CN107739669A - Moist maintenance anti-inflammation and sterilization camellia handmade soap through desensitization process and preparation method thereof - Google Patents

Moist maintenance anti-inflammation and sterilization camellia handmade soap through desensitization process and preparation method thereof Download PDF

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Publication number
CN107739669A
CN107739669A CN201710973002.2A CN201710973002A CN107739669A CN 107739669 A CN107739669 A CN 107739669A CN 201710973002 A CN201710973002 A CN 201710973002A CN 107739669 A CN107739669 A CN 107739669A
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parts
camellia
handmade soap
inflammation
sterilization
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Chinese (zh)
Inventor
黄闺
赖琼玮
陈劲松
成超丽
刘芳
罗秋兰
洪穗
谭传波
杨耀学
林永强
周娟
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Hunan Sanxiang Camellia Oil Agel Ecommerce Ltd
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Hunan Sanxiang Camellia Oil Agel Ecommerce Ltd
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Priority to CN201710973002.2A priority Critical patent/CN107739669A/en
Publication of CN107739669A publication Critical patent/CN107739669A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/02Compositions of detergents based essentially on soap on alkali or ammonium soaps
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06Inorganic compounds
    • C11D9/08Water-soluble compounds
    • C11D9/10Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/38Products in which the composition is not well defined

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Medicines Containing Plant Substances (AREA)
  • Cosmetics (AREA)

Abstract

A kind of moist maintenance anti-inflammation and sterilization camellia handmade soap through desensitization process, it is bound up according to mass fraction by following component:10 30 parts of camellia oil, 10 18 parts of avocado oil, 10 18 parts of coconut oil, 10 18 parts of palm oil, 14 20 parts of deionized water, 8 12 parts of sodium hydroxide, 36 parts of tea seed extract solution, extracts of Chinese herbal medicine 13,0.1 0.3 parts of salt, 0.1 0.5 parts of tea seed powder, 0.1 0.5 parts of essence;Its Chinese medicine extract 90 100 parts of deionized water, is filtered and obtained after heat extracts by 24 parts of centella, 24 parts of the fruit of summer cypress, 23 parts of flos caryophylli.The camellia handmade soap adds the tea seed extract solution that desensitizes completely, after natural Chinese medicinal herb of arranging in pairs or groups, there is anti-inflammation and sterilization to act on, unique cold press camellia oil and centella interaction so that handmade soap of the invention has extraordinary moist maintenance action.

Description

Moist maintenance anti-inflammation and sterilization camellia handmade soap through desensitization process and preparation method thereof
Technical field
It is particularly a kind of to moisten maintenance anti-inflammation and sterilization camellia handmade soap the present invention relates to a kind of camellia handmade soap.
Background technology
Since 2014, handmade soap product is a dark horse washing shield product market, and all kinds of vegetable fat collocation plants carry Thing is taken to apply in handmade soap and more and more common, the hand of a tea seed powder extracts of being arranged in pairs or groups using tea oil as main glyceride stock Work soap, there is the effect such as extraordinary oil-control, anti-acne, anti-inflammatory, as a kind of natural agents, tea seed powder but has anaphylactogen, makes Allergy sufferers pruitus is obtained, plays erythema so that tea seed powder class product can not largely use tea seed powder raw material, so solving tea seed powder Allergen issue, just tea seed powder class product can be enabled preferably to import market.
The content of the invention
An object of the present invention, it is to overcome existing tea seed extract solution allergic problem, there is provided one kind is moistened maintenance anti-inflammatory and killed Bacterium camellia handmade soap.
The second object of the present invention is to provide the preparation method of above-mentioned moist maintenance anti-inflammation and sterilization camellia handmade soap.
The technical scheme is that:
A kind of moist maintenance anti-inflammation and sterilization camellia handmade soap through desensitization process, it is made up according to mass fraction of following raw material: Camellia oil 10-30 parts, avocado oil 10-18 parts, coconut oil 10-18 parts, palm oil 10-18 parts, deionized water 14-20 parts, hydrogen-oxygen Change sodium 8-12 parts, tea seed extract solution 3-6 parts, extracts of Chinese herbal medicine 1-3, salt 0.1-0.3 parts, tea seed powder 0.1-0.5 parts, essence 0.1-0.5 parts.
Preferably, described Chinese medicine extract according to mass fraction by fruit of summer cypress 2-5 parts, centella 2-4 parts, flos caryophylli 2- 3 parts, deionized water 90-100 parts, are heated to 80-90 DEG C, after persistently stirring 1.5-2 hours, are obtained through 200 mesh filter-cloth filterings.
Preferably, described tea seed extract solution technique is specific as follows:
(1)Squeezing:Tea seed is squeezed and obtains camellia seed slag;
(2)Leach:By step(1)Camellia seed slag is obtained by n-hexane extraction, obtains the camellia seed slag that deoils;
(3)Crush:By step(2)The obtained camellia seed ground-slag that deoils is broken, is sieved through 30-100 eye mesh screens, obtains camellia seed powder;
(4)Heat extraction:By step(3)Obtained camellia seed powder and deionized water mixing, mixed proportion 1:(3-10), it is heated to 60 DEG C -100 DEG C, mixing speed is 20-60 revs/min, after stirring 40-60 minutes, adds adsorbent, and adsorbent addition is and tea The weight ratio of seed powder is(1-2):10, heating-up temperature is 60 DEG C -100 DEG C, and mixing time is 20-30 minutes, mixing speed 20- 60 revs/min, sedimentation centrifuge filters to get filtrate;Described adsorbent is activated carbon and atlapulgite, is calculated with part by weight, Activated carbon:Atlapulgite=1:(3-10);
(5)It is refined:By step(4)The filtrate addition filtrate 1%-6% diatomite of acquisition, is filtered by leaf-type filter, obtained clear Clear camellia seed extract solution.
Step(4)Described decolorising agent is activated carbon and atlapulgite, adsorption specific surface area 1000m2/g-1500m2/ g,
The present invention moistens the preparation method of maintenance anti-inflammation and sterilization camellia handmade soap, in turn includes the following steps:
(1)After coconut oil, palm oil are dissolved by heating, add camellia oil and avocado oil stirs;
(2)Sodium hydroxide is dissolved in deionized water, salt is added, after stirring, is slowly added to step(1)Obtained grease In, lasting stirring, saponification is abundant, and material body is in thread;
(3)Then tea seed extract solution, extracts of Chinese herbal medicine, essence and tea seed powder are added, reverse mould after stirring, is gone out after shaping Mould, soap is supported to complete curing, obtains handmade soap.
Primary raw material used in the present invention is described as follows:
Camellia seed:It is the fruit of tea oil tree.Tea oil tree is the main woody oleiferous plants tree in China, is described as " east tree ", belongs to camellia Section's Camellia evergreen dungarunga, it is the distinctive woody vegetable oil resource in China;3-6 meters of the height of tree, the diameter of a cross-section of a tree trunk 1.3 meters above the ground is up to 24-30 lis Rice, smooth bark is taupe.Tea oil tree list leaf alternate, flower are both sexes white, and October, Post flowering was until fruit between October next year Can be ripe, therefore, tea oil tree has rare flowers and fruits homophyletic phenomenon;Fruit is capsule, is mostly ellipse, has fine, soft fur;Seed Mostly yellowish-brown, glossy, triangular shape;Tea oil tree is grown in remote mountains, inhales natural nutrient to the greatest extent, evergreen longevity, the age of tree up to 200 years with On.
Camellia oil:Camellia seed kernel is through cleaning, air-drying(Temperature is less than 100 DEG C), shelling, seed selection sterilization after, at 20-50 DEG C Obtained by being squeezed, active material enriches, generally about containing vitamin E 200mg/Kg, sterol 30mg/Kg, squalene 100mg/Kg。
Avocado oil:Avocado oil is adapted to dry skin, aging or has eczema, psoriasic crowd to use.Because of sunlight or weather Caused by skin injury, such as dehydration or it is malnutritive when use, effect is very good, it also have make skin regeneration and softening skin The function of tissue, avocado oil are easily absorbed by deep tissues, can effectively softening skin tissue, skin moisturization is obvious, Eczema and psoriasic symptom can be alleviated, so being particularly suitable for the use of aging skin.
Coconut oil:Coconut oil is the indispensable glyceride stock of perfumed soap, and produces natural acid, fatty alcohol and surface The raw material of activating agent.It can increase the rich of foam with coconut oil soapmaking, strengthen cleaning effect.
Palm oil:Palm oil is also known as brown oily, brown skin oil, and the grease extracted by pericarp in oil palm fruit, is non-drying oil;In right amount Collocation can increase finished product hardness in the formula of handmade soap, be that handmade soap is more stable, effectively extend the resting period.
Sodium hydroxide:As the alkali reacted with fat saponification.
Deionized water:Refer to eliminate the pure water in after ionic species impurity, International Organization for standardization ISO/TC 147 is advised Fixed " deionization " is defined as:" deionized water is complete or incompletely removes ionic species;" using the method system of RO counter-infiltrations Take, the anion and cation gone using ion exchange resin in water removal.
Centella:Centella has clearing heat and detoxicating, inducing diuresis and reducing edema, nourishing, anti-inflammatory, quelling effect.Deep layer skin can be stimulated Skin cell substitutes, and compact epidermis and corium coupling part, skin can be made to limber up, and helps solve cutis laxa phenomenon, makes skin Skin is smooth flexible, promotes collagen in skin corium to be formed, regenerates fibrin, reconnect is got up, and reaches skin Compact smooth effect;Impaired organization healing and consolidation skin are also assisted in, can be promoted close between epidermis and corium Connection, and can suppress the increase of adipocyte, prevent hydroderma, obesity occur.Centella is applied to various skin quality, its young shoot Water extract there is anti-inflammation, it belongs to dicotyledon Umbelliferae, can subdhing swelling and detoxicating dispel running sore.
Flos caryophylli:Flos caryophylli is conventional Chinese medicine, is one of China's tradition import " southern medicine ", first recorded in《Haigoushen》, it is modern Research shows that cloves contains volatile oil, main oleic acid containing cloves, acetyl cloves oleic acid and cloves alkene, Methylpentanone, methyl in oily The compositions such as positive heptanone, vanillin, have antibacterial and anthelmintic action, as fragrance, antispastic carminative.
The fruit of summer cypress:For the dry mature fruit of the chenopod fruit of summer cypress, there are clearing heat and promoting diuresis, dispelling wind and arresting itching.
Salt:Main component is NaCl, can increase the viscosity of matched somebody with somebody liquid.
Essence:The smell of finished product is adjusted, is allowed to pleasant comfortable.
Embodiment
The preparation method of tea seed extract solution used is as follows in embodiment:
Desensitization process tea seed extract solution, is made up of following processing step:
Tea seed extract solution used in embodiment, it is made up of following processing step:
(1)Squeezing:Tea seed is squeezed and obtains camellia seed slag;
(2)Leach:By step(1)Camellia seed slag is obtained by n-hexane extraction, obtains the camellia seed slag that deoils;
(3)Crush:By step(2)The obtained camellia seed ground-slag that deoils is broken, is sieved through 50 eye mesh screens, obtains camellia seed powder;
(4)Heat extraction:By step(3)Obtained camellia seed powder and deionized water mixing, mixed weight ratio are 1:4, it is heated to 70 DEG C, mixing speed is 50 revs/min, after stirring 50 minutes, adds adsorbent, adsorbent addition is the weight ratio with tea seed powder For 2:10, heating-up temperature is 70 DEG C, and mixing time is 25 minutes, and mixing speed is 40 revs/min, and sedimentation centrifuge, which filters, to be filtered Liquid;Described adsorbent is activated carbon and atlapulgite, and average adsorption specific surface area is respectively 1200m2/ g and 1300m2/ g, with Part by weight calculates, activated carbon:Atlapulgite=1:4 ;
(5)It is refined:By step(4)4% diatomite of the filtrate addition filtrate weight of acquisition, is filtered by leaf-type filter, obtained Clarify camellia seed extract solution.
Above-mentioned tea seed extract solution is subjected to patch test, patch test results are without allergic reaction;Method of testing is as follows:
Experimental procedure:
Step 1:The gauze of four thickness is cut into a diameter of 1cm circle with scissors, totally 8, draws 25uL's respectively with liquid-transfering gun Tea seed extract solution, is dropped on circular gauze, and blank is done with deionized water;
Step 2:The gripping of gauze tweezers is placed on subject(To tea seed extract solution allergy sufferers)At anteflexion arm, adhesive tape is used Fix, start timing;
Step 3:Torn after 48h adhesive tape, and observe the reaction of skin at gauze covering immediately.
Chinese medicine extract:According to mass fraction by 4 parts of the fruit of summer cypress, 4 parts of centella, 2 parts of flos caryophylli, 90 parts of deionized water, 85 DEG C are heated to, after persistently stirring 2 hours, is obtained through 200 mesh filter-cloth filterings.
Embodiment 1
Handmade soap preparation method is as follows:170 grams of coconut oil is taken, 150 grams of palm oil, after heating for dissolving, adds 180 grams of camellia oil, 150 grams of avocado oil, after stirring, weigh 98 grams of sodium hydroxides and be dissolved in 175 grams of deionized waters, add 1.5 grams of salt, stirring After uniformly, it is slowly added in grease, lasting stirring, treats that saponification is abundant, when material body is in thread, adds 44.5 grams of above-mentioned tea seed extractions Liquid and 25 grams of extracts of Chinese herbal medicine, 3 grams of essence and 3 grams of tea seed powder, reverse mould after stirring, depanning after shaping, soap are supported to complete Curing, obtains handmade soap.
Embodiment 2-5
Embodiment 2-5 handmade soap, its preparation process condition is substantially with embodiment 1, the simply bar such as reaction raw materials and proportion scale Part is slightly different, specifically as listed in table 1.
The embodiment 1-5 of table 1, comparative example 1-2 moist maintenance anti-inflammation and sterilization camellia handmade soap preparation method
Comparative example 3
Comparative example 3 eliminates centella on the basis of embodiment 1, and flos caryophylli dosage is 6 parts, other same as Example 1.
Comparative example 4
Comparative example 4 eliminates the fruit of summer cypress on the basis of embodiment 1, and flos caryophylli dosage is 6 parts, other same as Example 1.
Comparative example 5
Comparative example 5 eliminates flos caryophylli on the basis of embodiment 1, and centella dosage is 6 parts, other same as Example 1.
Comparative example 6
Comparative example 6 is only in that tea seed extraction liquid and preparation method thereof is different from the difference of embodiment 1.
Tea seed extract solution used in comparative example 6, is made up of following processing step:
(1)Squeezing:Tea seed is squeezed and obtains camellia seed slag;
(2)Leach:By step(1)Camellia seed slag is obtained by n-hexane extraction, obtains the camellia seed slag that deoils;
(3)Crush:By step(2)The obtained camellia seed ground-slag that deoils is broken, is sieved through the eye mesh screen of 30 mesh -100, obtains camellia seed Powder;
(4)Heat extraction:By step(3)Obtained camellia seed powder and deionized water mixing, mixed proportion 1:4,70 DEG C are heated to, is stirred Speed is mixed as 50 revs/min, after stirring 50 minutes, adds adsorbent, adsorbent addition is 2 for the weight ratio with tea seed powder: 10, heating-up temperature is 70 DEG C, and mixing time is 25 minutes, and mixing speed is 40 revs/min, and sedimentation centrifuge filters to get filtrate; For described adsorbent only with activated carbon, dosage is identical with total dosage of activated carbon in embodiment 1 and atlapulgite;
(5)It is refined:By step(4)4% diatomite of the filtrate addition filtrate weight of acquisition, is filtered by leaf-type filter, obtained Clarify camellia seed extract solution.
After handmade soap obtained by embodiment 1-5, comparative example 1-6 is stood into 48 hours, depanning, it is placed at shady and cool ventilation, Its pH value is tested every a couple of days, when pH is reduced to below 10.5, tests and moistens moisturizing, antipruritic reparation;Specifically see table 2.
Its functional attributes test result of handmade soap obtained by the embodiment 1-5 of table 2, comparative example 1-6
Its functional attributes of handmade soap obtained by embodiment 1-5, comparative example 1-6 and the test side used in physical and chemical index test Method has:
(1)The method of testing for moistening performance of keeping humidity is tested for hand skin, and specific method is as follows:
By the moist maintenance anti-inflammation and sterilization camellia handmade soap obtained by embodiment 1-5, comparative example 1-6, got blisters with the net of getting blisters drenched, When foam fully it is abundant can not be further added by when, observe depth of foam, then rinse hand with clear water, record is rinsed to clean Time, untill not glutinous soapy feeling, with clean towel water purification beads, hand is detected with digital skin moisture detector after half an hour Back moisture value(Note:The back of the hand portion moisture value is detected before being washed one's hands using handmade soap, and is recorded), statistical result such as table 3.
The embodiment 1-5 of table 3, comparative example 1-6 camellia handmade soap trial effect mean scores tables
From table 3, it can be seen that the addition of the consistent lubricant such as the moisture retention of handmade soap and tea oil is related, adds the soap after consistent lubricant and protects It is moist better than what is do not added.
Embodiment 1-5, comparative example 1-6 moist maintenance anti-inflammation and sterilization camellia craft saponaria vaccaria anti-acne effect method of testing such as Under:
Embodiment 1-5, comparative example 1-6 moist maintenance anti-inflammation and sterilization camellia handmade soap are chosen into 10 examinations for having whelk respectively User, try out two months, count rehabilitation situation quantity, statistical conditions such as table 4.
The camellia craft saponaria vaccaria anti-acne effect quantity statistics table of table 4
From table 5, it can be seen that camellia oil, tea seed extract and the recovery after Chinese herbal medicine collocation to slight dermatitis patients have very Obvious effect, addition is bigger, and effect is better, and effect is more preferable after extracts of Chinese herbal medicine of arranging in pairs or groups.

Claims (6)

1. the moist maintenance anti-inflammation and sterilization camellia handmade soap through desensitization process, it is according to mass fraction by following raw material system:Camellia Oily 10-30 parts, avocado oil 10-18 parts, coconut oil 10-18 parts, palm oil 10-18 parts, deionized water 14-20 parts, sodium hydroxide 8-12 parts, tea seed extract solution 3-6 parts, extracts of Chinese herbal medicine 1-3, salt 0.1-0.3 parts, tea seed powder 0.1-0.5 parts, essence 0.1- 0.5 part.
2. a kind of moist maintenance anti-inflammation and sterilization camellia handmade soap through desensitization process according to claim 1, its feature exist In the medicament extracting solution by centella 2-4 parts, fruit of summer cypress 2-5 parts, flos caryophylli 2-3 parts, deionized water 90-100 parts, after heat extracts Filter and obtain.
3. a kind of moist maintenance anti-inflammation and sterilization camellia handmade soap through desensitization process according to claim 1, its feature exist In:Described raw material tea seed extract solution technique is specific as follows:
(1)Squeezing:Tea seed is squeezed and obtains camellia seed slag;
(2)Leach:By step(1)Camellia seed slag is obtained by n-hexane extraction, obtains the camellia seed slag that deoils;
(3)Crush:By step(2)The obtained camellia seed ground-slag that deoils is broken, is sieved through 30-100 eye mesh screens, obtains camellia seed powder;
(4)Heat extraction:By step(3)Obtained camellia seed powder and deionized water mixing, mixed proportion 1:(3-10), it is heated to 60-100 DEG C, mixing speed is 20-60 revs/min, after stirring 40-60 minutes, adds adsorbent, adsorbent addition is and tea The weight ratio of seed powder is(1-2):10, heating-up temperature is 60-100 DEG C, and mixing time is 20-30 minutes, mixing speed 20-60 Rev/min, sedimentation centrifuge filters to get filtrate;
(5)It is refined:By step(4)The 1-6% diatomite of the filtrate addition filtrate weight of acquisition, is filtered by leaf-type filter, obtained Obtain tea seed extract solution.
4. a kind of moist maintenance anti-inflammation and sterilization camellia handmade soap through desensitization process according to claim 3, its feature exist In:Step(4)Adsorbent is activated carbon and atlapulgite, is calculated with part by weight, activated carbon:Atlapulgite=1:(3-10).
5. a kind of moist maintenance anti-inflammation and sterilization camellia handmade soap through desensitization process according to claim 3, its feature exist In:Described bleaching agent activated carbon and atlapulgite, adsorption specific surface area 1000-1500m2/g。
6. a kind of preparation method of the moist maintenance anti-inflammation and sterilization camellia handmade soap through desensitization process according to claim 1, It is characterized by orderly comprising following steps:
(1)After coconut oil, palm oil are dissolved by heating, add camellia oil and avocado oil stirs;
(2)Sodium hydroxide is dissolved in deionized water, salt is added, after stirring, is slowly added to step(1)Obtained grease In, lasting stirring, saponification is abundant, and material body is in thread;
(3)Then tea seed extract solution, extracts of Chinese herbal medicine, essence and tea seed powder are added, reverse mould after stirring, is gone out after shaping Mould, soap is supported to complete curing, obtains handmade soap.
CN201710973002.2A 2017-10-18 2017-10-18 Moist maintenance anti-inflammation and sterilization camellia handmade soap through desensitization process and preparation method thereof Pending CN107739669A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110003999A (en) * 2019-03-25 2019-07-12 苏州优养健康科技有限公司 A kind of camellia seed cleaning powder and its preparation process

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1286297A (en) * 1999-09-28 2001-03-07 李玉海 Chinese-medicinal composite soap and its preparing process
KR20080090660A (en) * 2007-04-05 2008-10-09 농업회사법인(주)맛가마식품 Soap with fermented soybean and process of the same
CN102517174A (en) * 2011-11-27 2012-06-27 郴州邦尔泰苏仙油脂有限公司 Camellia facial soap
CN104974866A (en) * 2015-07-20 2015-10-14 永安市泽恩医疗器械有限公司 Tea seed essence soap and preparation method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1286297A (en) * 1999-09-28 2001-03-07 李玉海 Chinese-medicinal composite soap and its preparing process
KR20080090660A (en) * 2007-04-05 2008-10-09 농업회사법인(주)맛가마식품 Soap with fermented soybean and process of the same
CN102517174A (en) * 2011-11-27 2012-06-27 郴州邦尔泰苏仙油脂有限公司 Camellia facial soap
CN104974866A (en) * 2015-07-20 2015-10-14 永安市泽恩医疗器械有限公司 Tea seed essence soap and preparation method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110003999A (en) * 2019-03-25 2019-07-12 苏州优养健康科技有限公司 A kind of camellia seed cleaning powder and its preparation process
CN110003999B (en) * 2019-03-25 2021-11-05 苏州优养健康科技有限公司 Camellia seed cleaning powder and preparation process thereof

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