CN101307573A - Ultraviolet ray color-changing printing fabric preparation method - Google Patents

Ultraviolet ray color-changing printing fabric preparation method Download PDF

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Publication number
CN101307573A
CN101307573A CNA2008100627436A CN200810062743A CN101307573A CN 101307573 A CN101307573 A CN 101307573A CN A2008100627436 A CNA2008100627436 A CN A2008100627436A CN 200810062743 A CN200810062743 A CN 200810062743A CN 101307573 A CN101307573 A CN 101307573A
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Prior art keywords
fabric
percent
changing
color
ultraviolet color
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CNA2008100627436A
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CN101307573B (en
Inventor
余志成
马廷方
孙国君
王莲美
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HANGZHOU WANSLI SILK DIGITAL PRINTING Co.,Ltd.
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WANSHILI SILK SCIENCE-TECHNOLOGY Co Ltd HANGZHOU
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Publication of CN101307573A publication Critical patent/CN101307573A/en
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Abstract

The invention discloses a method for preparing ultraviolet color-changing printed fabrics. The prescription by weight percentage of fabric printing color paste is: X percent of ultraviolet color-changing dye, 60 percent of natural modified paste material with the lid containing rate of 10 percent, 0.5 percent of glacial acetic acid, 3 percent of urea, and the balance being water, wherein the mixture ratio of X percent of the ultraviolet color-changing dye in percentage by weight is: 0.2 percent of cationic violet 5BLH, 0.4-0.9 percent of cationic yellow X-10GFF, and 0.1-0.2 percent of cationic red X-5GN. A fabric printing process comprises the following procedures of taking a fabric, printing the fabric, steaming the fabric, washing the fabric, drying the fabric and obtaining a finished product. The parameters of a steaming process are as follows: the temperature of heating with superheated steam is 125 DEG C, and the heating time is 30 min. The method overcomes the problems of hand feeling, free formaldehyde, etc. caused by applying adhesive to prepare ultraviolet color-changing printed fabrics in the prior art, has simple-convenient process and low cost, does not change the prior style of fibers, and is excellent in wet fastness and rubbing fastness. Tests show that: the fabric is environmentally friendly and safe, does not contain 23 carcinogenic aromatic amines or heavy metal ions harmful to human body, and is broad in market prospects.

Description

A kind of preparing ultraviolet color-changing printed fabrics
Technical field
The present invention relates to the textile dyeing and finishing technical field, especially relate to a kind of preparing ultraviolet color-changing printed fabrics.
Technical background
Along with the continual renovation of the improving constantly of living standard, consumption idea, people are maked rapid progress to the pursuit of dress ornament, not only consider its material and functional, but also pay attention to the appearance style of product especially.Novel, unique product is very popular.
The pattern flower shape of variable color textiles presents different color and lusters with light, environment difference, has broken static, the stiff general layout of traditional decalcomania flower shape, and pattern is true to nature, has innervation, matches as polychrome, and is then with countless changes.It wins people's favor with brand-new fabric style.Superior to clothes these people, the personalized requirement strengthens day by day and the functional treatment fabric required to improve constantly the epoch, and allochroic clothes or ornaments etc. can satisfy the rat-fuck demand of a lot of people.Also can be applicable to the textiles anti-counterfeiting technology.
At present, the research report of existing ultraviolet color-changing powder or color shifting ink or coating, but some is not suitable for textiles processing, and some promptly enables to be applied to textiles, also there is the use adhesive and causes problems such as feel, free formaldehyde, do not meet the ecological requirement of textiles.
CN1283658 discloses a kind of antiforge ink able to change colour under ultrayviolet ray radiation, have under ultraviolet light or ordinary light, can observe marker color change to confirm the true and false, disguised extremely strong, detect advantage simply accurately, but be not suitable for textiles processing.CN200956838 discloses a kind of ultraviolet color-changing button and ornaments, and when irradiation ultraviolet ray can automatic color-changing, can remind the user, and the uitraviolet intensity of harmful human body is higher hastens to make suitable safeguard measure, also is not suitable for textiles processing.CN1590637 discloses a kind of color-changing printing fabric, and photochromic pigment, thermosensitive pigment may, wet quick pigment are printed on the towel by the COAT PRINTING method, obtains photosensitive, temperature-sensitive, wet sensitive colour changing effect.But there is the use adhesive and causes problems such as feel, free formaldehyde, COLOR FASTNESS.
Summary of the invention
The object of the present invention is to provide a kind of preparing ultraviolet color-changing printed fabrics.
The technical solution used in the present invention is as follows:
1) print paste prescription:
Ultraviolet color-changing dyestuff X%, solid content 10% natural modified thickener 60%, glacial acetic acid 0.5%, urea 3%, all the other are water; Below all be weight percentage.
Wherein the proportioning of ultraviolet color-changing dyestuff X% is:
Cationic violet 5BLH 0.2%, cationic yellow X-10GFF 0.4~0.9%, cationic red X-5GN 0.1~0.2%.
2) printing technology flow process: fabric → stamp → evaporate → wash → dry → finished product;
Evaporate technological parameter: superheated steam heating 125 ℃, time 30min.
Described solid content 10% natural modified thickener is a kind of natural plants seed glue PA-40.
Specify: the independent stamp of above-mentioned three dyestuffs there is no the ultraviolet color-changing effect, has only and just has the ultraviolet color-changing effect under the said ratio.
The beneficial effect that the present invention has is:
1) the invention provides a kind of specific combination prescription of using the common cation dyestuff obtains the ultraviolet color-changing effect on the cationic-dyeable dacron printing method, overcome that present ultraviolet color-changing textile is used adhesive and problems such as the feel problem that produces, free formaldehyde;
2) ultraviolet ray color-changing printing fabric technology is simple, convenient, with low cost, does not change the original style of fiber, and wet fastness, friction fastness are good.
3) fabric after tested, Environmental Safety does not contain 23 kinds of carcinogenic aromatic amines and harmful heavy metal ion, market prospects are wide.
The specific embodiment
Embodiment 1:
Cationic-dyeable terylene (CDP) fabric technology stamp routinely, technological process is as follows:
Fabric → stamp → evaporate → wash → dry → finished product
Printing technology prescription: cationic violet 5BLH0.2%, yellow X-10GFF 0.4%, red X-5GN 0.1%, solid content 10% natural modified thickener 60%, acetic acid 0.5%, urea 3%, all the other are water; By above-mentioned prescription modulation mill base, stamp on continuous automatic printing machine evaporates technological parameter: superheated steam heating 125 ℃, time 30min then.Carry out the open width washing after evaporating, oven dry.Natural modified thickener is a kind of natural plants seed glue PA-40.
Printed fabric is light green color at the D65 light source, is light yellow under the UV light source, and 3 grades of washing fastness, friction fastness reach 3 grades.
Embodiment 2:
Cationic-dyeable terylene (CDP) fabric technology stamp routinely, technological process is as follows:
Fabric → stamp → evaporate → wash → dry → finished product
Printing technology prescription: cationic violet 5BLH0.2%, yellow X-10GFF 0.9%, red X-5GN 0.2%, solid content 10% natural modified thickener 60%, acetic acid 0.5%, urea 3%, all the other are water; By above-mentioned prescription modulation mill base, stamp on continuous automatic printing machine evaporates technological parameter: superheated steam heating 125 ℃, time 30min then.Carry out the open width washing after evaporating, oven dry.Natural modified thickener is a kind of natural plants seed glue PA-40.
It is yellow that PRINTED FABRIC D65 light source is, and is fluorescence green under the UV light source, and 3 grades of washing fastness, friction fastness reach 3 grades.

Claims (2)

1, a kind of preparing ultraviolet color-changing printed fabrics is characterized in that the step of this method is as follows:
1) print paste prescription:
Ultraviolet color-changing dyestuff X%, solid content 10% natural modified thickener 60%, glacial acetic acid 0.5%, urea 3%, all the other are water; Below all be weight percentage.
Wherein the proportioning of ultraviolet color-changing dyestuff X% is:
Cationic violet 5BLH 0.2%, cationic yellow X-10GFF 0.4~0.9%, cationic red X-5GN 0.1~0.2%;
2) printing technology flow process: fabric → stamp → evaporate → wash → dry → finished product;
Evaporate technological parameter: superheated steam heating 125 ℃, time 30min.
2, the preparation method of a kind of ultraviolet color-changing stamp according to claim 1 is characterized in that: described solid content 10% natural modified thickener is a kind of natural plants seed glue PA-40.
CN2008100627436A 2008-07-01 2008-07-01 Ultraviolet ray color-changing printing fabric preparation method Active CN101307573B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2008100627436A CN101307573B (en) 2008-07-01 2008-07-01 Ultraviolet ray color-changing printing fabric preparation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2008100627436A CN101307573B (en) 2008-07-01 2008-07-01 Ultraviolet ray color-changing printing fabric preparation method

Publications (2)

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CN101307573A true CN101307573A (en) 2008-11-19
CN101307573B CN101307573B (en) 2010-12-15

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102002866A (en) * 2010-11-02 2011-04-06 华纺股份有限公司 Photochromic printing process of real wax clothing material
CN102115984A (en) * 2010-12-30 2011-07-06 东华大学 Method for printing copolyester paster fiber fabric
CN102330360A (en) * 2011-07-28 2012-01-25 吴江征明纺织有限公司 Ultraviolet-resistant luminescence textile fabric dye liquor
CN102330365A (en) * 2011-07-28 2012-01-25 吴江征明纺织有限公司 Anti-ultraviolet pearlescent textile dye liquor
CN102433769A (en) * 2011-11-21 2012-05-02 苏州贵族公子服饰有限公司 Novel clothing dye
CN102505456A (en) * 2011-11-01 2012-06-20 常熟新诚鑫织造有限公司 Photochromic fabric and production method thereof
CN102888751A (en) * 2012-06-11 2013-01-23 浙江理工大学 Method for preparing ferrous ion inducted color-changing fabric and method for using fabric
CN106351027A (en) * 2016-08-25 2017-01-25 宁波大千纺织品有限公司 Light-storing allochroic knitted printed fabric and preparation method thereof
CN109054440A (en) * 2018-07-19 2018-12-21 苏州大上科高新材料有限公司 It is a kind of to use up the preparation method for becoming dyestuff capsule based on photosensitive colour-changing stamp
CN113005794A (en) * 2021-03-24 2021-06-22 浙江丝绸科技有限公司 Multi-color real silk or real silk-containing fabric capable of displaying ultraviolet intensity and manufacturing process thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85102447A (en) * 1985-07-01 1986-12-31 黑龙江省嫩江县毛纺织厂 Polyacryloninitrile thread and colouring method thereof
CN1590637A (en) * 2003-09-02 2005-03-09 淄博环峰纺织品有限公司 Colour changing printed fabric
CN1314855C (en) * 2005-03-21 2007-05-09 浙江理工大学 Printing discharge dyeing paste for coating material to discharge dye silk broadcloth, and discharge printing technique of extracting activity of coating material
CN100523368C (en) * 2007-09-27 2009-08-05 黄欢 Method for producing variable color garment

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102002866A (en) * 2010-11-02 2011-04-06 华纺股份有限公司 Photochromic printing process of real wax clothing material
CN102002866B (en) * 2010-11-02 2012-11-14 华纺股份有限公司 Photochromic printing process of real wax clothing material
CN102115984A (en) * 2010-12-30 2011-07-06 东华大学 Method for printing copolyester paster fiber fabric
CN102330365A (en) * 2011-07-28 2012-01-25 吴江征明纺织有限公司 Anti-ultraviolet pearlescent textile dye liquor
CN102330360A (en) * 2011-07-28 2012-01-25 吴江征明纺织有限公司 Ultraviolet-resistant luminescence textile fabric dye liquor
CN102505456A (en) * 2011-11-01 2012-06-20 常熟新诚鑫织造有限公司 Photochromic fabric and production method thereof
CN102433769A (en) * 2011-11-21 2012-05-02 苏州贵族公子服饰有限公司 Novel clothing dye
CN102888751A (en) * 2012-06-11 2013-01-23 浙江理工大学 Method for preparing ferrous ion inducted color-changing fabric and method for using fabric
CN102888751B (en) * 2012-06-11 2015-03-25 浙江理工大学 Method for preparing ferrous ion inducted color-changing fabric and method for using fabric
CN106351027A (en) * 2016-08-25 2017-01-25 宁波大千纺织品有限公司 Light-storing allochroic knitted printed fabric and preparation method thereof
CN106351027B (en) * 2016-08-25 2018-11-27 宁波大千纺织品有限公司 A kind of light storage discoloration knitted printed fabric and preparation method thereof
CN109054440A (en) * 2018-07-19 2018-12-21 苏州大上科高新材料有限公司 It is a kind of to use up the preparation method for becoming dyestuff capsule based on photosensitive colour-changing stamp
CN113005794A (en) * 2021-03-24 2021-06-22 浙江丝绸科技有限公司 Multi-color real silk or real silk-containing fabric capable of displaying ultraviolet intensity and manufacturing process thereof

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Effective date of registration: 20211103

Address after: 310000 No. 2, Xingfu South Road, Xiasha street, Hangzhou Economic and Technological Development Zone, Zhejiang Province

Patentee after: HANGZHOU WANSLI SILK DIGITAL PRINTING Co.,Ltd.

Address before: 310021 No. 309 Airport Road, Hangzhou, Zhejiang, Jianggan District

Patentee before: Hangzhou Wensli Silk Sciences and Technology Co.,Ltd.

TR01 Transfer of patent right