CN107827395A - A kind of cracking resistance artificial quartz stone plate - Google Patents

A kind of cracking resistance artificial quartz stone plate Download PDF

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Publication number
CN107827395A
CN107827395A CN201711080533.5A CN201711080533A CN107827395A CN 107827395 A CN107827395 A CN 107827395A CN 201711080533 A CN201711080533 A CN 201711080533A CN 107827395 A CN107827395 A CN 107827395A
Authority
CN
China
Prior art keywords
parts
artificial quartz
stone plate
quartz stone
cracking resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711080533.5A
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Chinese (zh)
Inventor
陆顺欢
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan City Opal Stone Industry Co Ltd
Original Assignee
Foshan City Opal Stone Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan City Opal Stone Industry Co Ltd filed Critical Foshan City Opal Stone Industry Co Ltd
Priority to CN201711080533.5A priority Critical patent/CN107827395A/en
Publication of CN107827395A publication Critical patent/CN107827395A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/18Polyesters; Polycarbonates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54Substitutes for natural stone, artistic materials or the like
    • C04B2111/542Artificial natural stone
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80Optical properties, e.g. transparency or reflexibility
    • C04B2111/82Coloured materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Macromonomer-Based Addition Polymer (AREA)

Abstract

The invention discloses a kind of cracking resistance artificial quartz stone plate, and it is prepared by the raw material of following parts by weight:20 25 parts of quartz sand, 18 35 parts of silica flour, 0.2 0.3 parts of nano silicon, 26 parts of wood fibre, 8 10 parts of unsaturated polyester resin, 12 parts of curing agent, 0.2 3 parts of γ aminopropyl triethoxysilanes, 0.2 0.3 parts of pigment, its solid content >=72% of the unsaturated polyester resin, viscosity are 1.3 1.6Pas(25℃), acid number is 18 20mgKOH/g.The artificial quartz stone plate of the present invention, which has, solves the problems such as artificial quartz in lump cracking, deformation.The artificial quartz stone plate of the present invention is unlikely to deform, ftractures, bubbles, fades, tarnished, low with production cost, good decorating effect, indeformable feature.

Description

A kind of cracking resistance artificial quartz stone plate
Technical field
The present invention relates to building decoration technology field, more particularly to a kind of cracking resistance artificial quartz stone plate.
Background technology
Artificial quartz in lump(Or Buddha's warrior attendant/hard rock)Cradle is cried when entering Chinese within 2005 and matches sharp stone in Spain, After artificial quartz in lump is approved by increasing consumer, China in 2006 starts someone and researches and develops artificial quartz in lump, 2007 Year successively has many producers to be proposed domestic artificial quartz in lump.Artificial quartz in lump is as new Artificial construction material, moistureproof, anti- Acid, spelling property etc. have the advantages of lithotome is incomparable.In natural stone resource increasingly exhausted today, artificial stone Diamond stone is its best substitute.Meanwhile artificial quartz in lump can make raw material using discarded glass, thus while environmental protection Resource reutilization is realized, these advantages allow artificial quartz in lump to turn into the upstart of architectural decoration, therefore, are widely used in The public buildings such as hotel, dining room, bank, hospital, exhibition, laboratory and kitchen countertop, commode, kitchen and bath's metope, dining table, tea The house decoration such as several, windowsill, door pocket field.
However, artificial quartz in lump of the prior art also has the shortcomings that its is intrinsic, for example, it is easily cracking.
The content of the invention
The defects of in order to make up prior art, the present invention provide a kind of cracking resistance artificial quartz stone plate.
The technical problems to be solved by the invention are achieved by the following technical programs:
A kind of cracking resistance artificial quartz stone plate, it is prepared by the raw material of following parts by weight:Quartz sand 20-25 parts, silica flour 18-35 parts, nano silicon 0.2-0.3 parts, wood fibre 2-6 parts, unsaturated polyester resin 8-10 parts, curing agent 1-2 parts, Gamma-aminopropyl-triethoxy-silane 0.2-3 parts, pigment 0.2-0.3 parts, its solid content >=72% of the unsaturated polyester resin, stick Spend for 1.3-1.6Pas(25℃), acid number 18-20mgKOH/g.
The nano silicon that the present invention uses is added in quartzite slate, can play a part of nano particle, can Improve the toughness of quartzite slate.
Further, the curing agent is peroxidating(2 ethyl hexanoic acid)The tert-butyl ester, methyl ethyl ketone peroxide, benzoyl peroxide first Combination more than one or both of tert-butyl acrylate or fat polyamine.
Further, the pigment is titanium white, iron oxide yellow, iron oxide red, barba hispanica, cadmium red, cadmium yellow, carbon black, iron oxide black, azophosphine, phthalein One or more in dark green and phthalocyanine blue.
The present invention has the advantages that:
(1)The artificial quartz stone plate of the present invention, which has, solves the problems such as artificial quartz in lump cracking, deformation.
(2)The artificial quartz stone plate of the present invention is unlikely to deform, ftractures, bubbles, fades, tarnished, and has production Cost is low, good decorating effect, indeformable feature.
Embodiment
With reference to embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention, It is not limitation of the invention.
Embodiment 1
A kind of cracking resistance artificial quartz stone plate, it is prepared by the raw material of following parts by weight:22 parts of quartz sand, silica flour 25 Part, 0.2 part of nano silicon, 4 parts of wood fibre, 9 parts of unsaturated polyester resin, 1 part of curing agent, the ethoxy of γ-aminopropyl three 1.5 parts of base silane, 0.2 part of pigment, its solid content >=72% of the unsaturated polyester resin, viscosity 1.3-1.6Pas(25 ℃), acid number 18-20mgKOH/g;Wherein described curing agent is peroxidating(2 ethyl hexanoic acid)The tert-butyl ester;The pigment is titanium In vain.
Embodiment 2
A kind of cracking resistance artificial quartz stone plate, it is prepared by the raw material of following parts by weight:20 parts of quartz sand, silica flour 35 Part, 0.2 part of nano silicon, 2 parts of wood fibre, 8 parts of unsaturated polyester resin, 1 part of curing agent, the ethoxy of γ-aminopropyl three 0.2 part of base silane, 0.2 part of pigment, its solid content >=72% of the unsaturated polyester resin, viscosity 1.3-1.6Pas(25 ℃), acid number 18-20mgKOH/g;Wherein described curing agent is methyl ethyl ketone peroxide;The pigment is cadmium red.
Embodiment 3
A kind of cracking resistance artificial quartz stone plate, it is prepared by the raw material of following parts by weight:25 parts of quartz sand, silica flour 18 Part, 0.3 part of nano silicon, 6 parts of wood fibre, 10 parts of unsaturated polyester resin, 2 parts of curing agent, the ethoxy of γ-aminopropyl three 3 parts of base silane, 0.3 part of pigment, its solid content >=72% of the unsaturated polyester resin, viscosity 1.3-1.6Pas(25℃), Acid number is 18-20mgKOH/g;Wherein described curing agent is combination more than one or both of fat polyamine;The face Expect for azophosphine.
Embodiment described above only expresses embodiments of the present invention, and its description is more specific and detailed, but can not Therefore the limitation to the scope of the claims of the present invention is interpreted as, as long as the skill obtained using the form of equivalent substitution or equivalent transformation Art scheme, it all should fall within the scope and spirit of the invention.

Claims (3)

1. a kind of cracking resistance artificial quartz stone plate, it is characterised in that it is prepared by the raw material of following parts by weight:Quartz sand 20-25 parts, silica flour 18-35 parts, nano silicon 0.2-0.3 parts, wood fibre 2-6 parts, unsaturated polyester resin 8-10 Part, curing agent 1-2 parts, gamma-aminopropyl-triethoxy-silane 0.2-3 parts, pigment 0.2-0.3 parts, the unsaturated polyester resin Its solid content >=72%, viscosity 1.3-1.6Pas(25℃), acid number 18-20mgKOH/g.
2. cracking resistance artificial quartz stone plate as claimed in claim 1, it is characterised in that the curing agent is peroxidating(2- ethyls Caproic acid)More than one or both of the tert-butyl ester, methyl ethyl ketone peroxide, peroxidized t-butyl perbenzoate or fat polyamine Combination.
3. cracking resistance artificial quartz stone plate as claimed in claim 1, it is characterised in that the pigment be titanium white, iron oxide yellow, iron oxide red, One or more in barba hispanica, cadmium red, cadmium yellow, carbon black, iron oxide black, azophosphine, dark green and phthalocyanine blue.
CN201711080533.5A 2017-11-06 2017-11-06 A kind of cracking resistance artificial quartz stone plate Pending CN107827395A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711080533.5A CN107827395A (en) 2017-11-06 2017-11-06 A kind of cracking resistance artificial quartz stone plate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711080533.5A CN107827395A (en) 2017-11-06 2017-11-06 A kind of cracking resistance artificial quartz stone plate

Publications (1)

Publication Number Publication Date
CN107827395A true CN107827395A (en) 2018-03-23

Family

ID=61653721

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711080533.5A Pending CN107827395A (en) 2017-11-06 2017-11-06 A kind of cracking resistance artificial quartz stone plate

Country Status (1)

Country Link
CN (1) CN107827395A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109020303A (en) * 2018-11-02 2018-12-18 广东雄杰建材有限公司 A kind of cracking resistance artificial quartz stone plate
CN112939515A (en) * 2020-12-25 2021-06-11 湖北赛典新材料科技有限公司 Manufacturing method of artificial quartz stone plate with good crack resistance

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102531468A (en) * 2012-01-16 2012-07-04 吉林吉瑞莱板材科技有限公司 Composite nano silicon dioxide/quartz stone plate product and preparation method thereof
CN104496271A (en) * 2014-12-15 2015-04-08 田忠和 Artificial quartzite plate and manufacturing method thereof
CN105819748A (en) * 2016-03-14 2016-08-03 广东中旗新材料科技有限公司 High strength artificial quartz stone sheet and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102531468A (en) * 2012-01-16 2012-07-04 吉林吉瑞莱板材科技有限公司 Composite nano silicon dioxide/quartz stone plate product and preparation method thereof
CN104496271A (en) * 2014-12-15 2015-04-08 田忠和 Artificial quartzite plate and manufacturing method thereof
CN105819748A (en) * 2016-03-14 2016-08-03 广东中旗新材料科技有限公司 High strength artificial quartz stone sheet and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109020303A (en) * 2018-11-02 2018-12-18 广东雄杰建材有限公司 A kind of cracking resistance artificial quartz stone plate
CN112939515A (en) * 2020-12-25 2021-06-11 湖北赛典新材料科技有限公司 Manufacturing method of artificial quartz stone plate with good crack resistance

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Application publication date: 20180323

RJ01 Rejection of invention patent application after publication