CN107772528B - A kind of temperature display Three-element composite filter core of changeable colour - Google Patents

A kind of temperature display Three-element composite filter core of changeable colour Download PDF

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Publication number
CN107772528B
CN107772528B CN201710948975.0A CN201710948975A CN107772528B CN 107772528 B CN107772528 B CN 107772528B CN 201710948975 A CN201710948975 A CN 201710948975A CN 107772528 B CN107772528 B CN 107772528B
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China
Prior art keywords
temperature
substance
color changing
quick
cigarette
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Application number
CN201710948975.0A
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CN107772528A (en
Inventor
岳保山
詹建波
程量
余振华
王涛
龚为民
张莹
王浩
丁海燕
桂永发
张静
王旭
李利伟
丁卫
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China Tobacco Yunnan Industrial Co Ltd
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China Tobacco Yunnan Industrial Co Ltd
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Priority to CN201710948975.0A priority Critical patent/CN107772528B/en
Publication of CN107772528A publication Critical patent/CN107772528A/en
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Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/02Manufacture of tobacco smoke filters
    • A24D3/0204Preliminary operations before the filter rod forming process, e.g. crimping, blooming
    • A24D3/0212Applying additives to filter materials
    • A24D3/0216Applying additives to filter materials the additive being in the form of capsules, beads or the like
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/062Use of materials for tobacco smoke filters characterised by structural features
    • A24D3/063Use of materials for tobacco smoke filters characterised by structural features of the fibers

Abstract

The present invention provides a kind of temperature display Three-element composite filter cores of changeable colour, it includes with the sequentially connected first vinegar fibre filter rod segments (1) of end to end system, hollow section (2) and the second vinegar fibre filter rod segments (3) containing cigarette with quick-fried pearl, wherein the cigarette has frangible shell with quick-fried pearl (4), flavors and fragrances substance is accommodated in shell, it is characterized in that, temperature induced color changing substance is added in aforementioned any one section, the discoloring temperature of the temperature induced color changing substance is equal to or higher than the hot volatilization temperature of the flavors and fragrances substance.The present invention intuitively shows flue-gas temperature by the discoloration of temperature induced color changing substance, and cigarette of crumbing accurately is grasped convenient for user with opportunity of quick-fried pearl, so that fragrance releasing effect is best.

Description

A kind of temperature display Three-element composite filter core of changeable colour
Technical field
The invention belongs to tobacco plug preparation technical fields, are related to a kind of temperature display Three-element composite filter core of changeable colour.
Background technique
People wish to make more improve to attract increasingly fastidious consumer on the basis of traditional point lit cigarettes always Concern.A kind of improve is to increase the functionality of traditional cigarette, such as be arranged in cigarette filter and accommodate by frangible shell The cigarette that flavors and fragrances substance is constituted is with quick-fried pearl, and when smoking, smoker crumbs the quick-fried pearl to release various specific tastes Fragrance enrich the odor type of traditional cigarette, and give the unique suction experience of smoker.
The country has carried out a large amount of developmental research with quick-fried pearl to cigarette, and CN201610564325.1 one kind can make up cigarette cigarette perfume And insufficient quick-fried pearl of moisture feeling and preparation method thereof, a kind of CN201611072960.4 cigarette patents pair such as quick-fried pearl and preparation method thereof Cigarette processes skill with quick-fried pearl, preparation method has carried out correlative study and improvement.CN201611114658.0 is a kind of macromolecule modified Cigarette quick-fried pearl lapping and preparation method thereof, the CN201611114616.7 a kind of quick-fried pearl rubber material of high weatherability cigarette and its A kind of quick-fried Zhu Guang of cigarette of preparation method, CN201610935665.0 is coated membrane material and pearly-lustre cigarette preparation method of quick-fried pearl etc. is special Benefit lays particular emphasis on the research of the lapping to quick-fried pearl, rubber material preparation method.Current patent all lays particular emphasis on the processing of quick-fried pearl Technique, rubber material, core material improvement etc., seldom pinch brokenly the time to quick-fried pearl from the heat exchange of quick-fried pearl, temperature change and quick-fried pearl Material or quick-fried pearl analog are researched and analysed.
During standard aspiration, with the burning of cigarette, away from flue-gas temperature at filter stick axis at pipe tobacco 5mm in rising Trend, maximum temperature are even up to 100 DEG C.In the actual aspiration procedure of consumer, due to draw volume, pipe tobacco burning quality Difference, the temperature of filter rod segments flue gas is also not quite similar.
But consumer, which usually holds, to be not allowed to crumb time point of the cigarette with quick-fried pearl, cigarette of crumbing too early when flue-gas temperature is too low use The volatilization temperature of flavors and fragrances substance is then not achieved in quick-fried pearl, influences flavouring effect;Cigarette is crumbed too late with quick-fried pearl, although can be true It protects flue-gas temperature and is higher than flavors and fragrances substance volatilization temperature, but remaining flue gas may be not enough to all wave all flavors and fragrancess Hair, influences the service efficiency of flavors and fragrances.
Therefore, how the temperature of institute's drawing smoke can be intuitively shown on cigarette, and carry out consumption guidance person accordingly and crumb cigarette Cigarette is significantly improved with the correct time point of quick-fried pearl utmostly to play quick-fried pearl filter stick volatilization efficiency and action time Aesthetic quality becomes a urgent problem to be solved.In addition, the cigarette of this energy displays temperature, because having unique function that can give The suction experience of user's uniqueness is given, and can be played in optimum time point and carry Studies of The Aromatic Substances, improves Sensory Quality of Cigarette.
Summary of the invention
The present invention then discloses a kind of temperature display Three-element composite filter core of changeable colour comprising is sequentially connected with end to end system The first vinegar fibre filter rod segments (1), containing the cigarette hollow section (2) and the second vinegar fibre filter rod segments (3) of quick-fried pearl, wherein the cigarette is with quick-fried Pearl (24) has frangible shell, accommodates flavors and fragrances substance in shell, which is characterized in that add in aforementioned any one section There is temperature induced color changing substance, the discoloring temperature of the temperature induced color changing substance is equal to or higher than the heat volatilization of the flavors and fragrances substance Temperature.
Preferably, the temperature induced color changing substance is added to containing cigarette in the hollow section (2) of quick-fried pearl.
Preferably, the temperature induced color changing substance is added in forming paper or the tipping paper for being wrapped in each section.
Preferably, the hot volatilization temperature of the flavors and fragrances substance is not less than the 80% of its boiling temperature.In general, when temperature When degree is higher than the 80% of its boiling temperature, flavors and fragrances substance begins to significantly volatilize and progress into main flume, uses Person can perceive, and when reaching boiling temperature or more, flavors and fragrances substance can largely volatilize, and continue into main flume.
Wherein, the selection of the temperature induced color changing substance, according to the specific boiling point of used flavors and fragrances substance and it is true It is fixed.For example, the flavors and fragrances substance is selected from Yunnan Special plant Yunnan olive extract, accordingly, the temperature induced color changing object Matter is selected from thermal discoloration type particle, and wherein temperature induced color changing substance is the mixture of the compositions such as crystal violet lactone and carboxylic-acid substance, It is green particles in low temperature, when temperature rises to 50-60 DEG C, particle is from green to colourless.
It is prepared in another example the flavors and fragrances substance is selected from the cool taste south Sinkiang ziziphora herb extract of Yunnan Special plant, Accordingly, the temperature induced color changing substance is selected from the reversible color substance of electron transfer type organic compound system preparation, such as halogen For the reversible color mixture system of the compositions such as alcohol, fusible higher aliphatic, crystal violet lactone, due to special chemical The organic chromophoric system of structure.At a certain temperature because electronics transfer makes the molecular structure of the organic matter change, thus real Existing color transition.This electrochromic substance is not only bright-colored, and may be implemented from " coloured===colourless " and " it is colourless== =coloured " color change of state.Reversible color particle is prepared using the substance, and passes through the transparent materials such as polypropylene material note Modeling, extrusion molding, compression molding show that bright-coloured degree, the dosage of electrochromic substance are the 0.2-1% of polypropylene material according to discoloration, become Color substance and polypropylene material will be sufficiently mixed uniformly, be prepared into filter stick discoloration firmware, and wrap up the discoloration using capsule wall material Firmware can't release harmful substance, and outer layer covers have quick-fried pearl outer wall since electrochromic substance is sealed by polypropylene material Class material will not have an impact cigarette smoke.
The structure of firmware can be set to hollow structure, facilitate firmware and flue gas heat exchange, improve color changeable effect.
Under normal circumstances, quick-fried pearl is placed in the closer vinegar fibre filter rod segments 3 of aspiration end, in order to preferably react mainstream Flue-gas temperature, firmware segments hollow structure can be divided into 2 sections or more, and each section of hollow structure perimeter can place identical discoloration object Matter or different electrochromic substances, larger compared with proximal segment firmware radius apart from quick-fried pearl, discoloration precision is more preferable, significantly more efficient can develop the color out The temperature change of main flume, to preferably determine crumbing the time for quick-fried pearl.
It is sealed additionally, due to electrochromic substance by polypropylene material, harmful substance can't be released, it will not be to cigarette cigarette Gas has an impact.
Preferably, the temperature induced color changing substance has the subregion knot of multiple discoloring temperatures or different discoloring temperature material compositions Structure, it is every to cross over its color change of generation of a discoloring temperature.
Preferably, the temperature induced color changing substance is sprayed in a patterned manner in forming paper or tipping paper.
Wherein, the tipping paper of that section of package containing the temperature induced color changing substance is transparent, in order to which consumer is straight Temperature induced color changing situation is observed in sight.
The utility model has the advantages that
(1) it is equal to or higher than the hot volatilization temperature of the flavors and fragrances substance in the present invention by using its discoloring temperature Temperature induced color changing substance also just reached perfume (or spice) of the cigarette in quick-fried pearl when flue-gas temperature is higher than when its discoloring temperature changes colour Smart fragrance material is capable of the temperature of significantly big calorimetric volatilization, and intuitively consumption guidance person crumbs the cigarette Perfect Time of quick-fried pearl for this Point.
(2) it is sprayed on filter stick formation paper or tipping paper in a patterned manner by temperature induced color changing substance, moreover it is possible to temperature occur Specific pattern is shown when mutagens color on filter stick, especially when using the temperature induced color changing substance with multiple discoloring temperatures, Pattern color can repeatedly change colour with smoke temperature change, this can give user's novelty and unique suction is experienced.
(3) electrochromic substance is mainly developed the color or is changed colour by temperature change, due to that by chemical reaction discoloration, will not generate Harmful components, and since electrochromic substance is sealed in firmware, adverse effect will not be generated to cigarette smoke.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the temperature display Three-element composite filter core of changeable colour of the invention.
Wherein, appended drawing reference meaning is as follows:
1, the first vinegar fibre filter rod segments;2, hollow section;3, the second vinegar fibre filter rod segments;4, cigarette is with quick-fried pearl;5, forming paper;6, it is hinged with Paper.
Specific embodiment
Embodiment 1
Three-element composite filter core is divided into the first vinegar fibre filter rod segments 1, hollow section 2, the second vinegar fibre filter rod segments 3, wherein in hollow section Containing cigarette with quick-fried pearl 4.Each section has respective forming paper 5, and three sections are shaped to tri compound filter with the package of tipping paper 6 on the whole Stick.The mode that 5mm+15mm+10mm can be used in Three-element composite filter core is compound.
In the embodiment, cigarette is Special plant extract Yunnan, Yunnan olive with the flavors and fragrances substance in quick-fried pearl, and heat is waved Sending out temperature is 65 DEG C, and the temperature induced color changing substance is selected from thermal discoloration type particle, is green particles when low temperature, when temperature rises to 50- 60 DEG C, particle is from green to colourless.Particle made of the temperature induced color changing substance is placed in the hollow firmware of filter stick.
When cigarette smoking, flue gas enters the hollow region of firmware, and firmware segments temperature increases, when flue-gas temperature reaches 50- At 60 degree, electrochromic substance is become colorless by green, and quick-fried pearl is crumbed at this time, and Special plant extract Yunnan, Yunnan olive enters mainstream It is rich to promote fragrance for flue gas.
Embodiment 2
The structure of Three-element composite filter core is same as Example 1, and it is cool that the flavors and fragrances substance is selected from Yunnan Special plant Taste south Sinkiang ziziphora herb extract is prepared, and accordingly, the temperature induced color changing substance is selected from electron transfer type organic compound system The reversible color substance of preparation, due to the organic chromophoric system with special chemical structure.At a certain temperature because of electronics transfer The molecular structure of the organic matter is set to change, to realize color transition.This electrochromic substance is not only bright-colored, Er Qieke To realize the color change from " coloured===colourless " and " colourless===coloured " state.Possibility of reversal is prepared using the substance Coloured particles, and by transparent materials injection moldings, extrusion molding, compression molding such as polypropylene materials, bright-coloured degree, discoloration are shown according to discoloration The dosage of substance is the 0.2-1% of polypropylene material, and electrochromic substance and polypropylene material will be sufficiently mixed uniformly, is prepared into filter stick Change colour firmware, and wraps up the discoloration firmware using capsule wall material, since electrochromic substance is sealed by polypropylene material, can't discharge Harmful substance out, and outer layer covers have quick-fried pearl outer wall class material, will not have an impact to cigarette smoke.The structure of firmware can be with It is set as hollow structure, facilitates firmware and flue gas heat exchange, improves color changeable effect.It is close by polypropylene material additionally, due to electrochromic substance Envelope, can't release harmful substance, will not have an impact to cigarette smoke.
In the embodiment, cigarette is prepared with the cool taste south Sinkiang ziziphora herb extract of flavors and fragrances substance Yunnan Special plant in quick-fried pearl It forms, hot volatilization temperature is 55 DEG C, and the temperature induced color changing substance is reversible color substance, is colourless granules when low temperature, works as temperature When degree rises to 55 DEG C or more, particle becomes red from colourless, becomes colorless again when lower than 55 DEG C.Made of the temperature induced color changing substance Particle is placed in the hollow firmware of filter stick.When cigarette smoking, flue gas enters the hollow region of firmware, and firmware segments temperature increases, When flue-gas temperature, which reaches 50-60, to be spent, electrochromic substance is become colorless by green.
The structure setting of firmware is hollow structure, facilitates firmware and flue gas heat exchange, improves color changeable effect, quick-fried pearl be placed in away from From in the closer vinegar fibre filter rod segments 3 of aspiration end, firmware segments hollow structure can be divided into 3 sections or more, and 3 segment structures can be placed identical Different electrochromic substances, it is larger compared with proximal segment firmware radius apart from quick-fried pearl, select discoloration electrochromic substance with better accuracy, can more added with The temperature change of the main flume out of developing the color of effect, to preferably determine crumbing the time for quick-fried pearl.When in third section electrochromic substance When hollow structure changes colour, quick-fried pearl is crumbed, Special plant extract Yunnan, Yunnan olive enters main flume, and it is rich to promote fragrance.
Since electrochromic substance is sealed by polypropylene material, harmful substance can't be released, cigarette smoke will not be produced It is raw to influence.
Embodiment 3
The structure of Three-element composite filter core is same as Example 1, and it is cool that the flavors and fragrances substance is selected from Yunnan Special plant Taste south Sinkiang ziziphora herb extract is prepared, and accordingly, the temperature induced color changing substance is made of colorless materials, color developing agent, sensitizer, And be sprayed in the forming paper for being wrapped in the second vinegar fibre filter rod segments 3, transparent window is offered here on external tipping paper, with convenient User observes temperature induced color changing situation.

Claims (7)

1. a kind of temperature display Three-element composite filter core of changeable colour, which is characterized in that it includes with end to end system sequentially connected One vinegar fibre filter rod segments (1), containing the cigarette hollow section (2) and the second vinegar fibre filter rod segments (3) of quick-fried pearl, wherein the cigarette is with quick-fried pearl (4) there is frangible shell, accommodate flavors and fragrances substance in shell, which is characterized in that be added in aforementioned any one section Temperature induced color changing substance, the discoloring temperature of the temperature induced color changing substance are equal to or higher than the heat volatilization temperature of the flavors and fragrances substance Degree;
The flavors and fragrances substance is Yunnan olive extract, and accordingly, the temperature induced color changing substance is crystal violet lactone and carboxylic The mixture of acid composition;Alternatively, the flavors and fragrances substance is cool taste south Sinkiang ziziphora herb extract, it is accordingly, described Temperature induced color changing substance is the reversible color mixture system of halohydrin, the pure and mild crystal violet lactone composition of fusible higher aliphatic.
2. the temperature display Three-element composite filter core of changeable colour according to claim 1, which is characterized in that the temperature induced color changing substance It is added to containing cigarette in the hollow section (2) of quick-fried pearl.
3. the temperature display Three-element composite filter core of changeable colour according to claim 1, which is characterized in that the temperature induced color changing substance It is added in forming paper or the tipping paper for being wrapped in each section.
4. the temperature display Three-element composite filter core of changeable colour according to claim 1, which is characterized in that the flavors and fragrances class object The hot volatilization temperature of matter is not less than the 80% of its boiling temperature.
5. the temperature display Three-element composite filter core of changeable colour according to claim 1, which is characterized in that the temperature induced color changing substance It is every to cross over its color change of generation of a discoloring temperature with multiple discoloring temperatures.
6. the temperature display Three-element composite filter core of changeable colour according to claim 3, which is characterized in that the temperature induced color changing substance It is sprayed in forming paper or tipping paper in a patterned manner.
7. the temperature display Three-element composite filter core of changeable colour according to claim 1, which is characterized in that package is caused containing the temperature The tipping paper of that section of electrochromic substance is transparent.
CN201710948975.0A 2017-10-12 2017-10-12 A kind of temperature display Three-element composite filter core of changeable colour Active CN107772528B (en)

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CN108045118B (en) * 2017-12-06 2020-04-10 浙江荣丰纸业有限公司 Transparent cigarette tipping paper and production process thereof
CN108760065B (en) * 2018-05-29 2021-03-12 中国烟草总公司郑州烟草研究院 Cigarette smoking depth detection method and device based on temperature
CN109223297A (en) * 2018-08-02 2019-01-18 江西润丰药业有限公司 The discoloration of temperature-sensitive three-level is medical defervescence plaster used and preparation method thereof
CN109105954A (en) * 2018-09-27 2019-01-01 上海烟草集团有限责任公司 A kind of temperature discoloration cigarette filter
CN109497617A (en) * 2018-11-14 2019-03-22 云南中烟工业有限责任公司 A kind of heating with instruction function is not burnt Cigarette
CN109603777B (en) * 2018-12-29 2021-11-05 中国烟草总公司郑州烟草研究院 Temperature response type color-changing adsorbing material for cigarettes, preparation method of material and cigarette filter
CN109692670A (en) * 2018-12-29 2019-04-30 中国烟草总公司郑州烟草研究院 A kind of temperature response type cigarette filter functional material and preparation method thereof, cigarette filter
CN112021656A (en) * 2020-07-28 2020-12-04 武汉达汇新科技有限公司 Filter material, filter, and smoking set
CN115449432B (en) * 2022-09-22 2023-06-02 云南中烟工业有限责任公司 Color-changeable spice, preparation method and application thereof
CN116268561A (en) * 2023-02-17 2023-06-23 湖北中烟工业有限责任公司 Multi-temperature-zone reversible thermochromic window filter rod firmware and preparation method thereof

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