CN106758399A - A kind of antiultraviolet pearly-lustre figured cloth and preparation method thereof - Google Patents

A kind of antiultraviolet pearly-lustre figured cloth and preparation method thereof Download PDF

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CN106758399A
CN106758399A CN201710048308.7A CN201710048308A CN106758399A CN 106758399 A CN106758399 A CN 106758399A CN 201710048308 A CN201710048308 A CN 201710048308A CN 106758399 A CN106758399 A CN 106758399A
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parts
antiultraviolet
pearly
lustre
figured cloth
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许连习
蔡丽萍
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67383Inorganic compounds containing silicon
    • DTEXTILES; PAPER
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    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • D06B3/18Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
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    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic System; Zincates; Cadmates
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    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
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    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165Ethers
    • D06M13/175Unsaturated ethers, e.g. vinylethers
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    • D06M15/17Natural resins, resinous alcohols, resinous acids, or derivatives thereof
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    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
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    • D06P1/46General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
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    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642Compounds containing nitrogen
    • D06P1/649Compounds containing carbonamide, thiocarbonamide or guanyl groups
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    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
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    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82Textiles which contain different kinds of fibres
    • D06P3/8204Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8219Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and amide groups
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    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
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    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34Polyamides
    • D06M2101/36Aromatic polyamides
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    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments

Abstract

The present invention relates to a kind of antiultraviolet pearly-lustre figured cloth and preparation method thereof, belong to technical field of textile fabric.The antiultraviolet pearly-lustre figured cloth is included on fabric to carry out Pearl Printing and carries out antiultraviolet treatment by padding method;Wherein print paste is obtained by following component:12 18 parts of mica titanium nacreous material, 834 20 32 parts of adhesive R, 6 10 parts of starch, 58 parts of sodium alginate, 25 parts of propane diols, 0.5 3 parts of urea, 30 48 parts of water;Padding liquid during antiultraviolet treatment is obtained by following component:58 parts of nano zine oxide, 27 parts of nano titanium oxide, 14 parts of nano silicon, 12 20 parts of aqueous rosin resin emulsion, 0.5 2 parts of eugenol, 6 13 parts of amino silicone breast, 7 15 parts of KG 500A waterproofing agents, 32 45 parts of water.The antiultraviolet pearly-lustre figured cloth has bright color, color fastness high, and preventing ultraviolet effect it is good the advantages of.

Description

A kind of antiultraviolet pearly-lustre figured cloth and preparation method thereof
Technical field
The invention belongs to technical field of textile fabric, and in particular to a kind of antiultraviolet pearly-lustre figured cloth and preparation method thereof.
Background technology
Pearl Printing is a kind of stamp mode of special-effect, has used one kind to have " preparation of pearly luster " in fabric Upper stamp, this preparation can flash pearlescent gloss due to the multi-level reflex to light, produce textile printing surface Natural, graceful and poised graceful, splendid, exquisite unique, soft pleasing visual effect, takes the course of its own in numerous stamp modes, turns into A kind of pandemic dress and adornment technology.
Nowadays, people are not only high to appearance requirement, and increasingly focus on healthy and safe, and its middle-ultraviolet lamp is to human body Injury, is paid attention to by increasing consumer.Ultraviolet in solar spectrum not only makes textile fade and brittle, Human body skin sunburn can be made aging, melanin and color spot is produced, more serious can also induce canceration, endanger human health.
And in the prior art, to obtain the pearly-lustre figured cloth with anti-ultraviolet function, more using directly by ultraviolet screener Agent is added in print paste, and the product ability and ultraviolet resistance that the method is obtained is weaker, it is impossible to meet the high request of client;Or One layer of ultraviolet-proof is coated on pearly-lustre figured cloth surface, the product that this kind of method is obtained is initially that can meet antiultraviolet to want Ask, but by washing for several times after, effect can be faded, and the suction of cloth can be to a certain extent influenceed using coating way Green permeability.Therefore, be worth research carries out antiultraviolet treatment on the basis of pearly-lustre figured cloth, obtains the antiultraviolet of high-quality It is nontoxic, safe to the human body after pearly-lustre figured cloth, and treatment, it is non-stimulated to skin, without allergic reaction, while not influenceing the color of fabric Pool, strength and sucting wet air permeability.
The content of the invention
The invention aims to solve the deficiencies in the prior art, and provide a kind of antiultraviolet pearly-lustre figured cloth and its system Preparation Method, the antiultraviolet pearly-lustre figured cloth has bright color, color fastness high, and preventing ultraviolet effect it is good the advantages of.
The present invention is adopted the following technical scheme that:
A kind of antiultraviolet pearly-lustre figured cloth, being included on fabric carries out Pearl Printing and passes through on the pearly-lustre figured cloth for obtaining Padding method carries out antiultraviolet treatment;The print paste used in wherein described Pearl Printing is by according to the as follows of mass fraction meter Component is obtained:Mica titanium nacreous material 12-18 parts, 20-32 parts of adhesive R-834, starch 6-10 parts, sodium alginate 5-8 parts, Propane diols 2-5 parts, urea 0.5-3 parts, water 30-48 parts;The padding liquid carried out when antiultraviolet is processed is by according to mass parts The following component of number meter is obtained:Nano zine oxide 5-8 parts, nano titanium oxide 2-7 parts, nano silicon 1-4 parts, aqueous pine 12-20 parts of botany bar gum emulsion, eugenol 0.5-2 parts, 6-13 parts of amino silicone breast, 7-15 parts, water 32-45 parts of KG-500A waterproofing agents.
Further, it is obtained by spinning, weaving after the fabric is mixed by aramid fiber and FRC.
Further, weight ratio shared by the FRC is 20%-35%.
Further, the aramid fiber is one or two mixing in aramid fiber 1313 and Fanglun l414 fiber Thing.
Further, from silvery white mica titanium series, particle size is 400-800 to the mica titanium nacreous material Mesh.
The present invention also provides a kind of preparation method of antiultraviolet pearly-lustre figured cloth, comprises the following steps:
1) fiber is obtained fabric through spinning, weaving;
2) fabric pretreatment is made it have into good wetability, so that mill base is even into fiber, according to the quality , first be added to the water for starch, sodium alginate and propane diols and stir by proportioning, sequentially adds urea, mica titanium nacreous material With adhesive R-834, stir prepared print paste, carries out screen printing;
3) by step 2) vapour steaming colour fixing is carried out after the drying of the cloth that obtains;
4) cloth after fixation soaped, washed, thickener and chemical agent in removal loose colour and mill base;
5) according to the quality proportioning, first nano zine oxide, nano titanium oxide and nano silicon are well mixed, Stirred during itself and aqueous rosin resin emulsion, amino silicone breast are sequentially added into water again, be warming up to 35 DEG C, add eugenol and KG-500A waterproofing agents stir, and natural cooling obtains final product padding liquid, by step 4) cloth that obtains impregnated in wherein, a leaching one Roll, pick-up rate is 80%, in being dried at 140 DEG C -150 DEG C, obtain final product the antiultraviolet pearly-lustre figured cloth.
Further, the step 3) in vapour steaming colour fixing when, temperature be 100 DEG C -120 DEG C, the time is 30min.
Further, the step 4) in soap temperature for 95 DEG C, the time is 20min, and washing temperature is 95 DEG C, time It is 40min.
Compared with prior art, its advantage is the present invention:Antiultraviolet pearly-lustre figured cloth of the invention has color and luster bright Beautiful, color fastness advantage high, the suitable mica titanium nacreous material of particle diameter is with starch, sodium alginate in cosolvent urea and bonding In the presence of agent R-834, it is uniformly dispersed and is effectively attached on fiber, makes that textile printing gloss is beautiful, exquisite uniqueness;This hair It is bright to have used zinc oxide, titanium dioxide and the various nano-powder interworkings of silica, and in the print paste of abandoning tradition directly Addition ultraviolet light screener and coating, and antiultraviolet treatment is carried out to pearly-lustre figured cloth using padding method, obtain high-quality Antiultraviolet pearly-lustre figured cloth, UPF values reach 50+, and ultraviolet shielding rate is up to 99%, and nontoxic, safe to the human body, stingless to skin Swash, without allergic reaction, and do not influence color and luster, strength and the sucting wet air permeability of fabric, while also antibacterial, moldproof, anti-odour function, can Meaning is achieved many things at one stroke.
Specific embodiment
With reference to specific embodiment, the present invention is described in further detail.
It will be understood to those of skill in the art that the following example is merely to illustrate the present invention, and should not be regarded as limiting this hair Bright scope.
Embodiment 1
A kind of antiultraviolet pearly-lustre figured cloth, being included on fabric carries out Pearl Printing and passes through on the pearly-lustre figured cloth for obtaining Padding method carries out antiultraviolet treatment;The print paste used in wherein described Pearl Printing is by according to the as follows of mass fraction meter Component is obtained:400 12 parts of mesh Silver Mica Pearlescentpigments, 20 parts of adhesive R-834,6 parts of starch, 5 parts of sodium alginate, 2 parts of propane diols, 0.5 part of urea, 30 parts of water;It is described carry out antiultraviolet process when padding liquid by according to mass fraction meter as Lower component is obtained:5 parts of nano zine oxide, 2 parts of nano titanium oxide, 1 part of nano silicon, aqueous rosin resin emulsion 12 Part, 6 parts of 0.5 part of eugenol, amino silicone breast, 7 parts of KG-500A waterproofing agents, 32 parts of water, wherein the fabric is by aramid fiber 1313 It is obtained by spinning, weaving with after FRC mixing, weight ratio shared by FRC is 20%.
The preparation method of the antiultraviolet pearly-lustre figured cloth, comprises the following steps:
1) fiber is obtained fabric through spinning, weaving;
2) fabric pretreatment is made it have into good wetability, so that mill base is even into fiber, according to the quality , first be added to the water for starch, sodium alginate and propane diols and stir by proportioning, sequentially adds urea, mica titanium nacreous material With adhesive R-834, stir prepared print paste, carries out screen printing;
3) by step 2) vapour steaming colour fixing is carried out after the drying of the cloth that obtains, temperature is 100 DEG C, and the time is 30min;
4) cloth after fixation soaped, washed, thickener and chemical agent in removal loose colour and mill base are soaped Temperature is 95 DEG C, and the time is 20min, and washing temperature is 95 DEG C, and the time is 40min;
5) according to the quality proportioning, first nano zine oxide, nano titanium oxide and nano silicon are well mixed, Stirred during itself and aqueous rosin resin emulsion, amino silicone breast are sequentially added into water again, be warming up to 35 DEG C, add eugenol and KG-500A waterproofing agents stir, and natural cooling obtains final product padding liquid, by step 4) cloth that obtains impregnated in wherein, a leaching one Roll, pick-up rate is 80%, in being dried at 140 DEG C, obtain final product the antiultraviolet pearly-lustre figured cloth.
Embodiment 2
A kind of antiultraviolet pearly-lustre figured cloth, being included on fabric carries out Pearl Printing and passes through on the pearly-lustre figured cloth for obtaining Padding method carries out antiultraviolet treatment;The print paste used in wherein described Pearl Printing is by according to the as follows of mass fraction meter Component is obtained:600 15 parts of mesh Silver Mica Pearlescentpigments, 27 parts of adhesive R-834,8 parts of starch, 6 parts of sodium alginate, 3 parts of propane diols, 2 parts of urea, 40 parts of water;The padding liquid carried out when antiultraviolet is processed is by according to the as follows of mass fraction meter Component is obtained:6 parts of nano zine oxide, 5 parts of nano titanium oxide, 3 parts of nano silicon, 16 parts of aqueous rosin resin emulsion, 1 part of eugenol, 9 parts of amino silicone breast, 12 parts of KG-500A waterproofing agents, 38 parts of water, wherein the fabric is by Fanglun l414 fiber and resistance It is obtained by spinning, weaving after combustion viscose rayon mixing, weight ratio shared by FRC is 27%.
The preparation method of the antiultraviolet pearly-lustre figured cloth, comprises the following steps:
1) fiber is obtained fabric through spinning, weaving;
2) fabric pretreatment is made it have into good wetability, so that mill base is even into fiber, according to the quality , first be added to the water for starch, sodium alginate and propane diols and stir by proportioning, sequentially adds urea, mica titanium nacreous material With adhesive R-834, stir prepared print paste, carries out screen printing;
3) by step 2) vapour steaming colour fixing is carried out after the drying of the cloth that obtains, temperature is 110 DEG C, and the time is 30min;
4) cloth after fixation soaped, washed, thickener and chemical agent in removal loose colour and mill base are soaped Temperature is 95 DEG C, and the time is 20min, and washing temperature is 95 DEG C, and the time is 40min;
5) according to the quality proportioning, first nano zine oxide, nano titanium oxide and nano silicon are well mixed, Stirred during itself and aqueous rosin resin emulsion, amino silicone breast are sequentially added into water again, be warming up to 35 DEG C, add eugenol and KG-500A waterproofing agents stir, and natural cooling obtains final product padding liquid, by step 4) cloth that obtains impregnated in wherein, a leaching one Roll, pick-up rate is 80%, in being dried at 145 DEG C, obtain final product the antiultraviolet pearly-lustre figured cloth.
Embodiment 3
A kind of antiultraviolet pearly-lustre figured cloth, being included on fabric carries out Pearl Printing and passes through on the pearly-lustre figured cloth for obtaining Padding method carries out antiultraviolet treatment;The print paste used in wherein described Pearl Printing is by according to the as follows of mass fraction meter Component is obtained:800 18 parts of mesh Silver Mica Pearlescentpigments, 32 parts of adhesive R-834,10 parts of starch, 8 parts of sodium alginate, 5 parts of propane diols, 3 parts of urea, 48 parts of water;The padding liquid carried out when antiultraviolet is processed is by according to the as follows of mass fraction meter Component is obtained:8 parts of nano zine oxide, 7 parts of nano titanium oxide, 4 parts of nano silicon, 20 parts of aqueous rosin resin emulsion, 2 parts of eugenol, 13 parts of amino silicone breast, 15 parts of KG-500A waterproofing agents, 45 parts of water, wherein the fabric by aramid fiber 1313 and It is obtained by spinning, weaving after FRC mixing, weight ratio shared by FRC is 35%.
The preparation method of the antiultraviolet pearly-lustre figured cloth, comprises the following steps:
1) fiber is obtained fabric through spinning, weaving;
2) fabric pretreatment is made it have into good wetability, so that mill base is even into fiber, according to the quality , first be added to the water for starch, sodium alginate and propane diols and stir by proportioning, sequentially adds urea, mica titanium nacreous material With adhesive R-834, stir prepared print paste, carries out screen printing;
3) by step 2) vapour steaming colour fixing is carried out after the drying of the cloth that obtains, temperature is 120 DEG C, and the time is 30min;
4) cloth after fixation soaped, washed, thickener and chemical agent in removal loose colour and mill base are soaped Temperature is 95 DEG C, and the time is 20min, and washing temperature is 95 DEG C, and the time is 40min;
5) according to the quality proportioning, first nano zine oxide, nano titanium oxide and nano silicon are well mixed, Stirred during itself and aqueous rosin resin emulsion, amino silicone breast are sequentially added into water again, be warming up to 35 DEG C, add eugenol and KG-500A waterproofing agents stir, and natural cooling obtains final product padding liquid, by step 4) cloth that obtains impregnated in wherein, a leaching one Roll, pick-up rate is 80%, in being dried at 150 DEG C, obtain final product the antiultraviolet pearly-lustre figured cloth.
The antiultraviolet pearly-lustre figured cloth of the gained of the embodiment of the present invention 1 to 3 is carried out into performance test, it is as a result as shown in table 1 below:
The performance test data of the antiultraviolet pearly-lustre figured cloth of the gained of 1 embodiment of table 1 to 3
In from table, antiultraviolet pearly-lustre figured cloth of the invention is washable, colour fastness to rubbing is high, and preventing ultraviolet effect It is good, better than common like product on the market.
It should be understood by those skilled in the art that, the present invention is not limited to the above embodiments, above-described embodiment and explanation Merely illustrating the principles of the invention described in book, without departing from the spirit and scope of the present invention, the present invention also has Various changes and modifications, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention By appending claims and its equivalent thereof.

Claims (8)

1. a kind of antiultraviolet pearly-lustre figured cloth, it is characterised in that being included on fabric carries out Pearl Printing and in the pearly-lustre for obtaining Antiultraviolet treatment is carried out by padding method on figured cloth;The print paste used in wherein described Pearl Printing is by according to mass parts The following component of number meter is obtained:Mica titanium nacreous material 12-18 parts, 20-32 parts of adhesive R-834, starch 6-10 parts, marine alga Sour sodium 5-8 parts, propane diols 2-5 parts, urea 0.5-3 parts, water 30-48 parts;It is described carry out antiultraviolet process when padding liquid by Following component according to mass fraction meter is obtained:Nano zine oxide 5-8 parts, nano titanium oxide 2-7 parts, nano silicon 1- 4 parts, 12-20 parts of aqueous rosin resin emulsion, eugenol 0.5-2 parts, 6-13 parts of amino silicone breast, 7-15 parts of KG-500A waterproofing agents, Water 32-45 parts.
2. a kind of antiultraviolet pearly-lustre figured cloth according to claim 1, it is characterised in that the fabric by aramid fiber and It is obtained by spinning, weaving after FRC mixing.
3. a kind of antiultraviolet pearly-lustre figured cloth according to claim 2, it is characterised in that shared by the FRC Weight ratio is 20%-35%.
4. a kind of antiultraviolet pearly-lustre figured cloth according to claim 2, it is characterised in that the aramid fiber is aramid fiber One or two mixtures in 1313 fibers and Fanglun l414 fiber.
5. a kind of antiultraviolet pearly-lustre figured cloth according to claim 1, it is characterised in that the mica titanium nacreous material choosing With silvery white mica titanium series, particle size is 400-800 mesh.
6. the preparation method of a kind of antiultraviolet pearly-lustre figured cloth described in claim 1, it is characterised in that comprise the following steps:
1) fiber is obtained fabric through spinning, weaving;
2) soak it fabric pretreatment, according to the quality proportioning, be first added to the water starch, sodium alginate and propane diols Stir, sequentially add urea, mica titanium nacreous material and adhesive R-834, stir prepared print paste, carries out Screen printing;
3) by step 2) vapour steaming colour fixing is carried out after the drying of the cloth that obtains;
4) cloth after fixation soaped, washed;
5) according to the quality proportioning, first nano zine oxide, nano titanium oxide and nano silicon are well mixed, then will Itself and aqueous rosin resin emulsion, amino silicone breast stir in sequentially adding water, are warming up to 35 DEG C, add eugenol and KG- 500A waterproofing agents stir, and natural cooling obtains final product padding liquid, by step 4) cloth that obtains impregnated in wherein, an immersing and rolling, Pick-up rate is 80%, in being dried at 140 DEG C -150 DEG C, obtains final product the antiultraviolet pearly-lustre figured cloth.
7. the preparation method of a kind of antiultraviolet pearly-lustre figured cloth according to claim 6, it is characterised in that the step 3) During middle vapour steaming colour fixing, temperature is 100 DEG C -120 DEG C, and the time is 30min.
8. the preparation method of a kind of antiultraviolet pearly-lustre figured cloth according to claim 6, it is characterised in that the step 4) In soap temperature for 95 DEG C, the time is 20min, and washing temperature is 95 DEG C, and the time is 40min.
CN201710048308.7A 2017-01-19 2017-01-19 A kind of antiultraviolet pearly-lustre figured cloth and preparation method thereof Pending CN106758399A (en)

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Application publication date: 20170531