CN107686337A - A kind of toughness reinforcing clay based on particulate reinforcement technology - Google Patents

A kind of toughness reinforcing clay based on particulate reinforcement technology Download PDF

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Publication number
CN107686337A
CN107686337A CN201710782232.0A CN201710782232A CN107686337A CN 107686337 A CN107686337 A CN 107686337A CN 201710782232 A CN201710782232 A CN 201710782232A CN 107686337 A CN107686337 A CN 107686337A
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China
Prior art keywords
parts
carborundum
toughness reinforcing
particulate reinforcement
reinforcement technology
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CN201710782232.0A
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Chinese (zh)
Inventor
颜育文
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Foshan Jiayi Art Ceramic Research Co Ltd
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Foshan Jiayi Art Ceramic Research Co Ltd
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Priority to CN201710782232.0A priority Critical patent/CN107686337A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/36Reinforced clay-wares
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3804Borides
    • C04B2235/3813Refractory metal borides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3826Silicon carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3891Silicides, e.g. molybdenum disilicide, iron silicide

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Products (AREA)

Abstract

The present invention provides a kind of toughness reinforcing clay based on particulate reinforcement technology, belong to toughening ceramic technical field, it includes 30 40 parts of kaolinite, 25 35 parts of quartz, 20 30 parts of zirconium boride, 14 parts of carborundum, 48 parts of molybdenum disilicide, by the formula that have adjusted conventional clay, it with the addition of zirconium boride, carborundum and molybdenum disilicide, diffusing particle is used as by carborundum and molybdenum disilicide, add by the toughness of kaolinite, quartz and zirconium boride as the clay main body of main body, the pottery toughness for preparing it is higher, and service life is longer.

Description

A kind of toughness reinforcing clay based on particulate reinforcement technology
Technical field
The invention belongs to toughening ceramic technical field, more particularly to a kind of toughness reinforcing clay based on particulate reinforcement technology.
Background technology
Pottery, it is the utensil fired with clay or clay after kneading shapes.Pottery is with a long history, in the Neolithic Age The generation just pottery of first meeting simple coarse.Pottery is used as a kind of daily necessities in ancient times, is typically now being used as handicraft to collect.
But in order to retain traditional flavor, also there is part occasion to be adapted to, using pottery container, such as make tea.Common makes tea With with dark-red enameled pottery, dark-red enameled pottery falls within one kind of pottery, but due to lack of material and the result of market competition, at present boccaro Kettle holds at high price.It can actually be compared favourably using the effect of tea making of the common clay such as kaolinite with boccaro, but common pottery Pottery made by soil, pottery pot etc. of particularly heating up water need to receive the pottery of charcoal fire baking, and itself toughness to pottery has one Fixed requirement, but present pottery toughness deficiency, easily cracking, causes service life to be greatly reduced, and also have impact on using effect Fruit and the outward appearance of pottery.
The content of the invention
Above mentioned problem is had based on prior art, the present invention provides a kind of toughness reinforcing clay based on particulate reinforcement technology, leads to The formula that have adjusted conventional clay is crossed, zirconium boride, carborundum and molybdenum disilicide is with the addition of, is used as by carborundum and molybdenum disilicide Diffusing particle, it is tough to add the pottery for by the toughness of kaolinite, quartz and zirconium boride as the clay main body of main body preparing, it Property is higher, and service life is longer.
The present invention is achieved the goal by technical scheme in detailed below:
A kind of toughness reinforcing clay based on particulate reinforcement technology, it consists of composition and formed by certain mass fraction:Kaolinite Stone 30-40 parts, quartzy 25-35 parts, zirconium boride 20-30 parts, carborundum 1-4 parts, molybdenum disilicide 4-8 parts.
Preferably, it consists of composition and formed by certain mass fraction:Kaolinite 34-38 parts, quartzy 28-32 Part, zirconium boride 24-26 parts, carborundum 2-3 parts, molybdenum disilicide 5-7 parts.
Preferably, it consists of composition and formed by certain mass fraction:36 parts of kaolinite, quartzy 30 parts, boronation 25 parts of zirconium, 2.5 parts of carborundum, 6 parts of molybdenum disilicide.
Preferably, its sintering temperature is 2000-2200 DEG C, sintering pressure 20-24MPa.
Preferably, its sintering temperature is 2100 DEG C, sintering pressure 22MPa.
The device have the advantages that:Carborundum and molybdenum disilicide are distributed in clay main body as diffusing particle, are carried The high consistency of material, high-compactness improve the fracture toughness of material;Under diffusing particle inhibition, crackle occurs inclined Turn, bifurcated and bridging, energy needed for fracture is added, so as to add the toughness of material.
Embodiment
With reference to specific embodiment, the invention will be further described.
Embodiment one:
A kind of toughness reinforcing clay based on particulate reinforcement technology, it consists of composition and formed by certain mass fraction:Kaolinite 30 parts of stone, 25 parts of quartz, 20 parts of zirconium boride, 1 part of carborundum, 4 parts of molybdenum disilicide.
Add running water after above-mentioned material is pulverized and mixed to be reconciled, by the clay after the completion of mediation according to conventional drawing Embryo, dry technique formation pottery embryo.Pottery embryo is put into stove and carries out firing, its sintering temperature is 2000 DEG C, and sintering pressure is 24MPa, firing terminate after finished product.
Embodiment two:
A kind of toughness reinforcing clay based on particulate reinforcement technology, it consists of composition and formed by certain mass fraction:Kaolinite 40 parts of stone, 35 parts of quartz, 30 parts of zirconium boride, 4 parts of carborundum, 8 parts of molybdenum disilicide.
Add running water after above-mentioned material is pulverized and mixed to be reconciled, by the clay after the completion of mediation according to conventional drawing Embryo, dry technique formation pottery embryo.Pottery embryo is put into stove and carries out firing, its sintering temperature is 2000 DEG C, and sintering pressure is 24MPa, firing terminate after finished product.
Embodiment three:
A kind of toughness reinforcing clay based on particulate reinforcement technology, it consists of composition and formed by certain mass fraction:Kaolinite 34 parts of stone, 28 parts of quartz, 24 parts of zirconium boride, 2 parts of carborundum, 5 parts of molybdenum disilicide.
Add running water after above-mentioned material is pulverized and mixed to be reconciled, by the clay after the completion of mediation according to conventional drawing Embryo, dry technique formation pottery embryo.Pottery embryo is put into stove and carries out firing, its sintering temperature is 2200 DEG C, and sintering pressure is 20MPa, firing terminate after finished product.
Example IV:
A kind of toughness reinforcing clay based on particulate reinforcement technology, it consists of composition and formed by certain mass fraction:Kaolinite 38 parts of stone, 32 parts of quartz, 26 parts of zirconium boride, 3 parts of carborundum, 7 parts of molybdenum disilicide.
Add running water after above-mentioned material is pulverized and mixed to be reconciled, by the clay after the completion of mediation according to conventional drawing Embryo, dry technique formation pottery embryo.Pottery embryo is put into stove and carries out firing, its sintering temperature is 2200 DEG C, and sintering pressure is 20MPa, firing terminate after finished product.
Embodiment five:
A kind of toughness reinforcing clay based on particulate reinforcement technology, it consists of composition and formed by certain mass fraction:Kaolinite 36 parts of stone, 30 parts of quartz, 25 parts of zirconium boride, 2.5 parts of carborundum, 6 parts of molybdenum disilicide.
Add running water after above-mentioned material is pulverized and mixed to be reconciled, by the clay after the completion of mediation according to conventional drawing Embryo, dry technique formation pottery embryo.Pottery embryo is put into stove and carries out firing, its sintering temperature is 2100 DEG C, and sintering pressure is 22MPa, firing terminate after finished product.
Embodiment described above only expresses the several embodiments of the present invention, and its description is more specific and detailed, but simultaneously Therefore the limitation to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that for one of ordinary skill in the art For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the guarantor of the present invention Protect scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.

Claims (5)

1. a kind of toughness reinforcing clay based on particulate reinforcement technology, its spy is being that it consists of composition by certain quality Fraction forms:Kaolinite 30-40 parts, quartzy 25-35 parts, zirconium boride 20-30 parts, carborundum 1-4 parts, molybdenum disilicide 4-8 parts.
2. a kind of toughness reinforcing clay based on particulate reinforcement technology according to claim 1, it is characterised in that it is by with the following group Formed into composition by certain mass fraction:Kaolinite 34-38 parts, quartzy 28-32 parts, zirconium boride 24-26 parts, carborundum 2-3 Part, molybdenum disilicide 5-7 parts.
3. a kind of toughness reinforcing clay based on particulate reinforcement technology according to claim 2, it is characterised in that it is by with the following group Formed into composition by certain mass fraction:36 parts of kaolinite, 30 parts of quartz, 25 parts of zirconium boride, 2.5 parts of carborundum, two silication 6 parts of molybdenum.
A kind of 4. toughness reinforcing clay based on particulate reinforcement technology according to claim 3, it is characterised in that its sintering temperature It is 2000-2200 DEG C, sintering pressure 20-24MPa.
A kind of 5. toughness reinforcing clay based on particulate reinforcement technology according to claim 4, it is characterised in that its sintering temperature It is 2100 DEG C, sintering pressure 22MPa.
CN201710782232.0A 2017-09-02 2017-09-02 A kind of toughness reinforcing clay based on particulate reinforcement technology Pending CN107686337A (en)

Priority Applications (1)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1800086A (en) * 2005-01-04 2006-07-12 杭州民生陶瓷有限公司 Highly heatproof and shockproof ceramic and its production method
CN105367061A (en) * 2015-10-27 2016-03-02 合肥龙多电子科技有限公司 Nano molybdenum disilicide-enhanced high-thermal-conductivity silicon carbide-based ceramic circuit board substrate material and preparation method thereof
CN106116591A (en) * 2016-06-30 2016-11-16 苏州志英明建信息科技有限公司 A kind of Antistatic ceramic
CN106278342A (en) * 2016-08-17 2017-01-04 宁波高智科技咨询服务有限公司 A kind of insulator toughening pottery and manufacture method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1800086A (en) * 2005-01-04 2006-07-12 杭州民生陶瓷有限公司 Highly heatproof and shockproof ceramic and its production method
CN105367061A (en) * 2015-10-27 2016-03-02 合肥龙多电子科技有限公司 Nano molybdenum disilicide-enhanced high-thermal-conductivity silicon carbide-based ceramic circuit board substrate material and preparation method thereof
CN106116591A (en) * 2016-06-30 2016-11-16 苏州志英明建信息科技有限公司 A kind of Antistatic ceramic
CN106278342A (en) * 2016-08-17 2017-01-04 宁波高智科技咨询服务有限公司 A kind of insulator toughening pottery and manufacture method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
矿产资源工业要求手册编委会编: "《矿产资源工业要求手册》", 31 March 2014, 地质出版社 *

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Application publication date: 20180213