CN107699934A - 一种超大长径比细钛管内表面二氧化钛纳米管阵列的动态制备方法 - Google Patents
一种超大长径比细钛管内表面二氧化钛纳米管阵列的动态制备方法 Download PDFInfo
- Publication number
- CN107699934A CN107699934A CN201610647491.8A CN201610647491A CN107699934A CN 107699934 A CN107699934 A CN 107699934A CN 201610647491 A CN201610647491 A CN 201610647491A CN 107699934 A CN107699934 A CN 107699934A
- Authority
- CN
- China
- Prior art keywords
- titanium tube
- dynamic
- titanium
- electrolyte
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 81
- 239000010936 titanium Substances 0.000 title claims abstract description 81
- 229910052719 titanium Inorganic materials 0.000 title claims abstract description 81
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 239000002071 nanotube Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- 239000004408 titanium dioxide Substances 0.000 title claims abstract description 13
- 239000003792 electrolyte Substances 0.000 claims abstract description 31
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 25
- 230000003647 oxidation Effects 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000008367 deionised water Substances 0.000 claims description 15
- 229910021641 deionized water Inorganic materials 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 14
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 239000002699 waste material Substances 0.000 claims description 7
- 239000003599 detergent Substances 0.000 claims description 5
- 239000003643 water by type Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims 2
- 239000004810 polytetrafluoroethylene Substances 0.000 claims 2
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 1
- -1 Polytetrafluoroethylene Polymers 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims 1
- 229910001220 stainless steel Inorganic materials 0.000 claims 1
- 238000002604 ultrasonography Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 7
- 230000001276 controlling effect Effects 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 230000001105 regulatory effect Effects 0.000 abstract description 2
- 230000002269 spontaneous effect Effects 0.000 abstract description 2
- 238000001816 cooling Methods 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 230000005518 electrochemistry Effects 0.000 description 4
- LDDQLRUQCUTJBB-UHFFFAOYSA-N ammonium fluoride Chemical class [NH4+].[F-] LDDQLRUQCUTJBB-UHFFFAOYSA-N 0.000 description 3
- 238000007743 anodising Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000012805 post-processing Methods 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/26—Anodisation of refractory metals or alloys based thereon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/005—Apparatus specially adapted for electrolytic conversion coating
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/022—Anodisation on selected surface areas
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nanotechnology (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610647491.8A CN107699934B (zh) | 2016-08-09 | 2016-08-09 | 一种超大长径比细钛管内表面二氧化钛纳米管阵列的动态制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610647491.8A CN107699934B (zh) | 2016-08-09 | 2016-08-09 | 一种超大长径比细钛管内表面二氧化钛纳米管阵列的动态制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN107699934A true CN107699934A (zh) | 2018-02-16 |
CN107699934B CN107699934B (zh) | 2019-07-09 |
Family
ID=61168831
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610647491.8A Active CN107699934B (zh) | 2016-08-09 | 2016-08-09 | 一种超大长径比细钛管内表面二氧化钛纳米管阵列的动态制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN107699934B (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110552042A (zh) * | 2019-08-27 | 2019-12-10 | 重庆大学 | 一种u型钛管内表面超浸润涂层的制备方法 |
CN112547462A (zh) * | 2020-11-23 | 2021-03-26 | 重庆大学 | 一种采样针表面耐磨超疏水涂层的制备方法 |
CN112593280A (zh) * | 2020-11-23 | 2021-04-02 | 重庆大学 | 一种空心针内外表面及端面超疏水涂层的制备方法 |
CN112710588A (zh) * | 2020-11-23 | 2021-04-27 | 重庆大学 | 一种毛细管内表面静态接触角计算与测试方法及测试系统 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN200940167Y (zh) * | 2006-07-27 | 2007-08-29 | 台山市金桥铝型材厂有限公司 | 铝管内外壁阳极氧化设备 |
US20100116733A1 (en) * | 2008-11-12 | 2010-05-13 | Korea Electrotechnology Research Institute | Nanoporous oxide ceramic membranes of tubular and hollow fiber shape and method of making the same |
-
2016
- 2016-08-09 CN CN201610647491.8A patent/CN107699934B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN200940167Y (zh) * | 2006-07-27 | 2007-08-29 | 台山市金桥铝型材厂有限公司 | 铝管内外壁阳极氧化设备 |
US20100116733A1 (en) * | 2008-11-12 | 2010-05-13 | Korea Electrotechnology Research Institute | Nanoporous oxide ceramic membranes of tubular and hollow fiber shape and method of making the same |
Non-Patent Citations (3)
Title |
---|
LIDONG SUN: "Anodic Titania Nanotubes grown on titanium tubular electrodes", 《LANGMUIR》 * |
LIDONG SUN: "double-sided anodic titania nanotube arrays:A lopsided growth process", 《LANGMUIR》 * |
周文利: "《清洁与可再生能源研究 太阳能电池》", 31 May 2015, 中国水利水电出版社 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110552042A (zh) * | 2019-08-27 | 2019-12-10 | 重庆大学 | 一种u型钛管内表面超浸润涂层的制备方法 |
CN112547462A (zh) * | 2020-11-23 | 2021-03-26 | 重庆大学 | 一种采样针表面耐磨超疏水涂层的制备方法 |
CN112593280A (zh) * | 2020-11-23 | 2021-04-02 | 重庆大学 | 一种空心针内外表面及端面超疏水涂层的制备方法 |
CN112710588A (zh) * | 2020-11-23 | 2021-04-27 | 重庆大学 | 一种毛细管内表面静态接触角计算与测试方法及测试系统 |
CN112547462B (zh) * | 2020-11-23 | 2022-12-09 | 重庆大学 | 一种采样针表面耐磨超疏水涂层的制备方法 |
CN112710588B (zh) * | 2020-11-23 | 2023-10-13 | 重庆大学 | 一种毛细管内表面静态接触角计算与测试方法及测试系统 |
Also Published As
Publication number | Publication date |
---|---|
CN107699934B (zh) | 2019-07-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN107699934B (zh) | 一种超大长径比细钛管内表面二氧化钛纳米管阵列的动态制备方法 | |
Sun et al. | Effect of anodization voltage on performance of TiO2 nanotube arrays for hydrogen generation in a two-compartment photoelectrochemical cell | |
Syrek et al. | Effect of electrolyte agitation on anodic titanium dioxide (ATO) growth and its photoelectrochemical properties | |
CN107138111B (zh) | 一种二氧化碳催化还原反应装置 | |
CN107723777B (zh) | 电沉积二硫化钼量子点修饰二氧化钛纳米管阵列的制备方法 | |
Cao et al. | Current characterization and growth mechanism of anodic titania nanotube arrays | |
CN109701510A (zh) | 一种Magneli相氧化钛介孔表面的制备方法 | |
CN105780087B (zh) | 电氧化合成一维纳米氧化物结构的制备方法 | |
CN102191529A (zh) | 一种蜂窝状有序的二氧化钛纳米管阵列膜及其制备方法 | |
CN101660189A (zh) | 分枝可控的二氧化钛纳米管阵列薄膜及其制备方法 | |
Grez et al. | Synthesis and characterization of p-Cu2O nanowires arrays | |
CN104911668A (zh) | 一种制备纳米锥形孔阳极氧化铝模板的方法 | |
CN101781788A (zh) | 特殊形貌二氧化钛纳米管薄膜的制备方法 | |
CN105372320A (zh) | 基于在毛细管尖端合成具有沸石结构的咪唑酯框架zif-90制备纳米孔道的方法及其应用 | |
Xu et al. | Asymmetric heterostructured SiO2/Al2O3 nanofluidic diodes modulating ionic transport for highly efficient light-gating device | |
CN102980915B (zh) | 钯掺杂 TiO2纳米管阵列肖特基结氢敏传感器的制备方法 | |
Passalacqua et al. | Use of modified anodization procedures to prepare advanced TiO2 nanostructured catalytic electrodes and thin film materials | |
TWI465301B (zh) | 多孔性氧化鋁模板之製作裝置 | |
CN102691089B (zh) | 采用水电解液在铜基体上制备超疏水表面的电化学方法 | |
CN103225104A (zh) | 一种单晶锐钛矿二氧化钛纳米管阵列及制备方法 | |
CN105836698B (zh) | 一种金‑二氧化钛复合纳米管阵列与金纳米管阵列电极的制备方法 | |
CN105132989A (zh) | 一种二氧化钛纳米管透明薄膜的制备方法 | |
CN105040062B (zh) | Cu2O纳米粒子敏化TiO2纳米管阵列光电极的方法 | |
CN104928747B (zh) | 一种在钛合金表面制备纳米管的方法 | |
CN103938249A (zh) | 一种制备有序大结构单元氧化铝膜的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20230417 Address after: 402, 4th Floor, Building 4, Yard 67, Section 3, Xinghua Street, Daxing District, Beijing 102600 Patentee after: Wanzhongxiang (Beijing) Technology Co.,Ltd. Address before: 400044 No. 174 Sha Jie street, Shapingba District, Chongqing Patentee before: Chongqing University |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20230525 Address after: 410000 1004, building F1, Lugu enterprise Plaza, Changsha high tech Development Zone, Hunan Province Patentee after: Hunan Lidong Technology Co.,Ltd. Address before: 402, 4th Floor, Building 4, Yard 67, Section 3, Xinghua Street, Daxing District, Beijing 102600 Patentee before: Wanzhongxiang (Beijing) Technology Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240122 Address after: Room 301, Building 21, Beihang Science and Technology Park, No. 77 Aerospace Road, Mashan Street, High tech Zone, Yantai City, Shandong Province, China, 264035 Patentee after: Lidong New Materials Technology (Shandong) Co.,Ltd. Country or region after: China Address before: 410000 1004, building F1, Lugu enterprise Plaza, Changsha high tech Development Zone, Hunan Province Patentee before: Hunan Lidong Technology Co.,Ltd. Country or region before: China |