CN107686336A - A kind of high-ductility clay based on basalt fibre - Google Patents
A kind of high-ductility clay based on basalt fibre Download PDFInfo
- Publication number
- CN107686336A CN107686336A CN201710782201.5A CN201710782201A CN107686336A CN 107686336 A CN107686336 A CN 107686336A CN 201710782201 A CN201710782201 A CN 201710782201A CN 107686336 A CN107686336 A CN 107686336A
- Authority
- CN
- China
- Prior art keywords
- parts
- basalt fibre
- clay
- ductility
- polyvinylpyrrolidone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/36—Reinforced clay-wares
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/1305—Organic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3804—Borides
- C04B2235/3813—Refractory metal borides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/38—Non-oxide ceramic constituents or additives
- C04B2235/3817—Carbides
- C04B2235/3839—Refractory metal carbides
- C04B2235/3843—Titanium carbides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5216—Inorganic
- C04B2235/522—Oxidic
- C04B2235/5228—Silica and alumina, including aluminosilicates, e.g. mullite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The present invention provides a kind of high-ductility clay based on basalt fibre, belongs to technical field of ceramic material, and it consists of composition and formed by certain mass fraction：10 20 parts of titanium carbide, 30 40 parts of kaolinite, 25 35 parts of quartz, 0 30 parts of montmorillonite 2,10 15 parts of basalt fibre, 10 16 parts of zirconium boride, 5 10 parts of polyvinylpyrrolidone, one of the matrix material of titanium carbide as clay is with the addition of in the clay formula of routine, and it with the addition of basalt fibre and polyvinylpyrrolidone, clay formula is improved using the stability property of a variety of excellent properties combination titanium carbides such as basalt fibre high intensity, corrosion-resistant, high temperature resistant, makes it have higher toughness.
Description
Technical field
The invention belongs to technical field of ceramic material, more particularly to a kind of high-ductility clay based on basalt fibre.
Background technology
Pottery, it is the utensil fired with clay or clay after kneading shapes.Pottery is with a long history, in the Neolithic Age
The generation just pottery of first meeting simple coarse.Pottery is used as a kind of daily necessities in ancient times, is typically now being used as handicraft to collect.
But in order to retain traditional flavor, also there is part occasion to be adapted to, using pottery container, such as make tea.Common makes tea
With with dark-red enameled pottery, dark-red enameled pottery falls within one kind of pottery, but due to lack of material and the result of market competition, at present boccaro
Kettle holds at high price.It can actually be compared favourably using the effect of tea making of the common clay such as kaolinite with boccaro, but common pottery
Pottery made by soil, pottery pot etc. of particularly heating up water need to receive the pottery of charcoal fire baking, and itself toughness to pottery has one
Fixed requirement, but present pottery toughness deficiency, easily cracking, causes service life to be greatly reduced, and also have impact on using effect
Fruit and the outward appearance of pottery.
The content of the invention
Above mentioned problem is had based on prior art, the present invention provides a kind of high-ductility clay based on basalt fibre, its
One of the matrix material of titanium carbide as clay is with the addition of in conventional clay formula, and with the addition of basalt fibre and polyethylene
Pyrrolidones, utilize the stability property of a variety of excellent properties combination titanium carbides such as basalt fibre high intensity, corrosion-resistant, high temperature resistant
Clay formula is improved, makes it have higher toughness.
The present invention achieves the goal by the following technical programs：
A kind of high-ductility clay based on basalt fibre, it consists of composition and formed by certain mass fraction：Titanium carbide
10-20 parts, kaolinite 30-40 parts, quartzy 25-35 parts, montmorillonite 2 0-30 parts, basalt fibre 10-15 parts, zirconium boride 10-16
Part, polyvinylpyrrolidone 5-10 parts.
Preferably, it consists of composition and formed by certain mass fraction：Titanium carbide 14-16 parts, kaolinite 32-36
Part, quartzy 28-32 parts, montmorillonite 2 4-36 parts, basalt fibre 12-14 parts, zirconium boride 12-14 parts, polyvinylpyrrolidone 6-
8 parts.
Preferably, it consists of composition and formed by certain mass fraction：15 parts of titanium carbide, 34 parts of kaolinite, stone
30 parts of English, 30 parts of montmorillonite, 13 parts of basalt fibre, 13 parts of zirconium boride, 7 parts of polyvinylpyrrolidone.
Preferably, described basalt fibre is modified through peracetic acid, and method of modifying is：CH3COOH using 2 mol/L is molten
The h of basalt fibre 1.5 is soaked in liquid.
A kind of preparation method of high-ductility clay as described in claim 1-4, it comprises the following steps：
Step S10, titanium carbide, kaolinite, quartz, montmorillonite and zirconium boride are added to running water mediation after crushing；
Step S20, by basalt fibre using the h of basalt fibre 1.5 is soaked in 2 mol/L CH3COOH solution, take out and use
Clear water is rinsed to neutrality, then basalt fibre and polyvinylpyrrolidone are mixed；
Material obtained by step S30, step S10 and step S20 is well mixed, and produces high-ductility clay.
The device have the advantages that：Basalt fibre has high intensity, high-modulus and excellent high-temperature oxidation
The characteristics of, produce ceramics and transfer to effect, crack deflection, so as to improve the fracture toughness of clay；The life of other basalt fibre
Production. art determines that caused discarded object is few, and environmental pollution is small, and directly can be degraded in the environment after product abandonment, without any
Harm；Basalt fibre is modified with reference to polyvinylpyrrolidone through peracetic acid, fiber is preferably bonded with clay matrix.
Embodiment
With reference to specific embodiment, the invention will be further described.
Embodiment one：
A kind of high-ductility clay based on basalt fibre, it consists of composition and formed by certain mass fraction：Titanium carbide
10 parts, 30 parts of kaolinite, 25 parts of quartz, 0 part of montmorillonite 2,10 parts of basalt fibre, 10 parts of zirconium boride, polyvinylpyrrolidone 5
Part.
As the presently preferred embodiments, described basalt fibre is modified through peracetic acid, and method of modifying is：Use 2 mol/L's
The h of basalt fibre 1.5 is soaked in CH3COOH solution.
High-ductility clay is made by step once in above-mentioned material：
Step S10, titanium carbide, kaolinite, quartz, montmorillonite and zirconium boride are added to running water mediation after crushing；
Step S20, by basalt fibre using the h of basalt fibre 1.5 is soaked in 2 mol/L CH3COOH solution, take out and use
Clear water is rinsed to neutrality, then basalt fibre and polyvinylpyrrolidone are mixed；
Material obtained by step S30, step S10 and step S20 is well mixed, and produces high-ductility clay.
There is higher toughness and longer service life using pottery made of clay provided by the invention.
Embodiment two：
A kind of high-ductility clay based on basalt fibre, it consists of composition and formed by certain mass fraction：Titanium carbide
20 parts, 40 parts of kaolinite, 35 parts of quartz, 30 parts of montmorillonite, 15 parts of basalt fibre, 16 parts of zirconium boride, polyvinylpyrrolidone
10 parts.
As the presently preferred embodiments, described basalt fibre is modified through peracetic acid, and method of modifying is：Use 2 mol/L's
The h of basalt fibre 1.5 is soaked in CH3COOH solution.
High-ductility clay is made by step once in above-mentioned material：
Step S10, titanium carbide, kaolinite, quartz, montmorillonite and zirconium boride are added to running water mediation after crushing；
Step S20, by basalt fibre using the h of basalt fibre 1.5 is soaked in 2 mol/L CH3COOH solution, take out and use
Clear water is rinsed to neutrality, then basalt fibre and polyvinylpyrrolidone are mixed；
Material obtained by step S30, step S10 and step S20 is well mixed, and produces high-ductility clay.
There is higher toughness and longer service life using pottery made of clay provided by the invention.
Embodiment three：
A kind of high-ductility clay based on basalt fibre, it consists of composition and formed by certain mass fraction：Titanium carbide
14 parts, 32 parts of kaolinite, 28 parts of quartz, 4 parts of montmorillonite 2,12 parts of basalt fibre, 12 parts of zirconium boride, polyvinylpyrrolidone 6
Part.
As the presently preferred embodiments, described basalt fibre is modified through peracetic acid, and method of modifying is：Use 2 mol/L's
The h of basalt fibre 1.5 is soaked in CH3COOH solution.
High-ductility clay is made by step once in above-mentioned material：
Step S10, titanium carbide, kaolinite, quartz, montmorillonite and zirconium boride are added to running water mediation after crushing；
Step S20, by basalt fibre using the h of basalt fibre 1.5 is soaked in 2 mol/L CH3COOH solution, take out and use
Clear water is rinsed to neutrality, then basalt fibre and polyvinylpyrrolidone are mixed；
Material obtained by step S30, step S10 and step S20 is well mixed, and produces high-ductility clay.
There is higher toughness and longer service life using pottery made of clay provided by the invention.
Example IV：
A kind of high-ductility clay based on basalt fibre, it consists of composition and formed by certain mass fraction：Titanium carbide
14-16 parts, 36 parts of kaolinite, 32 parts of quartz, 36 parts of montmorillonite, 14 parts of basalt fibre, 14 parts of zirconium boride, polyvinylpyrrolidine
8 parts of ketone.
As the presently preferred embodiments, described basalt fibre is modified through peracetic acid, and method of modifying is：Use 2 mol/L's
The h of basalt fibre 1.5 is soaked in CH3COOH solution.
High-ductility clay is made by step once in above-mentioned material：
Step S10, titanium carbide, kaolinite, quartz, montmorillonite and zirconium boride are added to running water mediation after crushing；
Step S20, by basalt fibre using the h of basalt fibre 1.5 is soaked in 2 mol/L CH3COOH solution, take out and use
Clear water is rinsed to neutrality, then basalt fibre and polyvinylpyrrolidone are mixed；
Material obtained by step S30, step S10 and step S20 is well mixed, and produces high-ductility clay.
There is higher toughness and longer service life using pottery made of clay provided by the invention.
Embodiment five：
A kind of high-ductility clay based on basalt fibre, it consists of composition and formed by certain mass fraction：Titanium carbide
15 parts, 34 parts of kaolinite, 30 parts of quartz, 30 parts of montmorillonite, 13 parts of basalt fibre, 13 parts of zirconium boride, polyvinylpyrrolidone 7
Part.
As the presently preferred embodiments, described basalt fibre is modified through peracetic acid, and method of modifying is：Use 2 mol/L's
The h of basalt fibre 1.5 is soaked in CH3COOH solution.
High-ductility clay is made by step once in above-mentioned material：
Step S10, titanium carbide, kaolinite, quartz, montmorillonite and zirconium boride are added to running water mediation after crushing；
Step S20, by basalt fibre using the h of basalt fibre 1.5 is soaked in 2 mol/L CH3COOH solution, take out and use
Clear water is rinsed to neutrality, then basalt fibre and polyvinylpyrrolidone are mixed；
Material obtained by step S30, step S10 and step S20 is well mixed, and produces high-ductility clay.
There is higher toughness and longer service life using pottery made of clay provided by the invention.
Embodiment described above only expresses the several embodiments of the present invention, and its description is more specific and detailed, but simultaneously
Therefore the limitation to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that for one of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the guarantor of the present invention
Protect scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (5)
1. a kind of high-ductility clay based on basalt fibre, its spy is being, it consists of composition by certain quality point
Array into：Titanium carbide 10-20 parts, kaolinite 30-40 parts, quartzy 25-35 parts, montmorillonite 2 0-30 parts, basalt fibre 10-15
Part, zirconium boride 10-16 parts, polyvinylpyrrolidone 5-10 parts.
2. a kind of high-ductility clay based on basalt fibre according to claim 1, it is characterised in that it is consisted of
Composition is formed by certain mass fraction：Titanium carbide 14-16 parts, kaolinite 32-36 parts, quartzy 28-32 parts, montmorillonite 2 4-36
Part, basalt fibre 12-14 parts, zirconium boride 12-14 parts, polyvinylpyrrolidone 6-8 parts.
3. a kind of high-ductility clay based on basalt fibre according to claim 2, it is characterised in that it is consisted of
Composition is formed by certain mass fraction：15 parts of titanium carbide, 34 parts of kaolinite, 30 parts of quartz, 30 parts of montmorillonite, basalt fibre
13 parts, 13 parts of zirconium boride, 7 parts of polyvinylpyrrolidone.
4. according to a kind of any described high-ductility clay based on basalt fibre of claim 1-3, it is characterised in that described
Basalt fibre be modified through peracetic acid, method of modifying is：Using soaking basalt fibre in 2 mol/L CH3COOH solution
1.5 h。
5. the preparation method of a kind of high-ductility clay as described in claim 1-4, it is characterised in that it comprises the following steps：
Step S10, titanium carbide, kaolinite, quartz, montmorillonite and zirconium boride are added to running water mediation after crushing；
Step S20, by basalt fibre using the h of basalt fibre 1.5 is soaked in 2 mol/L CH3COOH solution, take out and use
Clear water is rinsed to neutrality, then basalt fibre and polyvinylpyrrolidone are mixed；
Material obtained by step S30, step S10 and step S20 is well mixed, and produces high-ductility clay.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710782201.5A CN107686336A (en) | 2017-09-02 | 2017-09-02 | A kind of high-ductility clay based on basalt fibre |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710782201.5A CN107686336A (en) | 2017-09-02 | 2017-09-02 | A kind of high-ductility clay based on basalt fibre |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107686336A true CN107686336A (en) | 2018-02-13 |
Family
ID=61155039
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710782201.5A Pending CN107686336A (en) | 2017-09-02 | 2017-09-02 | A kind of high-ductility clay based on basalt fibre |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107686336A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115044079A (en) * | 2022-06-30 | 2022-09-13 | 陕西科技大学 | Aramid nanofiber doped basalt nanosheet composite insulating film and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102701770A (en) * | 2012-03-27 | 2012-10-03 | 郭丰亮 | Continuous basalt fiber reinforced ceramic composite and preparation method for same |
| CN107056247A (en) * | 2016-12-21 | 2017-08-18 | 周易 | A kind of high tenacity ceramic material and preparation method thereof |
-
2017
- 2017-09-02 CN CN201710782201.5A patent/CN107686336A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102701770A (en) * | 2012-03-27 | 2012-10-03 | 郭丰亮 | Continuous basalt fiber reinforced ceramic composite and preparation method for same |
| CN107056247A (en) * | 2016-12-21 | 2017-08-18 | 周易 | A kind of high tenacity ceramic material and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 杨保祥等: "《钛基材料制造》", 31 January 2015, 冶金工业出版社 * |
| 颜贵龙: "玄武岩纤维表面改性研究", 《铜牛杯第九届功能性纺织品及纳米技术研讨会论文集》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115044079A (en) * | 2022-06-30 | 2022-09-13 | 陕西科技大学 | Aramid nanofiber doped basalt nanosheet composite insulating film and preparation method thereof |
| CN115044079B (en) * | 2022-06-30 | 2023-08-18 | 陕西科技大学 | Aramid nanofiber doped basalt nanosheet composite insulating film and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1765836B (en) | Ceramic glaze with metal sense of reality | |
| CN107011792A (en) | A kind of antibacterial wearable ceramic coat of non-stick pan and preparation method thereof | |
| CN104150863A (en) | Beautifully colored red mud ceramic tableware | |
| CN107686336A (en) | A kind of high-ductility clay based on basalt fibre | |
| CN107118688A (en) | A kind of heating pipe of water heater high-temperature resistant coating and preparation method thereof | |
| CN102286350A (en) | Dendrobium devonianum flower wine and preparation method thereof | |
| CN108726878A (en) | A kind of high cold-resistant thermal shock ceramic glaze, ceramic body and preparation method thereof | |
| CN107382065B (en) | Celadon secret color glaze and preparation method thereof and secret color glazed porcelain | |
| CN110330310B (en) | Preparation method of high-strength crack household porcelain | |
| CN103086603B (en) | Colored glass ceramic for manufacturing dental prosthesis and preparation method for colored glass ceramic | |
| CN105439641B (en) | Golden yellow crow drop reduction furnace transmutation glaze and the golden yellow crow drop reduction transmutation glazed pottery ceramic products and preparation method with its preparation | |
| CN107043214A (en) | Brownish black floor iron red colored crystalline point ceramic glaze and the method using its preparation ceramics | |
| CN107804994A (en) | A kind of preparation method of cracking resistance artificial quartz stone plate | |
| CN115894084B (en) | Texalized high-whiteness porcelain decorated by tortoise back texture and preparation process thereof | |
| CN103803987B (en) | Additive suitable for magnesium household porcelain and application method thereof | |
| CN107255012B (en) | Fire-proof and thermal-insulation pine Solid Door | |
| CN104803696A (en) | High-strength carbon fiber enhanced silicon nitride ceramic matrix composite and preparation method thereof | |
| CN104944907B (en) | A kind of glazed tiles utilizing Suzhou soil to prepare | |
| CN106221579B (en) | With bright pearl effect high intensity exterior coating and preparation method | |
| CN110218081A (en) | A kind of manufacturing method of enamel effect ceramics | |
| CN1765817A (en) | Green glaze ink color ceramics production method | |
| CN107827395A (en) | A kind of cracking resistance artificial quartz stone plate | |
| CN103864300A (en) | Milk white optical glass composition | |
| CN113402302A (en) | Dyeing material, preparation method thereof and application thereof to zirconium dioxide all-ceramic tooth | |
| CN107686337A (en) | A kind of toughness reinforcing clay based on particulate reinforcement technology |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180213 |