CN109044886A - A kind of micro-nano cleaning whitening mask mud - Google Patents
A kind of micro-nano cleaning whitening mask mud Download PDFInfo
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- CN109044886A CN109044886A CN201811013373.7A CN201811013373A CN109044886A CN 109044886 A CN109044886 A CN 109044886A CN 201811013373 A CN201811013373 A CN 201811013373A CN 109044886 A CN109044886 A CN 109044886A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
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- A—HUMAN NECESSITIES
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- A61K8/00—Cosmetics or similar toiletry preparations
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- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/90—Block copolymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
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Abstract
The invention discloses a kind of micro-nano cleaning whitening mask mud, belong to household chemicals technical field.The micro-nano cleaning whitening mask mud that the present invention develops includes: micro-nano sepiolite, plants essential oil, block copolymer, N'- cetyl-N, N- dimethyl ethyl amidine, dopamine, microcrystalline cellulose, anionic polyacrylamide, iron chloride, defoaming agent, preservative, antioxidant and water；Wherein micro-nano sepiolite is by obtaining after sepiolite and sulfuric acid hydro-thermal reaction；And block copolymer is then to react to obtain with polyethylene glycol phosphate by (N- amidino groups) dodecylacrylamide；Before filling the container, raw material is mixed under the conditions of inert gas shielding, vacuum defoamation is to get micro-nano cleaning whitening mask mud.The micro-nano cleaning whitening mask mud of gained of the invention has excellent cleaning effect.
Description
Technical field
The invention discloses a kind of micro-nano cleaning whitening mask mud, belong to household chemicals technical field.
Background technique
With the improvement of living standards, more and more people can be accustomed to making up, but after face makeup, if do not removed thorough
Bottom, remaining cosmetics can cause the pore of skin of face to block, and lead to skin oil and fat water oil dyssecretosis, so as to cause Cuo
Sore, acne and blackhead etc. make us the skin problem of puzzlement.Meanwhile present environmental pollution is again extremely serious, dust and cosmetics
It remains there is a great harm for skin, if cannot clean out in time, capsule can be formed with the breathing of pore, into hair follicle
Swollen problem, long-term existence are just difficult to clear up away again in skin surface, so, the cleaning link of skin is particularly significant.It is existing
There are the following problems for the face cleaning facial mask for having in technology: makeup removing step is more, not easy to use, smears uneven, and cleaning effect is poor.
Nowadays, the pursuit with the raising of people's quality of the life and to beauty, more and more persons select to be maintained using facial mask
Skin.Deep clean facial mask is a kind of carrier of face beautifying health keeping product, can remove blackhead, and pore refining has deep clean skin
And other effects, it is favored by people.Deep clean facial mask on the market is mostly sticking type facial mask now.Sticking type facial mask is
Use non-woven fabrics etc. as matrix, infiltrates Essence etc. and spread on skin.Main problem existing for this mode is due to individual
Difference, facial mask can not be bonded completely with skin.Daubing-type facial mask solves the problems, such as this.In use, cream pack is uniformly applied
It smears on skin, finishes, can be torn in flakes to Essence absorption.The painting type deep clean facial mask beautiful jade of all kinds of brands on the market
Thinkling sound meets the eye on every side.In order to win the market, manufacturers, which try one's best, makes miscellaneous product.They are formulated health environment-friendly, packaging
It is beautiful and generous.In contrast, the visual effect for the content that consumer more takes notice of itself, which but has no characteristic, to be sayed.It is traditional at present
The cleaning pack problem bad there is also cleaning effect, therefore also need to study it.
Summary of the invention
The present invention solves the technical problem of: for the bad problem of traditional cleaning pack cleaning effect, provide
A kind of micro-nano cleaning whitening mask mud.
In order to solve the above-mentioned technical problem, the technical scheme adopted by the invention is that:
A kind of micro-nano cleaning whitening mask mud, the raw material including following parts by weight:
20~30 parts of micro-nano sepiolite
8~10 parts of plants essential oil
8~10 parts of block copolymer
4~6 parts of amidine of N'- cetyl-N, N- dimethyl ethyl
8~10 parts of dopamine
10~15 parts of microcrystalline cellulose
8~10 parts of anionic polyacrylamide
0.1~0.3 part of iron chloride
3~5 parts of defoaming agent
1~3 part of antioxidant
40~60 parts of water
The process for preparation of the micro-nano cleaning whitening mask mud are as follows:
(1) each component is weighed by raw material composition；
(2) by micro-nano sepiolite, plants essential oil, block copolymer, N'- cetyl-N, N- dimethyl ethyl amidine, DOPA
Amine, microcrystalline cellulose, anionic polyacrylamide, iron chloride, defoaming agent, preservative, antioxidant sequentially add in water, in inertia
Under gas protection status, after being stirred 2~4h, vacuum defoamation is filling to get micro-nano cleaning whitening mask mud.
The micro-nano sepiolite preparation process are as follows: by sepiolite and sulfuric acid be in mass ratio 1:3~1:5 mix after, water
2~4h of thermal response, then separated, dry and washing obtains micro-nano sepiolite.
The plants essential oil is any one in Lavender, Rosa Damascana or camellia flower essential oil.
The block copolymer preparation process are as follows: press (N- amidino groups) dodecylacrylamide with polyethylene glycol phosphate
Mass ratio 8:1~10:1 mixing, and the paracide and polyethylene glycol phosphorus of 0.1~0.2 times of polyethylene glycol phosphate quality is added
The ferrocene that 0.1~0.2 times of acid esters quality, constant temperature are stirred to react, and discharging obtains block copolymer.
The microcrystalline cellulose is the microcrystalline cellulose that levelling off degree of polymerization is 100~120.
The anionic polyacrylamide is the anionic polyacrylamide that molecular weight is 800~12,000,000.
The defoaming agent be silicone emulsion, polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether,
Any one in polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether or dimethyl silicone polymer.
The antioxidant is any one in L-AA, anthocyanidin or tea polyphenols.
The inert gas is any one in nitrogen, helium or argon gas.
The beneficial effects of the present invention are:
(1) technical solution of the present invention, which passes through, adds embedding end copolymer and N'- cetyl-N, N- dimethyl ethyl amidine, both
Amidine group is all had in material molecular structure, wherein block copolymer can be self-assembly of miniature capsule in water solution system
Bubble structure, and in use, carbon dioxide is discharged in Skin Cell respiration, and the carbon dioxide of generation can be with amidine therein
Group reaction, thus so that amidine group in block copolymer is had positive charge, and because negatively charged on the outside of Skin Cell, it can be with band
The imitated vesicle structure of positive charge and N'- cetyl-N, N- dimethyl ethyl amidine are mutually adsorbed because of oppositely charged, to change
Become the distribution of charges on the outside of skin of face cell, cell permeability is made to change, the dopamine for being conducive to part small molecule seeps
It penetrates into inside Skin Cell；And the forming process of melanin is oxidation reaction in human skin, and dopamine molecule structure
Middle active group is abundant, can react to form high polymer with the intermediate product in melanin forming process, to effectively block black
The formation of element plays whitening effect；And partial dopamine is then contacted with oxygen in air outside Skin Cell and is aoxidized
Autohemagglutination forms poly-dopamine film in skin surface, to facilitate product film forming, and is formed well to the dirt of skin surface
Absorption so that dirt is effectively removed during tearing facial mask off；In addition, N'- cetyl-N, N- dimethyl ethyl
After amidine and carbon dioxide reaction, there is good surface-active, the oil-soluble dirt for being adsorbed in skin surface can be effectively removed,
Further function as cleaning effect；
(2) technical solution of the present invention, which passes through, adds anionic polyacrylamide, the raw materials such as microcrystalline cellulose and iron chloride, wherein acyl
Hydroxyl abundant can all form hydrogen bond structure abundant in amine groups and microcrystalline cellulose molecular structure, can be quick in skin surface
Film forming, and the addition of iron chloride can then ionize in water solution system and generate iron ion, so that anionic polyacrylamide be made to send out
First portion crosslinking, the formation of cross-linked network are conducive to for the effective components such as plants essential oil being fixed in cross-linked network structure, avoid
The loss of essential oil, and the formation of cross-linked network has and is conducive in film forming procedure that each component is effectively fixed, avoids tearing off in facial mask
During remain in skin surface and influence cleaning effect；
(3) technical solution of the present invention is by adding micro-nano sepiolite, firstly, sepiolite has stronger bonding after wetting
Performance can form a film in skin surface good adsorption, and have stronger absorption property to skin surface dirt, and pass through at modified
Micro-nano sepiolite interlayer structure after reason is widened, therefore its specific surface area and adsorptivity can be promoted, and in modification
In treatment process, surface silicon oxygen bond partial rupture in sepiolite structure and form active silicone hydroxyl, these silicone hydroxyls can be with
The substance of sepiolite absorption interacts, and has and form chemical bond with the active group in partial skin surface contaminants
Ability, thus further promoted product cleaning effect.
Specific embodiment
It is in mass ratio that 1:3~1:5 pours into the sulfuric acid mixing that sepiolite and mass fraction are 3~10% in water heating kettle, in
Temperature is 140~150 DEG C, and pressure is 1.2~2.2MPa, under the conditions of revolving speed is 300~500r/min, after 2~4h of hydro-thermal reaction,
Open water heating kettle, moment pressure release to normal pressure, filtering, obtain filter cake, and be washed with deionized filter cake until cleaning solution be in neutrality, then
Filter cake after washing is transferred in baking oven, dries under the conditions of being 105~110 DEG C in temperature to constant weight, obtains micro-nano sepiolite；It will
(N- amidino groups) dodecylacrylamide is mixed with polyethylene glycol phosphate 8:1~10:1 in mass ratio and is poured into three-necked flask,
And the paracide and polyethylene glycol phosphate of 0.1~0.2 times of polyethylene glycol phosphate quality are sequentially added into three-necked flask
Three-necked flask is then moved to digital display and tested the speed constant temperature blender with magnetic force by the ferrocene that 0.1~0.2 times of quality, in temperature be 42~
45 DEG C, under the conditions of revolving speed is 400~500r/min, after constant temperature is stirred to react 2~3h, discharging obtains block copolymer；By weight
Number meter, successively takes 20~30 parts of micro-nano sepiolites, 8~10 parts of plants essential oils, 8~10 parts of block copolymers, 4~6 parts of N'- ten
Six alkyl-N, N- dimethyl ethyl amidines, 8~10 parts of dopamines, 10~15 parts of microcrystalline celluloses, 8~10 parts of anion pps
Amide, 0.1~0.3 part of iron chloride, 3~5 parts of defoaming agents, 1~3 part of antioxidant, 40~60 parts of water are added in batch mixer, and to
It is passed through inert gas in batch mixer, displaces all air, then under the conditions of revolving speed is 600~800r/min, is stirred 2
After~4h, vacuum defoamation is filling to get micro-nano cleaning whitening mask mud.The plants essential oil is Lavender, rhodamine toner
Oil or camellia flower essential oil in any one.The microcrystalline cellulose is the microcrystalline cellulose that levelling off degree of polymerization is 100~120.
The anionic polyacrylamide is the anionic polyacrylamide that molecular weight is 800~12,000,000.The defoaming agent is emulsification
Silicone oil, polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxypropylene
Any one in polyoxyethylene glycerol ether or dimethyl silicone polymer.The antioxidant is L-AA, anthocyanidin or tea
Any one in polyphenol.The inert gas is any one in nitrogen, helium or argon gas.
In mass ratio it is that 1:5 pours into the sulfuric acid mixing that sepiolite and mass fraction are 10% in water heating kettle, is in temperature
150 DEG C, pressure 2.2MPa, under the conditions of revolving speed is 500r/min, after hydro-thermal reaction 4h, water heating kettle is opened, moment pressure release is to normal
Pressure, filtering, obtains filter cake, and filter cake is washed with deionized until cleaning solution is in neutrality, then the filter cake after washing is transferred to baking oven
In, it dries under the conditions of being 110 DEG C in temperature to constant weight, obtains micro-nano sepiolite；By (N- amidino groups) dodecylacrylamide with
Polyethylene glycol phosphate 10:1 in mass ratio mixing is poured into three-necked flask, and polyethylene glycol phosphorus is sequentially added into three-necked flask
The ferrocene of 0.2 times of the paracide and polyethylene glycol phosphate quality that 0.2 times of acid esters quality, then moves to number for three-necked flask
The constant temperature blender with magnetic force that tests the speed is shown, is 45 DEG C in temperature, under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 3h, discharges,
Obtain block copolymer；According to parts by weight, 30 parts of micro-nano sepiolites are successively taken, 10 parts of plants essential oils, 10 parts of block copolymers,
6 parts of N'- cetyl-N, N- dimethyl ethyl amidines, 10 parts of dopamines, 15 parts of microcrystalline celluloses, 10 parts of anion pp acyls
Amine, 0.3 part of iron chloride, 5 parts of defoaming agents, 3 parts of antioxidant, 60 parts of water are added in batch mixer, and are passed through indifferent gas into batch mixer
Body displaces all air, then in revolving speed be 800r/min under the conditions of, after being stirred 4h, vacuum defoamation, it is filling to get
Micro-nano cleaning whitening mask mud.The plants essential oil is Lavender.The microcrystalline cellulose is that levelling off degree of polymerization is 120
Microcrystalline cellulose.The anionic polyacrylamide is the anionic polyacrylamide that molecular weight is 12,000,000.The defoaming
Agent is silicone emulsion.The antioxidant is L-AA.The inert gas is nitrogen.
(N- amidino groups) dodecylacrylamide is mixed with polyethylene glycol phosphate 10:1 in mass ratio and pours into three mouthfuls of burnings
In bottle, and sequentially add into three-necked flask the paracide and polyethylene glycol phosphate of 0.2 times of polyethylene glycol phosphate quality
Three-necked flask is then moved to digital display and tested the speed constant temperature blender with magnetic force by the ferrocene that 0.2 times of quality, in temperature be 45 DEG C, revolving speed
Under the conditions of 500r/min, after constant temperature is stirred to react 3h, discharging obtains block copolymer；According to parts by weight, 30 parts of seas are successively taken
Afrodite, 10 parts of plants essential oils, 10 parts of block copolymers, 6 parts of N'- cetyl-N, N- dimethyl ethyl amidines, 10 parts of dopamines,
15 parts of microcrystalline celluloses, 10 parts of anionic polyacrylamide, 0.3 part of iron chloride, 5 parts of defoaming agents, 3 parts of antioxidant, 60 parts of water add
Enter in batch mixer, and be passed through inert gas into batch mixer, displace all air, then in revolving speed be 800r/min condition
Under, after being stirred 4h, vacuum defoamation is filling to get micro-nano cleaning whitening mask mud.The plants essential oil is lavender essence
Oil.The microcrystalline cellulose is the microcrystalline cellulose that levelling off degree of polymerization is 120.The anionic polyacrylamide is that molecular weight is
12000000 anionic polyacrylamide.The defoaming agent is silicone emulsion.The antioxidant is L-AA.The inertia
Gas is nitrogen.
(N- amidino groups) dodecylacrylamide is mixed with polyethylene glycol phosphate 10:1 in mass ratio and pours into three mouthfuls of burnings
In bottle, and sequentially add into three-necked flask the paracide and polyethylene glycol phosphate of 0.2 times of polyethylene glycol phosphate quality
Three-necked flask is then moved to digital display and tested the speed constant temperature blender with magnetic force by the ferrocene that 0.2 times of quality, in temperature be 45 DEG C, revolving speed
Under the conditions of 500r/min, after constant temperature is stirred to react 3h, discharging obtains block copolymer；According to parts by weight, 10 parts of plants are successively taken
Object essential oil, 10 parts of block copolymers, 6 parts of N'- cetyl-N, N- dimethyl ethyl amidines, 10 parts of dopamines, 15 parts of microcrystalline celluloses
Element, 10 parts of anionic polyacrylamide, 0.3 part of iron chloride, 5 parts of defoaming agents, 3 parts of antioxidant, 60 parts of water are added in batch mixer,
And inert gas is passed through into batch mixer, all air are displaced, then under the conditions of revolving speed is 800r/min, are stirred 4h
Afterwards, vacuum defoamation, it is filling to get micro-nano cleaning whitening mask mud.The plants essential oil is Lavender.The crystallite is fine
Dimension element is the microcrystalline cellulose that levelling off degree of polymerization is 120.The anionic polyacrylamide be molecular weight be 12,000,000 yin from
Sub- polyacrylamide.The defoaming agent is silicone emulsion.The antioxidant is L-AA.The inert gas is nitrogen.
In mass ratio it is that 1:5 pours into the sulfuric acid mixing that sepiolite and mass fraction are 10% in water heating kettle, is in temperature
150 DEG C, pressure 2.2MPa, under the conditions of revolving speed is 500r/min, after hydro-thermal reaction 4h, water heating kettle is opened, moment pressure release is to normal
Pressure, filtering, obtains filter cake, and filter cake is washed with deionized until cleaning solution is in neutrality, then the filter cake after washing is transferred to baking oven
In, it dries under the conditions of being 110 DEG C in temperature to constant weight, obtains micro-nano sepiolite；According to parts by weight, successively take 30 parts it is micro-nano
Sepiolite, 10 parts of plants essential oils, 6 parts of N'- cetyl-N, N- dimethyl ethyl amidines, 10 parts of dopamines, 15 parts of microcrystalline celluloses
Element, 10 parts of anionic polyacrylamide, 0.3 part of iron chloride, 5 parts of defoaming agents, 3 parts of antioxidant, 60 parts of water are added in batch mixer,
And inert gas is passed through into batch mixer, all air are displaced, then under the conditions of revolving speed is 800r/min, are stirred 4h
Afterwards, vacuum defoamation, it is filling to get micro-nano cleaning whitening mask mud.The plants essential oil is Lavender.The crystallite is fine
Dimension element is the microcrystalline cellulose that levelling off degree of polymerization is 120.The anionic polyacrylamide be molecular weight be 12,000,000 yin from
Sub- polyacrylamide.The defoaming agent is silicone emulsion.The antioxidant is L-AA.The inert gas is nitrogen.
In mass ratio it is that 1:5 pours into the sulfuric acid mixing that sepiolite and mass fraction are 10% in water heating kettle, is in temperature
150 DEG C, pressure 2.2MPa, under the conditions of revolving speed is 500r/min, after hydro-thermal reaction 4h, water heating kettle is opened, moment pressure release is to normal
Pressure, filtering, obtains filter cake, and filter cake is washed with deionized until cleaning solution is in neutrality, then the filter cake after washing is transferred to baking oven
In, it dries under the conditions of being 110 DEG C in temperature to constant weight, obtains micro-nano sepiolite；By (N- amidino groups) dodecylacrylamide with
Polyethylene glycol phosphate 10:1 in mass ratio mixing is poured into three-necked flask, and polyethylene glycol phosphorus is sequentially added into three-necked flask
The ferrocene of 0.2 times of the paracide and polyethylene glycol phosphate quality that 0.2 times of acid esters quality, then moves to number for three-necked flask
The constant temperature blender with magnetic force that tests the speed is shown, is 45 DEG C in temperature, under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 3h, discharges,
Obtain block copolymer；According to parts by weight, 30 parts of micro-nano sepiolites are successively taken, 10 parts of plants essential oils, 10 parts of block copolymers,
10 parts of dopamines, 15 parts of microcrystalline celluloses, 10 parts of anionic polyacrylamide, 0.3 part of iron chloride, 5 parts of defoaming agents, 3 parts of antioxygens
Agent, 60 parts of water are added in batch mixer, and are passed through inert gas into batch mixer, displace all air, be then in revolving speed
Under the conditions of 800r/min, after being stirred 4h, vacuum defoamation is filling to get micro-nano cleaning whitening mask mud.The plant essence
Oil is Lavender.The microcrystalline cellulose is the microcrystalline cellulose that levelling off degree of polymerization is 120.The anion pp acyl
Amine is the anionic polyacrylamide that molecular weight is 12,000,000.The defoaming agent is silicone emulsion.The antioxidant is that L- is anti-bad
Hematic acid.The inert gas is nitrogen.
In mass ratio it is that 1:5 pours into the sulfuric acid mixing that sepiolite and mass fraction are 10% in water heating kettle, is in temperature
150 DEG C, pressure 2.2MPa, under the conditions of revolving speed is 500r/min, after hydro-thermal reaction 4h, water heating kettle is opened, moment pressure release is to normal
Pressure, filtering, obtains filter cake, and filter cake is washed with deionized until cleaning solution is in neutrality, then the filter cake after washing is transferred to baking oven
In, it dries under the conditions of being 110 DEG C in temperature to constant weight, obtains micro-nano sepiolite；By (N- amidino groups) dodecylacrylamide with
Polyethylene glycol phosphate 10:1 in mass ratio mixing is poured into three-necked flask, and polyethylene glycol phosphorus is sequentially added into three-necked flask
The ferrocene of 0.2 times of the paracide and polyethylene glycol phosphate quality that 0.2 times of acid esters quality, then moves to number for three-necked flask
The constant temperature blender with magnetic force that tests the speed is shown, is 45 DEG C in temperature, under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 3h, discharges,
Obtain block copolymer；According to parts by weight, 30 parts of micro-nano sepiolites are successively taken, 10 parts of plants essential oils, 10 parts of block copolymers,
6 parts of N'- cetyl-N, N- dimethyl ethyl amidines, 15 parts of microcrystalline celluloses, 10 parts of anionic polyacrylamide, 0.3 part of chlorination
Iron, 5 parts of defoaming agents, 3 parts of antioxidant, 60 parts of water are added in batch mixer, and are passed through inert gas into batch mixer, displace institute
There is air, then under the conditions of revolving speed is 800r/min, after being stirred 4h, vacuum defoamation is filling to get micro-nano cleaning beauty
Fine flour film mud.The plants essential oil is Lavender.The microcrystalline cellulose is the microcrystalline cellulose that levelling off degree of polymerization is 120
Element.The anionic polyacrylamide is the anionic polyacrylamide that molecular weight is 12,000,000.The defoaming agent is emulsification silicon
Oil.The antioxidant is L-AA.The inert gas is nitrogen.
In mass ratio it is that 1:5 pours into the sulfuric acid mixing that sepiolite and mass fraction are 10% in water heating kettle, is in temperature
150 DEG C, pressure 2.2MPa, under the conditions of revolving speed is 500r/min, after hydro-thermal reaction 4h, water heating kettle is opened, moment pressure release is to normal
Pressure, filtering, obtains filter cake, and filter cake is washed with deionized until cleaning solution is in neutrality, then the filter cake after washing is transferred to baking oven
In, it dries under the conditions of being 110 DEG C in temperature to constant weight, obtains micro-nano sepiolite；By (N- amidino groups) dodecylacrylamide with
Polyethylene glycol phosphate 10:1 in mass ratio mixing is poured into three-necked flask, and polyethylene glycol phosphorus is sequentially added into three-necked flask
The ferrocene of 0.2 times of the paracide and polyethylene glycol phosphate quality that 0.2 times of acid esters quality, then moves to number for three-necked flask
The constant temperature blender with magnetic force that tests the speed is shown, is 45 DEG C in temperature, under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 3h, discharges,
Obtain block copolymer；According to parts by weight, 30 parts of micro-nano sepiolites are successively taken, 10 parts of plants essential oils, 10 parts of block copolymers,
6 parts of N'- cetyl-N, N- dimethyl ethyl amidines, 10 parts of dopamines, 15 parts of microcrystalline celluloses, 0.3 part of iron chloride, 5 parts of defoamings
Agent, 3 parts of antioxidant, 60 parts of water are added in batch mixer, and are passed through inert gas into batch mixer, displace all air, then
Under the conditions of revolving speed is 800r/min, after being stirred 4h, vacuum defoamation is filling to get micro-nano cleaning whitening mask mud.Institute
Stating plants essential oil is Lavender.The microcrystalline cellulose is the microcrystalline cellulose that levelling off degree of polymerization is 120.The defoaming agent
For silicone emulsion.The antioxidant is L-AA.The inert gas is nitrogen.
In mass ratio it is that 1:5 pours into the sulfuric acid mixing that sepiolite and mass fraction are 10% in water heating kettle, is in temperature
150 DEG C, pressure 2.2MPa, under the conditions of revolving speed is 500r/min, after hydro-thermal reaction 4h, water heating kettle is opened, moment pressure release is to normal
Pressure, filtering, obtains filter cake, and filter cake is washed with deionized until cleaning solution is in neutrality, then the filter cake after washing is transferred to baking oven
In, it dries under the conditions of being 110 DEG C in temperature to constant weight, obtains micro-nano sepiolite；By (N- amidino groups) dodecylacrylamide with
Polyethylene glycol phosphate 10:1 in mass ratio mixing is poured into three-necked flask, and polyethylene glycol phosphorus is sequentially added into three-necked flask
The ferrocene of 0.2 times of the paracide and polyethylene glycol phosphate quality that 0.2 times of acid esters quality, then moves to number for three-necked flask
The constant temperature blender with magnetic force that tests the speed is shown, is 45 DEG C in temperature, under the conditions of revolving speed is 500r/min, after constant temperature is stirred to react 3h, discharges,
Obtain block copolymer；According to parts by weight, 30 parts of micro-nano sepiolites are successively taken, 10 parts of plants essential oils, 10 parts of block copolymers,
6 parts of N'- cetyl-N, N- dimethyl ethyl amidines, 10 parts of dopamines, 15 parts of microcrystalline celluloses, 10 parts of anion pp acyls
Amine, 5 parts of defoaming agents, 3 parts of antioxidant, 60 parts of water are added in batch mixer, and are passed through inert gas into batch mixer, displace institute
There is air, then under the conditions of revolving speed is 800r/min, after being stirred 4h, vacuum defoamation is filling to get micro-nano cleaning beauty
Fine flour film mud.The plants essential oil is Lavender.The microcrystalline cellulose is the microcrystalline cellulose that levelling off degree of polymerization is 120
Element.The anionic polyacrylamide is the anionic polyacrylamide that molecular weight is 12,000,000.The defoaming agent is emulsification silicon
Oil.The antioxidant is L-AA.The inert gas is nitrogen.
Comparative example: certain commercially available brand facial mask mud.
1 to 8 gained facial mask mud of example and comparative example product are subjected to performance detection, the specific detection method is as follows:
20 subjects of each experimental group selection, the age 20~40 years old.After cleaning face, above-mentioned facial mask is applied to face, 20 points
It washes off after clock, uses 2~3 times weekly, after continuous use one month, use feeling investigation is carried out to subject, evaluation is divided into 5
Grade: 90% or more subject is satisfied, comments 5 points；80%~90% subject is satisfied, comments 4 points；70%~80% subject is satisfied, comments 3
Point；60~70% subjects are satisfied, comment 2 points；It is satisfied lower than 60% subject, comment 1 point.
Specific testing result is as shown in table 1:
Table 1: performance detection table
| Use feeling | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Example 6 | Example 7 | Example 8 | Comparative example |
| Remove blackhead effect | 5 | 4 | 4 | 3 | 3 | 4 | 3 | 4 | 3 |
| Pore refining effect | 4 | 3 | 2 | 2 | 3 | 2 | 3 | 2 | 2 |
| Deep clean effect | 5 | 4 | 3 | 4 | 3 | 4 | 4 | 3 | 3 |
By 1 testing result of table it is found that the micro-nano cleaning whitening mask mud of present invention gained has excellent cleaning effect.
Claims (9)
1. a kind of micro-nano cleaning whitening mask mud, it is characterised in that the raw material including following parts by weight:
20~30 parts of micro-nano sepiolite
8~10 parts of plants essential oil
8~10 parts of block copolymer
4~6 parts of amidine of N'- cetyl-N, N- dimethyl ethyl
8~10 parts of dopamine
10~15 parts of microcrystalline cellulose
8~10 parts of anionic polyacrylamide
0.1~0.3 part of iron chloride
3~5 parts of defoaming agent
1~3 part of antioxidant
40~60 parts of water
The process for preparation of the micro-nano cleaning whitening mask mud are as follows:
(1) each component is weighed by raw material composition；
(2) by micro-nano sepiolite, plants essential oil, block copolymer, N'- cetyl-N, N- dimethyl ethyl amidine, DOPA
Amine, microcrystalline cellulose, anionic polyacrylamide, iron chloride, defoaming agent, preservative, antioxidant sequentially add in water, in inertia
Under gas protection status, after being stirred 2~4h, vacuum defoamation is filling to get micro-nano cleaning whitening mask mud.
2. the micro-nano cleaning whitening mask mud of one kind according to claim 1, which is characterized in that the micro-nano sepiolite
Preparation process are as follows: by sepiolite and sulfuric acid be in mass ratio after 1:3~1:5 is mixed, 2~4h of hydro-thermal reaction, then separated is dry
And washing, obtain micro-nano sepiolite.
3. the micro-nano cleaning whitening mask mud of one kind according to claim 1, which is characterized in that the plants essential oil is to smoke
Any one in clothing grass essential oil, Rosa Damascana or camellia flower essential oil.
4. the micro-nano cleaning whitening mask mud of one kind according to claim 1, which is characterized in that the block copolymer system
Standby process are as follows: (N- amidino groups) dodecylacrylamide is mixed with polyethylene glycol phosphate 8:1~10:1 in mass ratio, and is added
Enter the paracide of 0.1~0.2 times of polyethylene glycol phosphate quality and two cyclopentadienyls of 0.1~0.2 times of polyethylene glycol phosphate quality
Iron, constant temperature are stirred to react, and discharging obtains block copolymer.
5. the micro-nano cleaning whitening mask mud of one kind according to claim 1, which is characterized in that the microcrystalline cellulose is
The microcrystalline cellulose that levelling off degree of polymerization is 100~120.
6. the micro-nano cleaning whitening mask mud of one kind according to claim 1, which is characterized in that the anion pp
Amide is the anionic polyacrylamide that molecular weight is 800~12,000,000.
7. the micro-nano cleaning whitening mask mud of one kind according to claim 1, which is characterized in that the defoaming agent is emulsification
Silicone oil, polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxypropylene
Any one in polyoxyethylene glycerol ether or dimethyl silicone polymer.
8. the micro-nano cleaning whitening mask mud of one kind according to claim 1, which is characterized in that the antioxidant is anti-for L-
Any one in bad hematic acid, anthocyanidin or tea polyphenols.
9. the micro-nano cleaning whitening mask mud of one kind according to claim 1, which is characterized in that the inert gas is nitrogen
Any one in gas, helium or argon gas.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109528616A (en) * | 2019-01-25 | 2019-03-29 | 无锡悦禧玫瑰科技有限公司 | A kind of preparation method of rose facial mask |
| CN110040938A (en) * | 2019-03-11 | 2019-07-23 | 南京思宇环保科技有限公司 | A kind of Organic-inorganic composite sludge dehydration conditioner |
-
2018
- 2018-08-31 CN CN201811013373.7A patent/CN109044886A/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109528616A (en) * | 2019-01-25 | 2019-03-29 | 无锡悦禧玫瑰科技有限公司 | A kind of preparation method of rose facial mask |
| CN110040938A (en) * | 2019-03-11 | 2019-07-23 | 南京思宇环保科技有限公司 | A kind of Organic-inorganic composite sludge dehydration conditioner |
| CN110040938B (en) * | 2019-03-11 | 2021-08-17 | 大地绿源环保科技(北京)有限公司 | Organic-inorganic composite sludge dewatering conditioner |
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