CN107746053A - 一种利用nh3·h2o‑nh4no3溶液制备磁性氧化石墨烯的方法 - Google Patents
一种利用nh3·h2o‑nh4no3溶液制备磁性氧化石墨烯的方法 Download PDFInfo
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- CN107746053A CN107746053A CN201710984385.3A CN201710984385A CN107746053A CN 107746053 A CN107746053 A CN 107746053A CN 201710984385 A CN201710984385 A CN 201710984385A CN 107746053 A CN107746053 A CN 107746053A
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 121
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 108
- 230000005291 magnetic effect Effects 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims abstract description 29
- 239000000243 solution Substances 0.000 claims abstract description 45
- 238000002604 ultrasonography Methods 0.000 claims abstract description 29
- 238000010792 warming Methods 0.000 claims abstract description 27
- 150000002505 iron Chemical class 0.000 claims abstract description 17
- 239000012266 salt solution Substances 0.000 claims abstract description 7
- 229910021577 Iron(II) chloride Inorganic materials 0.000 claims description 16
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 16
- 239000011259 mixed solution Substances 0.000 claims description 12
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 10
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 8
- 229910017343 Fe2 (SO4)3 Inorganic materials 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 40
- 229910002651 NO3 Inorganic materials 0.000 description 33
- 239000000725 suspension Substances 0.000 description 30
- 238000006243 chemical reaction Methods 0.000 description 28
- 229940056319 ferrosoferric oxide Drugs 0.000 description 18
- 239000012286 potassium permanganate Substances 0.000 description 18
- 238000005406 washing Methods 0.000 description 16
- 229910002804 graphite Inorganic materials 0.000 description 14
- 239000010439 graphite Substances 0.000 description 14
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 14
- 238000001816 cooling Methods 0.000 description 10
- 239000005457 ice water Substances 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical class S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 241000446313 Lamella Species 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000011229 interlayer Substances 0.000 description 7
- 235000010344 sodium nitrate Nutrition 0.000 description 7
- 239000004317 sodium nitrate Substances 0.000 description 7
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 235000010333 potassium nitrate Nutrition 0.000 description 3
- 239000004323 potassium nitrate Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000001473 noxious effect Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 206010054949 Metaplasia Diseases 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003302 ferromagnetic material Substances 0.000 description 1
- -1 graphite alkene Chemical class 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000005415 magnetization Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000015689 metaplastic ossification Effects 0.000 description 1
- 239000011806 microball Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000003019 stabilising effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000002525 ultrasonication Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/02—Oxides; Hydroxides
- C01G49/08—Ferroso-ferric oxide [Fe3O4]
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Carbon And Carbon Compounds (AREA)
- Compounds Of Iron (AREA)
Abstract
Description
Claims (10)
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CN201710984385.3A CN107746053B (zh) | 2017-10-20 | 2017-10-20 | 一种利用nh3·h2o-nh4no3溶液制备磁性氧化石墨烯的方法 |
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CN201710984385.3A CN107746053B (zh) | 2017-10-20 | 2017-10-20 | 一种利用nh3·h2o-nh4no3溶液制备磁性氧化石墨烯的方法 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114426676A (zh) * | 2021-12-20 | 2022-05-03 | 南京师范大学 | 一种磁性铁基mof微生物载体材料及其制备方法 |
CN114574238A (zh) * | 2020-12-02 | 2022-06-03 | 中国石油天然气股份有限公司 | 一种磁性氧化石墨烯表面活性剂及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103305185A (zh) * | 2013-06-08 | 2013-09-18 | 西北工业大学 | 还原氧化石墨烯/Fe3O4/Ag纳米复合吸波材料的制备方法 |
CN106475100A (zh) * | 2016-08-30 | 2017-03-08 | 江苏金茂源生物化工有限责任公司 | 石墨烯/四氧化三铁磁性纳米复合材料的制备方法及应用 |
CN107051411A (zh) * | 2016-12-19 | 2017-08-18 | 华南农业大学 | 一种磁性氧化石墨烯制备方法及应用 |
CN107252685A (zh) * | 2017-06-19 | 2017-10-17 | 中南大学 | 一种含羟基胺类化合物功能化磁性氧化石墨烯催化材料及其制备方法和应用 |
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- 2017-10-20 CN CN201710984385.3A patent/CN107746053B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103305185A (zh) * | 2013-06-08 | 2013-09-18 | 西北工业大学 | 还原氧化石墨烯/Fe3O4/Ag纳米复合吸波材料的制备方法 |
CN106475100A (zh) * | 2016-08-30 | 2017-03-08 | 江苏金茂源生物化工有限责任公司 | 石墨烯/四氧化三铁磁性纳米复合材料的制备方法及应用 |
CN107051411A (zh) * | 2016-12-19 | 2017-08-18 | 华南农业大学 | 一种磁性氧化石墨烯制备方法及应用 |
CN107252685A (zh) * | 2017-06-19 | 2017-10-17 | 中南大学 | 一种含羟基胺类化合物功能化磁性氧化石墨烯催化材料及其制备方法和应用 |
Non-Patent Citations (1)
Title |
---|
王洪荣: "《饲料检测与分析实验技术》", 30 June 2014, 东南大学出版社 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114574238A (zh) * | 2020-12-02 | 2022-06-03 | 中国石油天然气股份有限公司 | 一种磁性氧化石墨烯表面活性剂及其制备方法 |
CN114574238B (zh) * | 2020-12-02 | 2023-05-26 | 中国石油天然气股份有限公司 | 一种磁性氧化石墨烯表面活性剂及其制备方法 |
CN114426676A (zh) * | 2021-12-20 | 2022-05-03 | 南京师范大学 | 一种磁性铁基mof微生物载体材料及其制备方法 |
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