CN107670695A - 一种核‑壳异质结构材料的制备方法 - Google Patents
一种核‑壳异质结构材料的制备方法 Download PDFInfo
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- CN107670695A CN107670695A CN201710841240.8A CN201710841240A CN107670695A CN 107670695 A CN107670695 A CN 107670695A CN 201710841240 A CN201710841240 A CN 201710841240A CN 107670695 A CN107670695 A CN 107670695A
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- 239000000463 material Substances 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000012046 mixed solvent Substances 0.000 claims abstract description 14
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 claims abstract description 10
- GPNNOCMCNFXRAO-UHFFFAOYSA-N 2-aminoterephthalic acid Chemical compound NC1=CC(C(O)=O)=CC=C1C(O)=O GPNNOCMCNFXRAO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000011259 mixed solution Substances 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005864 Sulphur Substances 0.000 claims abstract description 8
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 238000005406 washing Methods 0.000 claims abstract description 6
- 239000000243 solution Substances 0.000 claims abstract description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 16
- 229920001577 copolymer Polymers 0.000 claims description 8
- 239000011258 core-shell material Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 230000035484 reaction time Effects 0.000 claims 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 abstract description 13
- 230000015556 catabolic process Effects 0.000 abstract description 12
- 238000006731 degradation reaction Methods 0.000 abstract description 12
- 229940043267 rhodamine b Drugs 0.000 abstract description 12
- 230000003197 catalytic effect Effects 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 6
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 24
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 24
- 239000010936 titanium Substances 0.000 description 21
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- 239000002904 solvent Substances 0.000 description 6
- 238000006555 catalytic reaction Methods 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
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- 238000000634 powder X-ray diffraction Methods 0.000 description 3
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- 238000003786 synthesis reaction Methods 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
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- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000005215 recombination Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- CBACFHTXHGHTMH-UHFFFAOYSA-N 2-piperidin-1-ylethyl 2-phenyl-2-piperidin-1-ylacetate;dihydrochloride Chemical compound Cl.Cl.C1CCCCN1C(C=1C=CC=CC=1)C(=O)OCCN1CCCCC1 CBACFHTXHGHTMH-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000013206 MIL-53 Substances 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- WVPXXDAFPMKJQQ-UHFFFAOYSA-N [Ag+].[S-2].[Cd+2] Chemical compound [Ag+].[S-2].[Cd+2] WVPXXDAFPMKJQQ-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- LHQLJMJLROMYRN-UHFFFAOYSA-L cadmium acetate Chemical compound [Cd+2].CC([O-])=O.CC([O-])=O LHQLJMJLROMYRN-UHFFFAOYSA-L 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 238000003421 catalytic decomposition reaction Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000002508 compound effect Effects 0.000 description 1
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- 239000003814 drug Substances 0.000 description 1
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- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
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- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002073 nanorod Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
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- 238000007254 oxidation reaction Methods 0.000 description 1
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- 239000001509 sodium citrate Substances 0.000 description 1
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- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/36—Organic compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Catalysts (AREA)
Abstract
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CN201710841240.8A CN107670695B (zh) | 2017-09-18 | 2017-09-18 | 一种核-壳异质结构材料的制备方法 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109569732A (zh) * | 2019-01-17 | 2019-04-05 | 济南大学 | 一种一锅法制备MIL-100(Fe)/BiOCl复合光催化剂的方法 |
CN111450898A (zh) * | 2020-05-18 | 2020-07-28 | 安徽工业大学 | 光催化降解有机染料的无定形CoSx/MOF复合催化剂及制备方法 |
CN112275275A (zh) * | 2020-10-13 | 2021-01-29 | 西北师范大学 | 一种多孔小尺寸Mo掺杂的Ti基金属材料及其制备方法和应用 |
CN113398996A (zh) * | 2021-06-21 | 2021-09-17 | 华东交通大学 | 一种CdS@UIO-66-NH2核壳复合材料的制备方法 |
Citations (5)
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US7908902B2 (en) * | 2008-10-16 | 2011-03-22 | Emitech, Inc | Amplified sensitivity of porous chemosensors based on bernoulli effect |
CN103316714A (zh) * | 2013-06-28 | 2013-09-25 | 中国石油大学(北京) | 一种光催化分解水制氢用催化剂及其制备方法 |
CN105944739A (zh) * | 2016-05-27 | 2016-09-21 | 郑州大学 | 一种基于二氧化钛与硫化钼复合的半导体产氢催化剂及其制备方法和应用 |
CN106582719A (zh) * | 2016-10-25 | 2017-04-26 | 上海大学 | 一种CdS/MIL‑53(Fe)可见光催化剂的制备方法 |
CN107159313A (zh) * | 2017-06-14 | 2017-09-15 | 上海应用技术大学 | 一种核壳结构TiO2纳米管@Ti‑MOF催化剂的制备方法 |
-
2017
- 2017-09-18 CN CN201710841240.8A patent/CN107670695B/zh active Active
Patent Citations (5)
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US7908902B2 (en) * | 2008-10-16 | 2011-03-22 | Emitech, Inc | Amplified sensitivity of porous chemosensors based on bernoulli effect |
CN103316714A (zh) * | 2013-06-28 | 2013-09-25 | 中国石油大学(北京) | 一种光催化分解水制氢用催化剂及其制备方法 |
CN105944739A (zh) * | 2016-05-27 | 2016-09-21 | 郑州大学 | 一种基于二氧化钛与硫化钼复合的半导体产氢催化剂及其制备方法和应用 |
CN106582719A (zh) * | 2016-10-25 | 2017-04-26 | 上海大学 | 一种CdS/MIL‑53(Fe)可见光催化剂的制备方法 |
CN107159313A (zh) * | 2017-06-14 | 2017-09-15 | 上海应用技术大学 | 一种核壳结构TiO2纳米管@Ti‑MOF催化剂的制备方法 |
Non-Patent Citations (2)
Title |
---|
王侯,: ""基于金属(钛)有机框架的光催化材的制备及其在可见光下去除水中污染物的应用与机理研究"", 《万方学位论文数据库》 * |
覃燕兰,: ""CdS/Ti-MOF光催化材料的制备及性能研究"", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109569732A (zh) * | 2019-01-17 | 2019-04-05 | 济南大学 | 一种一锅法制备MIL-100(Fe)/BiOCl复合光催化剂的方法 |
CN109569732B (zh) * | 2019-01-17 | 2021-04-06 | 济南大学 | 一种一锅法制备MIL-100(Fe)/BiOCl复合光催化剂的方法 |
CN111450898A (zh) * | 2020-05-18 | 2020-07-28 | 安徽工业大学 | 光催化降解有机染料的无定形CoSx/MOF复合催化剂及制备方法 |
CN111450898B (zh) * | 2020-05-18 | 2021-12-21 | 安徽工业大学 | 光催化降解有机染料的无定形CoSx/MOF复合催化剂及制备方法 |
CN112275275A (zh) * | 2020-10-13 | 2021-01-29 | 西北师范大学 | 一种多孔小尺寸Mo掺杂的Ti基金属材料及其制备方法和应用 |
CN112275275B (zh) * | 2020-10-13 | 2022-11-15 | 西北师范大学 | 一种多孔小尺寸Mo掺杂的Ti基金属材料及其制备方法和应用 |
CN113398996A (zh) * | 2021-06-21 | 2021-09-17 | 华东交通大学 | 一种CdS@UIO-66-NH2核壳复合材料的制备方法 |
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