CN107530686A - 氨合成催化剂及其制备方法 - Google Patents

氨合成催化剂及其制备方法 Download PDF

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Publication number
CN107530686A
CN107530686A CN201680011209.5A CN201680011209A CN107530686A CN 107530686 A CN107530686 A CN 107530686A CN 201680011209 A CN201680011209 A CN 201680011209A CN 107530686 A CN107530686 A CN 107530686A
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CN
China
Prior art keywords
ruthenium
catalyst
supported
temperature
ammonia synthesis
Prior art date
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Pending
Application number
CN201680011209.5A
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English (en)
Chinese (zh)
Inventor
永冈胜俊
今村和也
佐藤胜俊
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National Research And Development Corp Science And Technology Revitalization Organization
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National Research And Development Corp Science And Technology Revitalization Organization
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Priority claimed from PCT/JP2016/054941 external-priority patent/WO2016133213A1/ja
Publication of CN107530686A publication Critical patent/CN107530686A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F17/00—Compounds of rare earth metals
    • C01F17/20—Compounds containing only rare earth metals as the metal element
    • C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
    • C01F17/224—Oxides or hydroxides of lanthanides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/395—Thickness of the active catalytic layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0225—Coating of metal substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00—Ammonia; Compounds thereof
    • C01C1/02—Preparation, purification or separation of ammonia
    • C01C1/04—Preparation of ammonia by synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00—Ammonia; Compounds thereof
    • C01C1/02—Preparation, purification or separation of ammonia
    • C01C1/04—Preparation of ammonia by synthesis
    • C01C1/0405—Preparation of ammonia by synthesis from N2 and H2 in presence of a catalyst
    • C01C1/0411—Preparation of ammonia by synthesis from N2 and H2 in presence of a catalyst characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/85—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by XPS, EDX or EDAX data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Catalysts (AREA)
CN201680011209.5A 2015-02-20 2016-02-19 氨合成催化剂及其制备方法 Pending CN107530686A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2015-032192 2015-02-20
JP2015032192 2015-02-20
JP2016021712A JP2016155123A (ja) 2015-02-20 2016-02-08 アンモニア合成触媒とその製造方法
JP2016-021712 2016-02-08
PCT/JP2016/054941 WO2016133213A1 (ja) 2015-02-20 2016-02-19 アンモニア合成触媒とその製造方法

Publications (1)

Publication Number Publication Date
CN107530686A true CN107530686A (zh) 2018-01-02

Family

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Family Applications (1)

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CN201680011209.5A Pending CN107530686A (zh) 2015-02-20 2016-02-19 氨合成催化剂及其制备方法

Country Status (4)

Country Link
US (1) US20180071719A1 (cg-RX-API-DMAC10.html)
EP (1) EP3260198A4 (cg-RX-API-DMAC10.html)
JP (1) JP2016155123A (cg-RX-API-DMAC10.html)
CN (1) CN107530686A (cg-RX-API-DMAC10.html)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112387276A (zh) * 2019-08-15 2021-02-23 中国科学院大连化学物理研究所 一种用于氨合成的负载型钌团簇催化剂及其制备方法和应用

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109126787B (zh) * 2017-06-16 2021-08-03 中国科学院大连化学物理研究所 一种用于氨合成的稀土金属氧化物负载钌催化剂及其应用
JP7590730B2 (ja) * 2020-10-06 2024-11-27 株式会社豊田中央研究所 アンモニア合成触媒、アンモニア合成触媒の製造方法、及び、アンモニアの合成方法
CN114082413A (zh) * 2021-11-19 2022-02-25 中国科学院城市环境研究所 一种镨氧化物催化剂及其制备方法和用途
EP4552737A4 (en) 2022-07-04 2026-06-10 Eneos Holdings Inc AMMONIA SYNTHESIS CATALYST AND AMMONIA SYNTHESIS PROCESS
CN116272979A (zh) * 2023-03-31 2023-06-23 上海大学 一种钌负载的氧氢化钇合成氨催化剂及其制备方法
CN119680468B (zh) * 2024-11-05 2025-10-28 中国五环工程有限公司 柔性合成氨工艺

Citations (7)

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US4631263A (en) * 1982-01-18 1986-12-23 Hitachi, Ltd. Water-repellent catalyst for gas/liquid reactions and process for gas/liquid reactions by using the same
CN1390637A (zh) * 2002-06-03 2003-01-15 福州大学 一种钌－氧化铝催化剂及其制备方法
US20060043492A1 (en) * 2004-08-26 2006-03-02 Micron Technology, Inc. Ruthenium gate for a lanthanide oxide dielectric layer
US7255845B2 (en) * 2002-08-15 2007-08-14 Velocys, Inc. Process for conducting an equilibrium limited chemical reaction in a single stage process channel
JP2011056488A (ja) * 2009-09-09 2011-03-24 Yusaku Takita アンモニア改質触媒とこれを用いた水素の製造方法
JP2013111562A (ja) * 2011-11-30 2013-06-10 Sumitomo Chemical Co Ltd 組成物及び該組成物を用いたアンモニア製造方法
JP2013111563A (ja) * 2011-11-30 2013-06-10 Sumitomo Chemical Co Ltd 組成物及び該組成物を用いたアンモニア製造方法

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JPH08173806A (ja) * 1994-12-26 1996-07-09 Nissan Motor Co Ltd 排気ガス浄化用触媒及びその製造方法
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JP2006290732A (ja) * 2005-03-17 2006-10-26 Toshiba Corp Ｃｏ除去方法、ｃｏ除去装置とこの製造方法、これを用いた水素発生装置およびこれを用いた燃料電池システム
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Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4631263A (en) * 1982-01-18 1986-12-23 Hitachi, Ltd. Water-repellent catalyst for gas/liquid reactions and process for gas/liquid reactions by using the same
CN1390637A (zh) * 2002-06-03 2003-01-15 福州大学 一种钌－氧化铝催化剂及其制备方法
US7255845B2 (en) * 2002-08-15 2007-08-14 Velocys, Inc. Process for conducting an equilibrium limited chemical reaction in a single stage process channel
US20060043492A1 (en) * 2004-08-26 2006-03-02 Micron Technology, Inc. Ruthenium gate for a lanthanide oxide dielectric layer
JP2011056488A (ja) * 2009-09-09 2011-03-24 Yusaku Takita アンモニア改質触媒とこれを用いた水素の製造方法
JP2013111562A (ja) * 2011-11-30 2013-06-10 Sumitomo Chemical Co Ltd 組成物及び該組成物を用いたアンモニア製造方法
JP2013111563A (ja) * 2011-11-30 2013-06-10 Sumitomo Chemical Co Ltd 組成物及び該組成物を用いたアンモニア製造方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112387276A (zh) * 2019-08-15 2021-02-23 中国科学院大连化学物理研究所 一种用于氨合成的负载型钌团簇催化剂及其制备方法和应用

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EP3260198A1 (en) 2017-12-27
EP3260198A4 (en) 2018-12-05
US20180071719A1 (en) 2018-03-15
JP2016155123A (ja) 2016-09-01

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