CN107774301B - 用于C8芳族馏分的异构化的包含具有最优化Si/Al摩尔比的IZM-2沸石的催化剂 - Google Patents
用于C8芳族馏分的异构化的包含具有最优化Si/Al摩尔比的IZM-2沸石的催化剂 Download PDFInfo
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- CN107774301B CN107774301B CN201710617072.4A CN201710617072A CN107774301B CN 107774301 B CN107774301 B CN 107774301B CN 201710617072 A CN201710617072 A CN 201710617072A CN 107774301 B CN107774301 B CN 107774301B
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- 239000003054 catalyst Substances 0.000 title claims abstract description 144
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- 150000001925 cycloalkenes Chemical class 0.000 description 1
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- 238000000354 decomposition reaction Methods 0.000 description 1
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- 238000011161 development Methods 0.000 description 1
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
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- 239000008394 flocculating agent Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000001033 granulometry Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- 239000002638 heterogeneous catalyst Substances 0.000 description 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000000449 magic angle spinning nuclear magnetic resonance spectrum Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000320 mechanical mixture Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000006060 molten glass Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 229940078552 o-xylene Drugs 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002896 organic halogen compounds Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- HRGDZIGMBDGFTC-UHFFFAOYSA-N platinum(2+) Chemical class [Pt+2] HRGDZIGMBDGFTC-UHFFFAOYSA-N 0.000 description 1
- NDBYXKQCPYUOMI-UHFFFAOYSA-N platinum(4+) Chemical class [Pt+4] NDBYXKQCPYUOMI-UHFFFAOYSA-N 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001470 polyketone Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000004230 steam cracking Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000010555 transalkylation reaction Methods 0.000 description 1
- GSYXIGDIZRBXJH-UHFFFAOYSA-N triphenylindigane Chemical compound C1=CC=CC=C1[In](C=1C=CC=CC=1)C1=CC=CC=C1 GSYXIGDIZRBXJH-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/74—Noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
- C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
- C07C5/2732—Catalytic processes
- C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
- C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
- C07C5/2767—Changing the number of side-chains
- C07C5/277—Catalytic processes
- C07C5/2775—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
- C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
- C07C2529/74—Noble metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
- C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
- C07C2529/76—Iron group metals or copper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1657146 | 2016-07-26 | ||
| FR1657146A FR3054454B1 (fr) | 2016-07-26 | 2016-07-26 | Catalyseur comprenant une zeolithe izm-2 ayant un rapport molaire si/al optimise pour l'isomerisation de coupes c8 aromatiques |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107774301A CN107774301A (zh) | 2018-03-09 |
| CN107774301B true CN107774301B (zh) | 2022-07-08 |
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| CN201710617072.4A Active CN107774301B (zh) | 2016-07-26 | 2017-07-26 | 用于C8芳族馏分的异构化的包含具有最优化Si/Al摩尔比的IZM-2沸石的催化剂 |
Country Status (6)
| Country | Link |
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| US (1) | US10183902B2 (enExample) |
| EP (1) | EP3275538B1 (enExample) |
| JP (1) | JP6955925B2 (enExample) |
| CN (1) | CN107774301B (enExample) |
| DK (1) | DK3275538T3 (enExample) |
| FR (1) | FR3054454B1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| FR3074428B1 (fr) * | 2017-12-06 | 2022-01-21 | Ifp Energies Now | Procede de preparation d'un catalyseur a base d'izm-2 a partir d'une solution comprenant des precurseurs specifiques et utilisation pour l'isomerisation de charges paraffiniques |
| FR3082521B1 (fr) * | 2018-06-15 | 2021-05-07 | Ifp Energies Now | Utilisation d'un catalyseur bifonctionnel a base d'izm-2 a rapport si/al specifique pour l'isomerisation de charges paraffiniques longues en distillats moyens |
| CN108993585B (zh) * | 2018-08-20 | 2021-04-02 | 中触媒新材料股份有限公司 | 一种含多级孔euo分子筛的双功能催化剂及其制备方法 |
| DE102019124731A1 (de) * | 2019-09-13 | 2021-03-18 | Clariant International Ltd | Verbessertes verfahren zur katalysierten hydroisomerisierung von kohlenwasserstoffen |
| FR3104458B1 (fr) * | 2019-12-17 | 2022-01-07 | Ifp Energies Now | Catalyseur a base de zeolithe izm-2 ayant une teneur en alcalin faible et son utilisation pour l’isomerisation de la coupe c8 aromatique |
| US11370980B2 (en) | 2020-07-31 | 2022-06-28 | Saudi Arabian Oil Company | Recycle catalytic reforming process to increase aromatics yield |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101687656A (zh) * | 2007-06-29 | 2010-03-31 | Ifp公司 | Lzm-2结晶固体及其制造方法 |
| CN102119123A (zh) * | 2008-08-08 | 2011-07-06 | Ifp新能源公司 | 包含izm-2沸石和至少一种金属的催化剂及其在烃转化中的用途 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2477903A1 (fr) | 1980-03-13 | 1981-09-18 | Inst Francais Du Petrole | Nouveau catalyseur zeolithique d'isomerisation des hydrocarbures alkylaromatiques |
| US4482773A (en) | 1982-02-25 | 1984-11-13 | Mobil Oil Corporation | Catalyst for xylene isomerization |
| US4467129A (en) | 1982-11-24 | 1984-08-21 | Toray Industries, Inc. | Conversion of xylenes containing ethylbenzene |
| FR2642414B1 (fr) | 1989-02-01 | 1991-04-26 | Rhone Poulenc Chimie | Procede de fabrication d'agglomeres d'alumine active, agglomeres obtenus par le procede et dispositif pour sa mise en oeuvre |
| US6440980B1 (en) | 1996-09-17 | 2002-08-27 | Avanir Pharmaceuticals | Synergistic inhibition of viral replication by long-chain hydrocarbons and nucleoside analogs |
| EP0923987A1 (fr) | 1997-12-22 | 1999-06-23 | Institut Français du Pétrole | Catalyseur contenant une zéolithe EUO et son utilisation en isomérisation des composés C8 aromatiques |
| EP1699556A2 (en) | 2003-12-30 | 2006-09-13 | Uop Llc | Process and catalyst for c8 alkylaromatic isomerization |
| CN102105225A (zh) | 2008-07-04 | 2011-06-22 | 国际壳牌研究有限公司 | 催化剂和异构化方法 |
| FR2969511B1 (fr) * | 2010-12-22 | 2012-12-28 | IFP Energies Nouvelles | Materiau spherique comprenant des nanoparticules metalliques piegees dans une matrice oxyde mesostructuree et son utilisation comme catalyseur dans les procedes du raffinage |
| FR2989382B1 (fr) * | 2012-04-11 | 2016-01-01 | IFP Energies Nouvelles | Procede de deparaffinage de charges hydrocarbonees utilisant un catalyseur a base de zeolithe izm-2 |
| US20140296601A1 (en) | 2013-03-29 | 2014-10-02 | Uop Llc | Isomerization process with mtw catalyst |
-
2016
- 2016-07-26 FR FR1657146A patent/FR3054454B1/fr active Active
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- 2017-07-24 JP JP2017142366A patent/JP6955925B2/ja active Active
- 2017-07-25 EP EP17305989.0A patent/EP3275538B1/fr active Active
- 2017-07-25 US US15/658,900 patent/US10183902B2/en active Active
- 2017-07-25 DK DK17305989.0T patent/DK3275538T3/da active
- 2017-07-26 CN CN201710617072.4A patent/CN107774301B/zh active Active
Patent Citations (2)
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|---|---|---|---|---|
| CN101687656A (zh) * | 2007-06-29 | 2010-03-31 | Ifp公司 | Lzm-2结晶固体及其制造方法 |
| CN102119123A (zh) * | 2008-08-08 | 2011-07-06 | Ifp新能源公司 | 包含izm-2沸石和至少一种金属的催化剂及其在烃转化中的用途 |
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| 分子筛孔结构和酸性对碳八芳烃异构化反应性能影响;徐会青等;《分子催化》;20120630(第03期);第252-256页 * |
Also Published As
| Publication number | Publication date |
|---|---|
| US20180029957A1 (en) | 2018-02-01 |
| EP3275538A1 (fr) | 2018-01-31 |
| FR3054454B1 (fr) | 2020-04-10 |
| JP2018030833A (ja) | 2018-03-01 |
| DK3275538T3 (da) | 2020-09-21 |
| US10183902B2 (en) | 2019-01-22 |
| JP6955925B2 (ja) | 2021-10-27 |
| FR3054454A1 (fr) | 2018-02-02 |
| CN107774301A (zh) | 2018-03-09 |
| EP3275538B1 (fr) | 2020-06-24 |
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