great economic and social benefits when being popularized and applied.
Detailed Description
The following examples are not intended to limit the invention, but merely to illustrate how the invention may be carried out. These examples show particularly significant effectiveness against certain weeds. Examples are as follows:
A) examples of the embodiments
Dispersible oil-suspendable agent A1+ sulcotrione (8+ 30: representing 8% A1+ 30% sulcotrione, the same applies hereinafter)
A1+ sulcotrione + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + 5% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A1+ mesotrione (8+9)
A1+ mesotrione + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A1+ topramezone (8+2)
A1+ topramezone + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A1+ tembotrione (8+6)
A1+ tembotrione + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
A1+ fluroxypyr (8+3) dispersible oil suspension
A1+ fluroxypyr, 5% calcium dodecyl benzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 7% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
A1+ Furan sulcotrione (8+3) dispersible oil suspending agent
A1, Fusulcotrione, 6 percent calcium dodecyl benzene sulfonate, 7 percent fatty alcohol-polyoxyethylene ether, 5 percent castor oil-polyoxyethylene ether, 1.5 percent organic bentonite, 1.5 percent fumed silica, 5 percent 100# solvent oil and methyl oleate
7, A1+ benzobicyclon (8+10) dispersible oil suspending agent
A1+ benzobicyclon, 5% calcium dodecyl benzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 1% organobentonite, 0.5% fumed silica, 5% 100# solvent oil and methyl oleate
8, A1+ topramezone (8+2) dispersible oil suspending agent
A1+ Metronidazole, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A1+ bicyclopyrone (8+9)
A1+ cyflufenac + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.2% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A1+ triazasulamone (8+12)
A1+ triazophone + 5% calcium dodecylbenzenesulfonate + 7% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
11, A1+ benzoxaflutole (8+6) dispersible oil suspending agent
A1+ benzoxaflutole + 5% calcium dodecylbenzenesulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A1+ sulfonylopyrazole (8+2)
A1+ Sulfonyl pyrazole + 5% calcium dodecyl benzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organic bentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A1+ pyrazolate (4+32)
A1+ pyrazolate + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.5% organobentonite + 5% 100# solvent oil + methyl oleate
14, A1+ pyroxadim (4+30) dispersible oil suspending agent
A1+ Bifencotrione + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.5% organic bentonite + 5% 100# solvent oil + methyl oleate
A1+ tolpyralate (8+10) dispersible oil suspension
A1+ tolpyrate + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-oxyethylene ether + 1% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
A1+ fenquinotrione (8+10) dispersible oil suspension concentrate
A1+ fenquinotrione + 5% calcium dodecylbenzenesulfonate + 7% fatty alcohol-polyoxyethylene ether + 5% castor oil-oxyethylene ether + 1% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
A1+ isoxaflutole (8+6) dispersible oil suspending agent
A1+ isoxaflutole + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
A1+ benconazole (4+50) water dispersible granule
A1+ benzole + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement
19.
Dispersible oil suspension
Dispersible oil suspension concentrate of A1+ fluorochloridone (8+25)
A1, fluorochloridone, 5 percent calcium dodecyl benzene sulfonate, 6 percent fatty alcohol-polyoxyethylene ether, 6 percent castor oil-polyoxyethylene ether, 0.5 percent organic bentonite, 0.5 percent fumed silica, 5 percent 100# solvent oil and methyl oleate
21, A1+ flurtamone (8+10) dispersible oil suspending agent
A1+ Fufuulone + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
22, A1+ diflufenican (8+10) dispersible oil suspending agent
A1+ diflufenican + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
23, A1+ fluopicolide (8+10) dispersible oil suspending agent
A1+ Fluopyramid + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 5% 100# solvent oil + methyl oleate
A1+ beflubutamid (8+10) dispersible oil suspension
A1+ beflubutamid, 5% calcium dodecyl benzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1% fumed silica, 5% 100# solvent oil and methyl oleate
25, A1+ norflurazon (4+36) water dispersible granule
A1+ norflurazon + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement
26, A1+ fluazinone (4+70) wettable powder
A1+ fluazifop-butyl, 10% sodium lignosulfonate dispersant, 3% sodium dodecyl sulfate, 10% precipitated silica and kaolin
Dispersible oil suspension concentrate of A1+ clomazone (8+30)
A1+ clomazone + 6% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 0.5% organobentonite + 5% 100# solvent oil + methyl oleate
A1+ bixlone (8+20) dispersible oil suspension
A1+ bixlone + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-oxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + 5% 100# solvent oil + methyl oleate
29, A1+ tribenuron-methyl (8+2) dispersible oil suspending agent
A1+ tribenuron-methyl + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol polyoxyethylene ether + 5% castor oil polyoxyethylene ether + 2% organic bentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A1+ thifensulfuron methyl (8+2)
A1+ thifensulfuron methyl + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
31, A1+ bensulfuron methyl (8+2) dispersible oil suspending agent
A1+ bensulfuron methyl ++ 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
32, A1+ pyrazosulfuron-ethyl (8+2) dispersible oil suspending agent
A1+ pyrazosulfuron-ethyl, 5% calcium dodecylbenzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
Dispersible oil suspension agent of A1+ thiencarbazone-methyl (8+2)
A1+ Thiolosulfuron, 5% calcium dodecylbenzene sulfonate, 8% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
34, A1+ halosulfuron-methyl (8+2) dispersible oil suspending agent
A1+ halosulfuron-methyl, 5% calcium dodecylbenzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
35, A1+ propyrisulfuron (8+4) dispersible oil suspending agent
A1+ propyrisulfuron, 5% calcium dodecylbenzenesulfonate, 6% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
36, A1+ metazosulfuron (8+4) dispersible oil suspending agent
A1+ metazosulfuron-ethyl, 5% calcium dodecylbenzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
37, A1+ rimsulfuron (8+2) dispersible oil suspending agent
A1+ rimsulfuron, 5% calcium dodecylbenzenesulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
38, A1+ ethoxysulfuron (8+2) dispersible oil suspension
A1+ ethoxysulfuron + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
A1+ orthosulfamuron (8+5) dispersible oil suspending agent
A1+ sulfosulfuron, 5% calcium dodecylbenzenesulfonate, 6% fatty alcohol-polyoxyethylene ether, 6% castor oil-oxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
A1+ flucarbazone-sodium (8+2) dispersible oil suspending agent
A1+ Flucarbazone-sodium + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A1+ mesosulfuron (8+1)
A1+ methylsulfonyl amine + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
42, A1+ nicosulfuron (8+4) dispersible oil suspending agent
A1+ nicosulfuron + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
43, A1+ foramsulfuron (8+4) dispersible oil suspending agent
A1+ foramsulfuron + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
A1+ flumetsulam (8+3) dispersible oil suspending agent
A1+ flumetsulam + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
45.A1+ fluocinolone acetonide (8+2) dispersible oil suspending agent
A1+ Fluoroketosulfometuron-amine + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-oxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
46, A1+ penoxsulam (8+2) dispersible oil suspending agent
A1+ penoxsulam + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
47, A1+ cloransulam (8+2) dispersible oil suspending agent
A1+ cloransulam-methyl, 5% calcium dodecylbenzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
48, A1+ pyroxsulam (8+1) dispersible oil suspending agent
A1+ pyroxsulam + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
49, A1+ imazamox (8+2) dispersible oil suspending agent
A1+ metopimox, 5% calcium dodecylbenzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
Dispersible oil suspension agent containing A1 and mebendazole nicotinic acid (8+3)
A1+ mebendazole nicotinic acid + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
51, A1+ imazethapyr (8+5) dispersible oil suspending agent
A1+ imidazole acetic acid, 6% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 1.5% organic bentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
A1+ imazapyr (8+50) water dispersible granules
A1+ Imazapyr + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + Kaolin to complement
53.A1+ pyriminobac-methyl (8+3) dispersible oil suspending agent
A1+ pyriminobac-methyl, 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
54, A1+ florasulam (8+1) dispersible oil suspending agent
A1+ florasulam + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organic bentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
Aqueous suspension of A1+ pyriftalid (8+20)
A1+ pyriftalid + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.05% xanthan gum + 0.5% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
56.A1+ pyribenzoxim (8+5) dispersible oil suspending agent
A1+ pyribenzoxim + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
57, A1+ propoxycarbazone (8+2) dispersible oil suspending agent
A1+ Tribensulfuron-methyl, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
58.A1+ imazethapyr (8+5) dispersible oil suspending agent
A1+ imazethapyr + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
59, A1+ chlorsulfuron (8+2) dispersible oil suspending agent
A1+ chlorsulfuron + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
60, A1+ cinosulfuron (8+2) dispersible oil suspending agent
A1+ cinosulfuron + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
61.A1+ cyclosulfamuron (8+2) dispersible oil suspending agent
A1+ cyclosulfamuron + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-oxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
62, A1+ amidosulfuron (8+2) dispersible oil suspending agent
A1+ amidosulfuron, 5% calcium dodecylbenzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
63.A1+ Ether tribenuron-methyl (8+2) dispersible oil suspending agent
A1+ Ether tribenuron-methyl + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol polyoxyethylene ether + 5% castor oil polyoxyethylene ether + 2% organic bentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
64, A1+ iodosulfuron-methyl sodium salt (8+1) dispersible oil suspending agent
A1+ iodosulfuron-methyl sodium salt + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
65.A1+ fluazisulfuron (8+2) dispersible oil suspending agent
A1+ flazasulfuron + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
66.A1+ Fluopyrsulfuron (8+2) dispersible oil suspending agent
A1+ Fluorosulfuron + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
67, A1+ metsulfuron-methyl (8+1) dispersible oil suspending agent
A1+ metsulfuron-methyl + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
68.A1+ triflusulfuron-methyl (8+1) dispersible oil suspending agent
A1+ Trifluoromethsulfuron + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
69, A1+ sulfonylsulfuron (8+2) dispersible oil suspension
A1+ sulfosulfuron, 5% calcium dodecylbenzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
70, A1+ pyrazosulfuron-ethyl (8+1) dispersible oil suspending agent
A1+ pyrazosulfuron-ethyl, 5% calcium dodecylbenzenesulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
71.A1+ bispyribac-sodium (8+2) dispersible oil suspending agent
A1+ Bispyribac-sodium, 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
72, A1+ metosulam (8+1) dispersible oil suspending agent
A1+ metosulam + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
73.A1+ clodinafop-propargyl (8+4) dispersible oil suspending agent
A1+ clodinafop-propargyl, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 5% 100# solvent oil and methyl oleate
74, A1+ pinoxaden (8+4) dispersible oil suspending agent
A1+ pinoxaden + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
A1+ clethodim (8+6) dispersible oil suspending agent
A1+ clethodim + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 20% 100# solvent oil + methyl oleate
76.A1+ sethoxydim (8+12) dispersible oil suspending agent
A1+ sethoxydim, 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 6% 100# solvent oil + methyl oleate
77.A1+ quizalofop-p-ethyl (8+4) dispersible oil suspending agent
A1+ quizalofop-p-ethyl + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 6% 100# solvent oil + methyl oleate
78.A1+ clomazone (8+16) dispersible oil suspending agent
A1+ benzoximone + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 6% 100# solvent oil + methyl oleate
79.A1+ fluazifop-p-butyl (8+2) dispersible oil suspending agent
A1+ fluazifop-p-butyl, 5% calcium dodecylbenzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-polyoxyethylene ether, 2% organobentonite, 1.5% fumed silica, 6% 100# solvent oil and methyl oleate
80.A1+ haloxyfop (8+2) dispersible oil suspending agent
A1+ haloxyfop-R-methyl, 5% calcium dodecylbenzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 5% castor oil-oxyethylene ether, 2% organobentonite, 1.5% fumed silica, 6% 100# solvent oil and methyl oleate
81, A1+ diclofop-p-ethyl (4+30) dispersible oil suspending agent
A1+ diclofop-p-ethyl + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.5% organic bentonite + 6% 100# solvent oil + methyl oleate
82.A1+ fenoxaprop-p-ethyl (8+10) dispersible oil suspending agent
A1, fenoxaprop-p-ethyl, 6 percent of calcium dodecyl benzene sulfonate, 5 percent of fatty alcohol-polyoxyethylene ether, 6 percent of castor oil-polyoxyethylene ether, 1.5 percent of organic bentonite, 1.5 percent of fumed silica and methyl oleate
83, A1+ cyhalofop-butyl (8+10) dispersible oil suspending agent
A1+ cyhalofop-butyl, 5% calcium dodecylbenzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 7% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica and methyl oleate
84, A1+ clethodim (8+4) dispersible oil suspending agent
A1+ clethodim + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + methyl oleate
85.A1+ metamifop (8+10) dispersible oil suspending agent
A1+ metamifop + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + methyl oleate
86.A1+ oxaoxalic acid (8+5) dispersible oil suspending agent
A1+ oxa oxalic acid + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organic bentonite + 1.5% fumed silica + 10% 100# solvent oil + methyl oleate
87, A1+ oxyfluorfen (8+12) dispersible oil suspending agent
A1+ oxyfluorfen + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2.5% organobentonite + 2.5% fumed silica + 20% 100# solvent oil + methyl oleate
88.A1+ fomesafen (8+25) dispersible oil suspending agent
A1+ fomesafen + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + 20% 100# solvent oil + methyl oleate
89.A1+ oxadiazon (8+40) dispersible oil suspending agent
A1, oxadiazon, 5 percent calcium dodecyl benzene sulfonate, 5 percent fatty alcohol-polyoxyethylene ether, 6 percent castor oil-polyoxyethylene ether, 0.5 percent organic bentonite, 5 percent 100# solvent oil and methyl oleate
90.A1+ oxadiargyl (8+6) dispersible oil suspending agent
A1, oxadiargyl, 5 percent calcium dodecyl benzene sulfonate, 6 percent fatty alcohol-polyoxyethylene ether, 6 percent castor oil-polyoxyethylene ether, 1.5 percent organic bentonite, 1.5 percent fumed silica, 15 percent 100# solvent oil and methyl oleate
91, A1+ sulfentrazone (8+36) wettable powder
A1+ sulfentrazone + 12% calcium lignosulfonate dispersant + 3% sodium dodecyl sulfate + 10% precipitated silica and kaolin
92.A1+ pyraclonil (8+14) dispersible oil suspending agent
A1+ pyraclonil, 5% calcium dodecyl benzene sulfonate, 6% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1% organobentonite, 5% 100# solvent oil and methyl oleate
93.A1+ flumioxazin (8+6) dispersible oil suspending agent
A1+ flumioxazin + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.6% organobentonite + 15% 100# solvent oil + methyl oleate
94.A1+ pentoxazone (8+26) dispersible oil suspending agent
A1+ pentoxazone + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + 5% 100# solvent oil + methyl oleate
95.A1+ tiafenacil (8+2) dispersible oil suspending agent
A1+ tiafenacil + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + 5% 100# solvent oil + methyl oleate
96.A1+ saflufenacil (8+5) dispersible oil suspending agent
A1+ saflufenacil + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + methyl oleate
97, A1+ pyraflufen-ethyl (8+1) dispersible oil suspending agent
A1+ pyraflufen-ethyl, 5% calcium dodecylbenzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 2.0% organobentonite, 1.5% fumed silica and methyl oleate
98.A1+ carfentrazone-ethyl (8+2) dispersible oil suspending agent
A1+ carfentrazone-ethyl + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2.0% organic bentonite + 1.5% fumed silica + methyl oleate
99.A1+ flupropyrim (8+1) dispersible oil suspending agent
A1+ Fluropyrim-fluroxypyr ester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + methyl oleate
Dispersible oil suspension agent of A1+ Meclofenacet Ethyl ester (8+2)
A1+ Meclofenacet-ethyl ester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
101, A1+ fluoroglycofen-ethyl (8+1) dispersible oil suspending agent
A1+ fluoroglycofen-ethyl + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + 20% 100# solvent oil + methyl oleate
102, A1+ acifluorfen (8+30) water dispersible granules
A1+ acifluorfen + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement
A1+ triflumimoxazin (8+5) dispersible oil suspension concentrate
A1+ triflumimoxazin + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 10% 100# solvent oil + methyl oleate
Dispersible oil suspension agent containing A1+ oxazine methyl oxalate (8+1)
A1+ oxazine methyl oxalate + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 10% 100# solvent oil + methyl oleate
105, A1+ atrazine (4+30) aqueous suspension
A1+ atrazine + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
106, A1+ prometryn (8+30) aqueous suspension
A1+ prometryn + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
107, A1+ simetryn (8+30) aqueous suspension
A1+ simetryn + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
108, A1+ terbuthylazine (8+30) aqueous suspension
A1+ terbuthylazine + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A1+ terbutryn (8+30)
A1+ terbutryn + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
110, A1+ ametryn (8+40) aqueous suspension
A1+ ametryn, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% xanthan gum, 0.8% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
111, A1+ iprovalbumin (8+30) aqueous suspension
A1+ iprovalbumin + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
112, A1+ Fengcao (8+40) water suspension
A1+ fenfluramine + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
113, A1+ diquat (8+40) aqueous suspension
A1+ dimethomon + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
114, A1+ simazine (8+40) aqueous suspension
A1+ simazine + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
115.A1+ metribuzin (8+10) aqueous suspension
A1+ metribuzin + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
A1+ ethiprole (8+20) aqueous suspension
A1+ ethifluzone + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.2% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A1+ amicarbazone (8+10)
A1+ amicarbazone + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.2% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
A1+ metamitron (4+50) water dispersible granules
A1+ metamitron + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement
119, A1+ cyanazine (8+30) aqueous suspension
A1+ cyanazine + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
120, A1+ chlortoluron (8+50) water dispersible granule
A1+ chlortoluron + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement
Aqueous suspension of A1+ isoproturon (8+30)
A1+ isoproturon + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
122, A1+ diuron (8+30) aqueous suspension
A1+ diuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
123, A1+ fluometuron (8+40) aqueous suspension
A1+ fluometuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A1+ linuron (8+40)
A1+ linuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A1+ buthiuron (8+40)
A1+ buthiuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
126, A1+ Saposlon (8+30) aqueous suspension
A1+ Saplon + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
127, A1+ chlorsulfuron (8+50) wettable powder
A1+ Lu Gu Long + 12% calcium lignosulfonate dispersant + 3% sodium dodecyl sulfate + 10% precipitated silica and Kaolin for complement
128, A1+ bromogluron (8+30) aqueous suspension
A1+ bromogluron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A1+ stephania (4+30)
A1+ Gerbazone + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A1+ pyridazinol (8+20)
A1+ pyridazinol + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.1% xanthan gum + 1% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
131, A1+ hexazinone (8+40) aqueous suspension
A1+ hexazinone + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
132, A1+ Isoprenyl (8+40) aqueous suspension
A1+ isoamyl ethyl, 5% polycarboxylate, 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt, 0.08% xanthan gum, 0.8% magnesium aluminum silicate, 0.1% defoamer, 3% ethylene glycol and water
133, A1+ Oxydazine (8+40) aqueous suspension
A1+ Oxazin + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
134, A1+ Tribenidine (4+40) aqueous suspension
A1+ weedicide + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
135, A1+ lenacil (8+20) aqueous suspension
A1+ Cyclinum planiforme + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.1% xanthan gum + 1% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
136, A1+ terbacil (4+40) aqueous suspension
A1+ terbacil + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
137, A1+ Methylphenethiol (8+6) aqueous suspension
A1+ methabenzthiazuron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.5% magnesium aluminium silicate + 0.1% defoamer + 3% ethylene glycol + water
138, A1+ Cyclouron (4+40) aqueous suspension
A1+ cyhaloron + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A1+ Isooxan (8+30)
A1+ Isoxon + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
Aqueous suspension of A1+ Methylon (4+40)
A1+ Methylon + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
141, A1+ Subtilis-sodium (4+40) aqueous suspension
A1+ Kunlong + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
142, A1+ trifluoxazine (8+10) aqueous suspension
A1+ trifluoxazine + 5% polycarboxylate + 3% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.2% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
143, A1+ cycloprozoomate (8+8) aqueous suspension
A1+ cycloprominate + 5% polycarboxylate + 3% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.2% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
144, A1+ propanil (4+40) aqueous suspension
A1+ propanil + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminium silicate + 0.1% defoamer + 3% ethylene glycol + water
145, A1+ pyridate (8+30) aqueous suspension
A1+ pyridate + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
146, A1+ Betam (4+30) aqueous suspension
A1+ Beetalol + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
147, A1+ betanin (4+30) aqueous suspension
A1+ betanin + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
148, A1+ bentazone (8+40) aqueous suspension
A1+ bentazone + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
149, A1+ bromoxynil octanoate (8+12) aqueous suspension
A1+ bromoxynil octanoate + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.12% xanthan gum + 1.2% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
150, A1+ bromoxynil (8+8) aqueous suspension
A1+ bromoxynil + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.1% xanthan gum + 1.0% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
151, A1+ ioxynil (8+8) aqueous suspension
A1+ ioxynil + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.1% xanthan gum + 1.0% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
152, A1+ trifluralin (8+20) dispersible oil suspending agent
A1+ trifluralin + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + methyl oleate
153, A1+ butralin (8+30) dispersible oil suspending agent
A1+ butralin + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1% organic bentonite + 0.5% fumed silica + methyl oleate
154, A1+ pendimethalin (8+30) dispersible oil suspension
A1+ pendimethalin + 6% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 5% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + methyl oleate
155, A1+ dithiopyr (8+20) dispersible oil suspending agent
A1+ dithiopyr + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + methyl oleate
156, A1+ Flubenone (8+40) water dispersible granule
A1+ Fluoroxylen + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + Kaolin to complement
157, A1+ amisulpride (8+30) dispersible oil suspension
A1+ sulfamethoxazole + 5% calcium dodecylbenzene sulfonate + 7% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 20% 100# solvent oil + methyl oleate
158, A1+ flutolanil (acetopenyl) (8+30) dispersible oil suspending agent
A1+ flutolanil (benopentin), 6% calcium dodecylbenzenesulfonate, 7% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 10% 100# solvent oil and methyl oleate
159, A1+ fenthizamide (8+20) dispersible oil suspending agent
A1+ fenthizamide + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.5% organobentonite + 0.5% fumed silica + 10% 100# solvent oil + methyl oleate
160, A1+ propyzamide (8+20) dispersible oil suspending agent
A1+ Naxyfen (propyzamide), 5% calcium dodecylbenzenesulfonate, 9% fatty alcohol-polyoxyethylene ether, 6% castor oil-oxyethylene ether, 1% organobentonite, 0.5% fumed silica, 12% 100# solvent oil and methyl oleate
161, A1+ chlorthal (8+50) wettable powder
A1+ chlorthal + 10% sodium lignosulfonate dispersant + 3% sodium dodecyl sulfate + 10% precipitated silica and kaolin
162, A1+ glyphosate (8+50) wettable powder
A1+ P + 10% sodium lignosulfonate dispersant + 3% sodium dodecyl sulfate + 10% precipitated silica and kaolin
163, A1+ diacyl-chlor (8+30) dispersible oil suspending agent
A1+ diacyl-chlor, 5% calcium dodecyl benzene sulfonate, 7% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1% organic bentonite, 0.5% fumed silica, 8% 100# solvent oil and methyl oleate
164, A1+ acetochlor (8+30) dispersible oil suspension
A1+ acetochlor, 6% calcium dodecyl benzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 7% castor oil-polyoxyethylene ether, 1% organobentonite, 1% fumed silica, 8% 100# solvent oil and methyl oleate
165, A1+ butachlor (8+30) dispersible oil suspending agent
A1+ butachlor + 6% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.2% organobentonite + 1.5% fumed silica + methyl oleate
166, A1+ pretilachlor (8+30) dispersible oil suspending agent
A1+ pretilachlor + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.5% organobentonite + 0.5% fumed silica + methyl oleate
167, A1+ metolachlor (8+30) dispersible oil suspension
A1+ metolachlor + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + methyl oleate
168, A1+ mefenacet (8+30) dispersible oil suspending agent
A1+ mefenacet + 6% calcium dodecylbenzene sulfonate + 4% fatty alcohol-polyoxyethylene ether + 7% castor oil-oxyethylene ether + 1.2% organobentonite + 1% fumed silica + methyl oleate
169, A1+ s-metolachlor (8+30) dispersible oil suspending agent
A1+ s-metolachlor + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 0.5% fumed silica + 12% 100# solvent oil + methyl oleate
170, A1+ flufenacet (8+10) dispersible oil suspending agent
A1+ flufenacet + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.0% fumed silica + 20% 100# solvent oil + methyl oleate
171, A1+ napropamide (8+30) dispersible oil suspending agent
A1+ napropamide + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.0% organic bentonite + 1.0% fumed silica + 20% 100# solvent oil + methyl oleate
172, A1+ sulfonepyrazoxazole (8+10) dispersible oil suspending agent
A1+ Sulfuron pyrazoxazole + 5% calcium dodecylbenzene sulfonate + 4% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.5% organic bentonite + 10% 100# solvent oil + methyl oleate
173, A1+ anilofos (8+20) dispersible oil suspension concentrate
A1+ anilofos + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 7% castor oil-polyoxyethylene ether + 1.0% organobentonite + 1.0% fumed silica + 12% 100# solvent oil + methyl oleate
174, A1+ dimethenamid (8+30) dispersible oil suspending agent
A1, dimethenamid, 5% calcium dodecylbenzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.2% organobentonite, 8% 100# solvent oil and methyl oleate
175, A1+ fentrazamide (8+10) dispersible oil suspension
A1+ tetrazolium amide + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.6% organobentonite + 1.5% fumed silica + 8% 100# solvent oil + methyl oleate
176, A1+ Triazolecarboxamide (8+10) dispersible oil suspension
A1+ triazolyl oxamide + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.6% organobentonite + 1.5% fumed silica + 8% 100# solvent oil + methyl oleate
177, A1+ cafenstrole (8+10) dispersible oil suspending agent
A1+ cafenstrole + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.6% organobentonite + 1.5% fumed silica + 8% 100# solvent oil + methyl oleate
178, A1+ pipophos (8+30) dispersible oil suspension
A1+ piperalin P + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 1.6% organic bentonite + 1.5% fumed silica + 8% 100# solvent oil + methyl oleate
179, A1+ propisochlor (8+30) dispersible oil suspending agent
A1+ propisochlor + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 1% fumed silica + 8% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A1+ alachlor (8+30)
A1+ alachlor + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 8% 100# solvent oil + methyl oleate
181, A1+ metazachlor (8+20) dispersible oil suspending agent
A1+ metazachlor, 6% calcium dodecyl benzene sulfonate, 4% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 8% 100# solvent oil and methyl oleate
182.A1+ propachlor (8+30) dispersible oil suspending agent
A1+ phenthoamine + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 8% 100# solvent oil + methyl oleate
183, A1+ dimethenamid (8+30) dispersible oil suspension
A1+ dimethenamid, 5% calcium dodecylbenzenesulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1% organobentonite, 0.5% fumed silica, 8% 100# solvent oil and methyl oleate
184, A1+ prosulfocarb (2+30) dispersible oil suspending agent
A1+ carbofuran + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 8% 100# solvent oil + methyl oleate
185, A1+ molinate (8+50) water dispersible granules
A1+ molinate + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement
186, A1+ thiobencarb (8+50) water dispersible granule
A1+ thiobencarb + 10% naphthalenesulfonate dispersant + 2% polycarboxylate dispersant + 4% sodium dodecylsulfate + 10% precipitated silica + 1% polyvinyl alcohol + kaolin to complement
Dispersible oil suspension agent of A1+ furbenclamide (8+40)
A1+ Fulvhuang + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.6% organobentonite + methyl oleate
188, A1+ ethofumesate (8+40) dispersible oil suspending agent
A1+ ethofumesate + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 0.5% organobentonite + methyl oleate
189, A1+ triallate (8+40) dispersible oil suspension
A1+ Dicamba, 5% calcium dodecylbenzenesulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 0.5% organobentonite, 0.5% fumed silica and methyl oleate
190, A1+ molinate (2+30) dispersible oil suspending agent
A1+ metalaxyl + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.2% organobentonite + 12% 100# solvent oil + methyl oleate
191, A1+ butachlor (8+10) dispersible oil suspending agent
A1+ butachlor, 5% calcium dodecylbenzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 20% 100# solvent oil and methyl oleate
192, A1+ Cytophilus (8+10) dispersible oil suspending agent
A1+ cyhalofop-butyl, 5% calcium dodecyl benzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1.5% fumed silica, 20% 100# solvent oil and methyl oleate
193, A1+ pipindone (8+30) dispersible oil suspension
A1+ pipindone + 6% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.6% organobentonite + 12% 100# solvent oil + methyl oleate
194, A1+ penflufen (4+30) dispersible oil suspension
A1+ penflufen + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.6% organobentonite + 10% 100# solvent oil + methyl oleate
195, A1+ quinclorac (8+25) dispersible oil suspension
A1+ quinclorac + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 0.6% organobentonite + 10% 100# solvent oil + methyl oleate
196, A1+ fluroxypyr (8+12) dispersible oil suspension
A1+ fluroxypyr + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + methyl oleate
197.A1+ fluroxypyr meptyl (8+12) dispersible oil suspension
A1+ fluroxypyr-meptyl ester + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + methyl oleate
198, A1+ Fluorochloropyridine ester (8+0.5) dispersible oil suspending agent
A1+ Fluorochloropyridine ester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + methyl oleate
199, A1+ triclopyr (4+50) wettable powders
A1+ triclopyr + 10% sodium lignosulfonate dispersant + 3% sodium dodecyl sulfate + 10% precipitated silica and kaolin
Dispersible oil suspension of A1+ clopyralid (8+12)
A1+ clopyralid + 5% calcium dodecylbenzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A1+ picloram (2+30)
A1+ amlodipine acid + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 20% 100# solvent oil + methyl oleate
202, A1+ aminopyralid (4+30) dispersible oil suspending agent
A1+ amlodipine acid + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 20% 100# solvent oil + methyl oleate
203, A1+ dicamba (8+14) dispersible oil suspension
A1+ Dicamba, 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 20% 100# solvent oil + methyl oleate
204, A1+ Chlorofluoropyridine ester (8+2) dispersible oil suspension
A1+ fluroxypyridine ester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 2% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
205, A1+ 2-methyl-4-chlorophenoxyacetic acid (4+30) dispersible oil suspending agent
A1+ 2-methyl-4-chlorophenoxyacetic acid + 6% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1% organobentonite + 0.5% fumed silica + 12% 100# solvent oil + methyl oleate
Dispersible oil suspension of A1+ 2-methyl-4-chloro-phenol ethylthioester (4+30)
A1+ 2-methyl-4-chloro-phenol ethyl thioester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organic bentonite + 0.5% fumed silica + 12% 100# solvent oil + methyl oleate
207, A1+ MCPB (4+30) dispersible oil suspension
A1+ MCPB + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1% organobentonite + 0.5% fumed silica + 8% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A1+ 2-methyl-4-chlorophenoxypropionic acid (4+30)
A1+ 2-methyl-4-chlorophenoxypropionic acid + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1% organobentonite + 0.5% fumed silica + 8% 100# solvent oil + methyl oleate
209, A1+ 2-methyl-4-sodium chlorophenoxyacetate (4+30) dispersible oil suspension agent
A1+ 2-methyl-4-sodium chlorophenoxy acetate + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.2% organobentonite + 10% 100# solvent oil + methyl oleate
210, A1+ 2-methyl-4-chlorophenoxyacetic acid isooctyl ester (4+30) dispersible oil suspending agent
A1+ 2-methyl-4-chlorophenoxyacetic acid isooctyl ester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + 10% 100# solvent oil + methyl oleate
211, A1+2, 4-dichlorphenoxyacetic acid butyl ester (8+35) dispersible oil suspending agent
A1+2, 4-dichlorophenoxyacetic acid butyl ester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + methyl oleate
212, A1+2, 4-dichlorophenoxyacetic acid isooctyl ester (8+40) dispersible oil suspending agent
A1+2, 4-dichlorophenoxyacetic acid isooctyl ester + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 0.5% organobentonite + 0.5% fumed silica + methyl oleate
213, A1+2, 4-dichlorophenoxyacetic acid (8+30) dispersible oil suspension concentrate
A1+2, 4-dichlorophenoxyacetic acid + 5% calcium dodecylbenzenesulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1% organobentonite + 0.5% fumed silica + methyl oleate
214, A1+ chloromethylquinolinic acid (8+18) dispersible oil suspending agent
A1+ chloromethylquinolinic acid + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.5% organobentonite + 0.5% fumed silica + methyl oleate
215.A1+2 methyl 4 chlorodimethylammonium salt (8+15) dispersible oil suspension concentrate
A1+2 methyl-4-chlorodimethylammonium salt + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.8% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
Dispersible oil suspension agent of A1+2, 4-dichlorprop (4+30)
A1+2, 4-dichlorprop acid, 5% calcium dodecylbenzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 0.5% fumed silica, 20% 100# solvent oil and methyl oleate
217, A1+2,4-DB/2, 4-D butanoic acid (4+30) dispersible oil suspension
A1+2,4-DB/2, 4-D butyric acid, 5% calcium dodecylbenzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 0.5% organobentonite, 0.5% fumed silica, 20% 100# solvent oil and methyl oleate
218, A1+ benazolin (8+20) dispersible oil suspending agent
A1+ benazolin + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 20% 100# solvent oil + methyl oleate
219, A1+ Cyclopropylpyrimidineoic acid (8+10) dispersible oil suspending agent
A1+ cyclopropane pyrimidinic acid + 5% calcium dodecyl benzene sulfonate + 6% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.8% organic bentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
Aqueous suspension of A1+ glyphosate (8+40)
A1+ glyphosate + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
221, A1+ phosphinothricin (4+30) aqueous suspension
A1+ phosphinothricin + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.08% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
222, A1+ glufosinate-ammonium (8+40) aqueous suspension
A1+ glufosinate-ammonium + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
A1+ bialaphos (4+40) aqueous suspension
A1+ bialaphos + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
224, A1+ glufosinate-ammonium (8+30) aqueous suspension
A1+ glufosinate-ammonium + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
225, A1+ paraquat (8+40) aqueous suspension
A1+ paraquat + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
226, A1+ diquat (4+40) aqueous suspension
A1+ diquat + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
227, A1+ asulam (2+40) aqueous suspension
A1+ asulam + 5% polycarboxylate + 2% phenethylphenol polyoxyethylene ether phosphate triethanolamine salt + 0.07% xanthan gum + 0.8% magnesium aluminum silicate + 0.1% defoamer + 3% ethylene glycol + water
228, A1+ triazine flumioxazin (8+0.5) dispersible oil suspending agent
A1+ triazine flumioxazin + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol polyoxyethylene ether + 6% castor oil polyoxyethylene ether + 2% organic bentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
229, A1+ indexazine flumioxazin (8+0.5) dispersible oil suspension
A1+ indenyloxazine-fluorchlor, 5% calcium dodecylbenzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.8% organobentonite, 1.5% fumed silica, 12% 100# solvent oil and methyl oleate
230, A1+ oxaziclomefone (8+2) dispersible oil suspending agent
A1+ oxaziclomefone + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.8% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
231, A1+ cinmethylin (8+1) dispersible oil suspending agent
A1+ cycloheptane ether + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2% organic bentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
232, A1+ indanthrone (8+2) dispersible oil suspending agent
A1+ indene clomazone + 5% calcium dodecyl benzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 2% organic bentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
233.A1+ quinclorac (8+20) dispersible oil suspending agent
A1+ Quinclorac, 5% calcium dodecyl benzene sulfonate, 5% fatty alcohol-polyoxyethylene ether, 6% castor oil-polyoxyethylene ether, 1.5% organobentonite, 1% fumed silica, 12% 100# solvent oil and methyl oleate
234, A1+ quintocet (8+4) dispersible oil suspending agent
A1+ quintocet-mefone + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.8% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
235, A1+ benzuron (8+20) dispersible oil suspending agent
A1+ benzuron + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
236, A1+ meturon (8+20) dispersible oil suspending agent
A1+ meturon-methyl + 5% calcium dodecylbenzene sulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-polyoxyethylene ether + 1.5% organobentonite + 1% fumed silica + 12% 100# solvent oil + methyl oleate
237, A1+ tetflupyrolimet (8+4) dispersible oil suspension concentrate
A1+ tetflupulolimet + 5% calcium dodecylbenzenesulfonate + 5% fatty alcohol-polyoxyethylene ether + 6% castor oil-oxyethylene ether + 1.8% organobentonite + 1.5% fumed silica + 12% 100# solvent oil + methyl oleate
The processing equipment of the aqueous suspending agent comprises: mixing kettles, colloid mills, sand mills, shearing machines and the like.
The processing process of the aqueous suspending agent comprises the following steps: putting all materials into a mixing kettle, stirring and mixing, passing through a colloid mill, then entering a sand mill for three-stage sand milling, finally uniformly shearing in a shearing machine, and transferring to a storage tank for filling after the test is qualified.
The processing equipment of the dispersible oil suspending agent comprises the following steps: mixing kettles, colloid mills, sand mills, shearing machines and the like.
The processing process of the dispersible oil suspending agent comprises the following steps: putting all materials into a mixing kettle, stirring and mixing, passing through a colloid mill, then entering a sand mill for three-stage sand milling, finally uniformly shearing in a shearing machine, and transferring to a storage tank for filling after the test is qualified.
The water dispersible granule processing equipment comprises an air flow crusher, a colter type mixer, a basket type granulator, a drying box, a sieving machine and the like.
The water dispersible granule is prepared by uniformly mixing the materials, crushing the materials by airflow, adding water, kneading, granulating, drying and finally screening to obtain a finished product.
The processing equipment of the wettable powder comprises: mechanical disintegrators, jet mills, coulter mixers.
The processing process of the wettable powder comprises the following steps: all the materials enter a coulter type mixer, and then are mechanically crushed and airflow crushed to obtain a finished product.
B) Test of drug efficacy
Spraying treatment of stems and leaves after seedling:
1) test conditions
1.1) test target
Chenopodium quinoa is collected from Shaanxi Shaanyang, Setaria viridis is collected from Shandong Qingdao, Potentilla chinensis is collected from Chuzhou, Anhui, and Avena sativa is collected from Henan Staima shop. The weeds are cultured by a pot culture method, plastic nutrition bowls with the size of 180 х 140mm are placed in an enamel tray, surface soil (4/5) which is collected from a farmland and is dried and sieved is filled in the enamel tray, the soil humidity is controlled to be 20% at the initial stage, weed seeds with full and uniform seeds are selected, the weed seeds are soaked in warm water with the temperature of 25 ℃ for 6 hours, germination is accelerated in a biochemical incubator (dark) with the temperature of 28 ℃, the weed seeds which are just exposed to the white are uniformly placed on the surface of the soil, and then the enamel tray is covered with 0.5-1cm of soil according to the particle size of the seeds.
1.2) culture conditions
The method is carried out in a controllable sunlight greenhouse, the temperature is 20-30 ℃, the natural illumination is carried out, and the relative humidity is 57-72%. The soil type is loam, the organic matter content is 1.63%, the pH value is 7.1, the alkaline hydrolysis nitrogen is 84.3mg/kg, the quick-acting phosphorus is 38.5mg/kg, and the quick-acting potassium is 82.1 mg/kg.
1.3), instrumentation
3WP-2000 model walking spray tower, Minn Jing agricultural machinery research institute of agricultural department. Ten thousandth electronic balance type GA10 (germany); ZDR2000 intelligent data recorder (hangzhou ze large instruments ltd); SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument factory).
2) Design of experiments
2.1), reagents
The desired active ingredient a was obtained from patent CN201811035352.5 and the specific preparation process is as follows:
(1) preparation of intermediates
(1.1) dissolving the compound C-1 in dioxane solution, adding sodium methoxide solution (30% content, 1.5eq) and heating to 100 ℃ for reaction for 16-18 hours, and monitoring the completion of the reaction by a liquid phase. Cooling the reaction liquid to room temperature, removing the solvent by using concentrated acid, dissolving by using a 1M hydrochloric acid solution, extracting by using ethyl acetate until a water phase has no product, concentrating an organic phase to obtain a solid, and adding petroleum ether: and (3) pulping and purifying the ethyl acetate which is 10:1, and filtering to obtain the product C-2.
(1.2) Compound C-2 was dissolved in DCE, and phosphorus oxychloride (3eq) and DMF (2%) were added to react at 100 ℃ for 16 to 18 hours. And after the liquid phase monitoring reaction is finished, cooling the reaction liquid, concentrating, controlling the temperature of the obtained product, adding the obtained product into water, separating out a large amount of solids, continuously stirring for 30 minutes, and filtering the solids to obtain a product C.
(2) Preparation of Compound A1
(2.1) dissolving the intermediate C in dioxane solution, adding 10% by volume of water, then adding potassium carbonate (3eq) and a compound A1-1(1.05eq), replacing with nitrogen, adding a palladium catalyst (5%) under the protection of nitrogen, and heating the nitrogen protection system to 120 ℃ for reaction for 16-18 hours. After completion of the reaction, liquid phase monitoring was carried out, water was added to the reaction solution, extraction was carried out with ethyl acetate until the aqueous phase was free from the product, the organic phase was concentrated, and the sample was purified by column chromatography (petroleum ether: ethyl acetate 5: 1) to obtain product a 1-2.
(2.2) dissolving the compound A1-2 in DMSO, adding potassium acetate (5eq), heating the reaction system to 120 ℃, and reacting for 16-18 hours. And (3) after the liquid phase monitoring reaction is finished, cooling to room temperature, then pouring into water, extracting with DCM for three times, adjusting the pH value of the water phase to 4 by using 1M hydrochloric acid, separating out a large amount of solid, continuing stirring for 30 minutes, filtering, and drying a filter cake to obtain the product A1.
The active ingredients B required are diconazole, bicyclopyrone, topramezone and triazophone which are produced by the company, and others are purchased from a reagent company. The raw medicines are all diluted by using an emulsifier Tween-80 aqueous solution with the content of 0.1 percent and taking acetone as a solvent.
2.2) test treatment
2.2.1), dose setting
When determining the ratio or content of the component A and the component B, the main use purpose of the formula is also considered according to the action characteristics of the two medicaments and the measurement of toxicity and the like. On the basis of preliminary experiments, A, B active ingredients are respectively used singly and mixed in different amounts. Water without drug, containing the same solvent and emulsifier was used as a blank.
2.2.2), test repetition
Each treatment was repeated 4 times, 3 pots each time, 20 weed seeds were sown per pot, 60 plants each time.
2.3) treatment method
2.3.1), treatment time and number of times
The test was performed 1 time in total. And (3) thinning when the weeds are in a 3-4 leaf period, keeping 15 weeds in each pot, keeping 45 weeds in each treatment, and then continuously culturing until the weeds are 4-5 leaves for treatment.
2.3.2), instruments and methods of use
Uniformly placing the cultured test material on a 0.5m area2Spraying stem and leaf by using a 3WP-2000 model walking spray tower on the platform, wherein the liquid spraying amount is 450 kg/hectare. The spraying pressure is 0.3 MPa. And after all the liquid medicine is sprayed, closing the air valve, opening the spraying tower door after 30 seconds, and taking out the nutrition pot. Then the air valve is opened, 50mL of clean water is sprayed, and the liquid spraying pipe is cleaned.
3) Test method
The potting method is adopted. The weed cultivation is shown in 1.1), and the method is carried out according to 'herbicide in pesticide indoor bioassay test guidelines'. The application method is shown in 2.3.2), and stem and leaf treatment method is adopted. After treatment, the cells were transferred to a greenhouse for conventional culture.
4) Data investigation and statistical analysis
4.1) investigation method
The complete survival weed seedlings are cut off along the soil surface by a blade by adopting an absolute number survey method, and the fresh weight of the weeds is weighed by an analytical balance. For the weeds that have died, the fresh weight is zero.
4.2), investigation time and number of surveys
The investigation was carried out 20 days after the treatment, and the total number of the investigations was 1.
4.3), statistical analysis of data
The theoretical fresh weight inhibition rate (E0 ═ X + Y-X Y/100) of each treatment mixed combination is calculated by a Gowing method, and then compared with the actually measured inhibition rate (E), the combined action type of the two mixed combinations on the weeds is evaluated, and when the E-E0 value is more than 10 percent, the effect is synergistic, when the E-E0 value is less than-10 percent, the effect is antagonistic, and when the E-E0 value is between-10 percent and 10 percent, the effect is additive. And the optimal proportion is determined according to factors such as actual control effect, characteristics of the herbicide, balance of the formula and the like. Wherein X is the fresh weight inhibition rate when the dosage of the active component A is P; y is the fresh weight inhibition rate of the active component B when the dosage is Q.
The statistical results are shown in tables 1-237 below.
TABLE 1 evaluation of the actual control and combination of Chenopodium album by compounding sulcotrione 1
TABLE 2A 1 evaluation of the actual control and combination of mesotrione compounded to Chenopodium album
TABLE 3A 1 evaluation of the actual control and Combined Effect of the Compound topramezone on Chenopodium quinoa
TABLE 4A 1 evaluation of the actual control and combination of the Ring Sulfonone on Chenopodium quinoa
TABLE 5A 1 evaluation of the actual control and Combined Effect of Fluoropyridone on Chenopodium quinoa
TABLE 6A 1 evaluation of the actual control and Combined Effect of Fusulcotrione on Chenopodium album
TABLE 7 evaluation of the actual control and combination of Chenopodium album by the combination of Dosulcotrione A1
TABLE 8A 1 evaluation of the actual control and Combined Effect of compounded Bixaflutole on Chenopodium album
TABLE 9A 1 evaluation of the actual control and Combined Effect of Cyclopyridoxal on Chenopodium album
TABLE 10A 1 evaluation of the actual control and combination of the Tribuli effects of the compounded triazophone
TABLE 11A 1 evaluation of the actual control and combination of the effect of the blended benzoxaflutole on Chenopodium quinoa
TABLE 12A 1 evaluation of the actual control and Combined action of the Mixed Sulfonylopyrazole on Chenopodium quinoa
TABLE 13A 1 evaluation of the actual control and combination of pyrazolate-compounded Tribuli
TABLE 14A 1 evaluation of the actual control and Combined Effect of blended pyridoxal on Chenopodium quinoa
TABLE 15A 1 evaluation of the actual control and combination of tolpyralate on Chenopodium quinoa
TABLE 16A 1 evaluation of the actual control and Combined action of the blended fenquinotrione on Chenopodium quinoa
TABLE 17 evaluation of the actual control and Combined Effect of isoxaflutole on Chenopodium quinoa by compounding with Isoxaflutole A1
TABLE 18A 1 evaluation of the actual control and combination of the blended benzonatazole on Chenopodium quinoa
TABLE 19A 1 compounding
Evaluation of actual control and combined action of Chenopodium quinoa
TABLE 20A 1 evaluation of the actual control and Combined Effect of the Compound fluorochloridone on Chenopodium quinoa
TABLE 21A 1 evaluation of the actual control and combination of Fuurodim versus Chenopodium quinoa
TABLE 22A 1 evaluation of actual control and Combined Effect of Bighua with Diflufenican
TABLE 23A 1 evaluation of actual control and Combined action of Fluopyramid on Chenopodium quinoa
TABLE 24A 1 evaluation of the actual control and combination of beflubutamid formulated for Chenopodium quinoa
TABLE 25A 1 evaluation of the actual control and Combined Effect of compounded norflurazon on Chenopodium quinoa
TABLE 26A 1 evaluation of the actual control and combination of fluazinone on Chenopodium quinoa
TABLE 27A 1 evaluation of the actual control and combination of clomazone on Chenopodium quinoa
TABLE 28A 1 evaluation of actual Bixlozone control and combination on Chenopodium quinoa
TABLE 29A 1 evaluation of the actual control and combination of tribenuron-methyl on Chenopodium quinoa
TABLE 30A 1 evaluation of the actual control and Combined Effect of Thifensulfuron methyl on Chenopodium quinoa
TABLE 31A 1 evaluation of the actual control and combination of bensulfuron methyl for Chenopodium quinoa
TABLE 32A 1 evaluation of the actual control and combination of pyrazosulfuron-ethyl on Chenopodium album
TABLE 33A 1 evaluation of the actual control and combination of the Thiolosulfuron
TABLE 34A 1 evaluation of the actual control and combination of halosulfuron-methyl on Chenopodium album
TABLE 35A 1 evaluation of the actual control and combination of the Tribuli effects of the blended propyrisulfuron
TABLE 36A 1 evaluation of the actual control and combination of the Ring-pyrazosulfuron-ethyl
TABLE 37A 1 evaluation of the actual control and combination of rimsulfuron with quinoa
TABLE 38A 1 evaluation of the actual control and combination of the Tribuli by the Ethoxysulfuron mixture
TABLE 39A 1 evaluation of the actual control and combination of Anilinosulfuron-P-Chenopodium
TABLE 40A 1 evaluation of the actual control and combination of Flucarbazone-sodium for Chenopodium quinoa
TABLE 41A 1 evaluation of the actual control and combination of Chenopodium album by compounding with mesosulfuron
TABLE 42A 1 evaluation of the actual control and combination of nicosulfuron on Chenopodium album
TABLE 43A 1 evaluation of the actual control and combination of foramsulfuron pairs of Chenopodium quinoa
TABLE 44A 1 evaluation of the actual control and combined action of mixed flumetsulam on Chenopodium quinoa
TABLE 45A 1 evaluation of the actual control and combination of Ottelia quinoa with Fluoroketofonamide
TABLE 46A 1 evaluation of the actual control and combination of penoxsulam on Chenopodium quinoa
TABLE 47A 1 evaluation of the actual control and combination of cloransulam-chloratum on Chenopodium quinoa
TABLE 48A 1 evaluation of the actual control and Combined action of mixed pyroxsulam on Chenopodium quinoa
TABLE 49A 1 evaluation of the actual control and Combined Effect of compounding imazamox on Chenopodium quinoa
TABLE 50A 1 evaluation of the actual control and combination of imazapic with compounding of Chenopodium album
TABLE 51A 1 evaluation of the actual control and combination of imazethapyr versus Chenopodium quinoa
TABLE 52A 1 evaluation of the actual control and combination of imazapyr on Chenopodium quinoa
TABLE 53 evaluation of the actual control and combination of pyriminobac-sodium for Chenopodium quinoa by compounding pyriminobac-methyl with 1
TABLE 54A 1 evaluation of the actual control and combination of florasulam on Chenopodium
TABLE 55A 1 evaluation of the actual control and combination of the Mixed pyriftalid on Chenopodium quinoa
TABLE 56A 1 evaluation of the actual control and combination of pyribenzoxim on Chenopodium quinoa
TABLE 57A 1 evaluation of the actual control and Combined Effect of Tribuli with Tribensulfuron mixture
TABLE 58A 1 evaluation of the actual control and combination of imazethapyr versus Chenopodium quinoa
TABLE 59A 1 evaluation of the actual control and combination of chlorsulfuron on Chenopodium quinoa
TABLE 60A 1 evaluation of the actual control and Combined Effect of Etosulfuron-methyl-compounded on Chenopodium quinoa
TABLE 61A 1 evaluation of the actual control and combination of cyclosulfamuron for Chenopodium quinoa
TABLE 62A 1 evaluation of the actual control and combination of amidosulfuron on Chenopodium album
TABLE 63A 1 evaluation of the actual control and Combined Effect of Tribuli's Mixed Ether tribenuron-methyl
TABLE 64A 1 evaluation of the actual control and combination of the sodium iodosulfuron for Chenopodium quinoa
TABLE 65A 1 evaluation of the actual control and combination of flazasulfuron on Chenopodium album
TABLE 66A 1 evaluation of the actual control and combination of Fluoropyrosulfuron on Chenopodium quinoa
TABLE 67A 1 evaluation of the actual control and Combined Effect of Tribuli with Tribena metsulfuron
TABLE 68A 1 evaluation of the actual control and Combined action of Tribuli with Tribenum Triben Tribute
TABLE 69 evaluation of the actual control and combination of the Sulfosulfuron-methyl-mixed to Chenopodium quinoa
TABLE 70A 1 evaluation of the actual control and combination of halosulfuron-methyl on Chenopodium album
TABLE 71A 1 evaluation of the actual control and combination of Bispyribac-sodium for Chenopodium quinoa
TABLE 72A 1 evaluation of the actual control and Combined action of Sulfocap-sodium on Chenopodium quinoa
TABLE 73A 1 evaluation of the actual control and combination of Clodinafop-propargyl for green grass
TABLE 74A 1 evaluation of the actual control and combination of pinoxaden with pinoxaden
TABLE 75A 1 evaluation of the actual control and combination of clethodim on green setaria
TABLE 76A 1 evaluation of the actual control and combination of sethoxydim for green setaria
TABLE 77A 1 evaluation of the actual control and combined action of quizalofop-p-ethyl on green setaria
TABLE 78A 1 evaluation of the actual control and combination of amiloride on green Setaria viridis
TABLE 79 evaluation of actual control and combination of fluazifop-p-butyl to green setaria viridis by A1 blending
TABLE 80A 1 evaluation of the actual control and joint action of haloxyfop-R-methyl on green setaria viridis
TABLE 81A 1 evaluation of the actual control and combination of diclofop-p-methyl on green setaria
TABLE 82A 1 evaluation of the actual control and joint action of fenoxaprop-p-ethyl on green setaria viridis
TABLE 83A 1 evaluation of actual control and combination of Cyhalofop-butyl for green setaria
TABLE 84A 1 evaluation of the actual control and combination of cycloxydim on green setaria
TABLE 85A 1 evaluation of the actual control and combination of metamifop to green bristlegrass
TABLE 86A 1 evaluation of the actual control and combination of green grass
TABLE 87A 1 evaluation of actual control and combination of oxyfluorfen in Chenopodium quinoa
TABLE 88A 1 evaluation of the actual control and combination of fomesafen versus Chenopodium quinoa
TABLE 89A 1 evaluation of the actual control and combination of oxadiazon on Chenopodium quinoa
TABLE 90A 1 evaluation of the actual control and Combined Effect of the Compound oxadiargyl on Chenopodium quinoa
TABLE 91A 1 evaluation of the actual control and combination of the grass-roots mixed with sulfentrazone
TABLE 92A 1 evaluation of the actual control and Combined action of Bixapyroxad on Chenopodium quinoa
TABLE 93A 1 evaluation of the actual control and combination of the quinoa with the compounded flumioxazin
TABLE 94 evaluation of the actual control and combination of the Effect of Cyclopentoxazone on Chenopodium quinoa by A1 compounding
TABLE 95A 1 evaluation of the actual control and Combined action of the Tiafenac blends on Chenopodium quinoa
TABLE 96A 1 evaluation of the actual control and combination of saflufenacil on Chenopodium quinoa
TABLE 97A 1 evaluation of the actual control and Combined Effect of Bighua with Bispyribac-sodium
TABLE 98A 1 evaluation of the actual control and Combined Effect of Mixed carfentrazone-ethyl on Chenopodium quinoa
TABLE 99A 1 evaluation of the actual control and combination of Flavering for Chenopodium quinoa
TABLE 100A 1 evaluation of the actual control and Combined Effect of the compounded ethoxyfen-ethyl on Chenopodium quinoa
TABLE 101A 1 evaluation of actual control and combination of haloxyfop-ethyl on Chenopodium quinoa
TABLE 102A 1 evaluation of actual control and combination of acifluorfen-sodium for Chenopodium quinoa
TABLE 103A 1 evaluation of the actual control and combination of triflumimoxazin against Chenopodium quinoa
TABLE 104A 1 evaluation of the actual control and combination of the methyl ester of mixed oxazine oxalate on Chenopodium quinoa
TABLE 105A 1 evaluation of actual prevention and Combined Effect of atrazine compounded on Chenopodium quinoa
TABLE 106A 1 evaluation of the actual control and combination of the Compound prometryn against Chenopodium quinoa
TABLE 107A 1 evaluation of actual control and combination of simetryn combinations on Chenopodium quinoa
TABLE 108A 1 evaluation of actual control and combination of Tribuli with terbuthylazine
TABLE 109A 1 evaluation of actual control and combination of Terbutyrn with Tribuli
TABLE 110A 1 evaluation of the actual control and Combined Effect of mixed ametryn on Chenopodium quinoa
TABLE 111A 1 evaluation of the actual control and combination of isoprotulin over Chenopodium quinoa
TABLE 112A 1 evaluation of the actual control and combination of phytocide on Chenopodium quinoa
TABLE 113A 1 evaluation of the actual control and Combined action of the Compound Dipterex on Chenopodium quinoa
TABLE 114A 1 evaluation of actual control and combination of Ximadzu in combination with Chenopodium quinoa
TABLE 115A 1 evaluation of the actual control and Combined Effect of Mixed metribuzin on Chenopodium quinoa
TABLE 116A 1 evaluation of the actual control and Combined Effect of compounding ethisterone on Chenopodium quinoa
TABLE 117A 1 evaluation of the actual control and Combined Effect of the compounded amicarbazone on Chenopodium quinoa
TABLE 118A 1 evaluation of the actual control and Combined Effect of Mixed metamitron on Chenopodium album
TABLE 119A 1 evaluation of actual control and combination of cyanazine on Chenopodium quinoa
TABLE 120A 1 evaluation of the actual control and combination of the Mixed Chloroton on Chenopodium quinoa
TABLE 121A 1 evaluation of the actual control and combination of Isoproton versus Chenopodium quinoa
TABLE 122A 1 evaluation of the actual control and combination of diuron versus Chenopodium quinoa blends
TABLE 123A 1 evaluation of the actual control and combination of the combination of fluazuron to Chenopodium quinoa
TABLE 124A 1 evaluation of the actual control and combination of Riguron compounded on Chenopodium quinoa
TABLE 125A 1 evaluation of the actual control and combination of the Tribuli effects of the Mixed Thidiazuron
TABLE 126A 1 evaluation of the actual control and Combined action of the blended Shapu' ron on Chenopodium quinoa
TABLE 127A 1 evaluation of the actual control and combination of Lugulong on Chenopodium quinoa
TABLE 128A 1 evaluation of the actual control and combination of bromuron on Chenopodium quinoa
TABLE 129A 1 evaluation of the actual control and combination of the herbal Robusta on Chenopodium quinoa
TABLE 130A 1 evaluation of the actual control and Combined Effect of the Mixed pyridazinols on Chenopodium quinoa
TABLE 131A 1 evaluation of the actual controlling effect and combined action of the hexazinone compound on Gelidium japonicum
TABLE 132A 1 evaluation of the actual control and combination of the Potentilla discolor with isoamyl ethrin
TABLE 133A 1 evaluation of actual control and joint action of Suzuojin mixed with grass
TABLE 134A 1 evaluation of actual control and combined action of blend herbicide on Baogeli grass
TABLE 135A 1 evaluation of the actual control and combination of lenacil to BAOGANCAO
TABLE 136A 1 evaluation of the actual control and combination of terbacil with gemini
TABLE 137A 1 evaluation of the actual control and combination of the Mesothiaron to Baoguo grass
TABLE 138A 1 evaluation of the actual control and combination of the Cymbopogon Citratus
TABLE 139A 1 evaluation of the actual control and combination of the active ingredients of Baogancao
TABLE 140A 1 evaluation of the actual control and combination of the Metronidazole mixture for the treatment of Gelidium japonicum
Table 141A 1 evaluation of actual control and joint action of Sulfuron mixed with Baoguo on Baoguo grass
TABLE 142A 1 evaluation of actual control and combination of trifluoxazine on Gelidium japonicum
TABLE 143A 1 evaluation of the actual control and combined action of the cyclopyromate on Geum japonicum
TABLE 144A 1 evaluation of the actual control and combination of propanil with BAOGANCAO
TABLE 145A 1 evaluation of the actual control and combination of pyridate mixed with Baoguo grass
TABLE 146A 1 evaluation of the actual control and combination of the use of betaine Ampelopsis Grossdentata
TABLE 147A 1 evaluation of the actual control and combination of Baogesi with betanin
TABLE 148A 1 evaluation of the actual control and combination of bentazon mixtures on Gelidium sp
TABLE 149A 1 evaluation of the actual control and combination of bromoxynil octanoate on Gelidium japonicum
TABLE 150A 1 evaluation of the actual control and combination of bromoxynil compounds on Gelidium sp
TABLE 151A 1 evaluation of the actual control and combination of ioxynil to Gelidium sp
TABLE 152A 1 evaluation of the actual control and combination of the trifluralin mixed with the BAOGANCAO
TABLE 153A 1 evaluation of the actual control and joint action of butralin mixed to Baogeicao
TABLE 154A 1 evaluation of the actual control and combination of pendimethalin in combination with Gelidium japonicum
TABLE 155A 1 evaluation of the actual control and combination of the Sulfothiadine mixture on the grass
TABLE 156A 1 evaluation of actual control and joint action of ETBUNFULING on BAOGICAO
TABLE 157A 1 evaluation of the actual control and joint action of the amisulpride mixture on Baoguo grass
TABLE 158A 1 evaluation of the actual control and combination of the fluroxypyr with acetopenetrol
TABLE 159A 1 evaluation of the actual control and Combined action of the Mixed Thiacloprid on Gelidium
TABLE 160A 1 evaluation of the actual control and combination of Panaxadiol on penoxsulam
TABLE 161A 1 evaluation of actual control and combination of chlorthal on BAOGAO
TABLE 162A 1 evaluation of the actual control and combination of Potentilla discolor with the incorporation of glyphosate inhibitor
TABLE 163A 1 evaluation of the actual control and Combined action of the mixed diacyl-ureas on Geum japonicum
TABLE 164A 1 evaluation of the actual control and combination of the acetochlor in the mixture for the grass
Table 165A 1 evaluation of actual control and combined action of butachlor in mixed form on Geiger grass
TABLE 166A 1 evaluation of the actual control and combination of pretilachlor on Geiger
Evaluation of actual control effect and combined effect of metolachlor compounded in Table 167A 1 on Boraginaceae
TABLE 168A 1 evaluation of the actual control and combination of penoxsulam
TABLE 169A 1 evaluation of the actual control and combined action of s-metolachlor mixed with gemini on pennisetum sp
TABLE 170A 1 evaluation of the actual control and combination of flufenacet in combination with Gelidium sp
TABLE 171A 1 evaluation of the actual control and combination of napropamide with a mixture of napropamide
TABLE 172A 1 evaluation of the actual control and combination of Sulfurpur Bifone for Gelidium
TABLE 173A 1 evaluation of the actual control and combination of anilofos when mixed with fenchox
TABLE 174A 1 evaluation of the actual control and combination of gemfibrozil with dimethenamid
TABLE 175A 1 evaluation of the actual control and combination of fenugreek with fentrazamide
TABLE 176A 1 evaluation of the actual control and combination of the objective Gelidium by compounding with triazolam
TABLE 177A 1 evaluation of the actual control and combination of the cafenstrole with penoxsulam
TABLE 178A 1 evaluation of the actual control and combination of the penfenphos mixture for Gelidium sp
TABLE 179A 1 evaluation of the actual control and combination of the action of propisochlor on the grass
TABLE 180A 1 evaluation of the actual control and combination of alachlor for Geum japonicum
TABLE 181A 1 evaluation of the actual control and combination of the synergistic effect of the mixed pyraflufen-ethyl on the grass of Geiger
TABLE 182A 1 evaluation of the actual control and combination of gemfibrozil with the combination of Convolvulus arvensis
TABLE 183A 1 evaluation of the actual control and combination of the penoxsulam on Geiger grass
TABLE 184A 1 evaluation of the actual control and combination of the mixed prosulfocarb on Avena sativa
TABLE 185A 1 evaluation of the actual control and Combined Effect of blended Dimethoate Avena sativa
TABLE 186A 1 evaluation of the actual control and combination of the mixed erysipelas to Avena sativa
TABLE 187A 1 evaluation of the actual control and combination of the Fulviao mixed with wild oat
TABLE 188A 1 evaluation of the actual control and combination of the mixed ethofumesate to Avena sativa
TABLE 189A 1 evaluation of the actual control and Combined action of Dicamba mixed with Avena sativa
TABLE 190A 1 evaluation of the actual control and Combined action of the Mixed Metronidazole oat
Evaluation of actual control effect and combined effect of Table 191A 1 mixed butantp on wild oat
TABLE 192A 1 evaluation of the actual control and Combined action of the mixed cycloprophoron and paraquat Avena sativa
TABLE 193A 1 evaluation of the actual control and Combined action of mixed piptanthus chinensis on Avena sativa
TABLE 194A 1 evaluation of actual control and combination of penflufen for Avena sativa
Evaluation of actual control and combined action of Quinclorac on Baoguo grass by compounding in Table 195A 1
TABLE 196A 1 evaluation of the actual control and Combined Effect of fluroxypyr-compounded on Geiger grass
TABLE 197A 1 evaluation of the actual control and Combined Effect of fluroxypyr-meptyl on Geiger
TABLE 198A 1 evaluation of the actual control and combination of Baogesi with fluroxypyridine
TABLE 199A 1 evaluation of actual control and combination of triclopyr on Gem
TABLE 200A 1 evaluation of actual control and combination of pennisetum hydridum with clopyralid
TABLE 201A 1 evaluation of the actual prevention and combination of Picloram to Gelidium japonicum
TABLE 202A 1 evaluation of the actual control and combination of Baogesi with aminopyralid
TABLE 203A 1 evaluation of the actual control and Combined action of dicamba on Gelidium
TABLE 204A 1 evaluation of the actual control and combination of fluroxypyr esters compounded for Geiger grass
TABLE 205A 1 evaluation of the actual control and combination of Baogeli with 2-methyl-4-chlorophenoxyacetic acid
TABLE 206A 1 evaluation of actual control and combination of Baogeli by blending 2-methyl-4-chloro-phenoxathion
TABLE 207A 1 evaluation of the actual control and combination of MCPB blended with Gelidium japonicum
TABLE 208A 1 evaluation of the actual control and combination of Baogeli with 2-methyl-4-chlorophenoxypropionic acid
TABLE 209 evaluation of the actual control and combination of Gelidium japonicum by compounding 2-methyl-4-sodium chlorophenoxylate with 1
TABLE 210A 1 evaluation of the actual control and combination of 2-methyl-4-chlorophenoxyacetic acid isooctyl ester on Geum japonicum
TABLE 211A 1 evaluation of the actual control and combination of butyl 2, 4-dichlorophenoxyacetate
TABLE 212 evaluation of the actual control and combination of the 2, 4-dichlorophenoxyacetic acid isooctyl ester blended with the grass of Geiger
TABLE 213A 1 evaluation of the actual control and combination of the 2, 4-dichlorophenoxyacetic acid with Geiger grass
Evaluation of actual prevention and combination of Table 214A 1 with chloromethylquinolinic acid for Gelidium japonicum
TABLE 215A 1 evaluation of the actual control and combination of Baogrash with 2-methyl-4-chlorodimethylammonium salt
TABLE 216 evaluation of actual control and joint action of 2, 4-Dipropionic acid mixed with Gelidium japonicum
TABLE 217A 1 evaluation of actual control and combination of Gelidium japonicum with 2,4-DB/2, 4-D-butyric acid
TABLE 218A 1 evaluation of the actual control and joint action of benazolin-compounded on BAOGICAO
TABLE 219 evaluation of the actual control and Combined action of Cytopyrimidic acid mixture of A1 on Gelidium japonicum
TABLE 220A 1 evaluation of actual control and Combined action of Glyphosate blends on Gelidium sp
TABLE 221A 1 evaluation of the actual control and combination of the grass-sulfur-phosphine compounds on the grass
TABLE 222A 1 evaluation of actual control and Combined action of glufosinate-ammonium compounded on Gelidium sp
TABLE 223A 1 evaluation of the actual control and Combined action of Bialanylphosphine blends on Geiger grass
TABLE 224A 1 evaluation of the actual control and combination of the Acronomum p-glufosinate on Geum japonicum
TABLE 225A 1 evaluation of the actual control and combination of paraquat on Gelidium sp
TABLE 226A 1 evaluation of the actual control and combination of the synergistic effect of diquat on Baoguo
TABLE 227A 1 evaluation of the actual control and combination of the Sulfocailin mixture to Baoguo grass
Table 228A 1 evaluation of the actual control and combination of triazineone-flumioxazin against Geiger grass
TABLE 229A 1 evaluation of the actual control and combination of the effects of the mixed indexazine flumioxazin on Geiger grass
Table 230A 1 evaluation of the actual control and combination of oxaziclomefone on Gelidium sp
TABLE 231A 1 evaluation of the actual control and combination of the grass
TABLE 232A 1 evaluation of the actual control and Combined action of the compounded indene-mefone on Gelidium
TABLE 233A 1 evaluation of the actual control and combination of quinoxydim on Boraginaceae
TABLE 234A 1 evaluation of the actual control and Combined action of the Compound Quinclorac on Gelidium
TABLE 235A 1 evaluation of the actual control and combination of the Bifenuron-blended compounds on the grass
TABLE 236A 1 evaluation of the actual control and combination of the Mesona Procumbens Hemsl
Evaluation of actual control and Combined action of Tetflubolimet mixed with Table 237A 1 on Geum japonicum
C) Demonstration of field
The herbicidal compositions prepared in examples 1 to 237 were used for field weed effect tests.
An exemplary popularization test was carried out in 2017 at the test point of Jiangsu Huai' an. The weeds in the field are mainly: amaranthus retroflexus, Chenopodium album, Setaria viridis, Echinochloa crusgalli, and the like.
The test method comprises the following steps:
treating stems and leaves, namely adding 30 kg of water per 667m by a manual sprayer when the weeds are in the 1-1.5 leaf stage2The stem and leaf are sprayed evenly.
The specific test agents and dosages are detailed in table 238, with a cell area of 50 square meters, repeated 4 times per treatment. The control effect 20 days after application is shown in Table 238.
Table 238 exemplary field Effect of the compounded compositions
Through a large number of tests and explorations, the composition is unexpectedly found to be used for preventing and removing weeds such as chenopodium quinoa, green setaria viridis, pagoda grass, wild oat, redroot amaranth, barnyard grass and the like, has a surprising and unexpected synergistic effect, is more remarkable in low-dosage performance, can reduce the dosage and the pollution to the environment, is reasonably compounded to reduce the agricultural cost, is efficient for ALS and ACCase inhibitor resistant weeds, and has a good application prospect. Meanwhile, the herbicide composition shows good selectivity and excellent synergistic effect in wheat fields, corn fields, paddy fields, peanuts, sugarcane, sorghum, millet, potatoes, rape, soybeans, cotton, vegetables, bluegrass, tall fescue, zoysia japonica and other plants through tests, and can be developed into herbicide mixtures with wide market value.
Claims (10)
1.A herbicidal composition comprising 3-aryl-6-trifluoromethylpyridazinol compounds, characterized by comprising a herbicidally effective amount of an active ingredient A and an active ingredient B, wherein,
the active ingredient A is selected from one or more than two compounds shown in a general formula I:
x represents an unsubstituted or substituted aryl group;
the active ingredient B is selected from one or more of the following compounds and salts/esters thereof:
(1) HPPD inhibitors: sulcotrione, mesotrione, topramezone, tembotrione, fluroxypyr, mesotrione, bicyclosulfuron, topramezone, trazodone, triazophone, topramezone, pyrazote, pyraflutole, tolpyralate, fenquinotrione, isoxaflutole, pyraclonil, fenflurazone, topramezone,
(2) (ii) a PDS inhibitor: flurtamone, diflufenican, beflubutamid, fluroxypyr and fluridone;
(3) a DOXP inhibitor: clomazone, bixlazone;
(4) ALS inhibitors: tribenuron-methyl, thifensulfuron-methyl, bensulfuron-methyl, pyrazosulfuron-ethyl, thiencsulfuron-methyl, halosulfuron-methyl, propyrisulfuron-methyl, metrisulfuron-methyl, rimsulfuron-methyl, flucarbazone-methyl, mesosulfuron-methyl, nicosulfuron-methyl, foramsulfuron-methyl, flumetsulam-methyl, triasulfuron-methyl, fluazincarbazide-methyl, penoxsulam-methyl, cloransulam-methyl, pyroxsulam-methyl, imazamox, imazethapyr, imazapyr, pyriminobac-methyl, florasulam, pyribenzoxim-methyl, propbensulfuron-methyl, imazethapyr-methyl, chlorosulfuron, cinosulfuron, cyclosulfamuron, amidosulfuron, triasulfuron-methyl, tribenuron-methyl, iodosulfuron-methyl sodium, flazasulfuron-methyl, flucetosulfuron, metsulfuron-methyl, triflusulfuron-methyl, sulfosulfuron-methyl, pyrazosulfuron-methyl;
(5) ACCase inhibitors: clodinafop-propargyl, pinoxaden, clethodim, sethoxydim, quizalofop-p-ethyl, tralkoxydim, fluazifop-p-butyl, haloxyfop-methyl, diclofop-methyl, fenoxaprop-p-ethyl, cyhalofop-butyl, clethodim, metamifop, oxadiargyl;
(6) PPO inhibitors: oxyfluorfen, fomesafen, oxadiazon, oxadiargyl, sulfentrazone, pyraclonil, flumioxazin, pentoxazone, tiafenacil, saflufenacil, pyraflufen, carfentrazone-ethyl, butafenacil, trifluoromethoxyfen, triflumimoxazin, metribuzin methyl ester;
(7) PSII inhibitors: atrazine, prometryn, simetryn, terbuthylazine, terbutryn, ametryn, ipratron, fenfluryn, diquat, simazine, metribuzin, ethiprole, amicarbazone, metamitron, cyanazine, chlortoluron, isoproturon, diuron, fluometuron, linuron, buthiuron, sumuron, gluron, bromuron, glufosinate, pyridazinol, hexazinone, isoethazine, prodazine, bromacil, lenacil, triclopyr, thiuron, isoxauron, metoxuron, subtilon, trifluoxazine, cycloprozoximate, propanil, pyridate, desmetryn, bromoxynil octanoate, bromoxynil, ioxynil;
(8) microtubule assembly inhibitors: trifluralin, butralin, pendimethalin, dithiopyr, butyfluing, oryzalin, sulfluralin, flumetsulam, fenthizamide, natremit, chlorthal and butafosinate;
(9) microtubule combination inhibitors: diacyl urea;
(10) VLCFA inhibitors: acetochlor, butachlor, pretilachlor, metolachlor, mefenacet, s-metolachlor, flufenacet, napropamide, pyroxafen, anilofos, dimethenamid, fentrazamide, triazolamide, cafenstrole, mephos, propisochlor, metazachlor, propyzamide, pethoxamid;
(11) lipid synthesis (non-acetyl-coa carboxylase) inhibitors: prosulfocarb, molinate, prosulfocarb, furbengal, ethofumesate, triallate, dichlormate, dichlorvos, penflufen and penflufen;
(12) synthesis of hormones: quinclorac, fluroxypyr-meptyl, triclopyr, clopyralid, picloram, aminopyralid, dicamba, fluroxypyr, 2-methyl-4-chlorophenoxyacetic acid, 2-methyl-4-chloro-phenothiolester, MCPB, 2-methyl-4-chlorophenoxypropionic acid, 2-methyl-4-sodium chlorophenoxyacetate, 2-methyl-4-isooctyl chlorophenoxyacetate, 2, 4-butyl dichlorophenoxyacetate, 2, 4-isooctyl dichlorophenoxyacetate, 2, 4-dichlorophenoxyacetate, chloroquinolinic acid, 2-methyl-4-chlorodimethylammonium salt, 2, 4-dichlorpropionic acid, 2, 4-dichlorbutyric acid, benazolin and cyprodinil;
(13) EPSPS inhibitors: glyphosate, phosphinothricin;
(14) a GS inhibitor: glufosinate, bialaphos, refined glufosinate;
(15) PSI inhibitor selected from paraquat, diquat;
(16) DHP inhibitors: asulam;
(17) cellulose synthesis inhibitors: triazinyl flufenacet, indexazine flufenacet;
(18) other herbicides: oxaziclomefone, cinmethylin, indanthrone, quinclomazone, cumyluron, tetflupyrlomet.
2.A herbicidal composition comprising 3-aryl-6-trifluoromethylpyridazinol compounds according to claim 1, wherein X represents pyrazolyl which is unsubstituted or substituted by at least one group selected from C1-C6 alkyl, halo-substituted C1-C6 alkyl, cyano, halogen, C1-C6 alkoxy, C1-C6 alkylcarbonyl; preferably, X represents
3.A herbicidal composition comprising 3-aryl-6-trifluoromethylpyridazinol compounds according to claim 1 or 2, wherein the weight ratio of A, B is 1:1000 to 200:1 and 1:600 to 150: 1; preferably 1: 500-100: 1 and 1: 400-80: 1; more preferably 1: 300-60: 1 and 1: 200-50: 1; further preferably 1: 100-30: 1 and 1: 50-20: 1; further preferred are 1:20 to 10:1, 1:10 to 5:1 and 1:5 to 1: 1.
4.A herbicidal composition comprising 3-aryl-6-trifluoromethylpyridazinol compounds according to any of the claims 1 to 3, wherein A, B represents 1 to 95% by weight of the total amount, preferably 10 to 80% by weight.
5.A herbicidal composition containing 3-aryl-6-trifluoromethylpyridazinol compounds according to any one of claims 1 to 3, wherein conventional adjuvants are further included, preferably the conventional adjuvants include carriers, surfactants.
6. The herbicidal composition comprising 3-aryl-6-trifluoromethylpyridazinol compounds according to any one of claims 1 to 5, wherein the herbicidal composition further comprises at least one safener.
7.A herbicidal composition comprising 3-aryl-6-trifluoromethylpyridazinol compounds according to claim 6, wherein the safener is selected from one or more of isoxadifen, cyprosulfamide, mefenpyr, cloquintocet, gibberellic acid, furilazole, mecamifen.
8. The herbicidal composition containing the 3-aryl-6-trifluoromethylpyridazinol compound according to any one of claims 1 to 7, wherein the formulation of the herbicidal composition is dispersible oil suspension, aqueous suspension, suspoemulsion, wettable powder, emulsifiable concentrate, water dispersible granule, aqueous emulsion or microemulsion.
9. Use of the herbicidal composition comprising 3-aryl-6-trifluoromethylpyridazinol compound according to any one of claims 1 to 8 for controlling weeds.
10.A method for controlling unwanted plant growth, which comprises applying the herbicidal composition comprising a 3-aryl-6-trifluoromethylpyridazinol compound according to any one of claims 1 to 8 to a plant, a plant part, a plant seed or an area where a plant is grown.
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| AT309883B (en) * | 1971-06-16 | 1973-09-10 | Chemie Linz Ag | Herbicidal agent |
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| CN105451558B (en) * | 2013-08-05 | 2018-10-23 | 先正达参股股份有限公司 | Pyrazolyl pyrrolinone and its purposes as herbicide |
| EA031259B1 (en) * | 2014-04-23 | 2018-12-28 | Басф Се | Herbicidal combination comprising azines |
| AR112682A1 (en) * | 2017-08-17 | 2019-11-27 | Syngenta Participations Ag | HERBICIDE COMPOUNDS |
| WO2019148850A1 (en) * | 2018-02-02 | 2019-08-08 | 青岛清原化合物有限公司 | Pyridine ring-substituted pyridazinol compound and derivatives thereof, preparation method, herbicidal composition, and application |
| WO2019148851A1 (en) * | 2018-02-02 | 2019-08-08 | 青岛清原化合物有限公司 | Five-membered ring-substituted pyridazinol compound and derivatives thereof, preparation method, herbicidal composition, and application |
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| US3790571A (en) * | 1971-06-11 | 1974-02-05 | Oesterr Stickstoffwerke Ag | Phenylpyridazines |
| AT309883B (en) * | 1971-06-16 | 1973-09-10 | Chemie Linz Ag | Herbicidal agent |
| US4058390A (en) * | 1974-12-17 | 1977-11-15 | Chemie Linz Aktiengesellschaft | Amine salts of phenyl-4-hydroxypyridazines and the preparation and herbicidal compositions thereof |
| WO2005077178A2 (en) * | 2004-02-16 | 2005-08-25 | Syngenta Participations Ag | Herbicidal composition |
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| CN110128352A (en) * | 2018-02-02 | 2019-08-16 | 青岛清原化合物有限公司 | Pyridazine alcohol compound and its derivative, preparation method, Herbicidal combinations and application |
| CN109479888A (en) * | 2018-12-19 | 2019-03-19 | 青岛清原化合物有限公司 | Ternary weeding composition and its application comprising cyclopyrimorate |
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| WO2020215604A1 (en) | 2020-10-29 |
| CN111820225B (en) | 2022-04-05 |
| CN111820224A (en) | 2020-10-27 |
| CN111820224B (en) | 2022-04-05 |
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