CN107816130B - Steel construction assembled architecture system and its assembly method - Google Patents

Steel construction assembled architecture system and its assembly method Download PDF

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Publication number
CN107816130B
CN107816130B CN201711045432.4A CN201711045432A CN107816130B CN 107816130 B CN107816130 B CN 107816130B CN 201711045432 A CN201711045432 A CN 201711045432A CN 107816130 B CN107816130 B CN 107816130B
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China
Prior art keywords
steel construction
prefabricated
stone material
tailing
graphene
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Expired - Fee Related
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CN201711045432.4A
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Chinese (zh)
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CN107816130A (en
Inventor
黄聿新
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Guangxi Xu Teng Industry Group Co Ltd
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Guangxi Xu Teng Industry Group Co Ltd
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    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/18—Structures comprising elongated load-supporting parts, e.g. columns, girders, skeletons
    • E04B1/24—Structures comprising elongated load-supporting parts, e.g. columns, girders, skeletons the supporting parts consisting of metal
    • E04B1/2403—Connection details of the elongated load-supporting parts
    • C—CHEMISTRY; METALLURGY
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    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
    • C—CHEMISTRY; METALLURGY
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    • C04B33/00—Clay-wares
    • C04B33/36—Reinforced clay-wares
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    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
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    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/063—Preparing or treating the raw materials individually or as batches
    • C04B38/0635—Compounding ingredients
    • C04B38/064—Natural expanding materials, e.g. clay
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  • Joining Of Building Structures In Genera (AREA)

Abstract

The present invention provides a kind of steel construction assembled architecture system, if including prefabricated foundation, structural support frame, precast floor slab and drywall panel；Structural support frame includes the prefabricated reinforcing prop of steel construction and precast beam, and the prefabricated reinforcing prop of steel construction is connect with prefabricated foundation；Precast beam includes steel construction girder and plug connector, and steel construction girder is connect with the prefabricated reinforcing prop of steel construction；Plug connector is connect with steel construction girder, and precast floor slab is connect with steel construction girder；Using anchoring steel structure connection wallboard and the prefabricated reinforcing prop of steel construction；Wallboard is equipped with plug division, plug division and plug connector grafting, and is fixed using bonding agent.Wallboard is to have many advantages, such as anticorrosive, insulation, fire prevention, waterproof, impervious, antidetonation, cracking resistance, high-strength light based on graphene and nonmetallic foamed wall slab.The fabricated construction mode that this building system uses can shorten the construction period, and energy-saving and environment friendly.The present invention also provides a kind of assembly methods of steel construction assembled architecture system.

Description

Steel construction assembled architecture system and its assembly method
【Technical field】
The present invention relates to technical field of buildings, in particular to a kind of steel construction assembled architecture system and its assembly method.
【Background technique】
Traditional building uses cast-in-place concrete floor, and wall uses conventional concrete aerated blocks, shale porous brick, common brick When, it needs wet process sporadicly to construct, two-sided batch time levelling, exterior wall is needed to need to carry out water-proof heat insulation construction etc., assembly rate pole It is low；Using blockwork, external wall plastering or tiling, to play waterproof thermal-insulated cold-proof purpose, but heat insulation effect is undesirable, every Sound is heat-insulated, fire-proof high-temperature resistant, water proof anti-seepage, corrosion-resistant antiageing effect are poor, does not have high-strength light, heat preserving heat insulating noise insulation, anti- Fiery high temperature resistant, water proof anti-seepage, antidetonation, it is anticorrosive it is anti-aging, the superior functions such as do not crack, with conventional concrete aerated blocks, shale Porous brick compared to not can solve building sound-insulating and heat-insulating heat preservation, water proof anti-seepage, antidetonation, do not crack a series of problems, such as, And work progress needs a large amount of exterior wall scaffolds, constructs many and diverse, and construction speed is slow, and labor intensive amount is big, the fragmentary operation of wet process is needed, The building waste generated of constructing is more.It can be improved using assembled architecture and shorten the construction period, save architectural engineering construction cost, Improve construction assembly rate slightly.However the assembled architecture of the prior art, prefabricated panel and steel construction girder use The modes such as cast-in-place concrete or prefabricated latch are attached, and are applied using what cast-in-site operation, wet process were sporadicly constructed Work mode causes that difficulty of construction is big, the big construction quality long in time limit, completing of project amount cannot ensure, junction intensity compared with Low, the assembly rate of assembled architecture is lower, and the quality and quake-resistant safety performance of building are low；It is attached using prefabricated latch, Need simultaneously be opened up on wallboard and girder with bolted screw hole, it is more demanding to installation accuracy, improve assembled and build The construction cost built, meanwhile, be attached using prefabricated latch, need scene open up link slot, nailing, drilling, installation it is multiple Bolt etc., installation speed are slower.In addition, seldom finding the connection side of reinforcing prop and wallboard in current assembled architecture Formula, and the connection type of reinforcing prop and wallboard also will affect assembled architecture anti-seismic performance.
【Summary of the invention】
In view of the above problems, it is necessary to which the construction period can be shortened by providing one kind, reduce the steel knot of building cost Structure assembled architecture system.
In order to achieve the above objectives, the technical scheme adopted by the invention is that：
A kind of steel construction assembled architecture system, if including prefabricated foundation, structural support frame, an at least precast floor slab and Drywall panel, the prefabricated foundation includes pedestal and the steel structure column on the pedestal, if the structural support frame includes The dry prefabricated reinforcing prop of steel construction and several precast beams, the prefabricated reinforcing prop of steel construction and steel structure column are by welding and/or insert The mode connect is attached, and the peripheral wall of the prefabricated reinforcing prop of steel construction is equipped with several anchoring steel structures；The precast beam includes Steel construction girder and plug connector, the steel construction girder and the prefabricated reinforcing prop of the steel construction pass through welding and/or prefabricated fixation Part connection, the plug connector are connect with the wherein one side of the steel construction girder；The precast floor slab is supported in the steel knot Structure girder is carried out on the side of the plug connector, and with the steel construction girder by bonding agent and/or prefabricated connector Connection, two blocks of adjacent wallboards mutually splice or are bonded, and the wallboard adjacent with the prefabricated reinforcing prop of the steel construction is equipped with Bar planting hole, the anchoring steel structure are anchored in the bar planting hole, to connect the wallboard and the prefabricated reinforcing prop of the steel construction；Institute It states wallboard and is equipped with plug division, the plug division and the plug connector grafting towards the side of the precast beam, and use bonding agent It is fixed.
Further, the wallboard is based on graphene and stone material foamed wall slab, based on graphene and nonmetallic tail Mine foamed wall slab and one or more based on graphene Yu stone material tailing foamed light high temperature resistant wallboard, wherein described In percentage by weight based on graphene and stone material foamed wall slab, including stone material tailing 45-90%, high temperature cosolvent 0.05-10%, graphene 0.05-15%, expanded graphite 0.05-5%, zirconium oxide 1-20%, calcium carbonate 0.05-10%, clay 1-10%, stabilizer 0.05-5%, degumming agent 0.05-5%, inorganic color 0.05-5%；It is described based on graphene with it is nonmetallic Tailing foamed wall slab in percentage by weight, including nonmetallic tailings 55-75%, graphene 0.05-15%, vermiculite 1- 15%, high temperature cosolvent 0.05-15%, high-temperature fibre 5-20%, foaming agent 0.05-5%, zirconium oxide 1-20%, clay 1- 10%, stabilizer 0.05-5%, degumming agent 0.05-5%；It is described to be based on graphene and stone material tailing foamed light high temperature resistant wallboard In percentage by weight, including stone material tailing 40%-65%, graphene 0.05%-15%, aluminium oxide 1%-30%, vermiculite 1-15%, calcium carbonate 0.05%-10%, high temperature cosolvent 0.05%-15%, high-temperature fibre particle 5-30%, foaming agent 0.05%-5%, stabilizer 0.05%-5%, degumming agent 0.05%-5%, clay 1%-10%, the additional 0%-5% of colorant.
Further, the steel structure column is equipped with first connecting portion backwards to one end of the pedestal, and the steel construction is pre- Reinforcing prop processed is equipped with second connecting portion towards an end face of the prefabricated foundation, and the first connecting portion is connect with described second One of portion is set as protrusion, and another groove structure being set as with the male cooperation, the protrusion is plugged in the groove knot In structure.
Further, the precast floor slab passes through prefabricated component with the wallboard being located above the precast floor slab and/or glues Connect agent connection.
Further, the wallboard includes several Side fascias and several linings, and several Side fascias surround one jointly Accommodation space, the Side fascia adjacent with the prefabricated reinforcing prop of the steel construction add by the way that the anchoring steel structure and the steel construction are prefabricated Strong column connection, several linings are set in the accommodation space, and adjacent two pieces of linings mutually splice to form interior wall, with The adjacent lining of the prefabricated reinforcing prop of steel construction is connect by the anchoring steel structure with the prefabricated reinforcing prop of the steel construction, institute It states and is equipped with the plug division at the top of the top and the lining of Side fascia.
Further, the Side fascia is additionally provided with water-proof precast product backwards to the side of the accommodation space, and the waterproof is pre- Product includes the first joint face, the second joint face and third joint face, and first joint face is opposite with second joint face Setting, the third joint face connect first joint face and the second joint face, and the third joint face is towards the appearance Receive space, first joint face and second joint face are fixed with adjacent two layers Side fascia by bonding agent respectively, described Third joint face is fixed with the precast floor slab and the precast beam by bonding agent.
Further, first joint face is inclined-plane, and first connection faces away from the direction of the accommodation space It is gradually tilted to the prefabricated foundation, the Side fascia connecting with first joint face is equipped with to be cooperated with first joint face The first inclined-plane, first inclined-plane is fixed with first joint face by bonding agent.
Further, second joint face includes support portion and rake, and the support portion is supported in corresponding exterior wall It is fixed on plate and with corresponding Side fascia by bonding agent, it is empty farthest away from the receiving that the rake is connected to the rake Between side, the rake towards far from the accommodation space direction gradually to the prefabricated foundation tilt, with described second The Side fascia of joint face connection is equipped with the second inclined-plane cooperated with the rake, and second inclined-plane and the rake are logical Bonding agent is crossed to fix.
Further, it is also provided with window mounting hole on the Side fascia, surrounds projection on the side wall of the window mounting hole One waterproof boss and recessed installing slot, fix that a stainless steel is flat to be led in the installing slot, the steel construction assembled architecture System further includes window, and the window includes installation outline border, and the installation outline border and the flat logical and described waterproof of the stainless steel are convex Platform connection.
Further, each Side fascia includes two blocks of sub- wallboards, and two blocks of sub- wallboards are bonded in along the thickness direction of a wall Together to form the Side fascia, each lining includes one block of sub- wallboard, adjacent with the prefabricated reinforcing prop of the steel construction The sub- wallboard in be equipped with several bar planting holes.
The present invention also provides a kind of assembly methods of steel construction assembled architecture system, include the following steps：
It is laid with prefabricated foundation；
By the welding of the steel structure column of one end of the prefabricated reinforcing prop of steel construction and prefabricated foundation and/or grafting；
The steel construction girder of precast beam and the prefabricated reinforcing prop of the steel construction are connected by welding and/or prefabricated fixing piece It connects；
Adjacent two blocks of wallboards are mutually spliced or are bonded, anchoring steel structure is plugged in the bar planting hole of wallboard, bonding agent is used The gap in bar planting hole is filled, to connect the wallboard and the prefabricated reinforcing prop of the steel construction；By the plug division of the wallboard with The plug connector grafting of precast beam, and fixed using bonding agent, to connect wallboard and precast beam；
The precast floor slab is supported on the steel construction girder of the precast beam, and the steel construction master with the precast beam Beam is connected by bonding agent and/or prefabricated connector.
Due to the adoption of the above technical scheme, the invention has the advantages that：
1, steel construction assembled architecture system of the invention, prefabricated foundation, precast floor slab, wallboard and structural support frame It is the prefabricated components of plant produced.Scene need to only carry out cast-in-place, anchoring between a small amount of component or bolt connects and splice etc. and fills With operation, no setting is required full hall scaffold is easy for construction simple, has shortened the construction period, has saved architectural engineering construction cost, make Construction assembly rate reaches 95% or more, and reusable after structural demolition, reduces building waste and environmental pollution, green Environmental protection really realizes that less manpower saves cost, environmentally protective, energy-efficient industrialized building target economic, safety is beautiful；To biography The revolution of system construction material has sexually revised profound significance, to the build model of traditional architecture realize personalized designs, Industrialized production, information system management, prefabricated construction reach the target of sustainable development.
2, steel construction assembled architecture system of the invention, wallboard have high-strength light, heat preserving heat insulating noise insulation, fire prevention resistance to High temperature, water proof anti-seepage, antidetonation, it is anticorrosive it is anti-aging, the superior functions such as do not crack, give and build that more long-life, quality be more excellent, peace Full performance index is high, environmentally protective；And wallboard is light material, can easily realize carrying and splicing operation by a people, because This overcomes cast-in-site operation, the form of construction work that wet process is sporadicly constructed causes that difficulty of construction is big, project amount is big long in time limit, complete At construction quality cannot ensure the drawbacks of.In addition, big plate splicing can be used in wallboard, it is concrete aerated compared to existing For wall made of block, shale porous brick, traditional red brick masonry, the globality of building is increased, and then greatly improve and build The performances such as insulation, sound insulation, fireproof, waterproof and dampproof, the impervious, cracking resistance built do not have to cement mortar, structure glue or porcelain Brick gelling agent carry out two-sided batch it is time levelling, without secondary progress water-proof heat insulation layer construction, reduce building own wt, have Effect extends building whole service life, solves security hidden trouble caused by traditional architecture falls off because of external-wall exterior insulation layer.
3, steel construction assembled architecture system of the invention, wallboard and the prefabricated reinforcing prop of steel construction are connected by anchoring steel structure It connects, this building system not only increases the globality of wall, and improves force path, improves building adaptive deformation Ability improve the anti-seismic performance of building so that junction connection is reliable.Precast beam includes steel construction girder and plug connector, The progress of the plug division of plug connector and wallboard is mating, then is fixedly connected using bonding agent, and scene can pacify without installing bolt Dress speed is improved, and can reduce wallboard and cooperation precision needed for precast beam, reduces building system construction cost to reach Purpose, meanwhile, plug connector and plug division it is mating so that building can also be transmitted suffered by steel construction girder by wall Plane shearing and vertical force, the quality and quake-resistant safety performance of building be greatly improved, anti-seismic performance can reach 9 degree with Upper standard.
4, steel construction assembled architecture system of the invention is also equipped with waterproof in the junction of Side fascia and precast floor slab Part further improves the waterproof impervious characteristic of wall.
5, some communal facilitys in the prior art, such as city police service sentry box, public lavatory, passive room etc., are generally deposited The defects of poor in sound insulation, heat-insulation and heat-preservation is poor, fire prevention, the performances such as impervious are poor；Between passive one layer half to two layers half of room, thermal insulation separation Thermal effect is bad, is easy to be corroded；Public lavatory waterproof impervious characteristic is bad, weather-proof, corrosion resistance is lower.Steel knot of the invention Structure assembled architecture system improves the property such as insulation, sound insulation, fireproof, waterproof and dampproof, the impervious, cracking resistance of building Can, particularly suitable for communal facility, such as the construction in city police service sentry box, public lavatory, passive room.
【Detailed description of the invention】
Fig. 1 be the Side fascia of steel construction assembled architecture system in first embodiment of the invention, structural support frame with The connection schematic diagram of precast floor slab.
Fig. 2 is the structure chart of the prefabricated foundation of steel construction assembled architecture system in first embodiment of the invention.
Fig. 3 is the schematic top plan view of prefabricated foundation shown in Fig. 2.
Fig. 4 is the structure chart of the prefabricated reinforcing prop of steel construction shown in Fig. 1.
Fig. 5 is the diagrammatic cross-section of Fig. 1.
Fig. 6 is enlarged drawing of the Fig. 5 at A.
Fig. 7 is the structure chart of prefabricated component in Fig. 5.
Fig. 8 be the lining of steel construction assembled architecture system in first embodiment of the invention, structural support frame with The connection schematic diagram of precast floor slab.
Fig. 9 is the diagrammatic cross-section of Fig. 8.
Figure 10 is the top view of Side fascia in first embodiment of the invention.
Figure 11 is the connection schematic diagram of Side fascia shown in Figure 10.
Figure 12 is the top view of Side fascia in another embodiment of the present invention.
Figure 13 is the top view of lining in first embodiment of the invention.
Figure 14 is lining in Fig. 8 along the schematic cross-sectional view of line B-B.
Figure 15 is the schematic diagram of lining in another embodiment of the present invention.
Figure 16 is the Side fascia, precast beam and prefabricated building of steel construction assembled architecture system in second embodiment of the invention The connection schematic diagram of plate.
Figure 17 is enlarged drawing of the Figure 16 at C.
Figure 18 is the lining, precast beam and prefabricated building of steel construction assembled architecture system in third embodiment of the invention The connection schematic diagram of plate.
Figure 19 is the Side fascia, precast beam and prefabricated building of steel construction assembled architecture system in four embodiment of the invention The connection schematic diagram of plate.
Figure 20 is the lining, precast beam and prefabricated building of steel construction assembled architecture system in fifth embodiment of the invention The connection schematic diagram of plate.
Figure 21 is the Side fascia, precast beam and prefabricated building of steel construction assembled architecture system in sixth embodiment of the invention The connection schematic diagram of plate.
Figure 22 is the lining, precast beam and prefabricated building of steel construction assembled architecture system in seventh embodiment of the invention The connection schematic diagram of plate.
Figure 23 is the lining, precast beam and prefabricated building of steel construction assembled architecture system in eighth embodiment of the invention The connection schematic diagram of plate.
Figure 24 is the Side fascia, precast beam and prefabricated building of steel construction assembled architecture system in ninth embodiment of the invention The connection schematic diagram of plate.
Figure 25 is the exterior wall of steel construction assembled architecture system and the connection signal of window in first embodiment of the invention Figure.
Figure 26 is the connection schematic diagram that outline border is installed in the side wall and window for install in Figure 25 slot.
In attached drawing, 100- steel construction assembled architecture system, 1- prefabricated foundation, the prefabricated reinforcing prop of 2- steel construction, 3- structure Braced frame, 4- anchor steel structure, 6- pedestal, 7- steel structure column, 8- first foundation bottom, the second subfoundation of 9-, 10- concrete Base for post, 11- first connecting portion, 12- suspension hook, 13- reinforce flange, 14- second connecting portion, 17- precast floor slab, prefabricated on the outside of 18- Beam, precast beam inside 19-, 20- steel construction girder, 21- plug connector, the prefabricated connector of 22-, 23- Side fascia, 24- lining, 25- wallboard, 26- public affairs slot, 27- female groove, 28- bar planting hole, the plug division 29-, the first side plate of 30-, the second side plate of 32-, 34- connection Plate, 36- prefabricated component, 37- mounting groove, 38- fixed plate, the first bolt of 39-, the second bolt of 40-, the first fixed plate of 41-, 42- Two fixed plates, 43- water-proof precast product, the first joint face of 44-, the second joint face of 45-, 46- third joint face, 47- grouting seam, 48- support portion, 49- rake, 50- bottom plate, 51- extension board, 53- fixing groove, 54- arc panel, 55- mounting plate, 56- locking spiral shell Bolt, 57- bolt retainer, the first inclined-plane 60-, the second inclined-plane 61-, 62- window mounting hole, 63- waterproof boss, 64- installing slot, 65- stainless steel flat logical, 66- window, 67- install outline border.
【Specific embodiment】
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
It should be noted that it can be directly on another component when component is referred to as " being fixed on " another component Or there may also be components placed in the middle.When a component is considered as " connection " another component, it, which can be, is directly connected to To another component or it may be simultaneously present component placed in the middle.When a component is considered as " being set to " another component, it It can be and be set up directly on another component or may be simultaneously present component placed in the middle.Term as used herein is " vertical ", " horizontal ", "left", "right" and similar statement for illustrative purposes only.
Unless otherwise defined, all technical and scientific terms used herein and belong to technical field of the invention The normally understood meaning of technical staff is identical.Term as used herein in the specification of the present invention is intended merely to description tool The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term " and or " used herein includes one or more phases Any and all combinations of the listed item of pass.
First embodiment
Please referring also to Fig. 1 to Fig. 4, first embodiment of the invention provide a kind of steel construction assembled architecture system 100, If including prefabricated foundation 1, structural support frame 3, several precast floor slabs 17 and drywall panel (not indicating).
Prefabricated foundation 1 includes pedestal 6 and at least steel structure column 7 on pedestal 6.In the present embodiment, each Pedestal 6 is equipped with a steel structure column 7.Pedestal 6 includes first foundation bottom 8, the second subfoundation 9 and concrete base for post 10, the Two subfoundations 9 are connected on the one side of first foundation bottom 8, and concrete base for post 10 is connected to the second subfoundation 9 backwards The side of first foundation bottom 8.In the present embodiment, first foundation bottom 8 and the second subfoundation 9 are concrete material Matter.Steel structure column 7 is connected to side of the concrete base for post 10 backwards to first foundation bottom 8.In the present embodiment, first foundation Bottom 8, the second subfoundation 9, concrete base for post 10 and steel structure column 7 axis overlap, first foundation bottom 8 it is transversal Face area is identical as the cross-sectional area of the second subfoundation 9, cross-sectional area, the concrete base for post 10 of first foundation bottom 8 Cross-sectional area and the cross-sectional area of steel structure column 7 be sequentially reduced.The prefabricated foundation 1 of this kind of structure can increase prefabricated base The forced area of plinth 1, and then extend the service life of building.Steel structure column 7 is equipped with first connecting portion backwards to one end of pedestal 6 11, in the present embodiment, first connecting portion 11 is protrusion.Suspension hook 12 is also connected on the periphery wall of steel structure column 7.Suspension hook 12 It is welded on steel structure column 7, hoisting prefabricated basic 1 when facilitating subsequent installation.In the present embodiment, steel structure column 7 is outer It is additionally provided on side wall and reinforces flange 13, reinforced flange 13 and connect steel structure column 7 and concrete base for post 10, it is pre- to further increase this The intensity on system basis 1.
Structural support frame 3 includes the prefabricated reinforcing prop 2 of steel construction and precast beam (not indicating).The prefabricated reinforcing prop 2 of steel construction With 7 grafting of steel structure column.In the present embodiment, the prefabricated reinforcing prop 2 of steel construction is equipped with the towards an end face of prefabricated foundation 1 Two interconnecting pieces 14, second connecting portion 14 are the groove structure used with the male cooperation, and protrusion is plugged in the groove structure It is interior.Prefabricated foundation 1 and the prefabricated reinforcing prop 2 of steel construction are connected by the way of grafting, and it is pre- with steel construction to can be improved prefabricated foundation 1 The assembly efficiency of reinforcing prop 2 processed.The peripheral wall of the prefabricated reinforcing prop 2 of steel construction is equipped with several anchoring steel structures 4.In present embodiment In, one end of each anchoring steel structure 4 is welded on the prefabricated reinforcing prop 2 of steel construction, and anchors steel structure 4 along the prefabricated reinforcing prop of steel construction 2 radially extend.Precast beam and the prefabricated reinforcing prop 2 of steel construction pass through welded connecting.Please also refer to Fig. 8, in present embodiment In, precast beam includes outside precast beam 18 and internal precast beam 19, wherein outside precast beam 18 is set to the steel construction assembled and builds Building body is 100 periphery, and internal precast beam 19 is set in the inner space of the steel construction assembled architecture system 100.Outside is pre- Beam 18 processed includes steel construction girder 20 and plug connector 21 with internal precast beam 19, and plug connector 21 is connected to steel construction girder 20 Side.Steel construction girder 20 and the prefabricated reinforcing prop 2 of steel construction pass through welded connecting.
Please also refer to Fig. 1, Fig. 5 to Fig. 9, in the present embodiment, steel construction assembled architecture system 100 includes several Layer precast floor slab 17, several layers precast floor slab 17 are spaced setting along the vertical direction.Every layer of precast floor slab 17 is superposed on same On the steel construction girder 20 of the steel construction girder 20 of the outside precast beam 18 of layer and internal precast beam 19, and with corresponding steel construction Girder 20 is connected using bonding agent, and in the present embodiment, bonding agent can be in cement mortar, structure glue or ceramic tile gelling agent It is one or more of.It is spread between adjacent two layers precast floor slab 17 and between the precast floor slab 17 and prefabricated foundation 1 of the bottom Equipped with wallboard.Wallboard is equipped with plug division 29,21 grafting of plug connector of plug division 29 and precast beam towards the side of precast beam, and adopts It is connected with bonding agent, in the present embodiment, bonding agent can be one of cement mortar, structure glue or ceramic tile gelling agent or several Kind.Plug division 29 is set to side of the wallboard towards precast beam, and plug connector 21 is set to side of the steel construction girder 20 towards wallboard, because This will not occupy the inner space of building when plug division 29 and when 21 grafting of plug connector substantially, thus make to have in building compared with Big space and preferable appearance.
Please also refer to Figure 10 to Figure 15, every layer of wallboard includes several Side fascias 23 and several linings 24, in this implementation In mode, the thickness of Side fascia 23 is greater than the thickness of lining 24, and each Side fascia 23 includes two blocks of sub- wallboards 25, two pieces of sub- walls Plate 25 along wall thickness direction gluing together to form a Side fascia 23, to enhance the intensity of Side fascia 23.Adjacent two A Side fascia 23 is plugged in together by male and female groove 26,27, specially：The opposite sides of each sub- wallboard 25 is respectively equipped with public slot 26 and female groove 27, each Side fascia 23 passes through 27 grafting of female groove of public slot 26 and adjacent Side fascia 23.In the present embodiment, public Slot 26 and female groove 27 are all set in the center of Side fascia 23, to reduce the damage of wallboard during transportation.It is appreciated that In other embodiments, adjacent two blocks of Side fascias 23 can also be attached by other modes such as bonding, Z-type slots.It is preferred that Ground, public slot 26 and female groove 27 along two adjacent sub- wallboards 25 of thickness of wall body direction arrangement are arranged alternately (Figure 10).It is appreciated that In other embodiments, along two adjacent Side fascias 23 of thickness of wall body direction arrangement, the same end can be respectively provided with public slot 26 Or it is respectively provided with female groove 27 (Figure 12).
The Side fascia 23 adjacent with the prefabricated reinforcing prop 2 of steel construction is equipped with bar planting hole 28.In the present embodiment, bar planting hole 28 is horizontally extending.Anchoring steel structure 4 is anchored in bar planting hole 28, and Side fascia 23 and the prefabricated reinforcing prop 2 of steel construction are connected It is connected together.Several Side fascias 23 surround an accommodation space (not shown) jointly.
Referring again to Fig. 1 and Fig. 5, Side fascia 23 is equipped with plug division 29, plug division towards the side of outside precast beam 18 29 with 21 grafting of plug connector, and fixed using bonding agent, specially：In the present embodiment, the steel construction of outside precast beam 18 Girder 20 is Fang Tongliang, and plug connector 21 is U-shaped fixing piece, such as a channel steel.The side of steel construction girder 20 and precast floor slab 17 It is fixed using bonding agent, one or more of cement mortar, structure glue or ceramic tile gelling agent can be used in bonding agent.U-shaped fixation Part includes bottom plate 50 and two pieces of extension boards 51 being extended in the same direction by the opposite sides of bottom plate 50, bottom plate 50 and two pieces of extensions Plate 51 surrounds a grafting space (not indicating) jointly, and bottom plate 50 is connect with steel construction girder 20 backwards to the side of precast floor slab 17. In the present embodiment, bottom plate 50 is bolted part 57 with steel construction girder 20 and links together.Plug division 29 is one slotting Protrusion is connect, grafting protrusion is inserted in the grafting space, and uses bonding agent, such as cement mortar, structure with U-shaped fixing piece Glue or the cast-in-place fixation of ceramic tile gelling agent.
Please to Figure 15, lining 24 is made referring also to Fig. 8, Fig. 9 and Figure 13 of one block of sub- wallboard 25, thickness compared with It is small, to save the space in building.Several linings 24 are set in accommodation space, the sub- wallboard 25 of two pieces of adjacent linings 24 Mutually splicing is to form interior wall, so that accommodation space is divided into several compartments.In the present embodiment, adjacent two pieces of linings 24 connection type is identical as Side fascia 23, to omit length, is not described in detail here.With the prefabricated reinforcing prop 2 of steel construction Adjacent lining 24 is connect by anchoring steel structure 4 with the prefabricated reinforcing prop 2 of steel construction.Lining 24 is towards internal precast beam 19 Side is equipped with plug division 29,21 grafting of plug connector of plug division 29 and internal precast beam 19, and is fixed using bonding agent, bonding agent It can be one or more of cement mortar, structure glue or ceramic tile gelling agent.In the present embodiment, the steel of internal precast beam 19 Structure girder 20 is Fang Tongliang, and the side of steel construction girder 20 is connect with precast floor slab 17 using bonding agent.Plug connector 21 is to plant Enter reinforcing bar, the one end and steel construction girder 20 for being implanted into reinforcing bar are welded backwards to the side of precast floor slab 17.Plug division 29 is vertical plants Muscle hole.Bar Anchorage is implanted into vertical bar planting hole.In the present embodiment, plug connector 21 includes two rows of implantation reinforcing bars, each Two rows of vertical bar planting holes are correspondingly provided on lining 24, each implantation Bar Anchorage is in corresponding vertical bar planting hole.Preferably, Two rows implantation reinforcing bar is located at 24 opposite sides of lining, and vertical bar planting hole (the i.e. grafting in 24 opposite sides of lining Portion 29) (Figure 14) is arranged in a staggered manner, so that wallboard has higher intensity and better shear behavior.It is appreciated that at other In embodiment, the vertical bar planting hole (i.e. plug division 29) in 24 opposite sides of lining can also be aligned setting (Figure 15).
Referring again to Fig. 5 and Fig. 7, each precast floor slab 17 and the Side fascia 23 that is positioned above by prefabricated component 36 and Bonding agent connection, specially：In the present embodiment, the Side fascia 23 above the precast floor slab 17 is equipped with fixing groove 53, fixing groove 53 is located at Side fascia 23 towards the side of precast floor slab 17.Prefabricated component 36 includes 54, two pieces of mounting plates 55 of arc panel And several lock bolts 56, arc panel 54 are contained in fixing groove 53, two pieces of mounting plates 55 are divided by the opposite sides of arc panel 54 It is not extended to form towards two opposite directions, two pieces of mounting plates 55 are connected to by several lock bolts 56 with precast floor slab 17 respectively Together, it is fixed again using bonding agent between precast floor slab 17, Side fascia 23 and prefabricated component 36 above the precast floor slab 17. The one or more of cement mortar, structure glue or ceramic tile gelling agent can be used in bonding agent.It can be improved using this kind of connection type Precast floor slab 17 supports shearing force performance with 23 junction of Side fascia, in addition, can be accommodated prefabricated component 36 using fixing groove 53 In the inner space in wall, avoiding prefabricated component 36 from occupying building, and make building that there is preferable appearance.
Fig. 9 is referred to, each precast floor slab 17 is not necessarily to connection with the lining 24 being positioned above, only need to be by the lining 24 are supported in 17 top of precast floor slab.It is appreciated that in other embodiments, each precast floor slab 17 with it is disposed thereon Cement mortar, structure glue or the cast-in-place fixation of ceramic tile gelling agent can also be used in the lining 24 of side.
Referring again to Fig. 1, Fig. 5 and Fig. 6, Side fascia 23 is additionally provided with several water-proof precast products backwards to the side of accommodation space 43.In the present embodiment, water-proof precast product 43 is substantially in a long strip shape, and material preferably uses stone material foamed light wall Plate.Each water-proof precast product 43 includes the first joint face 44, the second joint face 45 and third joint face 46, the first joint face 44 with Second joint face 45 is oppositely arranged, and third joint face 46 connects the first joint face 44 and the second joint face 45, and third joint face 46 towards accommodation space.First joint face 44 and the second joint face 45 are solid using bonding agent with adjacent two layers Side fascia 23 respectively Fixed, bonding agent can be one or more of cement mortar, structure glue or ceramic tile gelling agent, third joint face 46 with it is corresponding in advance Floor 17 and outside precast beam 18 processed are fixed using bonding agent.The setting of water-proof precast product 43 can prevent rainwater from precast floor slab 17 penetrate into wall with the junction of exterior wall 23, can further increase the service life of building.It preferably, can be in extension board 51 A grouting seam 47 is reserved, between Side fascia 23 to facilitate injection bonding agent.
In the present embodiment, the first joint face 44 be inclined-plane, the first joint face 44 towards far from accommodation space direction by It is gradually tilted to prefabricated foundation 1, the Side fascia 23 connecting with the first joint face 44 is equipped with first cooperated with the first joint face 44 Inclined-plane 60, the first inclined-plane 60 are fixed with the first joint face 44 using bonding agent.Second joint face 45 includes support portion 48 and inclination Portion 49, support portion 48 are supported on corresponding Side fascia 23 and are fixed with corresponding Side fascia 23 using bonding agent, rake 49 Rake 49 is connected to farthest away from the side of the accommodation space, rake 49 is towards the direction far from accommodation space gradually to prefabricated Basis 1 tilts, and the Side fascia 23 connecting with the second joint face 45 is equipped with the second inclined-plane 61 cooperated with rake 49, and second tiltedly Face 61 is fixed with rake 49 using bonding agent.Utilize the inclined design of the first joint face 44 and the second joint face 45, Neng Gougeng Good ground resistance is kept off the rain water, and the waterproof performance of wall is further improved.
Please also refer to Figure 25 to Figure 26, it is also provided with window mounting hole 62 on Side fascia 23, surrounds the window mounting hole One waterproof boss 63 of projection and recessed installing slot 64 on 62 side wall.A stainless steel flat logical 65 is fixed in installing slot 64.Steel Standard formula building system 100 further includes window 66, and window 66 includes metal outer frame 67, and metal outer frame 67 can be used for installing window The windowpane at family 66.In the present embodiment, metal outer frame 67 uses aluminum alloy frame.Metal outer frame 67 and stainless steel flat logical 65 And waterproof boss 63 connects.The setting of waterproof boss 63 can prevent rainwater from the junction of window 66 and Side fascia 23, and infiltration is built Build inside.
In the present embodiment, Side fascia 23 and lining 24 are all made of based on graphene and stone material foamed wall slab, In percentage by weight, including stone material tailing 45-90%, high temperature cosolvent 0.05-10%, graphene 0.05-15%, expansion Graphite 0.05-5%, zirconium oxide 1-20%, calcium carbonate 0.05-10%, clay 1-10%, stabilizer 0.05-5%, degumming agent 0.05-5%, inorganic color 0.05-5%.
Preferably, it should be based on graphene and stone material foamed wall slab, in percentage by weight, including stone material tailing 75%, graphene 3%, high temperature cosolvent 7%, zirconium oxide 2%, expanded graphite 1%, calcium carbonate 3%, clay 3%, stabilizer 3%, degumming agent 3%.
It further illustrates, the stone material tailing is granite, feldspar, quartz, sandstone, diabase, shale, limestone, profound One of Wu Yan, griotte, Desert Sand or more than one.
It further illustrates, the stone material tailing also passes through modification before compounding, and the modification is specific as follows：It will Stone material tailing, brown sugar water, pseudomonas aeruginosa or Pseudomonas Pseudomonas or Pseudomonas pseudoflava or the false unit cell of corruption Bacterium, Colibacter are 100 according to weight ratio:10:0.2:0.1 build heap mixing, then will treated stone material tailing into Row is broken, then carries out then sieving with 100 mesh sieve for grinding 1-3 minutes, and the stone material tailing after sieving is then carried out bacterial screening, will Strain is separated with stone material tailing, and leaving stone material tailing can be obtained modified stone material tailing.
Further explanation, the pseudomonas aeruginosa or Pseudomonas Pseudomonas or Pseudomonas pseudoflava or corruption It is 1.52 × 10 that pseudomonad or Colibacter, which are arranged to effective bacteria containing amount,8-6.35×108The bacterium solution of a/mL is made With.
Further explanation, the pseudomonas aeruginosa or Pseudomonas Pseudomonas or Pseudomonas pseudoflava or corruption Thallus also passes through activation culture before the bacterium solution of pseudomonad configures, and the culture medium prescription that the activation culture culture uses is：It is bright Glue peptone 16.0g, tryptone 10.0g, extract of soybean 8-15g, Radix Schisandrae Bicolori extract 8-20g, K2SO4 10.0g、MgCl2 1.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 7.1 ± 0.2.
It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution of the Colibacter configures The culture medium prescription used is cultivated in culture：Tryptone 5-18g/L, extract of soybean 1-8g/L, Radix Schisandrae Bicolori extract 3- 10g/L, sodium chloride 5-20g/L, pH 7.4 ± 0.2.
It further illustrates, the content containing soybean polyoses reaches 90% or more in the extract of soybean；Fructus schisandrae mentions The content in object containing fructus schisandrae polysaccharide is taken to reach 90% or more.
It further illustrates, the high temperature fluxing agent includes one of calcination of talc, raw talcum, fluorite, diopside or one Kind or more.
Further illustrate, the clay include one of yellow mud, red soil, manganese mud and kaolin or more than one.
Further illustrate, the stabilizer be yttrium, cerium one of oxide or more than one.
A kind of preparation method based on graphene Yu stone material foamed wall slab as described above, preparation method include following step Suddenly：
S1, washup：After stone material tailing is smashed it through 1-10 mesh, smashed stone material tailing is sent into fermentation vat, leaching Steeping pond is cone cylinder, and feeding inlet diameter is the 1/5-1/3 of base diameter, in the high-pressure water pipeline that the inside front of feeding inlet is arranged High-pressure fog mass concentration is that the ammonium oxalate solution of 1.5-5.5% is drenched by spraying while being sent into stone material tailing, up to The volume of spraying ammonium oxalate solution can stop spraying process after being 1.1-1.32 times of stone material tailing volume, impregnate 30- 100min stirs a material at interval of 5min in soak period, is then separated by solid-liquid separation, by the filtrate siphon containing ammonium oxalate It into catch basin, and is separated by solid-liquid separation after taking filtrate to be washed, the step of 2-3 washing is separated by solid-liquid separation is repeated, by separation Washing filtrate returns after merging to be repeated to use when washup next time, and the solid after washing is dried to the stone material tail after being washed It is stand-by after mine；
S2, raw material mixing：By weight percent weighing shared by each raw material is formulated, with ball mill mixing ball milling 3-15h, ball milling Fineness reached 250 meshes full by, be subsequently placed into storage warehouse mix homogenizing；
S3, the powder after homogenizing is put into savings storehouse into drier by mist projection granulating；
S4, cloth firing：The dry granulation material of spray drying tower is subjected to cloth, is put into roller kilns or tunnel oven, Through 900-1300 DEG C, after the firing of soak in 30-300 minutes, it is taken out by kiln cooling, is made and is based on graphene and stone Material foamed wall slab crude product；
S5, by crude product through excision forming, obtain based on graphene and stone material foamed wall slab finished product.
It further illustrates, in S4, the time of soak firing is 100-150 minutes.
It further illustrates, in S5, foamed wall slab product specification is：It is long：2400-3000mm, width：600-1200mm, It is thick：80-500mm.
Since wallboard uses above-mentioned technical proposal, have the advantages that：
1, graphene is a kind of two dimensional crystal, is arranged by carbon atom according to hexagon, is connected with each other, forms a carbon Molecule, structure are highly stable；As the amount of carbon atom connected is increasing, this two-dimensional carbon molecules plane constantly expands Greatly, molecule also constantly becomes larger.The thickness of only one carbon atom of single-layer graphene, i.e., 0.335 nanometer are equivalent to a hair The thickness of 20 a ten thousandths nearly has 1,500,000 layers or so of graphene in the graphite of 1 millimeters thick.Graphene is known most thin A kind of two-dimensional material, and have many advantages, such as high specific surface area and intensity.Each raw material phase in formula in the present invention Mutually auxiliary plays the effect of anti-aging, anticorrosive energy, heat-insulation and heat-preservation, sound insulation, water proof anti-seepage, fireproof, high-strength light, special It is not to have breakthrough discovery on fire endurance, fire endurance can achieve 120min or more.Firstly, various stone material tailings are Substrate, and add graphene, improves the hardness, high temperature resistant and flame retardant property of wallboard, overcomes organic material and is afraid of open fire, easy to aging The deadly defect of deformation, improves the fire protecting performance of inorganic material, and compensates for the defect of inorganic material poor compatibility, Hua Gang The stone materials tailing such as rock, shale, hardness, fire prevention and higher compressive property with higher, to assign wallboard stabilization, high temperature resistant With the performances such as fire-proof and water-proof；Meanwhile substrate is done using various stone material tailings, be conducive to ecological environmental protection, effectively improve resource Production cost is largely saved in comprehensive utilization；It by using expanded graphite as foaming agent, and is combined with foam stabilizer, realization pair The integrally-built Effective Regulation of wallboard during pore structure and foaming, the pore structure partial size formed it into is fine and smooth, is evenly distributed, wallboard Shape is regular, orderly aligned, so that wallboard has cross-linked structure, to achieve the purpose that improve wallboard strength and toughness； Graphene is added in additional stone material tailing and expanded graphite passes through chemical oxidization method in the high temperature environment and changes stone material tailing appearance The property in face, it is easier to other substance association reactions, and be combined rapidly in foaming process with other raw material of substance, expand stone material The foaming aperture size of tailing, but foaming aperture size can not be excessive, causes the wallboard prepared outside face bumps not It is flat, therefore be added after zirconium oxide, calcium carbonate, clay progress ball milling while adding graphene, expanded graphite in hot environment The gap during the reduction of stone material tailing is foamed between stone material tailing is changed, and the composition of microelement in stone material tailing can be changed, Improve stone material tailing itself inoxidizability, control foaming degree also to add stabilizer guarantee reaction in each ion it Between stability make face outside foamed wall slab relatively flat, reduce six panel thickness for being further cut into finished product Degree, the high temperature cosolvent of addition can be rapidly performed by reaction in hot stage, and the gap formed during foaming is fine and smooth uniformly, Each raw material carries out ball milling and reaches 250 mesh full by homogenizing and then mist projection granulating, intermolecular active force strengthens, in high temperature Under environment, although intermolecular be interrupted, the stronger particle of molecular force of homogenizing still has mutual power, raw material each in this way The wallboard so that making on a large scale during reacting can be uniformly filled, it is all uniform smooth in plane of structure, vertical face, be not in The phenomenon of large-area concave-convex injustice, will not be intermolecular to be kept completely separate as common raw material is under high temperature action, arbitrarily flows, makes The filling of each of entire product place substance disunity, when carrying out detection data, thermal coefficient, bulk density, Compression strength, flexural strength have biggish difference；What the present invention was prepared is passed through based on graphene and stone material foamed wall slab Test, bulk density 170-800kg/m3, compression strength >=5MPa, flexural strength >=2.5MPa, conduction heat transfer coefficient≤ 2.0W/m DEG C, A1 grades of combustion rating, oise insulation factor >=35dB, water absorption rate < 0.1%, fire endurance >=2h, radionuclide limitation (interior photograph, outer photograph)≤1.0.
2, in the method for the preparation in present embodiment, ammonium oxalate washing step is also carried out for stone material tailing, can be returned It receives and utilizes rare earth metal such as scandium (Sc), the yttrium (Y), lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium in stone material tailing (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu) etc. So that stone material tailing eliminates rare metal, radiation is reduced, realizes the real environmentally protective purpose of construction material.After testing Filtrate containing ammonium oxalate is siphoned into the liquid in catch basin, and the content of rare earth reaches 0.598g/L-0.785g/L.Stone simultaneously Material tailing can remove the remaining of the ammonium oxalate in stone material tailing by washing process, and water lotion can recycle repetitive cycling use, Extraction of rare earth metal is first carried out when rare earth metal content is high in water lotion, is recycled, not will cause secondary pollution.And the present invention Raw material suitable foaming aperture size is obtained by formula rate by local take with can be convenient, formation is not connected to largely Closed pore independence minute bubbles (in diameter range 5mm), being made has significant anti-aging, anticorrosive, heat-insulation and heat-preservation, sound insulation, waterproof Impervious, fireproof, high-strength light, do not crack, be environmentally protective etc. comprehensive performances in integrally based on graphene and stone material foaming gently Matter wallboard.
3, in application graphene produced by the present invention and stone material tailing foamed wall slab, because of this wallboard product collection green Various functions required for energy saving building in the feature of one, and it is small in size, occupy that space is few, own wt is light, is not required to Want wet work and fragmentary building construction, it is often more important that do not need using a large amount of sandstone cement.Exterior wall does not need to increase water Cement mortar batch time screed-coat, does not need again secondary construction and installation heat insulation layer yet.Working procedure is simple and convenient, greatly reduces and builds Build construction cost cost.This wallboard product can be carried out directly as traditional architecture, assembled architecture inside and outside wall board wall board material The integrated assembling installation of building, can meet building heat preservation heat-insulating decorative integrative installation technology effect；Especially in assembled During architecture construction construction and installation, it is greatly improved the assembly rate of building course using inside and outside wall board product of the invention, contracts The short integral construction duration, largely reduce it is artificial, save material, save construction construction cost, it is comprehensive to improve overall building and apply Work safe mass.And application this wall board material building waste can very recycling, really realize less manpower save Cost, environmentally protective, energy-efficient industrialized building target economic, safety is beautiful.Revolution to traditional architecture materials for wall Profound significance has been sexually revised, personalized designs, industrialized production, information-based pipe are realized to the build model of traditional architecture Reason, prefabricated construction reach the target of sustainable development.
Being sent out based on graphene and stone material in first embodiment that present invention will be further explained below with reference to specific examples Steep lightweight wall plate.The chemical component of tailing used in following embodiments is SiO2< 65%, Al2O3> 8%, Fe2O3< 11%, K2O < 5%, Na2O < 5%, CaO < 5%, MgO < 2%, loss on ignition < 18%, rare earth content 1.246g/L-1.784g/L%.
Embodiment 1
One, raw material proportioning is shown in Table 1；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature fluxing agent is It is shown in Table 4；The stabilizer is yttrium oxide and cerium oxide.
Two, it prepares：
Foamed wall slab specific method will be prepared in above-mentioned proportion raw material to include the following steps：
S1, washup：After stone material tailing is smashed it through 1 mesh, smashed stone material tailing is sent into fermentation vat, fermentation vat To bore cylinder, feeding inlet diameter is the 1/5 of base diameter, is being sent into stone in the high-pressure water pipeline that the inside front of feeding inlet is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 1.5% while material tailing is drenched by spraying, until spraying ammonium oxalate The volume of solution can stop spraying process after being 1.1 times of stone material tailing volume, impregnate 30min, soak period at interval of 5min stirs a material, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and takes filtrate It is separated by solid-liquid separation after being washed, is repeated 2 times the step of washing is separated by solid-liquid separation, weight next time is returned after isolated washing filtrate is merged It is used when after backwashing mine, the solid after washing is dried after the stone material tailing after being washed for use；
S2, raw material mixing：By weight percent weighing shared by each raw material is formulated, with ball mill mixing ball milling 3h, ball milling is thin Degree reached 250 meshes full by, be subsequently placed into storage warehouse mix homogenizing；
S3, the powder after homogenizing is put into savings storehouse into drier by mist projection granulating；
S4, cloth firing：The dry granulation material of spray drying tower is subjected to cloth, is put into roller kilns or tunnel oven, It through 900 DEG C, after the firing of soak in 30 minutes, is taken out by kiln cooling, is made light based on graphene and stone material foaming Matter wallboard crude product；
S5, it is through cut form by crude product：It is long：2400mm, width：600mm, thickness：80mm based on graphene and stone material Foamed wall slab finished product.
Embodiment 2
One, raw material proportioning is shown in Table 1；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature fluxing agent is It is shown in Table 4；The stabilizer is yttrium oxide and cerium oxide.
Two, it prepares：
Foamed wall slab specific method will be prepared in above-mentioned proportion raw material to include the following steps：
S1, washup：After stone material tailing is smashed it through 10 mesh, smashed stone material tailing is sent into fermentation vat, is impregnated Pond is cone cylinder, and feeding inlet diameter is the 1/3 of base diameter, is being sent into the high-pressure water pipeline that the inside front of feeding inlet is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 5.5% while stone material tailing is drenched by spraying, until spraying oxalic acid The volume of ammonium salt solution can stop spraying process after being 1.32 times of stone material tailing volume, 100min be impregnated, at soak period every A material is stirred every 5min, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and takes filtering Object is separated by solid-liquid separation after being washed, and is repeated 3 times the step of washing is separated by solid-liquid separation, and returns to next time after isolated washing filtrate is merged It repeats to use when washup, the solid after washing is dried after the stone material tailing after being washed for use；
S2, raw material mixing：By weight percent weighing shared by each raw material is formulated, with ball mill mixing ball milling 15h, ball milling is thin Degree reached 250 meshes full by, be subsequently placed into storage warehouse mix homogenizing；
S3, the powder after homogenizing is put into savings storehouse into drier by mist projection granulating；
S4, cloth firing：The dry granulation material of spray drying tower is subjected to cloth, is put into roller kilns or tunnel oven, Through 1300 DEG C, after the firing of soak in 300 minutes, it is taken out by kiln cooling, foamed wall slab crude product is made；
S5, it is through cut form by crude product：It is long：3000mm, width：1200mm, thickness：500mm based on graphene and stone Material foamed wall slab finished product.
Embodiment 3
One, raw material proportioning is shown in Table 1；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature fluxing agent is It is shown in Table 4；The stabilizer is yttrium oxide.
Two, it prepares：
Foamed wall slab specific method will be prepared in above-mentioned proportion raw material to include the following steps：
S1, washup：After stone material tailing is smashed it through 4 mesh, smashed stone material tailing is sent into fermentation vat, fermentation vat To bore cylinder, feeding inlet diameter is the 1/4 of base diameter, is being sent into stone in the high-pressure water pipeline that the inside front of feeding inlet is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 2.5% while material tailing is drenched by spraying, until spraying ammonium oxalate The volume of solution can stop spraying process after being 1.21 times of stone material tailing volume, impregnate 60min, soak period at interval of 5min stirs a material, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and takes filtrate It is separated by solid-liquid separation after being washed, is repeated 3 times the step of washing is separated by solid-liquid separation, weight next time is returned after isolated washing filtrate is merged It is used when after backwashing mine, the solid after washing is dried after the stone material tailing after being washed for use；
S2, raw material mixing：By weight percent weighing shared by each raw material is formulated, with ball mill mixing ball milling 4h, ball milling is thin Degree reached 250 meshes full by, be subsequently placed into storage warehouse mix homogenizing；
S3, the powder after homogenizing is put into savings storehouse into drier by mist projection granulating；
S4, cloth firing：The dry granulation material of spray drying tower is subjected to cloth, is put into roller kilns or tunnel oven, It through 950 DEG C, after the firing of soak in 100 minutes, is taken out by kiln cooling, is made light based on graphene and stone material foaming Matter wallboard crude product；
S5, it is through cut form by crude product：It is long：2500mm, width：700mm, thickness：90mm based on graphene and stone material Foamed wall slab finished product.
Embodiment 4
One, raw material proportioning is shown in Table 1；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature fluxing agent is It is shown in Table 4；The stabilizer is cerium oxide.
Two, it prepares：
It includes such as that above-mentioned proportion raw material, which will be prepared based on graphene and stone material foamed wall slab specific method, Lower step：
S1, washup：After stone material tailing is smashed it through 6 mesh, smashed stone material tailing is sent into fermentation vat, fermentation vat To bore cylinder, feeding inlet diameter is the 1/5 of base diameter, is being sent into stone in the high-pressure water pipeline that the inside front of feeding inlet is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 3.5% while material tailing is drenched by spraying, until spraying ammonium oxalate The volume of solution can stop spraying process after being 1.15 times of stone material tailing volume, impregnate 90min, soak period at interval of 5min stirs a material, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and takes filtrate It is separated by solid-liquid separation after being washed, is repeated 3 times the step of washing is separated by solid-liquid separation, weight next time is returned after isolated washing filtrate is merged It is used when after backwashing mine, the solid after washing is dried after the stone material tailing after being washed for use；
S2, raw material mixing：By weight percent weighing shared by each raw material is formulated, with ball mill mixing ball milling 5h, ball milling is thin Degree reached 250 meshes full by, be subsequently placed into storage warehouse mix homogenizing；
S3, the powder after homogenizing is put into savings storehouse into drier by mist projection granulating；
S4, cloth firing：The dry granulation material of spray drying tower is subjected to cloth, is put into roller kilns or tunnel oven, Through 1000 DEG C, after the firing of soak in 150 minutes, it is taken out by kiln cooling, is made and is foamed based on graphene and stone material Lightweight wall plate crude product；
S5, it is through cut form by crude product：It is long：2600mm, width：800mm, thickness：100mm based on graphene and stone material Foamed wall slab finished product.
Embodiment 5
One, raw material proportioning is shown in Table 1；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature fluxing agent is It is shown in Table 4；The stabilizer is cerium oxide.
Two, preparation method is same as Example 2.
Embodiment 6
One, raw material proportioning is shown in Table 1；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature fluxing agent is It is shown in Table 4；The stabilizer is cerium oxide.
Two, preparation method is same as Example 2.
Embodiment 7
One, raw material proportioning is shown in Table 1；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature fluxing agent is It is shown in Table 4；The stabilizer is cerium oxide.
Wherein, also pass through modification before stone material tailing compounding, the modification is specific as follows：By stone material tailing, red Syrup, pseudomonas aeruginosa, Colibacter are 100 according to weight ratio:10:0.2:0.1 carries out building heap mixing, then will processing Stone material tailing afterwards is crushed, then carry out grinding 1 minute then sieve with 100 mesh sieve, then by the stone material tailing after sieving into Row bacterial screening separates strain with stone material tailing, and leaving stone material tailing can be obtained modified stone material tailing.
It further illustrates, it is 1.52 × 10 that pseudomonas aeruginosa, Colibacter, which are arranged to effective bacteria containing amount,8- 2.02×108The bacterium solution of a/mL carry out using.
It further illustrates, thallus also passes through activation culture, the activation training before the bacterium solution of the pseudomonas aeruginosa configures The feeding culture medium prescription that uses cultivated is：Gelatin peptone 16.0g, tryptone 10.0g, extract of soybean 8g, fructus schisandrae extract Object 8g, K2SO4 10.0g、MgCl21.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 7.1.
It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution of the Colibacter configures The culture medium prescription used is cultivated in culture：Tryptone 5g/L, extract of soybean 1g/L, Radix Schisandrae Bicolori extract 3g/L, chlorine Change sodium 5g/L, pH 7.4.
It further illustrates, the content containing soybean polyoses reaches 90% or more in the extract of soybean；Fructus schisandrae mentions The content in object containing fructus schisandrae polysaccharide is taken to reach 90% or more.
Two, preparation method is same as Example 2.Wherein above-mentioned modification is carried out between the step S1 and S2 in preparation method Processing step.
Embodiment 8
One, raw material proportioning is shown in Table 1；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature fluxing agent is It is shown in Table 4；The stabilizer is cerium oxide.
Wherein, also pass through modification before stone material tailing compounding, the modification is specific as follows：By stone material tailing, red Syrup, Pseudomonas Pseudomonas, Colibacter are 100 according to weight ratio:10:0.2:0.1 carries out building heap mixing, then will place Stone material tailing after reason is crushed, and then carries out then sieving with 100 mesh sieve for grinding 3 minutes, then by the stone material tailing after sieving Bacterial screening is carried out, strain is separated with stone material tailing, leaving stone material tailing can be obtained modified stone material tailing.
It further illustrates, it is 5.64 × 10 that Pseudomonas Pseudomonas, Colibacter, which are arranged to effective bacteria containing amount,8- 6.35×108The bacterium solution of a/mL carry out using.
Further explanation, the pseudomonas aeruginosa or Pseudomonas Pseudomonas or Pseudomonas pseudoflava or corruption Thallus also passes through activation culture before the bacterium solution of pseudomonad configures, and the culture medium prescription that the activation culture culture uses is：It is bright Glue peptone 16.0g, tryptone 10.0g, extract of soybean 15g, Radix Schisandrae Bicolori extract 20g, K2SO4 10.0g、MgCl2 1.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 6.9.
It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution of the Colibacter configures The culture medium prescription used is cultivated in culture：Tryptone 18g/L, extract of soybean 8g/L, Radix Schisandrae Bicolori extract 10g/L, Sodium chloride 20g/L, pH 7.2.
It further illustrates, the content containing soybean polyoses reaches 93% in the extract of soybean；Radix Schisandrae Bicolori extract In the content containing fructus schisandrae polysaccharide reach 92%.
Two, preparation method is same as Example 3.Wherein above-mentioned modification is carried out between the step S1 and S2 in preparation method Processing step.
Embodiment 9
One, raw material proportioning is shown in Table 1；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature fluxing agent is It is shown in Table 4；The stabilizer is cerium oxide；
Wherein, also pass through modification before stone material tailing compounding, the modification is specific as follows：By stone material tailing, red Syrup, Pseudomonas pseudoflava, Colibacter are 100 according to weight ratio:10:0.2:0.1 carries out building heap mixing, then will processing Stone material tailing afterwards is crushed, then carry out grinding 2 minutes then sieve with 100 mesh sieve, then by the stone material tailing after sieving into Row bacterial screening separates strain with stone material tailing, and leaving stone material tailing can be obtained modified stone material tailing.
It further illustrates, it is 2.89 × 10 that Pseudomonas pseudoflava, Colibacter, which are arranged to effective bacteria containing amount,8- 3.13×108The bacterium solution of a/mL carry out using.
Further explanation, the pseudomonas aeruginosa or Pseudomonas Pseudomonas or Pseudomonas pseudoflava or corruption Thallus also passes through activation culture before the bacterium solution of pseudomonad configures, and the culture medium prescription that the activation culture culture uses is：It is bright Glue peptone 16.0g, tryptone 10.0g, extract of soybean 11g, Radix Schisandrae Bicolori extract 15g, K2SO4 10.0g、MgCl2 1.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 7.3.
It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution of the Colibacter configures The culture medium prescription used is cultivated in culture：Tryptone 10g/L, extract of soybean 5g/L, Radix Schisandrae Bicolori extract 7g/L, chlorine Change sodium 15g/L, pH 7.6.
It further illustrates, the content containing soybean polyoses reaches 98% in the extract of soybean；Radix Schisandrae Bicolori extract In the content containing fructus schisandrae polysaccharide reach 96% or more.
Two, preparation method is same as Example 3.Wherein above-mentioned modification is carried out between the step S1 and S2 in preparation method Processing step.
Embodiment 10
One, raw material proportioning is shown in Table 1；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature fluxing agent is It is shown in Table 4；The stabilizer is cerium oxide.
Wherein, also pass through modification before stone material tailing compounding, the modification is specific as follows：By stone material tailing, red Syrup, pseudomonas putrefaciens, Colibacter are 100 according to weight ratio:10:0.2:0.1 carries out building heap mixing, then will processing Stone material tailing afterwards is crushed, then carry out grinding 3 minutes then sieve with 100 mesh sieve, then by the stone material tailing after sieving into Row bacterial screening separates strain with stone material tailing, and leaving stone material tailing can be obtained modified stone material tailing.
It further illustrates, it is 3.56 × 10 that pseudomonas putrefaciens, Colibacter, which are arranged to effective bacteria containing amount,8- 6.05×108The bacterium solution of a/mL carry out using.
Further explanation, the pseudomonas aeruginosa or Pseudomonas Pseudomonas or Pseudomonas pseudoflava or corruption Thallus also passes through activation culture before the bacterium solution of pseudomonad configures, and the culture medium prescription that the activation culture culture uses is：It is bright Glue peptone 16.0g, tryptone 10.0g, extract of soybean 14g, Radix Schisandrae Bicolori extract 18g, K2SO4 10.0g、MgCl2 1.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 7.2.
It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution of the Colibacter configures The culture medium prescription used is cultivated in culture：Tryptone 16g/L, extract of soybean 7g/L, Radix Schisandrae Bicolori extract 9g/L, chlorine Change sodium 18g/L, pH 7.5.
It further illustrates, the content containing soybean polyoses reaches 99% in the extract of soybean；Radix Schisandrae Bicolori extract In the content containing fructus schisandrae polysaccharide reach 98%.
Two, preparation method is same as Example 3.Wherein above-mentioned modification is carried out between the step S1 and S2 in preparation method Processing step.
Embodiment 11
One, raw material proportioning is same as Example 7；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature Fluxing agent is to be shown in Table 4；The stabilizer is cerium oxide.
Two, preparation method is same as Example 3.
Embodiment 12
One, raw material proportioning is same as Example 7；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature Fluxing agent is to be shown in Table 4；The stabilizer is cerium oxide.
Two, preparation method is same as Example 4.
Embodiment 13
One, raw material proportioning is same as Example 8；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature Fluxing agent is to be shown in Table 4；The stabilizer is cerium oxide.
Two, preparation method is same as Example 4.
Embodiment 14
One, raw material proportioning is same as Example 8；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature Fluxing agent is to be shown in Table 4；The stabilizer is cerium oxide.
Two, preparation method is same as Example 4.
Embodiment 15
One, raw material proportioning is same as Example 9；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature Fluxing agent is to be shown in Table 4；The stabilizer is cerium oxide.
Two, preparation method is same as Example 4.
Embodiment 16
One, raw material proportioning is shown in same as Example 9；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The height Warm fluxing agent is to be shown in Table 4；The stabilizer is cerium oxide.
Two, preparation method is same as Example 4.
Embodiment 17
One, raw material proportioning is same as Example 9；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature Fluxing agent is to be shown in Table 4；The stabilizer is cerium oxide.
Two, preparation method is same as Example 4.
Embodiment 18
One, raw material proportioning is same as Example 9；The stone material tailing is to be shown in Table 2；The clay is to be shown in Table 3；The high temperature Fluxing agent is to be shown in Table 4；The stabilizer is cerium oxide.
Two, preparation method is same as Example 4.
Ingredient percentage composition list in each embodiment of table 1
Embodiment 1 2 3 4 5 6 7 8 9 10
Stone material tailing 75 78 70 80 45 90 48 79 45 45
Graphene 3 3 6 2 15 0.05 1 1 7 10
High temperature cosolvent 7 5 6 2 10 0.05 1 1 4 9
Zirconium oxide 2 1 1 2 8.95 3 20 5 15 10
Expanded graphite 1 3 5 2 5 0.05 1 3 3 4
Calcium carbonate 3 2 3 4 0.05 1 10 3 8 6
Clay 3 4 4 4 1 2 10 5 8 9
Stabilizer 3 2 2 2 5 0.05 5 1 4 1
Degumming agent 3 2 3 2 5 0.05 5 1 4 2
Inorganic color 0 0 0 0 5 3.75 0 1 2 4
Stone material tailing selective listing in each embodiment of table 2
Clay selective listing in each embodiment of table 3
The each embodiment high temperature cosolvent selective listing of table 4
Embodiment Burn talcum Raw talcum Fluorite Diopside
1 √ -- -- --
2 -- √ -- --
3 -- -- √ --
4 √ √ √ --
5 √ √ -- --
6 √ -- √ --
7 -- √ √ --
8 √ -- -- --
9 -- √ -- --
10 -- -- -- √
11 √ √ √ --
12 √ √ -- √
13 √ -- √ --
14 -- √ √ √
15 √ -- -- --
16 -- √ -- √
17 -- -- √ --
18 √ √ √ √
Testing inspection：
By embodiment 1-18 is prepared in present embodiment foamed wall slab, the comparative example (foaming of market purchase Lightweight wall plate) by the test of physical and mechanical properties, the specific method is as follows, and test result is referring to the following table 5.
One, quantitative measurement：
It is the obtained standard of 40mm × 40mm × 160mm mold molding based on graphene and stone material that specification is taken in this test Foamed wall slab, three samples of one-pass molding, size of sample after molding are 40mm × 40mm × 160mm.Sample is demoulded Afterwards, and by a series of processing standard specimen is obtained.
(1) bulk density：Foamed wall slab sample is placed in electric drying oven with forced convection, is to slowly warm up to 40 ± 5 DEG C, After weighed foamed wall slab sample mass change rate is less than 0.2% twice in 3h, sample is moved to cooling in drier To room temperature, with the oven dry weight G0 of electronic balance weighing sample, unit g is accurate to 0.1g.
The bulk density of sample is calculated by formula, is accurate to 1kg/m3
In formula, ρ-sample density, units/kg/m3；The absolute dry mass of G0- sample, units/kg.
(2) water absorption rate：With being surveyed based on graphene and stone material foamed wall slab sample for above-mentioned test volume density Fixed, quantity is three.Erecting with stone material foamed wall slab sample by width direction based on graphene for absolute dry mass will be dried to It rises and is put into 20 ± 5 DEG C or so of water, test specimen is not less than 25mm away from interval between periphery and test specimen, and the water surface should be higher by sample upper end Sample is taken out from water after 25mm, 2h, exists side by side and is placed on the towel of squeezing, after draining 10min, blots sample with sponge The residual moisture of adsorption.After each surface of sample at least absorbs water twice, its wet weight G1 is weighed immediately, is accurate to 0.1g.
The water absorption rate of sample is calculated by formula, is accurate to 0.1%
In formula, w- inhales the water rate of sample, unit %；The wet quality of G1- sample, unit g；The absolute dry mass of G0- sample, it is single Position g.
(3) radionuclide is limited the quantity：
External Exposure Index (internal exposure index) refers to Natural Radionuclides of Building Materials radium-226 Specific radioactivity, divided by as defined in this standard limit the quantity obtained by quotient.
--- External Exposure Index；
--- the specific radioactivity of Natural Radionuclides of Building Materials radium-226, unit are Becquerel/kilogram (Bq kg-1)；
200 --- in only considering under radiation situation.Radionuclide radium-226 puts in construction material as defined in this standard Penetrating property specific activity limitation, unit are Becquerel/kilogram (Bqkg-1)。
Outreach services (external exposure index) refer to Natural Radionuclides of Building Materials radium- 226, the specific radioactivity of thorium -232 and kalium-40 respectively divided by its respectively individualism when this standard regulation limitation obtained by quotient The sum of.
--- Outreach services：
--- it is respectively the specific radioactivity of Natural Radionuclides of Building Materials radium-226, thorium -232 and kalium-40, Unit is Becquerel/kilogram (Bqkg-1)；
370,260,4200 --- it is respectively in the case of only considering external exposure, naturally to be put in construction material as defined in this standard Penetrating property nucleic radium-226, thorium -232 and the kalium-40 limitation as defined in this standard in its respectively individualism, unit are Becquerel/thousand Gram (Bqkg-1)。
Specific radioactivity (specific activity) refers to certain nuclide radiation quality activity in substance divided by the object Quotient obtained by the quality of matter.
Expression formula is：C=A/m
In formula：C --- specific radioactivity, unit are Becquerel/kilogram (Bqkg-1)；A --- nuclide radiation quality activity, Unit is Becquerel (Bq)；The quality of m --- substance, unit are kilogram (kg).
Two, Mechanics Performance Testing
It is the obtained standard of 40mm × 40mm × 160mm mold molding based on graphene and stone material that specification is taken in this test Foamed wall slab, three samples of one-pass molding, sample obtain standard sample after demoulding, by a series of processing.
(1) flexural strength：In the center in specimen length direction, the width of sample upper and lower surface is measured, width takes two The arithmetic mean of instantaneous value of secondary measured value, is accurate to 0.5mm.In the center in specimen length direction, the thickness of sample two sides is measured Degree, thickness take the arithmetic mean of instantaneous value of measured value twice, are accurate to 0.1mm.Adjusting distance between two support roll shafts is 100mm, will Sample is symmetrically placed on the bearing roll shaft of Intensity of Breaking Tester, opens power supply, starts Intensity of Breaking Tester, is adjusted and is applied load speed Degree makes roll shaft decrease speed (10 ± 1) mm/min that pressurizes.Until sample fractures, the maximal destruction load of sample at this time is recorded P is accurate to 1N.Every group three, sample, the arithmetic mean of instantaneous value of the flexural strength value of 3 test specimens is calculated, to indicate this group of sample Flexural strength is accurate to 0.01MPa.The flexural strength R of sample is calculated as follows, and is accurate to 0.01MPa：
In formula,
R：The flexural strength of sample, units MPa；
P：The breaking load of sample, unit N；
L：Undersetting roll shaft center spacing, unit mm；
b：Specimen width, unit mm；
h：Sample thickness, unit mm.
(2) compression strength：In upper and lower two compression face of sample away from measuring length and width, length with straight steel ruler at the 10mm of side It is the arithmetic mean of instantaneous value of four measured values with width, is accurate to 1mm.Straight steel ruler is used in the middle part of two corresponding side surfaces of sample Thickness is measured, thickness takes the arithmetic mean of instantaneous value of two measured values, is accurate to 1mm.By flexural strength test in 6 pieces of half blocks leaving Test specimen is individually placed on the bearing plate of hydraulic pressure testing machine, and sample center and hydraulic pressure is made to test the center of machine bearing plate It is overlapped.Power supply is opened, oil pump is started, increase sample, when top board is soon contacted with sample, slows down the speed of sample rising Degree, is conveniently adjusted the balance of sample on pedestal, contacts sample compression face as far as possible with top board uniformly.Then with (10 ± 1) mm/ Min speed pressurizes to sample, until test specimen destroys.The arithmetic mean of instantaneous value of the compression strength value of 6 pieces of half block test specimens is calculated, to indicate The compression strength of this group of sample, is accurate to 0.01MPa.Test specimen compression strength σ is calculated as follows, and is accurate to 0.01MPa：
In formula, σ：Compression strength, units MPa；P：Breaking load, unit N；S：Test specimen compression area, unit mm2。
(3) Determination of conductive coefficients：The size of test sample is 200mm × 200mm × 10mm.The measuring method of thermal coefficient According to GB/T10294-2008《Technology of Steady State Thermal Resistance of Thermal Insulating Material and measurement in relation to characteristic》Method carries out, and Measured Results of Thermal Conductivity result is The average value of two test results is accurate to 0.001W/ (mK).
Table 5
By upper table data it is found that present embodiment formula composition with proportion is combined after obtain based on graphene and stone material bubble Lightweight wall plate after tested, is distinguished less consistent in combustion rating；The lightweight wall plate of the application is in bulk density 170-800kg/ m3, compression strength >=5MPa, flexural strength >=2.5MPa, conduction heat transfer coefficient≤2.0W/m DEG C, A1 grades of combustion rating, oise insulation factor >=35dB, water absorption rate < 0.1% are more excellent than comparative example on physical and mechanical properties.
It is gradually increased on compression strength, flexural strength from embodiment 1,2,3,4,5 as graphene dosage increases , but thermal coefficient increases as graphene dosage increases；Seeing after being added to expanded graphite from embodiment 1,2 can be The numerical value of thermal coefficient being controlled, and the amount embodiment 2 for adding expanded graphite is higher by embodiment 1 twice, thermal coefficient reduces faster, It illustrates that expanded graphite has certain abirritation, therefore wants strict control graphene and expansion when carrying out raw material configuration The ratio of graphite cannot pursue simply the promotion of compression strength, flexural strength, and the problem of have ignored thermal coefficient, therefore this Apply obtaining in the ratio of configuration graphene and expanded graphite by countless orthogonal tests, both can guarantee that compression strength, anti-folding are strong Degree improves can reduce thermal coefficient again.
And embodiment 7,8,9,10 bulk density, compression strength, flexural strength, conduction heat transfer coefficient, combustion rating, Oise insulation factor, water absorption rate are compared with superior numerical value, and stone material tailing also passes through modification before compounding, by having richness Some metallic elements can be removed after collecting the microorganism enrichment processing of the substance of specific certain metals, so that stone material tailing is purer Only, between so that stone material tailing is uniformly embedded in macromolecule in later period high-temperature calcination after the additional milled processed by sunflower oil, shape It reticulates structure and increases bulk density, reduce water absorption rate.The invention that the Chinese Patent Application No. that compares is 201610090524.3 A kind of cement base foamed light composite material and preparation method are disclosed, the bulk density of the application, compression strength, anti-folding are strong Degree, conduction heat transfer coefficient, combustion rating, oise insulation factor, water absorption rate are superior to Chinese patent 201610090524.3, give prominence to the key points It is far longer than Chinese patent 201610090524.3 in bulk density.The Chinese Patent Application No. that compares is 201610258377.6 A kind of bulk density for the light cellular partition board the application for adding loofah fiber of disclosure of the invention, compression strength, flexural strength, Conduction heat transfer coefficient, combustion rating, oise insulation factor, water absorption rate are superior to Chinese patent 201610258377.6, especially in water absorption rate The upper equal < 0.1% of the application, and 201610258377.6 water absorption rate of Chinese patent still reaches 21.4%, therefore, uses this Shen Compared with the prior art technical solution please has greatly improved in each physical characteristic and mechanical characteristic.
In the range of radionuclide limitation in embodiment 1-18 meets national regulation, the embodiment that compares 7,8,9, Radionuclide limitation in 10 includes IRa (External Exposure Index) and IRa (Outreach services) all than embodiment 1-6,11-18 It is small, because the rare earth metal content in tailing can be greatly reduced after carrying out washup recovering rare earth metal, it is well known that, There are many type of radiation metal, and cannot pass through a kind of method can remove, but the modification Jing Guo the application, moreover it is possible to reduce The content of radiation metal has been truly realized environmentally protective effect so that the wallboard radiation being prepared is smaller.
Same as Example 7 in raw material in comparative example 2, difference is：The bacterium solution of viscous pseudomonad configures preceding thallus also By activation culture, extracted in the culture medium prescription that the activation culture culture uses without containing extract of soybean, fructus schisandrae Object is replaced using glucose band.Escherichia coli also pass through activation culture, the activation culture before the bacterium solution of Colibacter configures It cultivates in the culture medium prescription used without containing extract of soybean, Radix Schisandrae Bicolori extract, is replaced using glucose band.And Strain during modification adds activation step, and plant polyose has been used to substitute conventional carbon source (glucose in the culture medium of activation Deng), the strain after discovery activation has the metallic element ability in more excellent absorption tailing；It was found that the activation of embodiment 7 Strain afterwards compares comparative example 2 with the metallic element ability in more excellent absorption tailing, so that the huge sum of money in raw material Belonging to content reduces.
In addition it gives the wallboard that embodiment 1 is prepared to coherent detection center to detect, the result and data of detection Such as following table：
As seen from the above table, the wallboard produced using the technical solution of the application meets national construction engineering quality prison Superintend and direct inspection center BETC-JN1-2017-00003, national building engineering quality supervision inspection center BETC-JN1-2017- 00004, the standard of national building engineering quality supervision inspection center BETC-JN1-2017-00004.Embodiment 2-17 is by inspection Survey also meets above-mentioned standard and does not just enumerate one by one.
Present embodiment also provides a kind of assembly method of steel construction assembled architecture system 100, includes the following steps：
It is laid with prefabricated foundation 1；
The steel structure column 7 of one end of the prefabricated reinforcing prop 2 of steel construction and prefabricated foundation 1 is plugged in together；
By the steel construction girder 20 of precast beam with the prefabricated reinforcing prop 2 of steel construction by being welded and fixed；
Two blocks of adjacent wallboards are mutually spliced or are bonded, anchoring steel structure 4 is plugged in bar planting hole 28, with bonding agent, Such as the gap in one or more of cement mortar, structure glue or ceramic tile gelling agent filling bar planting hole 28, to connect wallboard With the prefabricated reinforcing prop 2 of steel construction；The plug connector 21 of the plug division 29 of wallboard and precast beam is subjected to grafting, then solid using bonding agent It is fixed, to connect wallboard and precast beam；
Precast floor slab 17 is supported on the steel construction girder 20 of precast beam, and is passed through with the steel construction girder 20 of precast beam Bonding agent connection.
Anti-seismic performance test：This test is tested with 15 meters of high buildings, is pressed《Standard for earthquakeresistant evaluation of buildings》 GB50023-2009 carries out compound seismic capability analysis using identification method step by step accordingly, to compare comparative example 1-2 and this The anti-seismic performance of steel construction assembled architecture system in invention first embodiment, wherein comparative example 1 and the present invention first are implemented The structure of steel construction assembled architecture system 100 in mode is roughly the same, the difference is that, its steel construction in comparative example 1 Prefabricated reinforcing prop is connect with wallboard by mortar；Steel construction assembled architecture in comparative example 2 and first embodiment of the invention The structure of system 100 is roughly the same, the difference is that, its precast beam does not include plug connector 21 in comparative example 2, passes through steel knot Structure girder 20 is directly connect with wallboard by mortar.Test result shows that its seismic degree of the building in comparative example 1 is about 7 degree, right Building its seismic degree in ratio 1 is about 6 degree, steel construction assembled architecture system its antidetonation in first embodiment of the invention Degree is 10 degree or more, and compared to the building system in comparative example 1-2, its seismic degree improves a lot.
Second embodiment
Referring to Figure 16 to Figure 17, second embodiment of the invention provides a kind of steel construction assembled architecture system, knot Structure is roughly the same with the structure of steel construction assembled architecture system 100 in first embodiment, the difference is that：First is that outer The structure of portion's precast beam 18：In the present embodiment, steel construction girder 20 is I-beam comprising the first side plate 30, second side Plate 32 and connecting plate 34, the first side plate 30 are oppositely arranged with the second side plate 32, and connecting plate 34 connects the first side plate 30 and second side Plate 32.First side plate 30, the second side plate 32 and connecting plate 34 are welded with the prefabricated reinforcing prop 2 of steel construction.Plug connector 21 is that side is logical. Side is logical to be welded on the first side plate 30 and backwards to connecting plate 34, this kind of connection type can reduce to 20 structure of steel construction girder The destruction of globality, so that the intensity with higher of steel construction girder 20.Plug division 29 is a container, and side is logical to be inserted in In container, the first side plate 30 is supported in side of the Side fascia 23 towards precast beam, the first side plate 30 and Fang Tongjun and Side fascia 23 are fixed using one or more of bonding agent, such as cement mortar, structure glue or ceramic tile gelling agent.Precast floor slab 17 It is supported on the second side plate 32, and is fixed with second side plate 32 using bonding agent.Cement mortar, structure glue can be used in bonding agent Or one or more of ceramic tile gelling agent.Grouting seam 47 is between water-proof precast product 43 and Side fascia 23.Second is that prefabricated building Plate 17 and the connection type of Side fascia 23 being positioned above, in the present embodiment, precast floor slab 17 be positioned above Side fascia 23 is connected by prefabricated component 36, specially：Side fascia 23 above the precast floor slab 17 is equipped with mounting groove 37, Mounting groove 37 is located at Side fascia 23 towards the side of accommodation space.Prefabricated component 36 includes fixed plate 38, the first bolt 39 and second Bolt 40.The substantially L-shaped plate of fixed plate 38 comprising two pieces of first fixed plates 41 connected vertically and the second fixed plate 42. Fixed plate 38 is contained in the mounting groove 37, and the first fixed plate 41 is resisted against on the side wall of mounting groove 37, and the second fixed plate 42 is supported It is against on precast floor slab 17.First bolt 39 successively wears the first fixed plate 41 and Side fascia 23, and the second bolt 40 wears second Fixed plate 42 is simultaneously plugged in precast floor slab 17, thus by precast floor slab 17 and the Side fascia 23 for being located at 17 top of precast floor slab It links together.
Third embodiment
Referring to Figure 18, third embodiment of the invention provides a kind of steel construction assembled architecture system, structure and the The structure of steel construction assembled architecture system 100 in one embodiment is roughly the same, the difference is that internal precast beam 19 Structure：In the present embodiment, the steel construction girder 20 of internal precast beam 19 is I-beam, and plug connector 21 is U-shaped fixing piece. The side of I-beam is fixed with precast floor slab 17 using bonding agent, and cement mortar, structure glue or ceramic tile gelling can be used in bonding agent One or more of agent.U-shaped fixing piece is welded in I-beam on the side plate of precast floor slab 17.Grafting on lining 24 Portion 29 is grafting protrusion, and grafting protrusion is plugged in U-shaped fixing piece, and is fixed with U-shaped fixing piece using bonding agent, bonding agent One or more of cement mortar, structure glue or ceramic tile gelling agent can be used.
4th embodiment
Referring to Figure 19, four embodiment of the invention provides a kind of steel construction assembled architecture system, structure and the The structure of steel construction assembled architecture system 100 in one embodiment is roughly the same, the difference is that：In present embodiment In, by being welded to connect, this kind of connection type can be avoided to steel knot the bottom plate 50 and steel construction girder 20 of outside precast beam 18 The destruction of 20 structural integrity of structure girder, so that the intensity with higher of steel construction girder 20.
5th embodiment
Refer to Figure 20, fifth embodiment of the invention provides a kind of steel construction assembled architecture system, structure and the The structure of steel construction assembled architecture system in three embodiments is roughly the same, the difference is that, in the present embodiment, The steel construction girder 20 of its inside precast beam 19 is Fang Tongliang.
Sixth embodiment
Refer to Figure 21, sixth embodiment of the invention provides a kind of steel construction assembled architecture system, structure and the The structure of steel construction assembled architecture system in four embodiments is roughly the same, the difference is that steel construction girder 20 and pre- The connection type of floor 17 processed：In the present embodiment, steel construction girder 20 and precast floor slab 17 by prefabricated connector 22 into Row connection, prefabricated connector 22 use fourth of the twelve Earthly Branches hook spiral.Fourth of the twelve Earthly Branches hook spiral is embedded in precast floor slab 17 and steel construction girder 20 In, and cast-in-site is carried out, to connect steel construction girder 20 and precast floor slab 17.In the present embodiment, along thickness of wall body side It is located at side of 54 central axis of arc panel far from the accommodation space to the junction between two adjacent sub- wallboards 25 of arrangement, This kind of structure can stop the infiltration inside house to enter within doors using arc panel 54, for example, when stopping cleaning in house The water for penetrating into wall enters within doors, so that building has preferably waterproof performance.
7th embodiment
Refer to Figure 22, seventh embodiment of the invention provides a kind of steel construction assembled architecture system, structure and the The structure of steel construction assembled architecture system in six embodiments is roughly the same, the difference is that：In the present embodiment, Steel construction girder 20 is attached with precast floor slab 17 by prefabricated connector 22 and bonding agent, specially：Prefabricated connector 22 Using fourth of the twelve Earthly Branches hook spiral.In one end insertion precast floor slab 17 of fourth of the twelve Earthly Branches hook spiral, the other end and steel construction girder 20 are welded, It is fixed again by bonding agent between steel construction girder 20 and precast floor slab 17, to connect steel construction girder 20 and precast floor slab 17. It is one or more of cast-in-place that cement mortar, structure glue or ceramic tile gelling agent can be used in bonding agent.Using this kind of connection type energy The structural integrity to steel construction girder 20 is enough avoided to damage, so that steel construction girder 20 has higher intensity.
8th embodiment
Refer to Figure 23, eighth embodiment of the invention provides a kind of steel construction assembled architecture system, structure and the The structure of steel construction assembled architecture system in one embodiment is roughly the same, the difference is that inserting in internal precast beam 19 The structure of fitting 21：In the present embodiment, plug connector 21 is welded in steel construction girder 20 backwards to 17 side of precast floor slab for one Side it is logical, plug division 29 is a container, and side is logical to be inserted in container, and is fixed using bonding agent, and water can be used in bonding agent One or more of cement mortar, structure glue or ceramic tile gelling agent.
9th embodiment
Refer to Figure 24, ninth embodiment of the invention provides a kind of steel construction assembled architecture system, structure and the The structure of steel construction assembled architecture system in two embodiments is roughly the same, the difference is that the knot of steel construction girder 20 Structure：In the present embodiment, steel construction girder 20 uses Fang Tongliang.
Tenth embodiment
Tenth embodiment of the invention provides a kind of steel construction assembled architecture system, in structure and first embodiment Steel construction assembled architecture system structure it is roughly the same, the difference is that the material of wallboard, in the present embodiment, outside Wallboard 23 and lining 24 are all made of based on graphene and nonmetallic tailings foamed wall slab, in percentage by weight, packet Include nonmetallic tailings 55-75%, graphene 0.05-15%, vermiculite 1-15%, high temperature cosolvent 0.05-15%, high-temperature fibre 5-20%, foaming agent 0.05-5%, zirconium oxide 1-20%, clay 1-10%, stabilizer 0.05-5%, degumming agent 0.05-5%.
It further illustrates, the nonmetallic tailings refer to granite, feldspar, quartz, sandstone, diabase, shale, Dali One or more of rock, basalt, limestone, gangue, coal mine waste residue, ceramic waste residue, Desert Sand.
It further illustrates, the nonmetallic tailings also pass through modification before compounding, and the modification is specific as follows： By nonmetallic tailings, brown sugar water, strawberry pseudomonad or Pseudomonas taetrolens or Pseudomonas pseudoflava or the soft corruption of pineapple Sick leave monad, Colibacter are 200 according to weight ratio:20:0.2:0.3 build heap mixing, then will that treated is non- Metal tailings are crushed, and are then carried out grinding and 1-3 minute and then are sieved with 100 mesh sieve, then by the nonmetallic tailings after sieving into Row bacterial screening separates strain with nonmetallic tailings, and leaving nonmetallic tailings can be obtained modified nonmetallic tailings.
Further explanation, the strawberry pseudomonad or Pseudomonas taetrolens or Pseudomonas pseudoflava or pineapple are soft It is 2.01 × 10 that maize ear rot pseudomonad or Colibacter, which are arranged to effective bacteria containing amount,8-5.99×108The bacterium solution of a/mL into It exercises and uses.
Further explanation, the strawberry pseudomonad or Pseudomonas taetrolens or Pseudomonas pseudoflava or pineapple are soft Thallus also passes through activation culture, the culture medium prescription that the activation culture culture uses before the bacterium solution of maize ear rot pseudomonad configures For：Gelatin peptone 16.0g, tryptone 10.0g, extract of soybean 10-20g, vegetable seed extract 5-15g, K2SO4 10.0g、 MgCl21.4g, agar 15g, cetrimonium bronmide 0.2g, pH 7.1 ± 0.2.
It further illustrates, the content containing soybean polyoses reaches 90% or more in the extract of soybean；Vegetable seed extract In the content containing rapeseed polysaccharides reach 95% or more.
It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution of the Colibacter configures The culture medium prescription used is cultivated in culture：Tryptone 10g/L, extract of soybean 5-8g/L, vegetable seed extract 3-10g/L, Sodium chloride 10g/L, pH 7.4 ± 0.2.
It further illustrates, the clay includes one or more of yellow mud, red soil, manganese mud and kaolin.
It further illustrates, the fluxing agent includes one or more of calcination of talc, raw talcum, fluorite, diopside.
It further illustrates, the foaming agent is one or more of expanded graphite, silicon carbide, carbon dust, expanded perlite.
Further illustrate, the stabilizer be yttrium, cerium one of oxide or more than one.
Preparation method based on graphene Yu nonmetallic tailings foamed wall slab as described above, preparation method include such as Lower step：
S1, washup：After nonmetallic tailings are smashed it through 1-10 mesh, smashed nonmetallic tailings are sent into fermentation vat In, fermentation vat is cone cylinder, and feeding inlet diameter is the 1/5-1/3 of base diameter, in the high pressure that the inside front of feeding inlet is arranged Waterpipe high-pressure fog mass concentration while being sent into nonmetallic tailings is that the ammonium oxalate solution of 1.5-5.5% is beaten by spraying It is wet, until the volume of spraying ammonium oxalate solution can stop spraying process after being 1.1-1.32 times of nonmetallic tailings volume, 30-100min is impregnated, a material is stirred at interval of 5min in soak period, is then separated by solid-liquid separation, ammonium oxalate will be contained Filtrate is siphoned into catch basin, and is separated by solid-liquid separation after taking filtrate to be washed, and repeats the step of 2-3 washing is separated by solid-liquid separation, It is returned after isolated washing filtrate is merged and repeats next time to use when washup, the solid after washing is dried after obtaining washing Nonmetallic tailings after it is stand-by；
S2, raw material add other auxiliary materials mixing dry method to found powder-grinding：First weigh 30% nonmetallic original of weight in good formula Material (in addition to high-temperature fibre) is pre-mixed with other raw materials, and the weight ratio for being pre-mixed raw material is made to account for formula material total weight 30%, after batch mixer mixes, be transferred in raw material roll-over homogenizing into premix, then with remaining 70% nonmetallic tailings Raw material on cross section by uniformly proportion, be put into vertical mill Vertical Mill together, obtain fineness be 300 mesh full by Vertical Mill raw material Powder is transferred to excessive homogenizing bin, is granulated by granulating system, fluidisation, dry, screening obtain granulating raw material, then by high-temperature fibre Raw material and granulating raw material obtain base-material after mixing, are delivered to raw material finished product storage warehouse；Mixing machine incorporation time is 10-300 Minute, Vertical Mill incorporation time is 10-600 minutes；
S3, cloth：Base-material is subjected to automatic drying cloth, is put into roller kilns or tunnel oven, through 900-1300 DEG C, After 30-300 minutes high temperature firings, it is taken out, is made based on graphene and nonmetallic tailings foamed light by kiln cooling Wallboard crude product；
S4, crude product pass through excision forming, obtain based on graphene and nonmetallic tailings foamed wall slab finished product.
It further illustrates, in S3, the time of high temperature firing is 100-150 minutes.
It further illustrates, in S4, is based on graphene and nonmetallic tailings foamed wall slab product specification：It is long：2400- 3000mm, width：600-1200mm, thickness：80-600mm.
Since wallboard uses above-mentioned technical proposal, have the advantages that：
1, graphene is a kind of two dimensional crystal, is arranged by carbon atom according to hexagon, is connected with each other, forms a carbon Molecule, structure are highly stable；As the amount of carbon atom connected is increasing, this two-dimensional carbon molecules plane constantly expands Greatly, molecule also constantly becomes larger.The thickness of only one carbon atom of single-layer graphene, i.e., 0.335 nanometer are equivalent to a hair The thickness of 20 a ten thousandths nearly has 1,500,000 layers or so of graphene in the graphite of 1 millimeters thick.Graphene is known most thin A kind of two-dimensional material, and have many advantages, such as high specific surface area and intensity.Each raw material phase in formula in the present invention Mutually auxiliary plays the effect of anti-aging, anticorrosive energy, heat-insulation and heat-preservation, sound insulation, water proof anti-seepage, fireproof, high-strength light, special It is not to have breakthrough discovery on fire endurance, fire endurance can achieve 120min.Firstly, various nonmetallic tailings are base Material, and graphene is added, improve the hardness, high temperature resistant and flame retardant property of wallboard；It overcomes organic material and is afraid of open fire, change easy to aging The deadly defect of shape, improves the fire protecting performance of inorganic material, and compensates for the defect of inorganic material poor compatibility；Hua Gang The nonmetallic tailings such as rock, shale, hardness, fire prevention and higher compressive property with higher, to assign wallboard stabilization, resistance to height The performances such as mild fire prevention.Meanwhile substrate is done using various nonmetallic tailings, be conducive to ecological environmental protection, effectively improve resource Comprehensive utilization is turned waste into wealth, and production cost is largely saved；By using expanded graphite as foaming agent, and mutually tied with foam stabilizer It closes, realizes the pore structure partial size exquisiteness formed it into the integrally-built Effective Regulation of wallboard during pore structure and foaming, distribution Uniformly, wallboard shape is regular, orderly aligned, so that wallboard has cross-linked structure, improves wallboard strength and tough to reach The purpose of property；Additional nonmetallic tailings be added graphene pass through in the high temperature environment with expanded graphite chemical oxidization method change it is non- The property of metal tailings outer surface, it is easier to and rapid in foaming process and other raw material of substance with other substance association reactions In conjunction with expanding the foaming aperture size of nonmetallic tailings, but foaming aperture size can not be excessive, causes the wall prepared Plate outside face is uneven, aperture is uneven, therefore zirconium oxide is added while adding graphene, expanded graphite, calcium carbonate, glues Gap after soil progress Vertical Mill during hot environment changes nonmetallic tailings and reduces foaming between nonmetallic tailings, and can change The composition of microelement in nonmetallic tailings, improves the inoxidizability of nonmetallic tailings itself, and the degree for controlling foaming is also wanted Addition stabilizer guarantees that the stability in reaction between each ion makes outside foamed wall slab that face is relatively flat, reduce into Six plate thicknesses for being cut into finished product of one step, the high temperature cosolvent of addition can be rapidly performed by instead in hot stage Answer, the gap that is formed during foaming is fine and smooth uniformly, each raw material carry out Vertical Mill reach 300 mesh full by, then homogenizing is granulated, Intermolecular active force strengthens, under high temperature environment, although intermolecular be interrupted, the stronger particle of molecular force of homogenizing Still there is mutual power, raw material each in this way can uniformly fill the wallboard so that making on a large scale during reacting, Plane of structure, vertical face are all uniform smooth, are not in the phenomenon of large-area concave-convex injustice, will not be as common raw material is in high temperature action Under, it is intermolecular to be kept completely separate, arbitrarily flow, so that the substance disunity of each of entire product place filling, and add Raw material (arbitrarily selects high aluminium profiles ceramic fibre, zirconium shield fiber, quartz fibre, one in basalt fiber first is that high-temperature fibre Kind or a variety of compositions), other raw materials are granulated before this among manufacture craft, then cloth after directly being mixed with high-temperature fibre Material, the bubble formed during foaming can closely connect under the traction of high-temperature fibre, and obtained wallboard to be prepared has Superior resistance to compression, flexural strength, the advantages of will not being broken because of high-temp combustion during encountering fire.Carrying out testing number According to when, thermal coefficient, bulk density, compression strength, flexural strength have biggish difference；The present invention be prepared based on stone Black alkene and nonmetallic tailings foamed wall slab after tested, bulk density 170-750kg/m3, compression strength >=5MPa, resist Folding intensity >=2.5MPa, conduction heat transfer coefficient≤2.0W/m DEG C, A1 grades of combustion rating, oise insulation factor >=35dB, water absorption rate < 0.1%, fire endurance >=2h, radionuclide limitation (interior photograph, outer photograph)≤1.0；With more excellent anticorrosive, anti-ageing The advantages that change, insulation, sound insulation, fire prevention, waterproof, impervious, antidetonation, cracking resistance, high-strength light, green safe environmental protection.
2, in the method for the preparation of present embodiment, ammonium oxalate washing step is also carried out for nonmetallic tailings, can be returned It receives and utilizes rare earth metal such as scandium (Sc), the yttrium (Y), lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium in nonmetallic tailings (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu) etc. So that nonmetallic tailings are eliminating rare earth metal, radiation is reduced, realizes really environmentally protective construction material purpose.Through It crosses in the liquid that filtrate of the detection containing ammonium oxalate is siphoned into catch basin, the content of rare earth reaches 0.685g/L-0.842g/L. Nonmetallic tailings can remove the remaining of the ammonium oxalate in nonmetallic tailings by washing process simultaneously, and water lotion can recycle repetition It is recycled, Extraction of rare earth metal recycling is first carried out when rare earth metal content is high in water lotion, not will cause secondary pollution.
3, when using graphene made from present embodiment and nonmetallic tailings Foam light partition board, because this wallboard produces Product integrate the feature of various functions required for Green energy-saving buildings, and it is small in size, occupy that space is few, own wt Gently, wet work and fragmentary building construction are not needed, it is often more important that do not need using a large amount of sandstone cement.Exterior wall does not need Increase cement mortar batch time screed-coat, does not also need again secondary construction and installation heat insulation layer.Working procedure is simple and convenient, significantly Reduce building wall board construction cost cost.This wallboard product can directly as traditional architecture, assembled architecture inside and outside wall board every The integrated assembling installation that walling material is built can meet building heat preservation heat-insulating decorative integrative installation technology effect；Especially It is to be greatly improved building course using inside and outside wall board product of the invention during assembled architecture builds construction and installation Assembly rate shortens the integral construction duration, largely reduces artificial, saving material, saves construction construction cost, synthesis improves total Body construction safety quality.And application this wall board material building waste can very recycling, really realize Less manpower saves cost, environmentally protective, energy-efficient industrialized building target economic, safety is beautiful.To traditional architecture wall material The revolution of material has sexually revised profound significance, realizes personalized designs, industrialized production, letter to the build model of traditional architecture Breathization management, prefabricated construction reach the target of sustainable development.
Below with reference to embodiment, in the 8th embodiment that the present invention is further explained based on graphene and nonmetallic tailings Foamed wall slab.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to limit this Invention.The chemical component of tailing used in following embodiments is SiO2< 65%, Al2O3> 2%, Fe2O3< 3%, K2O < 5%, Na2O < 5%, CaO < 5%, MgO < 2%, loss on ignition < 10%, rare earth content 1.246g/L-1.784g/L.
Embodiment 1
One, raw material proportioning is shown in Table 6；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature fluxing agent To be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is yttrium oxide and cerium oxide.
Two, it prepares：
Foamed wall slab specific method will be prepared in above-mentioned proportion raw material to include the following steps：
S1, washup：After nonmetallic tailings are smashed it through 1 mesh, smashed nonmetallic tailings are sent into fermentation vat, leaching Steeping pond is cone cylinder, and feeding inlet diameter is the 1/5 of base diameter, is being sent in the high-pressure water pipeline that the inside front of feeding inlet is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 1.5% while entering nonmetallic tailings is drenched by spraying, until spraying The volume of ammonium oxalate solution can stop spraying process after being 1.1 times of nonmetallic tailings volume, 30min be impregnated, in soak period A material is stirred at interval of 5min, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and is taken Filtrate is separated by solid-liquid separation after being washed, and is repeated 2 times the step of washing is separated by solid-liquid separation, and is returned after isolated washing filtrate is merged It repeats next time to use when washup, the solid after washing is dried after the nonmetallic tailings after being washed for use；
S2, raw material add other auxiliary materials mixing dry method to found powder-grinding：First weigh 30% nonmetallic original of weight in good formula Material (in addition to high-temperature fibre) is pre-mixed with other raw materials, and the weight ratio for being pre-mixed raw material is made to account for formula material total weight 30%, after batch mixer mixes, be transferred in raw material roll-over homogenizing into premix, then with remaining 70% nonmetallic tailings Raw material on cross section by uniformly proportion, be put into vertical mill Vertical Mill together, obtain fineness be 300 mesh full by Vertical Mill raw material Powder is transferred to excessive homogenizing bin, is granulated by granulating system, fluidisation, dry, screening obtain granulating raw material, then by high-temperature fibre Raw material and granulating raw material obtain base-material after mixing, are delivered to raw material finished product storage warehouse；Mixing machine incorporation time is 10 minutes, Vertical Mill incorporation time is 10 minutes；
S3, cloth：Base-material is subjected to automatic drying cloth, is put into roller kilns or tunnel oven, through 900 DEG C, 30 minutes After high temperature firing, it is taken out, is made based on graphene and nonmetallic tailings foamed wall slab crude product by kiln cooling；
S4, crude product obtain specification by excision forming and are：It is long：3000mm, width：1200mm, thickness：80mm obtains base In graphene and nonmetallic tailings foamed wall slab finished product.
Embodiment 2
One, raw material proportioning is shown in Table 6；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature fluxing agent To be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is yttrium oxide and cerium oxide.
Two, it prepares：
Foamed wall slab specific method will be prepared in above-mentioned proportion raw material to include the following steps：
S1, washup：After nonmetallic tailings are smashed it through 10 mesh, smashed nonmetallic tailings are sent into fermentation vat, Fermentation vat is cone cylinder, and feeding inlet diameter is the 1/3 of base diameter, is existed in the high-pressure water pipeline that the inside front of feeding inlet is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 5.5% while being sent into nonmetallic tailings is drenched by spraying, until spraying Ammonium oxalate solution volume be 1.32 times of nonmetallic tailings volume after can stop spraying process, impregnate 100min, soaking The bubble phase stirs a material at interval of 5min, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, And be separated by solid-liquid separation after taking filtrate to be washed, it is repeated 3 times the step of washing is separated by solid-liquid separation, after isolated washing filtrate is merged It returns and repeats next time to use when washup, the solid after washing is dried after the nonmetallic tailings after being washed for use；
S2, raw material add other auxiliary materials mixing dry method to found powder-grinding：First weigh 30% nonmetallic original of weight in good formula Material (in addition to high-temperature fibre) is pre-mixed with other raw materials, and the weight ratio for being pre-mixed raw material is made to account for formula material total weight 30%, after batch mixer mixes, be transferred in raw material roll-over homogenizing into premix, then with remaining 70% nonmetallic tailings Raw material on cross section by uniformly proportion, be put into vertical mill Vertical Mill together, obtain fineness be 300 mesh full by Vertical Mill raw material Powder is transferred to excessive homogenizing bin, is granulated by granulating system, fluidisation, dry, screening obtain granulating raw material, then by high-temperature fibre Raw material and granulating raw material obtain base-material after mixing, are delivered to raw material finished product storage warehouse；Mixing machine incorporation time is 300 points Clock, Vertical Mill incorporation time are 600 minutes；
S3, cloth：Base-material is subjected to automatic drying cloth, is put into roller kilns or tunnel oven, through 1300 DEG C, 300 points After clock high temperature firing, it is taken out by kiln cooling, is made and is slightly produced based on graphene with nonmetallic tailings foamed wall slab Product；
S4, crude product obtain specification by excision forming and are：It is long：2800mm, width：1200mm, thickness：100mm obtains base In graphene and nonmetallic tailings foamed wall slab finished product.
Embodiment 3
One, raw material proportioning is shown in Table 6；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature fluxing agent To be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is yttrium oxide and cerium oxide.
Two, it prepares：
Foamed wall slab specific method will be prepared in above-mentioned proportion raw material to include the following steps：
S1, washup：After nonmetallic tailings are smashed it through 5 mesh, smashed nonmetallic tailings are sent into fermentation vat, leaching Steeping pond is cone cylinder, and feeding inlet diameter is the 1/4 of base diameter, is being sent in the high-pressure water pipeline that the inside front of feeding inlet is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 3.5% while entering nonmetallic tailings is drenched by spraying, until spraying The volume of ammonium oxalate solution can stop spraying process after being 1.22 times of nonmetallic tailings volume, 60min be impregnated, in soak period A material is stirred at interval of 5min, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and is taken Filtrate is separated by solid-liquid separation after being washed, and is repeated 3 times the step of washing is separated by solid-liquid separation, and is returned after isolated washing filtrate is merged It repeats next time to use when washup, the solid after washing is dried after the nonmetallic tailings after being washed for use；
S2, raw material add other auxiliary materials mixing dry method to found powder-grinding：First weigh 30% nonmetallic original of weight in good formula Material (in addition to high-temperature fibre) is pre-mixed with other raw materials, and the weight ratio for being pre-mixed raw material is made to account for formula material total weight 30%, after batch mixer mixes, be transferred in raw material roll-over homogenizing into premix, then with remaining 70% nonmetallic tailings Raw material on cross section by uniformly proportion, be put into vertical mill Vertical Mill together, obtain fineness be 300 mesh full by Vertical Mill raw material Powder is transferred to excessive homogenizing bin, is granulated by granulating system, fluidisation, dry, screening obtain granulating raw material, then by high-temperature fibre Raw material and granulating raw material obtain base-material after mixing, are delivered to raw material finished product storage warehouse；Mixing machine incorporation time is 50 minutes, Vertical Mill incorporation time is 100 minutes；
S3, cloth：Base-material is subjected to automatic drying cloth, is put into roller kilns or tunnel oven, through 1000 DEG C, 100 points After clock high temperature firing, it is taken out by kiln cooling, is made and is slightly produced based on graphene with nonmetallic tailings foamed wall slab Product；
S4, crude product obtain specification by excision forming and are：It is long：3000mm, width：1200mm, thickness：120mm obtains base In graphene and nonmetallic tailings foamed wall slab finished product.
Embodiment 4
One, raw material proportioning is shown in Table 6；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature fluxing agent To be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is yttrium oxide and cerium oxide.
Two, it prepares：
S1, washup：After nonmetallic tailings are smashed it through 8 mesh, smashed nonmetallic tailings are sent into fermentation vat, leaching Steeping pond is cone cylinder, and feeding inlet diameter is the 1/3 of base diameter, is being sent in the high-pressure water pipeline that the inside front of feeding inlet is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 4.5% while entering nonmetallic tailings is drenched by spraying, until spraying The volume of ammonium oxalate solution can stop spraying process after being 1.2 times of nonmetallic tailings volume, 90min be impregnated, in soak period A material is stirred at interval of 5min, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and is taken Filtrate is separated by solid-liquid separation after being washed, and is repeated 3 times the step of washing is separated by solid-liquid separation, and is returned after isolated washing filtrate is merged It repeats next time to use when washup, the solid after washing is dried after the nonmetallic tailings after being washed for use；
S2, raw material add other auxiliary materials mixing dry method to found powder-grinding：First weigh 30% nonmetallic original of weight in good formula Material (in addition to high-temperature fibre) is pre-mixed with other raw materials, and the weight ratio for being pre-mixed raw material is made to account for formula material total weight 30%, after batch mixer mixes, be transferred in raw material roll-over homogenizing into premix, then with remaining 70% nonmetallic tailings Raw material on cross section by uniformly proportion, be put into vertical mill Vertical Mill together, obtain fineness be 300 mesh full by Vertical Mill raw material Powder is transferred to excessive homogenizing bin, is granulated by granulating system, fluidisation, dry, screening obtain granulating raw material, then by high-temperature fibre Raw material and granulating raw material obtain base-material after mixing, are delivered to raw material finished product storage warehouse；Mixing machine incorporation time is 200 points Clock, Vertical Mill incorporation time are 400 minutes；
S3, cloth：Base-material is subjected to automatic drying cloth, is put into roller kilns or tunnel oven, through 1200 DEG C, 150 points After clock high temperature firing, it is taken out by kiln cooling, is made and is slightly produced based on graphene with nonmetallic tailings foamed wall slab Product；
S4, crude product obtain specification by excision forming and are：It is long：2400mm, width：1200mm, thickness：600mm obtains base In graphene and nonmetallic tailings foamed wall slab finished product.
Embodiment 5
One, raw material proportioning is shown in Table 6；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature fluxing agent To be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide.
Two, preparation method and embodiment 1 are same.
Embodiment 6
One, raw material proportioning is shown in Table 6；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature fluxing agent To be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide.
Two, preparation method and embodiment 1 are same.
Embodiment 7
One, raw material proportioning is shown in Table 6；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature fluxing agent To be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide.
Wherein, also pass through modification before nonmetallic tailings compounding, the modification is specific as follows：By nonmetallic tail Mine, brown sugar water, strawberry pseudomonad, Colibacter are 200 according to weight ratio:20:0.2:0.3 carries out building heap mixing, then By treated, nonmetallic tailings are crushed, and then carry out then sieving with 100 mesh sieve for grinding 1 minute, then will be non-after sieving Metal tailings carry out bacterial screening, strain is separated with nonmetallic tailings, leave nonmetallic tailings can be obtained be modified it is non- Metal tailings.
It further illustrates, it is 2.01 × 10 that strawberry pseudomonad, Colibacter, which are arranged to effective bacteria containing amount,8- 2.47×108The bacterium solution of a/mL carry out using.
It further illustrates, thallus also passes through activation culture, the activation training before the bacterium solution of the strawberry pseudomonad configures The feeding culture medium prescription that uses cultivated is：Gelatin peptone 16.0g, tryptone 10.0g, extract of soybean 18g, vegetable seed extract 12g、K2SO410.0g、MgCl21.4g, agar 15g, cetrimonium bronmide 0.2g, pH 7.2.
It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution of the Colibacter configures The culture medium prescription used is cultivated in culture：Tryptone 10g/L, extract of soybean 5g/L, vegetable seed extract 3g/L, sodium chloride 10g/L、pH 7.5。
It further illustrates, the content of soybean polyoses reaches 90% or more in extract of soybean；Contain dish in vegetable seed extract The content of seed polysaccharide reaches 95% or more.
Two, preparation method is same as Example 2.Wherein above-mentioned modification is carried out between the step S1 and S2 in preparation method Processing step.
Embodiment 8
One, raw material proportioning is shown in Table 6；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature fluxing agent To be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide.
Wherein, also pass through modification before nonmetallic tailings compounding, the modification is specific as follows：By nonmetallic tail Mine, brown sugar water, Pseudomonas taetrolens, Colibacter are 200 according to weight ratio:20:0.2:0.3 carries out building heap mixing, then By treated, nonmetallic tailings are crushed, and then carry out then sieving with 100 mesh sieve for grinding 3 minutes, then will be non-after sieving Metal tailings carry out bacterial screening, strain is separated with nonmetallic tailings, leave nonmetallic tailings can be obtained be modified it is non- Metal tailings.
It further illustrates, it is 4.51 × 10 that Pseudomonas taetrolens, Colibacter, which are arranged to effective bacteria containing amount,8- 5.99×108The bacterium solution of a/mL carry out using.
It further illustrates, thallus also passes through activation culture, the activation culture training before the bacterium solution of Pseudomonas taetrolens configures Supporting the culture medium prescription used is：Gelatin peptone 16.0g, tryptone 10.0g, extract of soybean 13g, vegetable seed extract 7g, K2SO4 10.0g、MgCl21.4g, agar 15g, cetrimonium bronmide 0.2g, pH 6.9.
It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution of the Colibacter configures The culture medium prescription used is cultivated in culture：Tryptone 10g/L, extract of soybean 8g/L, vegetable seed extract 10g/L, chlorination Sodium 10g/L, pH 7.2.
It further illustrates, the content of soybean polyoses reaches 95% in extract of soybean；It is more containing vegetable seed in vegetable seed extract The content of sugar reaches 96% or more.
Two, preparation method is same as Example 3.Wherein above-mentioned modification is carried out between the step S1 and S2 in preparation method Processing step.
Embodiment 9
One, raw material proportioning is shown in Table 6；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature fluxing agent To be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide；
Wherein, also pass through modification before nonmetallic tailings compounding, the modification is specific as follows：By nonmetallic tail Mine, brown sugar water, Pseudomonas pseudoflava, Colibacter are 200 according to weight ratio:20:0.2:0.3 carries out building heap mixing, then By treated, nonmetallic tailings are crushed, and then carry out then sieving with 100 mesh sieve for grinding 2 minutes, then will be non-after sieving Metal tailings carry out bacterial screening, strain is separated with nonmetallic tailings, leave nonmetallic tailings can be obtained be modified it is non- Metal tailings.
It further illustrates, it is 2.87 × 10 that Pseudomonas pseudoflava, Colibacter, which are arranged to effective bacteria containing amount,8- 3.67×108The bacterium solution of a/mL carry out using.
It further illustrates, thallus also passes through activation culture, the activation culture training before the bacterium solution of Pseudomonas pseudoflava configures Supporting the culture medium prescription used is：Gelatin peptone 16.0g, tryptone 10.0g, extract of soybean 10g, vegetable seed extract 5g, K2SO4 10.0g、MgCl21.4g, agar 15g, cetrimonium bronmide 0.2g, pH 7.3
It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution of the Colibacter configures The culture medium prescription used is cultivated in culture：Tryptone 10g/L, extract of soybean 6g/L, vegetable seed extract 5g/L, sodium chloride 10g/L、pH 7.6。
It further illustrates, the content of soybean polyoses reaches 92% in extract of soybean；It is more containing vegetable seed in vegetable seed extract The content of sugar reaches 98% or more.
Two, preparation method and embodiment 4 are same.It is wherein carried out between the step S1 and S2 in preparation method at above-mentioned modification Manage step.
Embodiment 10
One, raw material proportioning is shown in Table 6；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature fluxing agent To be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide.
Wherein, also pass through modification before nonmetallic tailings compounding, the modification is specific as follows：By nonmetallic tail Mine, brown sugar water, pineapple soft rot pseudomonad, Colibacter are 200 according to weight ratio:20:0.2:0.3 build heap mixed It closes, then by treated, nonmetallic tailings are crushed, and then carry out then sieving with 100 mesh sieve for grinding 3 minutes, then will sieving Nonmetallic tailings afterwards carry out bacterial screening, strain are separated with nonmetallic tailings, leaving nonmetallic tailings can be obtained Modified nonmetallic tailings.
Further illustrate, pineapple soft rot pseudomonad, Colibacter be arranged to effective bacteria containing amount be 3.23 × 108-4.15×108The bacterium solution of a/mL carry out using.
It further illustrates, thallus also passes through activation culture, the activation before the bacterium solution of pineapple soft rot pseudomonad configures The culture medium prescription used is cultivated in culture：Gelatin peptone 16.0g, tryptone 10.0g, extract of soybean 20g, vegetable seed extract 15g、K2SO4 10.0g、MgCl21.4g, agar 15g, cetrimonium bronmide 0.2g, pH 7.1.
It further illustrates, Escherichia coli also pass through activation culture, the activation culture before the bacterium solution of Colibacter configures Cultivating the culture medium prescription used is：Tryptone 10g/L, extract of soybean 7g/L, vegetable seed extract 9g/L, sodium chloride 10g/ L、pH 7.4。
It further illustrates, the content of soybean polyoses reaches 98% in extract of soybean；It is more containing vegetable seed in vegetable seed extract The content of sugar reaches 99% or more.
Two, preparation method is same as Example 3.Wherein above-mentioned modification is carried out between the step S1 and S2 in preparation method Processing step.
Embodiment 11
One, raw material proportioning and embodiment 3 are same；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature Fluxing agent is to be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide.
Two, preparation method is same as Example 3.
Embodiment 12
One, raw material proportioning and embodiment 9 are same；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature Fluxing agent is to be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide.
Two, preparation method is same as Example 4.
Embodiment 13
One, raw material proportioning and embodiment 10 are same；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The height Warm fluxing agent is to be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide.
Two, preparation method and embodiment 3 are same.
Embodiment 14
One, raw material proportioning and embodiment 3 are same；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature Fluxing agent is to be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide.
Two, preparation method is same as Example 4.
Embodiment 15
One, raw material is matched same with embodiment 3；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature helps Flux is to be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide.
Two, preparation method is same as Example 2.
Embodiment 16
One, raw material proportioning and embodiment 9 are same；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature Fluxing agent is to be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is cerium oxide.
Two, preparation method is same as Example 1.
Embodiment 17
One, raw material proportioning and embodiment 9 are same；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature Fluxing agent is to be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is yttrium, cerium oxide.
Two, preparation method is same as Example 1.
Embodiment 18
One, raw material proportioning and embodiment 9 are same；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature Fluxing agent is to be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is yttrium oxide.
Two, preparation method is same as Example 1.
Embodiment 19
One, raw material proportioning and embodiment 9 are same；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature Fluxing agent is to be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is yttrium oxide.
Two, preparation method is same as Example 4.
Embodiment 20
One, raw material proportioning and embodiment 9 are same；The nonmetallic tailings are to be shown in Table 7；The clay is to be shown in Table 8；The high temperature Fluxing agent is to be shown in Table 9；The foaming agent is to be shown in Table 10；The stabilizer is yttrium oxide.
Two, preparation method is same as Example 4.
Ingredient percentage composition (%) list in each embodiment of table 6
Embodiment 1 2 3 4 5 6 7 8 9 10
Nonmetallic tailings 62 75 60 55 55 65 62 51 59 57
Clay 5 3 2 4 10 1 2 9 7 2
Graphene 6 2 5 1 0.05 0.05 1 10 3 12
High temperature cosolvent 6 5 7 1 15 0.05 1 8 3 5
Foaming agent 3 2 3 1 5 0.05 1 4 1 1
Zirconium oxide 2 1 1 2 1.95 15.75 20 5 10 5
Stabilizer 3 2 2 1 5 0.05 1 2 1 2
Degumming agent 2 3 2 1 1 0.05 1 1 2 3
High-temperature fibre 10 5 8 20 6 16 6 6 9 10
Vermiculite 1 2 10 15 1 2 5 4 5 3
Nonmetallic tailings selective listing in each embodiment of table 7
Clay selective listing in each embodiment of table 8
Embodiment Yellow mud Red soil Manganese mud Kaolin
1 √ -- -- --
2 -- √ -- --
3 -- -- √ --
4 -- -- -- √
5 √ √ √ --
6 √ √ -- √
7 √ -- √ √
8 -- √ √ √
9 -- √ √ --
10 -- -- √ √
11 √ √ -- --
12 √ -- -- √
13 -- √ -- √
14 √ -- √ --
15 √ √ √ √
16 √ √ √ √
17 √ √ √ √
18 √ √ -- --
19 -- -- √ √
20 -- -- √ √
The each embodiment high temperature cosolvent selective listing of table 9
Foaming agent selective listing in each embodiment of table 10
Embodiment Expanded graphite Silicon carbide Carbon dust Expanded perlite
1 √ -- -- --
2 -- √ -- --
3 -- -- √ --
4 √ √ √ √
5 √ √ -- --
6 √ -- √ --
7 √ √ -- --
8 √ -- -- √
9 √ -- √ --
10 √ √ -- --
11 -- √ -- √
12 -- √ √ --
13 -- √ -- √
14 √ √ √ --
15 √ -- √ √
16 -- √ √ √
17 √ -- √ √
18 √ √ √ --
19 -- -- √ √
20 √ -- -- √
Testing inspection：
By embodiment 1-20 is prepared in present embodiment foamed wall slab, the comparative example (foaming of market purchase Lightweight wall plate) by the test of physical and mechanical properties, specific method is referring to first embodiment, and test result is referring to following table.
By upper table data it is found that the formula composition of present embodiment combined with proportion after obtained bubble lightweight wall plate through surveying Examination is distinguished little in combustion rating；The lightweight wall plate of present embodiment is 170-750kg/m in bulk density3, compression strength >=5MPa, flexural strength >=2.5MPa, conduction heat transfer coefficient≤2.0W/m DEG C, A1 grades of combustion rating, oise insulation factor >=35dB, water suction Rate < 0.1% is more excellent than comparative example on physical and mechanical properties.
From embodiment 5,6,2,1,3,4, successively sequence is as the increase of graphene amount is on compression strength, flexural strength It gradually increases, but as the increase thermal coefficient of amount can also improve, however find to add expansion stone in the feed after study Ink can mitigate this phenomenon；Again from the point of view of embodiment 5,6,2,1,15,16 with the increase of graphene amount compression strength, It is gradually increased on flexural strength, but as the increase thermal coefficient of amount can also improve, adds the energy of expanded graphite in the feed Enough mitigate this phenomenon；Therefore in the ratio for carrying out wanting strict control graphene and expanded graphite when raw material configuration, Bu Nengyi Taste pursues the promotion of compression strength, flexural strength, and the problem of have ignored thermal coefficient, thus the application configuration graphene with The ratio of expanded graphite is obtained by countless orthogonal tests, not only can guarantee that compression strength, flexural strength are improved but also can be reduced thermally conductive Coefficient.
It can be seen that being added to expansion stone in the feed in embodiment 6, (7,9,10), (1,4), 5 from embodiment 1-10 Ink, and as the increase of amount is gradually decreased in conduction heat transfer coefficient, it was demonstrated that addition expanded graphite can improve wallboard and prepare The size in aperture is finer and smoother in the process, and the porosity is high, to reduce conduction heat transfer coefficient；Embodiment 6, (7,9,10), (1, 4), embodiment 7,9,10 has more excellent performance on conduction heat transfer coefficient in 5, it was demonstrated that modified tailing is carrying out The size that there can be finer and smoother aperture of the process of fermentation is compounded, the porosity is higher, because after removing metal ion, the member of tailing Element is purer, until aperture is finer and smoother during foaming, the radionuclide limitation in embodiment 1-20 meets the model of national regulation In enclosing, the radionuclide limitation in the embodiment that compares 7,8,9,10 includes IRa(External Exposure Index) and IRa(external exposure refers to Number) all than embodiment 1-6,11-20 it is small because can be greatly reduced after carrying out washup recovering rare earth metal dilute in tailing Earth metal content, it is well known that, there are many type of radiation metal, and cannot pass through a kind of method can remove, but pass through The modification of the application, moreover it is possible to reduce the content of radiation metal, so that the wallboard radiation being prepared is smaller, be truly realized Environmentally protective effect.And discovery embodiment 7,8,9,10 bulk density, compression strength, flexural strength, conduction heat transfer coefficient, Combustion rating, oise insulation factor, water absorption rate are compared with superior numerical value, and nonmetallic tailings are before compounding also by modification Reason, by the way that some metallic elements can be removed after there is the microorganism enrichment for the substance for being enriched with specific certain metals processing, so that Nonmetallic tailings are purer, and the strain during modification adds activation step, has used plant in the culture medium of activation Polysaccharide substitutes conventional carbon source (glucose etc.), and the strain after discovery activation has the metallic element in more excellent absorption tailing Ability；Nonmetallic tailings are enable uniformly to be embedded in macromolecule in later period high-temperature calcination after the additional milled processed by olive oil Between, it forms reticular structure and increases bulk density, reduce water absorption rate.The Chinese Patent Application No. that compares is 201610090524.3 A kind of cement base foamed light composite material of disclosure of the invention and preparation method, the bulk density of the application, compression strength, anti-folding Intensity, conduction heat transfer coefficient, combustion rating, oise insulation factor, water absorption rate are superior to Chinese patent 201610090524.3, give prominence to the key points It is far longer than Chinese patent 201610090524.3 in bulk density.The Chinese Patent Application No. that compares is A kind of bulk density for the light cellular partition board the application for adding loofah fiber of 201610258377.6 disclosure of the invention, resistance to compression Intensity, flexural strength, conduction heat transfer coefficient, combustion rating, oise insulation factor, water absorption rate are superior to Chinese patent 201610258377.6, the equal < 0.1% of the application especially on water absorption rate, and 201610258377.6 water absorption rate of Chinese patent is also It is to reach 21.4%, therefore, using the technical solution of the application, in each physical characteristic and mechanical characteristic compared with the prior art Have greatly improved.
Same as Example 7 in raw material in comparative example 2, difference is：The bacterium solution of viscous pseudomonad configures preceding thallus also By activation culture, extract of soybean, vegetable seed extract are not contained in the culture medium prescription that the activation culture culture uses, is adopted It is replaced with glucose band.Escherichia coli also pass through activation culture, the activation culture culture before the bacterium solution of Colibacter configures Extract of soybean, vegetable seed extract are not contained in the culture medium prescription used, are replaced using glucose band.It was found that embodiment 7 Strain after activation compares comparative example 2 with the metallic element ability in more excellent absorption tailing, so that in raw material Content of beary metal reduces.
In addition it gives the wallboard that embodiment 1 is prepared to coherent detection center to detect, the result and data of detection Such as following table：
As seen from the above table, the wallboard produced using the technical solution of present embodiment meets national architectural engineering matter Measure Supervision Test Center BETC-JN1-2017-00003, national building engineering quality supervision inspection center BETC-JN1-2017- 00004, the standard of national building engineering quality supervision inspection center BETC-JN1-2017-00004.Embodiment 2-20 is by inspection Survey also meets above-mentioned standard and does not just enumerate one by one.
11st embodiment
Eleventh embodiment of the invention provides a kind of steel construction assembled architecture system, structure and first embodiment In steel construction assembled architecture system structure it is roughly the same, the difference is that the material of wallboard, in the present embodiment, Lining 24 and Side fascia 23 are all made of based on graphene and stone material tailing foamed light high temperature resistant wallboard, according to weight percent Meter, including stone material tailing 40%-65%, graphene 0.05%-15%, aluminium oxide 1%-30%, vermiculite 1-15%, calcium carbonate It is 0.05%-10%, high temperature cosolvent 0.05%-15%, high-temperature fibre particle 5%-30%, foaming agent 0.05%-5%, steady Determine agent 0.05%-5%, degumming agent 0.05%-5%, clay 1%-10%, the additional 0%-5% of colorant.
It is preferably based on graphene and stone material tailing foamed light high temperature resistant wallboard, in percentage by weight, including stone Material tailing 44%, graphene 6%, aluminium oxide 10%, vermiculite 10%, calcium carbonate 3%, high temperature cosolvent 4%, high-temperature fibre Grain 10%, foaming agent 3%, stabilizer 4%, degumming agent 4%, clay 2%.
It further illustrates, it is described based on graphene and stone material tailing foamed light high temperature resistant wallboard, it is characterised in that：Institute State high-temperature fibre particle in percentage by weight, including stone material tailing 10%-40%, high-temperature fibre 15%-40%, leech Stone 10-40%, expanded perlite 1%-20%, clay 1%-5%；The high-temperature fibre is by high aluminium profiles ceramic fibre, zirconium shield One or more of fiber, quartz fibre, basalt fiber form high-temperature fibre 35%-80%.
Further illustrate, the stone material tailing refer to granite, feldspar, quartz, sandstone, diabase, shale, griotte, One or more of basalt, limestone, Desert Sand.
It further illustrates, the stone material tailing also passes through modification before compounding, and the modification is specific as follows：It will Stone material tailing, brown sugar water, viscous pseudomonad or raw hole pseudomonas or pseudomonas syncyanea or Pseudomonas taetrolens, Colibacter is 100 according to weight ratio:5:0.1:0.1 carries out building heap mixing, and then by treated, stone material tailing is carried out brokenly It is broken, it then carries out then sieving with 100 mesh sieve for grinding 1-3 minutes, the stone material tailing after sieving is then subjected to bacterial screening, by strain It is separated with stone material tailing, leaving stone material tailing can be obtained modified stone material tailing.
Further explanation, the viscous pseudomonad or raw hole pseudomonas or pseudomonas syncyanea or rancid vacation It is 1.65 × 10 that monad or Colibacter, which are arranged to effective bacteria containing amount,8-6.05×108The bacterium solution of a/mL is made With.
Further explanation, the viscous pseudomonad or raw hole pseudomonas or pseudomonas syncyanea or rancid vacation Thallus also passes through activation culture before the bacterium solution of monad configures, and the culture medium prescription that the activation culture culture uses is：Gelatin Peptone 16.0g, tryptone 10.0g, yam extract 8-15g, Radix Schisandrae Bicolori extract 8-20g, K2SO4 10.0g、MgCl2 1.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 7.1 ± 0.2.
It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution of the Colibacter configures The culture medium prescription used is cultivated in culture：Tryptone 5-18g/L, yam extract 1-8g/L, Radix Schisandrae Bicolori extract 3- 10g/L, sodium chloride 5-20g/L, pH 7.4 ± 0.2.
It further illustrates, the content containing Chinese yam polysaccharide reaches 88% or more in the yam extract；Fructus schisandrae mentions The content in object containing fructus schisandrae polysaccharide is taken to reach 90% or more.
It further illustrates, the clay includes one or more of yellow mud, red soil, manganese mud, kaolin.
It further illustrates, the fluxing agent includes one or more of calcination of talc, raw talcum, fluorite, diopside.
It further illustrates, the foaming agent is one or more of expanded graphite, silicon carbide, carbon dust, expanded perlite； The stabilizer be yttrium, cerium one of oxide or more than one.
Preparation method based on graphene Yu stone material tailing foamed light high temperature resistant partition plate as described above, preparation method Include the following steps：
S1, washup：After stone material tailing is smashed it through 1-10 mesh, smashed stone material tailing is sent into fermentation vat, leaching Steeping pond is cone cylinder, and feeding inlet diameter is the 1/5-1/3 of base diameter, in the high-pressure water pipeline that the inside front of feeding inlet is arranged High-pressure fog mass concentration is that the ammonium oxalate solution of 1.5-5.5% is drenched by spraying while being sent into stone material tailing, up to The volume of spraying ammonium oxalate solution can stop spraying process after being 1.1-1.32 times of stone material tailing volume, impregnate 30- 100min stirs a material at interval of 5min in soak period, is then separated by solid-liquid separation, by the filtrate siphon containing ammonium oxalate It into catch basin, and is separated by solid-liquid separation after taking filtrate to be washed, the step of 2-3 washing is separated by solid-liquid separation is repeated, by separation Washing filtrate returns after merging to be repeated to use when washup next time, and the solid after washing is dried to the stone material tail after being washed It is stand-by after mine；
S2, raw material mixing：In addition to high-temperature fibre particle, remaining raw material claims by weight percent shared by each raw material is formulated Material, is milled to 3-18h with ball mill or vertical mill mixing；Reach 250 mesh full by into rotation mixing by screening fineness of grinding Machine mixing homogenizing 10-300 minutes；
S3, the powder after mixing homogenizing is put into savings storehouse into drier by mist projection granulating；
S4, the mixing of high-temperature fibre particulate material：Stone material tailing 10%-40%, high temperature resistant are weighed according to weight percent Fiber 15%-40%, vermiculite 10-40%, expanded perlite 1%-20%, clay 1%-5% are ground with ball mill or vertical mill After crushing, fineness reach 50 mesh full by, into rotary blender mixing homogenizing 10-150 minute, obtain high-temperature fibre mix Material is stored into warehouse；
S5, high-temperature fibre mixture is passed through into rotary kiln, through 900-1280 DEG C, high-temperature fusion calcining is 30-300 minutes high It is taken out after temperature firing is cooling, obtains high-temperature fibre particle；
S6, partial size after high-temperature fibre pellet through sieves, will be taken for the high-temperature fibre particle and the first base granule of 1-6mm It is sufficiently mixed to obtain and is granulated mixture, stored into warehouse；
S7, cloth firing：Granulation mixture in S6 is subjected to cloth, is put into tunnel oven or roller kilns, through 900- It 1300 DEG C, after 30-300 minutes high temperature firings, is taken out by kiln cooling, is made and is foamed based on graphene and stone material tailing Lightening fire resistant partition plate crude product；
S8, by crude product through excision forming, obtain based on graphene and stone material tailing foamed light high temperature resistant partition plate Finished product.
It further illustrates, in S7, the time of soak firing is 100-150 minutes.
It further illustrates, in S8, is based on graphene and stone material tailing foamed light high temperature resistant partition plate product specification： It is long：2400-3000mm, width：600-1200mm, thickness：80-500mm.
It further illustrates, in S6, after high-temperature fibre pellet through sieves, taking partial size is the high-temperature fibre of 1-6mm Grain, concrete operations, which are fiber grains, which first crosses a matched mesh for high-temperature fibre particle, can cross maximum particle diameter (6mm) High-temperature fibre particle, but also have the high-temperature fibre that many high-temperature fibre particles less than 6mm are especially less than 1mm Particle will affect the snap-resistent ability of wallboard in this way, so also to carry out second crosses mesh, select a matched mesh The high-temperature fibre particle of maximum particle diameter (1mm) cannot be crossed, the high-temperature fibre of 1-6mm can be obtained in the partial size then taken Grain.
Since wallboard uses above-mentioned technical proposal, have the advantages that：
1, graphene is a kind of two dimensional crystal, is arranged by carbon atom according to hexagon, is connected with each other, forms a carbon Molecule, structure are highly stable；As the amount of carbon atom connected is increasing, this two-dimensional carbon molecules plane constantly expands Greatly, molecule also constantly becomes larger.The thickness of only one carbon atom of single-layer graphene, i.e., 0.335 nanometer are equivalent to a hair The thickness of 20 a ten thousandths nearly has 1,500,000 layers or so of graphene in the graphite of 1 millimeters thick.Graphene is known most thin A kind of two-dimensional material, and have many advantages, such as high specific surface area and intensity.Each raw material phase in formula in the present invention Mutually auxiliary plays the effect of anti-aging, anticorrosive energy, heat-insulation and heat-preservation, sound insulation, water proof anti-seepage, fireproof, high-strength light, special It is not to have breakthrough discovery on fire endurance, fire endurance can achieve 180min or more.Stone material tailings various first are Substrate, and graphene is added, improve the hardness, high temperature resistant and flame retardant property of wallboard；It overcomes organic material and is afraid of open fire, easy to aging The deadly defect of deformation, improves the fire protecting performance of inorganic material, and compensates for the defect of inorganic material poor compatibility；Hua Gang The stone materials tailing such as rock, shale, hardness, fire prevention and higher compressive property with higher, to assign wallboard stabilization, high temperature resistant With fire prevention etc. performances.Meanwhile substrate is done using various stone material tailings, be conducive to ecological environmental protection, effectively improve resource comprehensive Using, largely save production cost；When the high-temperature fibre particle of addition independent research is able to extend resistant to high temperature in the feed Between, in the identical situation of raw material, it is added to the high-temperature fibre particle of independent research, compares, is added to independent research High-temperature fibre particle numerically extends 30-60 minutes in the fire endurance of script, by using expanded graphite as foaming agent, And combined with foam stabilizer, realize the hole knot formed it into the integrally-built Effective Regulation of wallboard during pore structure and foaming Structure partial size is fine and smooth, is evenly distributed, and wallboard shape is regular, orderly aligned, so that wallboard has cross-linked structure, mentions to reach The purpose of high wallboard strength and toughness；Graphene is added in additional stone material tailing and expanded graphite passes through chemical oxygen in the high temperature environment Change method changes the property of stone material tailing outer surface, it is easier to other substance association reactions, and in foaming process and other objects Matter raw material combines rapidly, expands the foaming aperture size of stone material tailing, but foaming aperture size can not be excessive, causes to prepare Face is uneven outside wallboard out, therefore zirconium oxide is added while adding graphene, expanded graphite, calcium carbonate, glues Gap after soil progress ball milling during hot environment changes stone material tailing and reduces foaming between stone material tailing, and stone material can be changed The composition of microelement in tailing, improves the inoxidizability of stone material tailing itself, and the degree for controlling foaming will also add stabilization Agent guarantees that the stability in reaction between each ion makes face outside foamed wall slab relatively flat, and reduction is further cut Six plate thicknesses that finished product is made are cut, the high temperature cosolvent of addition can be rapidly performed by reaction in hot stage, foam The gap that period is formed is fine and smooth uniformly, and each raw material carries out grinding and reaches 250 mesh full by then homogenizing is granulated, intermolecular Active force strengthens, and under high temperature environment, although intermolecular be interrupted, the stronger particle of molecular force of homogenizing still has Mutual power, raw material each in this way can uniformly fill the wallboard so that making on a large scale during reacting, in plane of structure, vertical face It is all uniform smooth, it is not in the phenomenon of large-area concave-convex injustice, it will not be intermolecular complete as common raw material is under high temperature action It is fully separating, arbitrarily flow, so that the substance disunity of each of entire product place filling, when carrying out detection data, Thermal coefficient, bulk density are, compression strength, flexural strength have biggish difference；The present invention be prepared based on graphene After tested with stone material tailing foamed light high temperature resistant partition plate, bulk density 100-800kg/m3, compression strength >=5MPa, Flexural strength >=2.5MPa, conduction heat transfer coefficient≤2.0W/m DEG C, A1 grades of combustion rating, oise insulation factor >=35dB, water absorption rate < 0.1%, fire endurance >=2h, radionuclide limitation (interior photograph, outer photograph)≤1.0；With more excellent anticorrosive, anti-ageing The advantages that change, insulation, sound insulation, fire prevention, waterproof, impervious, antidetonation, cracking resistance, high-strength light, green safe environmental protection.
2, the method for the preparation in present embodiment also carries out ammonium oxalate washing step for stone material tailing, can recycle Using such as scandium of the rare earth metal in stone material tailing (Sc), yttrium (Y), lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), Samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu) etc., so that Stone material tailing is eliminating rare earth metal, reduces radiation, realizes really environmentally protective construction material purpose.Contain after testing There is the filtrate of ammonium oxalate to be siphoned into the liquid in catch basin, the content of rare earth reaches 0.598g/L-0.785g/L.Stone material simultaneously Tailing can remove the remaining of the ammonium oxalate in stone material tailing by washing process, and water lotion can recycle repetitive cycling use, when Extraction of rare earth metal is first carried out when rare earth metal content is high in water lotion, is recycled, not will cause secondary pollution.
3, using direct based on graphene and stone material tailing foamed light high temperature resistant partition plate made from present embodiment Building partition plate is made, increases that its lightweight intensity is high, pressure-proof and snap-resistent intensity is high, has that significant anti-aging weatherability is strong, thermal insulation separation Hot sound-proofing is good, fire prevention, resistance to 1000 DEG C of high temperature, water proof anti-seepage are excellent, anticorrosive anti-mildew etc..Applying graphite produced by the present invention When alkene and stone material tailing Foam light partition board, product of the present invention collects various functions required for green safe energy saving building in one The characteristics of body, especially solves to build to fire-fighting fire-proof, fire endurance and the building materials limit gauge quality requirement for passing thermal coefficient, With revolutionary strategic structural, it is ensured that building is to safety and energy-efficient effective guarantee.The present invention has small in size, occupancy building Space is few, own wt is light, does not need wet work and fragmentary building construction, it is often more important that does not need using a large amount of sandstone Cement.Exterior wall does not need to increase cement mortar batch time screed-coat, does not need again secondary construction and installation heat insulation layer yet.Construction work Sequence is simple and convenient, greatly reduces building wall board construction cost cost.This wallboard product can be directly as traditional architecture, assembled The integrated assembling installation that Discussion on architecture wallboard partition material is built can meet building heat preservation heat-insulating decorative integration Installation effect；It, can be significantly using inside and outside wall board product of the invention especially during assembled architecture builds construction and installation The assembly rate for improving building course, shortens the integral construction duration, largely reduces artificial, saving material, saving is built into This, synthesis improves overall construction safety quality.And the building waste of this wall board material of application can be very recycled back to It receives and utilizes, really realize that less manpower saves cost, environmentally protective, energy-efficient industrialized building target economic, safety is beautiful.It is right The revolution of traditional architecture materials for wall has sexually revised profound significance, realizes that personalization is set to the build model of traditional architecture Meter, industrialized production, information system management, prefabricated construction reach the target of sustainable development.
Below with reference to embodiment, being sent out based on graphene and stone material tailing in the 9th embodiment that the present invention is further explained Steep lightening fire resistant wallboard.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to limit The fixed present invention.The chemical component of stone material tailing used in following embodiments is SiO2< 65%, Al2O3> 8%, Fe2O3< 11%, K2O < 5%, Na2O < 5%, CaO < 5%, MgO < 2%, loss on ignition < 18%, rare earth content 1.246g/L-1.784g/L.
Embodiment 1
One, raw material proportioning is shown in Table 11；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The high temperature is fluxing Agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is yttrium oxide and cerium oxide.
Two, it prepares：
Foamed wall slab specific method will be prepared in above-mentioned proportion raw material to include the following steps：
S1, washup：After stone material tailing is smashed it through 1 mesh, smashed stone material tailing is sent into fermentation vat, fermentation vat To bore cylinder, feeding inlet diameter is the 1/5 of base diameter, is being sent into stone in the high-pressure water pipeline that the inside front of feeding inlet is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 1.5% while material tailing is drenched by spraying, until spraying ammonium oxalate The volume of solution can stop spraying process after being 1.1 times of stone material tailing volume, impregnate 30min, soak period at interval of 5min stirs a material, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and takes filtrate It is separated by solid-liquid separation after being washed, is repeated 2 times the step of washing is separated by solid-liquid separation, weight next time is returned after isolated washing filtrate is merged It is used when after backwashing mine, the solid after washing is dried after the stone material tailing after being washed for use；
S2, raw material mixing：In addition to high-temperature fibre particle, remaining raw material claims by weight percent shared by each raw material is formulated Material, is milled to 3h with ball mill or vertical mill mixing；Reach 250 mesh full by into rotary blender by screening fineness of grinding Mixing homogenizing 10 minutes；
S3, the powder after mixing homogenizing is obtained into the first base granule by being granulated, into drier, is put into savings Storehouse；
S4, the mixing of high-temperature fibre particulate material：Stone material tailing 10%, high-temperature fibre are weighed according to weight percent 40% (high-temperature fibre is made of high aluminium profiles ceramic fibre, zirconium shield fiber, quartz fibre, basalt fiber), vermiculite 40%, expansion Perlite 5%, clay 5%, after being ground with ball mill or vertical mill, fineness reaches 50 mesh full by into rotation mixing Machine mixing homogenizing 10 minutes, high-temperature fibre mixture is obtained, is stored into warehouse；
S5, high-temperature fibre mixture is passed through into rotary kiln, through 900 DEG C, it is cold that high-temperature fusion calcines 30 minutes high temperature firings But it takes out afterwards, obtains high-temperature fibre particle；
S6, partial size after high-temperature fibre pellet through sieves, will be taken to fill for the high-temperature fibre particle of 1mm with the first base granule Divide and be mixed to get granulation mixture, is stored into warehouse；
S7, cloth firing：Granulation mixture in S6 is subjected to cloth, is put into tunnel oven or roller kilns, through 900 DEG C, After 30 minutes high temperature firings, it is taken out, is made based on graphene and stone material tailing foamed light high temperature resistant by kiln cooling Partition plate crude product；
S8, by crude product through excision forming, obtaining specification is：It is long：3000mm, width：1200mm, thickness：80mm is based on stone Black alkene and stone material tailing foamed light high temperature resistant partition wall board finished product.
Embodiment 2
One, raw material proportioning is shown in Table 11；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The high temperature is fluxing Agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is yttrium oxide and cerium oxide.
Two, it prepares：
Foamed wall slab specific method will be prepared in above-mentioned proportion raw material to include the following steps：
S1, washup：After stone material tailing is smashed it through 10 mesh, smashed stone material tailing is sent into fermentation vat, is impregnated Pond is cone cylinder, and feeding inlet diameter is the 1/3 of base diameter, is being sent into the high-pressure water pipeline that the inside front of feeding inlet is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 5.5% while stone material tailing is drenched by spraying, until spraying oxalic acid The volume of ammonium salt solution can stop spraying process after being 1.32 times of stone material tailing volume, 100min be impregnated, at soak period every A material is stirred every 5min, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and takes filtering Object is separated by solid-liquid separation after being washed, and is repeated 3 times the step of washing is separated by solid-liquid separation, and returns to next time after isolated washing filtrate is merged It repeats to use when washup, the solid after washing is dried after the stone material tailing after being washed for use；
S2, raw material mixing：In addition to high-temperature fibre particle, remaining raw material claims by weight percent shared by each raw material is formulated Material, is milled to 18h with ball mill or vertical mill mixing；Reach 250 mesh full by into rotary blender by screening fineness of grinding Mixing homogenizing 300 minutes；
S3, the powder after mixing homogenizing is obtained into the first base granule by being granulated, into drier, is put into savings Storehouse；
S4, the mixing of high-temperature fibre particulate material：Stone material tailing 40%, high-temperature fibre are weighed according to weight percent 15% (high-temperature fibre is made of high aluminium profiles ceramic fibre, zirconium shield fiber, quartz fibre), vermiculite 20%, expanded perlite 20%, clay 5%, after being ground with ball mill or vertical mill, fineness reaches 50 mesh full by into rotary blender mixing Homogenizing 150 minutes, obtains high-temperature fibre mixture, stores into warehouse；
S5, high-temperature fibre mixture is passed through into rotary kiln, through 1280 DEG C, high-temperature fusion calcines 300 minutes high temperature firings It is taken out after cooling, obtains high-temperature fibre particle；
S6, partial size after high-temperature fibre pellet through sieves, will be taken to fill for the high-temperature fibre particle of 6mm with the first base granule Divide and be mixed to get granulation mixture, is stored into warehouse；
S7, cloth firing：Granulation mixture in S6 is subjected to cloth, is put into tunnel oven or roller kilns, through 1300 DEG C, After 300 minutes high temperature firings, it is taken out, is made based on graphene and stone material tailing foamed light high temperature resistant by kiln cooling Partition plate crude product；
S8, by crude product through excision forming, obtaining specification is：It is long：3000mm, width：1200mm, thickness：100mm is based on stone Black alkene and stone material tailing foamed light high temperature resistant partition wall board finished product.
Embodiment 3
One, raw material proportioning is shown in Table 11；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The high temperature is fluxing Agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is yttrium oxide and cerium oxide.
Two, it prepares：
Foamed wall slab specific method will be prepared in above-mentioned proportion raw material to include the following steps：
S1, washup：After stone material tailing is smashed it through 4 mesh, smashed stone material tailing is sent into fermentation vat, fermentation vat To bore cylinder, feeding inlet diameter is the 1/4 of base diameter, is being sent into stone in the high-pressure water pipeline that the inside front of feeding inlet is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 2.5% while material tailing is drenched by spraying, until spraying ammonium oxalate The volume of solution can stop spraying process after being 1.22 times of stone material tailing volume, impregnate 50min, soak period at interval of 5min stirs a material, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and takes filtrate It is separated by solid-liquid separation after being washed, is repeated 3 times the step of washing is separated by solid-liquid separation, weight next time is returned after isolated washing filtrate is merged It is used when after backwashing mine, the solid after washing is dried after the stone material tailing after being washed for use；
S2, raw material mixing：In addition to high-temperature fibre particle, remaining raw material claims by weight percent shared by each raw material is formulated Material, is milled to 3-18h with ball mill or vertical mill mixing；Reach 250 mesh full by into rotation mixing by screening fineness of grinding Machine mixing homogenizing 100 minutes；
S3, the powder after mixing homogenizing is obtained into the first base granule by being granulated, into drier, is put into savings Storehouse；
S4, the mixing of high-temperature fibre particulate material：Stone material tailing 30%, high-temperature fibre are weighed according to weight percent 35% (high-temperature fibre is made of high aluminium profiles ceramic fibre, basalt fiber), vermiculite 33%, expanded perlite 1%, clay 1%, After being ground with ball mill or vertical mill, fineness reach 50 mesh full by, into rotary blender mixing homogenizing 50 minutes, obtain To high-temperature fibre mixture, stored into warehouse；
S5, high-temperature fibre mixture is passed through into rotary kiln, through 1000 DEG C, high-temperature fusion calcines 100 minutes high temperature firings It is taken out after cooling, obtains high-temperature fibre particle；
S6, partial size after high-temperature fibre pellet through sieves, will be taken to fill for the high-temperature fibre particle of 2mm with the first base granule Divide and be mixed to get granulation mixture, is stored into warehouse；
S7, cloth firing：Granulation mixture in S6 is subjected to cloth, is put into tunnel oven or roller kilns, through 1000 DEG C, After 100 minutes high temperature firings, it is taken out, is made based on graphene and stone material tailing foamed light high temperature resistant by kiln cooling Partition plate crude product；
S8, by crude product through excision forming, obtaining specification is：It is long：3000mm, width：1200mm, thickness：120mm is based on stone Black alkene and stone material tailing foamed light high temperature resistant partition wall board finished product.
Embodiment 4
One, raw material proportioning is shown in Table 11；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The high temperature is fluxing Agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is yttrium oxide and cerium oxide.
Two, it prepares：
S1, washup：After stone material tailing is smashed it through 8 mesh, smashed stone material tailing is sent into fermentation vat, fermentation vat To bore cylinder, feeding inlet diameter is the 1/5 of base diameter, is being sent into stone in the high-pressure water pipeline that the inside front of feeding inlet is arranged The ammonium oxalate solution that high-pressure fog mass concentration is 4.5% while material tailing is drenched by spraying, until spraying ammonium oxalate The volume of solution can stop spraying process after being 1.21 times of stone material tailing volume, impregnate 90min, soak period at interval of 5min stirs a material, is then separated by solid-liquid separation, the filtrate containing ammonium oxalate is siphoned into catch basin, and takes filtrate It is separated by solid-liquid separation after being washed, is repeated 3 times the step of washing is separated by solid-liquid separation, weight next time is returned after isolated washing filtrate is merged It is used when after backwashing mine, the solid after washing is dried after the stone material tailing after being washed for use；
S2, raw material mixing：In addition to high-temperature fibre particle, remaining raw material claims by weight percent shared by each raw material is formulated Material, is milled to 3-18h with ball mill or vertical mill mixing；Reach 250 mesh full by into rotation mixing by screening fineness of grinding Machine mixing homogenizing 200 minutes；
S3, the powder after mixing homogenizing is obtained into the first base granule by being granulated, into drier, is put into savings Storehouse；
S4, the mixing of high-temperature fibre particulate material：Stone material tailing 25%, high-temperature fibre are weighed according to weight percent 25% (high-temperature fibre is made of high aluminium profiles ceramic fibre), vermiculite 32%, expanded perlite 15%, clay 3%, use ball mill Or after vertical mill is ground, fineness reach 50 mesh full by, into rotary blender mixing homogenizing 100 minutes, obtain resistance to height Warm fiber mixture is stored into warehouse；
S5, high-temperature fibre mixture is passed through into rotary kiln, through 1100 DEG C, high-temperature fusion calcines 250 minutes high temperature firings It is taken out after cooling, obtains high-temperature fibre particle；
S6, partial size after high-temperature fibre pellet through sieves, will be taken to fill for the high-temperature fibre particle of 5mm with the first base granule Divide and be mixed to get granulation mixture, is stored into warehouse；
S7, cloth firing：Granulation mixture in S6 is subjected to cloth, is put into tunnel oven or roller kilns, through 1200 DEG C, After 150 minutes high temperature firings, it is taken out, is made based on graphene and stone material tailing foamed light high temperature resistant by kiln cooling Partition plate crude product；
S8, by crude product through excision forming, obtaining specification is：It is long：3000mm, width：1200mm, thickness：240mm is based on stone Black alkene and stone material tailing foamed light high temperature resistant partition wall board finished product.
Embodiment 5
One, raw material proportioning is shown in Table 11；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The high temperature is fluxing Agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide.
Two, preparation method and embodiment 1 are same.
Embodiment 6
One, raw material proportioning is shown in Table 11；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The high temperature is fluxing Agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide.
Two, preparation method and embodiment 1 are same.
Embodiment 7
One, raw material proportioning is shown in Table 11；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The high temperature is fluxing Agent is to be shown in Table 14；The stabilizer is cerium oxide.
Wherein, also pass through modification before stone material tailing compounding, the modification is specific as follows：By stone material tailing, red Syrup, viscous pseudomonad, Colibacter are 100 according to weight ratio:5:0.1:0.1 carries out building heap mixing, after then handling Stone material tailing be crushed, then carry out grinding 1 minute then sieve with 100 mesh sieve, then by after sieving stone material tailing carry out Bacterial screening separates strain with stone material tailing, and leaving stone material tailing can be obtained modified stone material tailing.
It further illustrates, it is 1.65 × 10 that viscous pseudomonad, Colibacter, which are arranged to effective bacteria containing amount,8-2.11 ×108The bacterium solution of a/mL carry out using.
It further illustrates, thallus also passes through activation culture, the activation culture before the bacterium solution of the viscous pseudomonad configures Cultivating the culture medium prescription used is：Gelatin peptone 16.0g, tryptone 10.0g, Chinese yam polysaccharide content reach 88% or more Yam extract 8g, fructus schisandrae polysaccharide content reach 90% or more Radix Schisandrae Bicolori extract 8g, K2SO4 10.0g、 MgCl21.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 7.2.
It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution of the Colibacter configures The culture medium prescription used is cultivated in culture：Tryptone 5g/L, Chinese yam polysaccharide content reach 88% or more Chinese yam extract Object 1g/L, fructus schisandrae polysaccharide content reach 90% or more Radix Schisandrae Bicolori extract 3g/L, sodium chloride 5g/L, pH 7.5.
Two, preparation method is substantially the same manner as Example 2, difference be wherein between the step S1 and S2 in preparation method into The above-mentioned modifying processing step of row.
Embodiment 8
One, raw material proportioning is shown in Table 11；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The high temperature is fluxing Agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide.
Wherein, also pass through modification before stone material tailing compounding, the modification is specific as follows：By stone material tailing, red Syrup, raw hole pseudomonas, Colibacter are 100 according to weight ratio:5:0.1:0.1 carries out building heap mixing, then will place Stone material tailing after reason is crushed, and then carries out then sieving with 100 mesh sieve for grinding 3 minutes, then by the stone material tailing after sieving Bacterial screening is carried out, strain is separated with stone material tailing, leaving stone material tailing can be obtained modified stone material tailing.
It further illustrates, it is 5.14 × 10 that raw hole pseudomonas, Colibacter, which are arranged to effective bacteria containing amount,8- 6.05×108The bacterium solution of a/mL carry out using.
It further illustrates, thallus also passes through activation culture, the activation culture before the bacterium solution of raw hole pseudomonas configures Cultivating the culture medium prescription used is：Gelatin peptone 16.0g, tryptone 10.0g, yam extract 15g, Radix Schisandrae Bicolori extract 20g、K2SO4 10.0g、MgCl21.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 6.9.
It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution of the Colibacter configures The culture medium prescription used is cultivated in culture：Tryptone 18g/L, yam extract 8g/L, Radix Schisandrae Bicolori extract 10g/L, Sodium chloride 20g/L, pH 7.2.
It further illustrates, the content containing Chinese yam polysaccharide reaches 89% in yam extract；Contain in Radix Schisandrae Bicolori extract There is the content of fructus schisandrae polysaccharide to reach 91%.
Two, preparation method is substantially the same manner as Example 3, difference be wherein between the step S1 and S2 in preparation method into The above-mentioned modifying processing step of row.
Embodiment 9
One, raw material proportioning is shown in Table 11；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The high temperature is fluxing Agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide；
Wherein, also pass through modification before stone material tailing compounding, the modification is specific as follows：By stone material tailing, red Syrup, pseudomonas syncyanea, Colibacter are 100 according to weight ratio:5:0.1:0.1 carries out building heap mixing, then will processing Stone material tailing afterwards is crushed, then carry out grinding 2 minutes then sieve with 100 mesh sieve, then by the stone material tailing after sieving into Row bacterial screening separates strain with stone material tailing, and leaving stone material tailing can be obtained modified stone material tailing.
It further illustrates, it is 2.89 × 10 that pseudomonas syncyanea, Colibacter, which are arranged to effective bacteria containing amount,8- 3.13×108The bacterium solution of a/mL carry out using.
It further illustrates, thallus also passes through activation culture, the activation culture training before the bacterium solution of pseudomonas syncyanea configures Supporting the culture medium prescription used is：Gelatin peptone 16.0g, tryptone 10.0g, yam extract 10g, Radix Schisandrae Bicolori extract 12g、K2SO410.0g、MgCl21.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 7.3
It further illustrates, Escherichia coli also pass through activation culture, the activation before the bacterium solution of the Colibacter configures The culture medium prescription used is cultivated in culture：Tryptone 9g/L, yam extract 3g/L, Radix Schisandrae Bicolori extract 6g/L, chlorine Change sodium 8g/L, pH 7.6.
It further illustrates, the content containing Chinese yam polysaccharide reaches 92% in yam extract；Contain in Radix Schisandrae Bicolori extract There is the content of fructus schisandrae polysaccharide to reach 95%.
Two, preparation method is substantially the same manner as Example 4, difference be wherein between the step S1 and S2 in preparation method into The above-mentioned modifying processing step of row.
Embodiment 10
One, raw material proportioning is shown in Table 11；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The high temperature is fluxing Agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide.
Wherein, also pass through modification before stone material tailing compounding, the modification is specific as follows：By stone material tailing, red Syrup, Pseudomonas taetrolens, Colibacter are 100 according to weight ratio:5:0.1:0.1 carries out building heap mixing, then will processing Stone material tailing afterwards is crushed, then carry out grinding 3 minutes then sieve with 100 mesh sieve, then by the stone material tailing after sieving into Row bacterial screening separates strain with stone material tailing, and leaving stone material tailing can be obtained modified stone material tailing.
It further illustrates, it is 3.56 × 10 that Pseudomonas taetrolens, Colibacter, which are arranged to effective bacteria containing amount,8- 4.05×108The bacterium solution of a/mL carry out using.
It further illustrates, thallus also passes through activation culture, the activation culture training before the bacterium solution of Pseudomonas taetrolens configures Supporting the culture medium prescription used is：Gelatin peptone 16.0g, tryptone 10.0g, yam extract 14g, Radix Schisandrae Bicolori extract 18g、K2SO410.0g、MgCl21.4g, agar 15.0g, cetrimonium bronmide 0.2g, pH 7.1.
It further illustrates, Escherichia coli also pass through activation culture, the activation culture before the bacterium solution of Colibacter configures Cultivating the culture medium prescription used is：Tryptone 10g/L, yam extract 7g/L, Radix Schisandrae Bicolori extract 8g/L, sodium chloride 18g/L、pH 7.4。
It further illustrates, the content containing Chinese yam polysaccharide reaches 96% in yam extract；Contain in Radix Schisandrae Bicolori extract There is the content of fructus schisandrae polysaccharide to reach 98%.
Two, preparation method is substantially the same manner as Example 3, difference be wherein between the step S1 and S2 in preparation method into The above-mentioned modifying processing step of row.
Embodiment 11
One, raw material proportioning is same as Example 3；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The height Warm fluxing agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide.
Two, preparation method is same as Example 3.
Embodiment 12
One, raw material proportioning is same as Example 4；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The height Warm fluxing agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide.
Two, preparation method is same as Example 4.
Embodiment 13
One, raw material proportioning and embodiment 3 are same；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The high temperature Fluxing agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide.
Two, preparation method and embodiment 3 are same.
Embodiment 14
One, raw material proportioning is shown in same as Example 4；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；It is described High temperature fluxing agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide.
Two, preparation method is same as Example 4.
Embodiment 15
One, raw material proportioning is same as Example 4；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The height Warm fluxing agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide.
Two, preparation method is same as Example 4.
Embodiment 16
One, raw material proportioning is same as Example 1；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The height Warm fluxing agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is cerium oxide.
Two, preparation method is same as Example 1.
Embodiment 17
One, raw material proportioning is same as Example 1；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The height Warm fluxing agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is yttrium, cerium oxide.
Two, preparation method is same as Example 1.
Embodiment 18
One, raw material proportioning is same as Example 1；The stone material tailing is to be shown in Table 12；The clay is to be shown in Table 13；The height Warm fluxing agent is to be shown in Table 14；The foaming agent is to be shown in Table 15；The stabilizer is yttrium, cerium oxide.
Two, preparation method is same as Example 1.
Ingredient percentage composition (%) list in each embodiment of table 11
Embodiment 1 2 3 4 5 6 7 8 9 10
Stone material tailing 40 45 44 40 65 42 52 65 55 45
Graphene 5 8 6 15 0.05 10 1 3 7 6
Calcium carbonate 3 2 3 5 0.05 8 1 4 7 5
High temperature cosolvent 5 4 4 0.05 3 15 1 2 6 5
Foaming agent 1 1 3 5 0.05 3 1 3 1 1
Aluminium oxide 8 9 10 4.95 10.75 1 30 1 1 10
Stabilizer 2 3 4 2 0.05 5 1 2 1 2
Degumming agent 2 4 4 2 0.05 5 1 2 1 2
Clay 2 3 2 5 10 1 2 2 1 4
Inorganic color 1 0 0 4 5 2 0 1 1 0
High-temperature fibre particle 30 10 10 15 5 6 5 11 14 17
Vermiculite 1 15 10 2 1 2 5 4 5 3
Stone material tailing selective listing in each embodiment of table 12
Clay selective listing in each embodiment of table 13
Embodiment Yellow mud Red soil Manganese mud Kaolin
1 √ -- -- --
2 -- √ -- --
3 -- -- √ --
4 -- -- -- √
5 √ √ √ --
6 √ √ -- √
7 √ -- √ √
8 -- √ √ √
9 -- √ √ --
10 -- -- √ √
11 √ √ -- --
12 √ -- -- √
13 -- √ -- √
14 √ -- √ --
15 √ √ √ √
16 √ √ √ √
17 √ √ -- --
18 -- -- √ √
The each embodiment high temperature cosolvent selective listing of table 14
Foaming agent selective listing in each embodiment of table 15
Embodiment Expanded graphite Silicon carbide Carbon dust Expanded perlite
1 √ -- -- --
2 -- √ -- --
3 -- -- √ --
4 √ √ √ √
5 √ √ -- --
6 √ -- √ --
7 √ √ -- --
8 √ -- -- √
9 √ √ √ --
10 √ -- √ --
11 -- √ -- √
12 -- √ √ --
13 -- √ -- √
14 √ √ √ --
15 √ -- √ √
16 -- √ √ √
17 √ -- √ √
18 -- -- √ √
Testing inspection：
By embodiment 1-18 is prepared in present embodiment foamed wall slab, the comparative example (foaming of market purchase Lightweight wall plate) by the test of physical and mechanical properties, specific method is referring to first embodiment, and test result is referring to following table.
By upper table data it is found that the bubble lightweight wall plate that formula composition obtains after being combined with proportion in present embodiment is through surveying Examination is distinguished little in combustion rating；The lightweight wall plate of the application is 100-800kg/m in bulk density3, compression strength >= 5MPa, flexural strength >=2.5MPa, conduction heat transfer coefficient≤2.0W/m DEG C, A1 grades of combustion rating, oise insulation factor >=35dB, water absorption rate < 0.1% is more excellent than comparative example on physical and mechanical properties.
As the increase of graphene amount gradually increases on compression strength, flexural strength in terms of embodiment 1-6, but with The increase thermal coefficient of amount can also improve, however find to add in the feed after study expanded graphite can to mitigate this existing As；Therefore in the ratio for carrying out wanting strict control graphene and expanded graphite when raw material configuration, pressure resistance cannot be pursued simply The problem of spending, the promotion of flexural strength, and having ignored thermal coefficient, therefore the application is in the ratio of configuration graphene and expanded graphite Example is obtained by countless orthogonal tests, not only can guarantee that compression strength, flexural strength improve but also can reduce thermal coefficient.
It can be seen that adding in the feed in embodiment 5, (1,9,10,16,18), (6,8), (4,12) from embodiment 1-18 Expanded graphite is added, and as the increase of amount is gradually decreased in conduction heat transfer coefficient, it was demonstrated that addition expanded graphite can improve The size in wallboard aperture during the preparation process is finer and smoother, and the porosity is high, to reduce conduction heat transfer coefficient；Embodiment 5, Embodiment 7,8,9,10 has more excellent property on conduction heat transfer coefficient in (1,9,10,16,18), (6,8), (4,11) It can, it was demonstrated that the size that can have finer and smoother aperture of modified stone material tailing in the process for carrying out compounding fermentation, the porosity It is higher, because the element of stone material tailing is purer after removing metal ion, until aperture is finer and smoother during foaming, and find to implement Example 7,8,9,10 is in bulk density, compression strength, flexural strength, conduction heat transfer coefficient, combustion rating, oise insulation factor, water absorption rate Compared to having superior numerical value, stone material tailing also passes through modification before compounding, is enriched with specific certain gold by having Some metallic elements can be removed after the microorganism enrichment processing of the substance of category, so that stone material tailing is purer, and are being changed Property during strain add activation step, used in the culture medium of activation plant polyose to substitute conventional carbon source (glucose etc.), It was found that the strain after activation has the metallic element ability in more excellent absorption stone material tailing；It is additional by white oil grinding at Between so that stone material tailing is uniformly embedded in macromolecule in later period high-temperature calcination after reason, forms reticular structure and increases bulk density, Reduce water absorption rate.A kind of cement base foamed light of disclosure of the invention that the Chinese Patent Application No. that compares is 201610090524.3 Composite material and preparation method, the bulk density of the application, compression strength, flexural strength, conduction heat transfer coefficient, combustion rating, Oise insulation factor, water absorption rate are superior to Chinese patent 201610090524.3, and giving prominence to the key points, it is Chinese special to be far longer than in bulk density Benefit 201610090524.3.A kind of addition sponge gourd of disclosure of the invention that the Chinese Patent Application No. that compares is 201610258377.6 The bulk density of light cellular partition board the application of network fiber, compression strength, flexural strength, conduction heat transfer coefficient, combustion rating, every Volume, water absorption rate are superior to Chinese patent 201610258377.6, the equal < 0.1% of the application especially on water absorption rate, and Chinese 201610258377.6 water absorption rate of patent still reaches 21.4%, therefore, special in each physics using the technical solution of the application Compared with the prior art have greatly improved on property and mechanical characteristic.
In the range of radionuclide limitation in embodiment 1-18 meets national regulation, the embodiment that compares 7,8,9, Radionuclide limitation in 10 includes IRa(External Exposure Index) and IRa(Outreach services) are all than embodiment 1-6,11-18 It is small, because the rare earth metal content in stone material tailing can be greatly reduced after carrying out washup recovering rare earth metal, but many institutes Known, there are many type of radiation metal, and cannot pass through a kind of method can remove, but the modification Jing Guo the application, also The content of radiation metal can be reduced, so that the wallboard radiation being prepared is smaller, has been truly realized environmentally protective effect.
Same as Example 7 in raw material in comparative example 2, difference is：The bacterium solution of viscous pseudomonad configures preceding thallus also By activation culture, in the culture medium prescription that the activation culture culture uses without containing Chinese yam polysaccharide content reach 88% with On yam extract 8g, fructus schisandrae polysaccharide content reach 90% or more Radix Schisandrae Bicolori extract 8g, using glucose Band replacement.Escherichia coli also pass through activation culture, the training that the activation culture culture uses before the bacterium solution of Colibacter configures It supports the content in based formulas without containing Chinese yam polysaccharide and reaches 88% or more yam extract 1g/L, the content of fructus schisandrae polysaccharide The Radix Schisandrae Bicolori extract 3g/L for reaching 90% or more is replaced using glucose band.It was found that the strain phase after the activation of embodiment 7 Comparing comparative example 2 has the more excellent metallic element ability adsorbed in stone material tailing.
In addition it gives the wallboard that the embodiment 1 in present embodiment is prepared to coherent detection center to detect, examine Result and the data such as following table of survey：
As seen from the above table, the wallboard produced using the technical solution of the application meets national construction engineering quality prison Superintend and direct inspection center BETC-JN1-2017-00003, national building engineering quality supervision inspection center BETC-JN1-2017- 00004, the standard of national building engineering quality supervision inspection center BETC-JN1-2017-00004.Embodiment 2-17 is by inspection Survey also meets above-mentioned standard and does not just enumerate one by one.
It is appreciated that steel structure column 7 can also be by being welded and fixed with the prefabricated reinforcing prop 2 of steel construction.
It is appreciated that first connecting portion 11 can also be set as to groove structure, second connecting portion 14 is set as and the groove knot The protrusion that structure is used cooperatively.
It is appreciated that precast beam can also be connect with the prefabricated reinforcing prop 2 of steel construction by prefabricated fixing piece, or using prefabricated Fixing piece is attached with the mode that welding combines.
It is appreciated that between lining 24 and steel construction girder 20 between Side fascia 23 and steel construction girder 20, the two It can be attached, can also be attached using different connection types using identical connection type.
It is appreciated that lining 24 can be omitted according to actual needs.It is appreciated that steel construction assembled architecture system 100 can only include one layer of wallboard and one layer of precast floor slab 17.
It is appreciated that 20 structure of steel construction girder connecting with lining 24 and the steel construction girder connecting with Side fascia 23 20 structures can not be identical or identical, for example, the steel construction girder 20 connecting with lining 24 can use I-beam, outside The steel construction girder 20 that wallboard 23 connects can be the logical beam in side；Or the steel construction girder 20 and and exterior wall being connect with lining 24 The steel construction girder 20 that plate 23 connects is all made of I-beam.
It is appreciated that the quantity for the sub- wallboard 25 that Side fascia 23 and lining 24 include is not limited to above embodiment, it can It is configured according to actual needs.
Above description is the detailed description for the present invention preferably possible embodiments, but embodiment is not limited to this hair Bright patent claim, it is all the present invention suggested by technical spirit under completed same changes or modifications change, should all belong to In the covered the scope of the patents of the present invention.

Claims (6)

1. a kind of steel construction assembled architecture system, it is characterised in that：Including prefabricated foundation, precast construction braced frame, at least If a precast floor slab and drywall panel, the prefabricated foundation includes pedestal and the steel structure column on the pedestal, the structure Braced frame includes the prefabricated reinforcing prop of steel construction and precast beam, and the prefabricated reinforcing prop of steel construction and steel structure column pass through welding And/or the mode of grafting is attached, the peripheral wall of the prefabricated reinforcing prop of steel construction is equipped with several anchoring steel structures；It is described prefabricated Beam includes steel construction girder and plug connector, and the steel construction girder and the prefabricated reinforcing prop of the steel construction are by welding and/or in advance Fixing piece connection processed, the plug connector are connect with the wherein one side of the steel construction girder；The precast floor slab is supported in institute Steel construction girder is stated on the side of the plug connector, and passes through bonding agent and/or prefabricated connection with the steel construction girder Part is attached, and two blocks of adjacent wallboards mutually splice or are bonded, the wallboard adjacent with the prefabricated reinforcing prop of the steel construction It is equipped with bar planting hole, the anchoring steel structure is anchored in the bar planting hole, and the wallboard and the steel construction are prefabricated to be added to connect Qiang Zhu；The wallboard includes several Side fascias and several linings, and several Side fascias surround an accommodation space, with the steel The adjacent Side fascia of the prefabricated reinforcing prop of structure is connect by the anchoring steel structure with the prefabricated reinforcing prop of the steel construction, several described Lining is set in the accommodation space, and adjacent two pieces of linings mutually splice or be bonded to form interior wall, with the steel construction The adjacent lining of prefabricated reinforcing prop is connect by the anchoring steel structure with the prefabricated reinforcing prop of the steel construction；The Side fascia court The side of side and the lining towards the precast beam to the precast beam is equipped with plug division, the plug division and institute Plug connector grafting is stated, and is fixed using bonding agent；Each Side fascia includes two blocks of sub- wallboards, thickness of two blocks of sub- wallboards along wall Direction gluing is together to form a Side fascia；Each precast floor slab and the Side fascia that is positioned above pass through prefabricated component and bonding Agent connection, the Side fascia above the precast floor slab are equipped with fixing groove, and the fixing groove is located at the Side fascia towards institute The side of precast floor slab is stated, the prefabricated component includes arc panel, two pieces of mounting plates and several lock bolts, the arc panel receiving In in the fixing groove, two pieces of mounting plates are respectively facing two opposite directions by the opposite sides of the arc panel and extend to form, Several lock bolts respectively link together two pieces of mounting plates with the precast floor slab, and the precast floor slab is located at that this is prefabricated It is fixed again using bonding agent between Side fascia and the prefabricated component above floor；Along two adjacent sons of thickness of wall body direction arrangement Junction between wallboard is located at the side of the arc panel central axis far from the accommodation space；The Side fascia and described Lining is based on graphene and stone material foamed wall slab, based on graphene and nonmetallic tailings foamed wall slab and base In the one or more of graphene and stone material tailing foamed light high temperature resistant wallboard, wherein described to be sent out based on graphene and stone material Steep lightweight wall plate in percentage by weight, including stone material tailing 45-90%, high temperature cosolvent 0.05-10%, graphene 0.05-15%, expanded graphite 0.05-5%, zirconium oxide 1-20%, calcium carbonate 0.05-10%, clay 1-10%, stabilizer 0.05-5%, degumming agent 0.05-5%, inorganic color 0.05-5%；It is described to be based on graphene and nonmetallic tailings foamed light wall Plate in percentage by weight, including nonmetallic tailings 55-75%, graphene 0.05-15%, vermiculite 1-15%, high temperature hydrotropy Agent 0.05-15%, high-temperature fibre 5-20%, foaming agent 0.05-5%, zirconium oxide 1-20%, clay 1-10%, stabilizer 0.05-5%, degumming agent 0.05-5%；The graphene and stone material tailing foamed light high temperature resistant wallboard of being based on is according to weight hundred Divide than meter, including stone material tailing 40%-65%, graphene 0.05%-15%, aluminium oxide 1%-30%, vermiculite 1-15%, carbonic acid It is calcium 0.05%-10%, high temperature cosolvent 0.05%-15%, high-temperature fibre particle 5-30%, foaming agent 0.05%-5%, steady Determine agent 0.05%-5%, degumming agent 0.05%-5%, clay 1%-10%, the additional 0%-5% of colorant.
2. steel construction assembled architecture system as described in claim 1, it is characterised in that：The steel structure column is backwards to the bottom One end of seat is equipped with first connecting portion, and the prefabricated reinforcing prop of steel construction is equipped with the towards an end face of the prefabricated foundation Two interconnecting pieces, one of the first connecting portion and the second connecting portion are set as protrusion, another to be set as matching with the protrusion The groove structure of conjunction, the protrusion are plugged in the groove structure.
3. steel construction assembled architecture system as described in claim 1, it is characterised in that：The Side fascia is backwards to the receiving The side in space is additionally provided with water-proof precast product, and the water-proof precast product includes the first joint face, the second joint face and third connection Face, first joint face are oppositely arranged with second joint face, the third joint face connect first joint face with Second joint face, and the third joint face divides towards the accommodation space, first joint face and second joint face It is not fixed with adjacent two layers Side fascia by bonding agent, the third joint face passes through with the precast floor slab and the precast beam Bonding agent is fixed.
4. steel construction assembled architecture system as claimed in claim 3, it is characterised in that：First joint face is inclined-plane, The direction that first connection faces away from the accommodation space is gradually tilted to the prefabricated foundation, with first joint face The Side fascia of connection is equipped with the first inclined-plane cooperated with first joint face, first inclined-plane and first joint face It is fixed by bonding agent.
5. steel construction assembled architecture system as claimed in claim 3, it is characterised in that：Second joint face includes support Portion and rake, the support portion is supported on corresponding Side fascia and is fixed with corresponding Side fascia by bonding agent, described Rake is connected to the rake farthest away from the side of the accommodation space, and the rake is towards far from the accommodation space Direction is gradually tilted to the prefabricated foundation, and the Side fascia connecting with second joint face is equipped with to be cooperated with the rake The second inclined-plane, second inclined-plane is fixed with the rake by bonding agent.
6. steel construction assembled architecture system as described in claim 1, it is characterised in that：Window is also provided on the Side fascia Family mounting hole, surrounds on the side wall of the window mounting hole one waterproof boss of projection and recessed installing slot, in the installing slot It is flat logical to fix a stainless steel, the steel construction assembled architecture system further includes window, and the window includes installation outline border, described Installation outline border is connect with the flat logical and described waterproof boss of the stainless steel.
CN201711045432.4A 2017-10-31 2017-10-31 Steel construction assembled architecture system and its assembly method Expired - Fee Related CN107816130B (en)

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