CN107555869A - A kind of good plasticine of plasticity - Google Patents
A kind of good plasticine of plasticity Download PDFInfo
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- CN107555869A CN107555869A CN201710766125.9A CN201710766125A CN107555869A CN 107555869 A CN107555869 A CN 107555869A CN 201710766125 A CN201710766125 A CN 201710766125A CN 107555869 A CN107555869 A CN 107555869A
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Abstract
The invention discloses a kind of good plasticine of plasticity, including following components by weight percent：40 60 parts of Concave-convex clay rod gel powder,15 20 parts of modification infusorial earth,11 16 parts of beeswax,59 parts of vaseline,37 parts of rosin,4 12 parts of camphorated oil,15 parts of D-sorbite,26 parts of Arabic gum,13 parts of carragheen,0.1 2 parts of sodium tripolyphosphate,0.5 1.5 parts of natural plant pigment,0.1 0.5 parts of antiseptic,0.3 0.6 parts of erucyl amide,5 10 parts of deionized water,The plasticity of plasticine of the present invention is good,It is tack-free using process,The artifacts made using plasticine of the present invention are shelved will not also be hardened for a long time,So as to reuse,And harmful heavy metal and volatile chemical products are not contained in inventive formulation,The pigment used is also natural plant pigment,It is more environmentally-friendly,Potential threat will not be formed to children's health.
Description
Technical field
The present invention relates to toy for children field, the good plasticine of more particularly to a kind of plasticity.
Background technology
From after plasticine appearance, mud is instead of as modern toys, into one of favorite toy of children, rubber
Mud is also used to children, the instrument of juvenile's study, can be played in middle school is played, learn.Because it has stronger plasticity and reduction
Property, and cost is cheap, and is liked by people, by identifying color, pinches model etc., can promote children, juvenile to color, size,
The cognitive ability of shape etc., culture children, the divergent thinking of juvenile, so as to open the door of young, juvenile imagination.
Plasticine on the market is by flour, grease, talcum powder, Paris white, miberal powder, spices, pigment, anti-mostly
Rotten agent, poster paint, industrial pigment and water composition.Flour mixes under normal temperature condition with water, and adhesive property is relatively low, talcum powder,
Paris white and miberal powder can not form mineral gels after being mixed with water, be entirely to depend on flour and grease and be bonded together.This
Kind plasticine plasticity is poor, and the finished product after making, which easily produces, to be dried, ftractures, deforms, be mouldy and rotten, in manufacturing process
In operator is had a kind of greasy feeling on hand, it is bad to reuse effect.
The content of the invention
In view of the deficienciess of the prior art, it is an object of the invention to provide a kind of good plasticine of plasticity, it is plastic
Property it is good, tack-free using process, the artifacts of making are shelved and will not be also hardened for a long time, so as to reuse.
To achieve the above object, the invention provides following technical scheme：A kind of good plasticine of plasticity, including it is as follows
Components by weight percent：
Concave-convex clay rod gel powder 40-60 parts, modification infusorial earth 15-20 parts, beeswax 11-16 parts, vaseline 5-9 parts,
Rosin 3-7 parts, camphorated oil 4-12 parts, D-sorbite 1-5 parts, Arabic gum 2-6 parts, carragheen 1-3 parts, sodium tripolyphosphate 0.1-
2 parts, natural plant pigment 0.5-1.5 parts, antiseptic 0.1-0.5 parts, erucyl amide 0.3-0.6 parts, deionized water 5-10 parts.
As a further improvement on the present invention, including following components by weight percent：
55 parts of Concave-convex clay rod gel powder, 18 parts of modification infusorial earth, 11 parts of beeswax, 7 parts of vaseline, 5 parts of rosin, camphor
10 parts of oil, 3 parts of D-sorbite, 3 parts of Arabic gum, 1 part of carragheen, 0.7 part of sodium tripolyphosphate, 0.8 part of natural pigment, antiseptic
0.3 part, 0.5 part of erucyl amide, 8 parts of deionized water.
As a further improvement on the present invention, the specific preparation process of Concave-convex clay rod gel is as follows：
(1), 100g Concave-convex clay rods raw ore is passed through to the weathering of 30-120 days；
(2) Concave-convex clay rod after weathering, is taken to be dispersed in the phytic acid that mass concentration is 10-30% after crushing water-soluble
In liquid, it is 5-20% attapulgite clay water suspensions that mass concentration, which is made, crosses 200-300 mesh sieves and removes impurity, is warming up to 75-90
DEG C, 3-10h is reacted, is cooled to room temperature；
(3) above-mentioned steps (2), are obtained into material 55-75kg/cm2Pressure rolls to obtain wet feed, is added into wet feed
The double octadecyldimethyl ammoniums of 10-25g brominations, soak 1-2 days；
(4) step (3), is obtained into wet feed at 110 DEG C to be dried, be milled 200 mesh sieves, obtains Concave-convex clay rod
Gel powder.
As a further improvement on the present invention, the specific preparation process of the modification infusorial earth is as follows：
A, after 100g diatomite being put into 25-30% sodium hydroxide solutions immersion 3-5h, filtrate is washed with water in neutrality；
B, the liquor potassic permanganate for obtaining adding 10-15% in material to step a soaks 3-6h, filtering, at 55-60 DEG C
It is 3-5% to be dried to water content；
C, obtain adding 50-100g vinyl silane tri-butyl peroxy, 30-45g lignin in material to step b
Sulfoacid calcium, 40-50g titanium oxide, 50-70g carboxymethyl cellulose, ground after stirring 15-30min under 1800-2000r/min
Grind as 0.8-1.0 μm of powder, obtain modification infusorial earth.
As a further improvement on the present invention, the good plasticine preparation method of plasticity is as follows：
1), first deionized water is added in mixer, then D-sorbite, Arabic gum, carragheen, sodium tripolyphosphate, day
Right pigment, antiseptic add in deionized water and are stirred to obtain gel solution；
2), Concave-convex clay rod gel powder, modification infusorial earth and beeswax are added in gel solution and are uniformly mixed, is added
Heat keeps 2-4h to 30-45 DEG C；
3) vaseline, rosin, camphorated oil, erucyl amide, are added into step 2) to obtain being stirred in material, stirring is equal
12-24h is stood after even and both obtains plasticine finished product.
As a further improvement on the present invention, the natural plant pigment preparation method is as follows：
A) blue dyeing liquid is prepared：Take 50-60 parts by weight woaded blue cauline leafs to be cut into segment, be mixed into 0.5-0.8 parts by weight gooseberries
Fruit, it is placed in fermentation vat, adding clear water is totally submerged raw material, then toward adding milk of lime in fermentation vat and stir, institute
The main component for stating milk of lime is the calcium hydroxide aqueous solution that mass fraction is 38.6%, and the amount of addition is addition woaded blue weight
28-33%, fermentation vat cover film and are sealed by fermentation 5-7 days in normal temperature, then stir zymotic fluid, filter off residue and obtain blue dyeing
Liquid；
B) yellow dyeing liquor is produced：Pickled being added to after fresh lemon peel chopping in 20-35% sodium chloride solution
1-3h, then it is transferred in extractor, adds ethanol and be stripped, extracting reclaims ethanol after terminating, and obtains yellow dyeing liquor；
C) red staining liquid is produced：Fresh safflower is laid into 3-4h in the cool, then inserts at 95-100 DEG C and dries
0.6h-0.9h, beats powder and crosses 300 sieve meshes and obtain safflower fine powder；Take fresh Asian puccoon to lay 4-6h in the cool, then insert 95-
0.8h-1h is dried in 100 DEG C of drying machine, powder is beaten and crosses 300 sieve meshes and obtain Asian puccoon fine powder；By in 25-35 parts by weight Schisandra fruits
95-110 parts by weight water immersion 1-2h is added, 95-99 DEG C of heating 10-30min is warming up to, adds 40-45 parts by weight safflowers
Fine powder and 9-15 parts by weight Asian puccoon fine powders, 0.3-0.5h is stirred, normal temperature is cooled to, that is, red staining liquid is made；
D) one or more in the blueness of above-mentioned preparation, yellow and red staining liquid are mixed, be concentrated under reduced pressure dry
It is dry to obtain natural plant pigment.
As a further improvement on the present invention, the antiseptic is methyl hydroxybenzoate and propylben according to 1:2-1:3
The mixture being re-dubbed.
The good plasticine of plasticity of the invention, using Concave-convex clay rod gel powder and modification infusorial earth as main component,
Make plasticine that there is excellent plasticity and appropriate soft durometer, and cost is cheap, beeswax has good toughness, in formula
Effect be to utilize its density, viscosity, hardness, tensile viscosity and kinematic viscosity at normal temperatures and the affinity held
Power, make plasticine in use it is not easy to stick on hand, effect of the vaseline in formula is to soften beeswax and rosin, is formed
Plasticity feel, effect of the rosin in formula are regulation viscosity, density and hardness, and the effect of camphorated oil contributes to naturally plant
Look for element to be uniformly dispersed in mixed system, and contribute to color to keep, D-sorbite has water retention, can protect plasticine
Hold softness, high resilience, Arabic gum has dissolubility, good emulsification thickening characteristic in the water of height, moreover it is possible to improves rubber
The polishing effect of mud, arranged in pairs or groups simultaneously using carragheen in formula, be to adjust the stability of mixed system, while carragheen
Film forming characteristics can prevent that sodium tripolyphosphate is that a kind of moisture content is protected on skin for natural plant pigment contamination in use
Agent, softening agent and thickener are held, and the vividness of natural plant pigment in plasticine can be stablized, the effect of antiseptic is to prevent rubber
Skin mud is contaminated in long-time placement process, and erucyl amide can make plasticine have a smooth feel, and skin contact is more comfortable.
The artifacts made using plasticine of the present invention are shelved will not also be hardened for a long time, so as to reuse, and the present invention
Harmful heavy metal and volatile chemical products are not contained in formula, the pigment used is also natural plant pigment, more environmentally-friendly, no
Potential threat can be formed to children's health.
Embodiment
The present invention is described in further detail below in conjunction with embodiment.
Embodiment 1
A kind of good plasticine of plasticity, including following components by weight percent：
40 parts of Concave-convex clay rod gel powder, 15 parts of modification infusorial earth, 11 parts of beeswax, 5 parts of vaseline, 3 parts of rosin, camphor
It is 4 parts of oil, 1 part of D-sorbite, 2 parts of Arabic gum, 1 part of carragheen, 0.1 part of sodium tripolyphosphate, 0.5 part of natural plant pigment, anti-
0.1 part of microbial inoculum, 0.3 part of erucyl amide, 5 parts of deionized water.
Antiseptic is methyl hydroxybenzoate and propylben according to 1:2 mixtures being re-dubbed.
The natural plant pigment preparation method is as follows：
A) blue dyeing liquid is prepared：Take 50 parts by weight woaded blue cauline leafs to be cut into segment, be mixed into 0.5 parts by weight gooseberry fruit, be placed in
In fermentation vat, adding clear water is totally submerged raw material, then toward adding milk of lime in fermentation vat and stir, the milk of lime
Main component be calcium hydroxide aqueous solution that mass fraction is 38.6%, the amount of addition is adds the 28% of woaded blue weight, hair
Ferment pond covers film and is sealed by fermentation 5 days in normal temperature, then stirs zymotic fluid, filters off residue and obtains blue dyeing liquid；
B) yellow dyeing liquor is produced：1h is pickled by being added to after fresh lemon peel chopping in 20% sodium chloride solution,
Then it is transferred in extractor, adds ethanol and be stripped, extracting reclaims ethanol after terminating, and obtains yellow dyeing liquor；
C) red staining liquid is produced：Fresh safflower is laid into 3h in the cool, then inserts and 0.6h is dried at 95 DEG C, beat
Powder crosses 300 sieve meshes and obtains safflower fine powder；Take fresh Asian puccoon to lay 4h in the cool, then insert in 95 DEG C of drying machine and dry
0.8h, beats powder and crosses 300 sieve meshes and obtain Asian puccoon fine powder；95 parts by weight water immersion 1h, heating will be added in 25 parts by weight Schisandra fruits
To 95 DEG C of heating 10min, 40 parts by weight safflower fine powders and 9 parts by weight Asian puccoon fine powders are added, stir 0.3h, are cooled to often
Temperature, that is, red staining liquid is made；
D) one or more in the blueness of above-mentioned preparation, yellow and red staining liquid are mixed, be concentrated under reduced pressure dry
It is dry to obtain natural plant pigment.
The specific preparation process of Concave-convex clay rod gel is as follows：
(1), 100g Concave-convex clay rods raw ore is passed through to the weathering of 30 days；
(2) Concave-convex clay rod after weathering, is taken to be dispersed in the phytic acid aqueous solution that mass concentration is 10% after crushing
In, it is 5% attapulgite clay water suspensions that mass concentration, which is made, crosses 200 mesh sieves and removes impurity, is warming up to 75 DEG C, reacts 3h, cold
But to room temperature；
(3) above-mentioned steps (2), are obtained into material 55kg/cm2Pressure is rolled to obtain wet feed, and 10g bromines are added into wet feed
Change double octadecyldimethyl ammoniums, soak 1 day；
(4) step (3), is obtained into wet feed at 110 DEG C to be dried, be milled 200 mesh sieves, obtains Concave-convex clay rod
Gel powder.
The specific preparation process of modification infusorial earth is as follows：
A, after 100g diatomite being put into 25% sodium hydroxide solution immersion 3h, filtrate is washed with water in neutrality；
B, the liquor potassic permanganate for obtaining adding 10% in material to step a soaks 3h, filtering, is dried to and contains at 55 DEG C
Water is 3%；
C, to step b obtain adding in material 50g vinyl silane tri-butyl peroxy, 30g calcium lignosulfonate,
40g titanium oxide, 50g carboxymethyl cellulose, 0.8 μm of powder is ground to after stirring 15min under 1800r/min, is changed
Property diatomite.
The good plasticine preparation method of plasticity is as follows：
1), first deionized water is added in mixer, then D-sorbite, Arabic gum, carragheen, sodium tripolyphosphate, day
Right pigment, antiseptic add in deionized water and are stirred to obtain gel solution；
2), Concave-convex clay rod gel powder, modification infusorial earth and beeswax are added in gel solution and are uniformly mixed, is added
Heat keeps 2h to 30 DEG C；
3) vaseline, rosin, camphorated oil, erucyl amide, are added into step 2) to obtain being stirred in material, stirring is equal
12h is stood after even and both obtains plasticine finished product.
Embodiment 2
A kind of good plasticine of plasticity, including following components by weight percent：
55 parts of Concave-convex clay rod gel powder, 18 parts of modification infusorial earth, 11 parts of beeswax, 7 parts of vaseline, 5 parts of rosin, camphor
10 parts of oil, 3 parts of D-sorbite, 3 parts of Arabic gum, 1 part of carragheen, 0.7 part of sodium tripolyphosphate, 0.8 part of natural pigment, antiseptic
0.3 part, 0.5 part of erucyl amide, 8 parts of deionized water.
The antiseptic is methyl hydroxybenzoate and propylben according to 1:2 mixtures being re-dubbed.
The natural plant pigment preparation method is as follows：
A) blue dyeing liquid is prepared：Take 52 parts by weight woaded blue cauline leafs to be cut into segment, be mixed into 0.6 parts by weight gooseberry fruit, be placed in
In fermentation vat, adding clear water is totally submerged raw material, then toward adding milk of lime in fermentation vat and stir, the milk of lime
Main component be calcium hydroxide aqueous solution that mass fraction is 38.6%, the amount of addition is adds the 29% of woaded blue weight, hair
Ferment pond covers film and is sealed by fermentation 5 days in normal temperature, then stirs zymotic fluid, filters off residue and obtains blue dyeing liquid；
B) yellow dyeing liquor is produced：1h is pickled by being added to after fresh lemon peel chopping in 22% sodium chloride solution,
Then it is transferred in extractor, adds ethanol and be stripped, extracting reclaims ethanol after terminating, and obtains yellow dyeing liquor；
C) red staining liquid is produced：Fresh safflower is laid into 3h in the cool, then inserts and 0.7h is dried at 96 DEG C, beat
Powder crosses 300 sieve meshes and obtains safflower fine powder；Take fresh Asian puccoon to lay 5h in the cool, then insert in 96 DEG C of drying machine and dry
0.8h, beats powder and crosses 300 sieve meshes and obtain Asian puccoon fine powder；98 parts by weight water immersion 1h, heating will be added in 26 parts by weight Schisandra fruits
To 96 DEG C of heating 15min, 41 parts by weight safflower fine powders and 10 parts by weight Asian puccoon fine powders are added, stir 0.4h, are cooled to often
Temperature, that is, red staining liquid is made；
D) one or more in the blueness of above-mentioned preparation, yellow and red staining liquid are mixed, be concentrated under reduced pressure dry
It is dry to obtain natural plant pigment.
The specific preparation process of Concave-convex clay rod gel is as follows：
(1), 100g Concave-convex clay rods raw ore is passed through to the weathering of 50 days；
(2) Concave-convex clay rod after weathering, is taken to be dispersed in the phytic acid aqueous solution that mass concentration is 15% after crushing
In, it is 8% attapulgite clay water suspensions that mass concentration, which is made, crosses 200 mesh sieves and removes impurity, is warming up to 78 DEG C, reacts 4h, cold
But to room temperature；
(3) above-mentioned steps (2), are obtained into material 60kg/cm2Pressure is rolled to obtain wet feed, and 15g bromines are added into wet feed
Change double octadecyldimethyl ammoniums, soak 2 days；
(4) step (3), is obtained into wet feed at 110 DEG C to be dried, be milled 200 mesh sieves, obtains Concave-convex clay rod
Gel powder.
The specific preparation process of modification infusorial earth is as follows：
A, after 100g diatomite being put into 26% sodium hydroxide solution immersion 4h, filtrate is washed with water in neutrality；
B, the liquor potassic permanganate for obtaining adding 11% in material to step a soaks 4h, filtering, is dried to and contains at 56 DEG C
Water is 4%；
C, to step b obtain adding in material 60g vinyl silane tri-butyl peroxy, 33g calcium lignosulfonate,
42g titanium oxide, 55g carboxymethyl cellulose, 0.8 μm of powder is ground to after stirring 18min under 1800r/min, is changed
Property diatomite.
The good plasticine preparation method of plasticity is as follows：
1), first deionized water is added in mixer, then D-sorbite, Arabic gum, carragheen, sodium tripolyphosphate, day
Right pigment, antiseptic add in deionized water and are stirred to obtain gel solution；
2), Concave-convex clay rod gel powder, modification infusorial earth and beeswax are added in gel solution and are uniformly mixed, is added
Heat keeps 3h to 36 DEG C；
3) vaseline, rosin, camphorated oil, erucyl amide, are added into step 2) to obtain being stirred in material, stirring is equal
15h is stood after even and both obtains plasticine finished product.
Embodiment 3
A kind of good plasticine of plasticity, including following components by weight percent：
45 parts of Concave-convex clay rod gel powder, 16 parts of modification infusorial earth, 12 parts of beeswax, 6 parts of vaseline, 4 parts of rosin, camphor
It is 5 parts of oil, 2 parts of D-sorbite, 3 parts of Arabic gum, 2 parts of carragheen, 0.5 part of sodium tripolyphosphate, 0.6 part of natural plant pigment, anti-
0.2 part of microbial inoculum, 0.4 part of erucyl amide, 6 parts of deionized water.
The natural plant pigment preparation method is as follows：
A) blue dyeing liquid is prepared：Take 53 parts by weight woaded blue cauline leafs to be cut into segment, be mixed into 0.7 parts by weight gooseberry fruit, be placed in
In fermentation vat, adding clear water is totally submerged raw material, then toward adding milk of lime in fermentation vat and stir, the milk of lime
Main component be calcium hydroxide aqueous solution that mass fraction is 38.6%, the amount of addition is adds the 29% of woaded blue weight, hair
Ferment pond covers film and is sealed by fermentation 6 days in normal temperature, then stirs zymotic fluid, filters off residue and obtains blue dyeing liquid；
B) yellow dyeing liquor is produced：2h is pickled by being added to after fresh lemon peel chopping in 29% sodium chloride solution,
Then it is transferred in extractor, adds ethanol and be stripped, extracting reclaims ethanol after terminating, and obtains yellow dyeing liquor；
C) red staining liquid is produced：Fresh safflower is laid into 3h in the cool, then inserts and 0.8h is dried at 97 DEG C, beat
Powder crosses 300 sieve meshes and obtains safflower fine powder；Take fresh Asian puccoon to lay 5h in the cool, then insert in 97 DEG C of drying machine and dry
0.9h, beats powder and crosses 300 sieve meshes and obtain Asian puccoon fine powder；99 parts by weight water immersion 2h, heating will be added in 30 parts by weight Schisandra fruits
To 97 DEG C of heating 15min, 42 parts by weight safflower fine powders and 11 parts by weight Asian puccoon fine powders are added, stir 0.4h, are cooled to often
Temperature, that is, red staining liquid is made；
D) one or more in the blueness of above-mentioned preparation, yellow and red staining liquid are mixed, be concentrated under reduced pressure dry
It is dry to obtain natural plant pigment.
The antiseptic is methyl hydroxybenzoate and propylben according to 1:3 mixtures being re-dubbed.
The specific preparation process of Concave-convex clay rod gel is as follows：
(1), 100g Concave-convex clay rods raw ore is passed through to the weathering of 60 days；
(2) Concave-convex clay rod after weathering, is taken to be dispersed in the phytic acid aqueous solution that mass concentration is 15% after crushing
In, it is 10% attapulgite clay water suspensions that mass concentration, which is made, crosses 200 mesh sieves and removes impurity, be warming up to 80 DEG C, reacts 6h,
It is cooled to room temperature；
(3) above-mentioned steps (2), are obtained into material 70kg/cm2Pressure is rolled to obtain wet feed, and 15g bromines are added into wet feed
Change double octadecyldimethyl ammoniums, soak 2 days；
(4) step (3), is obtained into wet feed at 110 DEG C to be dried, be milled 200 mesh sieves, obtains Concave-convex clay rod
Gel powder.
The specific preparation process of modification infusorial earth is as follows：
A, after 100g diatomite being put into 27% sodium hydroxide solution immersion 5h, filtrate is washed with water in neutrality；
B, the liquor potassic permanganate for obtaining adding 13% in material to step a soaks 5h, filtering, is dried to and contains at 57 DEG C
Water is 5%；
C, to step b obtain adding in material 70g vinyl silane tri-butyl peroxy, 33g calcium lignosulfonate,
44g titanium oxide, 55g carboxymethyl cellulose, 1.0 μm of powder are ground to after stirring 20min under 2000r/min, are changed
Property diatomite.
The good plasticine preparation method of plasticity is as follows：
1), first deionized water is added in mixer, then D-sorbite, Arabic gum, carragheen, sodium tripolyphosphate, day
Right pigment, antiseptic add in deionized water and are stirred to obtain gel solution；
2), Concave-convex clay rod gel powder, modification infusorial earth and beeswax are added in gel solution and are uniformly mixed, is added
Heat keeps 3h to 35 DEG C；
(3) vaseline, rosin, camphorated oil, erucyl amide, are added into step 2) to obtain being stirred in material, stirred
20h is stood after uniformly and both obtains plasticine finished product.
Embodiment 4
A kind of good plasticine of plasticity, including following components by weight percent：
50 parts of Concave-convex clay rod gel powder, 17 parts of modification infusorial earth, 13 parts of beeswax, 8 parts of vaseline, 6 parts of rosin, camphor
It is 6 parts of oil, 3 parts of D-sorbite, 4 parts of Arabic gum, 3 parts of carragheen, 0.8 part of sodium tripolyphosphate, 0.9 part of natural plant pigment, anti-
0.4 part of microbial inoculum, 0.5 part of erucyl amide, 8 parts of deionized water.
The natural plant pigment preparation method is as follows：
A) blue dyeing liquid is prepared：Take 56 parts by weight woaded blue cauline leafs to be cut into segment, be mixed into 0.6 parts by weight gooseberry fruit, be placed in
In fermentation vat, adding clear water is totally submerged raw material, then toward adding milk of lime in fermentation vat and stir, the milk of lime
Main component be calcium hydroxide aqueous solution that mass fraction is 38.6%, the amount of addition is adds the 30% of woaded blue weight, hair
Ferment pond covers film and is sealed by fermentation 7 days in normal temperature, then stirs zymotic fluid, filters off residue and obtains blue dyeing liquid；
B) yellow dyeing liquor is produced：2h is pickled by being added to after fresh lemon peel chopping in 30% sodium chloride solution,
Then it is transferred in extractor, adds ethanol and be stripped, extracting reclaims ethanol after terminating, and obtains yellow dyeing liquor；
C) red staining liquid is produced：Fresh safflower is laid into 4h in the cool, then inserts and 0.6h is dried at 98 DEG C, beat
Powder crosses 300 sieve meshes and obtains safflower fine powder；Take fresh Asian puccoon to lay 5h in the cool, then insert in 98 DEG C of drying machine and dry
1h, beats powder and crosses 300 sieve meshes and obtain Asian puccoon fine powder；100 parts by weight water immersion 1-2h, heating will be added in 30 parts by weight Schisandra fruits
To 97 DEG C of heating 20min, 43 parts by weight safflower fine powders and 13 parts by weight Asian puccoon fine powders are added, stir 0.4h, are cooled to often
Temperature, that is, red staining liquid is made；
D) one or more in the blueness of above-mentioned preparation, yellow and red staining liquid are mixed, be concentrated under reduced pressure dry
It is dry to obtain natural plant pigment.
The antiseptic is methyl hydroxybenzoate and propylben according to 1:3 mixtures being re-dubbed.
The specific preparation process of Concave-convex clay rod gel is as follows：
(1), 100g Concave-convex clay rods raw ore is passed through to the weathering of 80 days；
(2) Concave-convex clay rod after weathering, is taken to be dispersed in the phytic acid aqueous solution that mass concentration is 25% after crushing
In, it is 16% attapulgite clay water suspensions that mass concentration, which is made, crosses 300 mesh sieves and removes impurity, be warming up to 80 DEG C, reacts 6h,
It is cooled to room temperature；
(3) above-mentioned steps (2), are obtained into material 65kg/cm2Pressure is rolled to obtain wet feed, and 22g bromines are added into wet feed
Change double octadecyldimethyl ammoniums, soak 2 days；
(4) step (3), is obtained into wet feed at 110 DEG C to be dried, be milled 200 mesh sieves, obtains Concave-convex clay rod
Gel powder.
The specific preparation process of modification infusorial earth is as follows：
A, after 100g diatomite being put into 28% sodium hydroxide solution immersion 4h, filtrate is washed with water in neutrality；
B, the liquor potassic permanganate for obtaining adding 13% in material to step a soaks 4h, filtering, is dried to and contains at 57 DEG C
Water is 4%；
C, to step b obtain adding in material 80g vinyl silane tri-butyl peroxy, 40g calcium lignosulfonate,
46g titanium oxide, 55g carboxymethyl cellulose, 0.9 μm of powder is ground to after stirring 15min under 1800r/min, is changed
Property diatomite.
The good plasticine preparation method of plasticity is as follows：
1), first deionized water is added in mixer, then D-sorbite, Arabic gum, carragheen, sodium tripolyphosphate, day
Right pigment, antiseptic add in deionized water and are stirred to obtain gel solution；
2), Concave-convex clay rod gel powder, modification infusorial earth and beeswax are added in gel solution and are uniformly mixed, is added
Heat keeps 3h to 42 DEG C；
3) vaseline, rosin, camphorated oil, erucyl amide, are added into step 2) to obtain being stirred in material, stirring is equal
20h is stood after even and both obtains plasticine finished product.
Embodiment 5
A kind of good plasticine of plasticity, including following components by weight percent：
58 parts of Concave-convex clay rod gel powder, 19 parts of modification infusorial earth, 15 parts of beeswax, 8 parts of vaseline, 6 parts of rosin, camphor
10 parts of oil, 4 parts of D-sorbite, 5 parts of Arabic gum, 3 parts of carragheen, 1.5 parts of sodium tripolyphosphate, 1 part of natural plant pigment, antibacterial
0.4 part of agent, 0.5 part of erucyl amide, 9 parts of deionized water.The natural plant pigment preparation method is as follows：
A) blue dyeing liquid is prepared：Take 58 parts by weight woaded blue cauline leafs to be cut into segment, be mixed into 0.7 parts by weight gooseberry fruit, be placed in
In fermentation vat, adding clear water is totally submerged raw material, then toward adding milk of lime in fermentation vat and stir, the milk of lime
Main component be calcium hydroxide aqueous solution that mass fraction is 38.6%, the amount of addition is adds the 32% of woaded blue weight, hair
Ferment pond covers film and is sealed by fermentation 6 days in normal temperature, then stirs zymotic fluid, filters off residue and obtains blue dyeing liquid；
B) yellow dyeing liquor is produced：3h is pickled by being added to after fresh lemon peel chopping in 30% sodium chloride solution,
Then it is transferred in extractor, adds ethanol and be stripped, extracting reclaims ethanol after terminating, and obtains yellow dyeing liquor；
C) red staining liquid is produced：Fresh safflower is laid into 4h in the cool, then inserts and 0.9h is dried at 99 DEG C, beat
Powder crosses 300 sieve meshes and obtains safflower fine powder；Take fresh Asian puccoon to lay 5h in the cool, then insert in 99 DEG C of drying machine and dry
1h, beats powder and crosses 300 sieve meshes and obtain Asian puccoon fine powder；105 parts by weight water immersion 2h will be added in 33 parts by weight Schisandra fruits, is warming up to
99 DEG C of heating 30min, add 42 parts by weight safflower fine powders and 13 parts by weight Asian puccoon fine powders, stir 0.4h, be cooled to normal temperature,
Red staining liquid is made；
D) one or more in the blueness of above-mentioned preparation, yellow and red staining liquid are mixed, be concentrated under reduced pressure dry
It is dry to obtain natural plant pigment.
The antiseptic is methyl hydroxybenzoate and propylben according to 1:3 mixtures being re-dubbed.
The specific preparation process of Concave-convex clay rod gel is as follows：
(1), 100g Concave-convex clay rods raw ore is passed through to the weathering of 100 days；
(2) Concave-convex clay rod after weathering, is taken to be dispersed in the phytic acid aqueous solution that mass concentration is 25% after crushing
In, it is 18% attapulgite clay water suspensions that mass concentration, which is made, crosses 300 mesh sieves and removes impurity, be warming up to 85 DEG C, reacts 7h,
It is cooled to room temperature；
(3) above-mentioned steps (2), are obtained into material 70kg/cm2Pressure is rolled to obtain wet feed, and 20g bromines are added into wet feed
Change double octadecyldimethyl ammoniums, soak 2 days；
(4) step (3), is obtained into wet feed at 110 DEG C to be dried, be milled 200 mesh sieves, obtains Concave-convex clay rod
Gel powder.
The specific preparation process of modification infusorial earth is as follows：
A, after 100g diatomite being put into 29% sodium hydroxide solution immersion 5h, filtrate is washed with water in neutrality；
B, the liquor potassic permanganate for obtaining adding 14% in material to step a soaks 5h, filtering, is dried to and contains at 58 DEG C
Water is 4%；
C, to step b obtain adding in material 90g vinyl silane tri-butyl peroxy, 40g calcium lignosulfonate,
45g titanium oxide, 65g carboxymethyl cellulose, 1.0 μm of powder are ground to after stirring 25min under 1900r/min, are changed
Property diatomite.
The good plasticine preparation method of plasticity is as follows：
1), first deionized water is added in mixer, then D-sorbite, Arabic gum, carragheen, sodium tripolyphosphate, day
Right pigment, antiseptic add in deionized water and are stirred to obtain gel solution；
2), Concave-convex clay rod gel powder, modification infusorial earth and beeswax are added in gel solution and are uniformly mixed, is added
Heat keeps 4h to 40 DEG C；
3) vaseline, rosin, camphorated oil, erucyl amide, are added into step (2) to obtain being stirred in material, stirred
22h is stood after uniformly and both obtains plasticine finished product.
Embodiment 6
A kind of good plasticine of plasticity, including following components by weight percent：
60 parts of Concave-convex clay rod gel powder, 20 parts of modification infusorial earth, 16 parts of beeswax, 9 parts of vaseline, 7 parts of rosin, camphor
12 parts of oil, 5 parts of D-sorbite, 6 parts of Arabic gum, 3 parts of carragheen, 2 parts of sodium tripolyphosphate, 1.5 parts of natural plant pigment, antibacterial
0.5 part of agent, 0.6 part of erucyl amide, 10 parts of deionized water.
The natural plant pigment preparation method is as follows：
A) blue dyeing liquid is prepared：Take 60 parts by weight woaded blue cauline leafs to be cut into segment, be mixed into 0.8 parts by weight gooseberry fruit, be placed in
In fermentation vat, adding clear water is totally submerged raw material, then toward adding milk of lime in fermentation vat and stir, the milk of lime
Main component be calcium hydroxide aqueous solution that mass fraction is 38.6%, the amount of addition is adds the 33% of woaded blue weight, hair
Ferment pond covers film and is sealed by fermentation 7 days in normal temperature, then stirs zymotic fluid, filters off residue and obtains blue dyeing liquid；
B) yellow dyeing liquor is produced：3h is pickled by being added to after fresh lemon peel chopping in 35% sodium chloride solution,
Then it is transferred in extractor, adds ethanol and be stripped, extracting reclaims ethanol after terminating, and obtains yellow dyeing liquor；
C) red staining liquid is produced：Fresh safflower is laid into 4h in the cool, then inserts and 0.9h is dried at 100 DEG C,
Powder is beaten to cross 300 sieve meshes and obtain safflower fine powder；Take fresh Asian puccoon to lay 6h in the cool, then insert in 100 DEG C of drying machine
1h is dried, powder is beaten and crosses 300 sieve meshes and obtain Asian puccoon fine powder；110 parts by weight water immersion 2h will be added in 35 parts by weight Schisandra fruits, is risen
Temperature adds 45 parts by weight safflower fine powders and 15 parts by weight Asian puccoon fine powders, stirs 0.5h, be cooled to 99 DEG C of heating 30min
Normal temperature, that is, red staining liquid is made；
D) one or more in the blueness of above-mentioned preparation, yellow and red staining liquid are mixed, be concentrated under reduced pressure dry
It is dry to obtain natural plant pigment.
The antiseptic is methyl hydroxybenzoate and propylben according to 1:3 mixtures being re-dubbed.
The specific preparation process of Concave-convex clay rod gel is as follows：
(1), 100g Concave-convex clay rods raw ore is passed through to the weathering of 120 days；
(2) Concave-convex clay rod after weathering, is taken to be dispersed in the phytic acid aqueous solution that mass concentration is 30% after crushing
In, it is 20% attapulgite clay water suspensions that mass concentration, which is made, crosses 300 mesh sieves and removes impurity, be warming up to 90 DEG C, reacts 10h,
It is cooled to room temperature；
(3) above-mentioned steps (2), are obtained into material 75kg/cm2Pressure is rolled to obtain wet feed, and 25g bromines are added into wet feed
Change double octadecyldimethyl ammoniums, soak 2 days；
(4) step (3), is obtained into wet feed at 110 DEG C to be dried, be milled 200 mesh sieves, obtains Concave-convex clay rod
Gel powder.
The specific preparation process of modification infusorial earth is as follows：
A, after 100g diatomite being put into 30% sodium hydroxide solution immersion 5h, filtrate is washed with water in neutrality；
B, the liquor potassic permanganate for obtaining adding 15% in material to step a soaks 6h, filtering, is dried to and contains at 60 DEG C
Water is 5%；
C, obtain adding 100g vinyl silane tri-butyl peroxy, 45g lignin sulfonic acid in material to step b
Calcium, 50g titanium oxide, 70g carboxymethyl cellulose, 1.0 μm of powder are ground to after stirring 30min under 2000r/min, are obtained
Modification infusorial earth.
The good plasticine preparation method of plasticity is as follows：
1), first deionized water is added in mixer, then D-sorbite, Arabic gum, carragheen, sodium tripolyphosphate, day
Right pigment, antiseptic add in deionized water and are stirred to obtain gel solution；
2), Concave-convex clay rod gel powder, modification infusorial earth and beeswax are added in gel solution and are uniformly mixed, is added
Heat keeps 4h to 45 DEG C；
3) vaseline, rosin, camphorated oil, erucyl amide, are added into step 2) to obtain being stirred in material, stirring is equal
24h is stood after even and both obtains plasticine finished product.
Performance test
Plasticity meter applies ordinance load by placing sample between two parallel plates, is read with dial indicator
Time and thickness change are taken, so as to calculate plasticity.
2. specification：ASTMD-926
2. form：WILLIAMS-DARLING Ton type
The load-carrying 3. standard conditions are pressurizeed：5Kg, pressurize area：A diameter of 60mm, dial dial gauge：Stroke15mm with
Upper 1/100mm, body weight：About 10kg
4. sample prepares：Sample thickness is 10mm, body diameter 16mm
5. test method：
A. dial indicator is adjusted to zero；
B.. wait to the environment temperature of test machine and obtain stabilization；
C. sample is put into rapidly between two parallel-plates；
D. by reading dial gauge after the time to be measured.
Embodiment 1-6 obtains the result of the test that plasticine and commercially available plasticine comparative example 1-3 plasticity change over time
(unit：1/100nm)
| Sample | First day | Second day | 3rd day | 4th day | 5th day | 6th day |
| Embodiment 1 | 186 | 189 | 192 | 194 | 197 | 202 |
| Embodiment 2 | 184 | 187 | 189 | 193 | 196 | 201 |
| Embodiment 3 | 201 | 201 | 198 | 196 | 202 | 203 |
| Embodiment 4 | 204 | 189 | 191 | 192 | 195 | 205 |
| Embodiment 5 | 185 | 188 | 193 | 195 | 201 | 204 |
| Embodiment 6 | 192 | 195 | 197 | 204 | 201 | 205 |
| Comparative example 1 | 213 | 278 | 489 | 782 | 724 | 738 |
| Comparative example 2 | 251 | 482 | 497 | 642 | 683 | 692 |
| Comparative example 3 | 452 | 467 | 543 | 757 | 769 | 764 |
From above-mentioned result of the test it is recognised that the plasticine of the present invention is shelved for a long time at room temperature, plasticity does not have yet
Very big change, then the artifacts of making are shelved will not also be hardened for a long time, so as to reuse, in contrast,
Over time, comparative example 1 and the plasticity of the plasticine of comparative example 2 become more and more higher, as long as by more than one day, production
Product can become very hard and the phenomenon of skin breakage occurs, so as to be made.The plasticity one of plasticine in comparative example 3
Beginning is just very high, is not manufactured products of craftsmanship suitable for child or children even.
Described above is only the preferred embodiment of the present invention, and protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical schemes belonged under thinking of the present invention belong to protection scope of the present invention.It should be pointed out that for the art
Those of ordinary skill for, some improvements and modifications without departing from the principles of the present invention, these improvements and modifications
It should be regarded as protection scope of the present invention.
Claims (7)
- A kind of 1. good plasticine of plasticity, it is characterised in that：Including following components by weight percent：Concave-convex clay rod gel powder 40-60 parts, modification infusorial earth 15-20 parts, beeswax 11-16 parts, vaseline 5-9 parts, rosin 3-7 parts, camphorated oil 4-12 parts, D-sorbite 1-5 parts, Arabic gum 2-6 parts, carragheen 1-3 parts, sodium tripolyphosphate 0.1-2 parts, Natural plant pigment 0.5-1.5 parts, antiseptic 0.1-0.5 parts, erucyl amide 0.3-0.6 parts, deionized water 5-10 parts.
- A kind of 2. good plasticine of plasticity according to claim 1, it is characterised in that：Including following components by weight percent：55 parts of Concave-convex clay rod gel powder, 18 parts of modification infusorial earth, 11 parts of beeswax, 7 parts of vaseline, 5 parts of rosin, camphorated oil 10 Part, 3 parts of D-sorbite, 3 parts of Arabic gum, 1 part of carragheen, 0.7 part of sodium tripolyphosphate, 0.8 part of natural pigment, antiseptic 0.3 Part, 0.5 part of erucyl amide, 8 parts of deionized water.
- A kind of 3. good plasticine of plasticity according to claim 2, it is characterised in that：The Concave-convex clay rod gel Specific preparation process is as follows：(1), 100g Concave-convex clay rods raw ore is passed through to the weathering of 30-120 days；(2) Concave-convex clay rod after weathering, is taken to be dispersed in the phytic acid aqueous solution that mass concentration is 10-30% after crushing In, it is 5-20% attapulgite clay water suspensions that mass concentration, which is made, crosses 200-300 mesh sieves and removes impurity, is warming up to 75-90 DEG C, 3-10h is reacted, is cooled to room temperature；(3) above-mentioned steps (2), are obtained into material 55-75kg/cm2Pressure is rolled to obtain wet feed, and 10-25g is added into wet feed The double octadecyldimethyl ammoniums of bromination, soak 1-2 days；(4) step (3), is obtained into wet feed at 110 DEG C to be dried, be milled 200 mesh sieves, obtains Concave-convex clay rod gel Powder.
- A kind of 4. good plasticine of plasticity according to claim 3, it is characterised in that：The modification infusorial earth is specifically made Standby step is as follows：A, after 100g diatomite being put into 25-30% sodium hydroxide solutions immersion 3-5h, filtrate is washed with water in neutrality；B, the liquor potassic permanganate for obtaining adding 10-15% in material to step a soaks 3-6h, filtering, is dried at 55-60 DEG C It is 3-5% to water content；C, obtain adding 50-100g vinyl silane tri-butyl peroxy, 30-45g lignin sulfonic acid in material to step b Calcium, 40-50g titanium oxide, 50-70g carboxymethyl cellulose, it is ground to after stirring 15-30min under 1800-2000r/min 0.8-1.0 μm of powder, obtains modification infusorial earth.
- A kind of 5. good plasticine of plasticity according to claim 4, it is characterised in that：Plasticine preparation method is as follows：1), first deionized water is added in mixer, then D-sorbite, Arabic gum, carragheen, sodium tripolyphosphate, natural colour Element, antiseptic add in deionized water and are stirred to obtain gel solution；2), Concave-convex clay rod gel powder, modification infusorial earth and beeswax are added in gel solution and are uniformly mixed, is heated to 30-45 DEG C, keep 2-4h；3) vaseline, rosin, camphorated oil, erucyl amide, are added into step 2) to obtain being stirred in material, after stirring Stand 12-24h and both obtain plasticine finished product.
- A kind of 6. good plasticine of plasticity according to claim any one of 1-5, it is characterised in that：The natural plants Pigment preparation method is as follows：A) blue dyeing liquid is prepared：Take 50-60 parts by weight woaded blue cauline leafs to be cut into segment, be mixed into 0.5-0.8 parts by weight gooseberry fruits, put In fermentation vat, adding clear water is totally submerged raw material, then toward adding milk of lime in fermentation vat and stir, the lime The main component of breast is the calcium hydroxide aqueous solution that mass fraction is 38.6%, and the amount of addition is to add the 28- of woaded blue weight 33%, fermentation vat covers film and is sealed by fermentation 5-7 days in normal temperature, then stirs zymotic fluid, filters off residue and obtains blue dyeing liquid；B) yellow dyeing liquor is produced：1-3h is pickled by being added to after fresh lemon peel chopping in 20-35% sodium chloride solution, Then it is transferred in extractor, adds ethanol and be stripped, extracting reclaims ethanol after terminating, and obtains yellow dyeing liquor；C) red staining liquid is produced：Fresh safflower is laid into 3-4h in the cool, then inserts and 0.6h- is dried at 95-100 DEG C 0.9h, beats powder and crosses 300 sieve meshes and obtain safflower fine powder；Take fresh Asian puccoon to lay 4-6h in the cool, then insert 95-100 DEG C Drying machine in dry 0.8h-1h, beat powder and cross 300 sieve meshes and obtain Asian puccoon fine powder；It will be added in 25-35 parts by weight Schisandra fruits 95-110 parts by weight water soaks 1-2h, is warming up to 95-99 DEG C of heating 10-30min, adds 40-45 parts by weight safflower fine powders With 9-15 parts by weight Asian puccoon fine powders, 0.3-0.5h is stirred, normal temperature is cooled to, that is, red staining liquid is made；D) one or more in the blueness of above-mentioned preparation, yellow and red staining liquid are mixed, be concentrated under reduced pressure dry To natural plant pigment.
- A kind of 7. good plasticine of plasticity according to claim 6, it is characterised in that：The antiseptic is Metagin Ester and propylben are according to 1:2-1:3 mixtures being re-dubbed.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109191999A (en) * | 2018-09-28 | 2019-01-11 | 安庆师范大学 | One kind being used for preschool education intellectual development learning aids |
| CN109180065A (en) * | 2018-08-07 | 2019-01-11 | 天津伊比沙玻璃珠有限公司 | Plasticine and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1352219A (en) * | 2000-11-10 | 2002-06-05 | 刘毅 | Method for producing super normal temperature bronze imitating plasticine |
| US20090234043A1 (en) * | 2006-04-21 | 2009-09-17 | Maurice Gregory Minuto | Exercise putty having variable hardness and method of making same |
| CN101875545A (en) * | 2010-03-26 | 2010-11-03 | 许庆华 | Oily attapulgite plasticine and production method thereof |
| CN103818916A (en) * | 2014-02-28 | 2014-05-28 | 中国科学院兰州化学物理研究所 | Method for preparing attapulgite nanometer inorganic gel by phytic acid modification |
| CN105038299A (en) * | 2015-06-29 | 2015-11-11 | 容中格能 | Manufacturing method for pigments used for painting thangka |
-
2017
- 2017-08-30 CN CN201710766125.9A patent/CN107555869A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1352219A (en) * | 2000-11-10 | 2002-06-05 | 刘毅 | Method for producing super normal temperature bronze imitating plasticine |
| US20090234043A1 (en) * | 2006-04-21 | 2009-09-17 | Maurice Gregory Minuto | Exercise putty having variable hardness and method of making same |
| CN101875545A (en) * | 2010-03-26 | 2010-11-03 | 许庆华 | Oily attapulgite plasticine and production method thereof |
| CN103818916A (en) * | 2014-02-28 | 2014-05-28 | 中国科学院兰州化学物理研究所 | Method for preparing attapulgite nanometer inorganic gel by phytic acid modification |
| CN105038299A (en) * | 2015-06-29 | 2015-11-11 | 容中格能 | Manufacturing method for pigments used for painting thangka |
Non-Patent Citations (3)
| Title |
|---|
| 孙传尧: "《选矿工程师手册 第1册 上 选矿通论》", 31 March 2015, 冶金工业出版社 * |
| 杨柳燕: "《有机蒙脱土和微生物联合处理有机污染物的机理与应用》", 31 July 2004, 中国环境科学出版社 * |
| 林丽霞: "《牛仔产品艺术加工》", 28 February 2014 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109180065A (en) * | 2018-08-07 | 2019-01-11 | 天津伊比沙玻璃珠有限公司 | Plasticine and preparation method thereof |
| CN109191999A (en) * | 2018-09-28 | 2019-01-11 | 安庆师范大学 | One kind being used for preschool education intellectual development learning aids |
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