CN107698248A - 一种防渗透钧瓷酒瓶及其制备方法 - Google Patents
一种防渗透钧瓷酒瓶及其制备方法 Download PDFInfo
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- CN107698248A CN107698248A CN201711076159.1A CN201711076159A CN107698248A CN 107698248 A CN107698248 A CN 107698248A CN 201711076159 A CN201711076159 A CN 201711076159A CN 107698248 A CN107698248 A CN 107698248A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000000463 material Substances 0.000 claims abstract description 19
- 239000010949 copper Substances 0.000 claims abstract description 15
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 13
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052802 copper Inorganic materials 0.000 claims abstract description 13
- 239000010433 feldspar Substances 0.000 claims abstract description 13
- 229910052742 iron Inorganic materials 0.000 claims abstract description 13
- 239000010453 quartz Substances 0.000 claims abstract description 13
- 239000003814 drug Substances 0.000 claims abstract description 10
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011787 zinc oxide Substances 0.000 claims abstract description 7
- 229960004643 cupric oxide Drugs 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 241001504624 Streptopelia Species 0.000 claims abstract description 5
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229910000366 copper(II) sulfate Inorganic materials 0.000 claims abstract description 5
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000010436 fluorite Substances 0.000 claims abstract description 5
- 239000011521 glass Substances 0.000 claims abstract description 5
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910001887 tin oxide Inorganic materials 0.000 claims abstract description 5
- 238000001816 cooling Methods 0.000 claims description 15
- 235000015895 biscuits Nutrition 0.000 claims description 12
- 239000000758 substrate Substances 0.000 claims description 9
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- 239000007921 spray Substances 0.000 claims description 6
- 239000004575 stone Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 238000000498 ball milling Methods 0.000 claims description 3
- 230000036760 body temperature Effects 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 235000019628 coolness Nutrition 0.000 claims description 3
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- 239000007788 liquid Substances 0.000 abstract description 7
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- 229910052573 porcelain Inorganic materials 0.000 description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
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- 239000000126 substance Substances 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
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- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
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- 238000005516 engineering process Methods 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
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- 229910052708 sodium Inorganic materials 0.000 description 2
- 229920002955 Art silk Polymers 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
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- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- MWKXCSMICWVRGW-UHFFFAOYSA-N calcium;phosphane Chemical compound P.[Ca] MWKXCSMICWVRGW-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 1
- 229910052951 chalcopyrite Inorganic materials 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
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- 230000007547 defect Effects 0.000 description 1
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- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000005188 flotation Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- -1 for painting Substances 0.000 description 1
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- 230000005484 gravity Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- 229910000015 iron(II) carbonate Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000007885 magnetic separation Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 239000005304 optical glass Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910021646 siderite Inorganic materials 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
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- 241000894007 species Species 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- CCEKAJIANROZEO-UHFFFAOYSA-N sulfluramid Chemical group CCNS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F CCEKAJIANROZEO-UHFFFAOYSA-N 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
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- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000005335 volcanic glass Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
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- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
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- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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Abstract
本发明涉及一种防渗透钧瓷酒瓶及其制备方法，它是由下列重量份数的原料制备而成的：坯料：长石50份，方解5份，石英3份，熔块3份，氧化锌1份，氧化铜3份，氧化锡2份，铁矿石2份；瓶体外壁釉料：长石20份，方解石5份，石英3份，草木灰7份，萤石5份，铜矿石2份，铁红粉2份，汝药3份；瓶体内壁釉料：长石40份，方解石5份，石英3份，汝蓝石2份，铜灰2份，玻璃2份，鸠山本药2份；能够祛除传统钧瓷中的有害成分，用于盛放物质，并且具有很好的防治液体渗透和酒分子渗透的功能。
Description
技术领域
本发明涉及瓷器领域，具体涉及一种防渗透钧瓷酒瓶及其制备方法。
背景技术
我国陶瓷历史悠久，万余年间，人类在定居生活中，用水、土、火创造了原始的陶器；唐宋盛世时期，陶瓷业空前发展，钧、汝、官、哥、定成为公认的五大名瓷；钧瓷釉以氧化铜还原着色所产生的神奇窑变而独步瓷林；改革开放后的三十年，钧瓷艺术品的发展空前繁荣；国礼钧瓷成为了中国的一张名片而享誉全球。它厚重的历史文化底蕴和瑰丽丰富的窑变神韵被尊为“纵有家财万贯，不如钧瓷一件”的稀释珍品。
但是钧瓷在观赏瓷器领域占据领先地位，其日用价值却始终不能凸显，特别是在盛具方面，钧瓷一直采用传统的坯料配方以及面釉和底釉配方，其生产出的瓷器仍然不能满足日用盛放液体并饮用方面的需求。时至今日，由于科学技术的进步，已出现了许多可以代替陶瓷器皿的材料，传统陶瓷器皿功能比较单一，仅仅只有装饰、盛物等简单功能，目前市场上急需一种用于盛放并保存液体并提供人体饮用器具的钧瓷，用于改变传统钧瓷单一的观赏功能，以提高陶瓷器皿的性能，并且能够在发挥瓷器稳定性的前提下，提高盛放液体饮用质量。
因此，生产一种健康保健，工艺简单，化繁为简，既实用又美观大气的防渗透钧瓷酒瓶及其制备方法，具有广泛的市场前景。
发明内容
针对现有技术的不足，本发明提供一种健康保健，工艺简单，化繁为简，既实用又美观大气的防渗透钧瓷酒瓶及其制备方法，用于克服现有技术的缺陷。
本发明的技术方案是这样实现：一种防渗透钧瓷酒瓶，它是由下列重量份数的原料制备而成的：
坯料：长石50份，方解5份，石英3份，熔块3份，氧化锌1份，氧化铜3份，氧化锡2份，铁矿石2份；
瓶体外壁釉料：长石20份，方解石5份，石英3份，草木灰7份，萤石5份，铜矿石2份，铁红粉2份，汝药3份；
瓶体内壁釉料：长石40份，方解石5份，石英3份，汝蓝石2份，铜灰2份，玻璃2份，鸠山本药2份。
一种如上所述的防渗透钧瓷酒瓶的制备方法，其制备方法如下：
1）首先按照上述重量份数分别制备坯料、瓶体外壁釉料和瓶体内壁釉料，制备时先分别捣碎物料，然后分别上球磨机加水球磨，坯料、瓶体外壁釉料和瓶体内壁釉料的制备满足条件为：坯料过200目筛备用，瓶体外壁釉料过250目筛备用，瓶体内壁釉料过250目筛备用；
2）制作工作模，使用步骤1）中得到的坯料，利用工作模制作坯体，然后将坯体入窑素烧，温度为1200℃，素烧时间为5小时，得素坯；
3）将步骤2）中的素坯修整，然后在素坯外壁刷抹步骤1）中所述的瓶体外壁釉料，并在素坯内壁采用喷釉器喷上步骤1）中所述的瓶体内壁釉料，喷料后放置在烘干机内烘干，烘干时间为30分钟，烘干温度为300℃；
4）将步骤3）中涂抹瓶体外壁釉料和瓶体内壁釉料的坯体入窑煅烧，点火前期，压力控制在0.01兆帕，温度省高至1000℃时保温半小时，半小时后调节闸门，保证每分钟升温5℃，并调整压力升高至0.1兆帕，当温度达到1180℃，微合闸板，升温速度控制在每分钟0.5℃，压力不变，当温度升高至1200摄氏度后再降压力至0.02兆帕，当温度升高是1250摄氏度后用闸板配合压力，使窑体温度处于保温状态，保温时间需要2至3个小时，当到1280℃时保温30分钟，停火，冷却时，温度从1280℃到800℃，降温速度控制在每分钟5℃；800℃至500℃，降温速度控制在每分钟3℃；500℃以下快速冷却，降温速度控制在每分钟5℃，烧成后检验既得本产品。
本发明具有如下的积极效果：本发明原料相互配合作用，能够祛除传统钧瓷中的有害成分，用于盛放物质，并且具有很好的防治液体渗透和酒分子渗透的功能。
具体实施方式
一种防渗透钧瓷酒瓶，它是由下列重量份数的原料制备而成的：
坯料：长石50份，方解5份，石英3份，熔块3份，氧化锌1份，氧化铜3份，氧化锡2份，铁矿石2份；
瓶体外壁釉料：长石20份，方解石5份，石英3份，草木灰7份，萤石5份，铜矿石2份，铁红粉2份，汝药3份；
瓶体内壁釉料：长石40份，方解石5份，石英3份，汝蓝石2份，铜灰2份，玻璃2份，鸠山本药2份。
一种如上所述的防渗透钧瓷酒瓶的制备方法，其制备方法如下：
1）首先按照上述重量份数分别制备坯料、瓶体外壁釉料和瓶体内壁釉料，制备时先分别捣碎物料，然后分别上球磨机加水球磨，坯料、瓶体外壁釉料和瓶体内壁釉料的制备满足条件为：坯料过200目筛备用，瓶体外壁釉料过250目筛备用，瓶体内壁釉料过250目筛备用；
2）制作工作模，使用步骤1）中得到的坯料，利用工作模制作坯体，然后将坯体入窑素烧，温度为1200℃，素烧时间为5小时，得素坯；
3）将步骤2）中的素坯修整，然后在素坯外壁刷抹步骤1）中所述的瓶体外壁釉料，并在素坯内壁采用喷釉器喷上步骤1）中所述的瓶体内壁釉料，喷料后放置在烘干机内烘干，烘干时间为30分钟，烘干温度为300℃；
4）将步骤3）中涂抹瓶体外壁釉料和瓶体内壁釉料的坯体入窑煅烧，点火前期，压力控制在0.01兆帕，温度省高至1000℃时保温半小时，半小时后调节闸门，保证每分钟升温5℃，并调整压力升高至0.1兆帕，当温度达到1180℃，微合闸板，升温速度控制在每分钟0.5℃，压力不变，当温度升高至1200摄氏度后再降压力至0.02兆帕，当温度升高是1250摄氏度后用闸板配合压力，使窑体温度处于保温状态，保温时间需要2至3个小时，当到1280℃时保温30分钟，停火，冷却时，温度从1280℃到800℃，降温速度控制在每分钟5℃；800℃至500℃，降温速度控制在每分钟3℃；500℃以下快速冷却，降温速度控制在每分钟5℃，烧成后检验既得本产品。
长石属于硅酸盐矿物盐，其内部含量为钾元素、钠元素和钙元素等，分为黄色、白色和红色等，是釉料的主要成分，主要对于釉料的形成起到重要作用。禹州分布有众多矿藏。
方解石主要降低釉料熔融温度，增加釉色的光泽度和透明度，防治釉面龟裂和堆积，用量不能过多，否则会导致釉面析晶失透，造成温度变窄，变化过少，并引起釉面吸烟。
石英是变质岩，其含量为二氧化硅，主要增加釉料的光泽度，不能过多，也不能少，否则会造成釉面变化色彩减少。
熔块具有不可溶性和稳定性等特征，加工研磨后备用，可做为釉的强溶剂，也可单独使用。蓝粉是化工常用原料。
氧化铜是一种铜的黑色氧化物，略显两性，稍有吸湿性。相对分子质量为79.545，密度为6.3～6.9 g/cm3，熔点1326℃。不溶于水和乙醇，溶于酸、氯化铵及氰化钾溶液，氨溶液中缓慢溶解，能与强碱反应。氧化铜主要用于制人造丝、陶瓷、釉及搪瓷、电池、石油脱硫剂、杀虫剂，也供制氢、催化剂、绿色玻璃等用。
氧化锡为白色、淡黄色或淡灰色四方、六方或斜方晶系粉末。熔点1630℃。
草木灰主要引入钙磷等元素，是良好的助溶剂，对釉浆有一定的悬浮性，可降低釉的熔融温度和釉的高温粘度，同时具有乳浊性和对钧釉分相的促进作用，用量应当控制。
萤石是一种矿物，等轴晶系，其主要成分是氟化钙，能降低釉的熔融温度，增加釉的流动性，同时具有乳浊作用，可提高钧釉的光泽度，提高釉浆的悬浮性。
铜矿石是最主要的铜矿石矿物，一般由Cu,Fe,S三种元素组成，理论组成（%）Cu34.56, Fe 30.52, S 34.92，理论化学式为CuFeS2。氧化锌是锌的一种氧化物。难溶于水，可溶于酸和强碱。
铁红粉，是一种化工原料，用于油漆,橡胶,塑料,建筑等的着色。用于油漆,橡胶,塑料,建筑等的着色，有天然的和人造的两种。由于生产方法和操作条件的不同，它们的晶体结构和物理性状都有很大的差别，色泽变动于橙光到蓝光至紫光之间。遮盖力和着色力都很大。有优越的耐光、耐高温性能，并耐大气影响、耐污浊气体、耐一切碱类。在浓酸中只有在加热情况下才逐渐被溶解。用途很广泛，普遍使用于建筑、橡胶、塑料、涂料等工业，特别是铁红底漆具有防锈功能，可以代替高价的红丹漆，节约有色金属。又是高级精磨材料，使用于精密的五金仪器、光学玻璃等的抛光。火山岩是一种功能型环保材料，是火山爆发后由火山玻璃、矿物与气泡形成的非常珍贵的多孔形石材，火山石中含有钠、镁、铝、硅、钙、钛、锰、铁、镍、钴和钼等几十种矿物质和微量元素，无辐射而具有远红外磁波。现已将其应用领域扩大到建筑、水利、研磨、滤材、烧烤炭、园林造景、无土栽培、观赏品等领域，在各行各业中发挥着无法替代的作用。
氧化锌是一种常用的化学添加剂，广泛地应用于塑料、硅酸盐制品、合成橡胶、润滑油、油漆涂料、药膏、粘合剂、食品、电池、阻燃剂等产品的制作中。氧化锌的能带隙和激子束缚能较大，透明度高，有优异的常温发光性能。
铁矿石是钢铁生产企业的重要原材料，天然矿石经过破碎、磨碎、磁选、浮选、重选等程序逐渐选出铁。是含有铁单质或铁化合物能够经济利用的矿物集合体。凡是含有可经济利用的铁元素的矿石叫做铁矿石。铁矿石的种类很多，用于炼铁的主要有磁铁矿（Fe3O4）、赤铁矿（Fe2O3）和菱铁矿（FeCO3）等。本专利中铁矿石是必不可少的形成黑色斑斓变化的重要原料。
汝药是河南当地出产的一种制备钧瓷釉料的石材，主要成分为二氧化硅，河南人民出版社《中国钧炉研究》一书123页有详细介绍。
汝蓝石是河南当地出产的一种制备钧瓷釉料的石材，主要成分为二氧化硅，河南人民出版社《中国钧炉研究》一书123页有详细介绍。铜灰自制，主要成分一氧化铜含量98﹪，鸠山本药主要含量为二氧化硅。草木灰主要引入钙元素和磷元素，是良好的助溶剂具有强碱性，在釉中具有很轻的电解作用，一般作为分散剂使用，对釉浆有一定的悬浮性，可以降低熔融温度和釉的高温粘度，同时具有乳浊作用和对钧釉的分相促进作用。
本发明原料相互配合作用，能够祛除传统钧瓷中的有害成分，用于盛放物质，并且具有很好的防治液体渗透和酒分子渗透的功能，具有很好的社会和经济效益。
Claims (2)
1.一种防渗透钧瓷酒瓶，其特征在于，它是由下列重量份数的原料制备而成的：
坯料：长石50份，方解5份，石英3份，熔块3份，氧化锌1份，氧化铜3份，氧化锡2份，铁矿石2份；
瓶体外壁釉料：长石20份，方解石5份，石英3份，草木灰7份，萤石5份，铜矿石2份，铁红粉2份，汝药3份；
瓶体内壁釉料：长石40份，方解石5份，石英3份，汝蓝石2份，铜灰2份，玻璃2份，鸠山本药2份。
2.一种如权利要求1所述的防渗透钧瓷酒瓶的制备方法，其特征在于，其制备方法如下：
1）首先按照上述重量份数分别制备坯料、瓶体外壁釉料和瓶体内壁釉料，制备时先分别捣碎物料，然后分别上球磨机加水球磨，坯料、瓶体外壁釉料和瓶体内壁釉料的制备满足条件为：坯料过200目筛备用，瓶体外壁釉料过250目筛备用，瓶体内壁釉料过250目筛备用；
2）制作工作模，使用步骤1）中得到的坯料，利用工作模制作坯体，然后将坯体入窑素烧，温度为1200℃，素烧时间为5小时，得素坯；
3）将步骤2）中的素坯修整，然后在素坯外壁刷抹步骤1）中所述的瓶体外壁釉料，并在素坯内壁采用喷釉器喷上步骤1）中所述的瓶体内壁釉料，喷料后放置在烘干机内烘干，烘干时间为30分钟，烘干温度为300℃；
4）将步骤3）中涂抹瓶体外壁釉料和瓶体内壁釉料的坯体入窑煅烧，点火前期，压力控制在0.01兆帕，温度省高至1000℃时保温半小时，半小时后调节闸门，保证每分钟升温5℃，并调整压力升高至0.1兆帕，当温度达到1180℃，微合闸板，升温速度控制在每分钟0.5℃，压力不变，当温度升高至1200摄氏度后再降压力至0.02兆帕，当温度升高是1250摄氏度后用闸板配合压力，使窑体温度处于保温状态，保温时间需要2至3个小时，当到1280℃时保温30分钟，停火，冷却时，温度从1280℃到800℃，降温速度控制在每分钟5℃；800℃至500℃，降温速度控制在每分钟3℃；500℃以下快速冷却，降温速度控制在每分钟5℃，烧成后检验既得本产品。
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| CN104150873A (zh) * | 2014-08-25 | 2014-11-19 | 龙泉市尚唐瓷艺发展有限公司 | 一种龙泉青瓷裂纹釉酒瓶及其制备方法 |
| CN106082664A (zh) * | 2016-06-16 | 2016-11-09 | 尹建中 | 一种黑色面釉及其制备方法 |
| CN106186697A (zh) * | 2016-07-04 | 2016-12-07 | 王建红 | 一种炉钧釉 |
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| CN104150873A (zh) * | 2014-08-25 | 2014-11-19 | 龙泉市尚唐瓷艺发展有限公司 | 一种龙泉青瓷裂纹釉酒瓶及其制备方法 |
| CN106082664A (zh) * | 2016-06-16 | 2016-11-09 | 尹建中 | 一种黑色面釉及其制备方法 |
| CN106186697A (zh) * | 2016-07-04 | 2016-12-07 | 王建红 | 一种炉钧釉 |
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