CN101891451B - High temperature resistance anti-cracking purple-sand vessel and manufacture method thereof - Google Patents
High temperature resistance anti-cracking purple-sand vessel and manufacture method thereof Download PDFInfo
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- CN101891451B CN101891451B CN2010102100792A CN201010210079A CN101891451B CN 101891451 B CN101891451 B CN 101891451B CN 2010102100792 A CN2010102100792 A CN 2010102100792A CN 201010210079 A CN201010210079 A CN 201010210079A CN 101891451 B CN101891451 B CN 101891451B
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Abstract
The invention discloses a high temperature resistance anti-cracking purple-sand vessel, which comprises the following components in percentage by weight: 5 to 65 percent of purple-sand raw ore materials, 10 to 35 percent of spodumene, 5 to 25 percent of magnesium-containing substances, and 5 to 35 percent of silicon-containing substances. The invention also discloses a method for manufacturing the purple-sand vessel. The high temperature resistance anti-cracking purple-sand vessel has excellent heat resistance, and is prevented from cracking after multiple times of heating. In the whole manufacture process, harmful heavy metals cannot be brought in, so the vessel has no influence on human bodies. Furthermore, when the purple-sand vessel is used for cooking food, various trace elements can permeate into the food in the cooking process to supplement the requirement of the human bodies.
Description
Technical field
The present invention relates to a kind of red stoneware ware and preparation method thereof, it is high temperature resistant specifically to relate to a kind of ability, red stoneware ware that is difficult for bursting and preparation method thereof.
Background technology
The raw ore purple clay, the ancient title " rich and honour soil ",, because of the vessel with its making have simple and tasteful, dignified and magnanimous appearance characteristics and unique physics and chemistry function and health protection function, generation is addressed respectfully " Qarnet gold sand ".High-grade artwork generally is more common in the application of raw ore purple clay, and is made into pure red stoneware ware with it, and cooking out delicious food then is the difficult problem in hundreds of years of puzzlement boccaro circle.The proportioning ratio of traditional dark-red enameled pottery, boccaro basin can not be high temperature resistant, is not suitable for cook food, in case run into steaming, fry, stew, boil and cause bursting of red stoneware ware easily.Yixing City pottery company just sets up special scientific research group at the beginning of set up and studies tackling key problem to how making high temperature resistant fried pure red stoneware ware, has expended great amount of manpower, financial resources, yet has not also seen successfully until company's graduation; 2006, the yixing purple sand pottery manufacture skill is criticized was the first batch of non-material cultural heritage in the whole nation, but making method high temperature resistant, that do not burst red stoneware ware is but had no main threads all the time.
At present, " the high temperature resistant red stoneware ware " that exists on the market all is to mix and make with white clay and chemical industry iron oxide red powder, chemical industry manganese powder, and its making method is to use white clay to be raw material nothing more than, adds heavy metals such as iron oxide red powder, is modulated into the color of boccaro." red stoneware ware " made like this just had the characteristics that white clay soil is high temperature resistant, be difficult for bursting, and the outward appearance of boccaro has been arranged again, misguide the consumer, heavy damage human consumer's interests.In addition, because these heavy metals are artificial interpolations, be not the contained trace element of natural purple clay, be easy to cause interpolation excessive, therefore be difficult to meet the relevant criterion of national heavy metal content, thereby cause threat each internal organs of human body.
Summary of the invention
Goal of the invention: the object of the present invention is to provide the red stoneware ware that a kind of ability is high temperature resistant, be difficult for bursting.
Another object of the present invention is to provide the making method of above-mentioned red stoneware ware.
Technical scheme: a kind of high temperature resistance anti-cracking purple-sand vessel disclosed by the invention comprises following components in weight percentage: the former mineral aggregate of 5～65% boccaro, 10～35% triphane, 5～25% contain magnesium material, 5～35% silicon-containing material.
Wherein, Fe in the former mineral aggregate of said boccaro
2O
3Content be 3～15%.
Wherein, the said magnesium material that contains is in talcum powder, trichroite, flint clay, MUSYUSHI or the medical stone one or more.
Wherein, said silicon-containing material is one or more in talcum powder, flint clay, quartz, MUSYUSHI, medical stone or the kaolin.
Make the method for above-mentioned a kind of high temperature resistance anti-cracking purple-sand vessel, may further comprise the steps:
(1) with the old naturally weathering of the former mineral aggregate of boccaro 3～12 months;
(2) take by weighing each raw material, pulverize separately by formula ratio;
(3) each raw materials mix after will pulverizing, and stir just and practice, old 1～7 day;
(4) with mixing raw material vacuum pugging 1～2 time, make water ratio＜25%;
(5) process base with practicing the raw mix that makes, repair;
(6) base of fixing is sent into the drying room drying, temperature is 40～70 ℃, continues 24～48 hours;
(7) treat base oven dry after, slurry from the teeth outwards, and drying naturally;
(8) base that will go up slurry is sent the kiln preheating to, divides and carries out for three times, is for the first time leading portion preheating just, 30～200 ℃; Continue 1～3.5 hour, for stage casing heating dehumidifier, 350～550 ℃, continue 0.5～2 hour for the second time; Be back segment stagnation point heating for the third time, 650～900 ℃, continue 1～2 hour;
(9) burn till with high temperature before base that preheating is good carries out and burn till, preceding firing temperature is 950～1130 ℃, continues 0.5～2 hour, and the high temperature firing temperature is 1150～1200 ℃, continues 0.5～2 hour;
(10) base that burns till through high temperature is sent into cooling section, divides three sections coolings, and leading portion is a quench zone, and temperature is 550～300 ℃, and the stage casing is the naturally cooling section, and temperature is 300～150 ℃, and back segment is for fall cold section again, and temperature is 130～20 ℃;
(11) finished product kiln discharge.
Wherein, each material fineness after the pulverizing is 25～120 orders in the step (2).
Wherein, slurry is chosen for carrying out manual work with the superfine picking raw ore of boccaro in the step (7).
Among the present invention, the ratio control of the former mineral aggregate of purple clay has conclusive effect to high temperature resistant not fried characteristic.The adding of other several kinds of raw materials, then the wearing quality to red stoneware ware has remarkable lifting.In addition, making method of the present invention is well suited for the processing of red stoneware ware and burns till, and the control of temperature and time then helps the raising of yield rate; And three preheatings can fully burn the carbon in the product, avoid causing the intermolecular excessive clearance of vessel because of the existence of carbon.
Beneficial effect: high temperature resistance anti-cracking purple-sand vessel of the present invention, have good thermotolerance, problem also can not appear bursting through heating for multiple times.In the entire making process, do not bring harmful heavy metal into, human body is had no effect.With red stoneware ware cook food of the present invention, various trace elements can overflow into food in the process of cooking, replenish needed by human body.
Embodiment
Embodiment 1:
At first with Fe
2O
3Content is 8% the old naturally weathering of the former mineral aggregate of boccaro 6 months; Take by weighing 5% the former mineral aggregate of boccaro (unit is a weight percentage), 35% triphane, 25% talcum powder and 35% flint clay; Above-mentioned raw materials is pulverized respectively, and fineness is 30 orders; With each raw materials mix after pulverizing, and stir just and practice, old 4 days; With mixing raw material vacuum pugging 1 time, make water ratio＜25%; Process base with practicing the raw mix that makes, repair; The base of fixing is sent into the drying room drying, and temperature is 40 ℃, continues 48 hours; After treating the base oven dry, starch from the teeth outwards, and dry naturally; Sending the last base of crossing slurry to the kiln preheating, divide and carry out for three times, is for the first time leading portion preheating just, 50 ℃, continue 3 hours, and be stage casing heating dehumidifier for the second time, 400 ℃, continue 1 hour, be for the third time back segment stagnation point heating 800 ℃, to continue 1 hour; Burn till with high temperature before the base that preheating is good carries out and burn till, preceding firing temperature is 1000 ℃, continues 1 hour, and the high temperature firing temperature is 1150 ℃, continues 2 hours; Base through high temperature burns till is sent into cooling section, divides three sections coolings, and leading portion is a quench zone, and temperature is 400 ℃, and the stage casing is the naturally cooling section, and temperature is 200 ℃, and back segment is for fall cold section again, and temperature is 50 ℃; The finished product kiln discharge.
Embodiment 2:
At first with Fe
2O
3Content is 5% the old naturally weathering of the former mineral aggregate of boccaro 8 months; Take by weighing 15% the former mineral aggregate of boccaro (unit is a weight percentage), 30% triphane, 25% trichroite and 30% quartz; Above-mentioned raw materials is pulverized respectively, and fineness is 50 orders; With each raw materials mix after pulverizing, and stir just and practice, old 3 days; With mixing raw material vacuum pugging 1 time, make water ratio＜25%; Process base with practicing the raw mix that makes, repair; The base of fixing is sent into the drying room drying, and temperature is 50 ℃, continues 40 hours; After treating the base oven dry, starch from the teeth outwards, and dry naturally; Sending the last base of crossing slurry to the kiln preheating, divide and carry out for three times, is for the first time leading portion preheating just, 80 ℃, continue 3 hours, and be stage casing heating dehumidifier for the second time, 420 ℃, continue 1 hour, be for the third time back segment stagnation point heating 650 ℃, to continue 2 hours; Burn till with high temperature before the base that preheating is good carries out and burn till, preceding firing temperature is 950 ℃, continues 2 hours, and the high temperature firing temperature is 1200 ℃, continues 0.5 hour; Base through high temperature burns till is sent into cooling section, divides three sections coolings, and leading portion is a quench zone, and temperature is 550 ℃, and the stage casing is the naturally cooling section, and temperature is 300 ℃, and back segment is for fall cold section again, and temperature is 80 ℃; The finished product kiln discharge.
Embodiment 3:
At first with Fe
2O
3Content is 6% the old naturally weathering of the former mineral aggregate of boccaro 9 months; Take by weighing 25% the former mineral aggregate of boccaro (unit is a weight percentage), 25% triphane, 25% MUSYUSHI and 25% medical stone; Above-mentioned raw materials is pulverized respectively, and fineness is 60 orders; With each raw materials mix after pulverizing, and stir just and practice, old 6 days; With mixing raw material vacuum pugging 1 time, make water ratio＜25%; Process base with practicing the raw mix that makes, repair; The base of fixing is sent into the drying room drying, and temperature is 60 ℃, continues 36 hours; After treating the base oven dry, starch from the teeth outwards, and dry naturally; Sending the last base of crossing slurry to the kiln preheating, divide and carry out for three times, is for the first time leading portion preheating just, 120 ℃, continue 2.5 hours, and be stage casing heating dehumidifier for the second time, 380 ℃, continue 1.5 hours, be for the third time back segment stagnation point heating 850 ℃, to continue 1 hour; Burn till with high temperature before the base that preheating is good carries out and burn till, preceding firing temperature is 1110 ℃, continues 1 hour, and the high temperature firing temperature is 1170 ℃, continues 1.5 hours; Base through high temperature burns till is sent into cooling section, divides three sections coolings, and leading portion is a quench zone, and temperature is 450 ℃, and the stage casing is the naturally cooling section, and temperature is 220 ℃, and back segment is for fall cold section again, and temperature is 70 ℃; The finished product kiln discharge.
Embodiment 4:
At first with Fe
2O
3Content is 7% the old naturally weathering of the former mineral aggregate of boccaro 10 months; Take by weighing 35% the former mineral aggregate of boccaro (unit is a weight percentage), 25% triphane, 15% medical stone and 25% talcum powder; Above-mentioned raw materials is pulverized respectively, and fineness is 80 orders; With each raw materials mix after pulverizing, and stir just and practice, old 5 days; With mixing raw material vacuum pugging 1 time, make water ratio＜25%; Process base with practicing the raw mix that makes, repair; The base of fixing is sent into the drying room drying, and temperature is 70 ℃, continues 24 hours; After treating the base oven dry, starch from the teeth outwards, and dry naturally; Sending the last base of crossing slurry to the kiln preheating, divide and carry out for three times, is for the first time leading portion preheating just, 150 ℃, continue 2 hours, and be stage casing heating dehumidifier for the second time, 500 ℃, continue 1 hour, be for the third time back segment stagnation point heating 860 ℃, to continue 1 hour; Burn till with high temperature before the base that preheating is good carries out and burn till, preceding firing temperature is 1130 ℃, continues 0.5 hour, and the high temperature firing temperature is 1180 ℃, continues 1 hour; Base through high temperature burns till is sent into cooling section, divides three sections coolings, and leading portion is a quench zone, and temperature is 500 ℃, and the stage casing is the naturally cooling section, and temperature is 230 ℃, and back segment is for fall cold section again, and temperature is 90 ℃; The finished product kiln discharge.
Embodiment 5:
At first with Fe
2O
3Content is 9% the old naturally weathering of the former mineral aggregate of boccaro 8 months; Take by weighing 45% the former mineral aggregate of boccaro (unit is a weight percentage), 20% triphane, 15% talcum powder and trichroite, 20% quartz and kaolin; Above-mentioned raw materials is pulverized respectively, and fineness is 50 orders; With each raw materials mix after pulverizing, and stir just and practice, old 3 days; With mixing raw material vacuum pugging 2 times, make water ratio＜25%; Process base with practicing the raw mix that makes, repair; The base of fixing is sent into the drying room drying, and temperature is 70 ℃, continues 24 hours; After treating the base oven dry, starch from the teeth outwards, and dry naturally; Sending the last base of crossing slurry to the kiln preheating, divide and carry out for three times, is for the first time leading portion preheating just, 200 ℃, continue 0.5 hour, and be stage casing heating dehumidifier for the second time, 520 ℃, continue 0.5 hour, be for the third time back segment stagnation point heating 850 ℃, to continue 1 hour; Burn till with high temperature before the base that preheating is good carries out and burn till, preceding firing temperature is 1000 ℃, continues 1 hour, and the high temperature firing temperature is 1180 ℃, continues 1.5 hours; Base through high temperature burns till is sent into cooling section, divides three sections coolings, and leading portion is a quench zone, and temperature is 420 ℃, and the stage casing is the naturally cooling section, and temperature is 210 ℃, and back segment is for fall cold section again, and temperature is 60 ℃; The finished product kiln discharge.
Embodiment 6:
At first with Fe
2O
3Content is 10% the old naturally weathering of the former mineral aggregate of boccaro 8 months; Take by weighing 55% the former mineral aggregate of boccaro (unit is a weight percentage), 20% triphane, 10% MUSYUSHI and trichroite, 15% flint clay and talcum powder; Above-mentioned raw materials is pulverized respectively, and fineness is 40 orders; With each raw materials mix after pulverizing, and stir just and practice, old 5 days; With mixing raw material vacuum pugging 2 times, make water ratio＜25%; Process base with practicing the raw mix that makes, repair; The base of fixing is sent into the drying room drying, and temperature is 50 ℃, continues 43 hours; After treating the base oven dry, starch from the teeth outwards, and dry naturally; Sending the last base of crossing slurry to the kiln preheating, divide and carry out for three times, is for the first time leading portion preheating just, 80 ℃, continue 2.5 hours, and be stage casing heating dehumidifier for the second time, 430 ℃, continue 1 hour, be for the third time back segment stagnation point heating 840 ℃, to continue 1 hour; Burn till with high temperature before the base that preheating is good carries out and burn till, preceding firing temperature is 1100 ℃, continues 1 hour, and the high temperature firing temperature is 1160 ℃, continues 1.5 hours; Base through high temperature burns till is sent into cooling section, divides three sections coolings, and leading portion is a quench zone, and temperature is 350 ℃, and the stage casing is the naturally cooling section, and temperature is 180 ℃, and back segment is for fall cold section again, and temperature is 40 ℃; The finished product kiln discharge.
Embodiment 7:
At first with Fe
2O
3Content is 11% the old naturally weathering of the former mineral aggregate of boccaro 10 months; Take by weighing 65% the former mineral aggregate of boccaro (unit is a weight percentage), 10% triphane, 5% MUSYUSHI and medical stone, 20% flint clay and quartz; Above-mentioned raw materials is pulverized respectively, and fineness is 60 orders; With each raw materials mix after pulverizing, and stir just and practice, old 6 days; With mixing raw material vacuum pugging 2 times, make water ratio＜25%; Process base with practicing the raw mix that makes, repair; The base of fixing is sent into the drying room drying, and temperature is 70 ℃, continues 24 hours; After treating the base oven dry, starch from the teeth outwards, and dry naturally; Sending the last base of crossing slurry to the kiln preheating, divide and carry out for three times, is for the first time leading portion preheating just, 150 ℃, continue 2 hours, and be stage casing heating dehumidifier for the second time, 450 ℃, continue 1 hour, be for the third time back segment stagnation point heating 900 ℃, to continue 0.5 hour; Burn till with high temperature before the base that preheating is good carries out and burn till, preceding firing temperature is 1100 ℃, continues 1 hour, and the high temperature firing temperature is 1200 ℃, continues 0.5 hour; Base through high temperature burns till is sent into cooling section, divides three sections coolings, and leading portion is a quench zone, and temperature is 430 ℃, and the stage casing is the naturally cooling section, and temperature is 260 ℃, and back segment is for fall cold section again, and temperature is 70 ℃; The finished product kiln discharge.
Embodiment 7:
A kind of high temperature resistant not each item physicochemical data of fried vessel provided by the invention
Table 1 each item physicochemical data of the present invention
| Sequence number | Test item | Detected result |
| 1 | The barium stripping quantity | ≤0.27mg/L |
| 2 | The manganese stripping quantity | ≤0.02mg/L |
| 3 | The cobalt stripping quantity | Do not detect |
| 4 | The chromium stripping quantity | ≤0.01mg/L |
| 5 | Lead release | ≤0.1mg/L |
| 6 | Quantity of cadmium release | ≤0.01mg/L |
| 7 | Fe 2O 3Content | ≤3.5％ |
| 8 | Water-intake rate | 6.5～9.5％ |
| 9 | Heat-resisting not fried temperature | ≤450℃ |
Claims (5)
1. the making method of a high temperature resistance anti-cracking purple-sand vessel is characterized in that, may further comprise the steps:
(1) with the old naturally weathering of the former mineral aggregate of boccaro 3～12 months;
(2) getting weight percent is 5～65% the former mineral aggregate of boccaro, 10～35% triphane, 5～25% the silicon-containing material that contains magnesium material and 5～35%, pulverize separately;
(3) each raw materials mix after will pulverizing, and stir just and practice, old 1～7 day;
(4) with mixing raw material vacuum pugging 1～2 time, make water ratio＜25%;
(5) process base with practicing the raw mix that makes, repair;
(6) base of fixing is sent into the drying room drying, temperature is 40～70 ℃, continues 24～48 hours;
(7) treat base oven dry after, slurry from the teeth outwards, and drying naturally;
(8) base that will go up slurry is sent the kiln preheating to, divides and carries out for three times, is for the first time leading portion preheating just, 30～200 ℃; Continue 1～3.5 hour, for stage casing heating dehumidifier, 350～550 ℃, continue 0.5～2 hour for the second time; Be back segment stagnation point heating for the third time, 650～900 ℃, continue 1～2 hour;
(9) burn till with high temperature before base that preheating is good carries out and burn till, preceding firing temperature is 950～1130 ℃, continues 0.5～2 hour, and the high temperature firing temperature is 1150～1200 ℃, continues 0.5～2 hour;
(10) base that burns till through high temperature is sent into cooling section, divides three sections coolings, and leading portion is a quench zone, and temperature is 550～300 ℃, and the stage casing is the naturally cooling section, and temperature is 300～150 ℃, and back segment is for fall cold section again, and temperature is 130～20 ℃;
(11) finished product kiln discharge.
2. the method for making high temperature resistance anti-cracking purple-sand vessel according to claim 1 is characterized in that Fe in the former mineral aggregate of said boccaro
2O
3Content be 3～15%.
3. the method for making high temperature resistance anti-cracking purple-sand vessel according to claim 1 is characterized in that the said magnesium material that contains is in talcum powder, trichroite, flint clay, MUSYUSHI or the medical stone one or more.
4. the method for making high temperature resistance anti-cracking purple-sand vessel according to claim 1 is characterized in that said silicon-containing material is one or more in talcum powder, flint clay, quartz, MUSYUSHI, medical stone or the kaolin.
5. the method for making high temperature resistance anti-cracking purple-sand vessel according to claim 1, each material fineness after it is characterized in that pulverizing in the step (2) is 25～120 orders.
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| CN2010102100792A CN101891451B (en) | 2010-06-24 | 2010-06-24 | High temperature resistance anti-cracking purple-sand vessel and manufacture method thereof |
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| CN2010102100792A CN101891451B (en) | 2010-06-24 | 2010-06-24 | High temperature resistance anti-cracking purple-sand vessel and manufacture method thereof |
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| CN101891451B true CN101891451B (en) | 2012-07-25 |
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| CN103274668A (en) * | 2013-05-31 | 2013-09-04 | 陈建华 | Anti-burst purple-sand ceramic utensil |
| CN106278151A (en) * | 2016-08-12 | 2017-01-04 | 袁野 | A kind of burning process of red stoneware ware |
| CN107285733B (en) * | 2017-05-27 | 2020-11-27 | 宜兴市凤凰陶瓷厂 | Purple sand kettle capable of boiling water without frying |
| CN107344850A (en) * | 2017-07-04 | 2017-11-14 | 德化县怡家工贸有限责任公司 | The formula and its manufacture craft of titanium selenium health compound ceramic feeding bottle |
| CN108178651A (en) * | 2017-11-23 | 2018-06-19 | 宜兴市玉见紫砂艺术有限公司 | A kind of method that red stoneware ware is combined with beautiful material |
| CN108158409A (en) * | 2018-01-05 | 2018-06-15 | 曹桂成 | A kind of boccaro health kettle and preparation method thereof and application method |
| CN108793945A (en) * | 2018-05-18 | 2018-11-13 | 宜兴市东山新型材料有限公司 | A kind of electrothermal dark-red pottery boiling pot and preparation method thereof |
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| CN1078876A (en) * | 1992-05-20 | 1993-12-01 | 北京市怀柔县庙城彩绘厂 | Maifan stone purple sand tea set, tableware and method for making thereof |
| CN1377851A (en) * | 2001-03-30 | 2002-11-06 | 李子诚 | Method for producing Chinese medicinal stone purlie sand container |
| CN101134672A (en) * | 2007-07-17 | 2008-03-05 | 朱绍波 | Heat-proof purple sand ceramic mud and method for preparing the product |
| CN101323520A (en) * | 2008-03-27 | 2008-12-17 | 熊禄生 | Heat resisting red porcelain chinaware |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1078876A (en) * | 1992-05-20 | 1993-12-01 | 北京市怀柔县庙城彩绘厂 | Maifan stone purple sand tea set, tableware and method for making thereof |
| CN1377851A (en) * | 2001-03-30 | 2002-11-06 | 李子诚 | Method for producing Chinese medicinal stone purlie sand container |
| CN101134672A (en) * | 2007-07-17 | 2008-03-05 | 朱绍波 | Heat-proof purple sand ceramic mud and method for preparing the product |
| CN101323520A (en) * | 2008-03-27 | 2008-12-17 | 熊禄生 | Heat resisting red porcelain chinaware |
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