CN113136725A - 一种高稳定性表面活性剂型复合抗静电剂 - Google Patents

一种高稳定性表面活性剂型复合抗静电剂 Download PDF

Info

Publication number
CN113136725A
CN113136725A CN202110622554.5A CN202110622554A CN113136725A CN 113136725 A CN113136725 A CN 113136725A CN 202110622554 A CN202110622554 A CN 202110622554A CN 113136725 A CN113136725 A CN 113136725A
Authority
CN
China
Prior art keywords
parts
stirring
antistatic agent
mixture
type composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110622554.5A
Other languages
English (en)
Inventor
吴月
吴余冬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong Hongshen Chemical Co ltd
Original Assignee
Nantong Hongshen Chemical Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong Hongshen Chemical Co ltd filed Critical Nantong Hongshen Chemical Co ltd
Priority to CN202110622554.5A priority Critical patent/CN113136725A/zh
Publication of CN113136725A publication Critical patent/CN113136725A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/328—Amines the amino group being bound to an acyclic or cycloaliphatic carbon atom
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
    • D06M15/513—Polycarbonates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/59—Polyamides; Polyimides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Medicinal Preparation (AREA)
  • Cosmetics (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

本发明公开了一种高稳定性表面活性剂型复合抗静电剂，抗静电剂组分按重量份数包括乙氧基化烷基胺10‑20份、聚乙二醇环氧甘油醚5‑15份、聚碳酸酯6‑12份、聚醚酯酰胺4‑10份、炭纳米管3‑9份、石墨烯2‑6份、柠檬酸钠5‑12份、硅藻土4‑12份、氧化聚乙烯蜡7‑14份和抗菌剂2‑4份，本发明制备方法简单，制得的抗静电剂无毒无害，具有优异的抗静电和导电性能，而且还具有优异的抑菌和抗菌性能，使用后不但能显著提高涤纶织物的抗静电性能，抗静电持久，而且对皮肤无刺激，健康安全。

Description

一种高稳定性表面活性剂型复合抗静电剂
技术领域
本发明涉及抗静电剂制备技术领域，具体为一种高稳定性表面活性剂型复合抗静电剂。
背景技术
抗静电剂是添加在塑料之中或涂敷于模塑制品的表面,以达到减少静电积累目的的一类添加剂。通常根据使用方法的不同,抗静电剂可分为内加型和外涂型两大类,用于塑料的主要是内加型抗静电剂。也可按抗静电剂的性能分为暂时性的和永久性的两大类。
目前的织物用抗静电剂具有一定的抗静电性能，但是效果差，而且抑菌抗菌效果差，因此，有必要进行改进。
发明内容
本发明的目的在于提供一种高稳定性表面活性剂型复合抗静电剂，以解决上述背景技术中提出的问题。
为实现上述目的，本发明提供如下技术方案：一种高稳定性表面活性剂型复合抗静电剂,其特征在于：抗静电剂组分按重量份数包括乙氧基化烷基胺10-20份、聚乙二醇环氧甘油醚5-15份、聚碳酸酯6-12份、聚醚酯酰胺4-10份、炭纳米管3-9份、石墨烯2-6份、柠檬酸钠5-12份、硅藻土4-12份、氧化聚乙烯蜡7-14份和抗菌剂2-4份。
优选的，抗静电剂组分优选的成分配比包括乙氧基化烷基胺15份、聚乙二醇环氧甘油醚10份、聚碳酸酯9份、聚醚酯酰胺7份、炭纳米管6份、石墨烯4份、柠檬酸钠9份、硅藻土8份、氧化聚乙烯蜡10份和抗菌剂3份。
优选的，所述抗菌剂由30％十二烷基-二甲基-苄基氯化铵、20％微晶高岭石粉、20％氟硅烷偶联剂、15％介孔纳米二氧化钛、15％介孔纳米三氧化二铝制成。
优选的，制备方法包括以下步骤：
A、将乙氧基化烷基胺、聚乙二醇环氧甘油醚、聚碳酸酯、聚醚酯酰胺混合后加入搅拌罐中低速搅拌，得到混合液A；
B、、将炭纳米管、石墨烯、柠檬酸钠、硅藻土、氧化聚乙烯蜡混合后加入搅拌釜中加热搅拌，得到混合液B；
C、将混合物A和混合物B混合后加入加热罐中加热反应，得到混合液C；
D、在混合液C中加入抗菌剂，在常温下充分搅拌混合，即得到抗静电剂。
优选的，所述步骤A中搅拌速率为200-400转/分，时间为20min-40min。
优选的，所述步骤B中搅拌温度为80-90℃，搅拌速率为1000-1400转/分，时间为30min-40min。
优选的，所述步骤C中加热温度为40-60℃，时间为10min-20min。
与现有技术相比，本发明的有益效果是：本发明制备方法简单，制得的抗静电剂无毒无害，具有优异的抗静电和导电性能，而且还具有优异的抑菌和抗菌性能，使用后不但能显著提高涤纶织物的抗静电性能，抗静电持久，而且对皮肤无刺激，健康安全。其中，本发明中添加的聚醚酯酰胺、炭纳米管、石墨烯，能够使聚合物表面电阻降低至107-109ohm/cm2。大大优于规定的指标1.9×1011ohm/cm2；此外，本发明添加的抗菌剂抑菌时间长，且不会损伤织物。
具体实施方式
下面对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
本发明提供如下技术方案：一种高稳定性表面活性剂型复合抗静电剂,抗静电剂组分按重量份数包括乙氧基化烷基胺10-20份、聚乙二醇环氧甘油醚5-15份、聚碳酸酯6-12份、聚醚酯酰胺4-10份、炭纳米管3-9份、石墨烯2-6份、柠檬酸钠5-12份、硅藻土4-12份、氧化聚乙烯蜡7-14份和抗菌剂2-4份。
实施例一：
抗静电剂组分按重量份数包括乙氧基化烷基胺10份、聚乙二醇环氧甘油醚5份、聚碳酸酯6份、聚醚酯酰胺4份、炭纳米管3份、石墨烯2份、柠檬酸钠5份、硅藻土4份、氧化聚乙烯蜡7份和抗菌剂2份。
本实施例中，抗菌剂由30％十二烷基-二甲基-苄基氯化铵、20％微晶高岭石粉、20％氟硅烷偶联剂、15％介孔纳米二氧化钛、15％介孔纳米三氧化二铝制成。
本实施例的制备方法包括以下步骤：
A、将乙氧基化烷基胺、聚乙二醇环氧甘油醚、聚碳酸酯、聚醚酯酰胺混合后加入搅拌罐中低速搅拌，得到混合液A；
B、、将炭纳米管、石墨烯、柠檬酸钠、硅藻土、氧化聚乙烯蜡混合后加入搅拌釜中加热搅拌，得到混合液B；
C、将混合物A和混合物B混合后加入加热罐中加热反应，得到混合液C；
D、在混合液C中加入抗菌剂，在常温下充分搅拌混合，即得到抗静电剂。
本实施例中，步骤A中搅拌速率为200转/分，时间为20min。
本实施例中，步骤B中搅拌温度为80℃，搅拌速率为1000转/分，时间为30min。
本实施例中，步骤C中加热温度为40℃，时间为10min。
实施例二：
抗静电剂组分按重量份数包括乙氧基化烷基胺20份、聚乙二醇环氧甘油醚15份、聚碳酸酯12份、聚醚酯酰胺10份、炭纳米管9份、石墨烯6份、柠檬酸钠12份、硅藻土12份、氧化聚乙烯蜡14份和抗菌剂4份。
本实施例中，抗菌剂由30％十二烷基-二甲基-苄基氯化铵、20％微晶高岭石粉、20％氟硅烷偶联剂、15％介孔纳米二氧化钛、15％介孔纳米三氧化二铝制成。
本实施例的制备方法包括以下步骤：
A、将乙氧基化烷基胺、聚乙二醇环氧甘油醚、聚碳酸酯、聚醚酯酰胺混合后加入搅拌罐中低速搅拌，得到混合液A；
B、、将炭纳米管、石墨烯、柠檬酸钠、硅藻土、氧化聚乙烯蜡混合后加入搅拌釜中加热搅拌，得到混合液B；
C、将混合物A和混合物B混合后加入加热罐中加热反应，得到混合液C；
D、在混合液C中加入抗菌剂，在常温下充分搅拌混合，即得到抗静电剂。
本实施例中，步骤A中搅拌速率为400转/分，时间为20min。
本实施例中，步骤B中搅拌温度为90℃，搅拌速率为1400转/分，时间为40min。
本实施例中，步骤C中加热温度为60℃，时间为20min。
实施例三：
抗静电剂组分按重量份数包括乙氧基化烷基胺12份、聚乙二醇环氧甘油醚8份、聚碳酸酯7份、聚醚酯酰胺6份、炭纳米管4份、石墨烯3份、柠檬酸钠6份、硅藻土5份、氧化聚乙烯蜡8份和抗菌剂3份。
本实施例中，抗菌剂由30％十二烷基-二甲基-苄基氯化铵、20％微晶高岭石粉、20％氟硅烷偶联剂、15％介孔纳米二氧化钛、15％介孔纳米三氧化二铝制成。
本实施例的制备方法包括以下步骤：
A、将乙氧基化烷基胺、聚乙二醇环氧甘油醚、聚碳酸酯、聚醚酯酰胺混合后加入搅拌罐中低速搅拌，得到混合液A；
B、、将炭纳米管、石墨烯、柠檬酸钠、硅藻土、氧化聚乙烯蜡混合后加入搅拌釜中加热搅拌，得到混合液B；
C、将混合物A和混合物B混合后加入加热罐中加热反应，得到混合液C；
D、在混合液C中加入抗菌剂，在常温下充分搅拌混合，即得到抗静电剂。
本实施例中，步骤A中搅拌速率为250转/分，时间为25min。
本实施例中，步骤B中搅拌温度为84℃，搅拌速率为1200转/分，时间为30min-40min。
本实施例中，步骤C中加热温度为45℃，时间为12min。
实施例四：
抗静电剂组分按重量份数包括乙氧基化烷基胺18份、聚乙二醇环氧甘油醚14份、聚碳酸酯11份、聚醚酯酰胺9份、炭纳米管8份、石墨烯5份、柠檬酸钠10份、硅藻土10份、氧化聚乙烯蜡13份和抗菌剂3份。
本实施例中，抗菌剂由30％十二烷基-二甲基-苄基氯化铵、20％微晶高岭石粉、20％氟硅烷偶联剂、15％介孔纳米二氧化钛、15％介孔纳米三氧化二铝制成。
本实施例的制备方法包括以下步骤：
A、将乙氧基化烷基胺、聚乙二醇环氧甘油醚、聚碳酸酯、聚醚酯酰胺混合后加入搅拌罐中低速搅拌，得到混合液A；
B、、将炭纳米管、石墨烯、柠檬酸钠、硅藻土、氧化聚乙烯蜡混合后加入搅拌釜中加热搅拌，得到混合液B；
C、将混合物A和混合物B混合后加入加热罐中加热反应，得到混合液C；
D、在混合液C中加入抗菌剂，在常温下充分搅拌混合，即得到抗静电剂。
本实施例中，步骤A中搅拌速率为350转/分，时间为35min。
本实施例中，步骤B中搅拌温度为88℃，搅拌速率为1300转/分，时间为38min。
本实施例中，步骤C中加热温度为45℃，时间为14min。
实施例五：
抗静电剂组分按重量份数包括乙氧基化烷基胺15份、聚乙二醇环氧甘油醚10份、聚碳酸酯9份、聚醚酯酰胺7份、炭纳米管6份、石墨烯4份、柠檬酸钠9份、硅藻土8份、氧化聚乙烯蜡10份和抗菌剂3份。
本实施例中，抗菌剂由30％十二烷基-二甲基-苄基氯化铵、20％微晶高岭石粉、20％氟硅烷偶联剂、15％介孔纳米二氧化钛、15％介孔纳米三氧化二铝制成。
本实施例的制备方法包括以下步骤：
A、将乙氧基化烷基胺、聚乙二醇环氧甘油醚、聚碳酸酯、聚醚酯酰胺混合后加入搅拌罐中低速搅拌，得到混合液A；
B、、将炭纳米管、石墨烯、柠檬酸钠、硅藻土、氧化聚乙烯蜡混合后加入搅拌釜中加热搅拌，得到混合液B；
C、将混合物A和混合物B混合后加入加热罐中加热反应，得到混合液C；
D、在混合液C中加入抗菌剂，在常温下充分搅拌混合，即得到抗静电剂。
本实施例中，步骤A中搅拌速率为300转/分，时间为30min。
本实施例中，步骤B中搅拌温度为85℃，搅拌速率为1200转/分，时间为30min-40min。
本实施例中，步骤C中加热温度为50℃，时间为15min。
实验例：
采用本发明各实施例制得的抗静电剂进行性能测试，得到数据如下表：
Figure BDA0003100083890000061
Figure BDA0003100083890000071
综上所述，本发明制备方法简单，制得的抗静电剂无毒无害，具有优异的抗静电和导电性能，而且还具有优异的抑菌和抗菌性能，使用后不但能显著提高涤纶织物的抗静电性能，抗静电持久，而且对皮肤无刺激，健康安全。其中，本发明中添加的聚醚酯酰胺、炭纳米管、石墨烯，能够使聚合物表面电阻降低至107-109ohm/cm2。大大优于规定的指标1.9×1011ohm/cm2；此外，本发明添加的抗菌剂抑菌时间长，且不会损伤织物。
尽管已经示出和描述了本发明的实施例，对于本领域的普通技术人员而言，可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的范围由所附权利要求及其等同物限定。

Claims (7)

1.一种高稳定性表面活性剂型复合抗静电剂,其特征在于：抗静电剂组分按重量份数包括乙氧基化烷基胺10-20份、聚乙二醇环氧甘油醚5-15份、聚碳酸酯6-12份、聚醚酯酰胺4-10份、炭纳米管3-9份、石墨烯2-6份、柠檬酸钠5-12份、硅藻土4-12份、氧化聚乙烯蜡7-14份和抗菌剂2-4份。
2.根据权利要求1所述的一种高稳定性表面活性剂型复合抗静电剂,其特征在于：抗静电剂组分优选的成分配比包括乙氧基化烷基胺15份、聚乙二醇环氧甘油醚10份、聚碳酸酯9份、聚醚酯酰胺7份、炭纳米管6份、石墨烯4份、柠檬酸钠9份、硅藻土8份、氧化聚乙烯蜡10份和抗菌剂3份。
3.根据权利要求1所述的一种高稳定性表面活性剂型复合抗静电剂,其特征在于：所述抗菌剂由30％十二烷基-二甲基-苄基氯化铵、20％微晶高岭石粉、20％氟硅烷偶联剂、15％介孔纳米二氧化钛、15％介孔纳米三氧化二铝制成。
4.实现权利要求1所述的一种高稳定性表面活性剂型复合抗静电剂的制备方法,其特征在于：制备方法包括以下步骤：
A、将乙氧基化烷基胺、聚乙二醇环氧甘油醚、聚碳酸酯、聚醚酯酰胺混合后加入搅拌罐中低速搅拌，得到混合液A；
B、、将炭纳米管、石墨烯、柠檬酸钠、硅藻土、氧化聚乙烯蜡混合后加入搅拌釜中加热搅拌，得到混合液B；
C、将混合物A和混合物B混合后加入加热罐中加热反应，得到混合液C；
D、在混合液C中加入抗菌剂，在常温下充分搅拌混合，即得到抗静电剂。
5.根据权利要求4所述的一种高稳定性表面活性剂型复合抗静电剂的制备方法,其特征在于：所述步骤A中搅拌速率为200-400转/分，时间为20min-40min。
6.根据权利要求4所述的一种高稳定性表面活性剂型复合抗静电剂的制备方法,其特征在于：所述步骤B中搅拌温度为80-90℃，搅拌速率为1000-1400转/分，时间为30min-40min。
7.根据权利要求4所述的一种高稳定性表面活性剂型复合抗静电剂的制备方法,其特征在于：所述步骤C中加热温度为40-60℃，时间为10min-20min。
CN202110622554.5A 2021-06-03 2021-06-03 一种高稳定性表面活性剂型复合抗静电剂 Pending CN113136725A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110622554.5A CN113136725A (zh) 2021-06-03 2021-06-03 一种高稳定性表面活性剂型复合抗静电剂

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110622554.5A CN113136725A (zh) 2021-06-03 2021-06-03 一种高稳定性表面活性剂型复合抗静电剂

Publications (1)

Publication Number Publication Date
CN113136725A true CN113136725A (zh) 2021-07-20

Family

ID=76816079

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110622554.5A Pending CN113136725A (zh) 2021-06-03 2021-06-03 一种高稳定性表面活性剂型复合抗静电剂

Country Status (1)

Country Link
CN (1) CN113136725A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112457672A (zh) * 2020-11-27 2021-03-09 合肥艺光高分子材料科技有限公司 一种抗静电发泡硅胶板组合物及发泡硅胶板生产方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104878597A (zh) * 2015-06-12 2015-09-02 张萍 一种织物抗静电剂
CN107603315A (zh) * 2017-09-22 2018-01-19 赵兰敏 儿童自行车专用复合抗菌涂料与复合抗菌剂及复合抗菌剂的制备方法
CN107687092A (zh) * 2017-08-15 2018-02-13 江苏新瑞贝科技股份有限公司 一种织物抗静电剂的制备方法
CN109401271A (zh) * 2018-10-12 2019-03-01 江门宇度科技有限责任公司 一种抗静电、导电增进剂及其制备方法
CN110938327A (zh) * 2019-12-13 2020-03-31 上海烯古能源科技有限公司 抗静电涂料及其制备方法和应用
CN111139570A (zh) * 2019-12-31 2020-05-12 宁波太平鸟时尚服饰创意研究院有限公司 一种抗静电针织面料

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104878597A (zh) * 2015-06-12 2015-09-02 张萍 一种织物抗静电剂
CN107687092A (zh) * 2017-08-15 2018-02-13 江苏新瑞贝科技股份有限公司 一种织物抗静电剂的制备方法
CN107603315A (zh) * 2017-09-22 2018-01-19 赵兰敏 儿童自行车专用复合抗菌涂料与复合抗菌剂及复合抗菌剂的制备方法
CN109401271A (zh) * 2018-10-12 2019-03-01 江门宇度科技有限责任公司 一种抗静电、导电增进剂及其制备方法
CN110938327A (zh) * 2019-12-13 2020-03-31 上海烯古能源科技有限公司 抗静电涂料及其制备方法和应用
CN111139570A (zh) * 2019-12-31 2020-05-12 宁波太平鸟时尚服饰创意研究院有限公司 一种抗静电针织面料

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王钰等: "《塑料改性实用技术与应用》", 30 June 2014 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112457672A (zh) * 2020-11-27 2021-03-09 合肥艺光高分子材料科技有限公司 一种抗静电发泡硅胶板组合物及发泡硅胶板生产方法

Similar Documents

Publication Publication Date Title
CN113136725A (zh) 一种高稳定性表面活性剂型复合抗静电剂
CN110898371A (zh) 一种森林灭火用的绿色环保水凝胶灭火剂及其制备方法
CN103463790A (zh) 耐海水型抗溶性水成膜泡沫灭火剂及其制备方法
CN102294105A (zh) 新型抗溶性水成膜泡沫灭火剂的制备方法
WO2012075073A2 (en) Play composition including crosslinkable binder
CN110041636A (zh) 一种无卤阻燃抗静电木塑复合材料及其制备方法
CN107779073A (zh) 一种耐热水性木器漆
CN109735049A (zh) 一种改性勃姆石无卤阻燃abs复合材料及其制备方法
CN110358141B (zh) 一种难燃高分子材料的制备方法
CN109320968B (zh) 一种复合型永久抗静电剂及其应用
CN103073982A (zh) 一种建筑玻璃用耐划伤性透明隔热涂料的制备方法
CN112341926B (zh) 一种红外隐身纺织涂料及其制备方法
CN114230805A (zh) 一种有机聚合物阻燃剂、水性防火阻燃涂料及其制备方法
CN109280259A (zh) 一种分布调控添加有ommt的eva/pa6阻燃复合材料及制备方法
CN111849296A (zh) 一种低碳环保防腐涂料及其制备方法
CN112521857A (zh) 一种高强度非固化沥青防水涂料及其制备方法
CN111234598A (zh) 一种耐醇阻燃油墨
CN110812765A (zh) 一种高分子凝胶超浓缩灭火剂及制备方法
CN112011267B (zh) 一种保温隔热涂料及其制备方法
CN114832267A (zh) 一种防冻型泡沫灭火剂及其制备方法
CN110421941B (zh) 一种保温防护服用的电加热面料
CN112921668A (zh) 一种石墨烯覆膜无纺布及其制备方法
CN111518429A (zh) 一种用于涂料的抗菌杀菌材料及其制备方法和应用
CN108484849B (zh) 一种离子聚合物抗静电剂及其制备方法
CN103788391B (zh) 一种家具防尘膜及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20210720