CN107663771A - A kind of fabric radiation agent and preparation method thereof - Google Patents

A kind of fabric radiation agent and preparation method thereof Download PDF

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Publication number
CN107663771A
CN107663771A CN201710680174.0A CN201710680174A CN107663771A CN 107663771 A CN107663771 A CN 107663771A CN 201710680174 A CN201710680174 A CN 201710680174A CN 107663771 A CN107663771 A CN 107663771A
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China
Prior art keywords
parts
fabric
radiation agent
metallic fiber
resin
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CN201710680174.0A
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Chinese (zh)
Inventor
储平
徐有琦
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Jiangsu New Lucky Polytron Technologies Inc
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Jiangsu New Lucky Polytron Technologies Inc
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Priority to CN201710680174.0A priority Critical patent/CN107663771A/en
Publication of CN107663771A publication Critical patent/CN107663771A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/49Oxides or hydroxides of elements of Groups 8, 9,10 or 18 of the Periodic Table; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/55Epoxy resins
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/59Polyamides; Polyimides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of preparation method of fabric radiation agent, the fabric radiation agent is made up of the raw material of following parts by weight:25 30 parts of resin, 5 10 parts of nano particle, 35 parts of silane coupler, 10 20 parts of metallic fiber powder, 35 parts of polyacrylate dispersion, 10 20 parts of water, 35 parts of polyethylene glycol, 50 100 parts of ethanol.After the fabric radiation agent application fabric of the present invention, the radiation proof efficiency of fabric reaches more than 90%.The fabric radiation agent manufacturing process of the present invention is simple to operation, and low in raw material price is easily obtained, and nontoxic, and human body is not stimulated, and volatility is low, and the fabric after arrangement its toughness, intensity, feel are substantially unaffected.

Description

A kind of fabric radiation agent and preparation method thereof
Technical field
The invention belongs to technical field of textile auxiliary agent, specifically relates to a kind of fabric radiation agent.
Background technology
With the further development of electrical technology, radiate and be seen everywhere around us.The hand being either seen everywhere Mechanical, electrical brain, printer, or household electrical appliance micro-wave oven, electric blanket, hair-dryer, can all there is certain radiation.Although household electrical appliance Harm of the radiation for people without very big, but when the electric radiation of human body local environment exceedes certain intensity or produces certain Cumulative effect when, can have the weaker old man of certain infringement, especially resistance, child, pregnant woman etc. to health.
The harm of radiation is a lot, such as:Children's intelligence can be caused incomplete;It is most likely the reason for causing children's cases with leukemia One of;Cancer can be induced and accelerate the cancer cell multiplication of human body;The reproductive system of people is influenceed, is mainly shown as man's sperm matter Amount reduces, and spontaneous abortion and fetal anomaly etc. occur for pregnant woman;The cardiovascular system of people is influenceed, palpitaition is shown as, hair loss, loses Sleep, bradycardia, heartbeat oligemia, Neuroleptic Leukocytopenia, immunologic function decline etc..
Radiation-proof fabric in the market, usually with blending metallic fiber, conductive fiber, cost is high, not water-fastness, Some people has allergic reaction, therefore, finds a kind of durable, comfortable fabric radiation agent and is very important.
The content of the invention
It is an object of the invention to provide a kind of fabric radiation agent and preparation method, to solve to carry in above-mentioned background technology The problem of going out.
To achieve the above object, the present invention provides following technical scheme:
A kind of fabric radiation agent, the fabric radiation agent include the raw material of following parts by weight:Resin 25-30 parts, Nano particle 5-10 parts, silane coupler 3-5 parts, metallic fiber powder 10-20 parts, polyacrylate dispersion 3-5 parts, plant juice Liquid 10-20 parts, polyethylene glycol 3-5 parts, ethanol 50-100 parts.
Preferably, described resin is in organic siliconresin, epoxy resin, polyamide, polyacrylics One or more than one kinds of mixtures.
Preferably, described nano particle is nano silicon, nano titanium oxide, nano ferriferrous oxide, nanometer One or more than one kinds of mixtures in aluminum oxide.
Preferably, described silane coupler is 3- aminopropyl trimethoxysilanes, γ-(2,3- the third oxygen of epoxy) propyl group three Ethoxysilane, γ-methacryloxypropyl trimethoxy silane, N- (β-aminoethyl)-gamma-aminopropyl-triethoxy silicon Any one in alkane, aniline isophorone and γ-aminopropyltriethoxy diethoxy silane or more than one mixture.
Preferably, described metallic fiber be silver plated fiber, plating aluminum fiber, Cu coated fibre, one kind in nickel plating fiber or More than one mixture of person.
Preferably, described water is Gem flower-shaped three-dimensional jig-saw puzzle juice, red-spotted stonecrop juice, cactus juice, rape juice, shepherd's purse juice One or more than one kinds of mixtures in liquid.
Preferably, the fabric radiation agent is made up of the raw material of following parts by weight:25 parts of resin, 5 parts of nano particle, 3 parts of silane coupler, 10 parts of metallic fiber powder, 3 parts of polyacrylate dispersion, 10 parts of water, 3 parts of polyethylene glycol, second 50 parts of alcohol.
Preferably, the fabric radiation agent is made up of the raw material of following parts by weight:28 parts of resin, 8 parts of nano particle, 4 parts of silane coupler, 15 parts of metallic fiber powder, 4 parts of polyacrylate dispersion, 15 parts of water, 4 parts of polyethylene glycol, second 75 parts of alcohol.
Preferably, the fabric radiation agent is made up of the raw material of following parts by weight:30 parts of resin, nano particle 10 Part, 5 parts of silane coupler, 20 parts of metallic fiber powder, 5 parts of polyacrylate dispersion, 20 parts of water, 5 parts of polyethylene glycol, 100 parts of ethanol.
Preferably, a kind of preparation method of fabric radiation agent, it is characterised in that:Comprise the following steps that:
Step 1, resin 25-30 parts, silane coupler 3-5 parts, nano particle 5-10 parts, 1000- are added in a kettle 3000 revs/min, stir 30-40 minutes;
Step 2, first the metallic fiber of 10-20 parts is crushed with pulverizer, then ground with grinder so that metallic fiber powder The particle diameter at end is in 1-100nm;
Step 3, the metallic fiber powder of step 2 is added in ethanol 50-100 parts, ultrasonic disperse, rate of dispersion 2000- 3000 revs/min, jitter time 20-30 minutes;
Step 4, the homogeneous solution of step 3 is poured into the solution of step 1,1000-3000 revs/min, 20-30 points of stirring Clock;
Step 5, heating temperature adds polyacrylate dispersion 3-5 parts, water 10-20 parts, poly- second two to 70-80 DEG C Alcohol 3-5 parts, 500-1000 revs/min, stir 20-30 minutes;
Step 6, room temperature is cooled to, closes down stirring, the liquid fabric antiradiation agent prepared;
Step 7, stand and be cooled in stirred tank liquid fabric antiradiation agent and be less than 20 DEG C, blowing encapsulation, finished product.
Compared with prior art, the beneficial effects of the invention are as follows:
1st, after fabric radiation agent application fabric of the invention, the radiation proof efficiency of fabric reaches more than 90%.
2nd, fabric radiation agent manufacturing process of the invention is simple to operation, and low in raw material price easily obtains, and nontoxic nothing Evil, is not stimulated human body, and volatility is low, and the fabric after arrangement its toughness, intensity, feel are substantially unaffected.
3rd, mutual compatibility, synergy between various raw materials used in fabric radiation agent of the invention, collectively constitute performance Excellent product.
4th, the addition of water, the shielding property of fabric is improved.
5th, technique is simplified, safe operation is simple, is easy to industrialized production.
6th, fabric radiation coating construction is simple of the invention, can by impregnating, spraying, roller coat etc. applied, it is raw Efficiency is produced to improve.
7th, use of the invention can receive good economic benefit.
Example is embodied
The invention discloses a kind of fabric radiation agent, according to important number, it is prepared from the following components:Resin 25- 30 parts, nano particle 5-10 parts, silane coupler 3-5 parts, metallic fiber powder 10-20 parts, polyacrylate dispersion 3-5 parts, Water 10-20 parts, polyethylene glycol 3-5 parts, ethanol 50-100 parts.
Present invention also offers a kind of preparation method of fabric radiation agent, comprise the following steps that:
(1) resin 25-30 parts, silane coupler 3-5 parts, nano particle 5-10 parts, 1000-3000 are added in a kettle Rev/min, stir 30-40 minutes;
(2) first the metallic fiber of 10-20 parts is crushed with pulverizer, then ground with grinder so that metallic fiber powder Particle diameter in 1-100nm;
(3) the metallic fiber powder of step (2) is added in ethanol 50-100 parts, ultrasonic disperse, rate of dispersion 2000- 3000 revs/min, jitter time 20-30 minutes;
(4) homogeneous solution of step (3) is poured into the solution of step (1), 1000-3000 revs/min, stirs 20-30 Minute;
(5) heating temperature adds polyacrylate dispersion 3-5 parts, water 10-20 parts, polyethylene glycol 3- to 70-80 DEG C 5 parts, 500-1000 revs/min, stir 20-30 minutes;
(6) room temperature is cooled to, closes down stirring, the liquid fabric antiradiation agent prepared;
(7) stand and be cooled in stirred tank liquid fabric antiradiation agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 1
The invention discloses a kind of fabric radiation agent, according to important number, it is prepared from the following components:Resin 25 Part, 5 parts of nano particle, 3 parts of silane coupler, 10 parts of metallic fiber powder, 3 parts of polyacrylate dispersion, 10 parts of water, 3 parts of polyethylene glycol, 50 parts of ethanol.
Present invention also offers a kind of preparation method of fabric radiation agent, comprise the following steps that:
(1) 25 parts of resin, 3 parts of silane coupler, 5 parts of nano particle are added in a kettle, 1000 revs/min, are stirred 30 minutes;
(2) first 10 parts of metallic fiber is crushed with pulverizer, then ground with grinder so that the grain of metallic fiber powder Footpath is in 1-100nm;
(3) the metallic fiber powder of step (2) is added in 50 parts of ethanol, ultrasonic disperse, 2000 revs/min of rate of dispersion Clock, jitter time 20 minutes;
(4) homogeneous solution of step (3) is poured into the solution of step (1), 1000 revs/min, stirred 20 minutes;
(5) heating temperature is to 70 DEG C, 3 parts of polyacrylate dispersion of addition, 10 parts of water, 3 parts of polyethylene glycol, 500 turns/ Minute, stir 20 minutes;
(6) room temperature is cooled to, closes down stirring, the liquid fabric antiradiation agent prepared;
(7) stand and be cooled in stirred tank liquid fabric antiradiation agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 2
The invention discloses a kind of fabric radiation agent, according to important number, it is prepared from the following components:Resin 28 Part, 8 parts of nano particle, 4 parts of silane coupler, 15 parts of metallic fiber powder, 4 parts of polyacrylate dispersion, 15 parts of water, 4 parts of polyethylene glycol, 75 parts of ethanol.
Present invention also offers a kind of preparation method of fabric radiation agent, comprise the following steps that:
(1) 28 parts of resin, 4 parts of silane coupler, 8 parts of nano particle are added in a kettle, 2000 revs/min, are stirred 35 minutes;
(2) first 15 parts of metallic fiber is crushed with pulverizer, then ground with grinder so that the grain of metallic fiber powder Footpath is in 1-100nm;
(3) the metallic fiber powder of step (2) is added in 75 parts of ethanol, ultrasonic disperse, 2500 revs/min of rate of dispersion Clock, jitter time 25 minutes;
(4) homogeneous solution of step (3) is poured into the solution of step (1), 2000 revs/min, stirred 25 minutes;
(5) heating temperature is to 75 DEG C, 4 parts of polyacrylate dispersion of addition, 15 parts of water, 4 parts of polyethylene glycol, 750 turns/ Minute, stir 25 minutes;
(6) room temperature is cooled to, closes down stirring, the liquid fabric antiradiation agent prepared;
(7) stand and be cooled in stirred tank liquid fabric antiradiation agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 3
The invention discloses a kind of fabric radiation agent, according to important number, it is prepared from the following components:Resin 30 Part, 10 parts of nano particle, 5 parts of silane coupler, 20 parts of metallic fiber powder, 5 parts of polyacrylate dispersion, water 20 Part, 5 parts of polyethylene glycol, 100 parts of ethanol.
Present invention also offers a kind of preparation method of fabric radiation agent, comprise the following steps that:
(1) 30 parts of resin, 5 parts of silane coupler, 10 parts of nano particle are added in a kettle, 3000 revs/min, are stirred 40 minutes;
(2) first 20 parts of metallic fiber is crushed with pulverizer, then ground with grinder so that the grain of metallic fiber powder Footpath is in 1-100nm;
(3) the metallic fiber powder of step (2) is added in 100 parts of ethanol, ultrasonic disperse, 3000 revs/min of rate of dispersion Clock, jitter time 30 minutes;
(4) homogeneous solution of step (3) is poured into the solution of step (1), 3000 revs/min, stirred 30 minutes;
(5) heating temperature is to 80 DEG C, 5 parts of polyacrylate dispersion of addition, 20 parts of water, 5 parts of polyethylene glycol, and 1000 Rev/min, stir 30 minutes;
(6) room temperature is cooled to, closes down stirring, the liquid fabric antiradiation agent prepared;
(7) stand and be cooled in stirred tank liquid fabric antiradiation agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 4
The invention discloses a kind of fabric radiation agent, according to important number, it is prepared from the following components:Resin 25 Part, 10 parts of nano particle, 4 parts of silane coupler, 15 parts of metallic fiber powder, 3 parts of polyacrylate dispersion, water 20 Part, 3 parts of polyethylene glycol, 80 parts of ethanol.
Present invention also offers a kind of preparation method of fabric radiation agent, comprise the following steps that:
(1) 25 parts of resin, 4 parts of silane coupler, 10 parts of nano particle are added in a kettle, 3000 revs/min, are stirred 40 minutes;
(2) first 15 parts of metallic fiber is crushed with pulverizer, then ground with grinder so that the grain of metallic fiber powder Footpath is in 1-100nm;
(3) the metallic fiber powder of step (2) is added in 80 parts of ethanol, ultrasonic disperse, 2000 revs/min of rate of dispersion Clock, jitter time 30 minutes;
(4) homogeneous solution of step (3) is poured into the solution of step (1), 3000 revs/min, stirs 20-30 minutes;
(5) heating temperature is to 80 DEG C, 3 parts of polyacrylate dispersion of addition, 20 parts of water, 3 parts of polyethylene glycol, and 1000 Rev/min, stir 30 minutes;
(6) room temperature is cooled to, closes down stirring, the liquid fabric antiradiation agent prepared;
(7) stand and be cooled in stirred tank liquid fabric antiradiation agent and be less than 20 DEG C, blowing encapsulation, finished product.
Test case
4 pieces of identical pure cotton cloths are put into the antiradiation agent solution of embodiment 1,2,3,4, roll, dry by two leachings two, Bake, wash, drying, 4 pieces of cloth with shielding property can be obtained.The result for testing radiation proof efficiency is as follows:
Embodiment Radiation proof efficiency (%)
1 90
2 95
3 99
4 98
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (10)

  1. A kind of 1. fabric radiation agent, it is characterised in that:The fabric radiation agent includes the raw material of following parts by weight:Resin 25-30 parts, nano particle 5-10 parts, silane coupler 3-5 parts, metallic fiber powder 10-20 parts, polyacrylate dispersion 3-5 Part, water 10-20 parts, polyethylene glycol 3-5 parts, ethanol 50-100 parts.
  2. 2. fabric radiation agent according to claim 1, it is characterised in that:Described resin is organic siliconresin, epoxy One or more than one kinds of mixtures in resin, polyamide, polyacrylics.
  3. 3. fabric radiation agent according to claim 1, it is characterised in that:Described nano particle is nanometer titanium dioxide One or more than one kinds of mixtures in silicon, nano titanium oxide, nano ferriferrous oxide, nano aluminium oxide.
  4. 4. fabric radiation agent according to claim 1, it is characterised in that:Described silane coupler is 3- aminopropyls three Methoxy silane, γ-(oxygen of 2,3- epoxies third) propyl-triethoxysilicane, γ-methacryloxypropyl trimethoxy silicon Alkane, N- (β-aminoethyl)-gamma-aminopropyl-triethoxy-silane, aniline isophorone and γ-aminopropyltriethoxy diethoxy silicon Any one in alkane or more than one mixture.
  5. 5. fabric radiation agent according to claim 1, it is characterised in that:Described metallic fiber is silver plated fiber, plating One or more than one kinds of mixtures in aluminum fiber, Cu coated fibre, nickel plating fiber.
  6. 6. fabric radiation agent according to claim 1, it is characterised in that:Described water be Gem flower-shaped three-dimensional jig-saw puzzle juice, One or more than one kinds of mixtures in red-spotted stonecrop juice, cactus juice, rape juice, shepherd's purse juice.
  7. 7. fabric radiation agent according to claim 1, it is characterised in that:The fabric radiation agent is by following parts by weight Several raw material compositions:25 parts of resin, 5 parts of nano particle, 3 parts of silane coupler, 10 parts of metallic fiber powder, polyacrylate breast 3 parts of liquid, 10 parts of water, 3 parts of polyethylene glycol, 50 parts of ethanol.
  8. 8. fabric radiation agent according to claim 1, it is characterised in that:The fabric radiation agent is by following parts by weight Several raw material compositions:28 parts of resin, 8 parts of nano particle, 4 parts of silane coupler, 15 parts of metallic fiber powder, polyacrylate breast 4 parts of liquid, 15 parts of water, 4 parts of polyethylene glycol, 75 parts of ethanol.
  9. 9. fabric radiation agent according to claim 1, it is characterised in that:The fabric radiation agent is by following parts by weight Several raw material compositions:30 parts of resin, 10 parts of nano particle, 5 parts of silane coupler, 20 parts of metallic fiber powder, polyacrylate 5 parts of emulsion, 20 parts of water, 5 parts of polyethylene glycol, 100 parts of ethanol.
  10. 10. a kind of preparation method of any described fabric radiation agent, its feature exist in a kind of 1-9 using the claims In:Comprise the following steps that:
    Step 1, resin 25-30 parts, silane coupler 3-5 parts, nano particle 5-10 parts, 1000-3000 are added in a kettle Rev/min, stir 30-40 minutes;
    Step 2, first the metallic fiber of 10-20 parts is crushed with pulverizer, then ground with grinder so that metallic fiber powder Particle diameter is in 1-100nm;
    Step 3, the metallic fiber powder of step 2 is added in ethanol 50-100 parts, ultrasonic disperse, rate of dispersion 2000-3000 Rev/min, jitter time 20-30 minutes;
    Step 4, the homogeneous solution of step 3 is poured into the solution of step 1,1000-3000 revs/min, stirs 20-30 minutes;
    Step 5, heating temperature adds polyacrylate dispersion 3-5 parts, water 10-20 parts, polyethylene glycol 3-5 to 70-80 DEG C Part, 500-1000 revs/min, stir 20-30 minutes;
    Step 6, room temperature is cooled to, closes down stirring, the liquid fabric antiradiation agent prepared;
    Step 7, stand and be cooled in stirred tank liquid fabric antiradiation agent and be less than 20 DEG C, blowing encapsulation, finished product.
CN201710680174.0A 2017-08-10 2017-08-10 A kind of fabric radiation agent and preparation method thereof Pending CN107663771A (en)

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CN109972405A (en) * 2019-04-04 2019-07-05 六安市海洋羽毛有限公司 A kind of processing method with shielding electromagnetic radiation and anti-static function natural feather
CN110387751A (en) * 2019-07-30 2019-10-29 南京工业大学 It is a kind of to radiate from cooling function fabric and preparation method thereof
CN110747634A (en) * 2019-11-28 2020-02-04 南京海派企业管理咨询有限公司 Textile radiation-proof agent and preparation method thereof

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CN109972405A (en) * 2019-04-04 2019-07-05 六安市海洋羽毛有限公司 A kind of processing method with shielding electromagnetic radiation and anti-static function natural feather
CN110387751A (en) * 2019-07-30 2019-10-29 南京工业大学 It is a kind of to radiate from cooling function fabric and preparation method thereof
CN110747634A (en) * 2019-11-28 2020-02-04 南京海派企业管理咨询有限公司 Textile radiation-proof agent and preparation method thereof

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