CN107772528A - A kind of temperature display Three-element composite filter core of changeable colour - Google Patents

A kind of temperature display Three-element composite filter core of changeable colour Download PDF

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Publication number
CN107772528A
CN107772528A CN201710948975.0A CN201710948975A CN107772528A CN 107772528 A CN107772528 A CN 107772528A CN 201710948975 A CN201710948975 A CN 201710948975A CN 107772528 A CN107772528 A CN 107772528A
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CN
China
Prior art keywords
temperature
color changing
quick
filter core
cigarette
Prior art date
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Granted
Application number
CN201710948975.0A
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Chinese (zh)
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CN107772528B (en
Inventor
岳保山
詹建波
程量
余振华
王涛
龚为民
张莹
王浩
丁海燕
桂永发
张静
王旭
李利伟
丁卫
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China Tobacco Yunnan Industrial Co Ltd
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China Tobacco Yunnan Industrial Co Ltd
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Priority to CN201710948975.0A priority Critical patent/CN107772528B/en
Publication of CN107772528A publication Critical patent/CN107772528A/en
Application granted granted Critical
Publication of CN107772528B publication Critical patent/CN107772528B/en
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Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/02Manufacture of tobacco smoke filters
    • A24D3/0204Preliminary operations before the filter rod forming process, e.g. crimping, blooming
    • A24D3/0212Applying additives to filter materials
    • A24D3/0216Applying additives to filter materials the additive being in the form of capsules, beads or the like
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/062Use of materials for tobacco smoke filters characterised by structural features
    • A24D3/063Use of materials for tobacco smoke filters characterised by structural features of the fibers

Abstract

The invention provides a kind of temperature display Three-element composite filter core of changeable colour, its first vinegar fibre filter rod segments (1) for including being sequentially connected with end to end system, hollow section (2) and the second vinegar fibre filter rod segments (3) containing cigarette with quick-fried pearl, wherein described cigarette has frangible shell with quick-fried pearl (4), essence and flavoring agent class material is accommodated in shell, it is characterized in that, temperature induced color changing material is added with foregoing any one section, the discoloring temperature of the temperature induced color changing material is equal to or higher than the hot volatilization temperature of the essence and flavoring agent class material.The present invention intuitively shows flue-gas temperature by the discoloration of temperature induced color changing material, is easy to user accurately to grasp opportunity of the cigarette with quick-fried pearl of crumbing, to cause fragrance releasing effect optimal.

Description

A kind of temperature display Three-element composite filter core of changeable colour
Technical field
The invention belongs to tobacco plug preparing technical field, it is related to a kind of temperature display Three-element composite filter core of changeable colour.
Background technology
People wish to make more improve to attract increasingly fastidious consumer on the basis of traditional point lit cigarettes always Concern.A kind of improve is the feature for increasing traditional cigarette, such as sets in cigarette filter and accommodate by frangible shell The cigarette that essence and flavoring agent class material is formed is with quick-fried pearl, and when smoking, smoker crumbs the quick-fried pearl so as to discharge various specific tastes Fragrance enrich the odor type of traditional cigarette, and give the unique suction experience of smoker.
The country has carried out substantial amounts of developmental research to cigarette with quick-fried pearl, and CN201610564325.1 one kind can make up cigarette cigarette perfume And quick-fried pearl of moisture feeling deficiency and preparation method thereof, a kind of CN201611072960.4 cigarette patents pair such as quick-fried pearl and preparation method thereof Cigarette processes skill with quick-fried pearl, preparation method has carried out correlative study and improvement.CN201611114658.0 is a kind of macromolecule modified A kind of high weather resisteant cigarette of cigarette quick-fried pearl lapping and preparation method thereof, CN201611114616.7 with quick-fried pearl rubber material and its A kind of quick-fried Zhu Guang of cigarette of preparation method, CN201610935665.0 is coated membrane material and pearly-lustre cigarette preparation method of quick-fried pearl etc. is special Profit lays particular emphasis on the research of the lapping to quick-fried pearl, rubber material preparation method.Current patent all lays particular emphasis on the processing of quick-fried pearl Technique, rubber material, core improvement etc., seldom pinch brokenly the time to quick-fried pearl from the heat exchange of quick-fried pearl, temperature change and quick-fried pearl Material or quick-fried pearl analog are researched and analysed.
During standard aspiration, with the burning of cigarette, away from flue-gas temperature at filter stick axis at pipe tobacco 5mm in rising Trend, maximum temperature are even up to 100 DEG C.In the actual aspiration procedure of consumer, due to draw volume, pipe tobacco burning quality Difference, the temperature of filter rod segments flue gas is also not quite similar.
But consumer, which usually holds, is forbidden time point of the cigarette with quick-fried pearl of crumbing, cigarette of being crumbed too early when flue-gas temperature is too low is used Quick-fried pearl, then do not reach the volatilization temperature of essence and flavoring agent material, influence flavouring effect;Cigarette is crumbed too late with quick-fried pearl, although can be true Protect flue-gas temperature and be higher than essence and flavoring agent material volatilization temperature, but remaining flue gas may be not enough to all wave all essence and flavoring agents Hair, influence the service efficiency of essence and flavoring agent.
Therefore, how the temperature of institute's drawing smoke can be intuitively shown on cigarette, and carrys out consumption guidance person accordingly and crumb cigarette With the correct time point of quick-fried pearl, at utmost to play quick-fried pearl filter stick volatilization efficiency and action time, cigarette is significantly improved Aesthetic quality, turn into a urgent problem to be solved.In addition, the cigarette of this energy displays temperature, because that can be given with unique function The unique suction experience of user is given, and can be played in optimum time point and carry Studies of The Aromatic Substances, improves Sensory Quality of Cigarette.
The content of the invention
Temperature display Three-element composite filter core that is of the invention then disclosing a kind of changeable colour, it includes being sequentially connected with end to end system The first vinegar fibre filter rod segments (1), hollow section (2) and the second vinegar fibre filter rod segments (3) containing cigarette with quick-fried pearl, wherein the cigarette is with quick-fried Pearl (24) has frangible shell, and essence and flavoring agent class material is accommodated in shell, it is characterised in that is added in foregoing any one section There is temperature induced color changing material, the discoloring temperature of the temperature induced color changing material is equal to or higher than the heat volatilization of the essence and flavoring agent class material Temperature.
Preferably, the temperature induced color changing material is added to containing cigarette with the hollow section (2) of quick-fried pearl.
Preferably, the temperature induced color changing material is added in forming paper or the tipping paper for being wrapped in each section.
Preferably, the hot volatilization temperature of the essence and flavoring agent class material is not less than the 80% of its boiling temperature.Generally, temperature is worked as When degree is higher than the 80% of its boiling temperature, essence and flavoring agent class material begins to significantly volatilize and progress into main flume, uses Person can perceive, and when reaching more than boiling temperature, essence and flavoring agent class material can largely volatilize, and continue into main flume.
Wherein, the selection of the temperature induced color changing material, the specific boiling point of essence and flavoring agent class material according to used in and it is true It is fixed.For example, the essence and flavoring agent class material is selected from Special plant Yunnan, Yunnan olive extract, accordingly, the temperature induced color changing thing Matter is selected from thermal discoloration type particle, and wherein temperature induced color changing material is the mixture of the compositions such as crystal violet lactone and carboxylic-acid substance, its It is green particles in low temperature, when temperature rises to 50-60 DEG C, particle is from green to colourless.
In another example the essence and flavoring agent class material is prepared selected from the cool taste south Sinkiang ziziphora herb extract of Yunnan Special plant, Accordingly, the temperature induced color changing material is selected from reversible color material prepared by electron transfer type organic compound system, such as halogen For the reversible color mixture system of the compositions such as alcohol, fusible higher aliphatic, crystal violet lactone, due to special chemical The organic chromophoric system of structure.At a certain temperature because electronics transfer makes the molecular structure of the organic matter change, so as to real Existing color transition.This electrochromic substance is not only bright-colored, and can realize from " coloured===colourless " and " it is colourless== =coloured " color change of state.Reversible color particle is prepared using the material, and is noted by transparent materials such as polypropylene materials Modeling, extrusion molding, compression molding, bright-coloured degree is shown according to discoloration, the dosage of electrochromic substance is the 0.2-1% of polypropylene material, is become Color substance will be sufficiently mixed uniformly with polypropylene material, be prepared into filter stick discoloration firmware, and wrap up the discoloration using capsule wall material Firmware, because electrochromic substance is sealed by polypropylene material, harmful substance can't be discharged, and outer layer covers have quick-fried pearl outer wall Class material, cigarette smoke will not be had an impact.
The structure of firmware could be arranged to hollow structure, facilitate firmware and flue gas heat exchange, improve color changeable effect.
Generally, quick-fried pearl is positioned in the vinegar fibre filter rod segments 3 nearer apart from aspiration end, in order to preferably react main flow Flue-gas temperature, firmware segments hollow structure can be divided into more than 2 sections, and each section of hollow structure perimeter can place identical discoloration thing Matter or different electrochromic substances, larger compared with proximal segment firmware radius apart from quick-fried pearl, discoloration precision is more preferable, can develop the color with significantly more efficient The temperature change of main flume, so as to preferably determine crumbing the time for quick-fried pearl.
Sealed additionally, due to electrochromic substance by polypropylene material, harmful substance can't be discharged, also will not be to cigarette cigarette Gas has an impact.
Preferably, the temperature induced color changing material has multiple discoloring temperatures or the subregion knot of different discoloring temperature material compositions Structure, often across discoloring temperature, a color change occurs in it.
Preferably, the temperature induced color changing material is sprayed in forming paper or tipping paper in a patterned manner.
Wherein, the tipping paper of that section of parcel containing the temperature induced color changing material is transparent, in order to which consumer is straight Observe temperature induced color changing situation.
Beneficial effect:
(1) it is equal to or higher than the hot volatilization temperature of the essence and flavoring agent class material in the present invention by using its discoloring temperature Temperature induced color changing material, when flue-gas temperature changes colour higher than its discoloring temperature, also just reached perfume (or spice) of the cigarette in quick-fried pearl Smart fragrance material is capable of the temperature of significantly big calorimetric volatilization, and intuitively consumption guidance person crumbs Perfect Time of the cigarette with quick-fried pearl for this Point.
(2) it is sprayed in a patterned manner on filter stick formation paper or tipping paper by temperature induced color changing material, moreover it is possible to temperature is occurring Specific pattern is shown during mutagens color on filter stick, especially when using the temperature induced color changing material with multiple discoloring temperatures, Pattern color can repeatedly change colour with smoke temperature change, and this can give the novel and unique suction experience of user.
(3) electrochromic substance is mainly developed the color or changed colour by temperature change, due to not changed colour by chemically reacting, will not be generated Harmful components, and because electrochromic substance is sealed in firmware, harmful effect will not be produced to cigarette smoke.
Brief description of the drawings
Fig. 1 is the structural representation of the temperature display Three-element composite filter core of the changeable colour of the present invention.
Wherein, reference implication is as follows:
1st, the first vinegar fibre filter rod segments;2nd, hollow section;3rd, the second vinegar fibre filter rod segments;4th, cigarette is with quick-fried pearl;5th, forming paper;6th, it is hinged with Paper.
Embodiment
Embodiment 1
Three-element composite filter core is divided into the first vinegar fibre filter rod segments 1, hollow section 2, the second vinegar fibre filter rod segments 3, wherein in hollow section Containing cigarette with quick-fried pearl 4.Each section has respective forming paper 5, and three sections are shaped to tri compound with the parcel of tipping paper 6 on the whole and filter Rod.Three-element composite filter core can be compound by the way of 5mm+15mm+10mm.
In the embodiment, cigarette is Special plant extract Yunnan, Yunnan olive with the essence and flavoring agent material in quick-fried pearl, and its heat is waved It is 65 DEG C to send out temperature, and the temperature induced color changing material is selected from thermal discoloration type particle, is green particles during low temperature, when temperature rises to 50- 60 DEG C, particle is from green to colourless.Particle made of the temperature induced color changing material is positioned in the hollow firmware of filter stick.
When cigarette smoking, flue gas enters the hollow region of firmware, firmware segments temperature rise, when flue-gas temperature reaches 50- At 60 degree, electrochromic substance is become colorless by green, and now quick-fried pearl is crumbed, and Special plant extract Yunnan, Yunnan olive enters main flow Flue gas, lifting fragrance are rich.
Embodiment 2
The structure of Three-element composite filter core is same as Example 1, and it is cool that the essence and flavoring agent class material is selected from Yunnan Special plant Taste south Sinkiang ziziphora herb extract is prepared, and accordingly, the temperature induced color changing material is selected from electron transfer type organic compound system The reversible color material of preparation, due to the organic chromophoric system with special chemical structure.At a certain temperature because electronics shifts The molecular structure of the organic matter is set to change, so as to realize color transition.This electrochromic substance is not only bright-colored, Er Qieke To realize the color change from " coloured===colourless " and " colourless===coloured " state.Possibility of reversal is prepared using the material Coloured particles, and by the injection of the transparent materials such as polypropylene material, extrusion molding, compression molding, bright-coloured degree, discoloration are shown according to discoloration The dosage of material is the 0.2-1% of polypropylene material, and electrochromic substance will be sufficiently mixed uniformly with polypropylene material, be prepared into filter stick Change colour firmware, and wraps up the discoloration firmware using capsule wall material, because electrochromic substance is sealed by polypropylene material, can't discharge Go out harmful substance, and outer layer covers have quick-fried pearl outer wall class material, and cigarette smoke will not be had an impact.The structure of firmware can be with Hollow structure is arranged to, facilitates firmware and flue gas heat exchange, improves color changeable effect.It is close by polypropylene material additionally, due to electrochromic substance Envelope, can't discharge harmful substance, also cigarette smoke will not be had an impact.
In the embodiment, cigarette is prepared with the cool taste south Sinkiang ziziphora herb extract of essence and flavoring agent material Yunnan Special plant in quick-fried pearl Form, its hot volatilization temperature is 55 DEG C, and the temperature induced color changing material is reversible color material, is colourless granules during low temperature, works as temperature For degree when rising to more than 55 DEG C, particle is changed into red from colourless, becomes colorless again during less than 55 DEG C.Made of the temperature induced color changing material Particle is positioned in the hollow firmware of filter stick.When cigarette smoking, flue gas enters the hollow region of firmware, and firmware segments temperature raises, When flue-gas temperature, which reaches 50-60, to be spent, electrochromic substance is become colorless by green.
The structure setting of firmware is hollow structure, facilitates firmware and flue gas heat exchange, improves color changeable effect, quick-fried pearl be positioned over away from In the vinegar fibre filter rod segments 3 nearer from aspiration end, firmware segments hollow structure can be divided into more than 3 sections, and 3 segment structures can be placed identical Different electrochromic substances, it is larger compared with proximal segment firmware radius apart from quick-fried pearl, from discoloration the more preferable electrochromic substance of precision, can more added with The temperature change of the main flume that develops the color of effect, so as to preferably determine crumbing the time for quick-fried pearl.When in the 3rd section of electrochromic substance When hollow structure changes colour, quick-fried pearl is crumbed, Special plant extract Yunnan, Yunnan olive enters main flume, and lifting fragrance is rich.
Because electrochromic substance is sealed by polypropylene material, harmful substance can't be discharged, cigarette smoke will not also be produced It is raw to influence.
Embodiment 3
The structure of Three-element composite filter core is same as Example 1, and it is cool that the essence and flavoring agent class material is selected from Yunnan Special plant Taste south Sinkiang ziziphora herb extract is prepared, and accordingly, the temperature induced color changing material is made up of colorless materials, developer, sensitizer, And be sprayed on and be wrapped in the forming paper of the second vinegar fibre filter rod segments 3, transparent window is offered here on outside tipping paper, with convenient User observes temperature induced color changing situation.

Claims (8)

1. the temperature display Three-element composite filter core of a kind of changeable colour, it is characterised in that it includes be sequentially connected with end to end system One vinegar fibre filter rod segments (1), hollow section (2) and the second vinegar fibre filter rod segments (3) containing cigarette with quick-fried pearl, wherein the cigarette is with quick-fried pearl (4) there is frangible shell, essence and flavoring agent class material is accommodated in shell, it is characterised in that be added with foregoing any one section Temperature induced color changing material, the discoloring temperature of the temperature induced color changing material are equal to or higher than the heat volatilization temperature of the essence and flavoring agent class material Degree.
2. the temperature display Three-element composite filter core of changeable colour according to claim 1, it is characterised in that the temperature induced color changing material It is added to containing cigarette with the hollow section (2) of quick-fried pearl.
3. the temperature display Three-element composite filter core of changeable colour according to claim 1, it is characterised in that the temperature induced color changing material It is added in forming paper or the tipping paper for being wrapped in each section.
4. the temperature display Three-element composite filter core of changeable colour according to claim 1, it is characterised in that the essence and flavoring agent class thing The hot volatilization temperature of matter is not less than the 80% of its boiling temperature.
5. the temperature display Three-element composite filter core of changeable colour according to claim 1, it is characterised in that the essence and flavoring agent class thing Matter is Yunnan olive extract, and accordingly, the temperature induced color changing material is the mixing of the compositions such as crystal violet lactone and carboxylic-acid substance Thing;Or the essence and flavoring agent class material is cool taste south Sinkiang ziziphora herb extract, accordingly, the temperature induced color changing material is halo The reversible color mixture system of alcohol, fusible higher aliphatic and crystal violet lactone composition.
6. the temperature display Three-element composite filter core of changeable colour according to claim 1, it is characterised in that the temperature induced color changing material With multiple discoloring temperatures, often across discoloring temperature, a color change occurs in it.
7. the temperature display Three-element composite filter core of changeable colour according to claim 3, it is characterised in that the temperature induced color changing material Sprayed in a patterned manner in forming paper or tipping paper.
8. the temperature display Three-element composite filter core of changeable colour according to claim 1, it is characterised in that parcel causes containing the temperature The tipping paper of that section of electrochromic substance is transparent.
CN201710948975.0A 2017-10-12 2017-10-12 A kind of temperature display Three-element composite filter core of changeable colour Active CN107772528B (en)

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CN108045118A (en) * 2017-12-06 2018-05-18 浙江荣丰纸业有限公司 Transparent cigarette tipping paper and its production technology
CN108760065A (en) * 2018-05-29 2018-11-06 中国烟草总公司郑州烟草研究院 A kind of cigarette based on temperature suction depth detection method and device
CN109105954A (en) * 2018-09-27 2019-01-01 上海烟草集团有限责任公司 A kind of temperature discoloration cigarette filter
CN109223297A (en) * 2018-08-02 2019-01-18 江西润丰药业有限公司 The discoloration of temperature-sensitive three-level is medical defervescence plaster used and preparation method thereof
CN109497617A (en) * 2018-11-14 2019-03-22 云南中烟工业有限责任公司 A kind of heating with instruction function is not burnt Cigarette
CN109603777A (en) * 2018-12-29 2019-04-12 中国烟草总公司郑州烟草研究院 A kind of temperature response type cigarette discoloration adsorbent material and preparation method thereof, cigarette filter
CN109692670A (en) * 2018-12-29 2019-04-30 中国烟草总公司郑州烟草研究院 A kind of temperature response type cigarette filter functional material and preparation method thereof, cigarette filter
CN112021656A (en) * 2020-07-28 2020-12-04 武汉达汇新科技有限公司 Filter material, filter, and smoking set
CN115449432B (en) * 2022-09-22 2023-06-02 云南中烟工业有限责任公司 Color-changeable spice, preparation method and application thereof
CN116268561A (en) * 2023-02-17 2023-06-23 湖北中烟工业有限责任公司 Multi-temperature-zone reversible thermochromic window filter rod firmware and preparation method thereof

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Cited By (11)

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Publication number Priority date Publication date Assignee Title
CN108045118A (en) * 2017-12-06 2018-05-18 浙江荣丰纸业有限公司 Transparent cigarette tipping paper and its production technology
CN108760065A (en) * 2018-05-29 2018-11-06 中国烟草总公司郑州烟草研究院 A kind of cigarette based on temperature suction depth detection method and device
CN109223297A (en) * 2018-08-02 2019-01-18 江西润丰药业有限公司 The discoloration of temperature-sensitive three-level is medical defervescence plaster used and preparation method thereof
CN109105954A (en) * 2018-09-27 2019-01-01 上海烟草集团有限责任公司 A kind of temperature discoloration cigarette filter
CN109497617A (en) * 2018-11-14 2019-03-22 云南中烟工业有限责任公司 A kind of heating with instruction function is not burnt Cigarette
CN109603777A (en) * 2018-12-29 2019-04-12 中国烟草总公司郑州烟草研究院 A kind of temperature response type cigarette discoloration adsorbent material and preparation method thereof, cigarette filter
CN109692670A (en) * 2018-12-29 2019-04-30 中国烟草总公司郑州烟草研究院 A kind of temperature response type cigarette filter functional material and preparation method thereof, cigarette filter
CN109603777B (en) * 2018-12-29 2021-11-05 中国烟草总公司郑州烟草研究院 Temperature response type color-changing adsorbing material for cigarettes, preparation method of material and cigarette filter
CN112021656A (en) * 2020-07-28 2020-12-04 武汉达汇新科技有限公司 Filter material, filter, and smoking set
CN115449432B (en) * 2022-09-22 2023-06-02 云南中烟工业有限责任公司 Color-changeable spice, preparation method and application thereof
CN116268561A (en) * 2023-02-17 2023-06-23 湖北中烟工业有限责任公司 Multi-temperature-zone reversible thermochromic window filter rod firmware and preparation method thereof

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