CN102330365A - Anti-ultraviolet pearlescent textile dye liquor - Google Patents
Anti-ultraviolet pearlescent textile dye liquor Download PDFInfo
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- CN102330365A CN102330365A CN201110213112A CN201110213112A CN102330365A CN 102330365 A CN102330365 A CN 102330365A CN 201110213112 A CN201110213112 A CN 201110213112A CN 201110213112 A CN201110213112 A CN 201110213112A CN 102330365 A CN102330365 A CN 102330365A
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Abstract
The invention discloses an anti-ultraviolet pearlescent textile dye liquor, wherein each liter of dye liquor is composed of the following components by grams: 15-60 of pearlescent pigment printing paste, 15-40 of anti-ultraviolet agent, 5-25 of castor oil ethoxylates, 10-35 of undecyl imidazoline, 10-35 of cellulose propionate, 10-20 of polyurethane, 4-30 of acrylpimaric acid and 30-100 of water.
Description
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Technical field
The invention belongs to field of textiles, and be particularly related to a kind of anti-ultraviolet pearly-lustre textiles dye liquor.
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Background technology
COAT PRINTING is exactly to print on the fabric with suitable macromolecular compound and coating; Through handling; On fiber, form have certain elasticity, wear-resisting transparent resin film, with the printing method on the fiber that anchors at of paint machine, this macromolecular compound is in adhesive.Coating claims that also pigment is the chromogen in the print paste, mainly is divided into two big types of organic pigment and inorganic pigments, and the COAT PRINTING of fabric mainly adopts organic pigment, and its heat resistance is good, adapts to high temperature and bakes or decatize, and chromatogram is also comparatively complete.
Coating direct printing painted principle on fiber is different with general dyestuff, and its nationality adhesive anchors at insoluble granules of pigments on the textiles.The environmental protection of COAT PRINTING technology need not washing, and little to the restriction of fabric, technology is simple, and colorant match is convenient, and coloured light is easy to adjustment and control, and the pattern profile of printing is clear, well arranged, be rich in third dimension.Some materials that can distribute similar pearl flicker radiance now also occurring joins in the print paste; Be printed on the fabric; After the oven dry of uniform temperature, PRINTED FABRIC just can send pearlescent gloss under the shining of light, intersperses out jewelly decalcomania.It is good not enough that but the problem that present this type of pigment printing paste exists mainly is exactly COLOR FASTNESS and friction, the soaping fastness of coating behind the stamp
Ultraviolet ray has throughout the year.Should be specifically noted that to prevent ultraviolet injury during to outdoor work summer.According to research, ultraviolet ray mainly shows as the injury to skin to people's harm, and the lighter can make skin burn, shines back skin and seems dry, coarse, is prone to give birth to wrinkle, seems old and feeble, also may bring out cutaneum carcinoma when serious.Though when light is strong, go out or swimming etc., can protect through putting suncream on the skin.Though the sun-proof articles sun-proof result that SPF is high is good, give the burden of skin also many.The bad of use also can cause allergic dermatitis.
It is good not enough that but the problem that present this type of pigment printing paste exists mainly is exactly a adsoptivity on fabric fibre, and light fastness is not enough.
Summary of the invention
The present invention the invention provides a kind of anti-ultraviolet pearly-lustre textiles dye liquor for the adsoptivity on the fabric fibre that overcomes existing coating, defective that light fastness is not enough, and washability improves greatly.
Technical scheme of the present invention is: a kind of anti-ultraviolet pearly-lustre textiles dye liquor, and every liter of contained component of dye liquor consists of in gram:
Pearly coating mill base 15～60,
Preventing ultraviolet agent 15～40
Castor oil polyoxyethylene ether 5～25,
Undecyl imidazole quinoline 10～35,
Cellulose propionate 10～35,
Polyurethanes 10～20,
Rosin acrylic acid 4～30,
Water 30～100.
Contain pearlescent pigment in the described pearly coating mill base, described pearlescent pigment is the natural mica sheet that is coated with metal, metal oxide or its mixture coating.
Thickness≤the 50nm of described natural mica sheet, diameter are that the thickness of 0.25～0.5 micron coating is 20～200nm.
Described metal is arbitrary in gold, copper, aluminium, chromium, titanium, the tungsten.
Described metal oxide is any one in alundum (Al, titanium oxide, di-iron trioxide, iron oxide, chrome green, zinc oxide, germanium oxide, the zirconia.
Described preventing ultraviolet agent is the mixture of the sunscreen actives agent of 4-tert-butyl group dibenzoyl methane and 2-ethylhexyl-Methoxycinnamate is formed according to mol ratio 1:1.
Beneficial effect
1. so make fiber after the dyeing have the good sun-resistant property can well uvioresistant because added anti-ultraviolet agent dye liquor of the present invention.
2. dye liquor of the present invention makes institute's dyeing and weaving thing send soft pearl or metallic luster.
The specific embodiment
Further explain in the face of the present invention down.
A kind of anti-ultraviolet pearly-lustre textiles dye liquor, every liter of contained component of dye liquor consists of in gram:
Pearly coating mill base 15～60,
Preventing ultraviolet agent 15～40
Castor oil polyoxyethylene ether 5～25,
Undecyl imidazole quinoline 10～35,
Cellulose propionate 10～35,
Polyurethanes 10～20,
Rosin acrylic acid 4～30,
Water 30～100.
Described pearly coating mill base wherein contains pearlescent pigment available from the BASF German company, and described pearlescent pigment is the natural mica sheet that is coated with metal, metal oxide or its mixture coating.
Thickness≤the 50nm of described natural mica sheet, diameter are that the thickness of 0.25～0.5 micron coating is 20～200nm.
Described metal is arbitrary in gold, copper, aluminium, chromium, titanium, the tungsten.
Described metal oxide is any one in alundum (Al, titanium oxide, di-iron trioxide, iron oxide, chrome green, zinc oxide, germanium oxide, the zirconia.
Described preventing ultraviolet agent is the mixture of the sunscreen actives agent of 4-tert-butyl group dibenzoyl methane and 2-ethylhexyl-Methoxycinnamate is formed according to mol ratio 1:1.Available from P&G.
Embodiment 1
A kind of anti-ultraviolet pearly-lustre textiles dye liquor, every liter of contained component of dye liquor consists of in gram:
Pearly coating mill base 60,
Preventing ultraviolet agent 40
Castor oil polyoxyethylene ether 25,
Undecyl imidazole quinoline 35,
Cellulose propionate 35,
Polyurethanes 20,
Rosin acrylic acid 30,
Water 100.
Contain pearlescent pigment in the described pearly coating mill base, described pearlescent pigment is the natural mica sheet that is coated with the crome metal coating.Thickness≤the 50nm of described natural mica sheet, diameter are that the thickness of 0.25 micron coating is 200nm.
Described preventing ultraviolet agent is the mixture of the sunscreen actives agent of 4-tert-butyl group dibenzoyl methane and 2-ethylhexyl-Methoxycinnamate is formed according to mol ratio 1:1.
Embodiment 2
A kind of anti-ultraviolet pearly-lustre textiles dye liquor, every liter of contained component of dye liquor consists of in gram:
Pearly coating mill base 15,
Preventing ultraviolet agent 15
Castor oil polyoxyethylene ether 5,
Undecyl imidazole quinoline 10,
Cellulose propionate 10,
Polyurethanes 10,
Rosin acrylic acid 4,
Water 60.
Contain pearlescent pigment in the described pearly coating mill base, described pearlescent pigment is the natural mica sheet that is coated with zirconia coating.Thickness≤the 50nm of described natural mica sheet, diameter are that the thickness of 0.25～0.5 micron coating is 20～200nm.
Described preventing ultraviolet agent is the mixture of the sunscreen actives agent of 4-tert-butyl group dibenzoyl methane and 2-ethylhexyl-Methoxycinnamate is formed according to mol ratio 1:1.
Embodiment 3
A kind of anti-ultraviolet pearly-lustre textiles dye liquor, every liter of contained component of dye liquor consists of in gram:
Pearly coating mill base 30,
Preventing ultraviolet agent 25
Castor oil polyoxyethylene ether 15,
Undecyl imidazole quinoline 15,
Cellulose propionate 15,
Polyurethanes 12,
Rosin acrylic acid 15,
Water 50.
Contain pearlescent pigment in the described pearly coating mill base, described pearlescent pigment is the natural mica sheet that is coated with tungsten, germanium oxide, zirconia blend coating.
Thickness≤the 50nm of described natural mica sheet, diameter are that the thickness of 0.25～0.5 micron coating is 20～200nm.
Described metal be gold, copper, aluminium, chromium, titanium, in arbitrary.
Described metal oxide be alundum (Al, titanium oxide, di-iron trioxide, iron oxide, chrome green, zinc oxide, in any one.
Described preventing ultraviolet agent is the mixture of the sunscreen actives agent of 4-tert-butyl group dibenzoyl methane and 2-ethylhexyl-Methoxycinnamate is formed according to mol ratio 1:1.
Embodiment 4
Dye liquor effect to embodiment 1 ~ 3 is tested, and adopts to pad dye liquor, and one soaks one rolls, 60%, 80 ℃ of oven dry of pick-up 2min, and 110 ℃ of gas steam 10min.
1. fast light test: shine 20h with carbon arc lamp after the heat treatment, wherein the fastness rate rank is 0-8;
2. heat resistant test: 180 ℃ of hot-air seasoning 30s, heat-resisting rank is 0-5;
3. solvent-resistance test: add tetrachloro-ethylene after the heat treatment, with 40 ℃ of emerge in worm water 30min, anti-solvent rank is 0-5,
4. the anti-test of soaping: add ground caustic after the heat treatment, in 70 ℃ of warm water, wash 45min, the anti-rank of soaping is 0-5;
Table 1 The performance test results
| ? | Fast light test | Heat resistant test | Solvent-resistance test | The anti-test of soaping |
| Embodiment 1 | 8 | 5 | 5 | 5 |
| Embodiment 2 | 7 | 4 | 4 | 4 |
| Embodiment 3 | 6 | 3 | 3 | 3 |
Table 2 antiultraviolet test result
| Embodiment | Daylight ultraviolet ray (UVA) transmittance % | Daylight ultraviolet ray (UVB) transmittance % | UPF .UPF | UPF mean value |
| 1 | 0.335 | 0.123 | 55 | 55 |
| 2 | 0.413 | 0.202 | 52 | 52 |
| 3 | 0.315 | 0.112 | 53 | 53 |
Annotate: as the UPF of product>30, and (UVA) transmittance 5% o'clock, can be described as " antiultraviolet product ".
Claims (6)
1. anti-ultraviolet pearly-lustre textiles dye liquor is characterized in that every liter of contained component of dye liquor consists of in gram:
Pearly coating mill base 15～60,
Preventing ultraviolet agent 15～40
Castor oil polyoxyethylene ether 5～25,
Undecyl imidazole quinoline 10～35,
Cellulose propionate 10～35,
Polyurethanes 10～20,
Rosin acrylic acid 4～30,
Water 30～100.
2. anti-ultraviolet pearly-lustre textiles dye liquor as claimed in claim 1 is characterized in that contain pearlescent pigment in the described pearly coating mill base, described pearlescent pigment is the natural mica sheet that is coated with metal, metal oxide or its mixture coating.
3. anti-ultraviolet pearly-lustre textiles dye liquor as claimed in claim 1 is characterized in that the thickness≤50nm of described natural mica sheet, diameter are that the thickness of 0.25～0.5 micron coating is 20～200nm.
4. anti-ultraviolet pearly-lustre textiles dye liquor as claimed in claim 2 is characterized in that, described metal is arbitrary in gold, copper, aluminium, chromium, titanium, the tungsten.
5. anti-ultraviolet pearly-lustre textiles dye liquor as claimed in claim 2 is characterized in that described metal oxide is any one in alundum (Al, titanium oxide, di-iron trioxide, iron oxide, chrome green, zinc oxide, germanium oxide, the zirconia.
6. as claimed in claim 1, it is characterized in that described preventing ultraviolet agent is the mixture of the sunscreen actives agent of 4-tert-butyl group dibenzoyl methane and 2-ethylhexyl-Methoxycinnamate is formed according to mol ratio 1:1.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201110213112A CN102330365A (en) | 2011-07-28 | 2011-07-28 | Anti-ultraviolet pearlescent textile dye liquor |
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| CN201110213112A CN102330365A (en) | 2011-07-28 | 2011-07-28 | Anti-ultraviolet pearlescent textile dye liquor |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106758399A (en) * | 2017-01-19 | 2017-05-31 | 许连习 | A kind of antiultraviolet pearly-lustre figured cloth and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101109129A (en) * | 2007-08-27 | 2008-01-23 | 洪桂焕 | Moisture permeable anti-ultraviolet multifunctional antibiotic facing material and process technique thereof |
| CN101307573A (en) * | 2008-07-01 | 2008-11-19 | 杭州万事利丝绸科技有限公司 | Ultraviolet ray color-changing printing fabric preparation method |
| CN101824761A (en) * | 2010-03-29 | 2010-09-08 | 河南工程学院 | Dyeing method |
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- 2011-07-28 CN CN201110213112A patent/CN102330365A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101109129A (en) * | 2007-08-27 | 2008-01-23 | 洪桂焕 | Moisture permeable anti-ultraviolet multifunctional antibiotic facing material and process technique thereof |
| CN101307573A (en) * | 2008-07-01 | 2008-11-19 | 杭州万事利丝绸科技有限公司 | Ultraviolet ray color-changing printing fabric preparation method |
| CN101824761A (en) * | 2010-03-29 | 2010-09-08 | 河南工程学院 | Dyeing method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106758399A (en) * | 2017-01-19 | 2017-05-31 | 许连习 | A kind of antiultraviolet pearly-lustre figured cloth and preparation method thereof |
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