CN107761963B

CN107761963B - Concrete structure assembled architecture system and its assembly method

Info

Publication number: CN107761963B
Application number: CN201711047509.1A
Authority: CN
Inventors: 黄聿新
Original assignee: Guangxi Xu Teng Industry Group Co Ltd
Current assignee: Guangxi Xu Teng Industry Group Co Ltd
Priority date: 2017-10-31
Filing date: 2017-10-31
Publication date: 2018-11-02
Anticipated expiration: 2037-10-31
Also published as: CN107761963A

Abstract

The present invention provides a kind of concrete structure novel fabricated building system, if including prefabricated foundation, structural support frame, precast floor slab and drywall panel；Structural support frame includes concrete prefabricated reinforcing prop and precast beam, and concrete prefabricated reinforcing prop is connect with prefabricated foundation；Precast beam includes concrete girder and plug connector, and concrete girder is connect with concrete prefabricated reinforcing prop；Plug connector is connect with concrete girder, and precast floor slab is connect with concrete girder；Using anchoring steel structure connection wallboard and concrete prefabricated reinforcing prop；Wallboard is equipped with plug division, plug division and plug connector grafting, and cast-in-place fixation.Wallboard is to have many advantages, such as excellent anticorrosive, insulation, fire prevention, waterproof, impervious, antidetonation, cracking resistance, high-strength light based on graphene and nonmetallic foamed wall slab.The fabricated construction mode that this building system uses can shorten the construction period, and safe and efficient.The present invention also provides a kind of assembly methods of concrete structure novel fabricated building system.

Description

Concrete structure assembled architecture system and its assembly method

【Technical field】

The present invention relates to technical field of buildings, more particularly to a kind of concrete structure assembled architecture system and its assembly side Method.

【Background technology】

Traditional building uses cast-in-place concrete floor, and wall is using conventional concrete aerated blocks, shale porous brick, common brick When, it needs wet method sporadicly to construct, two-sided batch time levelling, exterior wall is needed to need to carry out water-proof heat insulation construction etc., assembly rate pole It is low；Using blockwork, external wall plastering or tiling, to play waterproof thermal-insulated cold-proof purpose, but heat insulation effect is undesirable, every Sound is heat-insulated, fire-proof high-temperature resistant, water proof anti-seepage, corrosion-resistant antiageing effect are poor, does not have high-strength light, heat preserving heat insulating noise insulation, anti- Fiery high temperature resistant, water proof anti-seepage, antidetonation, it is anticorrosive it is anti-aging, the superior functions such as do not crack, with conventional concrete aerated blocks, shale Porous brick compared to not can solve building sound-insulating and heat-insulating heat preservation, water proof anti-seepage, antidetonation, do not crack a series of problems, such as, And work progress needs a large amount of exterior wall scaffolds, construction is complicated, and construction speed is slow, and labor intensive amount is big, needs the fragmentary operation of wet method, The building waste generated of constructing is more.It can be improved using assembled architecture and shorten the construction period, save architectural engineering construction cost, Construction assembly rate is set slightly to improve.However the assembled architecture of the prior art, prefabricated panel are used with steel construction girder The modes such as cast-in-place concrete or prefabricated latch are attached, and are applied using what cast-in-site operation, wet method were sporadicly constructed Work mode causes that difficulty of construction is big, the big construction quality long in time limit, completing of quantities cannot ensure, junction intensity compared with Low, the assembly rate of assembled architecture is relatively low, and the quality and quake-resistant safety performance of building are low；It is attached using prefabricated latch, Need simultaneously be opened up on wallboard and girder with bolted screw hole, it is more demanding to installation accuracy, improve assembled and build The construction cost built, meanwhile, be attached using prefabricated latch, need scene open up link slot, nailing, drilling, installation it is multiple Bolt etc., installation speed are slower.In addition, seldom finding the connection side of reinforcing prop and wallboard in current assembled architecture Formula, and the connection type of reinforcing prop and wallboard can also influence assembled architecture anti-seismic performance.

【Invention content】

In view of the above problems, it is necessary to which the construction period can be shortened by providing one kind, reduce the coagulation of building cost Soil structure assembled architecture system.

In order to achieve the above objectives, the technical solution adopted in the present invention is：

A kind of concrete structure assembled architecture system, including prefabricated foundation, structural support frame, at least a precast floor slab And if drywall panel, the prefabricated foundation include pedestal and the concrete structure column on the pedestal, the structural support frame Frame includes concrete prefabricated reinforcing prop and precast beam, and the concrete prefabricated reinforcing prop is solid using bonding agent with concrete structure column The peripheral wall of fixed connection, the concrete prefabricated reinforcing prop is equipped with several anchoring steel structures；The precast beam includes concrete girder And plug connector, the concrete girder are connect with the concrete prefabricated reinforcing prop by prefabricated fixing piece and/or bonding agent, institute Plug connector is stated to connect with the wherein one side of the concrete girder；The precast floor slab is supported in the concrete girder backwards On the side of the plug connector, and it is attached by bonding agent and/or prefabricated connector with the concrete girder, it is adjacent Two blocks of wallboards mutually splice or are bonded, and the wallboard adjacent with the concrete prefabricated reinforcing prop is equipped with bar planting hole, described Anchoring steel structure is anchored in the bar planting hole, to connect the wallboard and the concrete prefabricated reinforcing prop；The wallboard direction The side of the precast beam is equipped with plug division, the plug division and the plug connector grafting, and is fixed using bonding agent.

Further, the wallboard is based on graphene and stone material foamed wall slab, based on graphene and nonmetallic tail Mine foamed wall slab and one or more based on graphene Yu stone material tailing foamed light high temperature resistant wallboard, wherein described In percentage by weight based on graphene and stone material foamed wall slab, including stone material tailing 45-90%, high temperature cosolvent 0.05-10%, graphene 0.05-15%, expanded graphite 0.05-5%, zirconium oxide 1-20%, calcium carbonate 0.05-10%, clay 1-10%, stabilizer 0.05-5%, degumming agent 0.05-5%, inorganic color 0.05-5%；It is described based on graphene with it is nonmetallic Tailing foamed wall slab in percentage by weight, including nonmetallic tailings 55-75%, graphene 0.05-15%, vermiculite 1- 15%, high temperature cosolvent 0.05-15%, high-temperature fibre 5-20%, foaming agent 0.05-5%, zirconium oxide 1-20%, clay 1- 10%, stabilizer 0.05-5%, degumming agent 0.05-5%；It is described to be based on graphene and stone material tailing foamed light high temperature resistant wallboard In percentage by weight, including stone material tailing 40%-65%, graphene 0.05%-15%, aluminium oxide 1%-30%, vermiculite 1-15%, calcium carbonate 0.05%-10%, high temperature cosolvent 0.05%-15%, high-temperature fibre particle 5-30%, foaming agent 0.05%-5%, stabilizer 0.05%-5%, degumming agent 0.05%-5%, clay 1%-10%, the additional 0%-5% of colorant.

Further, the concrete structure column is equipped with several first rebar connectors backwards to one end of the pedestal, The end face of the concrete prefabricated reinforcing prop towards the prefabricated foundation is equipped with several second rebar connectors；Several first Rebar connector and several second rebar connectors are spaced apart in the concrete structure column and the concrete prefabricated reinforcement Between column, in the live formwork in the periphery of the first rebar connector and the second rebar connector, then in such a way that bonding agent is cast-in-place It is fixed.

Further, the precast floor slab by prefabricated component and/or is glued with the wallboard above the precast floor slab Connect agent connection.

Further, the wallboard includes several Side fascias and several linings, and several Side fascias surround one jointly Accommodation space, the Side fascia adjacent with the concrete prefabricated reinforcing prop by the anchoring steel structure with it is described it is concrete prefabricated plus Strong column connection, several linings are set in the accommodation space, and adjacent two pieces of linings mutually splice to form interior wall, with The adjacent lining of the concrete prefabricated reinforcing prop is connect by the anchoring steel structure with the concrete prefabricated reinforcing prop, institute It states and is equipped with the plug division at the top of the top and the lining of Side fascia.

Further, the Side fascia is additionally provided with water-proof precast product backwards to the side of the accommodation space, and the waterproof is pre- Product includes the first joint face, the second joint face and third joint face, and first joint face is opposite with second joint face Setting, the third joint face connect first joint face and the second joint face, and the third joint face is towards the appearance Receive space, first joint face and second joint face are fixed with adjacent two layers Side fascia by bonding agent respectively, described Third joint face is fixed with the precast floor slab and the precast beam by bonding agent.

Further, first joint face is inclined-plane, and first connection faces away from the direction of the accommodation space It is gradually tilted to the prefabricated foundation, the Side fascia being connect with first joint face is equipped with to be coordinated with first joint face The first inclined-plane, first inclined-plane is fixed with first joint face by bonding agent.

Further, second joint face includes support portion and rake, and the support portion is supported in corresponding exterior wall It is fixed by bonding agent on plate and with corresponding Side fascia, the rake is connected to the rake farthest away from receiving sky Between side, the rake towards far from the accommodation space direction gradually to the prefabricated foundation tilt, with described second The Side fascia of joint face connection is equipped with the second inclined-plane coordinated with the rake, and second inclined-plane is logical with the rake Bonding agent is crossed to fix.

Further, it is further opened with window mounting hole on the Side fascia, surrounds projection on the side wall of the window mounting hole One waterproof boss and recessed installing slot, fix that a stainless steel is flat to be led in the installing slot, the concrete structure assembled Building system further includes window, and the window includes installation outline border, and the installation outline border is flat logical and described anti-with the stainless steel Water boss connects.

Further, each Side fascia includes two blocks of sub- wallboards, and two blocks of sub- wallboards are bonded in along the thickness direction of a wall Together to form the Side fascia, each lining includes one block of sub- wallboard, adjacent with the concrete prefabricated reinforcing prop The sub- wallboard in be equipped with several bar planting holes.

The present invention also provides the assembly methods of above-mentioned concrete structure assembled architecture system, include the following steps：

It is laid with prefabricated foundation；

The concrete structure column of one end of concrete prefabricated reinforcing prop and prefabricated foundation is attached by bonding agent；

The concrete girder of precast beam and the concrete prefabricated reinforcing prop are connected by bonding agent and/or prefabricated fixing piece It connects；

Adjacent two blocks of wallboards are mutually spliced or are bonded, anchoring steel structure is plugged in the bar planting hole of wallboard, bonding agent is used The gap in bar planting hole is filled, to connect the wallboard and the concrete prefabricated reinforcing prop；By the plug division of the wallboard with The plug connector grafting of precast beam, and fixed using bonding agent, to connect wallboard and precast beam；

The precast floor slab is supported on the concrete girder of the precast beam, and with the concrete master of the precast beam Beam is connected using bonding agent and/or prefabricated connector.

Due to the adoption of the above technical scheme, the invention has the advantages that：

1, concrete structure assembled architecture system of the invention, prefabricated foundation, precast floor slab, wallboard and structural support Frame is the prefabricated components of plant produced.Scene need to only carry out cast-in-place, anchoring between a small amount of component or bolt connects and splices Equal assembly manipulations, it is easy for construction simple it is not necessary that full hall scaffold is arranged, the construction period has been shortened, architectural engineering has been saved and is built into This, makes construction assembly rate reach 95% or more, and repeat and utilize after structural demolition, reduces building waste and environment is dirty Dye, it is environmentally protective, really realize that less manpower saves cost, environmentally protective, energy-efficient industrialized building mesh economic, safety is beautiful Mark；Profound significance has been sexually revised to the revolution of traditional architecture materials for wall, individual character is realized to the build model of traditional architecture Change design, industrialized production, information system management, prefabricated construction reach the target of sustainable development.

2, concrete structure assembled architecture system of the invention, wallboard have high-strength light, heat preserving heat insulating noise insulation, prevent Fiery high temperature resistant, water proof anti-seepage, antidetonation, it is anticorrosive it is anti-aging, the superior functions such as do not crack, give and build more long-life, quality more Excellent, security performance index is high, environmentally protective；And wallboard is light material, and carrying and splicing work can be easily realized by a people Make, therefore, overcomes cast-in-site operation, the form of construction work that wet method is sporadicly constructed causes that difficulty of construction is big, the quantities big duration The drawbacks of construction quality that is long, completing cannot ensure.In addition, big plate splicing can be used in wallboard, compared to existing concrete For wall made of aerated blocks, shale porous brick, traditional red brick masonry, the globality of building is increased, and then be greatly improved The performances such as insulation, sound insulation, fireproof, waterproof and dampproof, the impervious, cracking resistance of building do not have to cement mortar, structure glue Or ceramic tile gelling agent carry out two-sided batch it is time levelling, without secondary progresss water-proof heat insulation layer construction, reduce building itself and weigh Amount effectively extends building whole service life, solves traditional architecture security risk caused by external-wall exterior insulation layer falls off Problem.

3, concrete structure assembled architecture system of the invention, wallboard is with concrete prefabricated reinforcing prop by anchoring steel Structure connects, and this building system not only increases the globality of wall, and improves force path, improves building adaptation The ability of deformation so that junction connection is reliable, improves the anti-seismic performance of building.Precast beam includes concrete girder and grafting The plug division progress of part, plug connector and wallboard is mating, then is fixedly connected using bonding agent, and scene can be not necessarily to install spiral shell Bolt, installation speed are improved, and can reduce wallboard and the cooperation precision needed for precast beam, and building system construction is reduced to reach The purpose of cost, meanwhile, plug connector and the mating of plug division transmit concrete girder institute so that building and can also pass through wall The plane shearing and vertical force, the quality and quake-resistant safety performance of building being subject to are greatly improved, and anti-seismic performance can reach 9 Spend or more standard.

4, concrete structure assembled architecture system of the invention is also equipped in the junction of Side fascia and precast floor slab anti- Water part further improves the waterproof impervious characteristic of wall.

5, some communal facilitys in the prior art, such as city police service sentry box, public lavatory, passive room etc., are generally deposited The defects of poor in sound insulation, heat-insulation and heat-preservation is poor, fire prevention, the poor performances such as impervious；Between passive one layer half to two layers half of room, thermal insulation separation Thermal effect is bad, is easy by corrosion；Public lavatory waterproof impervious characteristic is bad, weather-proof, corrosion resistance is relatively low.The coagulation of the present invention Soil structure assembled architecture system improves insulation, sound insulation, fireproof, waterproof and dampproof, the impervious, cracking resistance of building Etc. performances, particularly suitable for communal facility, such as the construction in city police service sentry box, public lavatory, passive room.

【Description of the drawings】

Fig. 1 is the Side fascia of concrete structure assembled architecture system, structural support frame in first embodiment of the invention The connection diagram of frame and precast floor slab.

Fig. 2 is the structure chart of the prefabricated foundation of concrete structure assembled architecture system in first embodiment of the invention.

Fig. 3 is the schematic top plan view of prefabricated foundation shown in Fig. 2.

Fig. 4 is the connection diagram of concrete prefabricated reinforcing prop and prefabricated foundation shown in Fig. 1.

Fig. 5 is the diagrammatic cross-section of Fig. 1.

Fig. 6 is enlarged drawings of the Fig. 5 at A.

Fig. 7 is the structure chart of prefabricated component in Fig. 5.

Fig. 8 is the lining of concrete structure assembled architecture system, structural support frame in first embodiment of the invention The connection diagram of frame and precast floor slab.

Fig. 9 is the diagrammatic cross-section of Fig. 8.

Figure 10 is the vertical view of Side fascia in first embodiment of the invention.

Figure 11 is the connection diagram of Side fascia shown in Figure 10.

Figure 12 is the vertical view of Side fascia in another embodiment of the present invention.

Figure 13 is the vertical view of lining in first embodiment of the invention.

Figure 14 is lining in Fig. 8 along the schematic cross-sectional view of line B-B.

Figure 15 is the schematic diagram of lining in another embodiment of the present invention.

Figure 16 be the Side fascia of concrete structure assembled architecture system in second embodiment of the invention, precast beam with it is pre- The connection diagram of floor processed.

Figure 17 is enlarged drawings of the Figure 16 at C.

Figure 18 be the lining of concrete structure assembled architecture system in third embodiment of the invention, precast beam with it is pre- The connection diagram of floor processed.

Figure 19 be the Side fascia of concrete structure assembled architecture system in four embodiment of the invention, precast beam with it is pre- The connection diagram of floor processed.

Figure 20 be the lining of concrete structure assembled architecture system in fifth embodiment of the invention, precast beam with it is pre- The connection diagram of floor processed.

Figure 21 be the Side fascia of concrete structure assembled architecture system in sixth embodiment of the invention, precast beam with it is pre- The connection diagram of floor processed.

Figure 22 is the connection of the exterior wall and window of concrete structure assembled architecture system in first embodiment of the invention Schematic diagram.

Figure 23 is the connection diagram for installing outline border in Figure 22 in the side wall and window of installing slot.

In attached drawing, 100- concrete structure assembled architectures system, 1- prefabricated foundations, the concrete prefabricated reinforcing props of 2-, 3- Structural support frame, 4- anchorings steel structure, 6- pedestals, 7- concrete structure columns, 8- first foundations bottom, the second subfoundations of 9-, 10- concrete base for post, the first rebar connectors of 11-, 12- suspension hooks, the second rebar connectors of 14-, 17- precast floor slabs, the outsides 18- Precast beam, 20- concrete girders, 21- plug connectors, 212-L types prefabricated component, the first side plates of 213-, 214- inside precast beam, 19- Second side plate, 215- bar plantings fixing piece, the prefabricated connectors of 22-, 23- Side fascias, 24- linings, 25- wallboards, 26- public affairs slot, 27- female grooves, 28- bar plantings hole, the plug divisions 29-, 36- prefabricated components, 37- mounting grooves, 38- fixed plates, the first bolts of 39-, 40- Two bolts, the first fixed plates of 41-, the second fixed plates of 42-, 43- water-proof precast products, the first joint faces of 44-, the second joint faces of 45-, 46- thirds joint face, 47- grouting seam, 48- support portions, 49- rakes, 50- bottom plates, 51- extension boards, 53- fixing grooves, 54- arcs Shape plate, 55- mounting plates, 56- lock bolts, 57- bolt retainers, the first inclined-planes 60-, the second inclined-planes 61-, the installation of 62- windows Hole, 63- waterproofs boss, 64- installings slot, 65- stainless steels flat logical, 66- windows, 67- install outline border.

【Specific implementation mode】

Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation describes, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.

It should be noted that when component is referred to as " being fixed on " another component, it can be directly on another component Or there may also be components placed in the middle.When a component is considered as " connection " another component, it can be directly connected to To another component or it may be simultaneously present component placed in the middle.When a component is considered as " being set to " another component, it Can be set up directly on another component or may be simultaneously present component placed in the middle.Term as used herein is " vertical ", " horizontal ", "left", "right" and similar statement for illustrative purposes only.

Unless otherwise defined, all of technologies and scientific terms used here by the article and belong to the technical field of the present invention The normally understood meaning of technical staff is identical.Used term is intended merely to description tool in the description of the invention herein The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term " and or " used herein includes one or more phases Any and all combinations of the Listed Items of pass.

First embodiment

Please referring also to Fig. 1 to Fig. 4, first embodiment of the invention provide a kind of concrete structure assembled architecture system 100, if including prefabricated foundation 1, structural support frame 3, several precast floor slabs 17 and drywall panel (not indicating).

Prefabricated foundation 1 includes pedestal 6 and at least concrete structure column 7 on pedestal 6.In the present embodiment, Each pedestal 6 is equipped with a concrete structure column 7.Pedestal 6 includes first foundation bottom 8, the second subfoundation 9 and concrete column Base 10, the second subfoundation 9 are connected on the one side of first foundation bottom 8, and concrete base for post 10 is connected to the second basic bottom Layer 9 is backwards to the side of first foundation bottom 8.In the present embodiment, first foundation bottom 8 and the second subfoundation 9 are mixed Solidifying soil material.Concrete structure column 7 is connected to side of the concrete base for post 10 backwards to first foundation bottom 8.In present embodiment In, first foundation bottom 8, the second subfoundation 9, concrete base for post 10 and concrete structure column 7 axis overlap, first The cross-sectional area of subfoundation 8 is identical as the cross-sectional area of the second subfoundation 9, the cross section face of first foundation bottom 8 The cross-sectional area of product, the cross-sectional area of concrete base for post 10 and concrete structure column 7 is sequentially reduced.This kind of structure it is prefabricated Basis 1 can increase the forced area of prefabricated foundation 1, and then extend the service life of building.Concrete structure column 7 is backwards to pedestal 6 one end is equipped with several first rebar connectors 11.Suspension hook 12 is also associated on the periphery wall of concrete structure column 7.Suspension hook 12 are embedded on concrete structure column 7 in advance, hoisting prefabricated basic 1 when facilitating subsequent installation.

Structural support frame 3 includes concrete prefabricated reinforcing prop 2 and precast beam (not indicating).Concrete prefabricated reinforcing prop 2 Bonding agent is used with concrete structure column 7, such as cement mortar, structure glue or ceramic tile gelling agent is cast-in-place is fixedly connected, specially： In the present embodiment, end face of the concrete prefabricated reinforcing prop 2 towards prefabricated foundation 1 is equipped with the second rebar connector 14, Several first rebar connectors 11 and several second rebar connectors 14 be spaced apart in concrete structure column 7 with it is concrete prefabricated Between reinforcing prop 2, in the live formwork in the periphery of the first rebar connector 11 and the second rebar connector 14, then by bonding agent, Such as cement mortar, structure glue or the cast-in-place fixation of ceramic tile gelling agent.The peripheral wall of concrete prefabricated reinforcing prop 2 is equipped with several anchorings Steel structure 4.In the present embodiment, each 4 radially extending along concrete prefabricated reinforcing prop 2 of anchoring steel structure.Precast beam and coagulation The prefabricated reinforcing prop 2 of soil passes through bonding agent, such as cement mortar, structure glue or the connection of ceramic tile gelling agent.Please also refer to Fig. 8, In present embodiment, precast beam includes outside precast beam 18 and internal precast beam 19, wherein outside precast beam 18 is set to the coagulation The periphery of soil structure assembled architecture system 100, internal precast beam 19 are set to the concrete structure assembled architecture system 100 In inner space.Outside precast beam 18 includes concrete girder 20 and plug connector 21 with internal precast beam 19, and plug connector 21 connects It is connected to the side of concrete girder 20.Concrete girder 20 uses bonding agent, such as cement bonded sand with concrete prefabricated reinforcing prop 2 It starches, the mode that structure glue or ceramic tile gelling agent are cast-in-place is attached.

Please also refer to Fig. 1, Fig. 5 to Fig. 9, in the present embodiment, concrete structure assembled architecture system 100 includes If dried layer precast floor slab 17, if dried layer precast floor slab 17 is vertically spaced setting.Every layer of precast floor slab 17 is superposed on On the concrete girder 20 of the concrete girder 20 of the outside precast beam 18 of same layer and internal precast beam 19, and mixed with corresponding Solidifying soil girder 20 uses bonding agent, such as cement mortar, structure glue or the connection of ceramic tile gelling agent.Adjacent two layers precast floor slab 17 it Between and between the precast floor slab 17 and prefabricated foundation 1 of the bottom be equipped with wallboard.The side of wallboard towards precast beam is set Have a plug division 29,21 grafting of plug connector of plug division 29 and precast beam, and by bonding agent, such as cement mortar, structure glue or The cast-in-place fixation of ceramic tile gelling agent.Plug division 29 is set to side of the wallboard towards precast beam, and plug connector 21 is set to concrete girder 20 Towards the side of wallboard, therefore, when plug division 29 and 21 grafting of plug connector, the inner space of building will not be occupied substantially, To make that there is larger space and preferable appearance in building.

Please also refer to Figure 10 to Figure 15, every layer of wallboard includes several Side fascias 23 and several linings 24, in this implementation In mode, the thickness of Side fascia 23 is more than the thickness of lining 24, and each Side fascia 23 includes two blocks of sub- wallboards 25, two pieces of sub- walls Plate 25 along wall thickness direction gluing together to form a Side fascia 23, to enhance the intensity of Side fascia 23.Adjacent two A Side fascia 23 is plugged in together by male and female groove 26,27, specially：The opposite sides of each sub- wallboard 25 is respectively equipped with public slot 26 and female groove 27,27 grafting of female groove that each Side fascia 23 passes through public slot 26 and adjacent Side fascia 23.In the present embodiment, public Slot 26 and female groove 27 may be contained within the center of Side fascia 23, to reduce damage of the wallboard in transportational process.It is appreciated that In other embodiments, adjacent two blocks of Side fascias 23 can also be attached by other modes such as bonding, Z-type slots.It is preferred that Ground, public slot 26 and female groove 27 along two adjacent sub- wallboards 25 of thickness of wall body direction arrangement are arranged alternately (Figure 10).It is appreciated that In other embodiments, along two adjacent Side fascias 23 of thickness of wall body direction arrangement, the same end can be respectively provided with public slot 26 Or it is respectively provided with female groove 27 (Figure 12).

The Side fascia 23 adjacent with concrete prefabricated reinforcing prop 2 is equipped with bar planting hole 28.In the present embodiment, bar planting hole 28 is horizontally extending.Anchoring steel structure 4 is anchored in bar planting hole 28, and Side fascia 23 and concrete prefabricated reinforcing prop 2 are connected It is connected together.Several Side fascias 23 surround an accommodation space (not shown) jointly.

Referring again to Fig. 1 and Fig. 5, Side fascia 23 is equipped with plug division 29, plug division towards the side of outside precast beam 18 29 with 21 grafting of plug connector, and by bonding agent, such as cement mortar, structure glue or the cast-in-place fixation of ceramic tile gelling agent, specially： In the present embodiment, the side of concrete girder 20 passes through the cast-in-place fixation of bonding agent with precast floor slab 17.Plug connector 21 is U-shaped Fixing piece, U-shaped fixing piece is using concrete prefabricated.U-shaped fixing piece include bottom plate 50 and by bottom plate 50 opposite sides towards same Two pieces of extension boards 51 that direction extends, bottom plate 50 and two pieces of extension boards 51 surround a grafting space (not indicating), bottom plate 50 jointly It is connect backwards to the side of precast floor slab 17 with concrete girder 20.In the present embodiment, bottom plate 50 and concrete girder 20 are logical Bolt retainer 57 is crossed to link together.Plug division 29 is grafting protrusion, and grafting protrusion is inserted in the grafting space, and Pass through the cast-in-place fixation of bonding agent with U-shaped fixing piece.For ease of pour into a mould bonding agent, in the present embodiment, also in Side fascia 23 with A grouting seam 47 is reserved between extension board 51.

Please to Figure 15, lining 24 is made referring also to Fig. 8, Fig. 9 and Figure 13 of one block of sub- wallboard 25, thickness compared with It is small, to save the space in building.Several linings 24 are set in accommodation space, the sub- wallboard 25 of adjacent two pieces of linings 24 Mutually splicing is to form interior wall, to which accommodation space is divided into several compartments.In the present embodiment, adjacent two pieces of linings 24 connection type is identical as Side fascia 23, to omit length, is not described in detail here.With concrete prefabricated reinforcing prop 2 Adjacent lining 24 is connect by anchoring steel structure 4 with concrete prefabricated reinforcing prop 2.Lining 24 is towards internal precast beam 19 Side is equipped with plug division 29,21 grafting of plug connector of plug division 29 and internal precast beam 19, and passes through bonding agent, such as cement bonded sand Slurry, structure glue or the cast-in-place fixation of ceramic tile gelling agent.In the present embodiment, plug connector 21 is implantation reinforcing bar, is implanted into the one of reinforcing bar End is anchored with concrete girder 20 backwards to the side of precast floor slab 17.Plug division 29 is vertical bar planting hole.Be implanted into Bar Anchorage in In vertical bar planting hole.In the present embodiment, plug connector 21 includes two rows of implantation reinforcing bars, and two are correspondingly provided on each lining 24 Vertical bar planting hole is arranged, each implantation Bar Anchorage is in corresponding vertical bar planting hole.Preferably, two rows of implantation reinforcing bars are located at 24 opposite sides of lining, and vertical bar planting hole (the i.e. plug division 29) stagger setting (Figure 14) in 24 opposite sides of lining, So that wallboard has the intensity of bigger and better shear behavior.It is appreciated that in other embodiments, 24 phase of lining Setting (Figure 15) can also be aligned to the vertical bar planting hole (i.e. plug division 29) on both sides.

Referring again to Fig. 5 and Fig. 7, each precast floor slab 17 and the Side fascia 23 that is positioned above by prefabricated component 36 and Bonding agent connects, specially：In the present embodiment, the Side fascia 23 for being located at 17 top of precast floor slab is equipped with fixing groove 53, fixing groove 53 is located at Side fascia 23 towards the side of precast floor slab 17.Prefabricated component 36 includes 54, two pieces of mounting plates 55 of arc panel And several lock bolts 56, arc panel 54 are contained in fixing groove 53, two pieces of mounting plates 55 are divided by the opposite sides of arc panel 54 It is not extended to form towards two opposite directions, two pieces of mounting plates 55 are connected to by several lock bolts 56 with precast floor slab 17 respectively Together, it precast floor slab 17, the Side fascia 23 above the precast floor slab 17 and is fixed again by bonding agent between prefabricated component 36. One or more of cement mortar, structure glue or ceramic tile gelling agent can be used in bonding agent.It can be carried using this kind of connection type High precast floor slab 17 supports shearing force performance with 23 junction of Side fascia, in addition, can be received prefabricated component 36 using fixing groove 53 It is dissolved in wall, avoids prefabricated component 36 from occupying the inner space of building, and make building that there is preferable appearance.

Fig. 9 is referred to, each precast floor slab 17 and the lining 24 being positioned above are not necessarily to connection, only need to be by the lining 24 are supported in 17 top of precast floor slab.It is appreciated that in other embodiments, each precast floor slab 17 with it is disposed thereon Cement mortar, structure glue or the cast-in-place fixation of ceramic tile gelling agent can also be used in the lining 24 of side.

Referring again to Fig. 1, Fig. 5 and Fig. 6, Side fascia 23 is additionally provided with several water-proof precast products backwards to the side of accommodation space 43.In the present embodiment, water-proof precast product 43 is substantially in a long strip shape, and material preferably uses stone material foamed light wall Plate.Each water-proof precast product 43 includes the first joint face 44, the second joint face 45 and third joint face 46, the first joint face 44 with Second joint face 45 is oppositely arranged, and third joint face 46 connects the first joint face 44 and the second joint face 45, and third joint face 46 towards accommodation space.First joint face 44 and the second joint face 45 pass through bonding agent, example with adjacent two layers Side fascia 23 respectively Such as cement mortar, structure glue or the cast-in-place fixation of ceramic tile gelling agent, third joint face 46 and corresponding precast floor slab 17 and outside are pre- Beam 18 processed passes through bonding agent, such as cement mortar, structure glue or the cast-in-place fixation of ceramic tile gelling agent.The setting energy of water-proof precast product 43 Enough prevent rainwater from penetrating into wall from the junction of precast floor slab 17 and exterior wall 23, can further increase building uses the longevity Life.

In the present embodiment, the first joint face 44 be inclined-plane, the first joint face 44 towards far from accommodation space direction by It is gradually tilted to prefabricated foundation 1, the Side fascia 23 being connect with the first joint face 44 is equipped with first coordinated with the first joint face 44 Inclined-plane 60, the first inclined-plane 60 are fixed with the first joint face 44 by bonding agent.Second joint face 45 includes support portion 48 and tilts Portion 49, support portion 48 are supported on corresponding Side fascia 23 and are fixed by bonding agent with corresponding Side fascia 23, rake 49 Rake 49 is connected to farthest away from the side of the accommodation space, rake 49 is towards the direction far from accommodation space gradually to prefabricated Basis 1 tilts, and the Side fascia 23 being connect with the second joint face 45 is equipped with the second inclined-plane 61 coordinated with rake 49, and second tiltedly Face 61 is fixed with rake 49 by bonding agent.Utilize the inclined design of the first joint face 44 and the second joint face 45, Neng Gougeng Good ground resistance is kept off the rain water, and the water resistance of wall is further improved.

Please also refer to Figure 22 to Figure 23, it is further opened with window mounting hole 62 on Side fascia 23, surrounds the window mounting hole One waterproof boss 63 of projection and recessed installing slot 64 on 62 side wall.A stainless steel flat logical 65 is fixed in installing slot 64.It is mixed Xtah Crude Clay structure assembled architecture system 100 further includes window 66, and window 66 includes metal outer frame 67, and metal outer frame 67 can be used for filling If the windowpane of window 66.In the present embodiment, metal outer frame 67 uses aluminum alloy frame.Metal outer frame 67 and stainless steel are flat Lead to 65 and the connection of waterproof boss 63.The setting of waterproof boss 63 can prevent rainwater from being oozed from window 66 and the junction of Side fascia 23 Enter building interior.

In the present embodiment, Side fascia 23 and lining 24 are all made of based on graphene and stone material foamed wall slab, In percentage by weight, including stone material tailing 45-90%, high temperature cosolvent 0.05-10%, graphene 0.05-15%, expansion Graphite 0.05-5%, zirconium oxide 1-20%, calcium carbonate 0.05-10%, clay 1-10%, stabilizer 0.05-5%, degumming agent 0.05-5%, inorganic color 0.05-5%.

Preferably, it should be based on graphene and stone material foamed wall slab, in percentage by weight, including stone material tailing 75%, graphene 3%, high temperature cosolvent 7%, zirconium oxide 2%, expanded graphite 1%, calcium carbonate 3%, clay 3%, stabilizer 3%, degumming agent 3%.

It further illustrates, the stone material tailing is granite, feldspar, quartz, sandstone, diabase, shale, limestone, profound One or more in Wu Yan, griotte, Desert Sand.

It further illustrates, the stone material tailing also passes through modification before compounding, and the modification is specific as follows：It will Stone material tailing, brown sugar water, pseudomonas aeruginosa either Pseudomonas Pseudomonas or Pseudomonas pseudoflava or the false unit cell of corruption Bacterium, Colibacter are 100 according to weight ratio:10:0.2:0.1 build heap mixing, then will treated stone material tailing into Row is broken, is then ground 1-3 minutes and then sieves with 100 mesh sieve, and the stone material tailing after sieving is then carried out bacterial screening, will Strain is detached with stone material tailing, is left stone material tailing and be can be obtained modified stone material tailing.

It further illustrates, the pseudomonas aeruginosa either Pseudomonas Pseudomonas or Pseudomonas pseudoflava or corruption It is 1.52 × 10 that pseudomonad or Colibacter, which are arranged to effective bacteria containing amount,⁸-6.35×10⁸The bacterium solution of a/mL is into enforcement With.

It further illustrates, the pseudomonas aeruginosa either Pseudomonas Pseudomonas or Pseudomonas pseudoflava or corruption Thalline also passes through activation culture before the bacterium solution configuration of pseudomonad, and the culture medium prescription that the activation culture culture uses is：It is bright Glue peptone 16.0g, tryptone 10.0g, extract of soybean 8-15g, Radix Schisandrae Bicolori extract 8-20g, K₂SO₄ 10.0g、MgCl₂ 1.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 7.1 ± 0.2.

It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution configuration of the Colibacter The culture medium prescription used is cultivated in culture：Tryptone 5-18g/L, extract of soybean 1-8g/L, Radix Schisandrae Bicolori extract 3- 10g/L, sodium chloride 5-20g/L, pH 7.4 ± 0.2.

It further illustrates, the content containing soybean polyoses reaches 90% or more in the extract of soybean；Fructus schisandrae carries The content containing fructus schisandrae polysaccharide in object is taken to reach 90% or more.

It further illustrates, the high temperature fluxing agent includes calcination of talc, raw talcum, fluorite, one kind in diopside or one Kind or more.

It further illustrates, the clay includes the one or more in yellow mud, red soil, manganese mud and kaolin.

It further illustrates, the stabilizer is the one or more in the oxide of yttrium, cerium.

A kind of preparation method based on graphene Yu stone material foamed wall slab as described above, preparation method include following step Suddenly：

S1, washup：After stone material tailing is smashed it through 1-10 mesh, the stone material tailing after crushing is sent into fermentation vat, leaching It is cone cylinder, the 1/5-1/3 of a diameter of base diameter of feeding mouth, in the high-pressure water pipeline that the inside front of feeding mouth is arranged to steep pond The ammonium oxalate solution that high-pressure fog mass concentration is 1.5-5.5% while being sent into stone material tailing carries out spraying and drenches, until The volume of the ammonium oxalate solution of spraying can stop spraying process after being 1.1-1.32 times of stone material tailing volume, impregnate 30- 100min stirs a material at interval of 5min in soak period, is then separated by solid-liquid separation, by the filtrate siphon containing ammonium oxalate It into catch basin, and is separated by solid-liquid separation after taking filtrate to be washed, the step of 2-3 washing is separated by solid-liquid separation is repeated, by separation Washing filtrate returns after merging to be repeated to use when washup next time, and the solid after washing is dried to the stone material tail after being washed It is for use after mine；

S2, raw material mixing：By weight percent weighing shared by each raw material is formulated, with ball mill batch mixing ball milling 3-15h, ball milling Fineness reached 250 mesh sieve full by, be subsequently placed into storage warehouse mix homogenizing；

S3, the powder after homogenizing is put into savings storehouse by mist projection granulating into drier；

S4, cloth firing：The granulation material of spray drying tower drying is subjected to cloth, is put into roller kilns or tunnel oven, Through 900-1300 DEG C, after the firing of soak in 30-300 minutes, it is taken out by kiln cooling, is made and is based on graphene and stone Material foamed wall slab crude product；

S5, crude product is molded after cutting, is obtained based on graphene and stone material foamed wall slab finished product.

It further illustrates, in S4, the time of soak firing is 100-150 minutes.

It further illustrates, in S5, foamed wall slab product specification is：It is long：2400-3000mm, width：600-1200mm, It is thick：80-500mm.

Since wallboard uses above-mentioned technical proposal, there is following beneficial effect：

1, graphene is a kind of two dimensional crystal, is arranged according to hexagon by carbon atom, is connected with each other, and a carbon is formed Molecule, structure are highly stable；As the amount of carbon atom connected is on the increase, this two-dimensional carbon molecules plane constantly expands Greatly, molecule also constantly becomes larger.Only there are one the thickness of carbon atom for single-layer graphene, i.e., 0.335 nanometer, are equivalent to hair The thickness of 20 a ten thousandths nearly has 1,500,000 layers or so of graphene in the graphite of 1 millimeters thick.Graphene is known most thin A kind of two-dimensional material, and have many advantages, such as high specific surface area and intensity.Each raw material phase in formula in the present invention Mutually auxiliary plays the effect of anti-aging, anticorrosive energy, heat-insulation and heat-preservation, sound insulation, water proof anti-seepage, fireproof, high-strength light, special It is not to have breakthrough discovery, fire endurance that can reach 120min or more on fire endurance.First, various stone material tailings are Base material, and add graphene, improves the hardness, high temperature resistant and flame retardant property of wallboard, overcomes organic material and is afraid of open fire, easy to aging The deadly defect of deformation, improves the fire protecting performance of inorganic material, and compensates for the defect of inorganic material poor compatibility, Hua Gang The stone materials tailing such as rock, shale has higher hardness, fire prevention and higher compressive property, to assign wallboard stabilization, high temperature resistant With the performances such as fire-proof and water-proof；Meanwhile base material is done using various stone material tailings, be conducive to ecological environmental protection, effectively improve resource Production cost is largely saved in comprehensive utilization；It by using expanded graphite as foaming agent, and is combined with foam stabilizer, realization pair The integrally-built Effective Regulation of wallboard during pore structure and foaming, the pore structure grain size exquisiteness formed it into are evenly distributed, wallboard Shape is regular, aligned orderly so that wallboard has cross-linked structure, to achieve the purpose that improve wallboard strength and toughness； Additional stone material tailing is added graphene and changes stone material tailing appearance by chemical oxidization method in the high temperature environment with expanded graphite The property in face, it is easier to other substance association reactions, and be combined rapidly with other raw material of substance in foaming process, expand stone material The foaming aperture size of tailing, but foaming aperture size can not be excessive, causes the wallboard prepared outside face bumps not It is flat, therefore be added after zirconium oxide, calcium carbonate, clay progress ball milling in hot environment while adding graphene, expanded graphite The gap between stone material tailing during the reduction of stone material tailing is foamed is changed, and composition micro- in stone material tailing can be changed, Improve stone material tailing itself inoxidizability, control foaming degree also to add stabilizer ensure reaction in each ion it Between stability make face outside foamed wall slab relatively flat, reduce six panel thickness for being further cut into finished product Degree, the high temperature cosolvent of addition can be rapidly performed by reaction in hot stage, and the gap formed during foaming is fine and smooth uniformly, Each raw material carries out ball milling and reaches 250 mesh full by homogenizing and then mist projection granulating, intermolecular active force strengthens, in high temperature Under environment, although intermolecular be interrupted, the stronger particle of molecular force of homogenizing still has mutual power, raw material each in this way The wallboard so that being made on a large scale during reacting can be uniformly filled, it is all uniform smooth in plane of structure, vertical face, be not in The phenomenon of large-area concave-convex injustice, will not be intermolecular to be kept completely separate as common raw material is under high temperature action, arbitrarily flows, makes The filling of each of entire product place substance disunity, when being detected data, thermal coefficient, bulk density, Compression strength, flexural strength have larger difference；What the present invention was prepared is passed through based on graphene and stone material foamed wall slab Test, bulk density 170-800kg/m³, compression strength >=5MPa, flexural strength >=2.5MPa, conduction heat transfer coefficient≤ 2.0W/m DEG C, A1 grades of combustion rating, oise insulation factor >=35dB, water absorption rate < 0.1%, fire endurance >=2h, radionuclide limitation (interior photograph, outer photograph)≤1.0.

2, in the method for the preparation in present embodiment, ammonium oxalate washing step is also carried out for stone material tailing, can be returned It receives and utilizes rare earth metal such as scandium (Sc), yttrium (Y), lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), the promethium in stone material tailing (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu) etc. So that stone material tailing eliminates rare metal, radiation is reduced, realizes the real environmentally protective purpose of construction material.By detection Filtrate containing ammonium oxalate is siphoned into the liquid in catch basin, and the content of rare earth reaches 0.598g/L-0.785g/L.Stone simultaneously Material tailing can remove the remaining of the ammonium oxalate in stone material tailing by washing process, and wash liquid energy recycling repetitive cycling and use, Extraction of rare earth metal is first carried out when water lotion middle rare earth tenor is high, is recycled, will not be caused secondary pollution.And the present invention Raw material suitable foaming aperture size can be obtained by formula rate conveniently by local take, formation is not connected to largely Closed pore independence minute bubbles (in diameter range 5mm), being made has notable anti-aging, anticorrosive, heat-insulation and heat-preservation, sound insulation, waterproof Impervious, fireproof, high-strength light, do not crack, be environmentally protective etc. comprehensive performances in integrally based on graphene with stone material foaming gently Matter wallboard.

3, in application graphene produced by the present invention and stone material tailing foamed wall slab, because of this wallboard product collection green The required various functions of energy saving building in the feature of one, and it is small, occupy that space is few, own wt is light, is not required to Want wet work and fragmentary building construction, it is often more important that a large amount of sandstone cement need not be used.Exterior wall need not increase water Cement mortar batch time screed-coat, also need not secondary construction and installation heat insulation layer again.Working procedure is simple and convenient, greatly reduces and builds Build construction cost cost.This wallboard product can be carried out directly as traditional architecture, assembled architecture inside and outside wall board wall board material The integrated assembling installation of building, can meet building heat preservation heat-insulating decorative integrative installation technology effect；Especially in assembled During architecture construction construction and installation, the assembly rate of building course, contracting are greatly improved using the inside and outside wall board product of the present invention The short integral construction duration, largely reduce it is artificial, save material, save and build construction cost, it is comprehensive to improve overall building and apply Work safe mass.And application this wall board material building waste can very recycling, really realize less manpower save Cost, environmentally protective, energy-efficient industrialized building target economic, safety is beautiful.Revolution to traditional architecture materials for wall Profound significance has been sexually revised, personalized designs, industrialized production, information-based pipe are realized to the build model of traditional architecture Reason, prefabricated construction reach the target of sustainable development.

Being sent out based on graphene and stone material in first embodiment that present invention will be further explained below with reference to specific examples Steep lightweight wall plate.The chemical composition of tailing used in following embodiments is SiO₂< 65%, Al₂O₃> 8%, Fe₂O₃< 11%, CaO The content 1.246g/L-1.784g/L of < 15%, loss on ignition < 18%, rare earth.

Embodiment 1

One, raw material proportioning is shown in Table 1；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature fluxing agent is It is shown in Table 4；The stabilizer is yttrium oxide and cerium oxide.

Two, it prepares：

Foamed wall slab specific method will be prepared in above-mentioned proportioning raw material to include the following steps：

S1, washup：After stone material tailing is smashed it through 1 mesh, the stone material tailing after crushing is sent into fermentation vat, fermentation vat For bore cylinder, the 1/5 of a diameter of base diameter of feeding mouth, feeding mouth inside front be arranged high-pressure water pipeline be sent into stone The ammonium oxalate solution that high-pressure fog mass concentration is 1.5% while material tailing carries out spraying and drenches, until the ammonium oxalate of spraying The volume of solution can stop spraying process after being 1.1 times of stone material tailing volume, impregnate 30min, soak period at interval of 5min stirs a material, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and takes filtrate It is separated by solid-liquid separation after being washed, is repeated 2 times the step of washing is separated by solid-liquid separation, weight next time is returned after the washing filtrate of separation is merged It is used when after backwashing mine, the solid after washing is dried after the stone material tailing after being washed for use；

S2, raw material mixing：By weight percent weighing shared by each raw material is formulated, with ball mill batch mixing ball milling 3h, ball milling is thin Degree reached 250 mesh sieve full by, be subsequently placed into storage warehouse mix homogenizing；

S4, cloth firing：The granulation material of spray drying tower drying is subjected to cloth, is put into roller kilns or tunnel oven, It through 900 DEG C, after the firing of soak in 30 minutes, is taken out by kiln cooling, is made light based on graphene and stone material foaming Matter wallboard crude product；

S5, it is by the cleaved specification of crude product：It is long：2400mm, width：600mm, thickness：80mm based on graphene and stone material Foamed wall slab finished product.

Embodiment 2

Two, it prepares：

S1, washup：After stone material tailing is smashed it through 10 mesh, the stone material tailing after crushing is sent into fermentation vat, is impregnated Pond is to bore cylinder, the 1/3 of a diameter of base diameter of feeding mouth, it is being sent into the high-pressure water pipeline that the inside front of feeding mouth is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 5.5% while stone material tailing carries out spraying and drenches, until the oxalic acid of spraying The volume of ammonium salt solution can stop spraying process after being 1.32 times of stone material tailing volume, impregnate 100min, in soak period every A material is stirred every 5min, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and takes filtering Object is separated by solid-liquid separation after being washed, and is repeated 3 times the step of washing is separated by solid-liquid separation, and next time is returned after the washing filtrate of separation is merged It repeats to use when washup, the solid after washing is dried after the stone material tailing after being washed for use；

S2, raw material mixing：By weight percent weighing shared by each raw material is formulated, with ball mill batch mixing ball milling 15h, ball milling is thin Degree reached 250 mesh sieve full by, be subsequently placed into storage warehouse mix homogenizing；

S4, cloth firing：The granulation material of spray drying tower drying is subjected to cloth, is put into roller kilns or tunnel oven, Through 1300 DEG C, after the firing of soak in 300 minutes, it is taken out by kiln cooling, foamed wall slab crude product is made；

S5, it is by the cleaved specification of crude product：It is long：3000mm, width：1200mm, thickness：500mm based on graphene and stone Material foamed wall slab finished product.

Embodiment 3

One, raw material proportioning is shown in Table 1；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature fluxing agent is It is shown in Table 4；The stabilizer is yttrium oxide.

Two, it prepares：

S1, washup：After stone material tailing is smashed it through 4 mesh, the stone material tailing after crushing is sent into fermentation vat, fermentation vat For bore cylinder, the 1/4 of a diameter of base diameter of feeding mouth, feeding mouth inside front be arranged high-pressure water pipeline be sent into stone The ammonium oxalate solution that high-pressure fog mass concentration is 2.5% while material tailing carries out spraying and drenches, until the ammonium oxalate of spraying The volume of solution can stop spraying process after being 1.21 times of stone material tailing volume, impregnate 60min, soak period at interval of 5min stirs a material, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and takes filtrate It is separated by solid-liquid separation after being washed, is repeated 3 times the step of washing is separated by solid-liquid separation, weight next time is returned after the washing filtrate of separation is merged It is used when after backwashing mine, the solid after washing is dried after the stone material tailing after being washed for use；

S2, raw material mixing：By weight percent weighing shared by each raw material is formulated, with ball mill batch mixing ball milling 4h, ball milling is thin Degree reached 250 mesh sieve full by, be subsequently placed into storage warehouse mix homogenizing；

S4, cloth firing：The granulation material of spray drying tower drying is subjected to cloth, is put into roller kilns or tunnel oven, It through 950 DEG C, after the firing of soak in 100 minutes, is taken out by kiln cooling, is made light based on graphene and stone material foaming Matter wallboard crude product；

S5, it is by the cleaved specification of crude product：It is long：2500mm, width：700mm, thickness：90mm based on graphene and stone material Foamed wall slab finished product.

Embodiment 4

One, raw material proportioning is shown in Table 1；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature fluxing agent is It is shown in Table 4；The stabilizer is cerium oxide.

Two, it prepares：

It includes such as that above-mentioned proportioning raw material, which will be prepared based on graphene and stone material foamed wall slab specific method, Lower step：

S1, washup：After stone material tailing is smashed it through 6 mesh, the stone material tailing after crushing is sent into fermentation vat, fermentation vat For bore cylinder, the 1/5 of a diameter of base diameter of feeding mouth, feeding mouth inside front be arranged high-pressure water pipeline be sent into stone The ammonium oxalate solution that high-pressure fog mass concentration is 3.5% while material tailing carries out spraying and drenches, until the ammonium oxalate of spraying The volume of solution can stop spraying process after being 1.15 times of stone material tailing volume, impregnate 90min, soak period at interval of 5min stirs a material, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and takes filtrate It is separated by solid-liquid separation after being washed, is repeated 3 times the step of washing is separated by solid-liquid separation, weight next time is returned after the washing filtrate of separation is merged It is used when after backwashing mine, the solid after washing is dried after the stone material tailing after being washed for use；

S2, raw material mixing：By weight percent weighing shared by each raw material is formulated, with ball mill batch mixing ball milling 5h, ball milling is thin Degree reached 250 mesh sieve full by, be subsequently placed into storage warehouse mix homogenizing；

S4, cloth firing：The granulation material of spray drying tower drying is subjected to cloth, is put into roller kilns or tunnel oven, Through 1000 DEG C, after the firing of soak in 150 minutes, it is taken out by kiln cooling, is made and is foamed based on graphene and stone material Lightweight wall plate crude product；

S5, it is by the cleaved specification of crude product：It is long：2600mm, width：800mm, thickness：100mm based on graphene and stone material Foamed wall slab finished product.

Embodiment 5

Two, preparation method is same as Example 2.

Embodiment 6

Two, preparation method is same as Example 2.

Embodiment 7

Wherein, also pass through modification before stone material tailing compounding, the modification is specific as follows：By stone material tailing, red Syrup, pseudomonas aeruginosa, Colibacter are 100 according to weight ratio:10:0.2:0.1 carries out building heap mixing, then will processing Stone material tailing afterwards is crushed, and is then ground and 1 minute and then is sieved with 100 mesh sieve, then by the stone material tailing after sieving into Row bacterial screening detaches strain with stone material tailing, leaves stone material tailing and can be obtained modified stone material tailing.

It further illustrates, it is 1.52 × 10 that pseudomonas aeruginosa, Colibacter, which are arranged to effective bacteria containing amount,⁸- 2.02×10⁸The bacterium solution of a/mL is used.

It further illustrates, thalline also passes through activation culture, the activation training before the bacterium solution configuration of the pseudomonas aeruginosa The foster culture medium prescription that uses cultivated is：Gelatin peptone 16.0g, tryptone 10.0g, extract of soybean 8g, fructus schisandrae extraction Object 8g, K₂SO₄ 10.0g、MgCl₂1.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 7.1.

It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution configuration of the Colibacter The culture medium prescription used is cultivated in culture：Tryptone 5g/L, extract of soybean 1g/L, Radix Schisandrae Bicolori extract 3g/L, chlorine Change sodium 5g/L, pH 7.4.

Two, preparation method is same as Example 2.Above-mentioned modification is carried out between step S1 and S2 wherein in preparation method Processing step.

Embodiment 8

Wherein, also pass through modification before stone material tailing compounding, the modification is specific as follows：By stone material tailing, red Syrup, Pseudomonas Pseudomonas, Colibacter are 100 according to weight ratio:10:0.2:0.1 carries out building heap mixing, then will place Stone material tailing after reason is crushed, and is then ground 3 minutes and then is sieved with 100 mesh sieve, then by the stone material tailing after sieving Bacterial screening is carried out, strain is detached with stone material tailing, stone material tailing is left and can be obtained modified stone material tailing.

It further illustrates, it is 5.64 × 10 that Pseudomonas Pseudomonas, Colibacter, which are arranged to effective bacteria containing amount,⁸- 6.35×10⁸The bacterium solution of a/mL is used.

It further illustrates, the pseudomonas aeruginosa either Pseudomonas Pseudomonas or Pseudomonas pseudoflava or corruption Thalline also passes through activation culture before the bacterium solution configuration of pseudomonad, and the culture medium prescription that the activation culture culture uses is：It is bright Glue peptone 16.0g, tryptone 10.0g, extract of soybean 15g, Radix Schisandrae Bicolori extract 20g, K₂SO₄ 10.0g、MgCl₂ 1.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 6.9.

It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution configuration of the Colibacter The culture medium prescription used is cultivated in culture：Tryptone 18g/L, extract of soybean 8g/L, Radix Schisandrae Bicolori extract 10g/L, Sodium chloride 20g/L, pH 7.2.

It further illustrates, the content containing soybean polyoses reaches 93% in the extract of soybean；Radix Schisandrae Bicolori extract In the content containing fructus schisandrae polysaccharide reach 92%.

Two, preparation method is same as Example 3.Above-mentioned modification is carried out between step S1 and S2 wherein in preparation method Processing step.

Embodiment 9

One, raw material proportioning is shown in Table 1；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature fluxing agent is It is shown in Table 4；The stabilizer is cerium oxide；

Wherein, also pass through modification before stone material tailing compounding, the modification is specific as follows：By stone material tailing, red Syrup, Pseudomonas pseudoflava, Colibacter are 100 according to weight ratio:10:0.2:0.1 carries out building heap mixing, then will processing Stone material tailing afterwards is crushed, and is then ground and 2 minutes and then is sieved with 100 mesh sieve, then by the stone material tailing after sieving into Row bacterial screening detaches strain with stone material tailing, leaves stone material tailing and can be obtained modified stone material tailing.

It further illustrates, it is 2.89 × 10 that Pseudomonas pseudoflava, Colibacter, which are arranged to effective bacteria containing amount,⁸- 3.13×10⁸The bacterium solution of a/mL is used.

It further illustrates, the pseudomonas aeruginosa either Pseudomonas Pseudomonas or Pseudomonas pseudoflava or corruption Thalline also passes through activation culture before the bacterium solution configuration of pseudomonad, and the culture medium prescription that the activation culture culture uses is：It is bright Glue peptone 16.0g, tryptone 10.0g, extract of soybean 11g, Radix Schisandrae Bicolori extract 15g, K₂SO₄ 10.0g、MgCl₂ 1.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 7.3.

It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution configuration of the Colibacter The culture medium prescription used is cultivated in culture：Tryptone 10g/L, extract of soybean 5g/L, Radix Schisandrae Bicolori extract 7g/L, chlorine Change sodium 15g/L, pH 7.6.

It further illustrates, the content containing soybean polyoses reaches 98% in the extract of soybean；Radix Schisandrae Bicolori extract In the content containing fructus schisandrae polysaccharide reach 96% or more.

Embodiment 10

Wherein, also pass through modification before stone material tailing compounding, the modification is specific as follows：By stone material tailing, red Syrup, pseudomonas putrefaciens, Colibacter are 100 according to weight ratio:10:0.2:0.1 carries out building heap mixing, then will processing Stone material tailing afterwards is crushed, and is then ground and 3 minutes and then is sieved with 100 mesh sieve, then by the stone material tailing after sieving into Row bacterial screening detaches strain with stone material tailing, leaves stone material tailing and can be obtained modified stone material tailing.

It further illustrates, it is 3.56 × 10 that pseudomonas putrefaciens, Colibacter, which are arranged to effective bacteria containing amount,⁸- 6.05×10⁸The bacterium solution of a/mL is used.

It further illustrates, the pseudomonas aeruginosa either Pseudomonas Pseudomonas or Pseudomonas pseudoflava or corruption Thalline also passes through activation culture before the bacterium solution configuration of pseudomonad, and the culture medium prescription that the activation culture culture uses is：It is bright Glue peptone 16.0g, tryptone 10.0g, extract of soybean 14g, Radix Schisandrae Bicolori extract 18g, K₂SO₄ 10.0g、MgCl₂ 1.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 7.2.

It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution configuration of the Colibacter The culture medium prescription used is cultivated in culture：Tryptone 16g/L, extract of soybean 7g/L, Radix Schisandrae Bicolori extract 9g/L, chlorine Change sodium 18g/L, pH 7.5.

It further illustrates, the content containing soybean polyoses reaches 99% in the extract of soybean；Radix Schisandrae Bicolori extract In the content containing fructus schisandrae polysaccharide reach 98%.

Embodiment 11

One, raw material proportioning is same as Example 7；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature Fluxing agent is to be shown in Table 4；The stabilizer is cerium oxide.

Two, preparation method is same as Example 3.

Embodiment 12

Two, preparation method is same as Example 4.

Embodiment 13

One, raw material proportioning is same as Example 8；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature Fluxing agent is to be shown in Table 4；The stabilizer is cerium oxide.

Two, preparation method is same as Example 4.

Embodiment 14

Two, preparation method is same as Example 4.

Embodiment 15

One, raw material proportioning is same as Example 9；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature Fluxing agent is to be shown in Table 4；The stabilizer is cerium oxide.

Two, preparation method is same as Example 4.

Embodiment 16

One, raw material proportioning is shown in same as Example 9；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The height Warm fluxing agent is to be shown in Table 4；The stabilizer is cerium oxide.

Two, preparation method is same as Example 4.

Embodiment 17

Two, preparation method is same as Example 4.

Embodiment 18

Two, preparation method is same as Example 4.

Ingredient percentage composition list in 1 each embodiment of table

Embodiment	1	2	3	4	5	6	7	8	9	10
											Stone material tailing	75	78	70	80	45	90	48	79	45	45
Graphene	3	3	6	2	15	0.05	1	1	7	10
											High temperature cosolvent	7	5	6	2	10	0.05	1	1	4	9
Zirconium oxide	2	1	1	2	8.95	3	20	5	15	10
											Expanded graphite	1	3	5	2	5	0.05	1	3	3	4
Calcium carbonate	3	2	3	4	0.05	1	10	3	8	6
											Clay	3	4	4	4	1	2	10	5	8	9
Stabilizer	3	2	2	2	5	0.05	5	1	4	1
											Degumming agent	3	2	3	2	5	0.05	5	1	4	2
Inorganic color	0	0	0	0	5	3.75	0	1	2	4

Stone material tailing selective listing in 2 each embodiment of table

Clay selective listing in 3 each embodiment of table

Embodiment	Yellow mud	Red soil	Manganese mud	Kaolin
					1	√	--	--	--
2	--	√	--	--
					3	--	--	√	--
4	--	--	--	√
					5	√	√	√	--
6	√	√	--	√
					7	√	--	√	√
8	--	√	√	√
					9	--	√	√	--
10	--	--	√	√
					11	√	√	--	--
12	√	--	--	√
					13	--	√	--	√
14	√	--	√	--
					15	√	√	√	√
16	√	√	√	√
					17	√	√	√	√
18	--	--	√	√

4 each embodiment high temperature cosolvent selective listing of table

Testing inspection：

By embodiment 1-18 is prepared in present embodiment foamed wall slab, the comparative example (foaming of market purchase Lightweight wall plate) by the test of physical and mechanical properties, the specific method is as follows, and test result is referring to the following table 5.

One, quantitative measurement：

This experiment take specification be 40mm × 40mm × 160mm mold molding be made standard based on graphene and stone material Foamed wall slab, three samples of one-pass molding, size of sample after molding are 40mm × 40mm × 160mm.Sample is demoulded Afterwards, and by a series of processing standard specimen is obtained.

(1) bulk density：Foamed wall slab sample is placed in electric drying oven with forced convection, is to slowly warm up to 40 ± 5 DEG C, After the foamed wall slab sample mass change rate weighed twice in 3h is less than 0.2%, sample is moved to cooling in drier To room temperature, with the oven dry weight G0 of electronic balance weighing sample, unit g is accurate to 0.1g.

The bulk density of sample is calculated by formula, is accurate to 1kg/m³

In formula, the density of ρ-sample, units/kg/m3；The absolute dry mass of G0- samples, units/kg.

(2) water absorption rate：It is surveyed based on graphene and stone material foamed wall slab sample with above-mentioned test volume density Fixed, quantity is three.Being erected by width direction with stone material foamed wall slab sample based on graphene for absolute dry mass will be dried to It rises and is put into 20 ± 5 DEG C or so of water, test specimen is not less than 25mm away from interval between periphery and test specimen, and the water surface should be higher by sample upper end Sample is taken out from water after 25mm, 2h, exists side by side and is placed on the towel of squeezing, after draining 10min, sample is blotted with sponge The residual moisture of adsorption.After each surface of sample at least absorbs water twice, its wet weight G1 is weighed immediately, is accurate to 0.1g.

The water absorption rate of sample is calculated by formula, is accurate to 0.1%

In formula, w- inhales the water rate of sample, unit %；The wet quality of G1- samples, unit g；The absolute dry mass of G0- samples, it is single Position g.

(3) radionuclide is limited the quantity：

External Exposure Index (internal exposure index) refers to Natural Radionuclides of Building Materials radium-226 Specific radioactivity divided by this standard as defined in limitation obtained by quotient.

--- External Exposure Index；

--- the specific radioactivity of Natural Radionuclides of Building Materials radium-226, unit are Becquerel/kilogram (Bq kg^-1)；

200 --- in only considering under radiation situation.Radionuclide radium-226 puts in construction material as defined in this standard Penetrating property specific activity is limited the quantity, and unit is Becquerel/kilogram (Bqkg^-1)。

Outreach services (external exposure index) refer to Natural Radionuclides of Building Materials radium- 226, the specific radioactivity of thorium -232 and kalium-40 respectively divided by its respectively individualism when this standard regulation limitation obtained by quotient The sum of.

--- Outreach services：

--- it is respectively the specific radioactivity of Natural Radionuclides of Building Materials radium-226, thorium -232 and kalium-40, Unit is Becquerel/kilogram (Bqkg^-1)；

370,260,4200 --- it is respectively in the case of only considering external exposure, naturally to be put in construction material as defined in this standard Penetrating property nucleic radium-226, thorium -232 and kalium-40 are limited the quantity in its respectively individualism as defined in this standard, and unit is Becquerel/thousand Gram (Bqkg^-1)。

Specific radioactivity (specific activity) refers to certain nuclide radiation quality activity divided by the object in substance Quotient obtained by the quality of matter.

Expression formula is：C=A/m

In formula：C --- specific radioactivity, unit are Becquerel/kilogram (Bqkg-1)；A --- nuclide radiation quality activity, Unit is Becquerel (Bq)；The quality of m --- substance, unit are kilogram (kg).

Two, Mechanics Performance Testing

This experiment take specification be 40mm × 40mm × 160mm mold molding be made standard based on graphene and stone material Foamed wall slab, three samples of one-pass molding, sample obtain standard sample after demoulding, by a series of processing.

(1) flexural strength：Center in specimen length direction, measures the width of sample upper and lower surface, and width takes two The arithmetic mean of instantaneous value of secondary measured value, is accurate to 0.5mm.Center in specimen length direction measures the thickness of sample two sides Degree, thickness take the arithmetic mean of instantaneous value of measured value twice, are accurate to 0.1mm.Distance is 100mm between adjusting two bearing roll shafts, will Sample is symmetrically placed on the bearing roll shaft of Intensity of Breaking Tester, opens power supply, starts Intensity of Breaking Tester, is adjusted and is applied load speed Degree, it is (10 ± 1) mm/min to make pressurization roll shaft decrease speed.Until sample fractures, the maximal destruction load of sample at this time is recorded P is accurate to 1N.Every group of three, sample calculates the arithmetic mean of instantaneous value of the flexural strength value of 3 test specimens, to indicate this group of sample Flexural strength is accurate to 0.01MPa.The flexural strength R of sample is calculated as follows, and is accurate to 0.01MPa：

In formula,

R：The flexural strength of sample, units MPa；

P：The breaking load of sample, unit N；

L：Undersetting roll shaft center spacing, unit mm；

b：Specimen width, unit mm；

h：Sample thickness, unit mm.

(2) compression strength：In upper and lower two compression face of sample away from measuring length and width, length with straight steel ruler at the 10mm of side It is respectively the arithmetic mean of instantaneous value for four measured values with width, is accurate to 1mm.Straight steel ruler is used in the middle part of two corresponding side surfaces of sample Thickness is measured, thickness takes the arithmetic mean of instantaneous value of two measured values, is accurate to 1mm.The 6 pieces of half blocks left during flexural strength is tested Test specimen is individually placed on the bearing plate of hydraulic pressure testing machine, and sample center is made to test the center of machine bearing plate with hydraulic pressure It overlaps.Power supply is opened, oil pump is started, sample is made to increase, when top board is soon contacted with sample, slows down the speed of sample rising Degree, is conveniently adjusted the balance of sample on pedestal, sample compression face is made to be contacted as possible with top board uniformly.Then with (10 ± 1) mm/ Min speed pressurizes to sample, until test specimen destroys.The arithmetic mean of instantaneous value for calculating the compression strength value of 6 pieces of half block test specimens, to indicate The compression strength of this group of sample, is accurate to 0.01MPa.Test specimen compression strength σ is calculated as follows, and is accurate to 0.01MPa：

In formula, σ：Compression strength, units MPa；P：Breaking load, unit N；S：Test specimen compression area, unit mm²。

(3) Determination of conductive coefficients：The size of test sample is 200mm × 200mm × 10mm.The assay method of thermal coefficient According to GB/T10294-2008《Technology of Steady State Thermal Resistance of Thermal Insulating Material and measurement in relation to characteristic》Method carries out, and Measured Results of Thermal Conductivity result is The average value of two test results is accurate to 0.001W/ (mK).

Table 5

By upper table data it is found that is obtained after present embodiment formula composition and proportioning combination is steeped based on graphene and stone material Lightweight wall plate after tested, is distinguished less consistent in combustion rating；The lightweight wall plate of the application is in bulk density 170-800kg/ m³, compression strength >=5MPa, flexural strength >=2.5MPa, conduction heat transfer coefficient≤2.0W/m DEG C, A1 grades of combustion rating, oise insulation factor >=35dB, water absorption rate < 0.1% are more excellent than comparative example on physical and mechanical properties.

It is gradually increased on compression strength, flexural strength from embodiment 1,2,3,4,5 as graphene dosage increases , but thermal coefficient increases as graphene dosage increases；Being seen after being added to expanded graphite from embodiment 1,2 can be The numerical value of thermal coefficient being controlled, and the amount embodiment 2 for adding expanded graphite is higher by embodiment 1 twice, thermal coefficient reduces faster, It illustrates that expanded graphite has certain abirritation, therefore strictly to control graphene and expansion when carrying out raw material configuration The ratio of graphite cannot pursue the promotion of compression strength, flexural strength simply, and the problem of have ignored thermal coefficient, therefore this Apply for that the ratio in configuration graphene and expanded graphite is obtained by countless orthogonal tests, both can guarantee that compression strength, anti-folding are strong Degree improves can reduce thermal coefficient again.

And embodiment 7,8,9,10 bulk density, compression strength, flexural strength, conduction heat transfer coefficient, combustion rating, Oise insulation factor, water absorption rate, which are compared, has superior numerical value, and stone material tailing also passes through modification before compounding, by having richness Some metallic elements can be removed after collecting the microorganism enrichment processing of the substance of specific certain metals so that stone material tailing is purer Only, between so that stone material tailing is uniformly embedded in macromolecule in later stage high-temperature calcination after the additional milled processed by sunflower oil, shape It reticulates structure and increases bulk density, reduce water absorption rate.The invention that the Chinese Patent Application No. that compares is 201610090524.3 A kind of cement base foamed light composite material and preparation method are disclosed, the bulk density of the application, compression strength, anti-folding are strong Degree, conduction heat transfer coefficient, combustion rating, oise insulation factor, water absorption rate are superior to Chinese patent 201610090524.3, give prominence to the key points It is far longer than Chinese patent 201610090524.3 in bulk density.The Chinese Patent Application No. that compares is 201610258377.6 A kind of bulk density of light cellular partition board the application of addition loofah fiber of disclosure of the invention, compression strength, flexural strength, Conduction heat transfer coefficient, combustion rating, oise insulation factor, water absorption rate are superior to Chinese patent 201610258377.6, especially in water absorption rate The upper equal < 0.1% of the application, and 201610258377.6 water absorption rate of Chinese patent still reaches 21.4%, therefore, uses this Shen Compared with the prior art technical solution please has greatly improved in each physical characteristic and mechanical characteristic.

In embodiment 1-18 radionuclide limitation meet national regulation in the range of, the embodiment that compares 7,8,9, Radionuclide limitation in 10 includes IRa (External Exposure Index) and IRa (Outreach services) all than embodiment 1-6,11-18 It is small, because of the rare earth metal content in it can greatly reduce tailing after carrying out washup recovering rare earth metal, it is well known that, There are many type of radiation metal, and cannot pass through a kind of method can remove, but the modification Jing Guo the application, moreover it is possible to reduce The content of radiation metal so that the wallboard radiation smaller being prepared has been truly realized environmentally protective effect.

Same as Example 7 in raw material in comparative example 2, difference is：The preceding thalline of bacterium solution configuration of viscous pseudomonad is also By activation culture, extracted without containing extract of soybean, fructus schisandrae in the culture medium prescription that the activation culture culture uses Object is replaced using glucose band.Escherichia coli also pass through activation culture, the activation culture before the bacterium solution configuration of Colibacter It cultivates in the culture medium prescription used without containing extract of soybean, Radix Schisandrae Bicolori extract, is replaced using glucose band.And Strain during modification adds activation step, and plant polyose has been used to substitute conventional carbon source (glucose in the culture medium of activation Deng), it is found that the strain after activation has the metallic element ability in more excellent absorption tailing；It was found that the activation of embodiment 7 Strain afterwards compares comparative example 2 with the metallic element ability in more excellent absorption tailing so that the huge sum of money in raw material Belonging to content reduces.

In addition it gives the wallboard that embodiment 1 is prepared to coherent detection center to be detected, the result and data of detection Such as following table：

As seen from the above table, the wallboard produced using the technical solution of the application meets national construction engineering quality prison Superintend and direct inspection center BETC-JN1-2017-00003, national building engineering quality supervision inspection center BETC-JN1-2017- 00004, the standard of national building engineering quality supervision inspection center BETC-JN1-2017-00004.Embodiment 2-17 is by inspection Survey also meets above-mentioned standard and does not just enumerate one by one.

Present embodiment also provides a kind of assembly method of concrete structure assembled architecture system 100, including following step Suddenly：

It is laid with prefabricated foundation 1；

The concrete structure column 7 of one end of concrete prefabricated reinforcing prop 2 and prefabricated foundation 1 is used into bonding agent, such as water Cement mortar, structure glue or ceramic tile gelling agent is cast-in-place is fixedly connected；

The concrete girder 20 of precast beam and concrete prefabricated reinforcing prop 2 are passed through into bonding agent, such as cement mortar, structure Glue or the cast-in-place mode of ceramic tile gelling agent are fixed；

Two blocks of adjacent wallboards are mutually spliced or are bonded, anchoring steel structure 4 is plugged in bar planting hole 28, with bonding agent, Such as the gap in cement mortar, structure glue or ceramic tile gelling agent filling bar planting hole 28, added with concrete prefabricated with connecting wallboard Strong column 2；The plug connector 21 of the plug division 29 of wallboard and precast beam is subjected to grafting, then uses bonding agent, such as cement mortar, knot Structure glue or the cast-in-place fixation of ceramic tile gelling agent, to connect wallboard and precast beam；

Precast floor slab 17 is supported on the concrete girder 20 of precast beam, and is passed through with the concrete girder of precast beam 20 Bonding agent, such as cement mortar, structure glue or the cast-in-place mode of ceramic tile gelling agent connect.

Anti-seismic performance is tested：This test is tested with 15 meters of high buildings, is pressed《Standard for earthquakeresistant evaluation of buildings》 GB50023-2009 carries out compound seismic capability analysis using identification method step by step accordingly, to compare comparative example 1-2 and this The anti-seismic performance of concrete structure assembled architecture system in invention first embodiment, wherein comparative example 1 and the present invention first The structure of concrete structure assembled architecture system 100 in embodiment is roughly the same, the difference is that, in comparative example 1 Its concrete prefabricated reinforcing prop is connect with wallboard by mortar；Comparative example 2 and the concrete knot in first embodiment of the invention The structure of structure assembled architecture system 100 is roughly the same, the difference is that, its precast beam does not include plug connector in comparative example 2 21, it is directly connect by mortar with wallboard by concrete girder 20.Test result shows, it is anti-for the building in comparative example 1 Earthquake degree is about 6 degree, and building its seismic degree in comparative example 1 is about 5 degree, the concrete structure dress in first embodiment of the invention With formula building system, its seismic degree is 9 degree or more, and compared to the building system in comparative example 1-2, its seismic degree improves a lot.

Second embodiment

Figure 16 to Figure 17 is referred to, second embodiment of the invention provides a kind of concrete structure assembled architecture system, Its structure is roughly the same with the structure of concrete structure assembled architecture system 100 in first embodiment, and difference exists In：When in the precast beam 18 of outside plug connector 21 structure, in the present embodiment, plug connector 21 is that side is logical.Fang Tongtong crosses spiral shell Bolt fixing piece 57 is bolted with concrete girder 20 backwards to the side of precast floor slab 17.Plug division 29 is a container, and side is logical to be plugged In in container, concrete girder 20 is supported in side of the Side fascia 23 towards precast beam, concrete girder 20 and Fang Tongjun with Side fascia 23 passes through bonding agent, such as cement mortar, structure glue or the cast-in-place fixation of ceramic tile gelling agent.It is pre- that grouting seam 47 is located at waterproof Between product 43 and Side fascia 23.Second is that the connection type of precast floor slab 17 and the Side fascia 23 being positioned above, in this implementation In mode, precast floor slab 17 is connect with the Side fascia 23 being positioned above by prefabricated component 36, specially：Positioned at the precast floor slab The Side fascia 23 of 17 tops is equipped with mounting groove 37, and mounting groove 37 is located at Side fascia 23 towards the side of accommodation space.Prefabricated component 36 include fixed plate 38, the first bolt 39 and the second bolt 40.The substantially L-shaped plate of fixed plate 38 comprising two pieces vertically connect The first fixed plate 41 and the second fixed plate 42 connect.Fixed plate 38 is contained in the mounting groove 37, and the first fixed plate 41 is resisted against On the side wall of mounting groove 37, the second fixed plate 42 is resisted against on precast floor slab 17.First bolt 39 wears the first fixed plate successively 41 and Side fascia 23, the second bolt 40 wear the second fixed plate 42 and be plugged in precast floor slab 17, to by precast floor slab 17 It links together with the Side fascia 23 above the precast floor slab 17.

Third embodiment

Figure 18 is referred to, third embodiment of the invention provides a kind of concrete structure assembled architecture system, structure It is roughly the same with the structure of concrete structure assembled architecture system 100 in first embodiment, the difference is that internal The structure of plug connector 21 in precast beam 19：In the present embodiment, plug connector 21 is that side is logical.Fang Tongtong cross bolt retainer 57 with Concrete girder 20 is bolted backwards to the side of precast floor slab 17.Plug division 29 is a container, and side is logical to be inserted in container, is mixed Solidifying soil girder 20 be supported in side of the lining 24 towards precast beam, concrete girder 20 and Fang Tongjun pass through with lining 24 it is viscous Connect agent, such as cement mortar, structure glue or the cast-in-place connection of ceramic tile gelling agent.

4th embodiment

Figure 19 is referred to, four embodiment of the invention provides a kind of concrete structure assembled architecture system, structure It is roughly the same with the structure of concrete structure assembled architecture system 100 in first embodiment, the difference is that outside The structure of plug connector 21 in precast beam 18：In the present embodiment, plug connector 21 includes L-type prefabricated component 212 and bar planting fixing piece 215.L-type prefabricated component 212 is using concrete prefabricated comprising two blocks of first side plates 213 and the second side plate being mutually connected vertically 214.Second side plate 214 is bolted part 57 and is bolted with concrete girder 20.The plug division 29 of Side fascia 23 is plugged in In the space that side plate 213 and the second side plate 214 surround, and pass through bonding agent, example with the first side plate 213 and the second side plate 214 Such as cement mortar, structure glue or the cast-in-place fixation of ceramic tile gelling agent.Bar planting fixing piece 214 is located at plug division 28 backwards to the first side plate 213 side, bar planting fixing piece 214 and concrete girder 20 anchor, and pass through with L-type prefabricated component 212 and plug division 29 Nian Jie Agent, such as cement mortar, structure glue or the cast-in-place fixation of ceramic tile gelling agent.

5th embodiment

Figure 20 is referred to, fifth embodiment of the invention provides a kind of concrete structure assembled architecture system, structure It is roughly the same with the structure of concrete structure assembled architecture system in first embodiment, the difference is that internal prefabricated The structure of plug connector 21 in beam 19：In the present embodiment, the plug connector 21 of inside precast beam 19 is U-shaped fixing piece.It is U-shaped solid Part is determined using concrete prefabricated.U-shaped fixing piece is bolted part with concrete girder 20 backwards to the side of precast floor slab 17 57 bolts.Plug division 29 is plugged in the grafting space that U-shaped fixing piece is formed, and passes through bonding agent, such as water with U-shaped fixing piece Cement mortar, structure glue or the cast-in-place fixation of ceramic tile gelling agent.

Sixth embodiment

Figure 21 is referred to, sixth embodiment of the invention provides a kind of concrete structure assembled architecture system, structure It is roughly the same with the structure of concrete structure assembled architecture system in first embodiment, the difference is that concrete master The connection type of beam 20 and precast floor slab 17：In the present embodiment, concrete girder 20 passes through prefabricated company with precast floor slab 17 Fitting 22 is attached, and prefabricated connector 22 uses fourth of the twelve Earthly Branches hook spiral.Fourth of the twelve Earthly Branches hook spiral insertion precast floor slab 17 and coagulation In native girder 20, to connect concrete girder 20 and precast floor slab 17.In the present embodiment, along the arrangement of thickness of wall body direction Junction between two adjacent sub- wallboards 25 is located at side of 54 central axis of arc panel far from the accommodation space, this kind of structure Arc panel 54 can be utilized to stop that the infiltration inside house enters within doors, for example, penetrating into wall when cleaning in blocking house Water enter within doors so that building has preferably water resistance.

7th embodiment

Seventh embodiment of the invention provides a kind of concrete structure assembled architecture system, structure and the first embodiment party The structure of concrete structure assembled architecture system in formula is identical, the difference is that the material of wallboard, in present embodiment In, Side fascia 23 and lining 24 are all made of based on graphene and nonmetallic tailings foamed wall slab, according to weight percent Meter, including nonmetallic tailings 55-75%, graphene 0.05-15%, vermiculite 1-15%, high temperature cosolvent 0.05-15%, resistance to height Warm fiber 5-20%, foaming agent 0.05-5%, zirconium oxide 1-20%, clay 1-10%, stabilizer 0.05-5%, degumming agent 0.05-5%.

It further illustrates, the nonmetallic tailings refer to granite, feldspar, quartz, sandstone, diabase, shale, Dali One or more of rock, basalt, limestone, gangue, coal mine waste residue, ceramic waste residue, Desert Sand.

It further illustrates, the nonmetallic tailings also pass through modification before compounding, and the modification is specific as follows： By either Pseudomonas taetrolens or Pseudomonas pseudoflava or the soft corruption of pineapple of nonmetallic tailings, brown sugar water, strawberry pseudomonad Sick leave monad, Colibacter are 200 according to weight ratio:20:0.2:0.3 build heap mixing, then will that treated is non- Metal tailings are crushed, and are then ground and 1-3 minutes and then are sieved with 100 mesh sieve, then by the nonmetallic tailings after sieving into Row bacterial screening detaches strain with nonmetallic tailings, leaves nonmetallic tailings and can be obtained modified nonmetallic tailings.

It further illustrates, either Pseudomonas taetrolens or Pseudomonas pseudoflava or pineapple are soft for the strawberry pseudomonad It is 2.01 × 10 that maize ear rot pseudomonad or Colibacter, which are arranged to effective bacteria containing amount,⁸-5.99×10⁸The bacterium solution of a/mL into It exercises and uses.

It further illustrates, either Pseudomonas taetrolens or Pseudomonas pseudoflava or pineapple are soft for the strawberry pseudomonad Thalline also passes through activation culture, the culture medium prescription that the activation culture culture uses before the bacterium solution configuration of maize ear rot pseudomonad For：Gelatin peptone 16.0g, tryptone 10.0g, extract of soybean 10-20g, vegetable seed extract 5-15g, K₂SO₄ 10.0g、 MgCl₂1.4g, agar 15g, cetrimonium bronmide 0.2g, pH 7.1 ± 0.2.

It further illustrates, the content containing soybean polyoses reaches 90% or more in the extract of soybean；Vegetable seed extract In the content containing rapeseed polysaccharides reach 95% or more.

It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution configuration of the Colibacter The culture medium prescription used is cultivated in culture：Tryptone 10g/L, extract of soybean 5-8g/L, vegetable seed extract 3-10g/L, Sodium chloride 10g/L, pH 7.4 ± 0.2.

It further illustrates, the clay includes one or more of yellow mud, red soil, manganese mud and kaolin.

It further illustrates, the fluxing agent includes one or more of calcination of talc, raw talcum, fluorite, diopside.

It further illustrates, the foaming agent is one or more of expanded graphite, silicon carbide, carbon dust, expanded perlite.

Preparation method based on graphene Yu nonmetallic tailings foamed wall slab as described above, preparation method include such as Lower step：

S1, washup：After nonmetallic tailings are smashed it through 1-10 mesh, the nonmetallic tailings after crushing are sent into fermentation vat In, fermentation vat is cone cylinder, the 1/5-1/3 of a diameter of base diameter of feeding mouth, in the high pressure that the inside front of feeding mouth is arranged The ammonium oxalate solution that waterpipe high-pressure fog mass concentration while being sent into nonmetallic tailings is 1.5-5.5% carries out spraying and beats It is wet, until the volume of the ammonium oxalate solution of spraying can stop spraying process after being 1.1-1.32 times of nonmetallic tailings volume, 30-100min is impregnated, a material is stirred at interval of 5min in soak period, is then separated by solid-liquid separation, ammonium oxalate will be contained Filtrate is siphoned into catch basin, and is separated by solid-liquid separation after taking filtrate to be washed, and repeats the step of 2-3 washing is separated by solid-liquid separation, It is returned after the washing filtrate of separation is merged and repeats next time to use when washup, the solid after washing is dried after obtaining washing Nonmetallic tailings after it is for use；

S2, raw material add other auxiliary materials mixing dry method to found powder-grinding：First weigh 30% nonmetallic original of weight in good formula Material (in addition to high-temperature fibre) is pre-mixed with other raw materials, and the weight ratio of premixing raw material is made to account for formula material total weight 30%, after batch mixer mixes, be transferred in raw material roll-over homogenizing into premix, then with remaining 70% nonmetallic tailings Raw material on cross section by uniformly proportioning, be put into vertical mill Vertical Mill together, obtain fineness be 300 mesh full by Vertical Mill raw material Powder is transferred to excessive homogenizing bin, is granulated by granulating system, fluidisation, dry, screening obtain granulating raw material, then by high-temperature fibre Raw material obtains base-material after mixing with granulating raw material, is delivered to raw material finished product storage warehouse；Mixing machine incorporation time is 10-300 Minute, Vertical Mill incorporation time is 10-600 minutes；

S3, cloth：Base-material is subjected to automatic drying cloth, is put into roller kilns or tunnel oven, through 900-1300 DEG C, After 30-300 minutes high temperature firings, it is taken out, is made based on graphene and nonmetallic tailings foamed light by kiln cooling Wallboard crude product；

S4, crude product pass through excision forming, obtain based on graphene and nonmetallic tailings foamed wall slab finished product.

It further illustrates, in S3, the time of high temperature firing is 100-150 minutes.

It further illustrates, in S4, is based on graphene and nonmetallic tailings foamed wall slab product specification：It is long：2400- 3000mm, width：600-1200mm, thickness：80-600mm.

1, graphene is a kind of two dimensional crystal, is arranged according to hexagon by carbon atom, is connected with each other, and a carbon is formed Molecule, structure are highly stable；As the amount of carbon atom connected is on the increase, this two-dimensional carbon molecules plane constantly expands Greatly, molecule also constantly becomes larger.Only there are one the thickness of carbon atom for single-layer graphene, i.e., 0.335 nanometer, are equivalent to hair The thickness of 20 a ten thousandths nearly has 1,500,000 layers or so of graphene in the graphite of 1 millimeters thick.Graphene is known most thin A kind of two-dimensional material, and have many advantages, such as high specific surface area and intensity.Each raw material phase in formula in the present invention Mutually auxiliary plays the effect of anti-aging, anticorrosive energy, heat-insulation and heat-preservation, sound insulation, water proof anti-seepage, fireproof, high-strength light, special It is not to have breakthrough discovery, fire endurance that can reach 120min on fire endurance.First, various nonmetallic tailings are base Material, and graphene is added, improve the hardness, high temperature resistant and flame retardant property of wallboard；It overcomes organic material and is afraid of open fire, change easy to aging The deadly defect of shape, improves the fire protecting performance of inorganic material, and compensates for the defect of inorganic material poor compatibility；Hua Gang The nonmetallic tailings such as rock, shale have higher hardness, fire prevention and higher compressive property, to assign wallboard stabilization, resistance to height The performances such as mild fire prevention.Meanwhile base material is done using various nonmetallic tailings, be conducive to ecological environmental protection, effectively improve resource Comprehensive utilization is turned waste into wealth, and production cost is largely saved；By using expanded graphite as foaming agent, and mutually tied with foam stabilizer It closes, realizes the pore structure grain size exquisiteness formed it into the integrally-built Effective Regulation of wallboard during pore structure and foaming, distribution Uniformly, wallboard shape is regular, aligned orderly so that wallboard has cross-linked structure, and wallboard strength and tough is improved to reach The purpose of property；Additional nonmetallic tailings addition graphene is changed by chemical oxidization method non-in the high temperature environment with expanded graphite The property of metal tailings outer surface, it is easier to and rapid in foaming process and other raw material of substance with other substance association reactions In conjunction with expanding the foaming aperture size of nonmetallic tailings, but foaming aperture size can not be excessive, causes the wall prepared Plate outside face is uneven, aperture is uneven, therefore zirconium oxide is added while adding graphene, expanded graphite, calcium carbonate, glues The gap during nonmetallic tailings reduce foaming between nonmetallic tailings is changed in hot environment after soil progress Vertical Mill, and can be changed Micro- composition in nonmetallic tailings, improves the inoxidizability of nonmetallic tailings itself, and the degree for controlling foaming is also wanted Addition stabilizer ensures that the stability in reaction between each ion so that face is relatively flat outside foamed wall slab, reduce into Six plate thicknesses for being cut into finished product of one step, the high temperature cosolvent of addition can be rapidly performed by instead in hot stage Answer, the gap that is formed during foaming is fine and smooth uniformly, each raw material carry out Vertical Mill reach 300 mesh full by, then homogenizing is granulated, Intermolecular active force strengthens, under high temperature environment, although intermolecular be interrupted, the stronger particle of molecular force of homogenizing Still there is mutual power, raw material each in this way can uniformly fill the wallboard so that being made on a large scale during reacting, Plane of structure, vertical face are all uniform smooth, are not in the phenomenon of large-area concave-convex injustice, will not be as common raw material is in high temperature action Under, it is intermolecular to be kept completely separate, arbitrarily flow so that the substance disunity of each of entire product place filling, and add One of raw material is that high-temperature fibre (arbitrarily selects one in high aluminium profiles ceramic fibre, zirconium shield fiber, quartz fibre, basalt fiber Kind or a variety of compositions), other raw materials are granulated before this among manufacture craft, then cloth after directly being mixed with high-temperature fibre Material, the bubble formed during foaming can closely connect under the traction of high-temperature fibre, and obtained wallboard to be prepared has Superior resistance to compression, flexural strength, the advantages of will not being broken because of high-temp combustion during encountering fire.It is being detected number According to when, thermal coefficient, bulk density, compression strength, flexural strength have larger difference；The present invention be prepared based on stone Black alkene and nonmetallic tailings foamed wall slab after tested, bulk density 170-750kg/m³, compression strength >=5MPa, resist Roll over intensity >=2.5MPa, conduction heat transfer coefficient≤2.0W/m DEG C, A1 grades of combustion rating, oise insulation factor >=35dB, water absorption rate < 0.1%, fire endurance >=2h, radionuclide limitation (interior photograph, outer photograph)≤1.0；With more excellent anticorrosive, anti-ageing The advantages that change, insulation, sound insulation, fire prevention, waterproof, impervious, antidetonation, cracking resistance, high-strength light, green safe environmental protection.

2, in the method for the preparation of present embodiment, ammonium oxalate washing step is also carried out for nonmetallic tailings, can be returned It receives and utilizes rare earth metal such as scandium (Sc), yttrium (Y), lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), the promethium in nonmetallic tailings (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu) etc. So that nonmetallic tailings are eliminating rare earth metal, radiation is reduced, realizes really environmentally protective construction material purpose.Through It crosses in the liquid that filtrate of the detection containing ammonium oxalate is siphoned into catch basin, the content of rare earth reaches 0.685g/L-0.842g/L. Nonmetallic tailings can remove the remaining of the ammonium oxalate in nonmetallic tailings by washing process simultaneously, and wash liquid energy recycling and repeat It recycles, Extraction of rare earth metal recycling is first carried out when water lotion middle rare earth tenor is high, secondary pollution will not be caused.

3, when using graphene made from present embodiment and nonmetallic tailings Foam light partition board, because this wallboard produces Product integrate the feature of the required various functions of Green energy-saving buildings, and it is small, occupy that space is few, own wt Gently, wet work and fragmentary building construction are not needed, it is often more important that a large amount of sandstone cement need not be used.Exterior wall does not need Increase cement mortar batch time screed-coat, it also need not secondary construction and installation heat insulation layer again.Working procedure is simple and convenient, significantly Reduce building wall board construction cost cost.This wallboard product can directly as traditional architecture, assembled architecture inside and outside wall board every The integrated assembling installation that walling material is built can meet building heat preservation heat-insulating decorative integrative installation technology effect；Especially It is to be greatly improved building course using the inside and outside wall board product of the present invention during assembled architecture builds construction and installation Assembly rate shortens the integral construction duration, largely reduces artificial, saving material, saves and build construction cost, synthesis improves total Body construction safety quality.And application this wall board material building waste can very recycling, really realize Less manpower saves cost, environmentally protective, energy-efficient industrialized building target economic, safety is beautiful.To traditional architecture wall material The revolution of material has sexually revised profound significance, and personalized designs, industrialized production, letter are realized to the build model of traditional architecture Breathization management, prefabricated construction reach the target of sustainable development.

With reference to embodiment, in the 8th embodiment that the present invention is further explained based on graphene and nonmetallic tailings Foamed wall slab.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to limit this Invention.The chemical composition of tailing used in following embodiments is SiO₂< 65%, Al₂O₃> 2%, Fe₂O₃< 3%, K₂O < 5%, Na₂O < 5%, CaO < 5%, MgO < 2%, loss on ignition < 10%, rare earth content 1.246g/L-1.784g/L.

Embodiment 1

One, raw material proportioning is shown in Table 6；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature fluxing agent To be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is yttrium oxide and cerium oxide.

Two, it prepares：

S1, washup：After nonmetallic tailings are smashed it through 1 mesh, the nonmetallic tailings after crushing are sent into fermentation vat, leaching It is to bore cylinder to steep pond, the 1/5 of a diameter of base diameter of feeding mouth, it is being sent in the high-pressure water pipeline that the inside front of feeding mouth is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 1.5% while entering nonmetallic tailings carries out spraying and drenches, until spraying The volume of ammonium oxalate solution can stop spraying process after being 1.1 times of nonmetallic tailings volume, 30min be impregnated, in soak period A material is stirred at interval of 5min, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and is taken Filtrate is separated by solid-liquid separation after being washed, and is repeated 2 times the step of washing is separated by solid-liquid separation, and is returned after the washing filtrate of separation is merged It repeats next time to use when washup, the solid after washing is dried after the nonmetallic tailings after being washed for use；

S2, raw material add other auxiliary materials mixing dry method to found powder-grinding：First weigh 30% nonmetallic original of weight in good formula Material (in addition to high-temperature fibre) is pre-mixed with other raw materials, and the weight ratio of premixing raw material is made to account for formula material total weight 30%, after batch mixer mixes, be transferred in raw material roll-over homogenizing into premix, then with remaining 70% nonmetallic tailings Raw material on cross section by uniformly proportioning, be put into vertical mill Vertical Mill together, obtain fineness be 300 mesh full by Vertical Mill raw material Powder is transferred to excessive homogenizing bin, is granulated by granulating system, fluidisation, dry, screening obtain granulating raw material, then by high-temperature fibre Raw material obtains base-material after mixing with granulating raw material, is delivered to raw material finished product storage warehouse；Mixing machine incorporation time is 10 minutes, Vertical Mill incorporation time is 10 minutes；

S3, cloth：Base-material is subjected to automatic drying cloth, is put into roller kilns or tunnel oven, through 900 DEG C, 30 minutes After high temperature firing, it is taken out, is made based on graphene and nonmetallic tailings foamed wall slab crude product by kiln cooling；

S4, crude product obtain specification by excision forming and are：It is long：3000mm, width：1200mm, thickness：80mm obtains base In graphene and nonmetallic tailings foamed wall slab finished product.

Embodiment 2

Two, it prepares：

S1, washup：After nonmetallic tailings are smashed it through 10 mesh, the nonmetallic tailings after crushing are sent into fermentation vat, Fermentation vat is to bore cylinder, the 1/3 of a diameter of base diameter of feeding mouth, exist in the high-pressure water pipeline that the inside front of feeding mouth is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 5.5% while being sent into nonmetallic tailings carries out spraying and drenches, until spraying Ammonium oxalate solution volume be 1.32 times of nonmetallic tailings volume after can stop spraying process, impregnate 100min, soaking The bubble phase stirs a material at interval of 5min, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, And be separated by solid-liquid separation after taking filtrate to be washed, it is repeated 3 times the step of washing is separated by solid-liquid separation, after the washing filtrate of separation is merged It returns and repeats next time to use when washup, the solid after washing is dried after the nonmetallic tailings after being washed for use；

S2, raw material add other auxiliary materials mixing dry method to found powder-grinding：First weigh 30% nonmetallic original of weight in good formula Material (in addition to high-temperature fibre) is pre-mixed with other raw materials, and the weight ratio of premixing raw material is made to account for formula material total weight 30%, after batch mixer mixes, be transferred in raw material roll-over homogenizing into premix, then with remaining 70% nonmetallic tailings Raw material on cross section by uniformly proportioning, be put into vertical mill Vertical Mill together, obtain fineness be 300 mesh full by Vertical Mill raw material Powder is transferred to excessive homogenizing bin, is granulated by granulating system, fluidisation, dry, screening obtain granulating raw material, then by high-temperature fibre Raw material obtains base-material after mixing with granulating raw material, is delivered to raw material finished product storage warehouse；Mixing machine incorporation time is 300 points Clock, Vertical Mill incorporation time are 600 minutes；

S3, cloth：Base-material is subjected to automatic drying cloth, is put into roller kilns or tunnel oven, through 1300 DEG C, 300 points After clock high temperature firing, it is taken out by kiln cooling, is made and is slightly produced with nonmetallic tailings foamed wall slab based on graphene Product；

S4, crude product obtain specification by excision forming and are：It is long：2800mm, width：1200mm, thickness：100mm obtains base In graphene and nonmetallic tailings foamed wall slab finished product.

Embodiment 3

Two, it prepares：

S1, washup：After nonmetallic tailings are smashed it through 5 mesh, the nonmetallic tailings after crushing are sent into fermentation vat, leaching It is to bore cylinder to steep pond, the 1/4 of a diameter of base diameter of feeding mouth, it is being sent in the high-pressure water pipeline that the inside front of feeding mouth is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 3.5% while entering nonmetallic tailings carries out spraying and drenches, until spraying The volume of ammonium oxalate solution can stop spraying process after being 1.22 times of nonmetallic tailings volume, 60min be impregnated, in soak period A material is stirred at interval of 5min, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and is taken Filtrate is separated by solid-liquid separation after being washed, and is repeated 3 times the step of washing is separated by solid-liquid separation, and is returned after the washing filtrate of separation is merged It repeats next time to use when washup, the solid after washing is dried after the nonmetallic tailings after being washed for use；

S2, raw material add other auxiliary materials mixing dry method to found powder-grinding：First weigh 30% nonmetallic original of weight in good formula Material (in addition to high-temperature fibre) is pre-mixed with other raw materials, and the weight ratio of premixing raw material is made to account for formula material total weight 30%, after batch mixer mixes, be transferred in raw material roll-over homogenizing into premix, then with remaining 70% nonmetallic tailings Raw material on cross section by uniformly proportioning, be put into vertical mill Vertical Mill together, obtain fineness be 300 mesh full by Vertical Mill raw material Powder is transferred to excessive homogenizing bin, is granulated by granulating system, fluidisation, dry, screening obtain granulating raw material, then by high-temperature fibre Raw material obtains base-material after mixing with granulating raw material, is delivered to raw material finished product storage warehouse；Mixing machine incorporation time is 50 minutes, Vertical Mill incorporation time is 100 minutes；

S3, cloth：Base-material is subjected to automatic drying cloth, is put into roller kilns or tunnel oven, through 1000 DEG C, 100 points After clock high temperature firing, it is taken out by kiln cooling, is made and is slightly produced with nonmetallic tailings foamed wall slab based on graphene Product；

S4, crude product obtain specification by excision forming and are：It is long：3000mm, width：1200mm, thickness：120mm obtains base In graphene and nonmetallic tailings foamed wall slab finished product.

Embodiment 4

Two, it prepares：

S1, washup：After nonmetallic tailings are smashed it through 8 mesh, the nonmetallic tailings after crushing are sent into fermentation vat, leaching It is to bore cylinder to steep pond, the 1/3 of a diameter of base diameter of feeding mouth, it is being sent in the high-pressure water pipeline that the inside front of feeding mouth is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 4.5% while entering nonmetallic tailings carries out spraying and drenches, until spraying The volume of ammonium oxalate solution can stop spraying process after being 1.2 times of nonmetallic tailings volume, 90min be impregnated, in soak period A material is stirred at interval of 5min, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and is taken Filtrate is separated by solid-liquid separation after being washed, and is repeated 3 times the step of washing is separated by solid-liquid separation, and is returned after the washing filtrate of separation is merged It repeats next time to use when washup, the solid after washing is dried after the nonmetallic tailings after being washed for use；

S2, raw material add other auxiliary materials mixing dry method to found powder-grinding：First weigh 30% nonmetallic original of weight in good formula Material (in addition to high-temperature fibre) is pre-mixed with other raw materials, and the weight ratio of premixing raw material is made to account for formula material total weight 30%, after batch mixer mixes, be transferred in raw material roll-over homogenizing into premix, then with remaining 70% nonmetallic tailings Raw material on cross section by uniformly proportioning, be put into vertical mill Vertical Mill together, obtain fineness be 300 mesh full by Vertical Mill raw material Powder is transferred to excessive homogenizing bin, is granulated by granulating system, fluidisation, dry, screening obtain granulating raw material, then by high-temperature fibre Raw material obtains base-material after mixing with granulating raw material, is delivered to raw material finished product storage warehouse；Mixing machine incorporation time is 200 points Clock, Vertical Mill incorporation time are 400 minutes；

S3, cloth：Base-material is subjected to automatic drying cloth, is put into roller kilns or tunnel oven, through 1200 DEG C, 150 points After clock high temperature firing, it is taken out by kiln cooling, is made and is slightly produced with nonmetallic tailings foamed wall slab based on graphene Product；

S4, crude product obtain specification by excision forming and are：It is long：2400mm, width：1200mm, thickness：600mm obtains base In graphene and nonmetallic tailings foamed wall slab finished product.

Embodiment 5

One, raw material proportioning is shown in Table 6；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature fluxing agent To be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide.

Two, preparation method and embodiment 1 are same.

Embodiment 6

Two, preparation method and embodiment 1 are same.

Embodiment 7

Wherein, also pass through modification before nonmetallic tailings compounding, the modification is specific as follows：By nonmetallic tail Mine, brown sugar water, strawberry pseudomonad, Colibacter are 200 according to weight ratio:20:0.2:0.3 carries out building heap mixing, then By treated, nonmetallic tailings are crushed, and are then ground 1 minute and then are sieved with 100 mesh sieve, then will be non-after sieving Metal tailings carry out bacterial screening, strain is detached with nonmetallic tailings, leave nonmetallic tailings can be obtained be modified it is non- Metal tailings.

It further illustrates, it is 2.01 × 10 that strawberry pseudomonad, Colibacter, which are arranged to effective bacteria containing amount,⁸- 2.47×10⁸The bacterium solution of a/mL is used.

It further illustrates, thalline also passes through activation culture, the activation training before the bacterium solution configuration of the strawberry pseudomonad The foster culture medium prescription that uses cultivated is：Gelatin peptone 16.0g, tryptone 10.0g, extract of soybean 18g, vegetable seed extract 12g、K₂SO₄10.0g、MgCl₂1.4g, agar 15g, cetrimonium bronmide 0.2g, pH 7.2.

It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution configuration of the Colibacter The culture medium prescription used is cultivated in culture：Tryptone 10g/L, extract of soybean 5g/L, vegetable seed extract 3g/L, sodium chloride 10g/L、pH 7.5。

It further illustrates, the content of soybean polyoses reaches 90% or more in extract of soybean；Contain dish in vegetable seed extract The content of seed polysaccharide reaches 95% or more.

Embodiment 8

Wherein, also pass through modification before nonmetallic tailings compounding, the modification is specific as follows：By nonmetallic tail Mine, brown sugar water, Pseudomonas taetrolens, Colibacter are 200 according to weight ratio:20:0.2:0.3 carries out building heap mixing, then By treated, nonmetallic tailings are crushed, and are then ground 3 minutes and then are sieved with 100 mesh sieve, then will be non-after sieving Metal tailings carry out bacterial screening, strain is detached with nonmetallic tailings, leave nonmetallic tailings can be obtained be modified it is non- Metal tailings.

It further illustrates, it is 4.51 × 10 that Pseudomonas taetrolens, Colibacter, which are arranged to effective bacteria containing amount,⁸- 5.99×10⁸The bacterium solution of a/mL is used.

It further illustrates, thalline also passes through activation culture, the activation culture training before the bacterium solution configuration of Pseudomonas taetrolens Supporting the culture medium prescription used is：Gelatin peptone 16.0g, tryptone 10.0g, extract of soybean 13g, vegetable seed extract 7g, K₂SO₄ 10.0g、MgCl₂1.4g, agar 15g, cetrimonium bronmide 0.2g, pH 6.9.

It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution configuration of the Colibacter The culture medium prescription used is cultivated in culture：Tryptone 10g/L, extract of soybean 8g/L, vegetable seed extract 10g/L, chlorination Sodium 10g/L, pH 7.2.

It further illustrates, the content of soybean polyoses reaches 95% in extract of soybean；It is more containing vegetable seed in vegetable seed extract The content of sugar reaches 96% or more.

Embodiment 9

One, raw material proportioning is shown in Table 6；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature fluxing agent To be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide；

Wherein, also pass through modification before nonmetallic tailings compounding, the modification is specific as follows：By nonmetallic tail Mine, brown sugar water, Pseudomonas pseudoflava, Colibacter are 200 according to weight ratio:20:0.2:0.3 carries out building heap mixing, then By treated, nonmetallic tailings are crushed, and are then ground 2 minutes and then are sieved with 100 mesh sieve, then will be non-after sieving Metal tailings carry out bacterial screening, strain is detached with nonmetallic tailings, leave nonmetallic tailings can be obtained be modified it is non- Metal tailings.

It further illustrates, it is 2.87 × 10 that Pseudomonas pseudoflava, Colibacter, which are arranged to effective bacteria containing amount,⁸- 3.67×10⁸The bacterium solution of a/mL is used.

It further illustrates, thalline also passes through activation culture, the activation culture training before the bacterium solution configuration of Pseudomonas pseudoflava Supporting the culture medium prescription used is：Gelatin peptone 16.0g, tryptone 10.0g, extract of soybean 10g, vegetable seed extract 5g, K₂SO₄ 10.0g、MgCl₂1.4g, agar 15g, cetrimonium bronmide 0.2g, pH 7.3

It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution configuration of the Colibacter The culture medium prescription used is cultivated in culture：Tryptone 10g/L, extract of soybean 6g/L, vegetable seed extract 5g/L, sodium chloride 10g/L、pH 7.6。

It further illustrates, the content of soybean polyoses reaches 92% in extract of soybean；It is more containing vegetable seed in vegetable seed extract The content of sugar reaches 98% or more.

Two, preparation method and embodiment 4 are same.It is carried out between step S1 and S2 wherein in preparation method at above-mentioned modification Manage step.

Embodiment 10

Wherein, also pass through modification before nonmetallic tailings compounding, the modification is specific as follows：By nonmetallic tail Mine, brown sugar water, pineapple soft rot pseudomonad, Colibacter are 200 according to weight ratio:20:0.2:0.3 build heap mixed It closes, then by treated, nonmetallic tailings are crushed, and are then ground 3 minutes and then are sieved with 100 mesh sieve, then will sieving Nonmetallic tailings afterwards carry out bacterial screening, and strain is detached with nonmetallic tailings, nonmetallic tailings is left and can be obtained Modified nonmetallic tailings.

Further illustrate, pineapple soft rot pseudomonad, Colibacter be arranged to effective bacteria containing amount be 3.23 × 10⁸-4.15×10⁸The bacterium solution of a/mL is used.

It further illustrates, thalline also passes through activation culture, the activation before the bacterium solution configuration of pineapple soft rot pseudomonad The culture medium prescription used is cultivated in culture：Gelatin peptone 16.0g, tryptone 10.0g, extract of soybean 20g, vegetable seed extract 15g、K₂SO₄ 10.0g、MgCl₂1.4g, agar 15g, cetrimonium bronmide 0.2g, pH 7.1.

It further illustrates, Escherichia coli also pass through activation culture, the activation culture before the bacterium solution configuration of Colibacter Cultivating the culture medium prescription used is：Tryptone 10g/L, extract of soybean 7g/L, vegetable seed extract 9g/L, sodium chloride 10g/ L、pH 7.4。

It further illustrates, the content of soybean polyoses reaches 98% in extract of soybean；It is more containing vegetable seed in vegetable seed extract The content of sugar reaches 99% or more.

Embodiment 11

One, raw material proportioning and embodiment 3 are same；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature Fluxing agent is to be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide.

Two, preparation method is same as Example 3.

Embodiment 12

One, raw material proportioning and embodiment 9 are same；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature Fluxing agent is to be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide.

Two, preparation method is same as Example 4.

Embodiment 13

One, raw material proportioning and embodiment 10 are same；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The height Warm fluxing agent is to be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide.

Two, preparation method and embodiment 3 are same.

Embodiment 14

Two, preparation method is same as Example 4.

Embodiment 15

One, raw material is matched same with embodiment 3；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature helps Flux is to be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide.

Two, preparation method is same as Example 2.

Embodiment 16

Two, preparation method is same as Example 1.

Embodiment 17

One, raw material proportioning and embodiment 9 are same；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature Fluxing agent is to be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is yttrium, cerium oxide.

Two, preparation method is same as Example 1.

Embodiment 18

One, raw material proportioning and embodiment 9 are same；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature Fluxing agent is to be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is yttrium oxide.

Two, preparation method is same as Example 1.

Embodiment 19

Two, preparation method is same as Example 4.

Embodiment 20

Two, preparation method is same as Example 4.

Ingredient percentage composition (%) list in 6 each embodiment of table

Embodiment	1	2	3	4	5	6	7	8	9	10
											Nonmetallic tailings	62	75	60	55	55	65	62	51	59	57
Clay	5	3	2	4	10	1	2	9	7	2
											Graphene	6	2	5	1	0.05	0.05	1	10	3	12
High temperature cosolvent	6	5	7	1	15	0.05	1	8	3	5
											Foaming agent	3	2	3	1	5	0.05	1	4	1	1
Zirconium oxide	2	1	1	2	1.95	15.75	20	5	10	5
											Stabilizer	3	2	2	1	5	0.05	1	2	1	2
Degumming agent	2	3	2	1	1	0.05	1	1	2	3
											High-temperature fibre	10	5	8	20	6	16	6	6	9	10
Vermiculite	1	2	10	15	1	2	5	4	5	3

Nonmetallic tailings selective listing in 7 each embodiment of table

Clay selective listing in 8 each embodiment of table

Embodiment	Yellow mud	Red soil	Manganese mud	Kaolin
					1	√	--	--	--
2	--	√	--	--
					3	--	--	√	--
4	--	--	--	√
					5	√	√	√	--
6	√	√	--	√
					7	√	--	√	√
8	--	√	√	√
					9	--	√	√	--
10	--	--	√	√
					11	√	√	--	--
12	√	--	--	√
					13	--	√	--	√
14	√	--	√	--
					15	√	√	√	√
16	√	√	√	√
					17	√	√	√	√
18	√	√	--	--
					19	--	--	√	√
20	--	--	√	√

9 each embodiment high temperature cosolvent selective listing of table

Embodiment	Calcination of talc	Raw talcum	Fluorite	Diopside
					1	√	--	--	--
2	--	√	--	--
					3	--	--	√	--
4	√	√	√	--
					5	√	√	--	--
6	√	--	√	--
					7	--	√	√	--
8	√	--	--	--
					9	--	√	--	--
10	--	--	√	√
					11	√	√	√	√
12	√	√	--	√
					13	√	--	√	--
14	--	√	√	√
					15	√	--	--	--
16	--	√	--	√
					17	--	--	√	--
18	√	√	--	√
					19	--	--	√	√
20	--	--	--	√

Foaming agent selective listing in 10 each embodiment of table

Testing inspection：

By the standby obtained foamed wall slabs of embodiment 1-20 in present embodiment, comparative example, (foaming of market purchase is light Matter wallboard) by the test of physical and mechanical properties, specific method is referring to first embodiment, and test result is referring to following table.

By upper table data it is found that the bubble lightweight wall plate obtained after the formula composition of present embodiment and proportioning combination is through surveying Examination is distinguished little in combustion rating；The lightweight wall plate of present embodiment is 170-750kg/m in bulk density³, compression strength >=5MPa, flexural strength >=2.5MPa, conduction heat transfer coefficient≤2.0W/m DEG C, A1 grades of combustion rating, oise insulation factor >=35dB, water suction Rate < 0.1% is more excellent than comparative example on physical and mechanical properties.

From embodiment 5,6,2,1,3,4, sequence is as the increase of graphene amount is on compression strength, flexural strength successively It gradually increases, but as the increase thermal coefficient of amount can also improve, however pass through research and find addition expansion stone in the feed Ink can mitigate this phenomenon；Again from the point of view of embodiment 5,6,2,1,15,16 with the increase of graphene amount compression strength, It is gradually increased on flexural strength, but as the increase thermal coefficient of amount can also improve, adds the energy of expanded graphite in the feed Enough mitigate this phenomenon；Therefore in the ratio for strictly to be controlled when raw material configuration graphene and expanded graphite, Bu Nengyi Taste pursues the promotion of compression strength, flexural strength, and the problem of have ignored thermal coefficient, thus the application configuration graphene with The ratio of expanded graphite is obtained by countless orthogonal tests, not only can guarantee that compression strength, flexural strength improve but also can reduce heat conduction Coefficient.

It can be seen that being added to expansion stone in the feed in embodiment 6, (7,9,10), (1,4), 5 from embodiment 1-10 Ink, and as the increase of amount is continuously decreased in conduction heat transfer coefficient, it was demonstrated that addition expanded graphite can improve wallboard and prepare The size in aperture is finer and smoother in the process, and the porosity is high, to reduce conduction heat transfer coefficient；Embodiment 6, (7,9,10), (1, 4), embodiment 7,9,10 has more excellent performance on conduction heat transfer coefficient in 5, it was demonstrated that modified tailing is carrying out Size of the energy with finer and smoother aperture of the process of compounding fermentation, porosity higher, because after removing metal ion, the member of tailing Element is purer, until aperture is finer and smoother during foaming, the radionuclide limitation in embodiment 1-20 meets the model of national regulation In enclosing, the radionuclide limitation in the embodiment that compares 7,8,9,10 includes I_Ra(External Exposure Index) and I_Ra(external exposure refers to Number) all than embodiment 1-6,11-20 it is small because dilute in it can greatly reduce tailing after carrying out washup recovering rare earth metal Earth metal content, it is well known that, there are many type of radiation metal, and cannot pass through a kind of method can remove, but pass through The modification of the application, moreover it is possible to reduce the content of radiation metal so that the wallboard radiation smaller being prepared is truly realized Environmentally protective effect.And find embodiment 7,8,9,10 bulk density, compression strength, flexural strength, conduction heat transfer coefficient, Combustion rating, oise insulation factor, water absorption rate, which are compared, has superior numerical value, and nonmetallic tailings are before compounding also by modification Reason, by the way that some metallic elements can be removed after the microorganism enrichment processing with the substance for being enriched with specific certain metals so that Nonmetallic tailings are purer, and the strain during modification adds activation step, and plant has been used in the culture medium of activation Polysaccharide substitutes conventional carbon source (glucose etc.), it is found that the strain after activation has the metallic element in more excellent absorption tailing Ability；Nonmetallic tailings are enable uniformly to be embedded in macromolecule in later stage high-temperature calcination after the additional milled processed by olive oil Between, it forms reticular structure and increases bulk density, reduce water absorption rate.The Chinese Patent Application No. that compares is 201610090524.3 A kind of cement base foamed light composite material of disclosure of the invention and preparation method, the bulk density of the application, compression strength, anti-folding Intensity, conduction heat transfer coefficient, combustion rating, oise insulation factor, water absorption rate are superior to Chinese patent 201610090524.3, give prominence to the key points It is far longer than Chinese patent 201610090524.3 in bulk density.The Chinese Patent Application No. that compares is A kind of bulk density of light cellular partition board the application of addition loofah fiber of 201610258377.6 disclosure of the invention, resistance to compression Intensity, flexural strength, conduction heat transfer coefficient, combustion rating, oise insulation factor, water absorption rate are superior to Chinese patent 201610258377.6, the equal < 0.1% of the application especially on water absorption rate, and 201610258377.6 water absorption rate of Chinese patent is also It is to reach 21.4%, therefore, using the technical solution of the application, in each physical characteristic and mechanical characteristic compared with the prior art Have greatly improved.

Same as Example 7 in raw material in comparative example 2, difference is：The preceding thalline of bacterium solution configuration of viscous pseudomonad is also By activation culture, without containing extract of soybean, vegetable seed extract in the culture medium prescription that the activation culture culture uses, adopt It is replaced with glucose band.Escherichia coli also pass through activation culture, the activation culture culture before the bacterium solution configuration of Colibacter Without containing extract of soybean, vegetable seed extract in the culture medium prescription used, replaced using glucose band.It was found that embodiment 7 Strain after activation compares comparative example 2 with the metallic element ability in more excellent absorption tailing so that in raw material Content of beary metal reduces.

As seen from the above table, the wallboard produced using the technical solution of present embodiment meets national architectural engineering matter Measure Supervision Test Center BETC-JN1-2017-00003, national building engineering quality supervision inspection center BETC-JN1-2017- 00004, the standard of national building engineering quality supervision inspection center BETC-JN1-2017-00004.Embodiment 2-20 is by inspection Survey also meets above-mentioned standard and does not just enumerate one by one.

8th embodiment

Eighth embodiment of the invention provides a kind of concrete structure assembled architecture system, structure and the first embodiment party The structure of concrete structure assembled architecture system in formula is identical, the difference is that the material of wallboard, in present embodiment In, lining 24 and Side fascia 23 are all made of based on graphene and stone material tailing foamed light high temperature resistant wallboard, according to weight hundred Divide than meter, including stone material tailing 40%-65%, graphene 0.05%-15%, aluminium oxide 1%-30%, vermiculite 1-15%, carbonic acid Calcium 0.05%-10%, high temperature cosolvent 0.05%-15%, high-temperature fibre particle 5%-30%, foaming agent 0.05%-5%, Stabilizer 0.05%-5%, degumming agent 0.05%-5%, clay 1%-10%, the additional 0%-5% of colorant.

It is preferably based on graphene and stone material tailing foamed light high temperature resistant wallboard, in percentage by weight, including stone Material tailing 44%, graphene 6%, aluminium oxide 10%, vermiculite 10%, calcium carbonate 3%, high temperature cosolvent 4%, high-temperature fibre Grain 10%, foaming agent 3%, stabilizer 4%, degumming agent 4%, clay 2%.

It further illustrates, it is described based on graphene and stone material tailing foamed light high temperature resistant wallboard, it is characterised in that：Institute State high-temperature fibre particle in percentage by weight, including stone material tailing 10%-40%, high-temperature fibre 15%-40%, leech Stone 10-40%, expanded perlite 1%-20%, clay 1%-5%；The high-temperature fibre is by high aluminium profiles ceramic fibre, zirconium shield One or more of fiber, quartz fibre, basalt fiber form high-temperature fibre 35%-80%.

Further illustrate, the stone material tailing refer to granite, feldspar, quartz, sandstone, diabase, shale, griotte, One or more of basalt, limestone, Desert Sand.

It further illustrates, the stone material tailing also passes through modification before compounding, and the modification is specific as follows：It will Stone material tailing, brown sugar water, viscous pseudomonad either raw hole pseudomonas or pseudomonas syncyanea or Pseudomonas taetrolens, Colibacter is 100 according to weight ratio:5:0.1:0.1 carries out building heap mixing, and then by treated, stone material tailing is broken It is broken, it is then ground 1-3 minutes and then sieves with 100 mesh sieve, the stone material tailing after sieving is then subjected to bacterial screening, by strain It is detached with stone material tailing, leaves stone material tailing and can be obtained modified stone material tailing.

It further illustrates, the viscous pseudomonad either raw hole pseudomonas or pseudomonas syncyanea or rancid vacation It is 1.65 × 10 that monad or Colibacter, which are arranged to effective bacteria containing amount,⁸-6.05×10⁸The bacterium solution of a/mL is into enforcement With.

It further illustrates, the viscous pseudomonad either raw hole pseudomonas or pseudomonas syncyanea or rancid vacation Thalline also passes through activation culture before the bacterium solution configuration of monad, and the culture medium prescription that the activation culture culture uses is：Gelatin Peptone 16.0g, tryptone 10.0g, yam extract 8-15g, Radix Schisandrae Bicolori extract 8-20g, K₂SO₄ 10.0g、MgCl₂ 1.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 7.1 ± 0.2.

It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution configuration of the Colibacter The culture medium prescription used is cultivated in culture：Tryptone 5-18g/L, yam extract 1-8g/L, Radix Schisandrae Bicolori extract 3- 10g/L, sodium chloride 5-20g/L, pH 7.4 ± 0.2.

It further illustrates, the content containing Chinese yam polysaccharide reaches 88% or more in the yam extract；Fructus schisandrae carries The content containing fructus schisandrae polysaccharide in object is taken to reach 90% or more.

It further illustrates, the clay includes one or more of yellow mud, red soil, manganese mud, kaolin.

It further illustrates, the foaming agent is one or more of expanded graphite, silicon carbide, carbon dust, expanded perlite； The stabilizer is the one or more in the oxide of yttrium, cerium.

Preparation method based on graphene Yu stone material tailing foamed light high temperature resistant partition plate as described above, preparation method Include the following steps：

S2, raw material mixing：In addition to high-temperature fibre particle, remaining raw material claims by weight percent shared by each raw material is formulated Material, 3-18h is milled to ball mill or vertical mill batch mixing；Reach 250 mesh full by into rotation mixing by screening fineness of grinding Machine mixing homogenizing 10-300 minutes；

S3, the powder after mixing homogenizing is put into savings storehouse by mist projection granulating into drier；

S4, the mixing of high-temperature fibre particulate material：Stone material tailing 10%-40%, high temperature resistant are weighed according to weight percent Fiber 15%-40%, vermiculite 10-40%, expanded perlite 1%-20%, clay 1%-5% are ground with ball mill or vertical mill After crushing, fineness reach 50 mesh full by, into rotary blender mixing homogenizing 10-150 minute, obtain high-temperature fibre mix Material is stored into warehouse；

S5, by high-temperature fibre mixture by rotary kiln, through 900-1280 DEG C, high-temperature fusion calcining is 30-300 minutes high It is taken out after temperature firing is cooling, obtains high-temperature fibre particle；

S6, grain size after high-temperature fibre pellet through sieves, will be taken for the high-temperature fibre particle and the first base-material of 1-6mm Grain, which is sufficiently mixed to obtain, is granulated mixture, is stored into warehouse；

S7, cloth firing：Granulation mixture in S6 is subjected to cloth, is put into tunnel oven or roller kilns, through 900- It 1300 DEG C, after 30-300 minutes high temperature firings, is taken out by kiln cooling, is made and is foamed based on graphene and stone material tailing Lightening fire resistant partition plate crude product；

S8, crude product is molded after cutting, is obtained based on graphene and stone material tailing foamed light high temperature resistant partition plate Finished product.

It further illustrates, in S7, the time of soak firing is 100-150 minutes.

It further illustrates, in S8, is based on graphene and stone material tailing foamed light high temperature resistant partition plate product specification： It is long：2400-3000mm, width：600-1200mm, thickness：80-500mm.

It further illustrates, in S6, after high-temperature fibre pellet through sieves, it is the high-temperature fibre of 1-6mm to take grain size Grain, concrete operations are that by high-temperature fibre particle, first a matched mesh sieve can cross maximum particle diameter (6mm) to fiber grain excessively High-temperature fibre particle, but also have the high-temperature fibre that many high-temperature fibre particles less than 6mm are especially less than 1mm Particle can influence the snap-resistent ability of wallboard in this way, so the sieve that also to be looked over so as to check for the second time, selects a matched mesh sieve The high-temperature fibre particle of maximum particle diameter (1mm) cannot be crossed, the grain size then taken can be obtained the high-temperature fibre of 1-6mm Grain.

1, graphene is a kind of two dimensional crystal, is arranged according to hexagon by carbon atom, is connected with each other, and a carbon is formed Molecule, structure are highly stable；As the amount of carbon atom connected is on the increase, this two-dimensional carbon molecules plane constantly expands Greatly, molecule also constantly becomes larger.Only there are one the thickness of carbon atom for single-layer graphene, i.e., 0.335 nanometer, are equivalent to hair The thickness of 20 a ten thousandths nearly has 1,500,000 layers or so of graphene in the graphite of 1 millimeters thick.Graphene is known most thin A kind of two-dimensional material, and have many advantages, such as high specific surface area and intensity.Each raw material phase in formula in the present invention Mutually auxiliary plays the effect of anti-aging, anticorrosive energy, heat-insulation and heat-preservation, sound insulation, water proof anti-seepage, fireproof, high-strength light, special It is not to have breakthrough discovery, fire endurance that can reach 180min or more on fire endurance.Stone material tailings various first are Base material, and graphene is added, improve the hardness, high temperature resistant and flame retardant property of wallboard；It overcomes organic material and is afraid of open fire, easy to aging The deadly defect of deformation, improves the fire protecting performance of inorganic material, and compensates for the defect of inorganic material poor compatibility；Hua Gang The stone materials tailing such as rock, shale has higher hardness, fire prevention and higher compressive property, to assign wallboard stabilization, high temperature resistant With fire prevention etc. performances.Meanwhile base material is done using various stone material tailings, be conducive to ecological environmental protection, effectively improve resource comprehensive Using, largely save production cost；When the high-temperature fibre particle of addition independent research can extend heat safe in the feed Between, it is identical in raw material, it is added to the high-temperature fibre particle of independent research, compares, is added to independent research High-temperature fibre particle numerically extends 30-60 minutes in the fire endurance of script, by using expanded graphite as foaming agent, And be combined with foam stabilizer, realize the hole knot formed it into the integrally-built Effective Regulation of wallboard during pore structure and foaming Structure grain size is fine and smooth, is evenly distributed, and wallboard shape is regular, aligned orderly so that wallboard has cross-linked structure, is carried to reach The purpose of high wallboard strength and toughness；Additional stone material tailing is added graphene and passes through chemical oxygen in the high temperature environment with expanded graphite Change method changes the property of stone material tailing outer surface, it is easier to other substance association reactions, and in foaming process and other objects Matter raw material combines rapidly, expands the foaming aperture size of stone material tailing, but foaming aperture size can not be excessive, causes to prepare Face is uneven outside wallboard out, therefore zirconium oxide is added while adding graphene, expanded graphite, calcium carbonate, glues The gap during stone material tailing reduces foaming between stone material tailing is changed in hot environment after soil progress ball milling, and stone material can be changed Micro- composition in tailing improves the inoxidizability of stone material tailing itself, and stabilization will also be added by controlling the degree of foaming Agent ensures that the stability in reaction between each ion so that face is relatively flat outside foamed wall slab, and reduction is further cut Six plate thicknesses that finished product is made are cut, the high temperature cosolvent of addition can be rapidly performed by reaction in hot stage, foam The gap that period is formed is fine and smooth uniformly, and each raw material, which is ground, reaches 250 mesh full by then homogenizing is granulated, intermolecular Active force strengthens, and under high temperature environment, although intermolecular be interrupted, the stronger particle of molecular force of homogenizing still has Mutual power, raw material each in this way can uniformly fill the wallboard so that being made on a large scale during reacting, in plane of structure, vertical face It is all uniform smooth, be not in the phenomenon of large-area concave-convex injustice, it will not be intermolecular complete as common raw material is under high temperature action It is fully separating, arbitrarily flow so that the substance disunity of each of entire product place filling, when being detected data, Thermal coefficient, bulk density are, compression strength, flexural strength have larger difference；The present invention be prepared based on graphene After tested with stone material tailing foamed light high temperature resistant partition plate, bulk density 100-800kg/m³, compression strength >=5MPa, Flexural strength >=2.5MPa, conduction heat transfer coefficient≤2.0W/m DEG C, A1 grades of combustion rating, oise insulation factor >=35dB, water absorption rate < 0.1%, fire endurance >=2h, radionuclide limitation (interior photograph, outer photograph)≤1.0；With more excellent anticorrosive, anti-ageing The advantages that change, insulation, sound insulation, fire prevention, waterproof, impervious, antidetonation, cracking resistance, high-strength light, green safe environmental protection.

2, the method for the preparation in present embodiment also carries out ammonium oxalate washing step for stone material tailing, can recycle Using such as scandium of the rare earth metal in stone material tailing (Sc), yttrium (Y), lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), Samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu) etc. so that Stone material tailing is eliminating rare earth metal, reduces radiation, realizes really environmentally protective construction material purpose.Contain by detection There is the filtrate of ammonium oxalate to be siphoned into the liquid in catch basin, the content of rare earth reaches 0.598g/L-0.785g/L.Stone material simultaneously Tailing can remove the remaining of the ammonium oxalate in stone material tailing by washing process, and wash liquid energy recycling repetitive cycling and use, when Extraction of rare earth metal is first carried out when water lotion middle rare earth tenor is high, is recycled, will not be caused secondary pollution.

3, direct based on graphene and stone material tailing foamed light high temperature resistant partition plate made from application present embodiment Building partition plate is made, increases that its lightweight intensity is high, pressure-proof and snap-resistent intensity is high, has that significant anti-aging weatherability is strong, thermal insulation separation Hot sound-proofing is good, fire prevention, resistance to 1000 DEG C of high temperature, water proof anti-seepage are excellent, anticorrosive anti-mildew etc..Applying graphite produced by the present invention When alkene is with stone material tailing Foam light partition board, product of the present invention collects the required various functions of green safe energy saving building in one The characteristics of body, especially solves building materials limit gauge quality requirement of the building to fire-fighting fire-proof, fire endurance and biography thermal coefficient, With revolutionary strategic structural, it is ensured that building is to safety and energy-efficient effective guarantee.The present invention has small, occupancy building Space is few, own wt is light, does not need wet work and fragmentary building construction, it is often more important that need not use a large amount of sandstone Cement.Exterior wall need not increase cement mortar batch time screed-coat, also need not secondary construction and installation heat insulation layer again.Construction work Sequence is simple and convenient, greatly reduces building wall board construction cost cost.This wallboard product can be directly as traditional architecture, assembled The integrated assembling installation that Discussion on architecture wallboard partition material is built can meet building heat preservation heat-insulating decorative integration Installation effect；It, can be significantly using the inside and outside wall board product of the present invention especially during assembled architecture builds construction and installation The assembly rate for improving building course, shortens the integral construction duration, largely reduces artificial, saving material, saving is built into This, synthesis improves overall construction safety quality.And the building waste of this wall board material of application can be very recycled back to It receives and utilizes, really realize that less manpower saves cost, environmentally protective, energy-efficient industrialized building target economic, safety is beautiful.It is right The revolution of traditional architecture materials for wall has sexually revised profound significance, realizes that personalization is set to the build model of traditional architecture Meter, industrialized production, information system management, prefabricated construction reach the target of sustainable development.

With reference to embodiment, being sent out based on graphene and stone material tailing in the 9th embodiment that the present invention is further explained Steep lightening fire resistant wallboard.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to limit The fixed present invention.The chemical composition of stone material tailing used in following embodiments is SiO₂< 65%, Al₂O₃> 8%, Fe₂O₃< 11%, K₂O < 5%, Na₂O < 5%, CaO < 5%, MgO < 2%, loss on ignition < 18%, rare earth content 1.246g/L-1.784g/L.

Embodiment 1

One, raw material proportioning is shown in Table 11；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The high temperature is fluxing Agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is yttrium oxide and cerium oxide.

Two, it prepares：

S2, raw material mixing：In addition to high-temperature fibre particle, remaining raw material claims by weight percent shared by each raw material is formulated Material, 3h is milled to ball mill or vertical mill batch mixing；Reach 250 mesh full by into rotary blender by screening fineness of grinding Mixing homogenizing 10 minutes；

S3, the powder after mixing homogenizing is obtained into the first base granule by being granulated, into drier, is put into savings Storehouse；

S4, the mixing of high-temperature fibre particulate material：Stone material tailing 10%, high-temperature fibre are weighed according to weight percent 40% (high-temperature fibre is made of high aluminium profiles ceramic fibre, zirconium shield fiber, quartz fibre, basalt fiber), vermiculite 40%, expansion Perlite 5%, clay 5%, after being ground with ball mill or vertical mill, fineness reaches 50 mesh full by into rotation mixing Machine mixing homogenizing 10 minutes, obtains high-temperature fibre mixture, is stored into warehouse；

S5, by high-temperature fibre mixture by rotary kiln, through 900 DEG C, it is cold that high-temperature fusion calcines 30 minutes high temperature firings But it takes out afterwards, obtains high-temperature fibre particle；

S6, grain size after high-temperature fibre pellet through sieves, will be taken to be filled with the first base granule for the high-temperature fibre particle of 1mm Divide and be mixed to get granulation mixture, is stored into warehouse；

S7, cloth firing：Granulation mixture in S6 is subjected to cloth, is put into tunnel oven or roller kilns, through 900 DEG C, After 30 minutes high temperature firings, it is taken out, is made based on graphene and stone material tailing foamed light high temperature resistant by kiln cooling Partition plate crude product；

S8, crude product is molded after cutting, obtaining specification is：It is long：3000mm, width：1200mm, thickness：80mm is based on stone Black alkene and stone material tailing foamed light high temperature resistant partition wall board finished product.

Embodiment 2

Two, it prepares：

S2, raw material mixing：In addition to high-temperature fibre particle, remaining raw material claims by weight percent shared by each raw material is formulated Material, 18h is milled to ball mill or vertical mill batch mixing；Reach 250 mesh full by into rotary blender by screening fineness of grinding Mixing homogenizing 300 minutes；

S4, the mixing of high-temperature fibre particulate material：Stone material tailing 40%, high-temperature fibre are weighed according to weight percent 15% (high-temperature fibre is made of high aluminium profiles ceramic fibre, zirconium shield fiber, quartz fibre), vermiculite 20%, expanded perlite 20%, clay 5%, after being ground with ball mill or vertical mill, fineness reaches 50 mesh full by into rotary blender mixing Homogenizing 150 minutes, obtains high-temperature fibre mixture, is stored into warehouse；

S5, by high-temperature fibre mixture by rotary kiln, through 1280 DEG C, high-temperature fusion calcines 300 minutes high temperature firings It is taken out after cooling, obtains high-temperature fibre particle；

S6, grain size after high-temperature fibre pellet through sieves, will be taken to be filled with the first base granule for the high-temperature fibre particle of 6mm Divide and be mixed to get granulation mixture, is stored into warehouse；

S7, cloth firing：Granulation mixture in S6 is subjected to cloth, is put into tunnel oven or roller kilns, through 1300 DEG C, After 300 minutes high temperature firings, it is taken out, is made based on graphene and stone material tailing foamed light high temperature resistant by kiln cooling Partition plate crude product；

S8, crude product is molded after cutting, obtaining specification is：It is long：3000mm, width：1200mm, thickness：100mm is based on stone Black alkene and stone material tailing foamed light high temperature resistant partition wall board finished product.

Embodiment 3

Two, it prepares：

S1, washup：After stone material tailing is smashed it through 4 mesh, the stone material tailing after crushing is sent into fermentation vat, fermentation vat For bore cylinder, the 1/4 of a diameter of base diameter of feeding mouth, feeding mouth inside front be arranged high-pressure water pipeline be sent into stone The ammonium oxalate solution that high-pressure fog mass concentration is 2.5% while material tailing carries out spraying and drenches, until the ammonium oxalate of spraying The volume of solution can stop spraying process after being 1.22 times of stone material tailing volume, impregnate 50min, soak period at interval of 5min stirs a material, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and takes filtrate It is separated by solid-liquid separation after being washed, is repeated 3 times the step of washing is separated by solid-liquid separation, weight next time is returned after the washing filtrate of separation is merged It is used when after backwashing mine, the solid after washing is dried after the stone material tailing after being washed for use；

S2, raw material mixing：In addition to high-temperature fibre particle, remaining raw material claims by weight percent shared by each raw material is formulated Material, 3-18h is milled to ball mill or vertical mill batch mixing；Reach 250 mesh full by into rotation mixing by screening fineness of grinding Machine mixing homogenizing 100 minutes；

S4, the mixing of high-temperature fibre particulate material：Stone material tailing 30%, high-temperature fibre are weighed according to weight percent 35% (high-temperature fibre is made of high aluminium profiles ceramic fibre, basalt fiber), vermiculite 33%, expanded perlite 1%, clay 1%, After being ground with ball mill or vertical mill, fineness reach 50 mesh full by, into rotary blender mixing homogenizing 50 minutes, obtain To high-temperature fibre mixture, stored into warehouse；

S5, by high-temperature fibre mixture by rotary kiln, through 1000 DEG C, high-temperature fusion calcines 100 minutes high temperature firings It is taken out after cooling, obtains high-temperature fibre particle；

S6, grain size after high-temperature fibre pellet through sieves, will be taken to be filled with the first base granule for the high-temperature fibre particle of 2mm Divide and be mixed to get granulation mixture, is stored into warehouse；

S7, cloth firing：Granulation mixture in S6 is subjected to cloth, is put into tunnel oven or roller kilns, through 1000 DEG C, After 100 minutes high temperature firings, it is taken out, is made based on graphene and stone material tailing foamed light high temperature resistant by kiln cooling Partition plate crude product；

S8, crude product is molded after cutting, obtaining specification is：It is long：3000mm, width：1200mm, thickness：120mm is based on stone Black alkene and stone material tailing foamed light high temperature resistant partition wall board finished product.

Embodiment 4

Two, it prepares：

S1, washup：After stone material tailing is smashed it through 8 mesh, the stone material tailing after crushing is sent into fermentation vat, fermentation vat For bore cylinder, the 1/5 of a diameter of base diameter of feeding mouth, feeding mouth inside front be arranged high-pressure water pipeline be sent into stone The ammonium oxalate solution that high-pressure fog mass concentration is 4.5% while material tailing carries out spraying and drenches, until the ammonium oxalate of spraying The volume of solution can stop spraying process after being 1.21 times of stone material tailing volume, impregnate 90min, soak period at interval of 5min stirs a material, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and takes filtrate It is separated by solid-liquid separation after being washed, is repeated 3 times the step of washing is separated by solid-liquid separation, weight next time is returned after the washing filtrate of separation is merged It is used when after backwashing mine, the solid after washing is dried after the stone material tailing after being washed for use；

S2, raw material mixing：In addition to high-temperature fibre particle, remaining raw material claims by weight percent shared by each raw material is formulated Material, 3-18h is milled to ball mill or vertical mill batch mixing；Reach 250 mesh full by into rotation mixing by screening fineness of grinding Machine mixing homogenizing 200 minutes；

S4, the mixing of high-temperature fibre particulate material：Stone material tailing 25%, high-temperature fibre are weighed according to weight percent 25% (high-temperature fibre is made of high aluminium profiles ceramic fibre), vermiculite 32%, expanded perlite 15%, clay 3%, use ball mill Or after vertical mill is ground, fineness reach 50 mesh full by, into rotary blender mixing homogenizing 100 minutes, obtain resistance to height Warm fiber mixture is stored into warehouse；

S5, by high-temperature fibre mixture by rotary kiln, through 1100 DEG C, high-temperature fusion calcines 250 minutes high temperature firings It is taken out after cooling, obtains high-temperature fibre particle；

S6, grain size after high-temperature fibre pellet through sieves, will be taken to be filled with the first base granule for the high-temperature fibre particle of 5mm Divide and be mixed to get granulation mixture, is stored into warehouse；

S7, cloth firing：Granulation mixture in S6 is subjected to cloth, is put into tunnel oven or roller kilns, through 1200 DEG C, After 150 minutes high temperature firings, it is taken out, is made based on graphene and stone material tailing foamed light high temperature resistant by kiln cooling Partition plate crude product；

S8, crude product is molded after cutting, obtaining specification is：It is long：3000mm, width：1200mm, thickness：240mm is based on stone Black alkene and stone material tailing foamed light high temperature resistant partition wall board finished product.

Embodiment 5

One, raw material proportioning is shown in Table 11；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The high temperature is fluxing Agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide.

Two, preparation method and embodiment 1 are same.

Embodiment 6

Two, preparation method and embodiment 1 are same.

Embodiment 7

One, raw material proportioning is shown in Table 11；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The high temperature is fluxing Agent is to be shown in Table 14；The stabilizer is cerium oxide.

Wherein, also pass through modification before stone material tailing compounding, the modification is specific as follows：By stone material tailing, red Syrup, viscous pseudomonad, Colibacter are 100 according to weight ratio:5:0.1:0.1 carries out building heap mixing, after then handling Stone material tailing be crushed, be then ground and 1 minute and then sieve with 100 mesh sieve, then carry out the stone material tailing after sieving Bacterial screening detaches strain with stone material tailing, leaves stone material tailing and can be obtained modified stone material tailing.

It further illustrates, it is 1.65 × 10 that viscous pseudomonad, Colibacter, which are arranged to effective bacteria containing amount,⁸-2.11 ×10⁸The bacterium solution of a/mL is used.

It further illustrates, thalline also passes through activation culture, the activation culture before the bacterium solution configuration of the viscous pseudomonad Cultivating the culture medium prescription used is：Gelatin peptone 16.0g, tryptone 10.0g, Chinese yam polysaccharide content reach 88% or more Yam extract 8g, fructus schisandrae polysaccharide content reach 90% or more Radix Schisandrae Bicolori extract 8g, K₂SO₄ 10.0g、 MgCl₂1.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 7.2.

It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution configuration of the Colibacter The culture medium prescription used is cultivated in culture：Tryptone 5g/L, Chinese yam polysaccharide content reach 88% or more Chinese yam extraction Object 1g/L, fructus schisandrae polysaccharide content reach 90% or more Radix Schisandrae Bicolori extract 3g/L, sodium chloride 5g/L, pH 7.5.

Two, preparation method is substantially the same manner as Example 2, difference be between step S1 and S2 wherein in preparation method into The above-mentioned modifying processing step of row.

Embodiment 8

Wherein, also pass through modification before stone material tailing compounding, the modification is specific as follows：By stone material tailing, red Syrup, raw hole pseudomonas, Colibacter are 100 according to weight ratio:5:0.1:0.1 carries out building heap mixing, then will place Stone material tailing after reason is crushed, and is then ground 3 minutes and then is sieved with 100 mesh sieve, then by the stone material tailing after sieving Bacterial screening is carried out, strain is detached with stone material tailing, stone material tailing is left and can be obtained modified stone material tailing.

It further illustrates, it is 5.14 × 10 that raw hole pseudomonas, Colibacter, which are arranged to effective bacteria containing amount,⁸- 6.05×10⁸The bacterium solution of a/mL is used.

It further illustrates, thalline also passes through activation culture, the activation culture before the bacterium solution configuration of raw hole pseudomonas Cultivating the culture medium prescription used is：Gelatin peptone 16.0g, tryptone 10.0g, yam extract 15g, Radix Schisandrae Bicolori extract 20g、K₂SO₄ 10.0g、MgCl₂1.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 6.9.

It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution configuration of the Colibacter The culture medium prescription used is cultivated in culture：Tryptone 18g/L, yam extract 8g/L, Radix Schisandrae Bicolori extract 10g/L, Sodium chloride 20g/L, pH 7.2.

It further illustrates, the content containing Chinese yam polysaccharide reaches 89% in yam extract；Contain in Radix Schisandrae Bicolori extract There is the content of fructus schisandrae polysaccharide to reach 91%.

Two, preparation method is substantially the same manner as Example 3, difference be between step S1 and S2 wherein in preparation method into The above-mentioned modifying processing step of row.

Embodiment 9

One, raw material proportioning is shown in Table 11；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The high temperature is fluxing Agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide；

Wherein, also pass through modification before stone material tailing compounding, the modification is specific as follows：By stone material tailing, red Syrup, pseudomonas syncyanea, Colibacter are 100 according to weight ratio:5:0.1:0.1 carries out building heap mixing, then will processing Stone material tailing afterwards is crushed, and is then ground and 2 minutes and then is sieved with 100 mesh sieve, then by the stone material tailing after sieving into Row bacterial screening detaches strain with stone material tailing, leaves stone material tailing and can be obtained modified stone material tailing.

It further illustrates, it is 2.89 × 10 that pseudomonas syncyanea, Colibacter, which are arranged to effective bacteria containing amount,⁸- 3.13×10⁸The bacterium solution of a/mL is used.

It further illustrates, thalline also passes through activation culture, the activation culture training before the bacterium solution configuration of pseudomonas syncyanea Supporting the culture medium prescription used is：Gelatin peptone 16.0g, tryptone 10.0g, yam extract 10g, Radix Schisandrae Bicolori extract 12g、K₂SO₄10.0g、MgCl₂1.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 7.3

It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution configuration of the Colibacter The culture medium prescription used is cultivated in culture：Tryptone 9g/L, yam extract 3g/L, Radix Schisandrae Bicolori extract 6g/L, chlorine Change sodium 8g/L, pH 7.6.

It further illustrates, the content containing Chinese yam polysaccharide reaches 92% in yam extract；Contain in Radix Schisandrae Bicolori extract There is the content of fructus schisandrae polysaccharide to reach 95%.

Two, preparation method is substantially the same manner as Example 4, difference be between step S1 and S2 wherein in preparation method into The above-mentioned modifying processing step of row.

Embodiment 10

Wherein, also pass through modification before stone material tailing compounding, the modification is specific as follows：By stone material tailing, red Syrup, Pseudomonas taetrolens, Colibacter are 100 according to weight ratio:5:0.1:0.1 carries out building heap mixing, then will processing Stone material tailing afterwards is crushed, and is then ground and 3 minutes and then is sieved with 100 mesh sieve, then by the stone material tailing after sieving into Row bacterial screening detaches strain with stone material tailing, leaves stone material tailing and can be obtained modified stone material tailing.

It further illustrates, it is 3.56 × 10 that Pseudomonas taetrolens, Colibacter, which are arranged to effective bacteria containing amount,⁸- 4.05×10⁸The bacterium solution of a/mL is used.

It further illustrates, thalline also passes through activation culture, the activation culture training before the bacterium solution configuration of Pseudomonas taetrolens Supporting the culture medium prescription used is：Gelatin peptone 16.0g, tryptone 10.0g, yam extract 14g, Radix Schisandrae Bicolori extract 18g、K₂SO₄10.0g、MgCl₂1.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 7.1.

It further illustrates, Escherichia coli also pass through activation culture, the activation culture before the bacterium solution configuration of Colibacter Cultivating the culture medium prescription used is：Tryptone 10g/L, yam extract 7g/L, Radix Schisandrae Bicolori extract 8g/L, sodium chloride 18g/L、pH 7.4。

It further illustrates, the content containing Chinese yam polysaccharide reaches 96% in yam extract；Contain in Radix Schisandrae Bicolori extract There is the content of fructus schisandrae polysaccharide to reach 98%.

Embodiment 11

One, raw material proportioning is same as Example 3；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The height Warm fluxing agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide.

Two, preparation method is same as Example 3.

Embodiment 12

One, raw material proportioning is same as Example 4；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The height Warm fluxing agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide.

Two, preparation method is same as Example 4.

Embodiment 13

One, raw material proportioning and embodiment 3 are same；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The high temperature Fluxing agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide.

Two, preparation method and embodiment 3 are same.

Embodiment 14

One, raw material proportioning is shown in same as Example 4；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；It is described High temperature fluxing agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide.

Two, preparation method is same as Example 4.

Embodiment 15

Two, preparation method is same as Example 4.

Embodiment 16

One, raw material proportioning is same as Example 1；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The height Warm fluxing agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide.

Two, preparation method is same as Example 1.

Embodiment 17

One, raw material proportioning is same as Example 1；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The height Warm fluxing agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is yttrium, cerium oxide.

Two, preparation method is same as Example 1.

Embodiment 18

Two, preparation method is same as Example 1.

Ingredient percentage composition (%) list in 11 each embodiment of table

Stone material tailing selective listing in 12 each embodiment of table

Embodiment	Granite	Feldspar	Quartz	Sandstone	Diabase	Shale	Griotte	Basalt	Limestone	Desert Sand
											1	√	--	--	--	--	--	--	--	--	--
2	--	√	--	--	--	--	--	--	--	--
											3	--	--	√	--	--	--	--	--	--	--
4	--	--	--	√	--	--	--	--	--	--
											5	--	--	--	--	√	--	--	--	--	--
6	--	--	--	--	--	√	--	--	--	--
											7	--	--	--	--	--	--	√	--	--	--
8	--	--	--	--	--	--	--	√	--	--
											9	--	--	--	--	--	--	--	--	√	--
10	--	--	--	--	--	--	--	--	--	√
											11	√	√	√	√	√	√	√	√	√	√
12	√	√	√	√	√	√	√	√	--	--
											13	√	√	√	√	√	√	√	--	--	--
14	√	√	√	√	√	√	--	--	--	--
											15	√	√	√	√	√	--	--	--	--	--
16	√	√	√	√	--	--	--	--	--	--
											17	√	√	√	--	--	--	--	--	--	--
18	√	√	--	--	--	--	--	--	--	--

Clay selective listing in 13 each embodiment of table

14 each embodiment high temperature cosolvent selective listing of table

Embodiment	Calcination of talc	Raw talcum	Fluorite	Diopside
					1	√	--	--	--
2	--	√	--	--
					3	--	--	√	--
4	√	√	√	--
					5	√	√	--	--
6	√	--	√	--
					7	--	√	√	--
8	√	--	--	--
					9	√	√	--	--
10	√	--	√	√
					11	√	√	√	--
12	√	√	--	√
					13	√	--	√	--
14	--	√	√	√
					15	√	--	--	--
16	--	--	--	√
					17	--	--	√	--
18	√	√	√	√

Foaming agent selective listing in 15 each embodiment of table

Testing inspection：

By the standby obtained foamed wall slabs of embodiment 1-18 in present embodiment, comparative example, (foaming of market purchase is light Matter wallboard) by the test of physical and mechanical properties, specific method is referring to first embodiment, and test result is referring to following table.

By upper table data it is found that the bubble lightweight wall plate that formula composition obtains after being combined with proportioning in present embodiment is through surveying Examination is distinguished little in combustion rating；The lightweight wall plate of the application is 100-800kg/m in bulk density³, compression strength >= 5MPa, flexural strength >=2.5MPa, conduction heat transfer coefficient≤2.0W/m DEG C, A1 grades of combustion rating, oise insulation factor >=35dB, water absorption rate < 0.1% is more excellent than comparative example on physical and mechanical properties.

As the increase of graphene amount gradually increases on compression strength, flexural strength in terms of embodiment 1-6, but with The increase thermal coefficient of amount can also improve, however pass through research find addition expanded graphite in the feed can to mitigate this existing As；Therefore in the ratio for strictly to be controlled when raw material configuration graphene and expanded graphite, pressure resistance cannot be pursued simply The problem of spending, the promotion of flexural strength, and having ignored thermal coefficient, therefore the application is in the ratio of configuration graphene and expanded graphite Example is obtained by countless orthogonal tests, not only can guarantee that compression strength, flexural strength improve but also can reduce thermal coefficient.

It can be seen that adding in the feed in embodiment 5, (1,9,10,16,18), (6,8), (4,12) from embodiment 1-18 Expanded graphite is added, and as the increase of amount is continuously decreased in conduction heat transfer coefficient, it was demonstrated that addition expanded graphite can improve Wallboard size in aperture in preparation process is finer and smoother, and the porosity is high, to reduce conduction heat transfer coefficient；Embodiment 5, Embodiment 7,8,9,10 has more excellent property on conduction heat transfer coefficient in (1,9,10,16,18), (6,8), (4,11) It can, it was demonstrated that modified stone material tailing has the size in finer and smoother aperture, the porosity in the energy for the process for carrying out compounding fermentation Higher, because after removing metal ion, the element of stone material tailing is purer, until aperture is finer and smoother during foaming, and finds to implement Example 7,8,9,10 is in bulk density, compression strength, flexural strength, conduction heat transfer coefficient, combustion rating, oise insulation factor, water absorption rate Comparing has superior numerical value, and stone material tailing also passes through modification before compounding, by having the specific certain gold of enrichment Some metallic elements can be removed after the microorganism enrichment processing of the substance of category so that stone material tailing is purer, and is changing Property during strain add activation step, used in the culture medium of activation plant polyose to substitute conventional carbon source (glucose etc.), It was found that the strain after activation has the metallic element ability in more excellent absorption stone material tailing；It is additional by white oil grinding at Between so that stone material tailing is uniformly embedded in macromolecule in later stage high-temperature calcination after reason, forms reticular structure and increases bulk density, Reduce water absorption rate.A kind of cement base foamed light of disclosure of the invention that the Chinese Patent Application No. that compares is 201610090524.3 Composite material and preparation method, the bulk density of the application, compression strength, flexural strength, conduction heat transfer coefficient, combustion rating, Oise insulation factor, water absorption rate are superior to Chinese patent 201610090524.3, and giving prominence to the key points, it is Chinese special to be far longer than in bulk density Profit 201610090524.3.A kind of addition sponge gourd of disclosure of the invention that the Chinese Patent Application No. that compares is 201610258377.6 The bulk density of light cellular partition board the application of network fiber, compression strength, flexural strength, conduction heat transfer coefficient, combustion rating, every Volume, water absorption rate are superior to Chinese patent 201610258377.6, the equal < 0.1% of the application especially on water absorption rate, and Chinese 201610258377.6 water absorption rate of patent still reaches 21.4%, therefore, using the technical solution of the application, in each physics spy Compared with the prior art have greatly improved on property and mechanical characteristic.

In embodiment 1-18 radionuclide limitation meet national regulation in the range of, the embodiment that compares 7,8,9, Radionuclide limitation in 10 includes I_Ra(External Exposure Index) and I_Ra(Outreach services) are all than embodiment 1-6,11-18 It is small, because of the rare earth metal content in it can greatly reduce stone material tailing after carrying out washup recovering rare earth metal, but many institutes Known, there are many type of radiation metal, and cannot pass through a kind of method can remove, but the modification Jing Guo the application, also The content of radiation metal can be reduced so that the wallboard radiation smaller being prepared has been truly realized environmentally protective effect.

Same as Example 7 in raw material in comparative example 2, difference is：The preceding thalline of bacterium solution configuration of viscous pseudomonad is also By activation culture, in the culture medium prescription that the activation culture culture uses without containing Chinese yam polysaccharide content reach 88% with On yam extract 8g, fructus schisandrae polysaccharide content reach 90% or more Radix Schisandrae Bicolori extract 8g, using glucose Band is replaced.Escherichia coli also pass through activation culture, the training that the activation culture culture uses before the bacterium solution configuration of Colibacter It supports the content without containing Chinese yam polysaccharide in based formulas and reaches 88% or more yam extract 1g/L, the content of fructus schisandrae polysaccharide The Radix Schisandrae Bicolori extract 3g/L for reaching 90% or more is replaced using glucose band.It was found that the strain phase after the activation of embodiment 7 Comparing comparative example 2 has the more excellent metallic element ability adsorbed in stone material tailing.

In addition it gives the wallboard that the embodiment 1 in present embodiment is prepared to coherent detection center to be detected, examine The result of survey and data such as following table：

It is appreciated that precast beam can also be connect with concrete prefabricated reinforcing prop 2 by prefabricated fixing piece, or using bonding The mode that agent and prefabricated fixing piece are combined is fixedly connected.

It is appreciated that between lining 24 and concrete girder 20 between Side fascia 23 and concrete girder 20, the two Identical connection type may be used to be attached, can also be attached using different connection types.

It is appreciated that lining 24 can be omitted according to actual needs.It is appreciated that concrete structure assembled architecture body It is that 100 can only include one layer of wallboard and one layer of precast floor slab 17.

It is appreciated that the quantity for the sub- wallboard 25 that Side fascia 23 includes with lining 24 is not limited to the above embodiment, it can It is configured according to actual needs.

Above description is the detailed description for the present invention preferably possible embodiments, but embodiment is not limited to this hair Bright patent claim, it is all the present invention suggested by technical spirit under completed same changes or modifications change, should all belong to In the covered the scope of the claims of the present invention.

Claims

1. a kind of concrete structure assembled architecture system, it is characterised in that：Including prefabricated foundation, structural support frame, at least If a precast floor slab and drywall panel, the prefabricated foundation includes pedestal and the concrete structure column on the pedestal, described Structural support frame includes concrete prefabricated reinforcing prop and precast beam, and the concrete prefabricated reinforcing prop is adopted with concrete structure column It is fixedly connected with bonding agent, the peripheral wall of the concrete prefabricated reinforcing prop is equipped with several anchoring steel structures；The precast beam includes Concrete girder and plug connector, the concrete girder by prefabricated fixing piece and/or are glued with the concrete prefabricated reinforcing prop Agent connection is connect, the plug connector is connect with the wherein one side of the concrete girder；The precast floor slab is supported in described mixed Solidifying soil girder on the side of the plug connector, and with the concrete girder by bonding agent and/or prefabricated connector into Row connection, adjacent two blocks of wallboards mutually splice or are bonded, set on the wallboard adjacent with the concrete prefabricated reinforcing prop There are bar planting hole, the anchoring steel structure to be anchored in the bar planting hole, to connect the wallboard and the concrete prefabricated reinforcing prop； The wallboard includes several Side fascias and several linings, and several Side fascias surround an accommodation space, with the concrete The adjacent Side fascia of prefabricated reinforcing prop is connect by the anchoring steel structure with the concrete prefabricated reinforcing prop, several interior walls Plate is set in the accommodation space, and adjacent two pieces of linings mutually splice or be bonded to form interior wall, and described concrete prefabricated The adjacent lining of reinforcing prop is connect by the anchoring steel structure with the concrete prefabricated reinforcing prop；The Side fascia is towards institute The side of the side and the lining towards the precast beam of stating precast beam is equipped with plug division, and the plug division is inserted with described Fitting grafting, and fixed using bonding agent；Each Side fascia includes two blocks of sub- wallboards, thickness direction of two blocks of sub- wallboards along wall Gluing is together to form a Side fascia；Each precast floor slab and the Side fascia being positioned above are connected by prefabricated component and bonding agent It connects, is located at the Side fascia above the precast floor slab and is equipped with fixing groove, the fixing groove is located at the Side fascia towards described pre- The side of floor processed, the prefabricated component include that arc panel, two pieces of mounting plates and several lock bolts, the arc panel are contained in institute It states in fixing groove, two pieces of mounting plates are respectively facing two opposite directions by the opposite sides of the arc panel and extend to form, several Lock bolt respectively links together two pieces of mounting plates with the precast floor slab, and the precast floor slab is located at the precast floor slab It is fixed again using bonding agent between the Side fascia of top and the prefabricated component；Along two adjacent sub- wallboards of thickness of wall body direction arrangement Between junction be located at the side of the arc panel central axis far from the accommodation space；The Side fascia and the interior wall Plate is based on graphene and stone material foamed wall slab, based on graphene and nonmetallic tailings foamed wall slab and based on stone The one or more of black alkene and stone material tailing foamed light high temperature resistant wallboard, wherein described light based on graphene and stone material foaming Matter wallboard in percentage by weight, including stone material tailing 45-90%, high temperature cosolvent 0.05-10%, graphene 0.05-15%, Expanded graphite 0.05-5%, zirconium oxide 1-20%, calcium carbonate 0.05-10%, clay 1-10%, stabilizer 0.05-5%, degumming agent 0.05-5%, inorganic color 0.05-5%；It is described to be based on graphene with nonmetallic tailings foamed wall slab according to weight percent Meter, including nonmetallic tailings 55-75%, graphene 0.05-15%, vermiculite 1-15%, high temperature cosolvent 0.05-15%, high temperature resistant are fine Tie up 5-20%, foaming agent 0.05-5%, zirconium oxide 1-20%, clay 1-10%, stabilizer 0.05-5%, degumming agent 0.05-5%；It is described In percentage by weight based on graphene and stone material tailing foamed light high temperature resistant wallboard, including stone material tailing 40%-65%, stone Black alkene 0.05%-15%, aluminium oxide 1%-30%, vermiculite 1-15%, calcium carbonate 0.05%-10%, high temperature cosolvent 0.05%-15%, resistance to height Warm fiber grain 5-30%, foaming agent 0.05%-5%, stabilizer 0.05%-5%, degumming agent 0.05%-5%, clay 1%-10%, colorant Additional 0%-5%.

2. concrete structure assembled architecture system as described in claim 1, it is characterised in that：The concrete structure column back of the body Several first rebar connectors are equipped with to one end of the pedestal, the concrete prefabricated reinforcing prop is towards the prefabricated foundation End face be equipped with several second rebar connectors；Several first rebar connectors and several second rebar connectors interval point It is distributed between the concrete structure column and the concrete prefabricated reinforcing prop, in the first rebar connector and the second bar connecting The live formwork in periphery of part, then use the cast-in-place fixation of bonding agent.

3. concrete structure assembled architecture system as described in claim 1, it is characterised in that：The Side fascia is backwards to described The side of accommodation space is additionally provided with water-proof precast product, and the water-proof precast product includes the first joint face, the second joint face and third Joint face, first joint face are oppositely arranged with second joint face, third joint face connection first connection Face and the second joint face, and the third joint face is towards the accommodation space, first joint face and second connection Face is fixed with adjacent two layers Side fascia by bonding agent respectively, the third joint face and the precast floor slab and the precast beam It is fixed by bonding agent.

4. concrete structure assembled architecture system as claimed in claim 3, it is characterised in that：First joint face is oblique Face, the direction that first connection faces away from the accommodation space gradually tilt to the prefabricated foundation, connect with described first The Side fascia of junction connection is equipped with the first inclined-plane coordinated with first joint face, and first inclined-plane connects with described first Junction is fixed by bonding agent.

5. concrete structure assembled architecture system as claimed in claim 3, it is characterised in that：Second joint face includes Support portion and rake, the support portion are supported on corresponding Side fascia and are fixed by bonding agent with corresponding Side fascia, The rake is connected to the rake farthest away from the side of the accommodation space, and the rake is towards far from receiving sky Between direction gradually to the prefabricated foundation tilt, Side fascia connect with second joint face equipped with and the rake Second inclined-plane of cooperation, second inclined-plane is fixed with the rake by bonding agent.

6. concrete structure assembled architecture system as described in claim 1, it is characterised in that：It is also opened up on the Side fascia There is window mounting hole, surrounds one waterproof boss of projection and recessed installing slot, the installing on the side wall of the window mounting hole It is flat logical that a stainless steel is fixed in slot, the concrete structure assembled architecture system further includes window, and the window includes installation Outline border, the installation outline border are connect with the flat logical and described waterproof boss of the stainless steel.