CN107687092A - 一种织物抗静电剂的制备方法 - Google Patents
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Abstract
本发明公开了一种织物抗静电剂的制备方法，所述织物抗静电剂由如下重量份数的原料组成：聚氧乙烯二胺15‑25份、柠檬酸钠2‑4份、三乙醇胺4‑10份、苯乙烯10‑20份、硫酸钠0.5‑1份、亚麻酸10‑20份、聚对苯二甲酸乙二醇酯0.5‑1.5份、油酸10‑20份、硅藻土2‑8份、乙醇50‑100份。本发明的织物抗静电剂应用于织物之后，织物的抗静电性能比原织物提高90％以上。本发明的织物抗静电剂制造工艺简单易操作，原料价格低廉易获得，且无毒无害，对人体不刺激，挥发性低，整理后的织物其韧性、强度、手感基本不受影响。
Description
技术领域
本发明属于纺织助剂技术领域，更具体是涉及一种织物抗静电剂。
背景技术
一般合成纤维的织物含湿量是比较低的，结晶度比较高，所以是一种比较容易产生静电的织物，合成纤维的静电一般可以达到2000V，最高时可以达到4000V左右。虽然它们电流比较小，不过也是让人很讨厌的，也是有麻烦的。静电的危害很多，比如：织物出现放电之后，在一些比较容易燃烧和爆炸的场合会容易出现火灾以及爆炸；静电容易造成通信干扰；在烘干之后，这种静电会让织物吸附在金属部件上，会造成缠绕等现象，使得设备紊乱；同一种织物的静电电荷可能会排斥，那么使得落布不易折叠整齐；当手或者其他部位触碰到的时候，可能会受到电击；织物穿在身上，可能会因为运动摩擦等原因产生了静电，当手指接触金属体如门把手、栏杆时会产生放电现象犹如蜂蜇，与人握手也像电击；晚上还会在脱衣服的时候噼里啪啦，还有火星，着实吓人，让人不安；静电的现象容易使得织物上沾染灰尘；静电对于心脏病、精神分裂以及神经衰弱等都是一种危险。
所以寻找一种织物抗静电剂是非常必要的。
发明内容
本发明的目的在于提供一种织物抗静电剂及制备方法，以解决上述背景技术中提出的问题。
为实现上述目的，本发明提供如下技术方案：
一种织物抗静电剂，所述织物抗静电剂包括如下重量份数的原料：聚氧乙烯二胺15-25份、柠檬酸钠2-4份、三乙醇胺4-10份、苯乙烯10-20份、硫酸钠0.5-1份、亚麻酸10-20份、聚对苯二甲酸乙二醇酯0.5-1.5份、油酸10-20份、硅藻土2-8份、乙醇50-100份。
优选地，所述乙醇为无水乙醇，纯度为分析纯。
优选地，按照重量份数，至少由以下组分制备而成：聚氧乙烯二胺15份、柠檬酸钠2份、三乙醇胺4份、苯乙烯10份、硫酸钠0.5份、亚麻酸10份、聚对苯二甲酸乙二醇酯0.5份、油酸10份、硅藻土2份、乙醇50份。
优选地，按照重量份数，至少由以下组分制备而成：聚氧乙烯二胺20份、柠檬酸钠3份、三乙醇胺7份、苯乙烯15份、硫酸钠0.8份、亚麻酸15份、聚对苯二甲酸乙二醇酯1份、油酸15份、硅藻土5份、乙醇75份。
优选地，按照重量份数，至少由以下组分制备而成：聚氧乙烯二胺25份、柠檬酸钠4份、三乙醇胺10份、苯乙烯20份、硫酸钠1份、亚麻酸20份、聚对苯二甲酸乙二醇酯1.5份、油酸20份、硅藻土8份、乙醇100份。
优选地，一种织物抗静电剂的制备方法，其特征在于：具体步骤如下：
步骤1，在反应釜中加入乙醇50-100份、硅藻土2-8份，500-1000转/分钟，搅拌5-10分钟；
步骤2，先将油酸10-20份、聚氧乙烯二胺15-25份、三乙醇胺4-10份，用超声分散10-20分钟，得到均匀溶液；
步骤3，将步骤2的均匀溶液加入步骤1的溶液中，500-1000转/分钟，搅拌20-30分钟；
步骤4，升高温度至60-80℃，加入苯乙烯10-20份、硫酸钠0.5-1份，500-1000转/分钟，搅拌20-30分钟；
步骤5，降温至20-30℃，加入柠檬酸钠2份、亚麻酸10份、聚对苯二甲酸乙二醇酯0.5份，500-1000转/分钟，搅拌20-30分钟；
步骤6，关停搅拌，得到配制好的液体织物抗静电剂；
步骤7，静置冷却至搅拌釜中液体织物抗静电剂低于20℃，放料封装，制得成品。
与现有技术相比，本发明的有益效果是：
1、本发明的织物抗静电剂应用织物之后，织物的抗静电性能比原织物提高90％以上。
2、本发明的织物抗静电剂制造工艺简单易操作，原料价格低廉易获得，且无毒无害，对人体不刺激，挥发性低，整理后的织物其韧性、强度、手感基本不受影响。
3、本发明的织物抗静电剂所用各种原料之间相互配伍、协同作用，共同组成性能优异的产品。
4、油酸的加入，提高了织物的织物抗静电性能。
5、简化工艺，操作安全简单，易于工业化生产。
6、本发明的织物抗静电涂层施工简单，可以通过浸渍、喷涂、辊涂等进行施加，生产效率提高。
7、本发明的使用可收到良好的经济效益。
具体实施实例
本发明公开了一种织物抗静电剂，按照重要份数，由以下组分制备而成：聚氧乙烯二胺15-25份、柠檬酸钠2-4份、三乙醇胺4-10份、苯乙烯10-20份、硫酸钠0.5-1份、亚麻酸10-20份、聚对苯二甲酸乙二醇酯0.5-1.5份、油酸10-20份、硅藻土2-8份、乙醇50-100份。
本发明还提供了一种织物抗静电剂的制备方法，具体步骤如下：
(1)在反应釜中加入乙醇50-100份、硅藻土2-8份，500-1000转/分钟，搅拌5-10分钟；
(2)先将油酸10-20份、聚氧乙烯二胺15-25份、三乙醇胺4-10份，用超声分散10-20分钟，得到均匀溶液；
(3)将步骤(2)的均匀溶液加入步骤(1)的溶液中，500-1000转/分钟，搅拌20-30分钟；
(4)升高温度至60-80℃，加入苯乙烯10-20份、硫酸钠0.5-1份，500-1000转/分钟，搅拌20-30分钟；
(5)降温至20-30℃，加入柠檬酸钠2-4份、亚麻酸10-20份、聚对苯二甲酸乙二醇酯0.5-1.5份，500-1000转/分钟，搅拌20-30分钟；
(6)关停搅拌，得到配制好的液体织物抗静电剂；
(7)静置冷却至搅拌釜中液体织物抗静电剂低于20℃，放料封装，制得成品。
实施例1
本发明公开了一种织物抗静电剂，按照重要份数，由以下组分制备而成：聚氧乙烯二胺15份、柠檬酸钠2份、三乙醇胺4份、苯乙烯10份、硫酸钠0.5份、亚麻酸10份、聚对苯二甲酸乙二醇酯0.5份、油酸10份、硅藻土2份、乙醇50份。
本发明还提供了一种织物抗静电剂的制备方法，具体步骤如下：
(1)在反应釜中加入乙醇50份、硅藻土2份，500转/分钟，搅拌5分钟；
(2)先将油酸10份、聚氧乙烯二胺15份、三乙醇胺4份，用超声分散10分钟，得到均匀溶液；
(3)将步骤(2)的均匀溶液加入步骤(1)的溶液中，500转/分钟，搅拌20分钟；
(4)升高温度至60℃，加入苯乙烯10份、硫酸钠0.5份，500转/分钟，搅拌20分钟；
(5)降温至20℃，加入柠檬酸钠2份、亚麻酸10份、聚对苯二甲酸乙二醇酯0.5份，500转/分钟，搅拌20分钟；
(6)关停搅拌，得到配制好的液体织物抗静电剂；
(7)静置冷却至搅拌釜中液体织物抗静电剂低于20℃，放料封装，制得成品。
实施例2
本发明公开了一种织物抗静电剂，按照重要份数，由以下组分制备而成：聚氧乙烯二胺20份、柠檬酸钠4份、三乙醇胺8份、苯乙烯16份、硫酸钠0.9份、亚麻酸18份、聚对苯二甲酸乙二醇酯1.2份、油酸18份、硅藻土5份、乙醇80份。
本发明还提供了一种织物抗静电剂的制备方法，具体步骤如下：
(1)在反应釜中加入乙醇80份、硅藻土5份，700转/分钟，搅拌8分钟；
(2)先将油酸18份、聚氧乙烯二胺20份、三乙醇胺8份，用超声分散15分钟，得到均匀溶液；
(3)将步骤(2)的均匀溶液加入步骤(1)的溶液中，800转/分钟，搅拌20分钟；
(4)升高温度至65℃，加入苯乙烯16份、硫酸钠0.9份，600转/分钟，搅拌23分钟；
(5)降温至25℃，加入柠檬酸钠4份、亚麻酸18份、聚对苯二甲酸乙二醇酯1.2份，800转/分钟，搅拌20分钟；
(6)关停搅拌，得到配制好的液体织物抗静电剂；
(7)静置冷却至搅拌釜中液体织物抗静电剂低于20℃，放料封装，制得成品。
实施例3
本发明公开了一种织物抗静电剂，按照重要份数，由以下组分制备而成：聚氧乙烯二胺20份、柠檬酸钠3份、三乙醇胺7份、苯乙烯15份、硫酸钠0.8份、亚麻酸15份、聚对苯二甲酸乙二醇酯1份、油酸15份、硅藻土5份、、乙醇75份。
本发明还提供了一种织物抗静电剂的制备方法，具体步骤如下：
(1)在反应釜中加入乙醇75份、硅藻土5份，900转/分钟，搅拌5分钟；
(2)先将油酸15份、聚氧乙烯二胺20份、三乙醇胺7份，用超声分散15分钟，得到均匀溶液；
(3)将步骤(2)的均匀溶液加入步骤(1)的溶液中，750转/分钟，搅拌25分钟；
(4)升高温度至70℃，加入苯乙烯15份、硫酸钠0.8份，750转/分钟，搅拌25分钟；
(5)降温至25℃，加入柠檬酸钠3份、亚麻酸15份、聚对苯二甲酸乙二醇酯1份，750转/分钟，搅拌25分钟；
(6)关停搅拌，得到配制好的液体织物抗静电剂；
(7)静置冷却至搅拌釜中液体织物抗静电剂低于20℃，放料封装，制得成品。
实施例4
本发明公开了一种织物抗静电剂，按照重要份数，由以下组分制备而成：聚氧乙烯二胺25份、柠檬酸钠4份、三乙醇胺10份、苯乙烯20份、硫酸钠1份、亚麻酸20份、聚对苯二甲酸乙二醇酯1.5份、油酸20份、硅藻土8份、乙醇100份。
本发明还提供了一种织物抗静电剂的制备方法，具体步骤如下：
(1)在反应釜中加入乙醇100份、硅藻土8份，1000转/分钟，搅拌10分钟；
(2)先将油酸20份、聚氧乙烯二胺25份、三乙醇胺10份，用超声分散20分钟，得到均匀溶液；
(3)将步骤(2)的均匀溶液加入步骤(1)的溶液中，1000转/分钟，搅拌30分钟；
(4)升高温度至80℃，加入苯乙烯20份、硫酸钠1份，1000转/分钟，搅拌30分钟；
(5)降温至30℃，加入柠檬酸钠4份、亚麻酸20份、聚对苯二甲酸乙二醇酯1.5份，1000转/分钟，搅拌30分钟；
(6)关停搅拌，得到配制好的液体织物抗静电剂；
(7)静置冷却至搅拌釜中液体织物抗静电剂低于20℃，放料封装，制得成品。
测试例
将4块相同的纯棉布放入实施例1、2、3、4的抗静电溶液中，经过两浸两轧，烘干，焙烘，水洗，烘干，可以得到4块具有抗静电性能的布。测试的结果如下：
尽管已经示出和描述了本发明的实施例，对于本领域的普通技术人员而言，可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的范围由所附权利要求及其等同物限定。
Claims (6)
1.一种织物抗静电剂，其特征在于：所述织物抗静电剂包括如下重量份数的原料：聚氧乙烯二胺15-25份、柠檬酸钠2-4份、三乙醇胺4-10份、苯乙烯10-20份、硫酸钠0.5-1份、亚麻酸10-20份、聚对苯二甲酸乙二醇酯0.5-1.5份、油酸10-20份、硅藻土2-8份、乙醇50-100份。
2.根据权利要求1所述的织物抗静电剂，其特征在于：所述乙醇为无水乙醇，纯度为分析纯。
3.根据权利要求1所述的一种织物抗静电剂，其特征在于：按照重量份数，至少由以下组分制备而成：聚氧乙烯二胺15份、柠檬酸钠2份、三乙醇胺4份、苯乙烯10份、硫酸钠0.5份、亚麻酸10份、聚对苯二甲酸乙二醇酯0.5份、油酸10份、硅藻土2份、乙醇50份。
4.根据权利要求1所述的一种织物抗静电剂，其特征在于：按照重量份数，至少由以下组分制备而成：聚氧乙烯二胺20份、柠檬酸钠3份、三乙醇胺7份、苯乙烯15份、硫酸钠0.8份、亚麻酸15份、聚对苯二甲酸乙二醇酯1份、油酸15份、硅藻土5份、乙醇75份。
5.根据权利要求1所述的一种织物抗静电剂，其特征在于：按照重量份数，至少由以下组分制备而成：聚氧乙烯二胺25份、柠檬酸钠4份、三乙醇胺10份、苯乙烯20份、硫酸钠1份、亚麻酸20份、聚对苯二甲酸乙二醇酯1.5份、油酸20份、硅藻土8份、乙醇100份。
6.一种根据上述权利要求1-5中任一所述的一种织物抗静电剂的制备方法，其特征在于：具体步骤如下：
步骤1，在反应釜中加入乙醇50-100份、硅藻土2-8份，500-1000转/分钟，搅拌5-10分钟；
步骤2，先将油酸10-20份、聚氧乙烯二胺15-25份、三乙醇胺4-10份，用超声分散10-20分钟，得到均匀溶液；
步骤3，将步骤2的均匀溶液加入步骤1的溶液中，500-1000转/分钟，搅拌20-30分钟；
步骤4，升高温度至60-80℃，加入苯乙烯10-20份、硫酸钠0.5-1份，500-1000转/分钟，搅拌20-30分钟；
步骤5，降温至20-30℃，加入柠檬酸钠2份、亚麻酸10份、聚对苯二甲酸乙二醇酯0.5份，500-1000转/分钟，搅拌20-30分钟；
步骤6，关停搅拌，得到配制好的液体织物抗静电剂；
步骤7，静置冷却至搅拌釜中液体织物抗静电剂低于20℃，放料封装，制得成品。
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113136725A (zh) * | 2021-06-03 | 2021-07-20 | 南通宏申化工有限公司 | 一种高稳定性表面活性剂型复合抗静电剂 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104130594A (zh) * | 2014-07-01 | 2014-11-05 | 青阳县永诚钙业有限责任公司 | 一种具有抗静电效果的改性碳酸钙及其制备方法 |
| CN104805687A (zh) * | 2015-05-12 | 2015-07-29 | 湖州厉华妤婕联合纺织有限公司 | 一种新型涤纶织物用抗静电整理剂组合物 |
| CN105696343A (zh) * | 2016-03-11 | 2016-06-22 | 湖州宏鑫绸厂 | 一种羊毛织物抗静电整理方法 |
| CN105755798A (zh) * | 2016-04-29 | 2016-07-13 | 江苏苏扬服帽有限公司 | 一种用于针织的多功能整理剂、其制备方法及其应用 |
| CN105780484A (zh) * | 2016-03-14 | 2016-07-20 | 湖州新创丝织品有限公司 | 一种涤纶织物抗静电整理方法 |
-
2017
- 2017-08-15 CN CN201710694477.8A patent/CN107687092A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104130594A (zh) * | 2014-07-01 | 2014-11-05 | 青阳县永诚钙业有限责任公司 | 一种具有抗静电效果的改性碳酸钙及其制备方法 |
| CN104805687A (zh) * | 2015-05-12 | 2015-07-29 | 湖州厉华妤婕联合纺织有限公司 | 一种新型涤纶织物用抗静电整理剂组合物 |
| CN105696343A (zh) * | 2016-03-11 | 2016-06-22 | 湖州宏鑫绸厂 | 一种羊毛织物抗静电整理方法 |
| CN105780484A (zh) * | 2016-03-14 | 2016-07-20 | 湖州新创丝织品有限公司 | 一种涤纶织物抗静电整理方法 |
| CN105755798A (zh) * | 2016-04-29 | 2016-07-13 | 江苏苏扬服帽有限公司 | 一种用于针织的多功能整理剂、其制备方法及其应用 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113136725A (zh) * | 2021-06-03 | 2021-07-20 | 南通宏申化工有限公司 | 一种高稳定性表面活性剂型复合抗静电剂 |
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