CN107056266A - The manufacture craft of Nixing pottery cooking ware - Google Patents

The manufacture craft of Nixing pottery cooking ware Download PDF

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Publication number
CN107056266A
CN107056266A CN201710073690.7A CN201710073690A CN107056266A CN 107056266 A CN107056266 A CN 107056266A CN 201710073690 A CN201710073690 A CN 201710073690A CN 107056266 A CN107056266 A CN 107056266A
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base substrate
parts
blank
mud
temperature
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Inventor
钟恒成
闭宗庭
甘冠蓝
梁鸿展
刘衡志
黄南男
孙继旋
黎国彪
张庆峰
袁丽娟
王宁
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Qinzhou University
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Qinzhou University
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Priority to CN201710073690.7A priority Critical patent/CN107056266A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • C04B35/18Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
    • C04B35/185Mullite 3Al2O3-2SiO2
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/6303Inorganic additives
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64Burning or sintering processes
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64Burning or sintering processes
    • C04B35/645Pressure sintering
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/444Halide containing anions, e.g. bromide, iodate, chlorite
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6562Heating rate
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9607Thermal properties, e.g. thermal expansion coefficient

Abstract

The invention discloses a kind of manufacture craft of Nixing pottery cooking ware, including blank, blank forming, finishing base substrate, body drying, base substrate firing are prepared, the blank is made up of the raw material of following parts by weight:Eastern 6~4 parts of mud, 4~6 parts of western mud, MgCl20.1~0.5 part;It is to send into base substrate in kiln that the base substrate, which is fired, and in temperature-rise period, when temperature is warming up to 700 DEG C, 10~15MPa is forced into base substrate, and when temperature rises to 1100 DEG C, stops pressurized treatments.The Nixing pottery vessel that the present invention makes have excellent heat-resisting acute degeneration and preferable mechanical strength, and thermal coefficient of expansion can be down to 2 × 10‑6/ DEG C (Rt~800 DEG C) below, directly can be used on various thermals source, prolonged without ftractureing, and can meet QB/T2580 2002《Fine ceramics cooking device》Standard requirement.

Description

The manufacture craft of Nixing pottery cooking ware
Technical field
The present invention relates to the manufacture craft of Nixing pottery, and in particular to a kind of manufacture craft of Nixing pottery cooking ware.
Background technology
Qiezhou Nixing pottery is made pottery with yixing purple sand pottery, Sichuan Rongchang County pottery and Yunnan Jian Shui, and claims China four big name pottery.Nixing pottery Manufacture craft include prepare blank, blank forming, finishing base substrate, body drying, base substrate decoration, base substrate fire and polishing grinding Process.Raw material used in Nixing pottery includes eastern mud and western mud, and eastern mud is the soil from the Jiang Yidong that admires for crossing Qiezhou urban district, is Mild-clay, color is yellow-white, containing micro quartz sand, and plasticity is good, is easy to shaping, but refractoriness is quite low, individually fires and holds It is yielding;Western mud is the soil of region to the west of river by the emperor himself, is a kind of higher purple mudstone of iron-holder, color is aubergine, superficial layer There is a small amount of irony to contaminate, be hard paste, fire resistance is good, it is not easy to deform, but poor plasticity, it is difficult to separately formed, by east Mud and western mud are matched with constant weight to be mixed, and plastic blank is made in the series of process such as ground, dehydration.The base of Nixing pottery SiO in material2Content is up to 67.7%, Al2O3Content is 18.14%, a part of SiO2With Al2O3Reaction generation mullite, Mo Lai The thermal coefficient of expansion of stone is higher;A part turns into Free quartz, and crystal transfer can occur at high temperature for Free quartz, from quartz change Into cristobalite, the coefficient of expansion of cristobalite is more much bigger than quartz, and to cristobalite conversion to produce larger volume swollen for quartz It is swollen, so as to cause the thermal coefficient of expansion of Nixing pottery vessel larger, typically 5 × 10-6/ DEG C more than.Therefore Nixing pottery vessel conduct Cooking ware in use, heating temperature can reach 600 DEG C, still suffers from the change of frequent thermal fluctuation, very under the conditions of naked light Easily burst during boiling.Therefore, Nixing pottery vessel can only be used as ceramics ware for daily use, such as conventional cup, dish, tea Kettle, vase, and cannot function as cooking ware and used under the conditions of naked light.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of manufacture craft of Nixing pottery cooking ware, and the technique is made The Nixing pottery cooking ware coefficient of expansion it is low, can be under the conditions of naked light using not rupturing.
The technical scheme that the present invention is provided is a kind of manufacture craft of Nixing pottery cooking ware, including prepares blank, base substrate Shaping, finishing base substrate, body drying, base substrate are fired, and the blank is made up of the raw material of following parts by weight:Eastern 6~4 parts of mud, west 4~6 parts of mud, MgCl20.1~0.5 part;
It is to send into base substrate in kiln that the base substrate, which is fired, in temperature-rise period, when temperature is warming up to 700 DEG C, to base Body is forced into 10~15MPa, and when temperature rises to 1100 DEG C, stops pressurized treatments.
Eastern mud and western mud main component are SiO2And Al2O3, during high-temperature firing, SiO2And Al2O3Aluminium silicon can be generated Spinelle, when more than 1000 DEG C, aluminium silicon spinel can be further converted to mullite.Mullite crystal structure can be regarded as The structural evolution of sillimanite, its structure cell is made up of 4 sillimanite structure cells, and each sillimanite structure cell is by 4 Al2O3·SiO2 Composition.Therefore, mullite structure cell is equivalent to 16Al2O3·SiO2's.Mullite belongs to orthorhombic system, and containing axle is parallel to, it contains It is parallel to axle AlO6Octahedron, these AlO6The octahedra SiO by transverse direction4Tetrahedron is connected.The application is added in blank MgCl2, in 700~1100 DEG C of baking temperature range, the SiO in blank2And Al2O3Activated by divalent magnesium, promote SiO2With Al2O3Mullite is converted into, due to 10~15MPa of condition of high voltage, SiO4Tetrahedron can combine to form N section rings by bridging oxygen key, AlO6It is octahedra to be connected to form the crystal structure with big cavity structure with N section rings.When crystal is heated, particle thermal vibration is shaken Width increases, and big cavity makes crystal not have obvious expansion, thus shows the less coefficient of expansion.
Preferably, the parts by weight of each raw material of blank are:Eastern 6 parts of mud, 4 parts of western mud, MgCl20.1~0.5 part.
It is further preferred that the parts by weight of each raw material of blank are:Eastern 6 parts of mud, 4 parts of western mud, MgCl20.3~0.5 Part.MgCl2Addition when being eastern mud and western mud gross weight 3~5%, activation effect is best.
It is to send into base substrate in kiln that the base substrate, which is fired, when being warming up to 1150~1200 DEG C, stops heating, goes out after cooling Kiln, completes to fire;When temperature is warming up to 700 DEG C, 10~15MPa is forced into base substrate, when temperature rises to 1100 DEG C, stopped Pressurized treatments.
Preferably, it is that dried base substrate is put into kiln that the base substrate, which is fired, to heat up per hour 20~30 DEG C Programming rate rise to 250~350 DEG C, then rise to 700 DEG C with 80~100 DEG C of the programming rate of heating up per hour, then with every The programming rate of 40~60 DEG C of hour heating rises to 1150~1200 DEG C, stops heating, kiln discharge after cooling.
Compared with prior art, the Nixing pottery vessel that the present invention makes have excellent heat-resisting acute degeneration and preferably machinery Intensity, thermal coefficient of expansion can be down to 2 × 10-6/ DEG C (Rt~800 DEG C) below, can directly be used on various thermals source, it is prolonged without Cracking, can meet QB/T2580-2002《Fine ceramics cooking device》Standard requirement.
Embodiment
The present invention is further elaborated for specific examples below, but not as a limitation of the invention.
Embodiment 1
1) blank is prepared:By eastern mud 600kg, western mud 400kg, MgCl210kg is well mixed, ground, press filtration, vacuum After pugging, old process, blank is obtained;
2) blank forming:Outer bore=250mm, capacity=3000ml jar base substrate 100 is made in base substrate;
3) body drying:Base substrate is dried;
4) base substrate is fired:Dried base substrate is put into kiln, to heat up per hour, 20 DEG C of programming rate rises to 250 DEG C, then rise to 700 DEG C with 80 DEG C of the programming rate of heating up per hour, then rise to 40 DEG C of the programming rate of heating up per hour 1150 DEG C, stop heating, kiln discharge after cooling;In temperature-rise period, when temperature is warming up to 700 DEG C, base substrate is forced into 10MPa, when temperature rises to 1100 DEG C, stops pressurized treatments.
Nixing pottery finished product is filled one by one to be directly introduced to heat on gas burner after water and has no cracking, and carries out 400 DEG C one by one Do not split once to 20 DEG C of heat exchanges.One of finished product detection is selected, thermal coefficient of expansion is 1.88 × 10-6/ DEG C (Rt~800 ℃)。
Embodiment 2
1) blank is prepared:By eastern mud 600kg, western mud 400kg, MgCl230kg is well mixed, ground, press filtration, vacuum After pugging, old process, blank is obtained;
2) blank forming:Outer bore=250mm, capacity=3000ml jar base substrate 100 is made in base substrate;
3) body drying:Base substrate is dried;
4) base substrate is fired:Dried base substrate is put into kiln, to heat up per hour, 30 DEG C of programming rate rises to 350 DEG C, then rise to 700 DEG C with 100 DEG C of the programming rate of heating up per hour, then rise to 60 DEG C of the programming rate of heating up per hour 1200 DEG C, stop heating, kiln discharge after cooling;In temperature-rise period, when temperature is warming up to 700 DEG C, base substrate is forced into 15MPa, when temperature rises to 1100 DEG C, stops pressurized treatments.
Nixing pottery finished product is filled one by one to be directly introduced to heat on gas burner after water and has no cracking, and carries out 400 DEG C one by one Do not split once to 20 DEG C of heat exchanges.One of finished product detection is selected, thermal coefficient of expansion is 1.82 × 10-6/ DEG C (Rt~800 ℃)。
Embodiment 3
1) blank is prepared:By eastern mud 600kg, western mud 400kg, MgCl250kg is well mixed, ground, press filtration, vacuum After pugging, old process, blank is obtained;
2) blank forming:Outer bore=250mm, capacity=3000ml jar base substrate 100 is made in base substrate;
3) body drying:Base substrate is dried;
4) base substrate is fired:Dried base substrate is put into kiln, to heat up per hour, 25 DEG C of programming rate rises to 300 DEG C, then rise to 700 DEG C with 90 DEG C of the programming rate of heating up per hour, then rise to 50 DEG C of the programming rate of heating up per hour 1180 DEG C, stop heating, kiln discharge after cooling;In temperature-rise period, when temperature is warming up to 700 DEG C, base substrate is forced into 12MPa, when temperature rises to 1100 DEG C, stops pressurized treatments.
Nixing pottery finished product is filled one by one to be directly introduced to heat on gas burner after water and has no cracking, and carries out 400 DEG C one by one Do not split once to 20 DEG C of heat exchanges.One of finished product detection is selected, thermal coefficient of expansion is 1.76 × 10-6/ DEG C (Rt~800 ℃)。
Embodiment 4
1) blank is prepared:By eastern mud 400kg, western mud 600kg, MgCl210kg is well mixed, ground, press filtration, vacuum After pugging, old process, blank is obtained;
2) blank forming:Outer bore=250mm, capacity=3000ml jar base substrate 100 is made in base substrate;
3) body drying:Base substrate is dried;
4) base substrate is fired:Dried base substrate is put into kiln, to heat up per hour, 20 DEG C of programming rate rises to 350 DEG C, then rise to 700 DEG C with 80 DEG C of the programming rate of heating up per hour, then rise to 60 DEG C of the programming rate of heating up per hour 1150 DEG C, stop heating, kiln discharge after cooling;In temperature-rise period, when temperature is warming up to 700 DEG C, base substrate is forced into 15MPa, when temperature rises to 1100 DEG C, stops pressurized treatments.
Nixing pottery finished product is filled one by one to be directly introduced to heat on gas burner after water and has no cracking, and carries out 400 DEG C one by one Do not split once to 20 DEG C of heat exchanges.One of finished product detection is selected, thermal coefficient of expansion is 1.89 × 10-6/ DEG C (Rt~800 ℃)。
Embodiment 5
1) blank is prepared:By eastern mud 500kg, western mud 500kg, MgCl250kg is well mixed, ground, press filtration, vacuum After pugging, old process, blank is obtained;
2) blank forming:Outer bore=250mm, capacity=3000ml jar base substrate 100 is made in base substrate;
3) body drying:Base substrate is dried;
4) base substrate is fired:Dried base substrate is put into kiln, to heat up per hour, 30 DEG C of programming rate rises to 250 DEG C, then rise to 700 DEG C with 100 DEG C of the programming rate of heating up per hour, then rise to 40 DEG C of the programming rate of heating up per hour 1200 DEG C, stop heating, kiln discharge after cooling;In temperature-rise period, when temperature is warming up to 700 DEG C, base substrate is forced into 10MPa, when temperature rises to 1100 DEG C, stops pressurized treatments.
Nixing pottery finished product is filled one by one to be directly introduced to heat on gas burner after water and has no cracking, and carries out 400 DEG C one by one Do not split once to 20 DEG C of heat exchanges.One of finished product detection is selected, thermal coefficient of expansion is 1.90 × 10-6/ DEG C (Rt~800 ℃)。

Claims (5)

1. the manufacture craft of Nixing pottery cooking ware, including prepare blank, blank forming, finishing base substrate, body drying, base substrate burning System, it is characterised in that:
The blank is made up of the raw material of following parts by weight:Eastern 6~4 parts of mud, 4~6 parts of western mud, MgCl20.1~0.5 part;
It is to send into base substrate in kiln that the base substrate, which is fired, in temperature-rise period, when temperature is warming up to 700 DEG C, to base substrate plus 10~15MPa is depressed into, and when temperature rises to 1100 DEG C, stops pressurized treatments.
2. the manufacture craft of Nixing pottery cooking ware according to claim 1, it is characterised in that:Each raw material of blank Parts by weight are:Eastern 6 parts of mud, 4 parts of western mud, MgCl20.1~0.5 part.
3. the manufacture craft of Nixing pottery cooking ware according to claim 1, it is characterised in that:Each raw material of blank Parts by weight are:Eastern 6 parts of mud, 4 parts of western mud, MgCl20.3~0.5 part.
4. the manufacture craft of Nixing pottery cooking ware according to claim 1, it is characterised in that:The base substrate fire be by In base substrate feeding kiln, when being warming up to 1150~1200 DEG C, stop heating, kiln discharge after cooling completes to fire;When temperature is warming up to At 700 DEG C, 10~15MPa is forced into base substrate, when temperature rises to 1100 DEG C, stops pressurized treatments.
5. the manufacture craft of Nixing pottery cooking ware according to claim 1, it is characterised in that:The base substrate fire be by Dried base substrate is put into kiln, and to heat up per hour, 20~30 DEG C of programming rate rises to 250~350 DEG C, then with every Hour 80~100 DEG C of programming rate of heating rises to 700 DEG C, then rises to 1150 with 40~60 DEG C of the programming rate of heating up per hour ~1200 DEG C, stop heating, kiln discharge after cooling.
CN201710073690.7A 2017-02-10 2017-02-10 The manufacture craft of Nixing pottery cooking ware Pending CN107056266A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108383497A (en) * 2018-05-28 2018-08-10 钦州学院 The preparation method of large-scale Nixing pottery plate
CN108530025A (en) * 2018-05-28 2018-09-14 钦州学院 The preparation method of on-deformable Nixing pottery plate
CN108610004A (en) * 2018-05-28 2018-10-02 钦州学院 The method for cooking of large-scale Nixing pottery
CN115466101A (en) * 2022-09-14 2022-12-13 钦州市登峰陶艺有限公司 Preparation method of landscape nixing pottery

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106242526A (en) * 2016-08-29 2016-12-21 钦州市鸿立坭兴有限责任公司 The processing technology of high temperature resistant Nixing pottery

Patent Citations (1)

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Publication number Priority date Publication date Assignee Title
CN106242526A (en) * 2016-08-29 2016-12-21 钦州市鸿立坭兴有限责任公司 The processing technology of high temperature resistant Nixing pottery

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Title
严东生主编: "《硅酸盐物理化学 第1版》", 30 November 1980, 北京:冶金工业出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108383497A (en) * 2018-05-28 2018-08-10 钦州学院 The preparation method of large-scale Nixing pottery plate
CN108530025A (en) * 2018-05-28 2018-09-14 钦州学院 The preparation method of on-deformable Nixing pottery plate
CN108610004A (en) * 2018-05-28 2018-10-02 钦州学院 The method for cooking of large-scale Nixing pottery
CN115466101A (en) * 2022-09-14 2022-12-13 钦州市登峰陶艺有限公司 Preparation method of landscape nixing pottery

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Application publication date: 20170818