CN106117630A - A kind of preparation method of Atoxic plasticine - Google Patents
A kind of preparation method of Atoxic plasticine Download PDFInfo
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- CN106117630A CN106117630A CN201610636575.1A CN201610636575A CN106117630A CN 106117630 A CN106117630 A CN 106117630A CN 201610636575 A CN201610636575 A CN 201610636575A CN 106117630 A CN106117630 A CN 106117630A
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- plasticine
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses the preparation method of a kind of Atoxic plasticine, belong to plasticine preparing technical field.The present invention using jelly on peach tree as raw material, with hydrogen peroxide, dehydrated alcohol and ferric chloride stirring reaction, the discharging thing obtained carries out filtration under diminished pressure again with activated carbon stirring, by filtrate and glycerol, starch etc. react, freezing processing subsequently, the filtering residue that obtain is collected by filtration and is Atoxic plasticine base material, by plasticine base material and silicon dioxide, sodium silicate and Gardenia Yellow stir, i.e. can get Atoxic plasticine, the present invention is easy and simple to handle, raw material safety non-toxic, human body will not be produced harm, and it is bright in luster, comfortable feel, can be used as child, the toy of pupil, teaching aid etc., it it is a kind of environment protection type multifunctional toy.
Description
Technical field
The invention discloses the preparation method of a kind of Atoxic plasticine, belong to plasticine preparing technical field.
Background technology
Since 1956 come out, plasticine has just become the favorite toy of children.The plasticine started most is only
Greyish white a kind of color, but in several years subsequently, plasticine has just had various color and fragrance.Including noctilucence, golden,
Silver color, shampoo taste, scrape recklessly water taste etc..
Plasticine is a kind of Fructus Alpiniae Oxyphyllae type toy deeply liked by teenager, is also applied for the neck such as sculpture, arts and crafts design
Territory, because the plasticity of plasticine is extremely strong, child can give full play to its imaginative power by playing plasticine, shows it abundant many
Color inward world, this is helpful to the intellectual development of teenager early stage.But child age is little, curiosity is strong, is using
During the phenomenon eaten by mistake easily occurs.
Plasticine possesses replicability, can arbitrarily pinch into variously-shaped, according to being furnished with difform mould, template, and can be by
Plasticine is fabricated to various article, or under the guide of teacher or the head of a family, creates the works oneself wanted, to child's
Hands brain eye coordinate is cultivated, and color recognition and creation thought ability aspect have the educational effect of uniqueness.
Traditional plasticine Main Ingredients and Appearance includes Animal fat leftover bits and pieces, old powder, Gypsum Fibrosum powder, sealing wax and rubber etc., its component
Containing certain toxicity, can affect healthy after using, and also exist that color is the most bright-coloured, temperature difference bad adaptability (cold day hard and
Pinch motionless, hot day is soft and easily send out the viscous hands of paste), and the problem causing environmental pollution.
Summary of the invention
The technical problem that present invention mainly solves: contain certain toxicity, after using for its component of existing plasticine
Can affect healthy, and the problem that there is temperature difference bad adaptability, it is provided that the preparation method of a kind of Atoxic plasticine, the method
First using jelly on peach tree as raw material, and hydrogen peroxide, dehydrated alcohol and ferric chloride stirring reaction, the discharging thing obtained with
Activated carbon stirring carries out filtration under diminished pressure again, is reacted by filtrate and glycerol, starch etc., freezing processing subsequently, is collected by filtration and obtains
Filtering residue be Atoxic plasticine base material, plasticine base material is stirred with silicon dioxide, sodium silicate and Gardenia Yellow,
To Atoxic plasticine, the present invention is easy and simple to handle, raw material safety non-toxic, human body will not be produced harm, and bright in luster, feel
Comfortable, can be used as child, the toy of pupil, teaching aid etc., be a kind of environment protection type multifunctional toy.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is:
(1) mass fraction 23% hydrogen peroxide taking jelly and its quality 1 on peach tree～2 times is put in glass reaction still, then divides
Not Jia Ru hydrogen peroxide volume 30～the dehydrated alcohol of 35% and jelly quality 28～the ferric chloride of 36%, use mass fraction
Being 45% sodium hydroxide solution regulation pH to 7.5～8.0, use nitrogen protection, design temperature is 78～84 DEG C, with 190r/min
Stirring 4～6h；
(2) after above-mentioned stirring terminates, naturally cool to room temperature, and use hydrogen to be discharged by the gas in glass reaction still, and
Standing 40～50min, discharging subsequently, collects discharging thing and the activated carbon with discharging material amount 4～6% stirs, 45～
50 DEG C stand 30～45min, then carry out filtration under diminished pressure, collect filtrate；
(3) count by weight, take 34～36 parts of above-mentioned filtrates, 12～16 parts of glycerol, 10～13 parts of starch, 8～9 parts of polypropylene
Acid sodium and 0.8～1.3 part of tetraethyl orthosilicate, first put into container by above-mentioned filtrate, glycerol and starch, uses nitrogen protection,
It is placed in water-bath, design temperature 90～100 DEG C, stirs 1～2h with 160r/min, sequentially add sodium polyacrylate, positive silicon
Acetoacetic ester, stirring reaction 6～8h；
(4) after above-mentioned reaction terminates, being placed in cold room by container, design temperature is 3～6 DEG C, freezing processing 38～46min
Rear filtration, collects filtering residue and also warms naturally to room temperature, obtain Atoxic plasticine base material, count by weight, take 46～52 parts nontoxic
Plasticine base material, 8～9 parts of silicon dioxide, 2～3 parts of sodium silicate and 0.8～1.6 part of Gardenia Yellow, put into stirring in blender equal
Even, i.e. can get Atoxic plasticine.
The application process of the present invention is: take the Atoxic plasticine that the appropriate present invention prepares, and is put by plasticine on the table, uses hands
Repeatedly rub 8～10 times, subsequently with particular manufacturing craft or free-hand pinch into random shape.After testing, the rubber that the present invention prepares
Mud safety non-toxic, thermal adaptability is good, and through 1～3 year tracking and monitoring, plasticine remained to normally use, and is in bright colors, and feel is relaxed
Suitable.
The invention has the beneficial effects as follows:
(1) plasticine of the present invention is bright in luster, comfortable feel, and plasticine exquisite in texture lubrication is tack-free, and fits temperature
Answering property is preferable, and winter will not be hardening, and summer will not become too soft；
(2) the plasticine Nantural non-toxic evil of the present invention, does not interferes with healthy, can be used as the object for appreciation of child, pupil after using
Tool, teaching aid, it is possible to be applied to the aspect such as modelling, sculpture draft, be a kind of environment protection type multifunctional toy.
Detailed description of the invention
First mass fraction 23% hydrogen peroxide taking jelly and its quality 1 on peach tree～2 times is put in glass reaction still,
It is separately added into hydrogen peroxide volume 30～the dehydrated alcohol of 35% and jelly quality 28～the ferric chloride of 36% again, uses quality
Mark is 45% sodium hydroxide solution regulation pH to 7.5～8.0, uses nitrogen protection, and design temperature is 78～84 DEG C, with
190r/min stirring 4～6h；After above-mentioned stirring terminates, naturally cool to room temperature, and use hydrogen by glass reaction still
Gas is discharged, and stands 40～50min, discharging subsequently, collect discharging thing and with discharging material amount 4～the activated carbon stirring of 6%
Uniformly, stand 30～45min at 45～50 DEG C, then carry out filtration under diminished pressure, collect filtrate；Count the most by weight, take 34～
36 parts of above-mentioned filtrates, 12～16 parts of glycerol, 10～13 parts of starch, 8～9 parts of sodium polyacrylate and 0.8～1.3 part of positive silicic acid second
Ester, first puts into container by above-mentioned filtrate, glycerol and starch, uses nitrogen protection, is placed in water-bath, design temperature 90～
100 DEG C, stir 1～2h with 160r/min, sequentially add sodium polyacrylate, tetraethyl orthosilicate, stirring reaction 6～8h；Finally
After above-mentioned reaction terminates, being placed in cold room by container, design temperature is 3～6 DEG C, filters after freezing processing 38～46min,
Collect filtering residue and warm naturally to room temperature, obtaining Atoxic plasticine base material, count by weight, take 46～52 parts of Atoxic plasticine bases
Material, 8～9 parts of silicon dioxide, 2～3 parts of sodium silicate and 0.8～1.6 part of Gardenia Yellow, put in blender and stir,
To Atoxic plasticine.
Example 1
First take mass fraction 23% hydrogen peroxide of jelly and its quality 1 times on peach tree to put in glass reaction still, then distinguish
Adding dehydrated alcohol and the ferric chloride of jelly quality 28% of hydrogen peroxide volume 30%, using mass fraction is 45% hydrogen-oxygen
Changing sodium solution regulation pH to 7.5, use nitrogen protection, design temperature is 78 DEG C, stirs 4h with 190r/min；Tie in above-mentioned stirring
Shu Hou, naturally cools to room temperature, and uses hydrogen to be discharged by the gas in glass reaction still, and stand 40min, discharging subsequently,
Collect discharging thing and the activated carbon with discharging material amount 4% stirs, stand 30min at 45 DEG C, then carry out filtration under diminished pressure, receive
Collection filtrate；Count the most by weight, take 34 parts of above-mentioned filtrates, 12 parts of glycerol, 10 parts of starch, 8 parts of sodium polyacrylate and 0.8 part
Tetraethyl orthosilicate, first puts into container by above-mentioned filtrate, glycerol and starch, uses nitrogen protection, is placed in water-bath, sets
Temperature 90 DEG C, stirs 1h with 160r/min, sequentially adds sodium polyacrylate, tetraethyl orthosilicate, stirring reaction 6h；Last upper
Stating after reaction terminates, be placed in cold room by container, design temperature is 3 DEG C, filters after freezing processing 38min, collects filtering residue also
Warm naturally to room temperature, obtain Atoxic plasticine base material, count by weight, take 46 parts of Atoxic plasticine base materials, 8 parts of titanium dioxide
Silicon, 2 parts of sodium silicate and 0.8 part of Gardenia Yellow, put in blender and stir, i.e. can get Atoxic plasticine.
This example operation is easy, during use, takes the Atoxic plasticine that the appropriate present invention prepares, is put by plasticine on the table,
8 times are repeatedly rubbed, subsequently with particular manufacturing craft or free-hand pinch into random shape with hands.After testing, the rubber that the present invention prepares
Mud safety non-toxic, thermal adaptability is good, and through 1 year tracking and monitoring, plasticine remained to normally use, and is in bright colors, comfortable feel.
Example 2
First take mass fraction 23% hydrogen peroxide of jelly and its quality 1.5 times on peach tree to put in glass reaction still, then divide
Not Jia Ru the dehydrated alcohol of hydrogen peroxide volume 33% and the ferric chloride of jelly quality 32%, using mass fraction is 45% hydrogen
Sodium hydroxide solution regulation pH to 7.8, uses nitrogen protection, and design temperature is 81 DEG C, stirs 5h with 190r/min；In above-mentioned stirring
After end, naturally cool to room temperature, and use hydrogen to be discharged by the gas in glass reaction still, and stand 45min, go out subsequently
Material, collects discharging thing and the activated carbon with discharging material amount 5% stirs, and stands 38min at 48 DEG C, then carries out reducing pressure
Filter, collects filtrate；Count the most by weight, take 35 parts of above-mentioned filtrates, 13 parts of glycerol, 12 parts of starch, 8.5 parts of sodium polyacrylate
And 1.1 parts of tetraethyl orthosilicates, first above-mentioned filtrate, glycerol and starch are put into container, uses nitrogen protection, be placed in water-bath
Pot, design temperature 95 DEG C, stirs 1.5h with 160r/min, sequentially adds sodium polyacrylate, tetraethyl orthosilicate, stirring reaction
7h；Finally after above-mentioned reaction terminates, being placed in cold room by container, design temperature is 5 DEG C, filters after freezing processing 42min,
Collect filtering residue and also warm naturally to room temperature, obtain Atoxic plasticine base material, count by weight, take 49 parts of Atoxic plasticine base materials,
8.5 parts of silicon dioxide, 2.5 parts of sodium silicate and 1.2 parts of Gardenia Yellow, put in blender and stir, i.e. can get nontoxic rubber
Mud.
This example operation is easy, during use, takes the Atoxic plasticine that the appropriate present invention prepares, is put by plasticine on the table,
9 times are repeatedly rubbed, subsequently with particular manufacturing craft or free-hand pinch into random shape with hands.After testing, the rubber that the present invention prepares
Mud safety non-toxic, thermal adaptability is good, and through 2 years tracking and monitorings, plasticine remained to normally use, and is in bright colors, comfortable feel.
Example 3
First take mass fraction 23% hydrogen peroxide of jelly and its quality 2 times on peach tree to put in glass reaction still, then distinguish
Adding dehydrated alcohol and the ferric chloride of jelly quality 36% of hydrogen peroxide volume 35%, using mass fraction is 45% hydrogen-oxygen
Changing sodium solution regulation pH to 8.0, use nitrogen protection, design temperature is 84 DEG C, stirs 6h with 190r/min；Tie in above-mentioned stirring
Shu Hou, naturally cools to room temperature, and uses hydrogen to be discharged by the gas in glass reaction still, and stand 50min, discharging subsequently,
Collect discharging thing and the activated carbon with discharging material amount 6% stirs, stand 45min at 50 DEG C, then carry out filtration under diminished pressure, receive
Collection filtrate；Count the most by weight, take 36 parts of above-mentioned filtrates, 16 parts of glycerol, 13 parts of starch, 9 parts of sodium polyacrylate and 1.3 parts
Tetraethyl orthosilicate, first puts into container by above-mentioned filtrate, glycerol and starch, uses nitrogen protection, is placed in water-bath, sets
Temperature 100 DEG C, stirs 2h with 160r/min, sequentially adds sodium polyacrylate, tetraethyl orthosilicate, stirring reaction 8h；Finally exist
After above-mentioned reaction terminates, being placed in cold room by container, design temperature is 6 DEG C, filters after freezing processing 46min, collects filtering residue
And warm naturally to room temperature, obtain Atoxic plasticine base material, count by weight, take 52 parts of Atoxic plasticine base materials, 9 parts of titanium dioxide
Silicon, 3 parts of sodium silicate and 1.6 parts of Gardenia Yellow, put in blender and stir, i.e. can get Atoxic plasticine.
This example operation is easy, during use, takes the Atoxic plasticine that the appropriate present invention prepares, is put by plasticine on the table,
10 times are repeatedly rubbed, subsequently with particular manufacturing craft or free-hand pinch into random shape with hands.After testing, the rubber that the present invention prepares
Mud safety non-toxic, thermal adaptability is good, and through 3 years tracking and monitorings, plasticine remained to normally use, and is in bright colors, comfortable feel.
Claims (1)
1. the preparation method of an Atoxic plasticine, it is characterised in that concrete preparation process is:
(1) mass fraction 23% hydrogen peroxide taking jelly and its quality 1 on peach tree～2 times is put in glass reaction still, then divides
Not Jia Ru hydrogen peroxide volume 30～the dehydrated alcohol of 35% and jelly quality 28～the ferric chloride of 36%, use mass fraction
Being 45% sodium hydroxide solution regulation pH to 7.5～8.0, use nitrogen protection, design temperature is 78～84 DEG C, with 190r/min
Stirring 4～6h；
(2) after above-mentioned stirring terminates, naturally cool to room temperature, and use hydrogen to be discharged by the gas in glass reaction still, and
Standing 40～50min, discharging subsequently, collects discharging thing and the activated carbon with discharging material amount 4～6% stirs, 45～
50 DEG C stand 30～45min, then carry out filtration under diminished pressure, collect filtrate；
(3) count by weight, take 34～36 parts of above-mentioned filtrates, 12～16 parts of glycerol, 10～13 parts of starch, 8～9 parts of polypropylene
Acid sodium and 0.8～1.3 part of tetraethyl orthosilicate, first put into container by above-mentioned filtrate, glycerol and starch, uses nitrogen protection,
It is placed in water-bath, design temperature 90～100 DEG C, stirs 1～2h with 160r/min, sequentially add sodium polyacrylate, positive silicon
Acetoacetic ester, stirring reaction 6～8h；
(4) after above-mentioned reaction terminates, being placed in cold room by container, design temperature is 3～6 DEG C, freezing processing 38～46min
Rear filtration, collects filtering residue and also warms naturally to room temperature, obtain Atoxic plasticine base material, count by weight, take 46～52 parts nontoxic
Plasticine base material, 8～9 parts of silicon dioxide, 2～3 parts of sodium silicate and 0.8～1.6 part of Gardenia Yellow, put into stirring in blender equal
Even, i.e. can get Atoxic plasticine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610636575.1A CN106117630A (en) | 2016-08-05 | 2016-08-05 | A kind of preparation method of Atoxic plasticine |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610636575.1A CN106117630A (en) | 2016-08-05 | 2016-08-05 | A kind of preparation method of Atoxic plasticine |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107474562A (en) * | 2017-08-30 | 2017-12-15 | 应芹绿 | A kind of strong durability plasticine |
| CN107501629A (en) * | 2017-08-30 | 2017-12-22 | 应芹绿 | A kind of Atoxic plasticine |
| CN114479200A (en) * | 2022-02-15 | 2022-05-13 | 上海晨光文具股份有限公司 | Food-grade rice color paste and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107474562A (en) * | 2017-08-30 | 2017-12-15 | 应芹绿 | A kind of strong durability plasticine |
| CN107501629A (en) * | 2017-08-30 | 2017-12-22 | 应芹绿 | A kind of Atoxic plasticine |
| CN114479200A (en) * | 2022-02-15 | 2022-05-13 | 上海晨光文具股份有限公司 | Food-grade rice color paste and preparation method thereof |
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Application publication date: 20161116 |