CN107683295A - 多孔丙烯聚合物 - Google Patents

多孔丙烯聚合物 Download PDF

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Publication number
CN107683295A
CN107683295A CN201680032425.8A CN201680032425A CN107683295A CN 107683295 A CN107683295 A CN 107683295A CN 201680032425 A CN201680032425 A CN 201680032425A CN 107683295 A CN107683295 A CN 107683295A
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CN
China
Prior art keywords
less
propylene
bigger
catalyst
acrylic polymers
Prior art date
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Pending
Application number
CN201680032425.8A
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English (en)
Chinese (zh)
Inventor
M·W·赫尔特卡姆
G·S·戴
J·杨
罗鲁斌
S·D·布朗
R·A·胡勒
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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Publication date
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Publication of CN107683295A publication Critical patent/CN107683295A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06—Catalyst characterized by its size
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/02—Heterophasic composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN201680032425.8A 2015-06-05 2016-04-29 多孔丙烯聚合物 Pending CN107683295A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201562171581P 2015-06-05 2015-06-05
US62/171,581 2015-06-05
EP15177118 2015-07-16
EP15177118.5 2015-07-16
PCT/US2016/029970 WO2016195865A1 (en) 2015-06-05 2016-04-29 Porous propylene polymers

Publications (1)

Publication Number Publication Date
CN107683295A true CN107683295A (zh) 2018-02-09

Family

ID=53783572

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201680032425.8A Pending CN107683295A (zh) 2015-06-05 2016-04-29 多孔丙烯聚合物

Country Status (3)

Country Link
EP (1) EP3303417A4 (de)
CN (1) CN107683295A (de)
WO (1) WO2016195865A1 (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102431269B1 (ko) 2018-11-02 2022-08-10 주식회사 엘지화학 신규 전이금속 화합물 및 이를 이용한 폴리프로필렌의 제조방법

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1054077A (zh) * 1989-12-21 1991-08-28 黑蒙特股份公司 聚烯烃接枝共聚物及其制备方法
US5547756A (en) * 1991-02-08 1996-08-20 Mitsubishi Rayon Co., Ltd. Porous polypropylene hollow fiber membrane of large pore diameter, production process thereof, and hydrophilized porous hollow fiber membranes
CN1309669A (zh) * 1998-08-26 2001-08-22 埃克森美孚化学专利公司 支化聚丙烯组合物
US20050003951A1 (en) * 2001-11-27 2005-01-06 Angelo Ferraro Porous polymers of propylene
CN1604914A (zh) * 2001-12-20 2005-04-06 巴塞尔聚烯烃股份有限公司 用于烯烃聚合的含氧化硅的催化剂固体
CN1649914A (zh) * 2002-06-25 2005-08-03 玻利阿黎斯技术有限公司 提高了抗刮性的聚烯烃及其制备方法
CN103108889A (zh) * 2010-09-15 2013-05-15 弗纳技术股份有限公司 负载型金属茂催化剂
US20150119537A1 (en) * 2013-10-28 2015-04-30 Exxonmobil Chemical Patents Inc. Processes Using Staged Hydrogen Addition
WO2015065676A1 (en) * 2013-10-28 2015-05-07 Exxonmobil Chemical Patents Inc. Processes using staged hydrogen addition

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1270125B (it) * 1994-10-05 1997-04-28 Spherilene Srl Processo per la ( co) polimerizzazione di olefine

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1054077A (zh) * 1989-12-21 1991-08-28 黑蒙特股份公司 聚烯烃接枝共聚物及其制备方法
US5547756A (en) * 1991-02-08 1996-08-20 Mitsubishi Rayon Co., Ltd. Porous polypropylene hollow fiber membrane of large pore diameter, production process thereof, and hydrophilized porous hollow fiber membranes
CN1309669A (zh) * 1998-08-26 2001-08-22 埃克森美孚化学专利公司 支化聚丙烯组合物
US20050003951A1 (en) * 2001-11-27 2005-01-06 Angelo Ferraro Porous polymers of propylene
CN1604914A (zh) * 2001-12-20 2005-04-06 巴塞尔聚烯烃股份有限公司 用于烯烃聚合的含氧化硅的催化剂固体
CN1649914A (zh) * 2002-06-25 2005-08-03 玻利阿黎斯技术有限公司 提高了抗刮性的聚烯烃及其制备方法
CN103108889A (zh) * 2010-09-15 2013-05-15 弗纳技术股份有限公司 负载型金属茂催化剂
US20150119537A1 (en) * 2013-10-28 2015-04-30 Exxonmobil Chemical Patents Inc. Processes Using Staged Hydrogen Addition
WO2015065676A1 (en) * 2013-10-28 2015-05-07 Exxonmobil Chemical Patents Inc. Processes using staged hydrogen addition

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
MADRI SMIT,ET AL.: "Effects of Methylaluminoxane Immobilization on Silica on the Performance of Zirconocene Catalysts in Propylene polymerization", 《JOURNAL OF POLYMER SCIENCE：PART A：POLYMER CHEMISTRY》 *
MOHAMAD MEHDI MORTAZAVI,ETAL,.: "Characterization of MAO-Modified Silicas for Ethylene Polymerization", 《APPLIED POLYMER SCIENCE》 *

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EP3303417A1 (de) 2018-04-11
WO2016195865A1 (en) 2016-12-08
EP3303417A4 (de) 2018-08-22

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Application publication date: 20180209