CN102330360A - Ultraviolet-resistant luminescence textile fabric dye liquor - Google Patents
Ultraviolet-resistant luminescence textile fabric dye liquor Download PDFInfo
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- CN102330360A CN102330360A CN201110213758A CN201110213758A CN102330360A CN 102330360 A CN102330360 A CN 102330360A CN 201110213758 A CN201110213758 A CN 201110213758A CN 201110213758 A CN201110213758 A CN 201110213758A CN 102330360 A CN102330360 A CN 102330360A
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Abstract
The invention discloses an ultraviolet-resistant luminescence textile fabric dye solution. Each liter of dye solution is prepared from the following components by gram: 15-60 grams of luminescence pigment printing paste, 15-40 grams of anti-ultraviolet light agent, 5-25 grams of caster oil polyoxyethylene ether, 10-35 grams of undecyl imidazoline, 10-35 grams of hydroxymethyl cellulose, 10-20 grams of polyurethane, 4-30 grams of maleopimaricacid, and 10-100 grams of water.
Description
Technical field
The invention belongs to field of textiles, and be particularly related to a kind of anti-Ultraluminescence textiles dye liquor.
Background technology
Occur the dyestuff that some can send fluorescence now, be commonly called as fluorescent dye.After absorbing visible light and ultraviolet light, can change ultraviolet light the visible light wave that wavelength grows into and reflect out, be glittering bright-coloured color.For example, tetrabromofluorescein, fluorescein, merbromin and some DISPERSE DYES etc.They are the compound that contains phenyl ring or heterocycle and have conjugated double bond mostly.Fluorescent dye is used for fluorescent dye product, leakage detection easily! The various fluorescence traffic paints that the brightening agent that is used for brightened goods washing detergent, index signal are used, fluorized marking clothes etc.Fluorescent dye is used for: the pollutant connected system of leachate system water and industry is measured the illegal sewage pipe that is connected of seepage of the liquid toilet of discharging in the power plant and is supervised; The research flow is analyzed corrupt system with drawing; Except that being used for the fabric printing and dyeing, also can be used as some extraordinary sign (like the dark place symbol) and military tracking etc.The visual effect of fluorescent dye had both comprised to be selected to absorb the color that the back produces to visible light, comprises the fluorescence that they itself emit again.Fluorescent dye belongs to a kind of functional dyestuff, has both had the painted characteristic of conventional dyestuff, can send fluorescence again, makes the saturation degree of fabric and vividness improve.The fluorescent dye kind that is used for textiles the earliest is Luo Danhong and derivative thereof, can be applied in the dyeing of textile fabrics such as silk, terylene, polyamide fibre, obtains gorgeous fabric.
Ultraviolet ray has throughout the year.Should be specifically noted that to prevent ultraviolet injury during to outdoor work summer.According to research, ultraviolet ray mainly shows as the injury to skin to people's harm, and the lighter can make skin burn, shines back skin and seems dry, coarse, is prone to give birth to wrinkle, seems old and feeble, also may bring out cutaneum carcinoma when serious.Though when light is strong, go out or swimming etc., can protect through putting suncream on the skin.Though the sun-proof articles sun-proof result that SPF is high is good, give the burden of skin also many.The bad of use also can cause allergic dermatitis.
It is good not enough that but the problem that present this type of pigment printing paste exists mainly is exactly a adsoptivity on fabric fibre, and light fastness is not enough.
Summary of the invention
The present invention the invention provides a kind of anti-Ultraluminescence textiles dye liquor for the adsoptivity on the fabric fibre that overcomes existing coating, defective that light fastness is not enough, and washability improves greatly.
Technical scheme of the present invention is: a kind of anti-Ultraluminescence textiles dye liquor, and every liter of contained component of dye liquor consists of in gram:
Fluorescent paint mill base 15～60,
Preventing ultraviolet agent 15～40
Castor oil polyoxyethylene ether 5～25,
Undecyl imidazole quinoline 10～35,
CMC 10～35,
Polyurethanes 10～20,
Maleopimaric acid 4～30,
Water 30～100.
Containing structural formula in the described fluorescent paint mill base does
The compound of
.
Also be added with L-tartaric acid 4～10 grams in every liter of dye liquor.
Described preventing ultraviolet agent is the mixture of the methane sunscreen actives agent of 2-methyldiphenyl formoxyl and 2-ethylhexyl-Methoxycinnamate is formed according to mol ratio 1:1.
Beneficial effect
1. so make fiber after the dyeing have the good sun-resistant property can well uvioresistant because added anti-ultraviolet agent dye liquor of the present invention.
2. dye liquor of the present invention makes the coordinate of institute's dyeing and weaving thing belong to fluorescence orange-red coloration zone.
The specific embodiment
Further explain in the face of the present invention down.
A kind of anti-Ultraluminescence textiles dye liquor, every liter of contained component of dye liquor consists of in gram:
Fluorescent paint mill base 15～60,
Preventing ultraviolet agent 15～40
Castor oil polyoxyethylene ether 5～25,
Undecyl imidazole quinoline 10～35,
CMC 10～35,
Polyurethanes 10～20,
Maleopimaric acid 4～30,
Water 30～100.
Containing structural formula in the described fluorescent paint mill base does
The compound of
.
Also be added with L-tartaric acid 4～10 grams in every liter of dye liquor.
Described preventing ultraviolet agent is the mixture of the methane sunscreen actives agent of 2-methyldiphenyl formoxyl and 2-ethylhexyl-Methoxycinnamate is formed according to mol ratio 1:1.Available from P&G.
Embodiment 1
A kind of anti-Ultraluminescence textiles dye liquor, every liter of contained component of dye liquor consists of in gram:
Fluorescent paint mill base 15,
Preventing ultraviolet agent 15
Castor oil polyoxyethylene ether 5,
Undecyl imidazole quinoline 10,
CMC 10,
Polyurethanes 10,
Maleopimaric acid 40,
Water 50.
Containing structural formula in the described fluorescent paint mill base does
The compound of
.
Described preventing ultraviolet agent is the mixture of the methane sunscreen actives agent of 2-methyldiphenyl formoxyl and 2-ethylhexyl-Methoxycinnamate is formed according to mol ratio 1:1.
Embodiment 2
A kind of anti-Ultraluminescence textiles dye liquor, every liter of contained component of dye liquor consists of in gram:
Fluorescent paint mill base 15,
Preventing ultraviolet agent 15
Castor oil polyoxyethylene ether 5,
Undecyl imidazole quinoline 10,
CMC 10,
Polyurethanes 10,
Maleopimaric acid 4,
Water 30.
Containing structural formula in the described fluorescent paint mill base does
The compound of
.
Also be added with L-tartaric acid 4 grams in every liter of dye liquor.
Described preventing ultraviolet agent is the mixture of the methane sunscreen actives agent of 2-methyldiphenyl formoxyl and 2-ethylhexyl-Methoxycinnamate is formed according to mol ratio 1:1.
Embodiment 3
A kind of anti-Ultraluminescence textiles dye liquor, every liter of contained component of dye liquor consists of in gram:
Fluorescent paint mill base 30,
Preventing ultraviolet agent 20
Castor oil polyoxyethylene ether 15,
Undecyl imidazole quinoline 15,
CMC 15,
Polyurethanes 12,
Maleopimaric acid 20,
Water 60.
Containing structural formula in the described fluorescent paint mill base does
The compound of
.
Also be added with L-tartaric acid 8 grams in every liter of dye liquor.
Described preventing ultraviolet agent is the mixture of the methane sunscreen actives agent of 2-methyldiphenyl formoxyl and 2-ethylhexyl-Methoxycinnamate is formed according to mol ratio 1:1.
Embodiment 4
Dye liquor institute dyeing and weaving fibres to embodiment 1 ~ 3 carries out thermodynamic analysis, levies the good accords with Langmuir type absorption of the absorption of bright dyestuff on fabric fibre, and the reflectivity of DYED FABRICS in 550nm～750nm zone surpasses 100%.According to visual warning clothing EN 471 European standards of height (2003), when dye bath concentration was 0.2～2.5%owf, the chromaticity coordinate of institute's dyeing and weaving thing belonged to fluorescence orange-red coloration zone.Light fastness tests 16 in Atlas XenoTest Alpha light fastness test aircraft measurements according to U.S. AATCC standard 2003 editions; Compare with blue wool standard specimen; Use the gray scale opinion rating again, show that the light fastness of the fabric that uses this dye liquor all reaches more than 3 grades.
Table 1 antiultraviolet test result
| Embodiment | Daylight ultraviolet ray (UVA) transmittance % | Daylight ultraviolet ray (UVB) transmittance % | UPF .UPF | UPF mean value |
| 1 | 0.435 | 0.223 | 52 | 52 |
| 2 | 0.313 | 0.102 | 55 | 55 |
| 3 | 0.315 | 0.112 | 53 | 53 |
Annotate: as the UPF of product>30, and (UVA) transmittance 5% o'clock, can be described as " antiultraviolet product ".
Claims (4)
1. an anti-Ultraluminescence textiles dye liquor is characterized in that, every liter of contained component of dye liquor consists of in gram:
Fluorescent paint mill base 15～60,
Preventing ultraviolet agent 15～40
Castor oil polyoxyethylene ether 5～25,
Undecyl imidazole quinoline 10～35,
CMC 10～35,
Polyurethanes 10～20,
Maleopimaric acid 4～30,
Water 30～100.
2. anti-Ultraluminescence textiles dye liquor as claimed in claim 1 is characterized in that, contains structural formula in the described fluorescent paint mill base and does
The compound of
.
3. anti-Ultraluminescence textiles dye liquor as claimed in claim 1 is characterized in that, also is added with L-tartaric acid 4～10 grams in every liter of dye liquor.
4. anti-Ultraluminescence textiles dye liquor as claimed in claim 1 is characterized in that, described preventing ultraviolet agent is the mixture of the methane sunscreen actives agent of 2-methyldiphenyl formoxyl and 2-ethylhexyl-Methoxycinnamate is formed according to mol ratio 1:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110213758A CN102330360A (en) | 2011-07-28 | 2011-07-28 | Ultraviolet-resistant luminescence textile fabric dye liquor |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110213758A CN102330360A (en) | 2011-07-28 | 2011-07-28 | Ultraviolet-resistant luminescence textile fabric dye liquor |
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| CN102330360A true CN102330360A (en) | 2012-01-25 |
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| CN201110213758A Pending CN102330360A (en) | 2011-07-28 | 2011-07-28 | Ultraviolet-resistant luminescence textile fabric dye liquor |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103334303A (en) * | 2013-04-16 | 2013-10-02 | 淳安县千岛湖桑园丝绸有限公司 | Anti-shrinkage silk cotton fiber fabric finishing method |
| CN104343022A (en) * | 2014-11-05 | 2015-02-11 | 北京泛博化学股份有限公司 | Fluorescent dye and preparation method and application thereof |
| CN105860576A (en) * | 2016-04-26 | 2016-08-17 | 浙江珊瑚化工有限公司 | Anti-ultraviolet fluorescent whitening agent emulsion |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101109129A (en) * | 2007-08-27 | 2008-01-23 | 洪桂焕 | Moisture-permeable anti-ultraviolet multifunctional antibacterial fabric and processing technology thereof |
| CN101307573A (en) * | 2008-07-01 | 2008-11-19 | 杭州万事利丝绸科技有限公司 | Ultraviolet ray color-changing printing fabric preparation method |
| CN101824761A (en) * | 2010-03-29 | 2010-09-08 | 河南工程学院 | Dyeing method |
-
2011
- 2011-07-28 CN CN201110213758A patent/CN102330360A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101109129A (en) * | 2007-08-27 | 2008-01-23 | 洪桂焕 | Moisture-permeable anti-ultraviolet multifunctional antibacterial fabric and processing technology thereof |
| CN101307573A (en) * | 2008-07-01 | 2008-11-19 | 杭州万事利丝绸科技有限公司 | Ultraviolet ray color-changing printing fabric preparation method |
| CN101824761A (en) * | 2010-03-29 | 2010-09-08 | 河南工程学院 | Dyeing method |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103334303A (en) * | 2013-04-16 | 2013-10-02 | 淳安县千岛湖桑园丝绸有限公司 | Anti-shrinkage silk cotton fiber fabric finishing method |
| CN104343022A (en) * | 2014-11-05 | 2015-02-11 | 北京泛博化学股份有限公司 | Fluorescent dye and preparation method and application thereof |
| CN104343022B (en) * | 2014-11-05 | 2016-08-17 | 北京泛博化学股份有限公司 | Fluorescent dye and its preparation method and application |
| CN105860576A (en) * | 2016-04-26 | 2016-08-17 | 浙江珊瑚化工有限公司 | Anti-ultraviolet fluorescent whitening agent emulsion |
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Effective date of abandoning: 20120125 |
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