JP4826989B2 - Indigo soap and its manufacturing method - Google Patents
Indigo soap and its manufacturing method Download PDFInfo
- Publication number
- JP4826989B2 JP4826989B2 JP2004302527A JP2004302527A JP4826989B2 JP 4826989 B2 JP4826989 B2 JP 4826989B2 JP 2004302527 A JP2004302527 A JP 2004302527A JP 2004302527 A JP2004302527 A JP 2004302527A JP 4826989 B2 JP4826989 B2 JP 4826989B2
- Authority
- JP
- Japan
- Prior art keywords
- indigo
- soap
- precipitated
- vegetable oil
- leaf
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Description
本発明は、葉藍の成分を含有する石けんとその製造方法に関する。 The present invention relates to a soap containing a leaf green component and a method for producing the same.
通常の石けんは、高級脂肪酸のアルカリ金属塩でできており、洗浄を目的に作られており、動植物油に水酸化ナトリウムや水酸化カリウム等を加えて、煮沸混合した後、冷却あるいは塩析等を行って固化、成形して製造される。しかし、最近の健康ブームで肌に優しい石けんが注目され、オリーブオイルやパームオイルなどの植物油に香料、着色剤のみならず、保湿性、抗菌性、抗アレルギー性など様々な薬効成分やハーブなどが添加された石けんが作られている。
例えば、入浴、洗顔に用いる肌に優しいミネラル含有石けんとして麦飯石やウコンを添加した石けん（特許文献１）、よもぎ抽出液、魚由来のコラーゲンと塩化マグネシウム等海洋ミネラルを加えた薬用石けん（特許文献２）、石けん基材にハーブ粉末を添加したハーブ石けん（特許文献３）、化粧石けん基材に木酢液あるいは竹酢液を加えた石けん（特許文献４）、化粧石けん基材に酢を加えた石けん（特許文献５）、クマザサ抽出成分を含有する化粧石けん（特許文献６）等が提案されている。
For example, soap with added barley stone or turmeric as a mineral-containing soap for bathing and facial cleansing (Patent Document 1), wormwood extract, medicinal soap with added marine minerals such as fish-derived collagen and magnesium chloride (Patent Document) 2), soap with herb powder added to soap base (Patent Literature 3), soap with wood vinegar or bamboo vinegar added to cosmetic soap base (Patent Literature 4), vinegar added to cosmetic soap base Soap (Patent Document 5), cosmetic soap containing a Kumazasa extract component (Patent Document 6), and the like have been proposed.
藍は古くから染料として利用されてきているが、藍の持つ不思議な力は万葉の昔から知られ、生活に生かされてきている。武士は鎧の下に藍染めの肌着を着て、切り傷や虫さされから守ったと言われている。藍染めの着物をタンスに入れて置くと、防虫効果があると言われている。ふぐ中毒、食あたり、熱冷ましなどの民間薬として利用されていたと言う。
藍は肌に優しい天然染料としてその良さが見直され、注目されるようになり、染毛剤としての利用が提案（特許文献６、７、８）されている。この他、藍の中には抗菌性物質が存在する溶媒抽出が行われている（特許文献９、１０、１１）。皮膚の炎症を止める機能があることから生理パッドに利用する特許などが提案されている（特許１２）。特許等を調べたが、藍成分の石けんへの応用は提案されていない。
藍の機能に着目し、石けんへの添加を試み、石けんの製造を鋭意研究してきたところである。
藍の色は水に溶けないために、発酵させて可溶化して取り出されており、ハーブのように乾燥粉末化して固化・成型時に添加しても機能発現は期待できない。葉藍成分による機能発現を期待するためには可溶化し、添加する必要があるが、ジクロロメタンやエーテルなどの有機溶媒抽出した場合、有機溶媒の除去などの課題が残る。
Indigo has been reviewed as a natural dye that is gentle on the skin, has attracted attention, and has been proposed for use as a hair dye (Patent Documents 6, 7, and 8). In addition, solvent extraction in which an antibacterial substance exists in indigo is performed (Patent Documents 9, 10, and 11). Since it has a function to stop inflammation of the skin, a patent used for a physiological pad has been proposed (Patent 12). Although patents were examined, no application of indigo ingredients to soap has been proposed.
Focusing on the function of indigo, we have tried to add it to the soap and have been studying the manufacture of soap.
Since the color of indigo is not soluble in water, it has been fermented and solubilized and extracted, and even if it is dried and powdered like an herb and added during solidification / molding, its function cannot be expected. It is necessary to solubilize and add in order to expect functional expression due to the leaf indigo component. However, when organic solvents such as dichloromethane and ether are extracted, problems such as removal of organic solvents remain.
本発明は、以下の（１）〜（７）の藍入り石けんの製造方法を要旨とする。
（１）アルカリと植物油を原料とする石けんの製造において、石けん原料に入れる藍として、沈殿藍、乾燥葉藍の油抽出成分、および藍種子の水抽出成分からなる群から選ばれる一以上を用いることを特徴とする藍入り石けんの製造方法。
１）前記沈殿藍が、葉藍を発酵させ、色素を溶解させた後、アルカリを加えて沈殿させた沈殿藍であって、それを溶解した水溶液に水酸化ナトリウムを溶かしたものをアルカリ原料として用いること。
２）前記藍種子の水抽出成分が、藍の種子を水に入れ、煮沸して水溶性成分を煮出した水溶液であって、それを溶解した水溶液に水酸化ナトリウムを溶かしたものをアルカリ原料として用いること。
３）前記乾燥葉藍の油抽出成分が、乾燥した葉藍を石けん原料である植物油に入れ、加熱・煮出し、葉藍中の油溶性成分を溶解させ、不溶性成分をろ過除去した植物油であって、それを植物油原料として用いること。
（２）前記沈殿藍および藍種子の水抽出成分が、藍の種子を水に入れ、煮沸して水溶性成分を煮出した水溶液に、葉藍を発酵させ色素を溶解させた後アルカリを加えて沈殿させた沈殿藍と水酸化ナトリウムを溶かし、それをアルカリ原料として用いることを特徴とする（１）の藍入り石けんの製造方法
（３）沈殿藍、乾燥葉藍の油抽出成分、および藍種子の水抽出成分を単独にあるいは複数あるいはすべてを用いて製造することにより藍色等の青色系統、白色系統、黄色系統、紫色系統の色彩を表現し、あるいは各色の濃淡を調節し、藍染をイメージ出来る色彩的にも美しい石けんを製造することを特徴とする（１）ないし（５）のいずれかの藍入り石けんの製造方法。
（４）全体が藍入りであり、デザイン構成の組み合わせにより幾何学的な模様を構成する（６）の藍入り石けんの製造方法。The gist of the present invention is the following methods (1) to (7) for producing indigo soap.
(1) In the production of soap using alkali and vegetable oil as raw materials, one or more selected from the group consisting of precipitated indigo, dried leaf indigo oil extract, and indigo seed water extract in the soap material A method for producing indigo soap characterized by the above.
1) The precipitated indigo is a precipitated indigo prepared by fermenting leaf indigo, dissolving the pigment, and then adding alkali to precipitate, and using an aqueous solution in which sodium hydroxide is dissolved as an alkali raw material Use it.
2) The water extraction component of indigo seed is an aqueous solution in which indigo seeds are put into water and boiled to boil out water-soluble components, and an aqueous solution in which sodium hydroxide is dissolved is used as an alkaline raw material. Use it.
3) The oil extract component of the dried leaf indigo is a vegetable oil in which the dried leaf indigo is put into vegetable oil, which is a raw material of soap, heated and boiled to dissolve the oil-soluble component in the leaf indigo, and the insoluble component is removed by filtration. Use it as a vegetable oil raw material.
(2) The water-extracted components of the precipitated indigo and indigo seeds are prepared by adding indigo seeds in water, boiled and boiled out the water-soluble components, fermented leaf indigo and dissolved the pigment, and then added alkali. (1) A method for producing indigo soap containing indigo, which comprises dissolving precipitated precipitated indigo and sodium hydroxide and using it as an alkaline raw material (3) Precipitated indigo, dried leaf indigo oil extract component, and indigo seed By using one or more or all of the water extractive components of this product, the color of blue, white, yellow, and purple can be expressed, or the shade of each color can be adjusted to create an image of indigo dyeing. A method for producing an indigo soap as set forth in any one of (1) to (5), wherein a soap which is also beautiful in color is produced.
(4) The method for producing indigo soap according to (6), wherein the whole is indigo and a geometric pattern is formed by a combination of design configurations.
また、本発明は、以下の（５）の藍入り石けんを要旨とする。
（５）（１）ないし（３）に記載した方法で製造したしたことを特徴とする藍成分入り植物油石けん。The gist of the present invention is the following (5) indigo soap.
(5) A vegetable oil soap containing indigo ingredients, which is produced by the method described in (1) to (3).
本発明では、人に優しい天然植物油と水酸化ナトリウム等からなる石けんに肌に優しい色素藍を加えてなる石けんである。すなわち、藍から抽出した成分の入った水溶液あるいは植物油を用いる藍入り石けんに関するものである。藍の成分の抽出溶液は下記に記載する方法がある。なお、藍成分の抽出方法としてはこれらの方法に限定されるものではない。
精製水で藍の種子を煮沸して水溶性成分を溶出させた水溶液、葉藍を発酵させて生成した沈殿藍、乾燥藍をもう一つの原料である植物油で煮出した油溶性成分を含有した植物油などを用いる。本発明では葉藍や種子中の水溶性成分、油溶性成分、発酵により溶出し出来る成分を利用するもので、藍の成分を余すところなく利用するもので、藍の持つ機能の発現が期待される。
藍の種子を水で煮出した水溶液に沈殿藍を混合し、次いで、水酸化ナトリウムを溶解させる。この水溶液と葉藍からに油溶性成分を煮出した植物油を等温に加温して、かき混ぜながら混合し、ケン化反応を進行させ、得られた粘凋な均一混合物を型に入れて所定温度に保温しながら静置して固化・成型して石けんを製造する。
なお、藍成分の利用方法として、先に記載した３つの藍抽出物を単独にあるいは複数あるいはすべてを混合して藍入り石けんを製造することができる。沈殿藍、乾燥葉藍の油抽出成分、および藍種子の水抽出成分を単独にあるいは複数あるいはすべてを用いて製造することにより藍色等の青色系統、白色系統、黄色系統、紫色系統の色彩を表現し、あるいは各色の濃淡を調節し、藍染をイメージ出来る色彩的にも美しい石けんを製造することができる。
本発明では藍種子中の水溶性物質、葉藍の発酵溶出成分及び油溶解成分をすべて利用するもので、植物油の持つ洗浄性等の機能に加えて、藍の持つ機能がすべて付加され、人の肌に対してより優しく、敏感肌の人にも優しい石けんが製造できる。藍は肌に優しいだけでなく、肌やタオルなどの布についても染まらない等の機能を有している。
アレルギー体質の肌にも優しく、抗菌性などの効果も期待できるなど新しい化粧石けんとして有効であると考えている。
In the present invention, the soap is a soap made by adding skin-friendly pigment indigo to a soap made of natural vegetable oil and sodium hydroxide. That is, it relates to an indigo soap using an aqueous solution or vegetable oil containing components extracted from indigo. The indigo component extraction solution has the method described below. The method for extracting indigo components is not limited to these methods.
Vegetable oil containing oil-soluble ingredients boiled in purified indigo seed, boiled indigo produced by fermenting leaf indigo, and dried indigo with other vegetable oil Etc. are used. In the present invention, water-soluble components in leaf indigo and seeds, oil-soluble components, components that can be eluted by fermentation are used, and indigo components are fully used, and expression of the functions of indigo is expected. The
Precipitated indigo is mixed in an aqueous solution of indigo seeds boiled in water, and then sodium hydroxide is dissolved. This aqueous solution and vegetable oil boiled from leaf green are heated isothermally and mixed while stirring to allow the saponification reaction to proceed, and the resulting viscous uniform mixture is put into a mold and brought to a predetermined temperature. It is allowed to stand while it is kept warm, solidified and molded to produce soap.
As a method of using the indigo component, indigo-containing soap can be produced by combining the above-described three indigo extracts alone or by mixing a plurality or all of them. Indigo blue, dried leaf indigo oil extract components and indigo seed water extract components can be used alone or in combination with multiple or all to produce indigo blue, white, yellow, and purple colors. It is possible to produce soaps that are beautiful in color and can express indigo dyeing by expressing or adjusting the shade of each color.
In the present invention, all of the water-soluble substances in indigo seeds, the fermented and dissolved components of leaf indigo and oil-dissolved components are used. In addition to the functions of vegetable oil such as detergency, all the functions of indigo are added. Soap that is gentler to the skin and gentler to people with sensitive skin can be manufactured. Indigo is not only gentle on the skin but also has the function of not dyeing the skin and towels.
It is gentle on allergic skin and can be expected to have antibacterial and other effects.
本発明は、藍の持つ機能を活かした藍入り石けんの製造に関するものである。本発明ではオリーブオイルやパームオイルなどの植物油に香料を加え、葉藍から抽出した成分や藍の種子から抽出した水溶性成分を加えて石けんとするもので、固形石けんのみならずシャンプーなどを製造する。
藍色を抽出するためには、葉藍を水に浸漬して発酵させ、残存する葉を濾し取り、消石灰を撹拌しながら添加する。泡が出なくなったら静置して、沈殿すると上澄みを捨てて沈殿藍を取り出し、スラリー状として利用あるいは乾燥粉末として利用する場合がある。この沈殿藍を石けんの製造工程に使用するものである。
また、乾燥葉藍を石けん原料の植物オイル中に入れ、所定時間加熱して、葉藍中の油性成分を抽出し、冷却後、葉をすべて濾して除去する。このように藍抽出油を用いて石けんを製造するものである。
The present invention relates to the production of indigo soap utilizing the functions of indigo. In the present invention, fragrance is added to vegetable oils such as olive oil and palm oil, and the ingredients extracted from leaf indigo and water-soluble ingredients extracted from indigo seeds are used to make soap, producing not only solid soap but also shampoos etc. To do.
In order to extract the indigo color, the leaf indigo is immersed in water and fermented, the remaining leaves are filtered and slaked lime is added with stirring. When bubbles no longer appear, leave it to stand, and when it settles, discard the supernatant and take out the precipitated indigo, and use it as a slurry or as a dry powder. This precipitated indigo is used in the soap manufacturing process.
In addition, the dried leaf indigo is put in the soap plant oil and heated for a predetermined time to extract the oily component in the leaf indigo. After cooling, all the leaves are filtered and removed. Thus, soap is manufactured using indigo extract oil.
本発明の沈殿藍の製造は、通常法で行った。すなわち、生葉藍を水に漬け込み、４８〜７２時間放置して発酵させた後、藍の葉を濾す。藍が溶出した水溶液に石灰水溶液を添加し、撹拌する。泡が出なくなると静置する。上澄み液を捨て、スラリー状の沈殿藍を取り出す。水に沈殿藍を溶解した後、水酸化ナトリウムを溶かして所定濃度（10~20%）の沈殿藍入りの水酸化ナトリウム水溶液を調整する。
オリーブオイル、パームオイル、大豆油などの植物油あるいはこの混合油を加熱して４０℃程度に保ちながら等温の藍入り水酸化ナトリウム水溶液を撹拌下添加して、ケン化させる。粘凋溶液を型枠に入れ、保温箱で覆い所定時間放置して固化させて、石けんを製造するものである。
Production of the precipitated indigo of the present invention was carried out by a usual method. That is, the green leaves are soaked in water and allowed to stand for 48 to 72 hours for fermentation, and then the green leaves are filtered. Add the lime aqueous solution to the aqueous solution from which the indigo has eluted and stir. Let stand when no more foam. Discard the supernatant and take out the slurry indigo blue. After dissolving precipitated indigo in water, sodium hydroxide is dissolved to prepare a sodium hydroxide aqueous solution containing precipitated indigo of a predetermined concentration (10 to 20%).
A vegetable oil such as olive oil, palm oil, soybean oil, or a mixed oil thereof is heated and kept at about 40 ° C., and an isothermal indigo sodium hydroxide aqueous solution is added with stirring to saponify. A viscous solution is placed in a mold, covered with a heat-retaining box, and allowed to solidify for a predetermined time to produce soap.
乾燥葉藍の油抽出成分を用いる藍入り石けんの製造方法の好ましい態様は次の通りである。乾燥葉藍を原料の植物油に添加して所定温度に加熱して、油溶性分を抽出する。この植物油から葉藍を濾別する。藍の油溶性成分を含有する植物油と等温の水酸化ナトリウム水溶液をかき混ぜながら混合してケン化する。上記の方法と同様に型枠に移して保温下に放置して固化する。 A preferred embodiment of the method for producing indigo soap using the dried leaf indigo oil extract component is as follows. Dried leaf indigo is added to the raw vegetable oil and heated to a predetermined temperature to extract the oil-soluble component. Filter the leaf indigo from this vegetable oil. Saponification is carried out by mixing vegetable oil containing indigo oil-soluble components and isothermal sodium hydroxide solution while stirring. In the same manner as described above, it is transferred to a mold and allowed to stand under heat retention to solidify.
藍種子の水抽出成分を用いる石けんの製造方法の好ましい態様は次の通りである。藍の種子を水に入れ、所定時間煮沸して、種子中の水溶性成分を溶解させる。この水溶液に水酸化トリウムを溶解して、所定温度で植物油とかき混ぜながら混合して、ケン化・固化させて石けんを製造することもできる。この場合の藍入り石けんは黄色あるいは白色である。 A preferred embodiment of the method for producing soap using the water extraction component of indigo seed is as follows. Indigo seeds are put in water and boiled for a predetermined time to dissolve water-soluble components in the seeds. Thorium hydroxide is dissolved in this aqueous solution, mixed with vegetable oil at a predetermined temperature and mixed, and saponified and solidified to produce soap. The indigo soap in this case is yellow or white.
藍入り石けん製造の上記とは別の態様、或いは全体が藍入りであり、藍特有の藍色の部分が藍染めをイメージした模様を構成する藍入り石けんの製造方法は、沈殿藍、油溶性成分含有植物油、種子の水溶性成分を含有する水溶液を組み合わせて藍入り石けんを製造するものである。種子から水溶性成分を抽出して水溶液と沈殿藍を混合した後、植物油と混合して石けんを作る場合、色の変化は白色系統より固化・熟成期間に紫色系統の石けんになる。
なお、種子中の水溶性成分を含有する水溶液と沈殿藍を利用して石けんを製造する場合、種子水溶性成分を含有する水溶液に水酸化ナトリウムを溶解し、植物油と混合してケン化させ、型枠に入れる直前の粘凋溶液に沈殿藍を混合して固化すると青色系統の石けんが製造できる。
A method of manufacturing indigo soap that is different from the above in the manufacture of indigo soap, or that is entirely indigo, and that has an indigo-colored indigo-colored pattern in the pattern of indigo dyeing. Indigo soap is produced by combining an ingredient-containing vegetable oil and an aqueous solution containing a water-soluble component of seeds. When water-soluble components are extracted from seeds and mixed with an aqueous solution and precipitated indigo blue, and then mixed with vegetable oil to make soap, the color change becomes a soap of purple color in the solidification / ripening period rather than white.
In addition, when producing soap using an aqueous solution containing water-soluble components in seeds and precipitated indigo, sodium hydroxide is dissolved in an aqueous solution containing seed water-soluble components, mixed with vegetable oil and saponified, Blue soap can be produced by mixing and solidifying the precipitating indigo solution just before putting into the mold.
本発明の石けんは３つの藍抽出物を単独にあるいは複数あるいはすべてを混合して製造することにより藍色等の青色系統、白色系統、黄色系統、紫色系統の色彩を表現することや各色の濃淡を調節し、また、デザイン構成の組み合わせにより幾何学的な模様を構成する藍染をイメージ出来る色彩的にも美しい石けんを製造することが出来る。
上記方法により製造した石けんの各種類を化粧箱へ梱包し視覚的にも様々な色彩を楽しめる機能も有するものである。
The soap of the present invention can be produced by producing three indigo extracts alone or by mixing a plurality or all of them to express blue, white, yellow, and purple colors such as indigo, and the shade of each color. In addition, it is possible to produce soaps that are beautiful in color that can image the indigo dye that composes the geometric pattern by combining the design composition.
Each type of soap manufactured by the above method is packed in a cosmetic box and has a function of enjoying various colors visually.
藍種子１６ｇを３００ｍｌの精製水に入れ、１０分間煮沸した後、種子を分別する。この水溶液で８６ｇの水酸化ナトリウムを溶解して、濃度１５０ｇ／Ｌの藍成分入りの水酸化ナトリウム水溶液を作る。
４０７ｇのオリーブ油と１２０ｇのココナッツ油と６３ｇのパーム油と４４ｇのシアバターの混合植物油を所定温度（４０℃）に加温し、同温度に加温した藍入りの水酸化ナトリウム水溶液をかき混ぜながら添加する。さらに粘凋になるまでかき混ぜながらケン化させる。つぎに４５ｇの阿波藍の沈殿藍を添加し、さらにかき混ぜ混合させ成型用の型枠に流し込み、保温箱に所定時間（２４時間）静置する。
得られた石けんは藍色で、泡立ち、水切れが良く、肌になめらかで、刺激がなく、使用後の肌はしっとりし、保湿性がよく、タオルなどにも藍が残らなかった。
16 g of indigo seeds are put into 300 ml of purified water, boiled for 10 minutes, and then seeds are separated. In this aqueous solution, 86 g of sodium hydroxide is dissolved to form a sodium hydroxide aqueous solution containing indigo component having a concentration of 150 g / L.
A mixed vegetable oil of 407 g olive oil, 120 g coconut oil, 63 g palm oil, and 44 g shea butter is heated to a predetermined temperature (40 ° C.) and added while stirring the indigo sodium hydroxide aqueous solution heated to the same temperature. To do. Saponify with stirring until more viscous. Next, 45 g of Awa indigo indigo blue is added, and the mixture is further agitated and mixed, poured into a mold for molding, and left in a heat insulating box for a predetermined time (24 hours).
The resulting soap was indigo-colored, foamed, drained well, smooth on the skin, non-irritating, moisturized and moisturized, and no indigo remained on towels.
実施例１で調整した石けんについて測色色差計EZ200を用いて色を測定した。測定したＬ、ａ、ｂ（Ｌが明るさ、ａは赤→緑、ｂは黄→青）を表１（石けんの色測定結果）に示す。藍の入ってない石けんを標準に藍入り石けんの色の差をΔＬ、Δａ，Δｂで示した。比較例として市販の青色化粧石けんと比較した。Ｌの数字が大きいものは明るく、小さいものほど暗い色で、ａ赤から緑で＋が赤、−は緑、ｂの＋は黄色、−は青を表している。藍入りの石けんは青色に着色しており、市販の青色石けんと同等の青に着色しており、明るい石けんであることが分かった。
次いで、この石けんを使用による着色残留性、すなわち、タオル等への色のこりを上記の装置を使用して測定した。
これらの石けんを白色のタオルにこすりつけて洗濯し、良く水洗いした後乾燥した。これを５回繰り返した後の色を未使用のタオルと比較した。その結果を表２（石けん５回使用後のタオル色）に示す。タオルの色はほぼ未処理のものと同じであり、タオルには藍色が着色しないことが分かった。
The color of the soap prepared in Example 1 was measured using a colorimetric color difference meter EZ200. The measured L, a, and b (L is brightness, a is red → green, and b is yellow → blue) are shown in Table 1 (soap color measurement results). The color difference of soap with indigo is shown as ΔL, Δa, Δb with soap without indigo as standard. As a comparative example, it was compared with a commercially available blue cosmetic soap. Larger L numbers are brighter, and smaller ones are darker colors, a red to green, + is red,-is green, b is +, yellow is-, and-is blue. The indigo soap is colored blue, and it is colored blue equivalent to the commercially available blue soap.
Subsequently, the color persistence due to the use of this soap, that is, the color residue on a towel or the like was measured using the above-mentioned apparatus.
These soaps were rubbed on a white towel, washed, thoroughly washed with water and then dried. The color after repeating this 5 times was compared with an unused towel. The results are shown in Table 2 (towel color after using soap 5 times). The color of the towel was almost the same as the untreated color, and it was found that the towel was not colored indigo.
乾燥した葉藍を所定量（３０ｇ）オリーブ油に入れて、所定時間（２分間）加熱し、冷却した後、葉藍をろ別して取り除く。この葉藍中の油性成分が溶解したオリーブ油は青緑色であった。この油と実施例１において調整した藍種子の水溶性成分を含有する水溶液に水酸化ナトリウムを溶解した水溶液とを所定温度（４０℃）に加温した後、かき混ぜながら混合してケン化する。さらに沈殿藍を混合し、これを成型用の型枠に流し込み、保温箱に所定時間（２４時間）静置して藍色の石けんを得た。泡立ち、洗浄力も通常のオリーブ石けんと同等であり、タオルや肌への着色もなく、使用後の肌の感触は非常に快適で、つるつるでしっとり感のある仕上がりであった。 A predetermined amount (30 g) of dried leaf indigo is placed in olive oil, heated for a specified time (2 minutes), cooled, and then filtered to remove the leaf indigo. The olive oil in which the oily component in the leaf was dissolved was blue-green. This oil and an aqueous solution in which sodium hydroxide is dissolved in an aqueous solution containing the water-soluble component of indigo seed prepared in Example 1 are heated to a predetermined temperature (40 ° C.) and then mixed and saponified while stirring. Further, the precipitated indigo was mixed, poured into a mold for molding, and left in a heat insulating box for a predetermined time (24 hours) to obtain indigo soap. Foaming and detergency were the same as ordinary olive soap, there was no coloring on towels and skin, the skin feel after use was very comfortable, and it was smooth and moist.
藍は古くから染料として利用されてきているが、藍の持つ不思議な機能は昔から知られ、生活に生かされてきている。抗菌性があると言われ、武士は鎧の下に藍染めの肌着を着て、切り傷や虫さされから守ったと言われている。藍染めの着物をタンスに入れて置くと、防虫効果があると言われている。また、ふぐ中毒、食あたり、熱冷ましなどの民間薬として利用されていたと言う。さらに、皮膚の抗炎症性や抗アレルギー性があると言われており、これらの機能を石けんに付与することにより、抗菌、防虫効果とともに、皮膚の炎症を抑えるなどの機能が期待できる。
本発明では藍の機能性成分を３種類の方法で抽出し、それらの成分を有効に利用するものであり、且つ、これらの操作は工業的に簡易であり、実用的なプロセスである。すべて天然物を利用した肌に優しい石けんである。
藍の種子の水溶性成分を熱水で抽出し、葉藍から抽出した沈殿藍、葉藍中の油性成分を植物油中で加熱溶出させる。これらの成分を適宜混合して藍入り石けんを製造するもので、藍中の水溶性、油溶性成分のすべてを利用するものであり、藍の持つ上記機能をすべて有する石けんが期待される。
本発明の石けんは、機能面のみならず藍色等の青色系統、白色系統、黄色系統、紫色系統の色彩を表現でき、該美しい色合を組み合わせて模様を構成する藍染をイメージ出来る色彩的にも美しい石けんとして消費者に届けることができる。また、各種類を化粧箱へ梱包し視覚的にも様々な色彩を楽しめる石けん包装品として、消費者に届けることができる。
Indigo has been used as a dye for a long time, but the mysterious functions of indigo have been known for a long time and have been utilized in daily life. It is said to have antibacterial properties, and samurai wear indigo-dyed underwear under armor to protect them from cuts and insect bites. It is said that placing an indigo-dyed kimono in a chiffon has an insect-repellent effect. In addition, it is said that it was used as a folk medicine such as puffer poisoning, per meal, and heat cooling. Furthermore, it is said that the skin has anti-inflammatory and anti-allergic properties. By adding these functions to soap, functions such as anti-inflammatory and insect-repellent effects as well as suppressing skin inflammation can be expected.
In the present invention, the functional component of indigo is extracted by three kinds of methods, and these components are used effectively, and these operations are industrially simple and practical processes. All soap is gentle on the skin using natural products.
Water-soluble components of indigo seeds are extracted with hot water, and the precipitated indigo extracted from leaf indigo and oily components in leaf indigo are heat-eluted in vegetable oil. These ingredients are mixed as appropriate to produce soap with indigo, which uses all the water-soluble and oil-soluble ingredients in indigo, and is expected to have soap having all the above-mentioned functions of indigo.
The soap of the present invention can express not only the functional aspect but also the blue, white, yellow, and purple colors of indigo, etc. It can be delivered to consumers as beautiful soap. In addition, it can be delivered to consumers as a soap package that can be packaged in a cosmetic box and enjoy various colors visually.
Claims (4)
（１）前記藍として、沈殿藍を用いる場合には、葉藍を発酵させ、色素を溶解させた後、アルカリを加えて沈殿させた沈殿藍を溶解した水溶液に水酸化ナトリウムを溶かしたものをアルカリ原料として用いること、
（２）前記藍として、藍種子の水抽出成分を用いる場合には、藍の種子を水に入れ、煮沸して水溶性成分を煮出した水溶液に水酸化ナトリウムを溶かしたものをアルカリ原料として用いること、
（３）前記藍として、乾燥葉藍の植物油抽出成分を用いる場合には、乾燥した葉藍を石けん原料である植物油に入れ、加熱・煮出し、葉藍中の油溶性成分を溶解させ、不溶性成分をろ過除去した植物油を植物油原料として用いることを特徴とする藍入り石けんの製造方 法。 In the production of soap using alkali and vegetable oil as raw materials, as the indigo to be included in the soap raw material, one or more selected from the group consisting of precipitated indigo, dried leaf indigo vegetable oil extract components, and indigo seed water extract components should be used. A method for producing indigo soap ,
(1) In the case of using precipitated indigo as the indigo , fermented leaf indigo , dissolved pigment, and then dissolved sodium hydroxide in an aqueous solution in which precipitated indigo was precipitated by adding alkali. Use as an alkali raw material,
(2) When using the water extract component of indigo seed as the indigo, a solution obtained by dissolving sodium hydroxide in an aqueous solution in which the indigo seed is put in water and boiled to boil the water-soluble component is used as the alkali raw material. thing,
(3) When using a vegetable oil extract of dried leaf indigo as the indigo, put the dried leaf indigo into vegetable oil, which is a soap raw material, and heat and boil it to dissolve the oil-soluble components in the leaf indigo. producing how indigo containing soap, characterized by using a vegetable oil which was filtered off components as vegetable oil feedstock.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004302527A JP4826989B2 (en) | 2004-10-18 | 2004-10-18 | Indigo soap and its manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004302527A JP4826989B2 (en) | 2004-10-18 | 2004-10-18 | Indigo soap and its manufacturing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2006111793A JP2006111793A (en) | 2006-04-27 |
| JP4826989B2 true JP4826989B2 (en) | 2011-11-30 |
Family
ID=36380581
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004302527A Expired - Fee Related JP4826989B2 (en) | 2004-10-18 | 2004-10-18 | Indigo soap and its manufacturing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4826989B2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI438000B (en) * | 2011-02-18 | 2014-05-21 | Galderma Res & Dev | Oil-extracted products of indigo naturalis, and the preparation process and uses thereof |
| JP6057610B2 (en) * | 2012-03-09 | 2017-01-11 | サンスター株式会社 | Composition containing indigo leaf extract and mugwort extract |
| JP6389492B2 (en) * | 2016-09-29 | 2018-09-12 | 久幸 吉田 | Method for producing tryptanthrin-containing indigo leaf solution |
| JP7244880B2 (en) * | 2020-02-19 | 2023-03-23 | 徳島県 | Method for producing precipitated indigo |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5239002B2 (en) * | 2002-11-28 | 2013-07-17 | 国立大学法人弘前大学 | Antibacterial active substances obtained from indigo grass and various compositions containing the same |
| JP4287719B2 (en) * | 2003-08-28 | 2009-07-01 | リアル化学株式会社 | Hair dye and hair dyeing method using the same |
-
2004
- 2004-10-18 JP JP2004302527A patent/JP4826989B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2006111793A (en) | 2006-04-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102517174B (en) | Camellia facial soap | |
| CN105861195B (en) | A kind of natural handmade soap and preparation method thereof with whitening spot-removing function | |
| CN107296762A (en) | Edible moistens lipstick and its manufacture craft | |
| CN103194334A (en) | Cold process soap added with fresh fig protoplasm | |
| CN102199500A (en) | Formula of Chinese soapberry fruit handmade soap and method for preparing Chinese soapberry fruit handmade soap | |
| CN102732395A (en) | Gingko handmade soap and manufacturing method thereof | |
| KR101587089B1 (en) | Manufacturing method of customized hand-made soap using soap chip containing herb extracts and natural dyes | |
| CN104974866A (en) | Tea seed essence soap and preparation method | |
| CN106309332A (en) | Making process of edible honey lip-moistening lipstick | |
| KR100787105B1 (en) | The herbal loess pack for cosmetic massage and the producing method | |
| CN104928080A (en) | Method for preparing peppermint-green tea handmade soap | |
| CN108373953A (en) | A kind of soapberry ferment handmade soap and preparation method thereof | |
| KR101412713B1 (en) | Natural Soap by using of Ripen and Decocted Oriental Medicine with the function of making age spots and wrinkles better and Manufacturing Method thereof | |
| CN107955757A (en) | A kind of beauty handmade soap and its cold method processed | |
| CN105754759A (en) | Cleaning and skin caring handmade soap | |
| JP4826989B2 (en) | Indigo soap and its manufacturing method | |
| CN104845766A (en) | Handmade Chinese-herbaceous-peony soap and manufacturing method thereof | |
| CN107502490A (en) | One breeding ass oil soap and preparation method thereof | |
| JP2007112943A (en) | Solid soybean milk soap and method for producing the same | |
| KR20130113757A (en) | Soap comprising wood-cultivated ginseng and manufacturing method thereof | |
| CN107653107A (en) | A kind of preparation method of cape jasmine whitening and skin-protecting type craft cold process soap | |
| CN104479937A (en) | Acne-resistant camellia soap for washing face | |
| JP2019523317A (en) | Bar soap composition | |
| CN106520416A (en) | Elsholtzia rugulosa hemsl essential oil soap and preparing method thereof | |
| KR20220029951A (en) | Honey soap and manufacturing method for the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A711 Effective date: 20070928 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20071016 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20080328 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20101130 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110122 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110412 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110524 |
|
| A521 | Written amendment |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110524 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20110809 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20110903 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140922 Year of fee payment: 3 |
|
| R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| LAPS | Cancellation because of no payment of annual fees |